CN108317602B - Cascaded annular cylinder discharge and catalysis combined air purification system - Google Patents
Cascaded annular cylinder discharge and catalysis combined air purification system Download PDFInfo
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/28—Arrangement or mounting of filters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/15—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means
- F24F8/167—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means using catalytic reactions
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/192—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by electrical means, e.g. by applying electrostatic fields or high voltages
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
本发明公开了一种级联式环筒放电与催化联合空气净化系统,包括净化器本体和风机,净化器本体包括多级放电与催化联合单元、第一气体检测单元、第二气体检测单元、PDM电源和数据采集与控制单元,多级放电与催化联用单元与进气口相连,出气口、第一、第二气体检测单元均与多级放电与催化联用单元相连,PDM电源与多级放电与催化联用单元相连,第一、第二气体检测单元和数据采集与控制单元相连,数据采集与控制单元分别与PDM电源、进气口相连,多级放电与催化联用单元包括介质管、导电金属杆、若干对高压电极和低压电极以及若干个催化结构;具有能够实现自动检测,处理效率高、能耗低、处理范围广、无二次污染、成本低的特点。
The invention discloses a cascading ring-tube discharge and catalysis combined air purification system, comprising a purifier body and a fan. The purifier body includes a multi-stage discharge and catalysis combined unit, a first gas detection unit, a second gas detection unit, The PDM power supply and data acquisition and control unit, the multi-stage discharge and catalysis combined unit is connected to the air inlet, the air outlet, the first and second gas detection units are all connected to the multi-stage discharge and catalysis combined unit, and the PDM power supply is connected to the multi-stage discharge and catalysis combined unit. The stage discharge is connected with the catalytic combined unit, the first and second gas detection units are connected with the data acquisition and control unit, the data acquisition and control unit are respectively connected with the PDM power supply and the air inlet, and the multi-stage discharge and catalytic combined unit includes a medium Tubes, conductive metal rods, several pairs of high-voltage electrodes and low-voltage electrodes, and several catalytic structures; it has the characteristics of being able to realize automatic detection, high processing efficiency, low energy consumption, wide processing range, no secondary pollution, and low cost.
Description
技术领域technical field
本发明属于空气净化领域,具体涉及一种级联式环筒放电与催化联合空气净化系统。The invention belongs to the field of air purification, and in particular relates to a cascaded ring-tube discharge and catalysis combined air purification system.
背景技术Background technique
空气污染问题日益尖锐,如何解决空气污染问题备受关注。近年来,PM2.5(环境空气中空气动力学当量直径小于等于2.5μm的颗粒物)被列为一级致癌物,中国每年工业烟(粉)尘排放超1278.1万吨(燃煤烟(粉)尘排放达100亿吨),中国目前约有10亿人生活在总悬浮颗粒物超标的环境中。减少空气污染不仅可以挽救数百万生命,还可以减少巨大的经济损失,解决空气污染问题已经刻不容缓。The problem of air pollution is becoming more and more acute, and how to solve the problem of air pollution has attracted much attention. In recent years, PM2.5 (particulate matter with aerodynamic equivalent diameter less than or equal to 2.5 μm in ambient air) has been listed as a first-class carcinogen, and China’s annual industrial smoke (powder) dust emissions exceed 12.781 million tons (burning soot (powder) Dust emissions reached 10 billion tons), and about 1 billion people in China currently live in an environment where the total suspended particulate matter exceeds the standard. Reducing air pollution can not only save millions of lives, but also reduce huge economic losses. It is urgent to solve the problem of air pollution.
目前,空气净化技术主要有过滤技术、臭氧技术、紫外线技术、负离子技术、光媒触技术等。大量研究表明紫外线技术无法去除有机污染物、异味和细小颗粒物等;而过滤技术无法去除细小颗粒物,效率低,且需定期更换滤网,成本过大;静电除尘技术能耗高,且产生固体废物难于清理;臭氧技术产生的臭氧浓度过高,对人体健康构成威胁。总之,这些技术在去除污染物种类、成本、效率以及无二次污染等方面各有不足。At present, air purification technologies mainly include filtration technology, ozone technology, ultraviolet technology, negative ion technology, and photocatalytic technology. A large number of studies have shown that UV technology cannot remove organic pollutants, odors and fine particulate matter, etc.; while filtration technology cannot remove fine particulate matter, the efficiency is low, and the filter screen needs to be replaced regularly, which is too expensive; electrostatic dust removal technology consumes high energy and generates solid waste. Difficult to clean up; ozone technology produces high concentrations of ozone, posing a threat to human health. All in all, these technologies have their own shortcomings in the types of pollutants, cost, efficiency, and no secondary pollution.
专利CN105170327A公开了一种电晕放电空气净化装置,使用高压电源驱动,在针板电极之间的区域内放电,并使用光催化处理副产物。但是,并没有在处理有毒气体的基础上,对其进行吸附。专利CN105920985A公开了一种介质阻挡放电等离子体处理废气的装置,使用高压电源驱动,放电电极为线-筒式。但是,其结构的限制,净化效率不高,且没有吸附、处理有毒气体中的有毒成分的作用。Patent CN105170327A discloses a corona discharge air purification device, which is driven by a high voltage power supply, discharges in the area between the needle plate electrodes, and uses photocatalysis to treat by-products. However, it has not been adsorbed on the basis of treating toxic gases. Patent CN105920985A discloses a device for treating waste gas by dielectric barrier discharge plasma, which is driven by a high-voltage power supply, and the discharge electrode is a wire-cylinder type. However, due to the limitation of its structure, the purification efficiency is not high, and it has no function of adsorbing and treating toxic components in toxic gases.
发明内容SUMMARY OF THE INVENTION
为解决上述现有技术中存在的技术问题,本发明提供了一种利用介质阻挡放电反应器处理有毒害气体,同时利用化学催化剂催化吸附副产物,处理效率高、能耗低、处理范围广、无二次污染、成本低的级联式环筒放电与催化联合空气净化系统。In order to solve the technical problems existing in the above-mentioned prior art, the present invention provides a process of using a dielectric barrier discharge reactor to process toxic gases, and using a chemical catalyst to catalyze the adsorption of by-products, with high treatment efficiency, low energy consumption, wide treatment range, A cascaded ring-tube discharge and catalytic combined air purification system with no secondary pollution and low cost.
本发明解决其技术问题是通过以下技术方案实现的:The present invention solves its technical problem and realizes through the following technical solutions:
一种级联式环筒放电与催化联合空气净化系统,包括净化器本体和风机,所述净化器本体上设有进气口和出气口,所述风机安装于净化器本体内,所述净化器本体包括多级放电与催化联用单元、第一气体检测单元、第二气体检测单元、PDM电源和数据采集与控制单元,所述第一气体检测单元的气体输入端与进气口相连,所述多级放电与催化联用单元的气体输入端与第一气体检测单元的气体输出端相连,所述多级放电与催化联用单元的气体输出端与第二气体检测单元的气体输入端相连,所述第二气体检测单元的气体输出端与出气口相连,所述PDM电源的输出端与多级放电与催化联用单元的输入端相连,第一气体检测单元的输出端、第二气体检测单元的输出端和数据采集与控制单元的输入端相连,所述数据采集与控制单元的输出端与进气口相连,所述PDM电源与数据采集与控制单元双向连接;所述多级放电与催化联用单元包括介质管、导电金属杆、若干对高压电极和低压电极以及若干个催化结构,所述高压电极置于介质管内,低压电极置于介质管外表面上,每对所述高压电极和低压电极沿介质管径向对齐,所有所述高压电极等间距轴向排布,且由导电金属杆穿过中心固定,所述导电金属杆固定于介质管的中心轴位置上,相邻两个所述高压电极之间安装有催化结构。A cascading ring-tube discharge and catalytic combined air purification system includes a purifier body and a fan, the purifier body is provided with an air inlet and an air outlet, the fan is installed in the purifier body, and the purification The device body includes a multi-stage discharge and catalysis combined unit, a first gas detection unit, a second gas detection unit, a PDM power supply and a data acquisition and control unit, and the gas input end of the first gas detection unit is connected to the air inlet, The gas input end of the multi-stage discharge and catalysis combined unit is connected with the gas output end of the first gas detection unit, and the gas output end of the multi-stage discharge and catalysis combined unit is connected with the gas input end of the second gas detection unit Connected, the gas output end of the second gas detection unit is connected with the gas outlet, the output end of the PDM power supply is connected with the input end of the multi-stage discharge and catalysis combined unit, the output end of the first gas detection unit, the second The output end of the gas detection unit is connected with the input end of the data acquisition and control unit, the output end of the data acquisition and control unit is connected with the air inlet, and the PDM power supply is bidirectionally connected with the data acquisition and control unit; The combined discharge and catalysis unit includes a dielectric tube, a conductive metal rod, several pairs of high-voltage electrodes, low-voltage electrodes, and several catalytic structures. The high-voltage electrodes are placed in the dielectric tube, and the low-voltage electrodes are placed on the outer surface of the dielectric tube. The high-voltage electrode and the low-voltage electrode are radially aligned along the medium tube, and all the high-voltage electrodes are axially arranged at equal intervals, and are fixed by a conductive metal rod passing through the center, and the conductive metal rod is fixed on the central axis position of the medium tube. A catalytic structure is installed between two adjacent high-voltage electrodes.
作为本发明进一步改进的技术方案,所述净化器本体还包括供电电压采集单元和放电电流采集单元,所述供电电压采集单元的两端分别连接多级放电与催化联用单元的输入端和数据采集与控制单元的输入端,所述放电电流采集单元的两端分别连接多级放电与催化联用单元的输出端和数据采集与控制单元的输入端。As a further improved technical solution of the present invention, the purifier body further includes a power supply voltage collection unit and a discharge current collection unit, and both ends of the power supply voltage collection unit are respectively connected to the input end and data of the multi-stage discharge and catalysis combined unit. The input end of the collection and control unit, the two ends of the discharge current collection unit are respectively connected to the output end of the multi-stage discharge and catalysis combined unit and the input end of the data collection and control unit.
作为本发明进一步改进的技术方案,所述高压电极包括电极骨架和金属环,所述电极骨架的侧表面上均贴合安装有金属环,所述导电金属杆通过介质管两端设置的通气骨架固定于介质管内,所述通风骨架上设有若干个通风孔,所述电极骨架上还固定设置若干个导电金属桥,所述导电金属桥一端连接导电金属杆,另一端连接金属环,所述低压电极为金属箔环,相邻两个所述金属箔环中间还设置有浮动电极环,所述浮动电极环与金属箔环平行设置。As a further improved technical solution of the present invention, the high-voltage electrode includes an electrode skeleton and a metal ring, the side surfaces of the electrode skeleton are fitted with metal rings, and the conductive metal rod passes through the ventilation skeletons provided at both ends of the medium tube. It is fixed in the medium pipe, the ventilation skeleton is provided with several ventilation holes, and the electrode skeleton is also fixedly provided with several conductive metal bridges, one end of the conductive metal bridge is connected to the conductive metal rod, and the other end is connected to the metal ring. The low-voltage electrode is a metal foil ring, and a floating electrode ring is also arranged between two adjacent metal foil rings, and the floating electrode ring is arranged in parallel with the metal foil ring.
作为本发明进一步改进的技术方案,单个所述催化结构包括两块筛板和催化剂,所述催化剂均匀分散于两块筛板之间,所述筛板上正中心设有供导电金属杆穿过的金属杆通孔,表面设有若干个通气筛孔。As a further improved technical solution of the present invention, the single catalytic structure includes two sieve plates and a catalyst, the catalyst is uniformly dispersed between the two sieve plates, and the center of the sieve plate is provided with a conductive metal rod to pass through The through hole of the metal rod is provided with several ventilation sieve holes on the surface.
作为本发明进一步改进的技术方案,所述第一气体检测单元内设置第一甲醛传感器,所述第二气体检测单元内设置第二甲醛传感器。As a further improved technical solution of the present invention, a first formaldehyde sensor is arranged in the first gas detection unit, and a second formaldehyde sensor is arranged in the second gas detection unit.
作为本发明进一步改进的技术方案,所述数据采集与控制单元包括MCU、开关按键、显示单元和MCU电源,所述MCU的面板上设置开关按键,所述显示单元、MCU电源均与MCU连接,所述MCU设有第一气体检测单元AD端、第二气体检测单元AD端、供电电压采集单元AD端、放电电流采集单元AD端、PDM电源控制单元AD端、风机控制单元AD端,所述第一气体检测单元AD端与第一气体检测单元的输出端相连,所述第二气体检测单元AD端与第二气体检测单元的输出端相连,所述供电电压采集单元AD端与供电电压采集单元的输出端相连,所述放电电流采集单元AD端与放电电流采集单元的输出端相连,所述PDM电源控制单元AD端与PDM电源相连,所述风机控制单元AD端与风机相连。As a further improved technical solution of the present invention, the data acquisition and control unit includes an MCU, a switch button, a display unit and an MCU power supply, a switch button is provided on the panel of the MCU, and the display unit and the MCU power supply are both connected to the MCU, The MCU is provided with an AD end of a first gas detection unit, an AD end of a second gas detection unit, an AD end of a power supply voltage collection unit, an AD end of a discharge current collection unit, an AD end of a PDM power supply control unit, and an AD end of a fan control unit. The AD terminal of the first gas detection unit is connected to the output terminal of the first gas detection unit, the AD terminal of the second gas detection unit is connected to the output terminal of the second gas detection unit, and the AD terminal of the power supply voltage acquisition unit is connected to the power supply voltage acquisition terminal. The output end of the unit is connected, the AD end of the discharge current collection unit is connected with the output end of the discharge current collection unit, the AD end of the PDM power supply control unit is connected with the PDM power supply, and the AD end of the fan control unit is connected with the fan.
作为本发明进一步改进的技术方案,所述介质管的材料采用聚四氟乙烯、高密度聚丙烯、陶瓷或者石英。As a further improved technical solution of the present invention, the material of the medium pipe adopts polytetrafluoroethylene, high-density polypropylene, ceramics or quartz.
作为本发明进一步改进的技术方案,所述催化剂呈颗粒状。As a further improved technical solution of the present invention, the catalyst is in the form of particles.
作为本发明进一步改进的技术方案,所述数据采集与控制单元包括MCU、开关按键、显示单元和MCU电源,所述MCU的面板上设置开关按键,所述显示单元、MCU电源均与MCU连接,所述MCU设有第一甲醛传感器AD端、第二甲醛传感器AD端、供电电压采集单元AD端、放电电流采集单元AD端、PDM电源控制单元AD端、风机控制单元AD端,所述第一甲醛传感器AD端与第一甲醛传感器的输出端相连,所述第二甲醛传感器AD端与第二甲醛传感器的输出端相连,所述供电电压采集单元AD端与供电电压采集单元的输出端相连,所述放电电流采集单元AD端与放电电流采集单元的输出端相连,所述PDM电源控制单元AD端与PDM电源相连,所述风机控制单元AD端与风机相连。As a further improved technical solution of the present invention, the data acquisition and control unit includes an MCU, a switch button, a display unit and an MCU power supply, a switch button is provided on the panel of the MCU, and the display unit and the MCU power supply are both connected to the MCU, The MCU is provided with a first formaldehyde sensor AD terminal, a second formaldehyde sensor AD terminal, a power supply voltage acquisition unit AD terminal, a discharge current acquisition unit AD terminal, a PDM power supply control unit AD terminal, and a fan control unit AD terminal. The AD end of the formaldehyde sensor is connected with the output end of the first formaldehyde sensor, the AD end of the second formaldehyde sensor is connected with the output end of the second formaldehyde sensor, and the AD end of the power supply voltage acquisition unit is connected with the output end of the power supply voltage acquisition unit, The AD end of the discharge current collection unit is connected to the output end of the discharge current collection unit, the AD end of the PDM power control unit is connected to the PDM power supply, and the AD end of the fan control unit is connected to the fan.
作为本发明进一步改进的技术方案,所述催化剂为Pd或Pt附着于Mn,Co,Ni和Ag的氧化物而成的组合物。As a further improved technical solution of the present invention, the catalyst is a composition in which Pd or Pt is attached to oxides of Mn, Co, Ni and Ag.
催化结构主要是将催化剂制成颗粒状,均匀分布于容器内,为保证副产物催化吸附充分。本发明利用贵金属附着于过渡金属氧化物催化剂分解和吸附NOX和O3,臭氧降解催化剂可以使用贵金属如Pd或Pt,或者过渡金属如Mn,Co,Ni和Ag的氧化物。分解O3的主要原理是将O3转化为O2。当臭氧气体流经MnO2时,臭氧分子通过将O原子插入氧空位而结合到MnO2表面。氧空位是2-电子,并将2-电子转移到臭氧的O原子上,从而在氧空位中形成氧物种(O2-),并在空气中解吸氧基分子。然后,另一个臭氧分子与O2反应生成气相氧分子和桥联O2二聚体(过氧化物O22-),这通过原位拉曼光谱观察到。最后,过氧化物(O22-)分解释放一个氧分子,因此氧空位被回收,它可以参与下一个循环以分解臭氧。分解NO2的主要原理是在过渡金属氧化物如MnOX催化剂上的O3分解通过从Mnn+到O3的电子转移而发生。这将导致O3分解成氧分子和原子氧O*。然后,不稳定的O22–Mn(n+2)+络合物通过将氧化的锰还原成Mn2+并解吸氧分子而分解。氧化锰催化剂在O3分解过程中形成活性原子氧O*。对于其他金属氧化物(例如FeO)或贵金属(例如Pd)也是类似的分解机制。另外,NO2可以被O*和O3氧化成NO3。且NO3极易消失,转化为固体N2O5。The catalytic structure is mainly to make the catalyst into particles and evenly distribute it in the container to ensure sufficient catalytic adsorption of by-products. The present invention utilizes noble metals attached to transition metal oxide catalysts to decompose and adsorb NOx and O 3 , and ozone degradation catalysts can use noble metals such as Pd or Pt, or oxides of transition metals such as Mn, Co, Ni and Ag. The main principle of decomposing O 3 is to convert O 3 to O 2 . When ozone gas flows through MnO2, ozone molecules bind to the surface of MnO2 by inserting O atoms into oxygen vacancies. Oxygen vacancies are 2-electrons, and the 2-electrons are transferred to the O atom of ozone, thereby forming oxygen species (O 2 -) in the oxygen vacancies and desorbing oxygen molecules in air. Then, another ozone molecule reacts with O 2 to form gas-phase oxygen molecules and a bridged O 2 dimer (peroxide O 22 − ), which is observed by in situ Raman spectroscopy. Finally, peroxide (O 22 − ) decomposes to release an oxygen molecule, so the oxygen vacancy is recovered, which can participate in the next cycle to decompose ozone. The main principle for the decomposition of NO2 is that the decomposition of O3 over transition metal oxides such as MnOx catalysts occurs through electron transfer from Mnn + to O3 . This will cause O to decompose into molecular oxygen and atomic oxygen O*. The unstable O 22 -Mn (n+2) + complex then decomposes by reducing the oxidized manganese to Mn 2 + and desorbing oxygen molecules. The manganese oxide catalyst forms active atomic oxygen O* during the decomposition of O3 . Similar decomposition mechanisms are also used for other metal oxides (eg FeO) or noble metals (eg Pd). Additionally, NO 2 can be oxidized to NO 3 by O* and O 3 . And NO 3 disappears easily and is converted into solid N 2 O 5 .
由气体反应物与固体催化剂构成的反应体系称为气-固多相催化反应,其催化过程一般包括5个步骤:(I)臭氧和NOX分子向催化剂表面扩散;(II)臭氧和NOX分子在催化剂表面吸附;(III)臭氧和NOX分子的中间反应(表面反应)产生O*和O2以及N2O5;(IV)产生的气体从催化剂表面脱附;(V)产生的气体扩散离开催化剂表面。The reaction system composed of gas reactants and solid catalysts is called gas-solid heterogeneous catalytic reaction, and its catalytic process generally includes five steps: (I) ozone and NOx molecules diffuse to the surface of the catalyst; (II) ozone and NOx Molecules are adsorbed on the catalyst surface; (III) the intermediate reaction (surface reaction) of ozone and NOx molecules produces O* and O 2 and N 2 O 5 ; (IV) the produced gas is desorbed from the catalyst surface; (V) the produced gas The gas diffuses away from the catalyst surface.
主要的方程式如下:The main equations are as follows:
4Mn4++O2-→4Mn4++2e+1/2O2→2Mn4++2Mn3++1/2O2 4Mn 4+ +O 2 -→4Mn 4+ +2e+1/2O 2 →2Mn 4+ +2Mn 3+ +1/2O 2
O3→O2+O*O 3 →O 2 +O*
NO+O*→NO2 NO+O*→NO 2
NO2+O3*→NO+2O2 NO 2 +O 3 *→NO+2O 2
HNO2+OH*→NO2+H2OHNO 2 +OH*→NO 2 +H 2 O
NO2+O*→NO3 NO 2 +O*→NO 3
N2O5在47℃时可以完全分解。因此当催化剂饱和后,对其进行加热,将挥发出来的气体通入NaOH溶液中,之后催化剂可以重复使用。经过催化单元的降解吸附后,本装置可以向空气中排出洁净的气体。N 2 O 5 can be completely decomposed at 47°C. Therefore, when the catalyst is saturated, it is heated, and the volatilized gas is passed into the NaOH solution, after which the catalyst can be reused. After the degradation and adsorption of the catalytic unit, the device can discharge clean gas into the air.
本发明的有益效果为:The beneficial effects of the present invention are:
(1)本发明在放电电极间隔内填充催化剂,利用风机的机械强力同时吸收室内和室外的含颗粒物和有毒害物质的受污染空气,首先对吸收的气体进行过滤,再采用介质阻挡放电单元对小颗粒物质和挥发性有毒害成分进行处理;针对放电单元产生的产物O3和NOX,本发明采用贵金属附着于过渡金属氧化物上,对其进行催化吸附处理;同时,在出口处设有专门设计的排风风机向外界排出洁净的空气;整个系统利用机械强力送风的同时对送入室内的空气进行过滤、净化。(1) The present invention fills a catalyst in the interval of the discharge electrode, utilizes the mechanical strength of the fan to simultaneously absorb indoor and outdoor contaminated air containing particulate matter and toxic substances, first filters the absorbed gas, and then uses a dielectric barrier discharge unit to Small particulate matter and volatile toxic components are treated; for the products O3 and NOX produced by the discharge unit, the present invention uses precious metals to adhere to transition metal oxides to carry out catalytic adsorption treatment; at the same time, there is a special design at the outlet. The exhaust fan exhausts clean air to the outside world; the whole system uses strong mechanical air supply while filtering and purifying the air sent into the room.
(2)相比传统技术,本发明具有处理效率高、能耗低、处理范围广、无二次污染、成本低等优点。(2) Compared with the traditional technology, the present invention has the advantages of high processing efficiency, low energy consumption, wide processing range, no secondary pollution, and low cost.
(3)本发明可以高效快速处理受污染的空气,比如雾霾等,改善大气质量,控制工厂废气等带来的空气污染,减少呼吸道等疾病的发病率。(3) The present invention can efficiently and quickly treat polluted air, such as smog, etc., improve air quality, control air pollution caused by factory exhaust gas, etc., and reduce the incidence of diseases such as respiratory tract.
附图说明Description of drawings
图1是本发明的框架图;Fig. 1 is the framework diagram of the present invention;
图2是本发明实施例1的框架图;2 is a frame diagram of Embodiment 1 of the present invention;
图3是本发明中的多级放电与催化联用单元的机构示意图;Fig. 3 is the mechanism schematic diagram of the multi-stage discharge and catalysis combined use unit in the present invention;
图4是本发明中的高压电极的剖面结构示意图;4 is a schematic cross-sectional structure diagram of a high-voltage electrode in the present invention;
图5是本发明实施例2的数据采集与控制单元的结构示意图;5 is a schematic structural diagram of a data acquisition and control unit according to
图6是本发明中的催化结构的结构示意图;Fig. 6 is the structural representation of the catalytic structure in the present invention;
附图标记说明:1、进气口;2、出气口;3、多级放电与催化联用单元;5、PDM电源;61、第一气体检测单元;611、第一甲醛传感器;62、第二气体检测单元;621、第二甲醛传感器;7、数据采集与控制单元;8、介质管;9、导电金属杆;12、催化结构;13、供电电压采集单元;14、放电电流采集单元;15、电极骨架;16、金属环;17、金属箔环;18、浮动电极环;19、筛板;20、催化剂;21、金属杆通孔;22、通气筛孔;23、导电金属桥;24、通气骨架。Description of reference numerals: 1. Air inlet; 2. Air outlet; 3. Multi-stage discharge and catalytic combined unit; 5. PDM power supply; 61, First gas detection unit; 611, First formaldehyde sensor; 62, No. 2. Gas detection unit; 621. The second formaldehyde sensor; 7. Data acquisition and control unit; 8. Medium tube; 9. Conductive metal rod; 12. Catalytic structure; 13. Supply voltage acquisition unit; 14. Discharge current acquisition unit; 15, electrode frame; 16, metal ring; 17, metal foil ring; 18, floating electrode ring; 19, sieve plate; 20, catalyst; 21, metal rod through hole; 22, ventilation sieve hole; 23, conductive metal bridge; 24. Ventilation skeleton.
具体实施方式Detailed ways
下面通过具体实施例对本发明作进一步详述,以下实施例只是描述性的,不是限定性的,不能以此限定本发明的保护范围。The present invention will be further described in detail below through specific examples. The following examples are only descriptive, not restrictive, and cannot limit the protection scope of the present invention.
实施例1Example 1
如图1所示,一种级联式环筒放电与催化联合空气净化系统,包括净化器本体和风机,所述净化器本体上设有进气口1和出气口2,所述风机安装于净化器本体内,所述净化器本体包括多级放电与催化联用单元3、第一气体检测单元61、第二气体检测单元62、PDM电源5和数据采集与控制单元7,所述第一气体检测单元61的气体输入端与进气口1相连,所述多级放电与催化联用单元3的气体输入端与第一气体检测单元61的气体输出端相连,所述多级放电与催化联用单元3的气体输出端与第二气体检测单元62的气体输入端相连,所述第二气体检测单元62的气体输出端与出气口2相连,所述PDM电源5的输出端与多级放电与催化联用单元3的输入端相连,第一气体检测单元61的输出端、第二气体检测单元62的输出端和数据采集与控制单元7的输入端相连,所述数据采集与控制单元7的输出端与进气口1相连,所述PDM电源5与数据采集与控制单元7双向连接;所述多级放电与催化联用单元3包括介质管8、导电金属杆9、若干对高压电极和低压电极以及若干个催化结构12,所述高压电极置于介质管8内,低压电极置于介质管8外表面上,每对所述高压电极和低压电极沿介质管8径向对齐,所有所述高压电极等间距轴向排布,且由导电金属杆9穿过中心固定,所述导电金属杆9固定于介质管8的中心轴位置上,相邻两个所述高压电极之间安装有催化结构12。As shown in Figure 1, a cascaded annular discharge and catalytic combined air purification system includes a purifier body and a fan. The purifier body is provided with an air inlet 1 and an
如图2所示,所述净化器本体还包括供电电压采集单元13和放电电流采集单元14,所述供电电压采集单元13的两端分别连接多级放电与催化联用单元3的输入端和数据采集与控制单元7的输入端,所述放电电流采集单元14的两端分别连接多级放电与催化联用单元3的输出端和数据采集与控制单元7的输入端。As shown in FIG. 2 , the purifier body further includes a power supply
如图3、4所示,所述高压电极包括电极骨架15和金属环16,所述电极骨架15的侧表面上均贴合安装有金属环16,所述导电金属杆9通过介质管8两端设置的通气骨架24固定于介质管8内,所述通风骨架上设有若干个通风孔,所述电极骨架15上还固定设置若干个导电金属桥23,所述导电金属桥23一端连接导电金属杆9,另一端连接金属环16,所述低压电极为金属箔环17,相邻两个所述金属箔环17中间还设置有浮动电极环18,所述浮动电极环18与金属箔环17平行设置。As shown in FIGS. 3 and 4 , the high-voltage electrode includes an
如图6所示,单个所述催化结构12包括两块筛板19和催化剂20,所述催化剂20均匀分散于两块筛板19之间,所述筛板19上正中心设有供导电金属杆9穿过的金属杆通孔21,表面设有若干个通气筛孔22。As shown in FIG. 6 , the single catalytic structure 12 includes two sieve plates 19 and a catalyst 20 , the catalyst 20 is evenly dispersed between the two sieve plates 19 , and the center of the sieve plate 19 is provided with a conductive metal The metal rod through holes 21 through which the
所述数据采集与控制单元7包括MCU、开关按键、显示单元和MCU电源,所述MCU的面板上设置开关按键,所述显示单元、MCU电源均与MCU连接,所述MCU设有第一气体检测单元AD端、第二气体检测单元AD端、供电电压采集单元AD端、放电电流采集单元AD端、PDM电源控制单元AD端、风机控制单元AD端,所述第一气体检测单元AD端与第一气体检测单元61的输出端相连,所述第二气体检测单元AD端与第二气体检测单元62的输出端相连,所述供电电压采集单元AD端与供电电压采集单元13的输出端相连,所述放电电流采集单元AD端与放电电流采集单元14的输出端相连,所述PDM电源控制单元AD端与PDM电源5相连,所述风机控制单元AD端与风机相连。The data acquisition and
所述介质管8的材料采用聚四氟乙烯、高密度聚丙烯、陶瓷或者石英。The material of the medium tube 8 is polytetrafluoroethylene, high-density polypropylene, ceramics or quartz.
所述催化剂20呈颗粒状。The catalyst 20 is in the form of particles.
所述催化剂20为Pd或Pt附着于Mn,Co,Ni和Ag的氧化物而成的组合物。The catalyst 20 is a composition in which Pd or Pt is attached to oxides of Mn, Co, Ni and Ag.
实施例2Example 2
如图1所示,一种级联式环筒放电与催化联合空气净化系统,包括净化器本体和风机,所述净化器本体上设有进气口1和出气口2,所述风机安装于净化器本体内,所述净化器本体包括多级放电与催化联用单元3、第一气体检测单元61、第二气体检测单元62、PDM电源5和数据采集与控制单元7,所述第一气体检测单元61的气体输入端与进气口1相连,所述多级放电与催化联用单元3的气体输入端与第一气体检测单元61的气体输出端相连,所述多级放电与催化联用单元3的气体输出端与第二气体检测单元62的气体输入端相连,所述第二气体检测单元62的气体输出端与出气口2相连,所述PDM电源5的输出端与多级放电与催化联用单元3的输入端相连,第一气体检测单元61的输出端、第二气体检测单元62的输出端和数据采集与控制单元7的输入端相连,所述数据采集与控制单元7的输出端与进气口1相连,所述PDM电源5与数据采集与控制单元7双向连接;所述多级放电与催化联用单元3包括介质管8、导电金属杆9、若干对高压电极和低压电极以及若干个催化结构12,所述高压电极置于介质管8内,低压电极置于介质管8外表面上,每对所述高压电极和低压电极沿介质管8径向对齐,所有所述高压电极等间距轴向排布,且由导电金属杆9穿过中心固定,所述导电金属杆9固定于介质管8的中心轴位置上,相邻两个所述高压电极之间安装有催化结构12。As shown in Figure 1, a cascaded annular discharge and catalytic combined air purification system includes a purifier body and a fan. The purifier body is provided with an air inlet 1 and an
所述净化器本体还包括供电电压采集单元13和放电电流采集单元14,所述供电电压采集单元13的两端分别连接多级放电与催化联用单元3的输入端和数据采集与控制单元7的输入端,所述放电电流采集单元14的两端分别连接多级放电与催化联用单元3的输出端和数据采集与控制单元7的输入端。The purifier body also includes a power supply
所述第一气体检测单元61内设置第一甲醛传感器611,所述第二气体检测单元62内设置第二甲醛传感器621。The first
所述高压电极包括电极骨架15和金属环16,所述电极骨架15的侧表面上均贴合安装有金属环16,所述导电金属杆9通过介质管8两端设置的通气骨架24固定于介质管8内,所述通风骨架上设有若干个通风孔,所述电极骨架15上还固定设置若干个导电金属桥23,所述导电金属桥23一端连接导电金属杆9,另一端连接金属环16,所述低压电极为金属箔环17,相邻两个所述金属箔环17中间还设置有浮动电极环18,所述浮动电极与金属箔环17平行设置。The high-voltage electrode includes an
单个所述催化结构12包括两块筛板19和催化剂20,所述催化剂20均匀分散于两块筛板19之间,所述筛板19上正中心设有供导电金属杆9穿过的金属杆通孔21,表面设有若干个通气筛孔22。The single catalytic structure 12 includes two sieve plates 19 and a catalyst 20, the catalyst 20 is evenly dispersed between the two sieve plates 19, and the center of the sieve plate 19 is provided with a metal for the
所述介质管8的材料采用聚四氟乙烯、高密度聚丙烯、陶瓷或者石英。The material of the medium tube 8 is polytetrafluoroethylene, high-density polypropylene, ceramics or quartz.
所述催化剂20呈颗粒状。The catalyst 20 is in the form of particles.
如图5所示,所述数据采集与控制单元7包括MCU、开关按键、显示单元和MCU电源,所述MCU的面板上设置开关按键,所述显示单元、MCU电源均与MCU连接,所述MCU设有第一甲醛传感器AD端、第二甲醛传感器AD端、供电电压采集单元AD端、放电电流采集单元AD端、PDM电源控制单元AD端、风机控制单元AD端,所述第一甲醛传感器AD端与第一甲醛传感器611的输出端相连,所述第二甲醛传感器AD端与第二甲醛传感器621的输出端相连,所述供电电压采集单元AD端与供电电压采集单元的输出端相连,所述放电电流采集单元AD端与放电电流采集单元14的输出端相连,所述PDM电源控制单元AD端与PDM电源5相连,所述风机控制单元AD端与风机相连。As shown in FIG. 5 , the data acquisition and
所述催化剂20为Pd或Pt附着于Mn,Co,Ni和Ag的氧化物而成的组合物。The catalyst 20 is a composition in which Pd or Pt is attached to oxides of Mn, Co, Ni and Ag.
需要说明的是,为了评估系统净化空气的效率,采用能效比(Eer)这个物理量来进行评估,其单位是g.kWh-1,其公式如下:It should be noted that, in order to evaluate the air purification efficiency of the system, the physical quantity of energy efficiency ratio (E er ) is used for evaluation, and its unit is g.kWh -1 , and its formula is as follows:
Δm是气体废气通过反应器后的质量变化,V是放电通道内的气体体积,t是放电通道内气体流过的时间,Et是高压电源消耗的总能量,c0是气体的初始浓度,c1是相应气体反应后的浓度。此外有V=Q.t,Et=Pin.t(Q表示气体流量,Pin表示高压电源的功率)所以,我们得到一个新的公式,如下:Δm is the mass change of the gas exhaust gas after passing through the reactor, V is the gas volume in the discharge channel, t is the gas flow time in the discharge channel, E t is the total energy consumed by the high-voltage power supply, c 0 is the initial concentration of the gas, c 1 is the concentration of the corresponding gas after reaction. In addition, there is V=Qt, E t =P in .t (Q represents the gas flow, and Pin represents the power of the high-voltage power supply) So, we get a new formula, as follows:
在本发明提供的系统中,净化空气的效率的最佳控制参数可由上述两个公式评估。其中c0可由第一气体检测单元得到,c1可由第二气体检测单元得到。In the system provided by the present invention, the optimal control parameters for the efficiency of purifying air can be estimated by the above two formulas. Wherein c 0 can be obtained by the first gas detection unit, and c 1 can be obtained by the second gas detection unit.
得到放电参数、气体浓度和气体流量等物理参数后,本发明与牛顿爬山算法相结合,设计了最佳放电效果评估方法。根据臭氧产生能效比(Eer)的变化规律,得到在最佳放电效果时对应的放电参数。根据牛顿爬山算法找出最佳Eer对应的放电条件,确定相应的参数范围。After obtaining physical parameters such as discharge parameters, gas concentration and gas flow rate, the present invention combines with Newton's hill-climbing algorithm to design an optimal discharge effect evaluation method. According to the change rule of the ozone generation energy efficiency ratio (Eer), the corresponding discharge parameters in the best discharge effect are obtained. According to Newton's hill-climbing algorithm, find out the discharge condition corresponding to the best Eer, and determine the corresponding parameter range.
牛顿爬山法又称扰动观察法,本发明中是通过不断调节放电反应系统的放电条件和气体流速来比较调整前后废气清除能效比的变化情况,再根据变化情况通过数据采集与控制单元来调整放电条件和气体流速,使系统工作在最佳能效比附近。Newton's hill-climbing method is also called disturbance observation method. In the present invention, the discharge conditions and gas flow rate of the discharge reaction system are continuously adjusted to compare the change of the exhaust gas removal energy efficiency ratio before and after the adjustment, and then the discharge is adjusted by the data acquisition and control unit according to the change. conditions and gas flow rates to make the system work near the best energy efficiency ratio.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only the preferred embodiments of the present invention. It should be pointed out that for those skilled in the art, without departing from the principles of the present invention, several improvements and modifications can be made. It should be regarded as the protection scope of the present invention.
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