CN108231731B - Bonding pad structure and manufacturing method thereof - Google Patents
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- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
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- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
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Abstract
一种接垫结构,包括多个材料对以及多个接垫。多个材料对相互堆叠于基底上,以形成一阶梯结构。阶梯结构的一阶包括一个材料对。每一个材料对包括导体层以及位于导体层上的介电层。每一个接垫嵌入于阶梯结构的一阶中且外露于该阶所对应的介电层与该阶上方的另一阶。接垫之一者的厚度大于导体层之一者的厚度。
A pad structure includes a plurality of material pairs and a plurality of pads. The plurality of material pairs are stacked on a substrate to form a stepped structure. One step of the stepped structure includes a material pair. Each material pair includes a conductor layer and a dielectric layer located on the conductor layer. Each pad is embedded in one step of the stepped structure and exposed to the dielectric layer corresponding to the step and another step above the step. The thickness of one of the pads is greater than the thickness of one of the conductor layers.
Description
技术领域technical field
本发明是有关于一种接垫结构及其制造方法,且特别是有关于一种用于三维存储元件的接垫结构及其制造方法。The present invention relates to a pad structure and a manufacturing method thereof, and more particularly, to a pad structure for a three-dimensional memory element and a manufacturing method thereof.
背景技术Background technique
随着存储元件的积集度增加,为了达到高密度以及高效能的目标,以三维存储元件取代二维存储元件已然成为一种趋势。而垂直式存储元件便是三维存储元件中的一种。虽然垂直式存储元件可提升单位面积内的存储器容量,但也增加了垂直式存储元件中内连线的困难度。As the integration of storage elements increases, in order to achieve the goals of high density and high performance, it has become a trend to replace two-dimensional storage elements with three-dimensional storage elements. The vertical storage element is one of the three-dimensional storage elements. Although vertical storage elements can increase the memory capacity per unit area, they also increase the difficulty of interconnecting the vertical storage elements.
一般而言,三维存储元件常以具有阶梯结构的导体层当作接垫,并利用接垫与其上的接触窗当作内连线结构,以利于连接每一层的元件与其他元件。然而,在进行接触窗刻蚀工艺时,会因阶梯结构中不同位置的接垫与其上的介电层的顶面之间的高度差异,使得阶梯结构中最顶接垫被过度刻蚀,进而导致接触窗开口贯穿最顶接垫并延伸至其下方的导体层上。如此一来,后续所形成的接触窗则会由于电性连接两个接垫或导体层,进而导致元件电性故障。因此,如何提供一种接垫结构及其制造方法,以避免过度刻蚀具有阶梯结构的接垫结构,为目前重要的一门课题。Generally speaking, three-dimensional memory devices often use conductor layers with a stepped structure as pads, and use the pads and the contact windows thereon as interconnect structures, so as to facilitate the connection between elements in each layer and other elements. However, when the contact window etching process is performed, due to the height difference between the pads at different positions in the stepped structure and the top surface of the dielectric layer thereon, the top pad in the stepped structure is over-etched, and further This causes the contact opening to extend through the topmost pad and onto the conductor layer below it. In this way, the subsequently formed contact window will electrically connect the two pads or conductor layers, thereby causing electrical failure of the device. Therefore, how to provide a pad structure and a manufacturing method thereof so as to avoid excessive etching of the pad structure with the stepped structure is an important topic at present.
发明内容SUMMARY OF THE INVENTION
本发明提供一种具有阶梯结构的接垫结构及其制造方法,其可防止接触窗开口工艺期间因过度刻蚀所导致的电性故障问题。The present invention provides a pad structure with a stepped structure and a manufacturing method thereof, which can prevent the electrical failure problem caused by excessive etching during the contact opening process.
本发明提供一种具有阶梯结构的接垫结构及其制造方法,其可提升工艺裕度并增加工艺合格率。The present invention provides a pad structure with a stepped structure and a manufacturing method thereof, which can improve the process margin and increase the process yield.
本发明提供一种接垫结构,包括多个材料对以及多个接垫。多个材料对相互堆叠于基底上,以形成一阶梯结构。阶梯结构的一阶包括一个材料对。每一个材料对包括导体层以及位于导体层上的介电层。每一个接垫嵌入于阶梯结构的一阶中且外露于该阶所对应的介电层与该阶上方的另一阶。接垫之一者的厚度大于导体层之一者的厚度。The present invention provides a pad structure, which includes a plurality of material pairs and a plurality of pads. A plurality of material pairs are stacked on the substrate to form a stepped structure. The first order of the ladder structure consists of a material pair. Each material pair includes a conductor layer and a dielectric layer overlying the conductor layer. Each pad is embedded in a level of the stepped structure and exposed to the dielectric layer corresponding to the level and another level above the level. The thickness of one of the pads is greater than the thickness of one of the conductor layers.
在本发明的一实施例中,所述多个材料对沿着XY方向的平面延伸。所述多个材料对之一者突出于其上方的所述多个材料对之另一者的一侧且暴露出相对应的所述接垫的表面。In an embodiment of the present invention, the plurality of material pairs extend along the plane of the XY direction. One of the plurality of material pairs protrudes from a side of the other of the plurality of material pairs above it and exposes the corresponding surface of the pad.
在本发明的一实施例中,所述接垫结构还包括多个插塞沿着Z方向延伸且分别配置于所述接垫上。In an embodiment of the present invention, the pad structure further includes a plurality of plugs extending along the Z direction and respectively disposed on the pad.
在本发明的一实施例中,各接垫的宽度大于所对应的插塞的底部宽度。In an embodiment of the present invention, the width of each pad is larger than the bottom width of the corresponding plug.
在本发明的一实施例中,所述插塞的材料与所述接垫的材料相同。In an embodiment of the present invention, the material of the plug is the same as the material of the pad.
在本发明的一实施例中,所述插塞的材料与所述接垫的材料不同。In an embodiment of the present invention, the material of the plug is different from the material of the pad.
在本发明的一实施例中,从上视角度而言,所述接垫的形状包括方形、圆形、矩形、长条形或其组合。In an embodiment of the present invention, from a top view, the shape of the pad includes a square, a circle, a rectangle, a strip, or a combination thereof.
在本发明的一实施例中,从上视角度而言,当所述接垫的形状为长条形时,所述接垫沿着X方向排列并沿着Y方向延伸。In an embodiment of the present invention, from a top view, when the shape of the pads is elongated, the pads are arranged along the X direction and extend along the Y direction.
在本发明的一实施例中,所述接垫结构还包括垫层位于所述阶梯结构与所述基底之间。In an embodiment of the present invention, the pad structure further includes a pad layer located between the stepped structure and the substrate.
本发明提供一种接垫结构的制造方法,其步骤如下。在基底上形成堆叠结构。堆叠结构包括相互堆叠的多个材料对。多个材料对由上至下包括第一材料对至第N材料对,N为大于1的整数。每一个材料对包括第一层以及位于第一层上的第二层。在第一材料对中形成多个第一开口。第一开口暴露出第二材料对的顶面。进行图案化工艺,以将堆叠结构图案化为阶梯结构,并在阶梯结构的每一阶中形成第二开口。第二开口的垂直投影位置分别对应于第一开口的位置。将多个第三层分别填入第二开口中,其中第三层之一者的厚度大于第一层之一者的厚度。The present invention provides a manufacturing method of a pad structure, the steps of which are as follows. A stacked structure is formed on the substrate. The stacked structure includes a plurality of material pairs stacked on each other. The plurality of material pairs include a first material pair to an Nth material pair from top to bottom, where N is an integer greater than 1. Each material pair includes a first layer and a second layer on the first layer. A plurality of first openings are formed in the first material pair. The first opening exposes the top surface of the second pair of materials. A patterning process is performed to pattern the stacked structure into a stepped structure, and a second opening is formed in each step of the stepped structure. The vertical projection positions of the second openings correspond to the positions of the first openings, respectively. A plurality of third layers are respectively filled into the second openings, wherein the thickness of one of the third layers is greater than that of one of the first layers.
在本发明的一实施例中,将第三层分别填入第二开口中之后,还包括以下步骤。在基底上形成介电层。介电层覆盖阶梯结构的表面与第三层的顶面。在介电层中形成多个接触窗开口。接触窗开口分别暴露出第三层的顶面。将多个插塞分别填入接触窗开口中,使得插塞之一者与所对应的第三层连接。In an embodiment of the present invention, after the third layers are respectively filled into the second openings, the following steps are further included. A dielectric layer is formed on the substrate. The dielectric layer covers the surface of the stepped structure and the top surface of the third layer. A plurality of contact openings are formed in the dielectric layer. The contact window openings expose the top surfaces of the third layers, respectively. A plurality of plugs are respectively filled into the openings of the contact windows, so that one of the plugs is connected to the corresponding third layer.
在本发明的一实施例中,所述第一层的材料包括氮化硅,第二层的材料包括氧化硅,第三层的材料包括氮化硅。In an embodiment of the present invention, the material of the first layer includes silicon nitride, the material of the second layer includes silicon oxide, and the material of the third layer includes silicon nitride.
在本发明的一实施例中,在基底上形成介电层之后且形成接触窗开口之前,还包括进行钨取代工艺,以将第一层的材料与第三层的材料取代为钨(W)。In an embodiment of the present invention, after the dielectric layer is formed on the substrate and before the contact opening is formed, a tungsten substitution process is further included to replace the material of the first layer and the material of the third layer with tungsten (W) .
在本发明的一实施例中,所述钨取代工艺包括以下步骤。在介电层与阶梯结构中形成至少一狭缝(slit)。至少一狭缝延伸至阶梯结构的底面,以暴露出多个材料对的第一层的部分截面。在至少一狭缝中施加刻蚀剂,移除第一层与第三层以形成多个空隙。进行沉积工艺,以在空隙中分别形成多个钨层。In an embodiment of the present invention, the tungsten substitution process includes the following steps. At least one slit is formed in the dielectric layer and the stepped structure. At least one slit extends to the bottom surface of the stepped structure to expose a partial cross-section of the first layer of the plurality of material pairs. An etchant is applied in at least one slit to remove the first and third layers to form a plurality of voids. A deposition process is performed to form a plurality of tungsten layers in the voids, respectively.
在本发明的一实施例中,所述第一层的材料包括多晶硅,第二层的材料包括氧化硅,第三层的材料包括多晶硅。In an embodiment of the present invention, the material of the first layer includes polysilicon, the material of the second layer includes silicon oxide, and the material of the third layer includes polysilicon.
在本发明的一实施例中,所述插塞的材料包括钨(W)。In an embodiment of the present invention, the material of the plug includes tungsten (W).
在本发明的一实施例中,进行所述图案化工艺的步骤如下。在堆叠结构上形成光刻胶层。光刻胶层暴露出第一开口之一者。进行第一刻蚀工艺,移除部分第一材料对与部分第二材料对,以将第一开口之一者的形状转移到第二材料对中。修整光刻胶层,以暴露出第一开口之另一者。进行第二刻蚀工艺,移除部分第一材料对、部分第二材料对以及部分第三材料对,以将第一开口之另一者的形状转移到第二材料对中并将第一开口之一者的形状转移到第三材料对中。重复修整光刻胶层与进行第二刻蚀工艺的步骤,直到形成阶梯结构。In an embodiment of the present invention, the steps of performing the patterning process are as follows. A photoresist layer is formed on the stacked structure. The photoresist layer exposes one of the first openings. A first etching process is performed to remove a portion of the first material pair and a portion of the second material pair to transfer the shape of one of the first openings into the second material pair. The photoresist layer is trimmed to expose the other of the first openings. A second etching process is performed to remove a portion of the first material pair, a portion of the second material pair, and a portion of the third material pair to transfer the shape of the other of the first openings into the second material pair and the first openings The shape of one is transferred to the third material pair. The steps of trimming the photoresist layer and performing the second etching process are repeated until a stepped structure is formed.
在本发明的一实施例中,所述接垫结构的制造方法还包括在阶梯结构与基底之间形成垫层。In an embodiment of the present invention, the manufacturing method of the pad structure further includes forming a pad layer between the stepped structure and the substrate.
基于上述,本实施例可通过在堆叠结构的最顶材料对中形成多个开口。接着,将所述堆叠结构图案化为一阶梯结构,以将所述开口转移并形成在阶梯结构的每一阶中。然后,将导体材料填入所述开口中,以形成接垫。因此,相比于现有的接垫,本实施例的接垫的厚度较厚,其可防止接触窗开口工艺期间因过度刻蚀所导致的电性故障问题。另外,以厚度较厚的接垫当作形成接触窗开口的刻蚀停止层,其可提升接触窗开口工艺的工艺裕度并增加工艺合格率。Based on the above, this embodiment can be achieved by forming a plurality of openings in the topmost material pair of the stacked structure. Next, the stacked structure is patterned into a stepped structure to transfer and form the openings in each step of the stepped structure. Then, conductive material is filled into the openings to form pads. Therefore, compared with the conventional pads, the thickness of the pads of the present embodiment is thicker, which can prevent electrical failures caused by excessive etching during the contact opening process. In addition, using a thicker pad as an etch stop layer for forming the contact opening can improve the process margin of the contact opening process and increase the process yield.
为让本发明的上述特征和优点能更明显易懂,下文特举实施例,并配合所附附图作详细说明如下。In order to make the above-mentioned features and advantages of the present invention more obvious and easy to understand, the following embodiments are given and described in detail with the accompanying drawings as follows.
附图说明Description of drawings
图1是依照本发明一实施例的一种存储元件的上视示意图。FIG. 1 is a schematic top view of a memory device according to an embodiment of the present invention.
图2是图1的A-A’线的剖面示意图。Fig. 2 is a schematic cross-sectional view taken along the line A-A' in Fig. 1 .
图3A至图3O是沿着图1的A-A’线的制造流程的剖面示意图。3A to 3O are schematic cross-sectional views of the manufacturing flow along the line A-A' of FIG. 1 .
图4A至图4B是依照本发明的第一实施例的一种接垫结构的制造流程的上视示意图。4A to 4B are schematic top views of a manufacturing process of a pad structure according to the first embodiment of the present invention.
图5A至图5B分别是沿着图4A至图4B的B-B’线的剖面示意图。5A to 5B are schematic cross-sectional views taken along the line B-B' of FIGS. 4A to 4B, respectively.
图6A至图6B是依照本发明的第二实施例的一种接垫结构的制造流程的上视示意图。6A to 6B are schematic top views of a manufacturing process of a pad structure according to a second embodiment of the present invention.
图7A至图7B分别是沿着图6A至图6B的C-C’线的剖面示意图。7A to 7B are schematic cross-sectional views taken along the line C-C' of FIGS. 6A to 6B, respectively.
图8A至图8B是依照本发明的第三实施例的一种接垫结构的制造流程的上视示意图。8A to 8B are schematic top views of a manufacturing process of a pad structure according to a third embodiment of the present invention.
图9A至图9B分别是沿着图8A至图8B的D-D’线的剖面示意图。9A to 9B are schematic cross-sectional views taken along the line D-D' of FIGS. 8A to 8B, respectively.
【符号说明】【Symbol Description】
10:接垫区10: Pad area
20:阵列区20: Array area
30:周边区30: Surrounding area
100:基底100: base
101:垫层101: Cushion
102:堆叠结构102: Stacked Structure
102’:阶梯结构102’: Ladder structure
102a、102b、102c、102d、102e、102f、132、132a、132b、132c、132d、132e、132f:材料对102a, 102b, 102c, 102d, 102e, 102f, 132, 132a, 132b, 132c, 132d, 132e, 132f: Material pairs
103a、103b、103c、103d、103e、103f:开口103a, 103b, 103c, 103d, 103e, 103f: Openings
104a、104b、104c、104d、104e、104f:第一层104a, 104b, 104c, 104d, 104e, 104f: first layer
105a、105b、105c、105d、105e、105f:开口105a, 105b, 105c, 105d, 105e, 105f: Openings
106a、106b、106c、106d、106e、106f:第二层(介电层)106a, 106b, 106c, 106d, 106e, 106f: second layer (dielectric layer)
108、110:光刻胶层108, 110: photoresist layer
112:绝缘层112: Insulation layer
112a、112b、112c、112d、112e、112f:第三层112a, 112b, 112c, 112d, 112e, 112f: the third layer
114a、114b、114c、114d、114e、114f:导体层114a, 114b, 114c, 114d, 114e, 114f: conductor layers
116、116a:介电层116, 116a: Dielectric layer
120、120a、120b、120c、120d、120e、120f、220、320;度垫120, 120a, 120b, 120c, 120d, 120e, 120f, 220, 320; degree pad
122a、122b、122c、122d、122e、122f:接触窗开口122a, 122b, 122c, 122d, 122e, 122f: Contact window openings
124、124a、124b、124c、124d、124e、124f:插塞124, 124a, 124b, 124c, 124d, 124e, 124f: Plugs
X、Y、Z:方向X, Y, Z: direction
D1、D2:距离D1, D2: distance
H1、H2、H3:高度H1, H2, H3: height
T1、T2、T3:厚度T1, T2, T3: Thickness
S:规范值S: normative value
ECDc、ECDs:宽度ECDc, ECDs: Width
具体实施方式Detailed ways
参照本实施例的附图以更全面地阐述本发明。然而,本发明亦可以各种不同的形式体现,而不应限于本文中所述的实施例。附图中的层与区域的厚度会为了清楚起见而放大。相同或相似的参考号码表示相同或相似的元件,以下段落将不再一一赘述。The present invention will be more fully explained with reference to the accompanying drawings of this embodiment. However, the present invention may be embodied in various forms and should not be limited to the embodiments described herein. The thicknesses of layers and regions in the figures may be exaggerated for clarity. The same or similar reference numerals denote the same or similar elements, and the detailed description in the following paragraphs will not be repeated.
图1是依照本发明一实施例的一种存储元件的上视示意图。图2是图1的A-A’线的剖面示意图。FIG. 1 is a schematic top view of a memory device according to an embodiment of the present invention. Fig. 2 is a schematic cross-sectional view taken along the line A-A' in Fig. 1 .
请参照图1与图2,本发明的第一实施例提供一种存储元件,其包括基底100。从上视图来看,基底100包括接垫区10、阵列区20以及周边区30。接垫区10位于阵列区20与周边区30之间。在一实施例中,阵列区20可例如是存储单元阵列区。周边区30可包括多个低压半导体元件,例如是低压N型金氧半导体(LV-NMOS)晶体管、低压P型金氧半导体(LV-PMOS)晶体管或其组合。从剖面图来看,如图2所示,接垫区10包括具有阶梯结构的多个材料对132、分别嵌入于多个材料对132的多个接垫120以及分别配置于多个接垫120上的多个插塞124。接垫120与插塞124可用以当作内连线结构,以电性连接阶梯结构中的每一阶的元件与其他元件。Referring to FIG. 1 and FIG. 2 , a first embodiment of the present invention provides a memory device including a
具体来说,请同时参照图1与图2,多个材料对132自阵列区20伸并终止于接垫区10。多个材料对132沿着XY方向的平面延伸并相互堆叠成一阶梯结构。所述阶梯结构的一阶包括一个材料对。每一个材料对包括导体层(或第一层)以及位于所述导体层上的一介电层(或第二层)。举例来说,如图2所示,导体层114a与介电层106a可视为一个材料对132a或是阶梯结构的一阶;而导体层114b与介电层106b可视为另一个材料对132b或是阶梯结构的另一阶。其他材料对的配置同上述,在此便不再赘述。在一实施例中,导体层114a与介电层106a的组合可视为最底材料对132a,其突出于其上方由导体层114b与介电层106b所构成的材料对132b的一侧,使得嵌入于导体层114a与介电层106a中的接垫120a暴露出来。相似地,由导体层114b与介电层106b所构成的材料对132b突出于其上方由导体层114c与介电层106c所构成的材料对132c的一侧,使得嵌入于导体层114b与介电层106b中的接垫120b暴露出来。其他材料对的堆叠方式同上述,在此便不再赘述。Specifically, referring to FIG. 1 and FIG. 2 simultaneously, a plurality of material pairs 132 extend from the
另一方面,如图2所示,多个插塞124沿着Z方向延伸且分别配置于多个接垫120上。举例来说,插塞124a配置并连接于接垫120a上,使得插塞124a通过接垫120a与导体层114a电性连接。相似地,插塞124b配置并连接于接垫120b上,使得插塞124b通过接垫120b与导体层114b电性连接。其他插塞的配置与连接方式同上述,在此便不再赘述。On the other hand, as shown in FIG. 2 , the plurality of
此外,接垫区10还包括多条狭缝130,其自阵列区20延伸并终止于接垫区10。详细地说,多条狭缝130沿着X方向延伸,并沿着Y方向排列,使得每一条狭缝130位于相邻两列(其沿着X方向延伸)的插塞124之间。虽然图1中仅绘示出排列成7×4阵列的插塞124以及3条狭缝130,但本发明不限于此。在其他实施例中,可依设计者的需求来调整插塞124与狭缝130的数量与排列。In addition, the
需注意的是,接垫120a-120f不仅用以电性连接插塞124a-124f以及导体层114a-114f,还可在接触窗开口工艺期间用以当作刻蚀停止层。举例来说,如图2的接垫120a的放大图所示,由于接垫120a的厚度T1大于导体层114a的厚度T2,因此,厚度较厚的接垫120a可有效阻挡接触窗开口工艺期间的过度刻蚀。也就是说,即使是最顶插塞124f也不会贯穿最顶接垫120f并延伸至其下方的导体层114e。因此,本实施例的厚度较厚的接垫120便可防止接触窗开口工艺期间因过度刻蚀所导致的电性故障问题。接垫120a的厚度T1可例如是70纳米(nm)至90nm。It should be noted that the
图3A至图3O是沿着图1的A-A’线的制造流程的剖面示意图。3A to 3O are schematic cross-sectional views of the manufacturing flow along the line A-A' of FIG. 1 .
请参照图3A,首先,提供基底100。在一实施例中,基底100可例如是半导体基底、半导体化合物基底或是绝缘层上有半导体基底(Semiconductor Over Insulator,SOI)。半导体例如是IVA族的原子,例如硅或锗。半导体化合物例如是IVA族的原子所形成的半导体化合物,例如是碳化硅或是硅化锗,或是IIIA族原子与VA族原子所形成的半导体化合物,例如是砷化镓。Referring to FIG. 3A , first, a
接着,在基底100上形成垫层101。在一实施例中,垫层101可以是氧化硅层,其可用以保护基底100的表面。Next, the
之后,在垫层101上形成堆叠结构102。详细地说,堆叠结构102包括相互堆叠的多个材料对102a-102f。如图3A所示,材料对102a可视为最底材料对;而材料对102f可视为最顶材料对。材料对102a包括第一层104a以及位于第一层104a上的第二层106a。相似地,材料对102b包括第一层104b以及位于第一层104b上的第二层106b。其他材料对102c-102f的配置如上述,在此便不再赘述。在一实施例中,第一层104a-104f可以是氮化硅层,而第二层106a-106f可以是氧化硅层。在一实施例中,氮化硅层104a-104f之一者的厚度为20nm至40nm,其可例如是28nm。氧化硅层106a-106f之一者的厚度为40nm至60nm,其可例如是52nm。在替代实施例中,第一层104a-104f可以是多晶硅层,而第二层106a-106f可以是氧化硅层。虽然图3A中仅绘示6个材料对,但本发明不以此为限。在其他实施例中,材料对的数量可包括8个、15个、21个、27个、33个、39个或更多个。After that, a
然后,在堆叠结构102上形成光刻胶层108。光刻胶层108具有多个开口103a-103f。开口103a-103f暴露出堆叠结构102(或第二层106f)的顶面。开口103a-103f的位置分别对应后续所形成的接垫120a-120f的位置(如图3O所示)。也就是说,开口103a-103f的垂直投影位置分别与后续所形成的接垫120a-120f的位置重叠。Then, a
请参照图3A与图3B,以光刻胶层108为掩模,进行刻蚀工艺并移除部分材料对102f,以在材料对102f中形成多个开口105a-105f。开口105a-105f暴露出材料对102e(或第二层106e)的顶面。在一实施例中,所述刻蚀工艺可包括干式刻蚀工艺,例如是反应性离子刻蚀法(Reactive Ion Etching,RIE)。Referring to FIG. 3A and FIG. 3B , using the
请参照图3B与图3C,移除光刻胶层108。在一实施例中,移除光刻胶层108的方法可以是先以高密度等离子体灰化光刻胶层108之后,再进行湿式清洗工艺。Referring to FIG. 3B and FIG. 3C , the
请参照图3C至图3I,进行图案化工艺,以将堆叠结构102图案化为阶梯结构102’。详细地说,请先参照图3C与图3D,在堆叠结构102上形成光刻胶层110。光刻胶层110暴露出开口105a,并覆盖其他开口105b-105f。在一实施例中,光刻胶层110的厚度或高度H1可例如是4000nm至6000nm。Referring to FIGS. 3C to 3I, a patterning process is performed to pattern the
请参照图3D与图3E,以光刻胶层110为掩模,进行第一刻蚀工艺,移除外露于光刻胶层110的部分材料对102f以及外露于开口105a的部分材料对102e,使得开口105a的形状转移到材料对102e中。因此,转移至材料对102e中的开口105a暴露出材料对102d(或第二层106d)的顶面。此时,如图3E所示,光刻胶层110亦被刻蚀,而使得光刻胶层110的厚度或高度H2减少为3950nm至5950nm。在一实施例中,所述第一刻蚀工艺可包括干式刻蚀工艺,例如是反应性离子刻蚀法。在一实施例中,所述第一刻蚀工艺可以是两道刻蚀步骤。举例来说,所述第一刻蚀工艺可以第一层当作刻蚀停止层,移除第二层的材料。之后,再以第二层当作刻蚀停止层,移除第一层的材料。如此一来,在所述第一刻蚀工艺期间,将移除一个材料对的厚度。但本发明不以此为限,在其他实施例中,亦可调整所述第一刻蚀工艺的工艺参数,以移除所需的材料对的厚度或数量。3D and FIG. 3E , a first etching process is performed using the
请参照图3E与图3F,修整(trim)光刻胶层110,以暴露出开口105b。所述修整是指将光刻胶层110回缩(pull back)一距离D1。在此情况下,如图3F所示,光刻胶层110暴露出开口105a、105b。在一实施例中,所述距离D1可例如是400nm至600nm。在修整并回缩光刻胶层110的同时,光刻胶层110的厚度也会消耗。经消耗的光刻胶层110的厚度(即厚度H2减去厚度H3的值)比距离D1大。在一实施例中,距离D1可例如是500nm,而所述经消耗的光刻胶层110的厚度可例如是625nm。修整光刻胶层110之后,光刻胶层110的厚度或高度H3减少为3325nm至5325nm。也就是说,当光刻胶层110的厚度或高度H1愈厚,其能够进行更多次的图案化及光刻胶修整工艺,以形成更多阶的阶梯结构。因此,光刻胶层110的厚度或高度H1可依需求来进行调整。Referring to FIGS. 3E and 3F, the
请参照图3F与图3G,以光刻胶层110为掩模,进行第二刻蚀工艺,移除部分材料对102f、部分材料对102e以及部分材料对102d,以将开口105a的形状转移到材料对102d中,并将开口105b的形状转移到材料对102e中。在此情况下,如图3G所示,转移至材料对102d中的开口105a暴露出材料对102c(或第二层106c)的顶面;而转移至材料对102e中的开口105b暴露出材料对102d(或第二层106d)的顶面。此时,如图3G所示,光刻胶层110亦被刻蚀,而使得光刻胶层110的厚度或高度H4减少为3275nm至5275nm。Referring to FIGS. 3F and 3G, a second etching process is performed using the
请参照图3G与图3H,修整光刻胶层110,使得光刻胶层110回缩一距离D2,以暴露出开口105c。在一实施例中,所述距离D2可例如是400nm至600nm。Referring to FIGS. 3G and 3H , the
请参照图3H与图3I,重复上述进行该第二刻蚀工艺与修整光刻胶层110的步骤,直到形成如图3I所示的阶梯结构102’。在此情况下,如图3I所示,多个开口105a-105f分别位于阶梯结构102’的每一阶中。Referring to FIG. 3H and FIG. 3I, the above-mentioned steps of performing the second etching process and trimming the
请参照图3I与图3J,在基底100上形成绝缘层112。绝缘层112覆盖阶梯结构102’的表面并填入开口105a-105f中。在一实施例中,绝缘层112的厚度T3可大于开口105a的二分之一宽度ECDs,以确保开口105a~105f可被填满。另一方面来说,如图3J所示,绝缘层112的厚度T3至少要大于一个材料对102a的厚度才能够填满开口105a。在一实施例中,绝缘层112的材料包括氮化硅,其形成方法可以是化学气相沉积法。Referring to FIG. 3I and FIG. 3J , an insulating
请参照图3J与图3K,移除部分绝缘层112,以在开口105a-105f中分别形成第三层112a-112f。在一实施例中,如图3K所示,第三层112a的顶面与材料对102a的顶面共平面。相似地,第三层112b的顶面与材料对102b的顶面共平面。其他第三层的顶面亦与所对应的材料对的顶面共平面,在此便不再赘述。Referring to FIGS. 3J and 3K, part of the insulating
请参照图3K与图3L,在基底100上形成介电层116。介电层116覆盖阶梯结构102’的表面与第三层112a-112f的顶面。在一实施例中,介电层116的材料包括氧化硅,其形成方法可以是利用化学气相沉积法,在基底100上沉积介电材料层。接着再进行平坦化工艺,例如化学机械研磨CMP,以平坦化介电材料层的顶面。Referring to FIG. 3K and FIG. 3L , a
请参照图3L与图3M,进行钨取代工艺,以将第一层104a-104f的材料与第三层112a-112f的材料取代为钨(W)。详细地说,所述钨取代工艺的步骤如下。首先,在介电层116与阶梯结构102’中形成狭缝130。需注意的是,虽然图3M的剖面未绘示出狭缝130,但从图1中可知,狭缝130的延伸方向平行于A-A’线方向。狭缝130延伸至阶梯结构102’的底面,以暴露出材料对102a-102f的第一层104a-104f的部分截面。在狭缝130中施加刻蚀剂,移除第一层104a-104f与第三层112a-112f以形成多个空隙(未绘示)。接着,进行沉积工艺,以在所述空隙中分别形成多个钨层。在此情况下,如图3M所示,在钨取代工艺之后,第一层104a-104f被取代为导体层114a-114f;而第三层112a-112f被取代为接垫120a-120f。在本实施例中,导体层114a-114f的材料与接垫120a-120f的材料相同,其皆为钨。在一实施例中,所述刻蚀剂可以是氢氟酸与热磷酸的组合。在一实施例中,可先施加氢氟酸,之后再施加热磷酸。Referring to FIGS. 3L and 3M, a tungsten replacement process is performed to replace the materials of the
在替代实施例中,当第一层104a-104f为多晶硅层,而第二层106a-106f为氧化硅层时,亦可不进行所述钨取代工艺。此时,接垫120a-120f的材料可例如是多晶硅。In an alternative embodiment, when the
请参照图3M与图3N,在介电层116a中形成多个接触窗开口122a-122f。接触窗开口122a-122f分别暴露出接垫120a-120f的表面。从图3N中可知,接垫120a-120f可用以当作形成接触窗开口122a-122f的刻蚀停止层。相比于接垫120a的顶面与介电层116a的顶面之间的距离,接垫120f的顶面与介电层116a的顶面之间的距离较短,因此,在进行接触窗开口工艺时,接触窗开口122f会先接触到最顶接垫120f的顶面,而使得最顶接垫120f的刻蚀耗损较多。相比于现有接垫的厚度,本实施例的厚度较厚的接垫120a-120f可防止接触窗开口工艺期间的过度刻蚀(尤其是对于最顶接垫120f的过度刻蚀),借此提升接触窗开口工艺的工艺裕度并增加工艺合格率。顺带一提的是,在形成接触窗开口122a-122f之前,尚需进行其他工艺,因此,图3N的介电层116a厚度比图3M的介电层116的厚度厚。Referring to FIGS. 3M and 3N, a plurality of
请参照图3N与图3O,将多个插塞124a-124f分别填入接触窗开口122a-122f中,使得插塞124a-124f分别与接垫120a-120f连接。因此,插塞124a-124f可通过接垫120a-120f分别与导体层114a-114f电性连接。插塞124a-124f与接垫120a-120f可用以当作内连线结构,以电性连接具有阶梯结构的材料对132中的每一阶的元件与其他元件。详细地说,将多个插塞124a-124f分别填入接触窗开口122a-122f中的步骤包括进行沉积工艺,以将金属材料填入接触窗开口122a-122f中并覆盖介电层116a的顶面。接着,进行平坦化工艺,移除介电层116a的顶面上的金属材料。此时,如图3O所示,插塞124a-124f的顶面与介电层116a的顶面为共平面。在一实施例中,所述金属材料包括钨,其形成方法可以是物理气相沉积法或化学气相沉积法。所述平坦化工艺可以是化学机械研磨(CMP)工艺。在一实施例中,插塞124a-124f的材料与接垫120a-120f的材料相同。在替代实施例中,插塞124a-124f的材料可与接垫120a-120f的材料不同。3N and FIG. 3O, a plurality of
图4A至图4B是依照本发明的第一实施例的一种接垫结构的制造流程的上视示意图。图5A至图5B分别是沿着图4A至图4B的B-B’线的剖面示意图。图6A至图6B是依照本发明的第二实施例的一种接垫结构的制造流程的上视示意图。图7A至图7B分别是沿着图6A至图6B的C-C’线的剖面示意图。图8A至图8B是依照本发明的第三实施例的一种接垫结构的制造流程的上视示意图。图9A至图9B分别是沿着图8A至图8B的D-D’线的剖面示意图。4A to 4B are schematic top views of a manufacturing process of a pad structure according to the first embodiment of the present invention. 5A to 5B are schematic cross-sectional views taken along the line B-B' of FIGS. 4A to 4B, respectively. 6A to 6B are schematic top views of a manufacturing process of a pad structure according to a second embodiment of the present invention. 7A to 7B are schematic cross-sectional views taken along the line C-C' of FIGS. 6A to 6B, respectively. 8A to 8B are schematic top views of a manufacturing process of a pad structure according to a third embodiment of the present invention. 9A to 9B are schematic cross-sectional views taken along the line D-D' of FIGS. 8A to 8B, respectively.
值得一提的是,从上视角度而言,所述接垫的形状包括方形(如图4A所示)、矩形(如图6A所示)、长条形(如图8A所示)或其组合。所述接垫之一者的宽度大于所对应的插塞(或接触窗开口)的底部宽度。It is worth mentioning that, from a top view, the shape of the pad includes a square (as shown in FIG. 4A ), a rectangle (as shown in FIG. 6A ), a long strip (as shown in FIG. 8A ) or combination. The width of one of the pads is greater than the bottom width of the corresponding plug (or contact window opening).
请参照图4A、图4B、图5A以及图5B。在第一实施例中,接垫120的形状为方形,且其所对应的接触窗开口122的形状亦为方形。在一实施例中,接垫120的宽度ECDs大于接触窗开口122的宽度ECDc加上2个规范值S(也就是,ECDs>ECDc+2S)。所谓规范值S是指迭对规范值(overlay specification value)或是迭对可容忍值,其取决于进行接触窗开口工艺的曝光机台。举例来说,当形成接触窗开口122的曝光机台为193nm的氟化氩(ArF)准分子激光步进机时(制造商为ASML,机台型号为1450H),规范值S可例如是10nm至20nm。需注意的是,虽然图4A所绘示的接垫120的形状为方形,但在实际形成的接垫120会呈圆形。Please refer to FIG. 4A , FIG. 4B , FIG. 5A and FIG. 5B . In the first embodiment, the shape of the
请参照图6A、图6B、图7A以及图7B。在第二实施例中,接垫220的形状为矩形,且其所对应的接触窗开口122的形状为方形。在一实施例中,接垫220的宽度ECDs大于接触窗开口122的宽度ECDc加上2个规范值S(也就是,ECDs>ECDc+2S)。Please refer to FIGS. 6A , 6B, 7A and 7B. In the second embodiment, the shape of the
请参照图8A、图8B、图9A以及图9B。在第三实施例中,接垫320的形状为长条形,且其所对应的接触窗开口122的形状为方形。呈长条形的接垫320沿着X方向排列并沿着Y方向延伸。在一实施例中,接垫320的宽度ECDs大于接触窗开口122的宽度ECDc加上2个规范值S(也就是,ECDs>ECDc+2S)。Please refer to FIG. 8A , FIG. 8B , FIG. 9A and FIG. 9B . In the third embodiment, the shape of the
综上所述,本实施例可通过在堆叠结构的最顶材料对中形成多个开口。接着,将所述堆叠结构图案化为一阶梯结构,以将所述开口转移并形成在阶梯结构的每一阶中。然后,将导体材料填入所述开口中,以形成接垫。因此,相比于现有的接垫,本实施例的接垫的厚度较厚,其可防止接触窗开口工艺期间因过度刻蚀所导致的电性故障问题。另外,以厚度较厚的接垫当作形成接触窗开口的刻蚀停止层,其可提升接触窗开口工艺的工艺裕度并增加工艺合格率。To sum up, this embodiment can be achieved by forming a plurality of openings in the topmost material pair of the stacked structure. Next, the stacked structure is patterned into a stepped structure to transfer and form the openings in each step of the stepped structure. Then, conductive material is filled into the openings to form pads. Therefore, compared with the conventional pads, the thickness of the pads of the present embodiment is thicker, which can prevent electrical failures caused by excessive etching during the contact opening process. In addition, using a thicker pad as an etch stop layer for forming the contact opening can improve the process margin of the contact opening process and increase the process yield.
虽然本发明已以实施例揭露如上,然其并非用以限定本发明,任何所属技术领域中普通技术人员,在不脱离本发明的精神和范围内,当可作部分的更改与修饰,故本发明的保护范围当视权利要求所界定者为准。Although the present invention has been disclosed as above with examples, it is not intended to limit the present invention. Any person of ordinary skill in the art can make some changes and modifications without departing from the spirit and scope of the present invention. The protection scope of the invention shall be determined by the claims.
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