CN107987637A - There is paint vehicle of fatigue-relieving and preparation method thereof - Google Patents
There is paint vehicle of fatigue-relieving and preparation method thereof Download PDFInfo
- Publication number
- CN107987637A CN107987637A CN201711279247.1A CN201711279247A CN107987637A CN 107987637 A CN107987637 A CN 107987637A CN 201711279247 A CN201711279247 A CN 201711279247A CN 107987637 A CN107987637 A CN 107987637A
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- Prior art keywords
- parts
- paint vehicle
- fatigue
- relieving
- sericite
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to paint vehicle technical field for this, and in particular to a kind of paint vehicle with fatigue-relieving and preparation method thereof;It is prepared by the raw material of following parts by weight:Emulsion acrylic resin, modified sericite, negative ion powder, diatomite, vermiculite power, bentonite, preservative, fatty alcohol-ether sodium sulfate, dispersant, hydroxyethyl cellulose, coalescents and deionized water;It is produced by the present invention it is a kind of there is the paint vehicle of fatigue-relieving, have antiseptic property is good, wear-resisting and water resistance is good, long shelf-life;Moreover, being less prone to caking phenomenon, indoor toxic gas can be effectively adsorbed, improves indoor air quality, so as to reach alleviation mental fatigue, improves the effect of energy;In addition, mutually cooperateed between vinyl bis-stearamides and Tissuemat E so that diatomite, negative ion powder, vermiculite power and bentonite can be more uniformly spread in paint vehicle so that the bactericidal effect of paint vehicle is more preferable, so as to extend the shelf-life of paint vehicle.
Description
Technical field
The present invention relates to paint vehicle technical field, and in particular to a kind of to have effects that the paint vehicle of fatigue-relieving and its preparation side
Method.
Background technology
Paint vehicle refers generally to all liquid phase components in colored paint, is the semi-finished product for preparing paint, and main component has base-material, molten
Agent, auxiliary agent.Paint or paint are high molecular materials to coating, through use different coating process be coated on the surface of object with
Afterwards, tough and tensile and continuous film is formed, the material being attached on the surface of object is commonly called as, and is referred to as coating now, formation
This film is referred to as coating.Such as:Blending oil paint material, interior enamel paint varniss (quick-drying paint vehicle), vehicle for ready-mixed enamel paint etc..In addition, also
There are more dedicated such as wrinkle paint vehicle, phenolic aldehyde paint vehicle.Coating or paint vehicle are a kind of converted products, and raw material used include oil
The species such as fat, resin, pigment, filler, auxiliary agent and solvent and a multitude of names.These components mostly derive from chemical plant and oil
Factory.Actually user to paint vehicle it is desirable that paint film it is dry and hard after formed dura mater, competence exertion protection, decoration etc. function, from
For this meaning, paint vehicle is only a kind of semi-finished product of processing, and paint film is only real product, and coating belongs to fine chemistry industry production
Product.
There are antiseptic property is poor, wear-resisting and water resistance is poor, the shelf-life is short for currently marketed paint vehicle;Moreover, easily lump
Phenomenon, it is impossible to the shortcomings of effectively adsorbing indoor toxic gas.
The content of the invention
For above-mentioned problem, it is produced by the present invention it is a kind of there is the paint vehicle of fatigue-relieving, there are anti-corrosive properties
Energy is good, wear-resisting and water resistance is good, long shelf-life;Moreover, be less prone to caking phenomenon, can effectively adsorb indoor has poison gas
Body, improves indoor air quality, so as to reach alleviation mental fatigue, improves the effect of energy.
To achieve the above object, the present invention uses following technical solution:
It is a kind of that there is the paint vehicle of fatigue-relieving, it is prepared by the raw material of following parts by weight:Acrylic resin breast
It is 180-210 parts of liquid, modified 18-25 parts of sericite, 15-21 parts of negative ion powder, 12-18 parts of diatomite, 10-15 parts of vermiculite power, swollen
It is fine to moisten 8-12 parts of soil, 6.3-8.3 parts of preservative, 5.4-7.5 parts of fatty alcohol-ether sodium sulfate, 4.6-6.5 parts of dispersant, ethoxy
Tie up 70-80 parts of 3.6-5.3 parts of element, 2.8-4.8 parts of coalescents and deionized water.
Preferably, a kind of to have effects that the paint vehicle of fatigue-relieving, its preparation method comprises the following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, are ground, individually storage,
It is spare;
B, dispersant and surfactant are added in deionized water and 30- is stirred with the speed of 80-110r/min
45min, then the diatomite after grinding, negative ion powder, vermiculite power and bentonite are added thereto, obtained component is denoted as blending ingredients
A, blending ingredients A is transferred in high speed dispersor, under the rotating speed of 1100-1300r/min, disperses 45-60min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 650-
The speed stirring 55-75min of 800r/min, adjusts viscosity, up to paint vehicle finished product.
Preferably, the preparation method of the modified sericite is:It is its 5-8 times Aluminate that sericite is immersed in quality
In the mixed solution of coupling agent and titanate coupling agent, 35-50min is disperseed in high speed dispersor, rotating speed is set to 1200-
1600r/min, then takes out sericite, and natural air drying at room temperature, up to modified sericite, wherein aluminate coupling agent
Volume ratio with titanate coupling agent is 1:1.
Preferably, the coalescents select propylene glycol methyl ether acetate.
Preferably, the dispersant by vinyl bis-stearamides and Tissuemat E according to mass ratio 2:1 mixes.
Preferably, the preservative selects septichen phenyl ester.
Using above-mentioned technical solution, the beneficial effect that the present invention reaches is:
It is of the invention tired with alleviating as preparing using modified sericite, negative ion powder, diatomite, vermiculite power and bentonite
The paint vehicle of labor effect.Negative ion powder and diatomite mutual cooperation can increase the concentration of the positive and negative ion in air, negative ions group
The harmful substance such as allergin and other bacteriums, mould is encountered, most they resolve into the harmless objects such as hydrone at last, so that
Strengthen sterilizing ability.Moreover, both cooperate also with the toxic gas in absorption air, improve Interior Space makings
Amount, improves the immunity of the human body and boosts metabolism, so as to reach alleviation mental fatigue, improve the effect of energy.Modified thin,tough silk
The use of mica so that sericite is changed into hydrophobicity from hydrophily so that sericite is can be uniformly dispersed in paint vehicle, strengthens paint vehicle
Wearability, heat resistance and water resistance.In addition, mutually cooperateed between vinyl bis-stearamides and Tissuemat E so that diatom
Soil, negative ion powder, vermiculite power and bentonite can be more uniformly spread in paint vehicle so that and the bactericidal effect of paint vehicle is more preferable, from
And extend the shelf-life of paint vehicle.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical solution in the embodiment of the present invention is clearly and completely described.Based on the embodiment of the present invention, the common skill in this area
Art personnel all other embodiments obtained without creative efforts, belong to the model that the present invention protects
Enclose.
Embodiment 1:
It is a kind of that there is the paint vehicle of fatigue-relieving, it is prepared by the raw material of following parts by weight:Acrylic resin breast
180 parts of liquid, modified 21 parts of sericite, 15 parts of negative ion powder, 14 parts of diatomite, 10 parts of vermiculite power, 9 parts of bentonite, preservative 6.3
Part, 6.2 parts of fatty alcohol-ether sodium sulfate, 4.6 parts of dispersant, 4.2 parts of hydroxyethyl cellulose, 2.8 parts of coalescents and deionized water
75 parts.
A kind of to have effects that the paint vehicle of fatigue-relieving, its preparation method comprises the following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, are ground, individually storage,
It is spare;
B, dispersant and surfactant are added in deionized water and 30min is stirred with the speed of 80r/min, then will ground
Diatomite, negative ion powder, vermiculite power and bentonite after mill are added thereto, and obtained component is denoted as blending ingredients A, by blending ingredients
A is transferred in high speed dispersor, under the rotating speed of 1100r/min, disperses 45min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 650r/
The speed stirring 55min of min, adjusts viscosity, up to paint vehicle finished product.
The preparation method of the modified sericite is:By sericite be immersed in quality for its 5 times aluminate coupling agent and
In the mixed solution of titanate coupling agent, 35min is disperseed in high speed dispersor, rotating speed is set to 1200r/min, then by thin,tough silk
Mica takes out, and natural air drying at room temperature, up to the body of modified sericite, wherein aluminate coupling agent and titanate coupling agent
Product is than being 1:1.
1st, first with the concentration of formaldehyde and benzene in methylene oxide detecting instrument and the benzene detector detection room to be painted.Then will be through reality
The paint vehicle for applying the preparation of example 1 paints indoor wall, measures the concentration of indoor formaldehyde and benzene after 10 days again, and the decrement for obtaining formaldehyde is
84.6%, the decrement of benzene is 86.2%.
2nd, paint vehicle prepared by embodiment 1 is applied on the wall in room, the burst size of anion is measured after two hours
For 4876/s*cm3, it is 276% to smear fracture rate, viscosity 109.8KU.
Embodiment 2:
It is a kind of that there is the paint vehicle of fatigue-relieving, it is prepared by the raw material of following parts by weight:Acrylic resin breast
190 parts of liquid, modified 18 parts of sericite, 17 parts of negative ion powder, 12 parts of diatomite, 13 parts of vermiculite power, 8 parts of bentonite, preservative 6.9
Part, 5.4 parts of fatty alcohol-ether sodium sulfate, 5.2 parts of dispersant, 3.6 parts of hydroxyethyl cellulose, 3.3 parts of coalescents and deionized water
70 parts.
A kind of to have effects that the paint vehicle of fatigue-relieving, its preparation method comprises the following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, are ground, individually storage,
It is spare;
B, dispersant and surfactant are added in deionized water and 35min is stirred with the speed of 90r/min, then will ground
Diatomite, negative ion powder, vermiculite power and bentonite after mill are added thereto, and obtained component is denoted as blending ingredients A, by blending ingredients
A is transferred in high speed dispersor, under the rotating speed of 1180r/min, disperses 50min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 700r/
The speed stirring 60min of min, adjusts viscosity, up to paint vehicle finished product.
The preparation method of the modified sericite is:By sericite be immersed in quality for its 6 times aluminate coupling agent and
In the mixed solution of titanate coupling agent, 40min is disperseed in high speed dispersor, rotating speed is set to 1350r/min, then by thin,tough silk
Mica takes out, and natural air drying at room temperature, up to the body of modified sericite, wherein aluminate coupling agent and titanate coupling agent
Product is than being 1:1.
1st, first with the concentration of formaldehyde and benzene in methylene oxide detecting instrument and the benzene detector detection room to be painted.Then will be through reality
The paint vehicle for applying the preparation of example 2 paints indoor wall, measures the concentration of indoor formaldehyde and benzene after 10 days again, and the decrement for obtaining formaldehyde is
86.8%, the decrement of benzene is 87.9%.
2nd, paint vehicle prepared by embodiment 2 is applied on the wall in room, the burst size of anion is measured after two hours
For 4803/s*cm3, it is 249% to smear fracture rate, viscosity 107.4KU.
Embodiment 3:
It is a kind of that there is the paint vehicle of fatigue-relieving, it is prepared by the raw material of following parts by weight:Acrylic resin breast
200 parts of liquid, modified 25 parts of sericite, 19 parts of negative ion powder, 18 parts of diatomite, 14 parts of vermiculite power, 12 parts of bentonite, preservative
7.7 parts, 7.5 parts of fatty alcohol-ether sodium sulfate, 5.8 parts of dispersant, 5.3 parts of hydroxyethyl cellulose, 4.0 parts of coalescents and deionization
80 parts of water.
A kind of to have effects that the paint vehicle of fatigue-relieving, its preparation method comprises the following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, are ground, individually storage,
It is spare;
B, dispersant and surfactant are added in deionized water and 40min is stirred with the speed of 100r/min, then will
Diatomite, negative ion powder, vermiculite power and bentonite after grinding are added thereto, and obtained component is denoted as blending ingredients A, will mix group
Divide A to be transferred in high speed dispersor, under the rotating speed of 1250r/min, disperse 55min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 750r/
The speed stirring 65min of min, adjusts viscosity, up to paint vehicle finished product.
The preparation method of the modified sericite is:By sericite be immersed in quality for its 7 times aluminate coupling agent and
In the mixed solution of titanate coupling agent, 45min is disperseed in high speed dispersor, rotating speed is set to 1500r/min, then by thin,tough silk
Mica takes out, and natural air drying at room temperature, up to the body of modified sericite, wherein aluminate coupling agent and titanate coupling agent
Product is than being 1:1.
1st, first with the concentration of formaldehyde and benzene in methylene oxide detecting instrument and the benzene detector detection room to be painted.Then will be through reality
The paint vehicle for applying the preparation of example 3 paints indoor wall, measures the concentration of indoor formaldehyde and benzene after 10 days again, and the decrement for obtaining formaldehyde is
89.4%, the decrement of benzene is 86.3%.
2nd, paint vehicle prepared by embodiment 3 is applied on the wall in room, the burst size of anion is measured after two hours
For 4923/s*cm3, it is 262% to smear fracture rate, viscosity 108.2KU.
Embodiment 4:
It is a kind of that there is the paint vehicle of fatigue-relieving, it is prepared by the raw material of following parts by weight:Acrylic resin breast
210 parts of liquid, modified 23 parts of sericite, 21 parts of negative ion powder, 16 parts of diatomite, 15 parts of vermiculite power, 11 parts of bentonite, preservative
8.3 parts, 6.9 parts of fatty alcohol-ether sodium sulfate, 6.5 parts of dispersant, 4.7 parts of hydroxyethyl cellulose, 4.8 parts of coalescents and deionization
78 parts of water.
A kind of to have effects that the paint vehicle of fatigue-relieving, its preparation method comprises the following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, are ground, individually storage,
It is spare;
B, dispersant and surfactant are added in deionized water and 45min is stirred with the speed of 110r/min, then will
Diatomite, negative ion powder, vermiculite power and bentonite after grinding are added thereto, and obtained component is denoted as blending ingredients A, will mix group
Divide A to be transferred in high speed dispersor, under the rotating speed of 1300r/min, disperse 60min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 800r/
The speed stirring 75min of min, adjusts viscosity, up to paint vehicle finished product.
The preparation method of the modified sericite is:By sericite be immersed in quality for its 8 times aluminate coupling agent and
In the mixed solution of titanate coupling agent, 50min is disperseed in high speed dispersor, rotating speed is set to 1600r/min, then by thin,tough silk
Mica takes out, and natural air drying at room temperature, up to the body of modified sericite, wherein aluminate coupling agent and titanate coupling agent
Product is than being 1:1.
1st, first with the concentration of formaldehyde and benzene in methylene oxide detecting instrument and the benzene detector detection room to be painted.Then will be through reality
The paint vehicle for applying the preparation of example 4 paints indoor wall, measures the concentration of indoor formaldehyde and benzene after 10 days again, and the decrement for obtaining formaldehyde is
90.1%, the decrement of benzene is 89.6%.
2nd, paint vehicle prepared by embodiment 4 is applied on the wall in room, the burst size of anion is measured after two hours
For 4809/s*cm3, it is 258% to smear fracture rate, viscosity 111.7KU.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those of ordinary skill in the art that:It still can be to foregoing each implementation
Technical solution described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical solution.
Claims (6)
1. a kind of have effects that the paint vehicle of fatigue-relieving, it is characterised in that is prepared by the raw material of following parts by weight:Propylene
180-210 parts of acid resin lotion, modified 18-25 parts of sericite, 15-21 parts of negative ion powder, 12-18 parts of diatomite, vermiculite power 10-
15 parts, 8-12 parts of bentonite, 6.3-8.3 parts of preservative, 5.4-7.5 parts of fatty alcohol-ether sodium sulfate, 4.6-6.5 parts of dispersant, hydroxyl
70-80 parts of 3.6-5.3 parts of ethyl cellulose, 2.8-4.8 parts of coalescents and deionized water.
A kind of there is the paint vehicle of fatigue-relieving 2. according to claim 1, it is characterised in that its preparation method includes
Following steps:
A, modified sericite, diatomite, negative ion powder, vermiculite power and bentonite crushed, ground, individually storage, spare;
B, dispersant and surfactant are added in deionized water and 30-45min is stirred with the speed of 80-110r/min, then
Diatomite after grinding, negative ion powder, vermiculite power and bentonite are added thereto, obtained component is denoted as blending ingredients A, will mix
Component A is transferred in high speed dispersor, under the rotating speed of 1100-1300r/min, disperses 45-60min;
C, modified sericite is added in emulsion acrylic resin, after mixing, obtains blending ingredients B;
D, step b obtained materials are transferred to mixer, add blending ingredients B and surplus stock while stirring, and with 650-800r/
The speed stirring 55-75min of min, adjusts viscosity, up to paint vehicle finished product.
3. a kind of there is the paint vehicle of fatigue-relieving according to described in power claim 1, it is characterised in that the modified sericite
Preparation method be:It is molten that sericite is immersed in the mixing that quality is its 5-8 times of aluminate coupling agent and titanate coupling agent
In liquid, 35-50min is disperseed in high speed dispersor, rotating speed is set to 1200-1600r/min, then takes out sericite, and
Natural air drying at room temperature, up to modified sericite, the wherein volume ratio of aluminate coupling agent and titanate coupling agent is 1:1.
A kind of there is the paint vehicle of fatigue-relieving 4. according to claim 1, it is characterised in that:The coalescents choosing
Use propylene glycol methyl ether acetate.
A kind of there is the paint vehicle of fatigue-relieving 5. according to claim 1, it is characterised in that:The dispersant is by second
Alkenyl bis-stearamides and Tissuemat E are according to mass ratio 2:1 mixes.
A kind of there is the paint vehicle of fatigue-relieving 6. according to claim 1, it is characterised in that:The preservative is selected
Septichen phenyl ester.
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CN201711279247.1A CN107987637A (en) | 2017-12-06 | 2017-12-06 | There is paint vehicle of fatigue-relieving and preparation method thereof |
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CN201711279247.1A CN107987637A (en) | 2017-12-06 | 2017-12-06 | There is paint vehicle of fatigue-relieving and preparation method thereof |
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CN201711279247.1A Pending CN107987637A (en) | 2017-12-06 | 2017-12-06 | There is paint vehicle of fatigue-relieving and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109437817A (en) * | 2019-01-10 | 2019-03-08 | 佛山市山河水家居配套有限公司 | A kind of scrubbable water negative ion diatom ooze formula and preparation method thereof |
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CN104513572A (en) * | 2014-11-27 | 2015-04-15 | 浙江大学自贡创新中心 | Negative ion based paint |
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2017
- 2017-12-06 CN CN201711279247.1A patent/CN107987637A/en active Pending
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EP1293520A1 (en) * | 2001-09-14 | 2003-03-19 | Cray Valley Kunstharze GmbH | Aqueous dispersion of a polymer with high washability, its preparation and its use as binder in coating compositions |
CN104513572A (en) * | 2014-11-27 | 2015-04-15 | 浙江大学自贡创新中心 | Negative ion based paint |
Non-Patent Citations (2)
Title |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109437817A (en) * | 2019-01-10 | 2019-03-08 | 佛山市山河水家居配套有限公司 | A kind of scrubbable water negative ion diatom ooze formula and preparation method thereof |
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Application publication date: 20180504 |