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CN107979997A - Anhydrous powder formulation cosmetic composition - Google Patents

Anhydrous powder formulation cosmetic composition Download PDF

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Publication number
CN107979997A
CN107979997A CN201680034564.4A CN201680034564A CN107979997A CN 107979997 A CN107979997 A CN 107979997A CN 201680034564 A CN201680034564 A CN 201680034564A CN 107979997 A CN107979997 A CN 107979997A
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CN
China
Prior art keywords
silicone
cosmetic composition
powder formulation
weight
anhydrous powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680034564.4A
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Chinese (zh)
Inventor
姜弦月
姜愉珍
金京南
崔庚浩
崔荣镇
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Amorepacific Corp
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Amorepacific Corp
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Publication of CN107979997A publication Critical patent/CN107979997A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • A61K8/022Powders; Compacted Powders
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/895Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to one kind to include:Elastomer silicone;Include the elastomer silicone powder of Dimethicone/Vinyl Dimethicone cross-linked polymer silica;Include the silicone powders of vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer;Silicone oil;And the anhydrous powder formulation cosmetic composition of silica gel agent.

Description

Anhydrous powder formulation cosmetic composition
Technical field
The present invention relates to anhydrous powder formulation cosmetic composition.
This application claims the korean patent application 10-2015- submitted with June 30th, 2015 to the Korean Patent Room The right of the applying date of No. 0093767 application, entire contents include in the specification of the present application.
Background technology
Cosmetics containing powder have the same of the improvement colour of skin, isolation pore, wrinkle, skin problem etc. when acting on skin When, also have the function that to strengthen skin equilibrium state.This cosmetics containing powder are prepared into a variety of formulations, make emulsification During formulation, using emulsifying agent with dispersed oil and moisture, but there is the problem of persistence declines when coating for a long time, also deposit Emulsifying agent trigger stimulation skin the problem of.
In addition, as no water aqua type, when increasing the content of ethereal oil to strengthen oil absorption, because of the stabilization of formulation Property is unstable and there are the problem of formulation separation.
It is then desired to one kind is developed while with excellent oil absorption, the anhydrous powder formulation of stable dosage forms.
The content of the invention
Technical problem
The present invention provides a kind of anhydrous powder formulation cosmetic composition, and said composition is due to excellent oil suction energy Power, has excellent sebum absorbing ability and makeup persistence, excellent dosage form stability.
The technical solution solved the problems, such as
The present invention provides a kind of anhydrous powder formulation cosmetic composition, and said composition includes:Silicone elastomer gels; Include the elastomer silicone powder of Dimethicone/Vinyl Dimethicone cross-linked polymer silica End;Include the silicone powders of vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer;Silicon Oil;And silica gel agent.
Invention effect
Anhydrous powder formulation cosmetic composition of the present invention has sebum, the oil such as sweat discharged on skin Excellent absorbability, due to for no water aqua type, without using emulsifying agent when dispersed oil and moisture, thus be not in because Reduced to coat caused persistence for a long time, skin will not be stimulated.
Anhydrous powder formulation cosmetic composition of the present invention can largely contain the silicone oil of enhancing oil absorption, and The formulation separation because triggering containing a large amount of silicone oil, excellent in stability will not be produced.
Brief description of the drawings
Fig. 1 is the picture for shooting the comparative example 3 after being preserved 3 at 55 DEG C coated on skin.
Fig. 2 is the picture for shooting the comparative example 4 after being preserved 14 at 55 DEG C coated on (left side) skin, will be in 55 DEG C preserve 14 after comparative example 5 be coated on the picture that shoots of (right side) skin.
Fig. 3 is the picture for shooting the embodiment 4 after being preserved 14 at 55 DEG C coated on (left side) skin, will be in 55 DEG C preserve 14 after embodiment 6 be coated on the picture that shoots of (right side) skin.
Fig. 4 is after embodiment 6 is loaded in pomade bottle is placed 3 at 55 DEG C, right after being drawn off in the air Formulation is shot the picture that (right side) obtains.
Fig. 5 is after comparative example 2 is loaded in pomade bottle is placed 3 at 55 DEG C, right after being drawn off in the air Formulation is shot the picture that (left side) obtains.
Embodiment
The present invention provides anhydrous powder formulation cosmetic composition.Below to the anhydrous powder formulation cosmetics group of the present invention Compound is specifically described.
According to the present invention, the upper content limit of each constituent of above-mentioned composition is limited in the sum of content of total composition component In the range of 100 weight %.
The compound name referred in this specification it is other it is specifically mentioned in the case of, refer to cosmetics association of the U.S. The international cosmetic raw material collection of meeting (Cosmetic, Toiletry and Fragrance Association, CTFA) distribution INCI (the International included in (International Cosmetic Ingredient Dictionary, ICID) Nomenclature Cosmetic Ingredient) compound involved in Name, if phase is not present in INCI Name Title is closed, is referred to according to International Union of Pure and Applied Chemistry (International Union of Pure and Applied Chemistry, IUPAC) in formulate IUPAC nomenclatures represented by compound, there is no named according to IUPAC During compound represented by method, refer to the corresponding compound of the compound name general with the technical field of the invention.
According to the present invention, anhydrous powder formulation refers to not contain moisture in composition.It is expressed as not having during manufacture composition Have addition moisture, in particular it relates to the moisture of cosmetic composition account for 10 weight % of composition total weight Below.
1)Silicone elastomer gels
According to the present invention, above-mentioned silicone elastomer gels refer to the gel being injected into elastomer silicone in silicone oil, To the combined amount of elastomer silicone and silicone oil, there is no particular limitation.
According to embodiment of the present invention, silicone elastomer gels are selected from by cyclopolymethyl siloxane poly- two Methylsiloxane/vinyl dimethicone cross polymer, the crosslinking of cyclopolymethyl siloxane dimethyl silicone polymer The group of polymer and dimethyl silicone polymer Dimethicone/Vinyl Dimethicone cross-linked polymer composition In any one or combinations thereof.
According to embodiment of the present invention, the content of above-mentioned silicone elastomer gels accounts for the 0 of composition total weight Below 50 weight % of more than weight %.
2) elastomer silicone powder
According to the present invention, above-mentioned elastomer silicone powder includes dimethyl silicone polymer/vinylpolydimethyl silica Alkane cross-linked polymer silica.
According to embodiment of the present invention, the content of above-mentioned elastomer silicone powder accounts for the 3- of composition total weight 20 weight %, are preferably 3-10 weight %.When the content of above-mentioned elastomer silicone powder is less than 3 weight %, time at any time Passage, oil separation produce formulation stability problem;And more than 10 weight % in the case of, composition does not agglomerate, powdered and Can not be into slurry, so that the problem of producing in formulation manufacture.Conversely, the content of above-mentioned elastomer silicone powder is in 3-20 weight % Scope when, formulation has mobility, has adhesion strength between powder, formulation will not occur over time separation or from Dissipate, be able to maintain that stable state.
3) silicone powders
According to the present invention, above-mentioned silicone powders include vinyldimethicone/polymethyl siloxane silicon sesquialter Oxygen alkane cross-linked polymer.
According to embodiment of the present invention, the content of above-mentioned silicone powders accounts for the 5-25 weights of composition total weight % is measured, is preferably 5-10 weight %.When the content of above-mentioned silicone powders is less than 5 weight %, because of the adhesion strength deficiency between powder And can not be into the problem of slurry when producing manufacture;And more than 25 weight % in the case of, because in formulation oil separation and producing agent The problem of type stability.
4) silicone oil
According to the present invention, above-mentioned composition includes silicone oil, due to comprising silicone oil, above-mentioned elastomer silicone powder and above-mentioned The silicone oil that silicone powders are absorbed volatilizees after being coated on skin so that above-mentioned elastomer silicone powder and above-mentioned silicon tree Cosmetics end can effectively absorb the oil components such as sebum on skin, sweat.
According to embodiment of the present invention, above-mentioned silicone oil is selected from by cyclopentasiloxane cyclohexasiloxane, poly- two Any one in the group of methylsiloxane trisiloxanes and dimethyl silicone polymer composition or combinations thereof.
According to embodiment of the present invention, composition is accounted for relative to the gross weight of composition, the content of above-mentioned silicone oil The 40-60 weight % of gross weight.When the content of above-mentioned silicone oil is less than 40 weight %, because of the adhesion between oil absorption deficiency, powder Power deficiency and produce manufacture when can not into slurry the problem of;And more than 60 weight % in the case of, because in formulation oil separation and The problem of producing dosage form stability.
5) silica gel agent
According to the present invention, above-mentioned composition is due to containing silica gel agent, even if the silicone oil containing high-content, formulation will not Phase separation, becomes stable, can assign its soft use feeling.
According to embodiment of the present invention, above-mentioned silica gel agent is poly- for dimethyl silicone polymer/PEG-10/15 crosslinkings Compound cyclopentasiloxane.
According to embodiment of the present invention, the content of above-mentioned silica gel agent accounts for the 2-5 weight % of composition total weight. When the content of above-mentioned silica gel agent is less than 2 weight %, when producing manufacture because of the adhesion strength deficiency between oil absorption deficiency, powder Can not be into slurry the problem of;And more than 5 weight % in the case of, because in formulation oil separation produce asking for dosage form stability Topic.
6) other powders
According to embodiment of the present invention, above-mentioned composition is also included and is selected from by titanium dioxide, mica, poly- methyl-prop In the group of e pioic acid methyl ester, polymethylsilsesquioxane, silica and titanium oxide, iron oxide and polymethyl methacrylate composition Any one more than powder.Above-mentioned powder improves the colour of skin, isolation pore, wrinkle, skin problem etc. by reflection light While, there is the effect such as the persistence for absorbing sebum, lifting dressing, enhancing skin state equalization.
According to embodiment of the present invention, the content of above-mentioned powder accounts for the 2-25 weight % of composition total weight.On When stating the content of powder less than 2 weight %, skin can not be adhere well to, and the greasy negative use feeling in surface occurs;And surpass , can not be into the problem of slurry when producing manufacture in the case of crossing 25 weight %.
According to embodiment of the present invention, above-mentioned cosmetic composition in formulation can contain cosmeceutical or The medium or matrix that can be allowed on Dermatology.These compositions can be made according to the conventional method of technical field.
On the other hand, cosmetic composition of the invention can include the makeup such as common any heterogeneity in cosmetics Common auxiliary agent in conduct and learning or Dermatology field.Above-mentioned auxiliary agent can be used by cosmeceutical or Dermatology field Amount is added.
Hereinafter, in order to help to understand the present invention, the instantiations such as embodiment, comparative example and test example is enumerated and are said It is bright.However, following embodiments are not to be construed as being used to limit the present invention, within the scope of the present invention, art technology Personnel can carry out conventional change.
【Preparation example 1】Prepare embodiment 1-5 and comparative example 1
According to the composition of table 1 below, the composition of embodiment 1-5 and comparative example 1, the following institute of its detailed process are prepared respectively State.
Table 1
1)Dow Corning Corporation/DC 1-9852 SILICONE GEL
2) 9040 SILICONE ELASTOMER BLEND of Dow Corning Corporation/DC, poly dimethyl silicon Oxygen alkane/vinyl dimethicone cross polymer (96 weight %) and silica (4 weight %)
3)KCC CORPORATION/SM9120G(SeraSilk EL 61)
4)Dow Corning Corporation/Dow Corning 9701Cosmetic Powder
5)Shin-Etsu Chemical Co.,Ltd./KSP-101
6)Dow Corning Corporation/PMX-0345SILOXANE BLEND
7)Dow Corning Corporation/XIAMETER PMX-2127 FLUID
8)Shin-Etsu Chemical Co.,Ltd./KSG-240
9)K.S.PEARL Co.,Ltd./Sericite J
10)Negami Chemical Industrial Co.,Ltd./Artpearl K-7P
11)Momentive Performance Materials Inc./Tospearl*2000B
12)JGC C&C/Spherica Microbeads P-1500
13)DAITO KASEI KOGYO CO.,LTD./OTS-2 TIO2 CR-50
14)DAITO KASEI KOGYO CO.,LTD./OTS-2 YELLOW LLXLO
15)DAITO KASEI KOGYO CO.,LTD./OTS-2 RED R-516L
16)DAITO KASEI KOGYO CO.,LTD./OTS-2 BLACK BL-100
Component 1 and component 4 are used into the trade name that Primix companies manufacture as HIVIS Disper Mixer, 2P-1's Mixer, mixes 5 minutes under room temperature (25 DEG C).Then, component 5 and component 6 are added to the mixture of component 1 and component 4 In, using above-mentioned mixer, temperature control mixes 5 minutes below 50 DEG C, makes it scattered.
Component 2 and component 3 are slowly added to component 1 and component 4 into the mixture of component 6, using above-mentioned mixer, Temperature control mixes 5 minutes below 50 DEG C, makes it scattered, prepares the composition of embodiment 1-5 and comparative example 1 respectively.
【Test example 1】Measure the oil absorption to sebum
During by cosmetics of the present invention coated on skin, silicone powders, the contour suction of elastomer silicone powder Oil-bound distemper end is coated on skin in the state of containing oil, although just being reduced after coating to the oil absorption of sebum, coating Afterwards over time, since volatile ingredient gasifies and discharges, so as to recover the oil absorption to sebum.In order to its into Line justification, takes each 5g of the composition of above-described embodiment 1-5 and comparative example 1 to be put into beaker, at 50 DEG C after 30 minutes, respectively Will be by the artificial sebum of caprylic/capric triglyceride (the trade name Imex MCT 60/40 of InterMed companies manufacture) setting Wetting is proceeded as described below, measures oil absorbency.
The caprylic/capric triglyceride in the composition of above-mentioned 5g embodiments 1-5 and comparative example 1 is measured respectively The weight of (CAPRYLIC/CAPRIC TRIGLYCERIDE), slowly shakes off, and absorbs caprylic/capric triglyceride in related reagent Stage persistently repeat the above process.When it does not reabsorb caprylic/capric triglyceride, each agent absorbent is recorded respectively Amount, sebum oil absorbency is calculated according to following formula 1.
【Formula 1】
Caprylic/capric triglyceride (CAPRYLIC/CAPRIC in sebum oil absorbency (%)=related reagent TRIGLYCERIDE the final uptake (initial weight (5g) × 100 (%) of unit g)/related reagent)
The measurement result of the sebum oil absorbency of above-described embodiment 1-5 and comparative example 1 is as described in Table 2.
Table 2
Understand that there is excellent sebum oil absorbency with embodiment 1-5 on the contrary, comparative example 1 is because of formulation point as shown in Table 2 above From and can not measure.
【Test example 2】Measure dosage form stability
Above-described embodiment 1-5 and comparative example 1 are respectively charged into pipe, are inverted, after 55 DEG C are placed more than 2 weeks, is poured out simultaneously Observe its formulation state.
Because viscosity reduces phenomenon and oil is separately separated out or coated on skin when oil occurs to one layer point of skin From phenomenon be determined as formulation " separation ", be judged to " stablizing " when this phenomenon is not observed.
The measurement result whether formulation of above-described embodiment 1-5 and comparative example 1 separates is as described in Table 3.
Table 3
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 1
Whether formulation separates Stablize Stablize Stablize Stablize Stablize Separation
Understand as shown in Table 3 above, with the stable dosage forms of the embodiment 1-5 in the present application compositing range on the contrary, Formulation beyond the comparative example 2 of the compositing range of the present application is unstable.
【Preparation example 2】Prepare embodiment 4,6 and comparative example 2-6
Prepare embodiment 4,6 and the composition of comparative example 2-6 respectively, its concrete technology as shown in the composition of table 4 below, its He is identical with preparation example 1.
Table 4
1)-16):It is identical with above-mentioned table 1.
8-1)Dow Corning Corporation/DC BY 11-030
8-2)Evonik/ABIL EM 90
8-3)Shin-Etsu Chemical Co.,Ltd./KF-6038
【Test example 3】Measure dosage form stability
The composition of obtained embodiment 4,6 and comparative example 3-5 is inserted in pipe respectively, is placed 3 days at 55 DEG C.Then, After each composition placed 3 days is coated on skin, it is shot.In addition, the respectively combination after being placed 14 days in 55 DEG C After thing is coated on skin, it is shot, as shown in Figure 1-Figure 3.
Observe Fig. 1 and Fig. 2 to understand, the group of comparative example 3 (Fig. 1), comparative example 4 (on the left of Fig. 2) and comparative example 5 (on the right side of Fig. 2) Oil separates in compound formulation, and formulation is unstable.
On the contrary, known by Fig. 3, in the combination dosage form of embodiment 4 (on the left of Fig. 3) and embodiment 6 (on the right side of Fig. 3), oil is not Separation, stable dosage forms.
In addition, above-described embodiment 6 and comparative example 2 are fitted into pomade bottle after 55 DEG C are placed 3 respectively, it is drawn off sudden and violent After being exposed in air, whether there is a phenomenon where face checking for observation formulation.
Observe Fig. 4 and understand that the situation of comparative example 2, as shown in left photo, it was observed that formulation is split, formulation is unstable.Phase Instead, observe Fig. 5 and understand that the situation of embodiment 4, as shown in right photograph, is not observed and splits, stable dosage forms.

Claims (8)

1. a kind of anhydrous powder formulation cosmetic composition, it is characterised in that the composition includes:
Silicone elastomer gels;
Include the elastomer silicone of Dimethicone/Vinyl Dimethicone cross-linked polymer silica Powder;
Include the silicone powders of vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer;
Silicone oil;And
Silica gel agent.
2. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that elastomer silicone is choosing Free cyclopolymethyl siloxane Dimethicone/Vinyl Dimethicone cross-linked polymer, the poly- methyl silicon of ring Oxygen alkane Dimethicone Crosspolymer and dimethyl silicone polymer dimethyl silicone polymer/vinylpolydimethyl Any one in the group of Dimethicone Crosspolymer composition or combinations thereof.
3. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the elastomer silicone The content of powder accounts for the 3-20 weight % of composition total weight.
4. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the silicone powders Content accounts for the 5-25 weight % of composition total weight.
5. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the silicone oil be selected from by Appointing in the group of cyclopentasiloxane cyclohexasiloxane, dimethyl silicone polymer trisiloxanes and dimethyl silicone polymer composition Meaning one kind or combinations thereof.
6. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the content of the silicone oil accounts for The 40-60 weight % of composition total weight.
7. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the silica gel agent is poly- Dimethyl siloxane/PEG-10/15 cross-linked polymer cyclopentasiloxanes.
8. anhydrous powder formulation cosmetic composition according to claim 1, it is characterised in that the silica gel agent contains Amount accounts for the 2-5 weight % of composition total weight.
CN201680034564.4A 2015-06-30 2016-06-24 Anhydrous powder formulation cosmetic composition Pending CN107979997A (en)

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KR1020150093767A KR102405999B1 (en) 2015-06-30 2015-06-30 Anhydrous powder type comsmetic composition
KR10-2015-0093767 2015-06-30
PCT/KR2016/006760 WO2017003139A1 (en) 2015-06-30 2016-06-24 Cosmetic composition in the form of anhydrous powder preparation

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CN108542802B (en) * 2018-04-16 2019-07-19 广州市宝琳化妆品有限公司 A kind of transparent muffin of cosmetic and preparation method thereof
KR102321529B1 (en) * 2019-06-17 2021-11-04 코스맥스 주식회사 Anhydrous Eyebrow Make-up Cosmetic Composition
US20220362130A1 (en) * 2021-04-30 2022-11-17 L'oreal Compositions and methods for treating keratin fibers

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KR20170003291A (en) 2017-01-09
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