CN107915501A - With the method for acid or salt treatment excrement the bubble fertilizer of Malaysia clothing health copolymer - Google Patents
With the method for acid or salt treatment excrement the bubble fertilizer of Malaysia clothing health copolymer Download PDFInfo
- Publication number
- CN107915501A CN107915501A CN201610879301.5A CN201610879301A CN107915501A CN 107915501 A CN107915501 A CN 107915501A CN 201610879301 A CN201610879301 A CN 201610879301A CN 107915501 A CN107915501 A CN 107915501A
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- CN
- China
- Prior art keywords
- copolymer
- malaysia
- acid
- clothing health
- fertilizer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of method of acid with Malaysia clothing health copolymer or salt treatment excrement bubble fertilizer, 0.035 0.05 liters of the acid or salt of Malaysia clothing health copolymer are added in the fecaluria excreta of every cube of animal, reaction curing finishes.The method of the present invention can be applied in animal-breeding production operation, when the acid or salt of Malaysia clothing health copolymer are applied in the fecaluria excreta of animal with certain proportion, through action-reaction, it can make a silk purse out of a sow's ear, change excrement as fertilizer, obtain enhanced muck product, the muck product can returning to the field apply to agricultural planting, increase improves absorption of the plant to nutriment in soil and promotes plant growth.
Description
Technical field
The present invention relates to a kind of method for handling excrement bubble fertilizer.
Background technology
Due to promoting scale, intensive aquaculture model energetically, current livestock culture industry can produce substantial amounts of livestock and poultry
The discharge of waste, the waste of discharge will cause the eutrophication of water body, and Dissolved Oxygen in Water amount declines, contaminated soil and underground water,
Surface water, causes water quality deterioration, destroys ecological environment, and pathogenic microorganism jeopardizes mankind itself's health also through various approach, sternly
Ghost image sound and the sustainable development for constraining livestock and poultry breeding industry.Livestock and poultry breeding industry intensive degree is higher and higher, specialized feature
It is more and more obvious, it result in increasingly separating for aquaculture and planting industry.Farmland fertility is supplemented mainly by chemical fertilizer is applied at present, is raiseeed
Poultry manure significantly declines as farmland fertilizer proportion, and it is more and more common that excrement is huddled the phenomenon disorderly arranged, has also aggravated to ring
The pressure in border.More and more excrement for failing timely processing do not only take up a large amount of soils, and have become very important life
State and the major issue of environmental protection.
Fowl and animal excrement is one of animal farming industry major pollutants, in animal wastes containing a large amount of pathogenic bacteria, parasitic ovum,
Pathogenic microorganism etc., if unprocessed discharge, can cause people and animals' cross-infection, greatly influence people's health, threaten and support
Grow industry sound development.Promulgated in the Chinese government《Pollution from livestock and poultry prevents best practicable technology guide》In, it is indicated that China is only
Pig, ox, about 3,000,000,000 tons of chicken three major types feces of livestock and poultry year total release, the overwhelming majority is unprocessed directly to discharge rivers.
Feces of livestock and poultry is important regenerated resources, but due to a lack of the feces of livestock and poultry Treatment process for having promotional value accordingly,
Lack the wide application market of feces of livestock and poultry again, feces of livestock and poultry does not make full use of not only, conversely into the important pollution in China
Source.In 2016《(2016-2020) is planned in national live pig production development》In, clearly write discarded object synthesis profit to be promoted exactly
With summary promotes economy and uses excrement Utilization Mode, gets through decontamination of human excreta cropland application passage, promotes organic fertilizer on the spot
Comprehensively utilize nearby.In November, 2013《Livestock and poultry breeding scale pollution prevention ordinance》In clearly propose promote livestock and poultry cultivation give up
Gurry comprehensively utilizes and the prevention and cure of pollution thinking of harmless treatment：Encourage and support takes muck returning to the field, Biogas, manufacture to have
The methods of machine is fertile, comprehensively utilizes animal waste.It answer this, how to animal waste comprehensive utilization and nothing
Evilization is treated as one of emphasis of current animal husbandry environmental protection development.
The content of the invention
For the above-mentioned deficiency of the prior art, according to an embodiment of the invention, it is desirable to provide one kind is copolymerized with Malaysia clothing health
The method of acid or salt treatment excrement the bubble fertilizer of thing, it is intended to using the fecaluria excreta of livestock culture industry as raw material, by processing, can dissolve
Using the discarded object of livestock and poultry cultivation, feces of livestock and poultry, sewage the like waste is promoted locally to utilize.
In the method for the present invention, Malaysia clothing health copolymer is the reaction product of following Malaysias and clothing health monomer, the reaction product
It is up to 2 waterborne polymeric mixture for a kind of pH.
Wherein X is independently respectively selected from cation, preferably hydrogen, alkali and alkaline earth metal ions, most preferably H, NH4, Na, K,
Ca, Mg and their mixture.
In the method for the present invention, the acid or salt of Malaysia clothing health copolymer have below general formula：
Wherein, X as defined above, p 10-500.
The copolymer is the material with strong negative electrical charge, there is many bifurcateds on copolymer long-chain, can Preferential adsorption cation,
Can be with the confactor nickel ion (Ni of urase2+) combine, urase structure is changed and lose activity, the hydrolysis rate of urea subtracts
Slowly, so that fecaluria ammonia yield is reduced.
Also there is metalloenzyme (monooxygenase monooxygenase and hydroxylamine in bubble excrement
Oxidorreductase azanols oxidoreducing enzyme), the metalloenzyme in nitrobacteria is needed such as copper ion, iron ion etc., Cai Nengyu
Nitration reaction occurs for Nitrobacter and nitrosation sporangium, so that ammonium ion is changed into nitrite, is then then converted into
Nitrate.The copolymer can the metal cation such as Preferential adsorption copper ion and iron ion, suppress the reaction of metalloenzyme, so as to drop
Low Ammonia valatilization, and reduce nitrobacteria and ammonium ion is converted into the process of nitrate, so as to reduce ammonium salt, ammonia nitrogen
Loss, make to retain more absorbable nitrogen in soil, improve nitrogen by the absorption rate of plant.
Cation and combination outside the high negative electrical charge energy quick adsorption crawl of the polymer, reach charge balance, and energy
Disperse in whole manure pit, rapid distribution is diffused in whole fecaluria, decomposes duricrust, and softening reduces the solid in manure pit or lagoon
Content, makes the excrement dispersing and dissolving of caking ultimately form more stable mixed uniformly mixture, the bubble of mistake treated with a polymer
Excrement can be directly applied to soil, suppress the nitrification in soil and increase crop yield.
Also there are many zwitterions in soil, which can occur cation exchange reaction with soil, discharge ammonium root
Ion, while adsorbing metal ions, reduce the nitrification of nitrobacteria, improve ammonia-nitrogen content in soil, the length of the polymer
Chain characteristic makes it not consumed at once by nitrobacteria, can keep relatively long time in the soil, can prevent nitrobacteria
Play a role, improve ammonium salt utilization rate, improve soil fertility.The cations such as calcium, magnesium can reduce free phosphorus acid radical anion in soil
Content in earth, but the cation such as copolymer energy Preferential adsorption calcium, the magnesium, so that phosphorus can be inhaled by plant in a free form
Receive.
The polymer is water solubility, biodegradable, in returning and fertilizing in use, the polymer can also protect ammonium ion
It is prevented to be converted into nitrate or volatilization.The retention of phosphorus in the soil is reduced, prevents nitrogen volatilization and nitrogen from leaching, reduces nitrogen discharge,
By reducing the loss of nutrient in muck, play the role of environmental protection and help to improve the quality and yield using crops.
During the specific implementation present invention, 0.035- is used in the fecaluria excreta (manure pit/lagoon/cesspool cleaner truck) of every cube of animal
0.05 liter of polymer, waits excrement reaction curing to finish, you can returning to the field.Reaction product is water solubility, nontoxic to animal, can biology
Degraded, safe non-corrosiveness, various crops can be used.In field fertilization, which can also protect ammonium to prevent its conversion
For nitrate or volatilization.The retention of phosphorus in the soil is reduced, prevents nitrogen volatilization and nitrogen from leaching, nitrogen discharge is reduced, by reducing excrement
The loss of nutrient in fertilizer, plays the role of environmental protection and helps to improve the quality and yield using crops.
Relative to the prior art, the method for the present invention can be applied in animal-breeding production operation, when Malaysia clothing health copolymer
Acid or salt when being applied to certain proportion in the fecaluria excreta of animal, through action-reaction, can make a silk purse out of a sow's ear, change excrement as fertilizer,
Obtain enhanced muck product, the muck product can returning to the field apply to agricultural planting, increase improves plant to nutrition in soil
The absorption of material simultaneously promotes plant growth.
The method of the present invention is using the fecaluria excreta of livestock culture industry as raw material, by the acid or salt of Malaysia clothing health copolymer
Processing, can dissolve the discarded object using livestock and poultry cultivation, promote feces of livestock and poultry, sewage the like waste locally to utilize, be conducive to
The animal agriculture environmental protection industry situation for promoting breeding to combine, the technology follow the policy political affairs for the environment-protecting cultivation that country widelys popularize at present
Plan, meets ecological rule, creates a pleasant ecological environment and can avoid polluting, can finally obtain good economy, environment
And social benefit.
Brief description of the drawings
Fig. 1 be the corn irrigated in embodiment 2 using the processed muck of sodium salt of Malaysia clothing health copolymer root mass and
Root structure figure.
Fig. 2 be in embodiment 2 be not used Malaysia clothing health copolymer sodium salt processing muck irrigate corn root mass and
Root structure figure.
Embodiment
Below in conjunction with the accompanying drawings and specific embodiment, the present invention is further explained.These embodiments are interpreted as being only used for
It is bright the present invention rather than limit the scope of the invention.After the content of the invention recorded has been read, art technology
Personnel can make various changes or modifications the present invention, these equivalence changes and modification equally fall into the claims in the present invention and limited
Fixed scope.
In the present invention, the acid of Malaysia clothing health copolymer or the preparation process of salt (for example ammonium salt, sodium salt or sylvite) have no spy
Not part, using method commonly used in the art.
Embodiment 1
Virginia, USA Harrison fort corn trials yield result
Unused processed muck irrigated crop yield=21.4 ton/acre；
The crop yield irrigated using the muck after sylvite (every cube of 0.04 liter of dosage) processing of Malaysia clothing health copolymer
=27.3 tons/acre.
Embodiment 2
U.S. Iowa Charles Winslow is general.Randomly select seven corn tassels.Gross weight has notable difference.Use Malaysia clothing
The plant that muck after sodium salt (every cube of 0.05 liter of dosage) processing of health copolymer is irrigated is weighed 4.4 pounds, untapped to weigh
3.4 pound.3 plants are dug out from every piece of ground respectively, 4 inches are cut more than root, as shown in Figs. 1-2, can be appreciated that root mass and root system knot
Structure has significant difference.The use of the ball gross weight of Malaysia clothing health copolymer it is 44 ounces, untapped is 12 ounces.
Embodiment 3
In tests below 1-8,1 bushel=36 liters, the amount of the pig manure used in same experiment or liquid pig manure is identical, and
0.035 liter of the ammonium salt of Malaysia clothing health copolymer is added in every cube of pig manure or liquid pig manure.
Claims (3)
1. a kind of method of acid or salt treatment excrement bubble fertilizer with Malaysia clothing health copolymer, it is characterized in that, the fecaluria of every cube of animal
The acid or salt 0.035-0.05 liters of the copolymer with below general formula are added in excreta, reaction curing finishes,
Wherein, X is selected from cation, p 10-500.
2. the method for the acid or salt treatment excrement bubble fertilizer according to claim 1 with Malaysia clothing health copolymer, it is characterized in that, X
Selected from hydrogen, ammonium, alkali and alkaline earth metal ions.
3. the method for the acid or salt treatment excrement bubble fertilizer according to claim 1 with Malaysia clothing health copolymer, it is characterized in that, X
Selected from H, NH4, Na, K, Ca and Mg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610879301.5A CN107915501A (en) | 2016-10-08 | 2016-10-08 | With the method for acid or salt treatment excrement the bubble fertilizer of Malaysia clothing health copolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610879301.5A CN107915501A (en) | 2016-10-08 | 2016-10-08 | With the method for acid or salt treatment excrement the bubble fertilizer of Malaysia clothing health copolymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107915501A true CN107915501A (en) | 2018-04-17 |
Family
ID=61892261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610879301.5A Pending CN107915501A (en) | 2016-10-08 | 2016-10-08 | With the method for acid or salt treatment excrement the bubble fertilizer of Malaysia clothing health copolymer |
Country Status (1)
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105873966A (en) * | 2013-08-27 | 2016-08-17 | 沃戴申生命科学有限责任公司 | Polyanionic polymers |
-
2016
- 2016-10-08 CN CN201610879301.5A patent/CN107915501A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105873966A (en) * | 2013-08-27 | 2016-08-17 | 沃戴申生命科学有限责任公司 | Polyanionic polymers |
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