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CN107760582A - The integrated processing system and processing method of high concentrated organic wastewater and solid waste - Google Patents

The integrated processing system and processing method of high concentrated organic wastewater and solid waste Download PDF

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Publication number
CN107760582A
CN107760582A CN201711140232.7A CN201711140232A CN107760582A CN 107760582 A CN107760582 A CN 107760582A CN 201711140232 A CN201711140232 A CN 201711140232A CN 107760582 A CN107760582 A CN 107760582A
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anaerobic
organic wastewater
concentrated organic
high concentrated
microorganism
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CN107760582B (en
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胡小勇
袁丁
蒋铭明
张俊涛
李媛
林蓝
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Guangzhou Puchun Environmental Protection Technology Co Ltd
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Guangzhou Puchun Environmental Protection Technology Co Ltd
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Abstract

The present invention relates to technical field of waste water processing, more particularly to high concentrated organic wastewater and the integrated processing system and processing method of solid waste, the integrated processing system includes regulating reservoir, constant-temperatureanaerobic anaerobic reaction unit, normal temperature anaerobic pond and the multi-stage stepped aerobic device being sequentially connected and the solar energy temperature control system for constant-temperatureanaerobic anaerobic reaction unit temperature in control, also include being used for the microbial augmentation device for carrying out microorganism hot housing, microbial augmentation device is connected by bypass-feed Guan Yuzhong constant-temperatureanaerobic anaerobics reaction unit.Compared with prior art, the present invention carries out hot housing using microbial augmentation device to microorganism, anaerobic reaction is carried out subsequently into middle constant-temperatureanaerobic anaerobic reaction unit, and controls middle constant temperature of the anaerobic reaction at 35~37 DEG C, so as to effectively avoid Anaerobic Treatment process from going out the problem of being acidified at this stage;Whole integrated processing system makes organic pollution conversion ratio be significantly improved, and substantially reduces the wastewater treatment cycle, and whole system is stable.

Description

The integrated processing system and processing method of high concentrated organic wastewater and solid waste
Technical field
The present invention relates to technical field of waste water processing, and in particular to the integration of high concentrated organic wastewater and solid waste Processing system and processing method.
Background technology
High concentrated organic wastewater is mainly characterized by that organic concentration height, complicated component, colourity are high, have peculiar smell, if directly Run in and put, into receiving water body, water hypoxia will be caused, aquatic organism is dead, and environment is caused seriously to pollute.With domestic population Constantly increase, a large amount of sanitary wastewaters and part industrial wastewater rich in organic matter are discharged into river, lake, cause oxygen content of water big Width decline, cause river, lake generally present it is organic seriously polluted.And due to being not added with administering for a long time, substantial amounts of pollutant sinks Accumulate in river, lake-bottom, cause river, bottom mud in lake alluvial.Reducing substances in bed mud produces substantial amounts of biochemical oxygen demand River, bottom mud in lake is formed anaerobic environment, progressively degenerated in the case where anaerobe acts on, it is blackening, smelly.
The surface water organic contamination of current National major river valley is universal, and the section organic contamination for particularly flowing through city is tighter Weight, most urban groundwaters also receive a certain degree of point-like or facial contamination.At present, the processing side of high concentrated organic wastewater The biologic treating technique that formula is mainly combined using anaerobic and aerobic.But conventional anaerobic digestion construction investment is big, operational administrative is tight Lattice, operation and maintenance cost are high, and some potential safety hazards in actual motion be present, and these deficiencies greatly limit anaerobic digestion Technique popularizing in China's sludge treatment.In the prior art, anaerobic reaction system is primarily present problems with:1) it is permanent in Temperature distributing disproportionation in warm anaerobic reaction device is even, and fermentation temperature is difficult to stably control so that anaerobic reaction efficiency is low;2) The growth and breeding speed of anaerobic bacteria is slower, and it is longer not only make it that system starts the cycle, also results in that local acid-producing bacteria is excessive, under pH Drop and influence methane flora, acetic acid flora growth, so as to destroy the process of three stage of anaerobism successive reaction, such as cause acetic acid to accumulate It is tired few, there is the stage acidifying problem during anaerobic reaction, therefore need to chemical agents such as anaerobic reactor feeding limes.With Upper problem causes that the anaerobic reaction effect of current high concentrated organic wastewater is poor, and organic pollution conversion ratio is low, anaerobic reaction system System is difficult to really run;On the other hand, the Aerobic Process for Treatment mode that prior art uses, which has problems with, is:(1) routine is good Oxygen technique is acted directly on filler, and prolonged aerobic aeration can cause aerobic microbiological to be produced in system Expose, produce endogenous respiration, microorganism even faces the danger of disintegration;(2) in wastewater treatment process, using one-level Aerobic Pond, But when pollutant concentration is higher, whole waste water enter Aerobic Pond, and for the Aerobic Pond of single-stage, microorganism tends to fit The waste water dominant growth of high density pollution thing is answered, microbiologic population's growth for the pollutant of low concentration is suppressed, and is caused Waste water treatment efficiency is undesirable;(3) it is although current also it has been proposed that micro- method for sludge treatment, disposal ability are limited.Normal In the aerobic treatment process of rule, sludge yield coefficient is about 0.3kgVSS/kgBOD, and excess sludge in activated sludge process Discharge and standard biologic embrane method in biomembrane come off, substitute, can all there is substantial amounts of excess sludge produce.
The content of the invention
Above-mentioned technical problem be present for prior art, it is an object of the invention to provide a kind of thermostatic control, organic dirt Contaminate thing high conversion rate and the integrated processing system of cycle short, stable high concentrated organic wastewater and solid waste and Processing method.
To achieve the above object, the present invention provides following technical scheme:
The integrated processing system of high concentrated organic wastewater and solid waste is provided, including be sequentially connected regulating reservoir, Middle constant-temperatureanaerobic anaerobic reaction unit, normal temperature anaerobic pond, multi-stage stepped aerobic device and in control constant-temperatureanaerobic anaerobic reaction dress The solar energy temperature control system of temperature is put, in addition to for carrying out the microbial augmentation device of hot housing to microorganism, it is described micro- The discharging opening of biologically-intensifying device is connected by bypass-feed pipe with the middle constant-temperatureanaerobic anaerobic reaction unit.
Wherein, the microbial augmentation device includes microorganism reactor, is used for what the microorganism reactor connected Store the culture medium charging tank of special culture media and the function microbial inoculum charging tank for store function microbial inoculum;
The middle constant-temperatureanaerobic anaerobic reaction unit includes anaerobic reactor, is arranged at the sewage (waste water) recirculating pump and cloth of anaerobic reactor Hydrophone, the output end of the sewage (waste water) recirculating pump are connected by outlet pipe with the water inlet of the water-locator;The microbial augmentation The discharging opening of device is connected by bypass-feed pipe with the anaerobic reactor.
Wherein, the solar energy temperature control system includes solar energy heat collector, hot water reservoir, hot water circulating pump, setting In the heating tube of anaerobic reactor inwall, temperature sensor and controller, controller follows with temperature sensor and hot water respectively Ring pump electrically connects;One end of the heating tube is connected with the delivery port of the hot water circulating pump, the other end of the heating tube with The water inlet connection of the solar energy heat collector, the delivery port of the solar energy heat collector enter with the hot water reservoir The mouth of a river connects, and the delivery port of the hot water reservoir connects with the water inlet of the hot water circulating pump, the hot water circulating pump and The controller electrical connection.
Wherein, multiple biological contact reaction units are provided with the anaerobic reactor and microorganism reactor, each Biological contact reaction unit includes several biofilm packing components.
Wherein, the biofilm packing component include hollow ball, be fixed on the hollow ball center flexible filler, It is fixed on multiple blades of the hollow ball inwall and in the center of the hollow ball and the flexible filler Central siphon;The outer wall of the hollow ball offers several slotted eyes so that the outer wall forms the hollow out that multiple curved surfaces are staggeredly connected Shape curved-surface structure, circle distribution of the multiple blade along the hollow ball are set, and each blade sets fluted.
Wherein, the hollow ball is the hollow ball of polypropylene material injection moulding integrated molding, and the flexible filler is fibre Tie up the Ball-type packing of material.
Wherein, gas skirt, the gas outlet connection marsh gas purifying of the gas skirt are provided with the top of the anaerobic reactor Device.
Wherein, the multi-stage stepped aerobic device includes multiple Aerobic Ponds for setting gradually step by step, adjacent Aerobic Pond it Between connected by overflow pipe, each Aerobic Pond is provided with aerator and filler.
The present invention also provides high concentrated organic wastewater and the integral treatment method of solid waste, comprises the following steps:
(a) high concentrated organic wastewater in regulating reservoir or mud are delivered to microbial augmentation device and middle constant-temperatureanaerobic anaerobic respectively Reaction unit;Meanwhile the function microbial inoculum and special culture media of complex microorganism bacterial classification and biological enzyme formulation composition are by a certain percentage Microbial augmentation device is dosed to, it in reaction temperature is 35~37 DEG C, dissolved oxygen to control microbial augmentation device<0.2mg/L's Under the conditions of, hot housing is carried out to microorganism, microorganism is quickly bred;
(b) high concentrated organic wastewater or mud are delivered to by a certain percentage with the mixed liquor in microbial augmentation device and detested Oxygen reactor, and control anaerobic reactor to carry out Anaerobic Treatment under 35~37 DEG C of middle constant temperature;Anaerobic reactor often completes one Secondary charging, the charging aperture of microbial augmentation device and anaerobic reactor is simultaneously closed off, stop charging, treated mixed in anaerobic reactor After compound material completes Anaerobic Treatment, discharging, step a and b are then repeated, carries out the processing of next batch;
(c) constant-temperatureanaerobic anaerobic reaction unit has often handled biogas slurry discharging caused by a collection of mixed material to normal temperature anaerobism in Pond, after continuing anaerobic reaction at normal temperatures for a period of time, then it is delivered to multi-stage stepped aerobic device and carries out connecing for continuous multi-stage Touch oxidation processes.
Wherein, in step a, the total amount of adding of the complex microorganism bacterial classification contains COD with high concentrated organic wastewater or mud For 104Mg/L is counted, and the dosage of the function microbial inoculum accounts for high concentrated organic wastewater or the percent by volume of mud inlet amount is 0.1%~0.2%, the volume ratio of the dosage of the function microbial inoculum and special culture media is 1:10~20;
The complex microorganism bacterial classification include bacillus licheniformis, bacillus subtilis, bacillus lentus, Bdellovibrio, Bacillus megaterium, unwrapping wire aspergillus and lactobacillus acidophilus, the biological enzyme formulation include methane monooxygenase, ammona monooxygenase, Halogen hydrolase and alkyl monooxygenase, the bacillus licheniformis:Bacillus subtilis:Bacillus lentus:Bdellovibrio:It is huge Bacterium anthracoides:Unwrapping wire aspergillus:Lactobacillus acidophilus:Methane monooxygenase:Ammona monooxygenase:Halogen hydrolase:Alkyl list oxygenation The mass ratio of enzyme is 1~2:1~2:3~4:1~2:2.5~4:1~2.5:1~2:1~2.5:2~3:2~3:2.5~4;
In step b, the volume ratio 1~2 of high concentrated organic wastewater or mud and the mixed liquor in microbial augmentation device:8 ~9;The moisture content of the high concentrated organic wastewater is 92~95%.
Beneficial effects of the present invention:
The high concentrated organic wastewater of the present invention and the integrated processing system of solid waste, including the regulation being sequentially connected Pond, constant-temperatureanaerobic anaerobic reaction unit, normal temperature anaerobic pond and multi-stage stepped aerobic device and reacted for constant-temperatureanaerobic anaerobic in control The solar energy temperature control system of unit temp, in addition to for carrying out the microbial augmentation device of hot housing, micro- life to microorganism The discharging opening of thing intensifying device is connected by bypass-feed Guan Yuzhong constant-temperatureanaerobic anaerobics reaction unit;Its processing method include step a, High concentrated organic wastewater or mud in regulating reservoir are delivered to microbial augmentation device and middle constant-temperatureanaerobic anaerobic reaction unit respectively;Together When, complex microorganism bacterial classification and the function microbial inoculum and special culture media of biological enzyme formulation composition are dosed to microorganism by a certain percentage Intensifying device, it in reaction temperature is 35~37 DEG C, dissolved oxygen to control microbial augmentation device<Under conditions of 0.2mg/L, to micro- life Thing carries out hot housing, microorganism is quickly bred;Step b, by high concentrated organic wastewater or mud and microbial augmentation device Interior mixed liquor is delivered to anaerobic reactor by a certain percentage, and controls anaerobic reactor to be carried out under 35~37 DEG C of middle constant temperature Anaerobic Treatment;Anaerobic reactor is often completed once to feed, and simultaneously closes off the charging aperture of microbial augmentation device and anaerobic reactor, Stop charging, after the mixed material in anaerobic reactor completes Anaerobic Treatment, discharging, then repeat step a and b, carry out The processing of next batch;Step c, middle constant-temperatureanaerobic anaerobic reaction unit has often handled biogas slurry discharging caused by a collection of mixed material extremely Normal temperature anaerobic pond, after continuing anaerobic reaction at normal temperatures for a period of time, then it is delivered to multi-stage stepped aerobic device and carries out continuously Multistage catalytic oxidation processing.After anaerobic reactor disposably fills the mixed material that need to be handled, that is, it is anti-that anaerobism takes place Should, integrated processing system of the invention solves the insurmountable following technical problem of prior art:
(1) during the Anaerobic Treatment of middle constant temperature, the water body in anaerobic reactor is heated by solar energy temperature control system, And inner loop stirring is carried out with reference to sewage (waste water) recirculating pump, the heat of mixed liquor is distinguished evenly, it is achieved thereby that 35~37 DEG C Middle thermostatic control;
(2) hot housing, high concentrated organic wastewater or mud and function are carried out to microorganism using microbial augmentation device The mixed liquor that microbial inoculum, special culture media three are formed provides sufficient nutrient source for microorganism fungus kind, and control temperature 35~ 37 DEG C of middle constant temperature, special efficacy microorganism is obtained fast breeding and domestication under the growth conditions of optimization, then pass through bypass Into anaerobic reactor, accelerate special efficacy microorganism fungus kind in the growth rate of follow-up anaerobic reactor, quickly establish its dominant bacteria Group status, and then greatly shorten the startup cycle of anaerobic reactor;
(3) in the prior art, the microorganism fungus kind in anaerobic reactor, due to the growth rate of acid-producing bacteria and methane backeria not Together, it may result in that local acid-producing bacteria is excessive, pH declines and suppresses the growth of methane backeria and acetic acid flora, so as to destroy anaerobism three The process of stage successive reaction, anaerobic reactor of the invention are conveyed through microbial augmentation device by bypass on startup The microorganism species of hot housing, inner loop stirring is carried out in conjunction with sewage (waste water) recirculating pump, so as to control whole anaerobic reactor The relative equilibrium of middle anaerobic reaction, the problem of anaerobic stages are acidified effectively is avoided the occurrence of, anaerobism effect is good, turns organic pollution Rate is significantly improved, and substantially reduces the wastewater treatment cycle, and whole system is stable.
(4) multi-stage stepped aerobic device carries out Wastewater Pollutant load rating Aerobic Process for Treatment using multi-stage aerobic pond, makes Waste water aerobic in Aerobic Pond is uniform, and microorganism equably obtains nutrients, strengthens the adaptability of each microbiologic population, and series is got over More, the treatment effect that microorganism is directed under pollutant burdens at different levels is better, and pollutants at different levels are directed to by different microorganisms group The Combined Treatment of load, substantially increase the treatment effeciency of waste water;
(5) present invention can be not only used for handling the high life/industrial wastewater of organic pollution concentration, can be also used for locating Manage the solid waste such as sludge, fecal pollution, kitchen, it is only necessary in entrance before constant-temperatureanaerobic anaerobic reaction unit, by solid waste powder The broken mud that moisture content is made 92~95%, thus the present invention has broad application prospects.
Brief description of the drawings
Fig. 1 be the present invention high concentrated organic wastewater and solid waste integrated processing system structural representation.
Fig. 2 is anti-for the middle constant-temperatureanaerobic anaerobic of the integrated processing system of high concentrated organic wastewater and solid waste of the invention Answer the structural representation of device.
Fig. 3 fills for the microbial augmentation of the integrated processing system of high concentrated organic wastewater and solid waste of the invention The structural representation put.
Fig. 4 be the present invention high concentrated organic wastewater and solid waste integrated processing system solar energy temperature control system The structural representation of system.
Fig. 5 be the present invention high concentrated organic wastewater and solid waste integrated processing system biofilm packing group The structural representation of part.
Fig. 6 be the present invention high concentrated organic wastewater and solid waste integrated processing system biofilm packing group The structural representation of another angle of part
Fig. 7 be the present invention high concentrated organic wastewater and solid waste integrated processing system biofilm packing group The internal structure schematic diagram of part.
Fig. 8 is multi-stage stepped good for the integrated processing system of high concentrated organic wastewater and solid waste of the invention The structural representation of oxygen device.
Fig. 9 be the present invention high concentrated organic wastewater and solid waste integrated processing system Aerobic Pond structure Schematic diagram.
Description of reference numerals:
Regulating reservoir 1;
Microbial augmentation device 2, microorganism reactor 21, biological reaction tank 211, culture medium charging tank 22, function microbial inoculum Charging tank 23, bypass water inlet pipe 24;
Middle constant-temperatureanaerobic anaerobic reaction unit 3, anaerobic reactor 31, sewage (waste water) recirculating pump 32, water-locator 33, feed pipe 34, bypass Feed pipe 35, discharge nozzle 36, overflow pipe 37, water seal voltage-stabiliser tube 38, gas skirt 39;
Normal temperature anaerobic pond 4;
Biological contact reaction unit 5, biofilm packing component 51, hollow ball 511, slotted eye 5111, curved surface 5112, reinforcement Curved surface 5113, blade 512, linear leaf group 5121, short blade group 5122, groove 5123, flexible filler 513, central siphon 514, circle Shape blade 515, lanyard 52;
Solar energy temperature control system 6, solar energy heat collector 61, hot-water line 62, hot water reservoir 63, temperature sensor 64, Hot water circulating pump 65, heating tube 66, controller 67;
Multi-stage stepped aerobic device 7, Aerobic Pond 71, overflow pipe 72, air blower 73, blast main 74, branch road airduct 741, Aeration head 75, filler 76, training wall 77, net cage 78, control valve 79;
Methane purifying device 8, biogas residue processing unit 9.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1:
The integrated processing system of high concentrated organic wastewater and solid waste, as shown in figure 1, including the tune being sequentially connected Save pond 1, middle constant-temperatureanaerobic anaerobic reaction unit 3, normal temperature anaerobic pond 4, multi-stage stepped aerobic device 7 and detest for constant temperature in control The solar energy temperature control system 6 of the stable constant temperature in 35~37 DEG C of the reaction temperature of oxygen reaction unit 3, in addition to for microorganism The microbial augmentation device 2 of hot housing is carried out, the discharging opening of microbial augmentation device 2 passes through bypass-feed pipe 35 and middle constant temperature Anaerobic reaction device 3 connects.Regulating reservoir 1 mixes well high concentrated organic wastewater by mechanical agitation, makes it into subsequent treatment section The water of balance is kept, pollution concentration fluctuates small.The present invention can be not only used for handling the high life/work of organic pollution concentration Industry waste water, it can be also used for handling the solid waste such as sludge, fecal pollution, kitchen, first will be solid when for handling solid waste Body discarded object is crushed, and the mud that moisture content is made 92~95% is then further stirred in regulating reservoir 1.By Regulating reservoir 1 mix well after high concentrated organic wastewater or mud reacted by being pumped into microbial augmentation device 2 and middle constant-temperatureanaerobic anaerobic Device 3, the two charging keep synchronous.The disposable operation for noncontinuity is pumped into every time, i.e., is once pumped into until filling middle perseverance Untill warm anaerobic reaction device 3, after constant-temperatureanaerobic anaerobic reaction completely in the progress of middle constant-temperatureanaerobic anaerobic reaction unit 3, feed next time Shi Zaici is pumped into, i.e., carries out to sequence batch.
As shown in Fig. 2 middle constant-temperatureanaerobic anaerobic reaction unit 3 includes anaerobic reactor 31, is arranged at the dirt of anaerobic reactor 31 Water-circulating pump 32 and water-locator 33, the output end of sewage (waste water) recirculating pump 32 are connected by outlet pipe with the water inlet of water-locator 33.It is dirty Water-circulating pump 32 plays the circulation played to the circulation stirring effect sewage (waste water) recirculating pump 32 of high concentrated organic wastewater to mixed material Stirring action, water-locator 33 are arranged at the top of anaerobic reactor 31, the high concentrated organic wastewater anaerobism in anaerobic reactor 31 Mixed material in reactor 31 is sucked by the water inlet pipe of sewage (waste water) recirculating pump 32, passes through the water outlet of sewage (waste water) recirculating pump 32 after pressurization Pipe enters water-locator 33, so as to equably be discharged from the top of anaerobic reactor 31, forms interior circulate.It is anti-according to every batch anaerobism The mixed material treating capacity in the high concentrated organic wastewater anaerobic reactor 31 in device 31 is answered, often natural gift are multiple for sewage (waste water) recirculating pump 32 The start-up period, such as each the start-up period are 8 hours, including open 4 hours, shut down 4 hours/cycle.Anaerobic reactor 31 is set Be equipped with feed pipe 34, discharge nozzle 36 and bypass-feed pipe 35, the discharging opening of microbial augmentation device 2 by bypass-feed pipe 35 with Anaerobic reactor 31 connects.
Specifically, the top of anaerobic reactor 31 is provided with gas skirt 39, the gas outlet connection marsh gas purifying of gas skirt 39 Device 8.There is H in biogas2S, the impurity such as moisture, impurity need to be removed by methane purifying device 8.After gas skirt 39 collects biogas, Follow-up methane purifying device 8 is transported to by biogas pipe and storage utilizes system.Biogas pipe is provided with air pressure valve, sets air pressure It is worth for 3~5kPa, when biogas pressure is higher than this limit value in pond, air pressure valve is opened, and biogas is transferred out out of pond by biogas pipe Go.
The top of anaerobic reactor 31 is additionally provided with overflow pipe 37 and water seal voltage-stabiliser tube 38, wherein:Overflow pipe 37 connects out Expects pipe 36, high concentrated organic wastewater anaerobic reaction through a period of time in anaerobic reactor 31, surplus materials is for biogas slurry and less The biogas residue of amount, fed by regulating reservoir 1, the upper strata biogas slurry of anaerobic reactor 31 and biogas residue is raised liquid level, pass through the flash at top Pipe 37 is overflowed, and the normal temperature anaerobic pond 4 of subsequent processing is delivered to then along discharge nozzle 36.It is steady that water seal voltage-stabiliser tube 38 is used for water seal Pressure, make biogas will not loss to normal temperature anaerobic pond 4, while form stable atmospheric pressure, avoid anaerobic reactor 31 and normal temperature Suck-back, stabilizing solution invariant position are produced between anaerobic pond 4.The bottom of anaerobic reactor 31 is provided with the emptying connected with discharge nozzle 36 Pipe, evacuated tube is provided with valve, when needing to empty anaerobic reactor 31, opens valve, bottom slag charge can discharge, and pass through Cross the subsequent treatment that biogas residue processing unit 9 carries out biogas residue.
As shown in figure 3, the use that microbial augmentation device 2 includes microorganism reactor 21, connected with microorganism reactor 21 Culture medium charging tank 22 in storage special culture media and function microbial inoculum charging tank 23 for store function microbial inoculum.Microorganism is anti- Device 21 is answered to be provided with water inlet and discharging opening, water inlet connection bypass water inlet pipe 24, high concentrated organic wastewater or mud are by bypassing Water inlet pipe 24 is delivered in microorganism reactor 21, while function microbial inoculum charging tank 23 and culture medium charging tank 22 are respectively to micro- life Quantitative function microbial inoculum (including microorganism fungus kind and biological enzyme formulation) and special culture media, microorganism are added in thing reactor 21 Four biological reaction tanks 211, high concentrated organic wastewater or mud, function microbial inoculum and special culture media are additionally provided with reactor 21 Mixed liquor is formed in into biological reaction tank 211.
On the connecting line of culture medium charging tank 22 and microorganism reactor 21 and function microbial inoculum charging tank 23 and micro- life Measuring pump is provided with the connecting line of thing reactor 21, accurately controls the dosage of function microbial inoculum and special culture media Volume ratio is 1:10~20, and the dosage of function microbial inoculum accounts for high concentrated organic wastewater or the percent by volume of mud inlet amount is 0.1%~0.2%.Function microbial inoculum and special culture media use to link with charging, and the mode of synchronous start and stop adds, and realizes sequence batch Ground Automated condtrol.
The heating of solar energy temperature control system 6 according to the start and stop rule of sewage (waste water) recirculating pump 32 come start and stop, to ensure in heating There is circulation of fluid to carry out uniform heat exchange.See Fig. 4, solar energy temperature control system 6 includes solar energy heat collector 61, hot water storage Case 63, hot water circulating pump 65, the heating tube 66 for being arranged at the inwall of anaerobic reactor 31, temperature sensor 64 and controller, control Device processed electrically connects with temperature sensor 64 and hot water circulating pump 65 respectively, one end of heating tube 66 and the water outlet of hot water circulating pump 65 Mouth connection, the other end of heating tube 66 are connected with the water inlet of solar energy heat collector 61, the water outlet of solar energy heat collector 61 Mouth is connected by hot-water line 62 with the water inlet of hot water reservoir 63, delivery port and the hot water circulating pump 65 of hot water reservoir 63 Water inlet connects, and hot water circulating pump 65 electrically connects with controller 67.During work, solar energy heat collector 61 is by absorbing sun spoke Heating running water is penetrated, the running water after heating enters hot water reservoir 63 by hot-water line 62, by hot water circulating pump 65 by heat To heating tube 66, the mixed liquor in each reactor flows through heating tube 66 and added by heat exchange the delivery of water storage bin 63 Heat, hot water in heating tube 66 temperature after heat exchange reduce, and return to solar energy heat collector 61 and reheat and recycle, the mistake The temperature signal detected is fed back to controller 67 by temperature sensor 64 in journey, and then controller 67 controls hot water circulating pump 65 Flow, to realize that the stable temperature accurately controlled in anaerobic reactor 31 as middle 35~37 DEG C of constant temperature, carries for anaerobic reaction For most suitable temperature, improve anaerobic reactor 31 and handle the efficiency of high concentrated organic wastewater, and have using solar energy heating The advantages of energy-conserving and environment-protective.
Specifically, heating tube 66 is arranged to Stainless Steel Coil, heating tube 66 may be provided at anaerobic reactor 31 side wall and/ Or bottom wall, the mixed liquor in anaerobic reactor 31 is carried out fully heat exchange with the hot water in heating tube 66.Temperature sensor 64 are arranged on the top of the discharging opening of anaerobic reactor 31.
Specifically, microorganism reactor 21 and anaerobic reactor 31 are provided with heat-insulation layer, hot water reservoir 3 is provided with guarantor Warm layer, hot water reservoir 3 are used to store hot water, it is ensured that system temperature constant state in rainy weather is also able to maintain that.
After anaerobic reactor 31 disposably fills the mixed material that need to be handled, that is, anaerobic reaction takes place, the present invention During Anaerobic Treatment, solves the insurmountable technical problem of prior art:(1) by solar energy temperature control system 6 to anaerobism Water body heating in reactor 31, and combine sewage (waste water) recirculating pump 32 and carry out inner loop stirring, make the heat difference of mixed liquor more Uniformly, it is achieved thereby that 35~37 DEG C of middle thermostatic control;(2) reinforcing training is carried out to microorganism using microbial augmentation device 2 Support, the mixed liquor that high concentrated organic wastewater or mud are formed with function microbial inoculum, special culture media three provides for microorganism fungus kind Sufficient nutrient source, and and control middle constant temperature of the temperature at 35~37 DEG C, make special efficacy microorganism under the growth conditions of optimization Fast breeding and domestication are obtained, is then bypassed to anaerobic reactor, it is anti-in follow-up anaerobism to accelerate special efficacy microorganism fungus kind The growth rate of device is answered, quickly establishes its dominant microflora status, and then greatly shortens the startup cycle of anaerobic reactor;(3) it is existing Have in technology, the microorganism fungus kind in anaerobic reactor, because acid-producing bacteria is different from the growth rate of methane backeria, may result in Local acid-producing bacteria is excessive, pH declines and suppresses the growth of methane backeria and acetic acid flora, so as to destroy three stage of anaerobism successive reaction Process, anaerobic reactor of the invention on startup i.e. by bypass is conveyed through the micro- of microbial augmentation device hot housing Biological flora, inner loop stirring is carried out in conjunction with sewage (waste water) recirculating pump, so as to control anaerobic reaction in whole anaerobic reactor Relative equilibrium, the problem of anaerobic stages are acidified effectively is avoided the occurrence of, anaerobism effect is good, organic pollution conversion ratio is obtained significantly Improve, substantially reduce the wastewater treatment cycle, and whole system is stable;(4) the inside whipping process of anaerobic reactor 31 Also help the effusion of biogas in anaerobic reaction.
In the present embodiment, it is linked with the biological reaction tank 211 of anaerobic reactor 31 and microorganism reactor 21 multiple Biological contact reaction unit 5 (see Fig. 2 and Fig. 3), each biological contact reaction unit 5 include several biofilm packing components 51.As preferred embodiment, each biological contact reaction unit 5 of the present embodiment is by several biofilm packing components 51 are in series.As shown in Figures 5 to 7, biofilm packing component 51 includes hollow ball 511, is fixed in hollow ball 511 The flexible filler 513 of the heart, the multiple blades 512 for being fixed on the inwall of hollow ball 511 and filled out through hollow ball 511 and flexibility Material 513 center central siphon 514, the outer wall of hollow ball 511 offer several U-type groove holes 5111 so that outer wall formed it is more The Openworks shape curved-surface structure that individual curved surface 5112 is staggeredly connected.Outer wall radially provided circumferentially about, which has, strengthens curved surface 5113, strengthens Curved surface 5113 is connected with other curved surfaces 5112 on outer wall.Hollow ball 511 is the sky of polypropylene material injection moulding integrated molding Bulbus cordis body 511, integrated formed structure is easy to process, and hollow ball 511 provides profile support with being connected, and its diameter is preferably arranged to 12~18cm, the width of curved surface 5112 are arranged to 1.8~2.2cm, but according to actual needs, the diameter of hollow ball 511 The width of size and curved surface 5112 can be adjusted arbitrarily.
Specifically, circle distribution of multiple blades 512 along hollow ball 511 is set, each blade 512 sets fluted 5123.Multiple blades 512 include linear leaf group 5121 and short blade group 5122, and linear leaf group 5121 is held within non-radial end The inwall of curved surface 5112 on, short blade group 5122 is held within the inwall of curved surface 5112 of longitudinal end.Linear leaf group 5121 is set It is equipped with and upper and lower spaced two layers of groove 5123, short blade group 5122 is provided with one layer of groove 5123.Increase on blade 512 The structure of groove 5123 is added, has thereby increased the specific surface area of filler, it is equal in biofilm packing component 51 to be advantageous to waste water Even distribution, microorganism is set to be easy to biofilm on filler surface, and blade 512 and the structure of groove 5123 also have the work(of cutting bubble Can (be used for aerobic in have the situation of aeration), improve the ventilatory effect in filler.As preferred embodiment, blade 512 Length is arranged to 2.5~4.5cm, and the spacing of adjacent blades 512 is arranged to 1.5~2.5cm, and the spacing of two layers of groove 5123 is set It is preferable for 1.5~2cm effect.
Specifically, flexible filler 513 is the Ball-type packing of Fiber Materials.The volume of Ball-type packing accounts for hollow ball 511 It is preferable when 1/3rd, a diameter of 4~6cm.The preferred acrylic fibers of Fiber Materials, polypropylene fibre, dacron thread form ball as raw material through ligation Shape filler, its performance indications meet that effect is preferable during following condition:1.08~1.48g/cm of density, 4~6cm of sphere diameter, hydroscopicity 0.35-0.55%, voidage 86%~90%.The 513 fluffy curling of flexible filler and softness, make microorganism adsorption effect good, Biofilm is fast, can be accelerated by the loss function of flexible filler 513 on the blade 512 and groove 5123 on outer hollow spheroid 511 Film forming speed, and flexible filler 513 is fixed on to the inside of hollow ball 511, floatation surface will not be gone up.Flexible filler 513 is logical The center that central siphon 514 is fixed on hollow ball 511 is crossed, is provided with above and below flexible filler 513 soft for fixing The circular blade 516 of property filler 513, circular blade 516 are fixedly connected with central siphon 514.The central siphon 514 can wear lanyard 52 (such as nylon rope) or other be used for the suspension member of biofilm packing component 51 of connecting, so as to which multiple biofilm packing components 51 be strung Ordered arrangement is carried out after coming, that is, obtains biological contact reaction unit 5, its water treatment effect is notable.It is determined that biofilm packing When the quantity of component 51 and the spacing of biofilm packing component 51, need to according to the depth of water situation of waste water disposal facility, water quality characteristicses, The factors such as treatment effect formulate Distribution Principles.
During work, the mixed liquor of high concentrated organic wastewater or mud, function microbial inoculum and special culture media composition is in microorganism Biofilm packing component 51 is slowly flowed across in the biological reaction tank 211 of reactor 21, mixed liquor with biomembrane by ceaselessly filling out Expect the contact of component 51, microorganism fungus kind absorption forms biomembrane on filler surface, and it is middle constant temperature to control temperature, so that mixed The microorganism fungus kind fast breeding in liquid is closed, finally conveys the mixed liquor after microbial augmentation by bypass-feed pipe 34 Follow-up wastewater treatment is carried out to anaerobic reactor 31, and further passes through the biofilm packing component in anaerobic reactor 31 51.After the reaction of every batch terminates, high concentrated organic wastewater or mud stop input to microorganism reactor 21 and anaerobic reaction Device 31, while function microbial inoculum charging tank 23 and culture medium charging tank 22 also stop feeding intake, remaining mixing in biological reaction tank 211 Microorganism fungus kind on liquid and biofilm packing component 51 continues to breed.Biofilm packing component 51 is fast with film forming, cloth water cloth The advantages of gas is preferable, the microorganism fungus kind for making to add are easy to absorption in filler surface and fast breeding, raising microorganism fungus kind Reproduction speed, and then realize that the efficient anaerobic bacteria flora of middle stabilization in anaerobic reactor 31 accounts for dominant advantage, and in every order Sufficient ripe acetic acid bacteria, methane flora are reserved when criticizing charging, to avoid the occurrence of stage acidifying problem, Anaerobic Treatment effect obtains Significantly improve.
In the present embodiment, as shown in Figure 8 and Figure 9, multi-stage stepped aerobic device 7 include set gradually step by step eight it is good Oxygen pond 71, waste water are handled by the catalytic oxidation of continuous multi-stage successively.Connected, given up by overflow pipe 72 between adjacent Aerobic Pond 71 Water enters upper level Aerobic Pond 71 and can pass through the Aerobic Pond 71 that overflow pipe 72 enters next stage after reaching certain water level.It is aerobic Pond 71 is provided with aerator, and aerator includes the blast main 74 connected with air blower 73, and blast main 74 connects some branch roads Airduct 741, branch road airduct 741 extend to the bottom of Aerobic Pond 71, and the bottom connection aeration head 75 of branch road airduct 741, each Branch road airduct 741 is provided with control valve 79 with the junction of blast main 74.The middle part of Aerobic Pond 71 is provided with filler 76, and by net cage 78 are limited in certain area, avoid filler 76 from arbitrarily being moved about in Aerobic Pond 71 with aeration gas flow.Per the pond of one-level Aerobic Pond 71 Bottom among body is respectively provided with training wall 77, and both sides current connect here.
During work, waste water enters after multi-stage stepped aerobic device 7, sets the Aerobic Pond 71 of multiple ranks, waste water point Level flows into, uniformly aerobic in Aerobic Pond 71;It is free in bacterium sparse in waste water and is attached to the surface of filler 76, with bacterium Breeding gradually forms biomembrane, and under conditions of dissolved oxygen and organic matter are all sufficient, microorganism breeds rapidly, by biomembrane with The contact of waste water, the organic matter in waste water are utilized and degraded and remove by microorganisms;When biomembrane grows to certain thickness, dissolved oxygen Internal layer biomembrane can not be diffused into, the anaerobic bacteria of internal layer starts to breed, and microorganism attachment bacterium colony steady in a long-term is formed, because of current Flow velocity is low, aeration is not directly placed on biomembrane, and it is low to wash away dynamics, and microorganism coefficient of producing sewage sludge is low, it is few produce it is remaining dirty Mud.Compared with prior art, multi-stage stepped aerobic device 7 has advantages below:(1) use and be not directly placed on biomembrane Aeration mode, make uniform aeration in Aerobic Pond 71, overexposure will not be produced, avoid microorganism and violent endogenous respiration occurs and disintegrates Phenomenon;(2) using the method for multisection type pollutant burden classification processing, it is beneficial to form the excellent of the respective pollutant burden of adaptation Gesture microbiologic population, greatly improved for the purification efficiency of pollutant burdens at different levels;(3) directly using the microorganism in waste water certainly So attachment forms microbial film, and stability is preferable, and microorganism coefficient of producing sewage sludge is low, and excess sludge is few.
Embodiment 2:
The high concentrated organic wastewater of the present embodiment and the integral treatment method of solid waste, it is to use embodiment 1 What reaction unit was carried out, this method is used to handle high concentrated organic wastewater, and it comprises the following steps:
(a) high concentrated organic wastewater in regulating reservoir or mud are delivered to microbial augmentation device and middle constant-temperatureanaerobic anaerobic respectively Reaction unit;Meanwhile the function microbial inoculum and special culture media of complex microorganism bacterial classification and biological enzyme formulation composition are by a certain percentage Microbial augmentation device is dosed to, it in reaction temperature is 35~37 DEG C, dissolved oxygen to control microbial augmentation device<0.2mg/L's Under the conditions of, hot housing is carried out to microorganism, microorganism is quickly bred;
(b) high concentrated organic wastewater or mud are delivered to by a certain percentage with the mixed liquor in microbial augmentation device and detested Oxygen reactor, and control anaerobic reactor to carry out Anaerobic Treatment under 35~37 DEG C of middle constant temperature;Anaerobic reactor often completes one Secondary charging, the charging aperture of microbial augmentation device and anaerobic reactor is simultaneously closed off, stop charging, treated mixed in anaerobic reactor After compound material completes Anaerobic Treatment, discharging, step a and b are then repeated, carries out the processing of next batch;
(c) constant-temperatureanaerobic anaerobic reaction unit has often handled biogas slurry discharging caused by a collection of mixed material to normal temperature anaerobic pond in 4, after continuing anaerobic reaction at normal temperatures for a period of time, then it is delivered to multi-stage stepped aerobic device and carries out Wastewater Pollutant load Aerobic Process for Treatment is classified, the water after processing is discharged from delivery port.
In step a, the total amount of adding of complex microorganism bacterial classification contains COD as 10 using high concentrated organic wastewater or mud4mg/L Meter, it is 0.1% that the dosage of function microbial inoculum, which accounts for high concentrated organic wastewater or the percent by volume of mud inlet amount, function microbial inoculum and The volume ratio of the dosage of special culture media is 1:10.
Complex microorganism bacterial classification includes bacillus licheniformis, bacillus subtilis, bacillus lentus, Bdellovibrio, huge Bacillus, unwrapping wire aspergillus and lactobacillus acidophilus;Biological enzyme formulation includes methane monooxygenase, ammona monooxygenase, halogen hydrolysis Enzyme and alkyl monooxygenase.Wherein, bacillus licheniformis:Bacillus subtilis:Bacillus lentus:Bdellovibrio:Huge gemma Bacillus:Unwrapping wire aspergillus:Lactobacillus acidophilus:Methane monooxygenase:Ammona monooxygenase:Halogen hydrolase:The matter of alkyl monooxygenase Amount is than being 1:1:3.3:1:3:1.6:1:1.8:2:2.4:3;
In step b, the volume ratio 1 of high concentrated organic wastewater or mud and the mixed liquor in microbial augmentation device:9.
Embodiment 3:
The high concentrated organic wastewater of the present embodiment and the integral treatment method of solid waste, main technical schemes and reality The identical of example 2 is applied, difference is:
In step a, the total amount of adding of complex microorganism bacterial classification contains COD as 10 using high concentrated organic wastewater or mud4mg/L Meter, it is 0.2% that the dosage of function microbial inoculum, which accounts for high concentrated organic wastewater or the percent by volume of mud inlet amount, function microbial inoculum and The volume ratio of the dosage of special culture media is 1:20;
Bacillus licheniformis:Bacillus subtilis:Bacillus lentus:Bdellovibrio:Bacillus megaterium:Unwrapping wire aspergillus: Lactobacillus acidophilus:Methane monooxygenase:Ammona monooxygenase:Halogen hydrolase:The mass ratio of alkyl monooxygenase is 1:1:3:1: 3:1:1:2:2:2:4;
In step b, the volume ratio 2 of high concentrated organic wastewater or mud and the mixed liquor in microbial augmentation device:8.
Embodiment 4:
The high concentrated organic wastewater of the present embodiment and the integral treatment method of solid waste, main technical schemes and reality The identical of example 2 is applied, difference is:
In step a, the total amount of adding of complex microorganism bacterial classification contains COD as 10 using high concentrated organic wastewater or mud4mg/L Meter, it is 0.15% that the dosage of function microbial inoculum, which accounts for high concentrated organic wastewater or the percent by volume of mud inlet amount, function microbial inoculum Volume ratio with the dosage of special culture media is 1:15;
Bacillus licheniformis:Bacillus subtilis:Bacillus lentus:Bdellovibrio:Bacillus megaterium:Unwrapping wire aspergillus: Lactobacillus acidophilus:Methane monooxygenase:Ammona monooxygenase:Halogen hydrolase:The mass ratio of alkyl monooxygenase is 2:1:4:2: 4:2.5:2:1:3:3:2.5;
In step b, the volume ratio 1.5 of high concentrated organic wastewater or mud and the mixed liquor in microbial augmentation device: 8.5。
Embodiment 5:
In the batch-type of the present embodiment constant-temperatureanaerobic anaerobic processing high concentrated organic wastewater processing method, main technical schemes with Embodiment 2 it is identical, difference is:The method of the present embodiment is to be used to handle the solid wastes such as sludge, fecal pollution, kitchen Thing, i.e. high concentrated organic wastewater replace with mud, meanwhile, this method also includes before step a:
Step a0, the pretreatment of solid waste:
By solid waste after crushing, regulating reservoir is delivered to, then by the solid waste of crushing in regulating reservoir It is agitated to be mixed and made into the mud that moisture content is 92~95%;
Also include between step b and c:
Step c0, dewater treatment:
Mixed liquor in middle constant-temperatureanaerobic anaerobic reaction unit is delivered to equipment for separating liquid from solid and carries out dewater treatment, dewater treatment Biogas slurry and biogas residue are produced afterwards;
Wherein biogas slurry continues the processing of subsequent processing through step c, and biogas residue then carries out follow-up place by biogas residue processing unit Reason.
The present invention can be not only used for handling industrial wastewater, can be also used for handling the solid wastes such as sludge, fecal pollution, kitchen Thing, to the high treating effect of organic pollution, thus have broad application prospects.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected The limitation of scope is protected, although being explained with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Work as understanding, technical scheme can be modified or equivalent substitution, without departing from the reality of technical solution of the present invention Matter and scope.

Claims (10)

1. the integrated processing system of high concentrated organic wastewater and solid waste, it is characterised in that:Including the tune being sequentially connected Save pond, middle constant-temperatureanaerobic anaerobic reaction unit, normal temperature anaerobic pond, multi-stage stepped aerobic device and anti-for constant-temperatureanaerobic anaerobic in control The solar energy temperature control system of unit temp is answered, in addition to for carrying out the microbial augmentation device of hot housing, institute to microorganism The discharging opening for stating microbial augmentation device is connected by bypass-feed pipe with the middle constant-temperatureanaerobic anaerobic reaction unit.
2. the integrated processing system of high concentrated organic wastewater according to claim 1 and solid waste, its feature exists In:The microbial augmentation device includes microorganism reactor, connected with the microorganism reactor for storing special training Support the culture medium charging tank of base and the function microbial inoculum charging tank for store function microbial inoculum;
The middle constant-temperatureanaerobic anaerobic reaction unit includes anaerobic reactor, is arranged at the sewage (waste water) recirculating pump and water distribution of anaerobic reactor Device, the output end of the sewage (waste water) recirculating pump are connected by outlet pipe with the water inlet of the water-locator;The microbial augmentation dress The discharging opening put is connected by bypass-feed pipe with the anaerobic reactor.
3. the integrated processing system of high concentrated organic wastewater according to claim 2 and solid waste, its feature exists In:The solar energy temperature control system includes solar energy heat collector, hot water reservoir, hot water circulating pump, is arranged at anaerobic reaction Heating tube, temperature sensor and the controller of device inwall, controller electrically connect with temperature sensor and hot water circulating pump respectively; One end of the heating tube is connected with the delivery port of the hot water circulating pump, the other end of the heating tube and the solar energy collection The water inlet connection of thermal, the delivery port of the solar energy heat collector connect with the water inlet of the hot water reservoir, institute The delivery port for stating hot water reservoir connects with the water inlet of the hot water circulating pump, the hot water circulating pump and controller electricity Connection.
4. the integrated processing system of high concentrated organic wastewater according to claim 2 and solid waste, its feature exists In:Multiple biological contact reaction units are provided with the anaerobic reactor and microorganism reactor, each biological is anti- Unit is answered to include several biofilm packing components.
5. the integrated processing system of high concentrated organic wastewater according to claim 4 and solid waste, its feature exists In:The biofilm packing component include hollow ball, be fixed on the flexible filler at the hollow ball center, be fixed on it is described The multiple blades and the central siphon through the hollow ball and the center of the flexible filler of hollow ball inwall;The sky The outer wall of bulbus cordis body offers several slotted eyes so that the outer wall forms multiple curved surfaces and interlocked connected Openworks shape curved-surface structure, Circle distribution of the multiple blade along the hollow ball is set, and each blade sets fluted.
6. the integrated processing system of high concentrated organic wastewater according to claim 5 and solid waste, its feature exists In:The hollow ball is the hollow ball of polypropylene material injection moulding integrated molding, and the flexible filler is the ball of Fiber Materials Shape filler.
7. the integrated processing system of high concentrated organic wastewater according to claim 2 and solid waste, its feature exists In:Gas skirt, the gas outlet connection methane purifying device of the gas skirt are provided with the top of the anaerobic reactor.
8. the integrated processing system of high concentrated organic wastewater according to claim 1 and solid waste, its feature exists In:The multi-stage stepped aerobic device includes the multiple Aerobic Ponds set gradually step by step, passes through overflow between adjacent Aerobic Pond Pipe connects, and each Aerobic Pond is provided with aerator and filler.
9. the integral treatment method of high concentrated organic wastewater and solid waste, it is characterised in that:Comprise the following steps:
(a) high concentrated organic wastewater in regulating reservoir or mud are delivered to microbial augmentation device and the reaction of middle constant-temperatureanaerobic anaerobic respectively Device;Meanwhile the function microbial inoculum that is formed with biological enzyme formulation of complex microorganism bacterial classification and special culture media feed intake by a certain percentage To microbial augmentation device, it in reaction temperature is 35~37 DEG C, dissolved oxygen to control microbial augmentation device<0.2mg/L condition Under, hot housing is carried out to microorganism, microorganism is quickly bred;
(b) that high concentrated organic wastewater or mud are delivered into anaerobism by a certain percentage with the mixed liquor in microbial augmentation device is anti- Device is answered, and controls anaerobic reactor to carry out Anaerobic Treatment under 35~37 DEG C of middle constant temperature;Anaerobic reactor is often completed once to enter Material, the charging aperture of microbial augmentation device and anaerobic reactor is simultaneously closed off, stop charging, treat the mixture in anaerobic reactor After material completes Anaerobic Treatment, discharging, step a and b are then repeated, carries out the processing of next batch;
(c) constant-temperatureanaerobic anaerobic reaction unit has often handled biogas slurry discharging caused by a collection of mixed material to normal temperature anaerobic pond in, After continuing anaerobic reaction under normal temperature for a period of time, then it is delivered to the catalytic oxidation that multi-stage stepped aerobic device carries out continuous multi-stage Processing.
10. the integrated processing system of high concentrated organic wastewater according to claim 9 and solid waste, its feature exists In:In step a, the total amount of adding of the complex microorganism bacterial classification contains COD as 10 using high concentrated organic wastewater or mud4mg/L Meter, the dosage of the function microbial inoculum account for the percent by volume of high concentrated organic wastewater or mud inlet amount for 0.1%~ 0.2%, the volume ratio of the dosage of the function microbial inoculum and special culture media is 1:10~20;
The complex microorganism bacterial classification includes bacillus licheniformis, bacillus subtilis, bacillus lentus, Bdellovibrio, huge Bacillus, unwrapping wire aspergillus and lactobacillus acidophilus, the biological enzyme formulation include methane monooxygenase, ammona monooxygenase, halogen Hydrolase and alkyl monooxygenase, the bacillus licheniformis:Bacillus subtilis:Bacillus lentus:Bdellovibrio:Huge bud Spore bacillus:Unwrapping wire aspergillus:Lactobacillus acidophilus:Methane monooxygenase:Ammona monooxygenase:Halogen hydrolase:Alkyl monooxygenase Mass ratio is 1~2:1~2:3~4:1~2:2.5~4:1~2.5:1~2:1~2.5:2~3:2~3:2.5~4;
In step b, the volume ratio 1~2 of high concentrated organic wastewater or mud and the mixed liquor in microbial augmentation device:8~9; The moisture content of the mud is 92~95%.
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