CN107760102A - A kind of back up label - Google Patents
A kind of back up label Download PDFInfo
- Publication number
- CN107760102A CN107760102A CN201711069699.7A CN201711069699A CN107760102A CN 107760102 A CN107760102 A CN 107760102A CN 201711069699 A CN201711069699 A CN 201711069699A CN 107760102 A CN107760102 A CN 107760102A
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- China
- Prior art keywords
- added
- ink
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of back up label, it includes printing layer, the printing layer is formed by ink printing, the ink attachment fastness of the present invention is good, ink setting is good, layer of ink adhesion, ink transfer are good, stability is not easy well colour cast, surface tension is moderate after treatment for the ink of the present invention, moderate viscosity, bubble is less prone to, the quality of finished product label can be effectively improved as back up label, is not easy to decolourize.
Description
Technical field
The invention belongs to TAG field, and in particular to a kind of back up label.
Background technology
The extensive use of label and the continuous development of label kind have naturally promoted the hair of label print: technology
Exhibition.Label printing covers all mode of printings, the applicable cases of various countries such as flat, convex, recessed, net and is not quite similar.But near several
The development trend of year global label can be seen that flexible version printing, narrow rotary printing, digital printing turn into mark in American-European countries
Endorse the bright spot of refreshing, and the development trend of label printing；
Ink is the pith of label printing, and the performance of label printing-ink mainly includes form and aspect, fineness, saturation degree, gloss
Degree, adhesive force, viscosity, drying property etc., these performances all have a major impact to typography and printing quality；It is divided at present water-based
Ink and solvent-based ink, solvent-borne type label printing-ink is to the strong adaptability of label material, stable performance, printing quality compared with
It is high；But problem of environmental pollution be present, some volatile solvents are harmful, water-based ink safety and sanitation, pollution-free, meet ring
Guaranteed request, be advantageous to health；But there is also shortcoming, as slow drying speed, color saturation be not high, stability difference etc. is unsuitable
Print large area on the spot, be long placed in and precipitation, lamination easily occurs.
The content of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of back up label.
To achieve the above object, the present invention uses following technical scheme：
A kind of back up label, it includes printing layer, and the printing layer is formed by ink printing, and described ink is by following
The raw material composition of parts by weight：
Isocyanuric acid three-glycidyl ester 3-4,2,2- dihydromethyl propionic acid 5-7, the tert-butyl group are sub- to biphenol 0.1-0.2, vulcanization
Tin 0.08-0.1, ethoxylated alkyl ammonium sulfate 1-2, borax 3-5, polyvinyl alcohol 4-6, calcium aluminate 2-4, methyl methacrylate
10-12, acrylic acid 6-7, rosin 3-4, Permethrin 0.1-0.3, pigment 10-12, initiator 0.3-0.5；
Described initiator is cumyl peroxide；
The preparation method of described ink comprises the following steps：
（1）Take the tert-butyl group that biphenol is added in the absolute ethyl alcohol of 5-7 times of its weight, stirred, obtains alcoholic solution；
（2）Above-mentioned borax, ethoxylated alkyl ammonium sulfate mixing are taken, is added in 34-40 times of deionized water of compound weight, adds
Heat arrives 60-65 DEG C, adds polyvinyl alcohol, insulated and stirred 10-20 minutes, obtains borax dispersion liquid；
（3）Initiator is taken, is added in the isopropanol of 3-5 times of its weight, stirs, obtain initiator solution；
（4）Above-mentioned alcoholic solution, the mixing of borax aqueous dispersions are taken, stirs, isocyanuric acid three-glycidyl ester is added, in 80-
10-13 minutes are preheated at 85 DEG C, methyl methacrylate is added, is sent in reactor, are passed through nitrogen, adjust temperature of reaction kettle
For 60-65 DEG C, above-mentioned initiator solution is added dropwise, rear insulated and stirred 3-5 hours are added dropwise, discharges, adds calcium aluminate, ultrasound
10-20 minutes, ethanol is distilled off, obtains polymer solution；
（5）Rosin is taken, is heated and softened, is added in above-mentioned polymer solution, stirs, adds remaining each raw material, rise temperature
Spend for 55-60 DEG C, emulsify 20-30 minutes in 1000-1600 revs/min of down cut, produce the ink.
Advantages of the present invention：
The ink attachment fastness of the present invention is good, ink setting is good, layer of ink adhesion, ink transfer are good, stability is not easy well
Colour cast, ink of the invention is moderate after treatment by surface tension, moderate viscosity, bubble is less prone to, as back up mark
Label can effectively improve the quality of finished product label, be not easy to decolourize.
Embodiment
Embodiment 1
A kind of back up label, it includes printing layer, and the printing layer is formed by ink printing, and described ink is by following
The raw material composition of parts by weight：
Isocyanuric acid three-glycidyl ester 4,2,2- dihydromethyl propionic acids 7, the tert-butyl group are to biphenol 0.2, stannous sulfide 0.1, second
Epoxide alkylsurfuric acid ammonium 2, borax 5, polyvinyl alcohol 6, calcium aluminate 4, methyl methacrylate 12, acrylic acid 7, rosin 4, chlorine chrysanthemum
Ester 0.3, pigment 12, initiator 0.5；
Described initiator is cumyl peroxide；
The preparation method of described ink comprises the following steps：
（1）The tert-butyl group is taken to be added in the absolute ethyl alcohol of 7 times of its weight to biphenol, stir, obtain alcoholic solution；
（2）Above-mentioned borax, ethoxylated alkyl ammonium sulfate mixing are taken, is added in 40 times of deionized waters of compound weight, heats
To 65 DEG C, polyvinyl alcohol is added, insulated and stirred 20 minutes, obtains borax dispersion liquid；
（3）Initiator is taken, is added in the isopropanol of 5 times of its weight, is stirred, obtain initiator solution；
（4）Above-mentioned alcoholic solution, the mixing of borax aqueous dispersions are taken, stirs, isocyanuric acid three-glycidyl ester is added, at 85 DEG C
Lower preheating 13 minutes, adds methyl methacrylate, is sent in reactor, is passed through nitrogen, and regulation temperature of reaction kettle is 65 DEG C,
Above-mentioned initiator solution is added dropwise, rear insulated and stirred is added dropwise 5 hours, discharges, adds calcium aluminate, ultrasound 20 minutes, distillation removes
Ethanol is removed, obtains polymer solution；
（5）Rosin is taken, is heated and softened, is added in above-mentioned polymer solution, stirs, adds remaining each raw material, rise temperature
Spend for 60 DEG C, emulsified 30 minutes in 1600 revs/min of down cuts, produce the ink.
Embodiment 2
A kind of back up label, it includes printing layer, and the printing layer is formed by ink printing, and described ink is by following
The raw material composition of parts by weight：
Isocyanuric acid three-glycidyl ester 3,2,2- dihydromethyl propionic acids 5, the tert-butyl group are to biphenol 0.1, stannous sulfide 0.08-
0.1st, ethoxylated alkyl ammonium sulfate 1, borax 3, polyvinyl alcohol 4, calcium aluminate 2, methyl methacrylate 10, acrylic acid 6, rosin
3rd, Permethrin 0.1, pigment 10, initiator 0.3；
Described initiator is cumyl peroxide；
The preparation method of described ink comprises the following steps：
（1）The tert-butyl group is taken to be added in the absolute ethyl alcohol of 5 times of its weight to biphenol, stir, obtain alcoholic solution；
（2）Above-mentioned borax, ethoxylated alkyl ammonium sulfate mixing are taken, is added in 34 times of deionized waters of compound weight, heats
To 60 DEG C, polyvinyl alcohol is added, insulated and stirred 10 minutes, obtains borax dispersion liquid；
（3）Initiator is taken, is added in the isopropanol of 3 times of its weight, is stirred, obtain initiator solution；
（4）Above-mentioned alcoholic solution, the mixing of borax aqueous dispersions are taken, stirs, isocyanuric acid three-glycidyl ester is added, at 80 DEG C
Lower preheating 10 minutes, adds methyl methacrylate, is sent in reactor, is passed through nitrogen, and regulation temperature of reaction kettle is 60 DEG C,
Above-mentioned initiator solution is added dropwise, rear insulated and stirred is added dropwise 3 hours, discharges, adds calcium aluminate, ultrasound 10 minutes, distillation removes
Ethanol is removed, obtains polymer solution；
（5）Rosin is taken, is heated and softened, is added in above-mentioned polymer solution, stirs, adds remaining each raw material, rise temperature
Spend for 55 DEG C, emulsified 20 minutes in 1000 revs/min of down cuts, produce the ink.
Performance test：
The viscosity of ink of the present invention is 10-11.5mPas, surface tension 27-29mN/m.
Claims (1)
1. a kind of back up label, it is characterised in that it includes printing layer, and the printing layer is formed by ink printing, described
Ink be made up of the raw material of following weight parts：
Isocyanuric acid three-glycidyl ester 3-4,2,2- dihydromethyl propionic acid 5-7, the tert-butyl group are sub- to biphenol 0.1-0.2, vulcanization
Tin 0.08-0.1, ethoxylated alkyl ammonium sulfate 1-2, borax 3-5, polyvinyl alcohol 4-6, calcium aluminate 2-4, methyl methacrylate
10-12, acrylic acid 6-7, rosin 3-4, Permethrin 0.1-0.3, pigment 10-12, initiator 0.3-0.5；
Described initiator is cumyl peroxide；
The preparation method of described ink comprises the following steps：
（1）Take the tert-butyl group that biphenol is added in the absolute ethyl alcohol of 5-7 times of its weight, stirred, obtains alcoholic solution；
（2）Above-mentioned borax, ethoxylated alkyl ammonium sulfate mixing are taken, is added in 34-40 times of deionized water of compound weight, adds
Heat arrives 60-65 DEG C, adds polyvinyl alcohol, insulated and stirred 10-20 minutes, obtains borax dispersion liquid；
（3）Initiator is taken, is added in the isopropanol of 3-5 times of its weight, stirs, obtain initiator solution；
（4）Above-mentioned alcoholic solution, the mixing of borax aqueous dispersions are taken, stirs, isocyanuric acid three-glycidyl ester is added, in 80-
10-13 minutes are preheated at 85 DEG C, methyl methacrylate is added, is sent in reactor, are passed through nitrogen, adjust temperature of reaction kettle
For 60-65 DEG C, above-mentioned initiator solution is added dropwise, rear insulated and stirred 3-5 hours are added dropwise, discharges, adds calcium aluminate, ultrasound
10-20 minutes, ethanol is distilled off, obtains polymer solution；
（5）Rosin is taken, is heated and softened, is added in above-mentioned polymer solution, stirs, adds remaining each raw material, rise temperature
Spend for 55-60 DEG C, emulsify 20-30 minutes in 1000-1600 revs/min of down cut, produce the ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711069699.7A CN107760102A (en) | 2017-11-03 | 2017-11-03 | A kind of back up label |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711069699.7A CN107760102A (en) | 2017-11-03 | 2017-11-03 | A kind of back up label |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107760102A true CN107760102A (en) | 2018-03-06 |
Family
ID=61273162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711069699.7A Pending CN107760102A (en) | 2017-11-03 | 2017-11-03 | A kind of back up label |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107760102A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610744A (en) * | 2018-04-27 | 2018-10-02 | 佛山市智巢电子科技有限公司 | A kind of preparation method of spray printing polyester electric conduction film |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1142518A (en) * | 1995-04-26 | 1997-02-12 | 伊马治公司 | Water-based ink composition for marking carrier |
| CN102093516A (en) * | 2010-12-28 | 2011-06-15 | 东莞市英科水墨有限公司 | Waterborne polyurethane-acrylate emulsion prepared by seed emulsion polymerization method |
| CN102459412A (en) * | 2009-06-19 | 2012-05-16 | 爱克发印艺公司 | Polymeric dispersants and non-aqueous dispersions |
| CN104031202A (en) * | 2014-06-17 | 2014-09-10 | 中国科学院化学研究所 | Polyacrylic acid printing ink resin and preparation method thereof |
| CN104962130A (en) * | 2015-07-04 | 2015-10-07 | 佛山市南方包装有限公司 | Heat-resistant yellow-stain-resistant epoxy acrylate low polymer and preparation method of UV (ultraviolet) ink |
| CN105086594A (en) * | 2015-08-18 | 2015-11-25 | 常熟市汇丰印刷有限公司 | Electronic product label |
-
2017
- 2017-11-03 CN CN201711069699.7A patent/CN107760102A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1142518A (en) * | 1995-04-26 | 1997-02-12 | 伊马治公司 | Water-based ink composition for marking carrier |
| CN102459412A (en) * | 2009-06-19 | 2012-05-16 | 爱克发印艺公司 | Polymeric dispersants and non-aqueous dispersions |
| CN102093516A (en) * | 2010-12-28 | 2011-06-15 | 东莞市英科水墨有限公司 | Waterborne polyurethane-acrylate emulsion prepared by seed emulsion polymerization method |
| CN104031202A (en) * | 2014-06-17 | 2014-09-10 | 中国科学院化学研究所 | Polyacrylic acid printing ink resin and preparation method thereof |
| CN104962130A (en) * | 2015-07-04 | 2015-10-07 | 佛山市南方包装有限公司 | Heat-resistant yellow-stain-resistant epoxy acrylate low polymer and preparation method of UV (ultraviolet) ink |
| CN105086594A (en) * | 2015-08-18 | 2015-11-25 | 常熟市汇丰印刷有限公司 | Electronic product label |
Non-Patent Citations (1)
| Title |
|---|
| 黎阳晖等: "《标签印刷500问》", 31 January 2014, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610744A (en) * | 2018-04-27 | 2018-10-02 | 佛山市智巢电子科技有限公司 | A kind of preparation method of spray printing polyester electric conduction film |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180306 |
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| RJ01 | Rejection of invention patent application after publication |