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CN107620406A - A kind of preparation method of Light Wall - Google Patents

A kind of preparation method of Light Wall Download PDF

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Publication number
CN107620406A
CN107620406A CN201710755986.7A CN201710755986A CN107620406A CN 107620406 A CN107620406 A CN 107620406A CN 201710755986 A CN201710755986 A CN 201710755986A CN 107620406 A CN107620406 A CN 107620406A
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CN
China
Prior art keywords
biomass
preparation
mesh
sheet material
wall
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CN201710755986.7A
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Chinese (zh)
Inventor
生晓东
何雨飞
李学业
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Beijing Homoo Home Technology Development Co Ltd
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Beijing Homoo Home Technology Development Co Ltd
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Priority to CN201710755986.7A priority Critical patent/CN107620406A/en
Publication of CN107620406A publication Critical patent/CN107620406A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/90Passive houses; Double facade technology

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  • Finishing Walls (AREA)

Abstract

The invention discloses a kind of preparation method of Light Wall, including:Step 1: producing building structure main frame using I-steel or square steel, sprayed in its inner space or pour into a mould biomass-based polyurethane hard foam material, using biomass-based thermoplastic material as thin case frame;Step 2: auxiliary part is connected on building structure main frame, the inside and outside wallboard of bottom is connected on auxiliary part;Step 3: cast or sprayed biological matter based polyurethanes stiff foam material into the cavity of the inside and outside wallboard of bottom, form lower wall body;Step 4: the inside and outside wallboard in installation middle part, cast or sprayed biological matter based polyurethanes stiff foam material into its cavity, form wall segment;Step 5: the method according to step three and four successively forms each several part wall, until forming integral light wall.The Product environment close friend of the present invention, simple and quick construction, improve that house whole service life, energy-saving heat preserving, sound insulation value are excellent, bulk strength is high, wall integral light.

Description

A kind of preparation method of Light Wall
Technical field
The present invention is applied in architectural decoration, is related to a kind of preparation method of Light Wall.
Background technology
Material mine exploitation brings more than 70% barren rock material, handles these barren rock material or land occupation is stacked or filled out Bury, damaged substantial amounts of valuable soil, rock material resource is become environmentally hazardous one big public hazards.Barren rock material is selected removes for these A part of handicraft, colored stone sand grains are produced, the marble wastes of high whiteness are produced beyond some light powdered whitings, other equal nothings Effectively there is the method for economic value to utilize it.It is unbroken it is tens of in each mining area be seen everywhere colors stone riprap clinker Cheng Shan Cheng Ling, fills up gully, and ruinate environment also easily forms mud-rock flow.
With the development of modern industry and the surge of world population, energy crisis, crisis in food, environmental crisis day are increasingly It is acute.World economy is too dependent on the fossil resources such as oil, coal, and its is non-renewable just to cause such resource gradually withered Exhaust, and price is climbing up and up, and such resource of burning produces gas and the suspended particulates such as substantial amounts of carbon dioxide, sulfur dioxide Thing has resulted in the worsening of climatic environment.Find reproducible clean energy resource and substitute them as the concern of scientific research department of various countries Focus.Wherein biomass energy is because excellent with wide material sources, cheap, strong, the carbon dioxide reusable edible of recyclability etc. Point, turn into most potential energy substance.Ethanol has been attached great importance as regenerative resource, at present, the life of alcohol fuel Production is mainly using grains such as sugarcane, cereal as raw material, but population expansion, food shortage determine this raw material production alcohol fuel Limitation.Cellulosic ethanol is derived from the important energy source of renewable biomass.Lignocellulosic be it is most abundant on the earth can be again Production-goods source, every year by about 1,000,000,000,000 tons of plant cellulose caused by photosynthesis, to avoid striving grain with people, ground, wood being striven with grain Matter cellulose is as the most potential raw material of the production of cellulosic ethanol.From the point of view of at this stage, most area is made by stalk For fuel, or directly burned in field, not only pollute environment, and because the utilization rate of straw burning energy is low, Cause the serious waste of resource.Making raw material cellulose ethanol using agricultural wastes has without soda acid steam explosion, enzyme hydrolysis work Skill mild condition, equipment are simple, energy consumption is low, it is environment-friendly the features such as.Not only can the substantial amounts of conversion of biomass energy, alleviate energy Source crisis, but also atmosphere pollution can be alleviated, improve the ecological environment, promote agricultural sustainable development, drive agriculture industrialization And benign ecological cycles.Last remaining slag charge is lignin, can be in many because lignin is natural high molecular substance Field replaces petroleum chemicals productive target organic products.
Artificial stone typically refers to artificial solid material, artificial stone quartz, artificial stone hilllock stone etc..Artificial stone type is not Together, its composition is also not quite similar.Composition is mainly resin, aluminium powder, pigment and curing agent.Artificial stone is that " high polymer material polymerize Body ", typically using unsaturated-resin and aluminium hydroxide inserts as main material, the technological forming such as agitated, cast, heating, polymerization " macromolecule solid slab ", commonly referred to as:" resin plate artificial stone ".
Resin type artificial stone be using unsaturated polyester resin as cementing agent, with aluminium hydrate powder, natural marble rubble, Quartz sand, calcite, stone flour or other inorganic fillers coordinate according to a certain percentage, and it is outer to add catalyst, curing agent, pigment etc. The process such as agent, blended stirring, curing molding, demoulding drying, surface polishing is added to be process.
Shortcoming one:Resin type artificial stone is using unsaturated polyester resin as cementing agent, because unsaturated polyester resin is Liquid, other inorganic fillers are solid powder, are not easy to be well mixed during mixing, during mixing easy heat production cause resin solid in advance Change, cause finished product sheet material material uneven, easily cracking, buckling deformation.
Shortcoming two:Resin type artificial stone is that resin demand is too big using unsaturated polyester resin as cementing agent, causes finished product Board cost is higher, non-refractory and belongs to combustible material.
The content of the invention
It is an object of the invention to solve at least the above or defect, and provide the advantages of at least will be described later.
It is a still further object of the present invention to provide a kind of preparation method of Light Wall.
Therefore, technical scheme provided by the invention is:
A kind of preparation method of Light Wall, including:
Step 1: according to building construction design, first, the main frame of building structure is produced using I-steel or square steel material Frame, meanwhile, in the I-steel or the spraying of square steel inner space or biomass-based polyurethane hard foam material is poured into a mould, afterwards using life Material base thermoplastic material is as thin case frame;
Step 2: the auxiliary part for connecting inside and outside wallboard is connected on building structure main frame first, afterwards the bottom of by The inside and outside wallboard of layer is connected on the auxiliary part;
Step 3: the biomass-based polyurethane hard foam is poured into a mould or sprayed into the cavity of the inside and outside wallboard of the bottom Material, its wallboard inside and outside with the bottom and building structure main frame herein and auxiliary part is set to form closely knit lower walls Body;
Step 4: after forming the lower wall body, the inside and outside wallboard in middle part is installed, afterwards also to the middle part inner, external wall Pour into a mould in the cavity of plate or spray the biomass-based polyurethane hard foam material, make it inside and outside with the lower wall body, middle part Wallboard, building structure main frame and auxiliary part form closely knit wall segment herein;
Step 5: each several part wall is successively formed according to the method for step 3 and step 4, until it is complete close to form one Real Light Wall.
Preferably, in the preparation method of described Light Wall, the preparation method of the inside and outside wallboard includes following step Suddenly:
2.1) in terms of mass fraction, 10~20 parts of 50~80 parts of waste material of stone, cement, the sand 0~20 of 40~200 mesh are taken 6~8 parts of part, 0~20 part of the mica powder of 40~200 mesh and resin-oatmeal mixing;
2.2) by mixed raw material in 2.1), 3~10min of voltage stabilizing carries out precompressed processing under normal temperature, pressure 20MPa;
2.3) by the voltage stabilizing 30 at 140~160 DEG C of temperature and pressure 25MPa~30MPa of the raw material after precompressed is handled ~120min carries out hot-press solidifying processing, obtains workblank sheet material;
2.4) workblank sheet material is processed as finished product sheet material, as the inside and outside wallboard.
Preferably, in the preparation method of described Light Wall, the preparation method bag of the biomass-based thermoplastic material Include following steps:
Lignin is mixed with polyvinyl chloride resin and the first auxiliary agent first, is then fed into twin-screw thermoplastic extruder, described Corresponding mould is loaded onto in twin (double) screw extruder output section, produces the biomass-based thermoplastic material of different size, wherein, with matter Part meter is measured, lignin is 75~90 parts, polyvinyl chloride resin is 10~25 parts and 3~5 parts of the first auxiliary agent.
Preferably, in the preparation method of described Light Wall, the system of the biomass-based polyurethane hard foam material Preparation Method comprises the following steps:
1.1) raw material mixes:In terms of mass fraction, 400 40~50 parts of taking polyethylene glycol, 20~25 parts of glycerine is wooden 25~40 parts of element, 0.5~1 part of the concentrated sulfuric acid, is placed in reactor;
1.2) High-temperature Liquefaction:Mixed material is warming up to 140~160 DEG C, and at this temperature normal pressure liquefaction 60~ 90min;
1.3) dehydration is neutralized:The hydroxide with the concentrated sulfuric acid chemistry equivalent reacting dose is added first into the reactor Sodium, vacuum dehydration to condensation produces under vacuum 0.09MPa afterwards;
1.4) cool:Normal temperature is cooled to, obtains biological polyol finished product;
1.5) biological polyol finished product is combined:The second auxiliary agent is added in refined biometric polyalcohol, forms combination biological multielement Alcohol finished product;
1.6) biomass-based polyurethane hard foam material:By combination biological polyol and the isocyanates by volume 1: 0.9~1.2 mixing, that is, obtain the biomass-based polyurethane hard foam material.
Preferably, in the preparation method of described Light Wall, the waste material of stone be color aggregate in one kind or A variety of, the cement is Portland cement P.O 32.5 or white portland cement P.W 32.5, and the sand is dry matter Thin river sand, the mica powder are the one or more of assorted colored mica powder, and the resin-oatmeal is thermosetting phenol-formaldehyde resin powder end.
Preferably, in the preparation method of described Light Wall, in step 2.2), mixed raw material is placed in first In board mould, the precompressed processing is carried out again afterwards;
In step 2.3), after the hot-press solidifying processing, water cooled system is cooled to 60~80 DEG C, then through air cooling system Normal temperature is cooled to, obtains the workblank sheet material.
Preferably, in the preparation method of described Light Wall, in step 2.4), by workblank sheet material be processed as it is described into Product sheet material specifically comprises the following steps:
It is first that workblank sheet material is stable by the curing of 7~10 days, the workblank sheet material after shaping is placed in cutting system afterwards Four side surface trimmings are carried out in system, then carries out determining thick sanding, is finally polished, obtains the finished product sheet material;
Wherein, when carrying out four side surface trimmings, 4~5mm is cut off per side;
When carrying out the fixed thick sanding, the three-level abrasive band mesh number of sanding system is respectively that 60 mesh, 80 mesh and 120 mesh, sand remove The ply of paper of the workblank sheet material upper and lower surface;
When carrying out the polishing, the three-level abrasive band mesh number of polishing system is respectively 240 mesh, 320 mesh and 600 mesh.
Preferably, in the preparation method of described Light Wall, in the preparation method of the biomass-based thermoplastic material, The lignin requires moisture≤5%, and mesh number, more than 400 mesh, the temperature in front and rear each area of the twin (double) screw extruder is 130~180 DEG C.
Preferably, in the preparation method of described Light Wall, second auxiliary agent includes fire retardant, foam stabilizer and hair Infusion;
In step 1.6), biological polyol and isocyanates are combined by described by spraying or casting type polyurethane foaming machine By volume 1:0.9~1.2 mixing.
Preferably, in the preparation method of described Light Wall, in the preparation method of the biomass-based thermoplastic material, After lignin is mixed with polyvinyl chloride resin and the first auxiliary agent, the ultrasonic 3min first under 300~400W of ultrasonic power, after micro- 2~5min of microwave treatment under 500~800W of wave power, is then re-fed into the twin (double) screw extruder.
The present invention comprises at least following beneficial effect:
The wall prepared according to the present invention has the advantage that respectively:
1), wall integral light.Because the volume of whole wall more than 80% is biomass-based polyurethane hard foam material Fill, the density of biomass-based polyurethane hard foam material is in 30~60kg/m3, and the wall of conventional wooden or inorganic stone material base Volume density is all significantly larger than this novel wall.
2), bulk strength is high.Because wallboard sheet material has higher intensity and hardness, it is connected to by certain auxiliary part Inside and outside wallboard is used as on the wall body structure main frame in the house made by materials such as I-steel, square steel, thin case frame uses extrusion Including type Wood-plastic profiles, in the cavity of Side fascia, then including, spraying or pour into a mould biomass-based polyurethane hard foam among Side fascia Material, general frame and inside and outside wallboard is set to be bonded into a closely knit entirety, whole wall is provided with high intensity.
3), energy-saving heat preserving, sound insulation value are excellent.It is all naked at its because the component of main frame is I-steel, square steel material The surface of dew all coats biomass-based polyurethane hard foam material, and thin lattice piece is Wood-plastic material, and Wood-plastic profiles compare steel Also there is relatively low thermal conductivity factor, wrapped up by biomass-based polyurethane hard foam material and improve part insulation, sound-proofing Energy.Furthermore the volume of whole wall more than 80% is that biomass-based polyurethane hard foam material is filled, the maximum property of this material Can advantage thermal conductivity factor is low, energy-saving heat preserving, sound insulation.
4) house whole service life, is improved.Due to material outer surfaces such as metals used in whole house wall All sprayed biological matter based polyurethanes stiff foam materials, contact of these metallic materials with air, moisture is blocked, has been served anti- Rotten effect, substantially increase the service life in whole house.
5), simple and quick construction.Because this wall is to be used as house frame structure using the I-steel of welding, square steel etc. On the basis of be attached installation, and the sheet material used in inside and outside wallboard can carry out cutting for arbitrary dimension, furthermore spray, pour Noting biomass-based polyurethane hard foam material 3~40 seconds can curing molding.The above advantage can greatly improve entirely The construction cycle in house.
6), environmental friendly product.Because this wall has used substantial amounts of waste material of stone and lignin, instead of increasingly exhausted The resource such as petrochemical industry, be work, agricultural wastes belong to the maximum high-quality utilization of recycling, be to meet national industrial policies guidance quality The model utilized.
Further advantage, target and the feature of the present invention embodies part by following explanation, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Brief description of the drawings
Fig. 1 is a kind of process chart of the preparation method of Light Wall of the present invention;
Fig. 2 is the process chart of the preparation method of inside and outside wallboard of the present invention;
Fig. 3 is the process chart of biomass-based thermoplastic material of the present invention;
Fig. 4 is the process chart of biomass-based polyurethane hard foam material of the present invention.
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings, to make those skilled in the art with reference to specification text Word can be implemented according to this.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein do not allot one or more The presence or addition of individual other elements or its combination.
As shown in Figures 1 to 4, the present invention provides a kind of preparation method of Light Wall, including:
Step 1: according to building construction design, first, the main frame of building structure is produced using I-steel or square steel material Frame, meanwhile, in the I-steel or the spraying of square steel inner space or biomass-based polyurethane hard foam material is poured into a mould, afterwards using life Material base thermoplastic material is as thin case frame;
Step 2: the auxiliary part for connecting inside and outside wallboard is connected on building structure main frame first, afterwards the bottom of by The inside and outside wallboard of layer is connected on the auxiliary part;
Step 3: the biomass-based polyurethane hard foam is poured into a mould or sprayed into the cavity of the inside and outside wallboard of the bottom Material, its wallboard inside and outside with the bottom and building structure main frame herein and auxiliary part is set to form closely knit lower walls Body;
Step 4: after forming the lower wall body, the inside and outside wallboard in middle part is installed, afterwards also to the middle part inner, external wall Pour into a mould in the cavity of plate or spray the biomass-based polyurethane hard foam material, make it inside and outside with the lower wall body, middle part Wallboard, building structure main frame and auxiliary part form closely knit wall segment herein;
Step 5: each several part wall is successively formed according to the method for step 3 and step 4, until it is complete close to form one Real Light Wall.
In such scheme, preferably, in the preparation method of the Light Wall, the preparation method of the inside and outside wallboard Comprise the following steps:
2.1) in terms of mass fraction, 10~20 parts of 50~80 parts of waste material of stone, cement, the sand 0~20 of 40~200 mesh are taken 6~8 parts of part, 0~20 part of the mica powder of 40~200 mesh and resin-oatmeal mixing;
2.2) by mixed raw material in 2.1), 3~10min of voltage stabilizing carries out precompressed processing under normal temperature, pressure 20MPa;
2.3) by the voltage stabilizing 30 at 140~160 DEG C of temperature and pressure 25MPa~30MPa of the raw material after precompressed is handled ~120min carries out hot-press solidifying processing, obtains workblank sheet material;
2.4) workblank sheet material is processed as finished product sheet material, as the inside and outside wallboard.
In such scheme, preferably, in the preparation method of the Light Wall, the system of the biomass-based thermoplastic material Preparation Method comprises the following steps:
Lignin is mixed with polyvinyl chloride resin and the first auxiliary agent first, is then fed into twin-screw thermoplastic extruder, described Corresponding mould is loaded onto in twin (double) screw extruder output section, produces the biomass-based thermoplastic material of different size, wherein, with matter Part meter is measured, lignin is 75~90 parts, polyvinyl chloride resin is 10~25 parts, 3~5 parts of the first auxiliary agent.
In such scheme, preferably, in the preparation method of the Light Wall, the biomass-based polyurethane hard foam The preparation method of material comprises the following steps:
1.1) raw material mixes:In terms of mass fraction, 400 40~50 parts of taking polyethylene glycol, 20~25 parts of glycerine is wooden 25~40 parts of element, 0.5~1 part of the concentrated sulfuric acid, is placed in reactor;
1.2) High-temperature Liquefaction:Mixed material is warming up to 140~160 DEG C, and at this temperature normal pressure liquefaction 60~ 90min;
1.3) dehydration is neutralized:The hydroxide with the concentrated sulfuric acid chemistry equivalent reacting dose is added first into the reactor Sodium, vacuum dehydration to condensation produces under vacuum 0.09MPa afterwards;
1.4) cool:Normal temperature is cooled to, obtains biological polyol finished product;
1.5) biological polyol finished product is combined:The second auxiliary agent is added in refined biometric polyalcohol, forms combination biological multielement Alcohol finished product;
1.6) biomass-based polyurethane hard foam material:By combination biological polyol and the isocyanates by volume 1: 0.9~1.2 mixing, that is, obtain the biomass-based polyurethane hard foam material.
In such scheme, preferably, in the preparation method of the Light Wall, the waste material of stone is in color aggregate One or more, the cement is Portland cement P.O 32.5 or white portland cement P.W 32.5, the sand Son is the thin river sand of dry matter, and the mica powder is the one or more of assorted colored mica powder, and the resin-oatmeal is thermosetting phenolic Toner.
In such scheme, preferably, in the preparation method of the Light Wall, in step 2.2), after mixing first Raw material be placed in board mould, carry out the precompressed processing again afterwards;
In step 2.3), after the hot-press solidifying processing, water cooled system is cooled to 60~80 DEG C, then through air cooling system Normal temperature is cooled to, obtains the workblank sheet material.
In such scheme, preferably, in the preparation method of the Light Wall, in step 2.4), by workblank sheet material plus Work is that the finished product sheet material specifically comprises the following steps:
It is first that workblank sheet material is stable by the curing of 7~10 days, the workblank sheet material after shaping is placed in cutting system afterwards Four side surface trimmings are carried out in system, then carries out determining thick sanding, is finally polished, obtains the finished product sheet material;
Wherein, when carrying out four side surface trimmings, 4~5mm is cut off per side;
When carrying out the fixed thick sanding, the three-level abrasive band mesh number of sanding system is respectively 60 mesh, 80 mesh, 120 mesh, and sand removes institute State the ply of paper of workblank sheet material upper and lower surface;
When carrying out the polishing, the three-level abrasive band mesh number of polishing system is respectively 240 mesh, 320 mesh, 600 mesh.
In such scheme, preferably, in the preparation method of the Light Wall, the system of the biomass-based thermoplastic material In Preparation Method, the lignin requires moisture≤5%, and mesh number is more than 400 mesh, front and rear each area of the twin (double) screw extruder Temperature be 130~180 DEG C.
In such scheme, preferably, in the preparation method of the Light Wall, second auxiliary agent include fire retardant, Foam stabilizer and foaming agent;
In step 1.6), biological polyol and isocyanates are combined by described by spraying or casting type polyurethane foaming machine By volume 1:0.9~1.2 mixing.
In such scheme, preferably, in the preparation method of the Light Wall, the system of the biomass-based thermoplastic material In Preparation Method, after lignin is mixed with polyvinyl chloride resin and the first auxiliary agent, the ultrasonic 3min first under 300~400W of ultrasonic power, After 2~5min of microwave treatment under 500~800W of microwave power, be then re-fed into the twin (double) screw extruder.By super Sonication, rapidly raw material can be caused to obtain the fusion on molecular level, so that the toughness of obtained material, intensity are more It is good, then by microwave treatment, while storeroom fusion is further promoted, preheating also is provided for material, makes itself and double spiral shells Machine-shaping is more easily implemented in bar extruder.
The invention provides a kind of preparation method of Light Wall, comprise the following steps:
1), by the inorganic mineral materials such as waste material of stone of the regulatory specifications through accurately measuring, cement, sand, mica powder with Thermosetting phenol-formaldehyde resin powder mixes, and is uniformly mated formation into proprietary mould by special cloth system, by precompressed, then passes through machinery System is placed the mould into the multi-daylight press for having reached set point of temperature, and the height of certain time is passed through in heating press system Curing molding under temperature, condition of high voltage.Mould is taken out by mechanical system again, defined temperature is cooled into cooling system, Mold a kind of obtained sheet material.This sheet material cuts by deburring, determines thick sanding again, polishing finally obtains different size, difference is used The sheet material on way.
This sheet material is a kind of Novel environment-friendlymaterial material, is mainly used in architectural decoration.Density range 1500~ 2600kg/m3, length range≤3600mm, width range≤2000mm, thickness range 4mm~150mm.Compared to stainless steel, pottery The traditional construction materials such as porcelain, cement plate, wooden boards, this sheet material is non-toxic, "dead", flame retardancy A2 levels, non-viscous oil, it is not permeable it is dirty, Antibacterial and mouldproof, wear-resisting, impact resistance, easily maintenance, seamless spliced, moulding is changeable.This sheet material various colors, color is homogeneous, material is close It is real uniform, there is very high natural texture and intensity, hardness, there is good secondary workability.Not aqueous, the extremely low suction of this sheet material Water rate, do not shunk in high temperature, high humidity environment, not buckling deformation.This sheet material is not only vdiverse in function, and application is also wider It is general.
2), biomass material is digested, separation of fermenting, obtains slag charge, the slag charge main component is lignin;Will After the slag charge drying and crushing, lignin particles raw material is obtained;By the lignin particles raw material and polyethylene glycol 400, third Triol is liquefied as biological polyol under conditions of the micro concentrated sulfuric acid makees catalyst, and this biological polyol is mixed with related auxiliaries Biological polyol is closed in groups, recycles this combination biological polyol and isocyanates by volume 1:0.9~1.2 hybrid reaction is given birth to Into biomass-based polyurethane hard foam material.
3), biomass material is digested, separation of fermenting, obtains slag charge, the slag charge main component is lignin;Will After slag charge drying and crushing, lignin particles raw material is obtained;Lignin particles raw material, polyvinyl chloride resin, auxiliary agent etc. are mixed into double Screw extruder carries out thermoplastic extrusion, obtains a kind of biomass-based thermoplastic material.
4), according to building construction design, the wall body structure main frame in house, thin lattice are made with materials such as I-steel, square steel Framework uses extrusion type Wood-plastic profiles, by certain auxiliary part be connected above-mentioned identical or different sheet material respectively as Inside and outside wallboard, by respectively inside the square steel of main frame and the surface spraying of surface and I-steel or cast it is biomass-based Sprayed in polyurethane hard foam material, above-mentioned inside and outside wallboard space, pour into a mould biomass-based polyurethane hard foam material as wall A kind of novel light wall body that solid material combines.
To make those skilled in the art more fully understand the present invention, examples below is now provided:
Embodiment 1
One), sheet material technique specific steps and parameter declaration:
1), raw material
In terms of mass fraction, waste material of stone from it is featured, crush 40 mesh color aggregate one or more, 50 Part;
32.5,10 parts of cement selection Portland cement P.O;
Mica powder from 40 mesh assorted colored mica powder one or more, 20 parts;
Resin-oatmeal is last from thermosetting phenol-formaldehyde resin powder, 6 parts.
2), mould
Required according to the sheet material of different size, make the 65Mn Carbon Steel Dies with cover of different size, all surface of mould by oneself Handled through sanding and polishing.In the wheat cangue paper or ox-hide of the appropriate specification in die bottom plate (12mm thickness 65Mn carbon steels) one layer of upper berth before cloth Paper, loading onto four detachable mould frames, (mould frame is 15*15mm 65Mn carbon steel square steel, according to the plate of different size Material thickness assembles the 15*15mm65Mn carbon steels square steel of the appropriate number of plies) on die bottom plate, it will be measured by special cloth system Mixed material afterwards is uniformly mated formation into mould, in the wheat cangue paper or brown paper of the one layer of appropriate specification in the material bed upper berth struck off, then (18mm thickness 65Mn carbon steels, suitable number of die cover plate, cover plate are assembled according to the sheet metal thickness of different size plus die cover plate Length and width size it is more each small 6mm than the length and width in effective interior space of band edge frame bottom plate).
3), precompressed
Pressure 20MPa under normal temperature, voltage stabilizing 3min.
4), hot-press solidifying
Temperature:140℃;
Pressure:25MPa;Voltage stabling control:120min.
5), cool down, mold, curing
After mould takes out from hot-pressing system, water cooled system is cooled to 60 DEG C, then is cooled to normal temperature through air cooling system, beats Covered on mold, remove bottom plate frame, take out the workblank sheet material after shaping, this workblank sheet material is stable by the curing of 7 days, you can Carry out following process.
6), deburring is cut
Workblank sheet material after shaping enters diced system and carries out four side surface trimmings, the excision 4mm per side.
7), fixed thick sanding
Workblank sheet material after deburring cutting carries out determining thick sanding into sanding system.The three-level abrasive band mesh number of sanding system point Not Wei 60 mesh, 80 mesh, 120 mesh, sand remove the upper and lower surface of sheet material ply of paper, sheet material is reached defined thickness.
8), polish
Sheet material after fixed thick sanding carries out regulation into polishing system and requires surface polishing, the three-level abrasive band mesh of polishing system Number is respectively 240 mesh, 320 mesh, 600 mesh, and the sheet material after polishing has higher flatness and finish.
9), finished product sheet material
1500~2600kg/m of this finished product sheet material density range3, length range≤3600mm, width range≤2000mm, Thickness range 4mm~150mm.The finished product sheet material of dimension can also be cut into again by different size requirement.
Two), biomass-based thermoplastic material technique specific steps and parameter declaration:
1), lignin, polyvinyl chloride resin, auxiliary agent mixing
Enter high temperature double-screw rod thermoplastic extruder after the lignin crushed after drying is mixed with polyvinyl chloride resin, the first auxiliary agent, By different moulds, the thermoplastic section bar of different size is produced.
Lignin requires moisture≤5%, and mesh number is more than 400 mesh, in terms of mass fraction, 75 parts of lignin, and polyvinyl chloride resin 10 Part, 3 parts of the first auxiliary agent.
2), high-temperature thermoplastic
The temperature in each area is at 130 DEG C~180 DEG C before and after twin (double) screw extruder, and between front and rear each area of twin (double) screw extruder Temperature difference be present.
3), finished product thermoplastic material
According to different target thermoplastic material requirements, corresponding mould is loaded onto in twin (double) screw extruder output section, you can Obtain the thermoplastic material of regulation requirement.
Three), biomass-based polyurethane hard foam material technology specific steps and parameter declaration:
1), raw material mixes
The polyethylene glycol 400 of formula ratio, glycerine, lignin, the concentrated sulfuric acid are added in reactor, wherein with mass fraction Meter, 40 parts of polyethylene glycol 400,20 parts of glycerine, 25 parts of lignin, 0.5 part of the concentrated sulfuric acid.
2), High-temperature Liquefaction
Mixed material is warming up to 140 DEG C, and normal pressure liquefaction 90min at this temperature.
3) dehydration, is neutralized
Material in the sodium hydrate particle and reactor of chemical equivalent reacting dose is added by the concentrated sulfuric acid amount in formula to neutralize After reaction, vacuum dehydration to condensation produces under vacuum 0.09MPa.
4), cool
Material is cooled to by the cooling system of reactor by normal temperature, that is, obtains biological polyol finished product.
5) biological polyol finished product, is combined
Added in refined biometric polyalcohol a certain amount of fire retardant, foam stabilizer, foaming agent it is well mixed combination biology Polyalcohol finished product.
6), biomass-based polyurethane hard foam material
When needing to use, body is pressed with isocyanates by biological polyol is combined by spraying or casting type polyurethane foaming machine Product ratio 1:0.9 mixing obtains biomass-based polyurethane hard foam material.
Four), Light Wall technique specific steps and parameter declaration:
1), building structure framework and inside and outside wallboard connection auxiliary part
Building structure framework is gone out by welding production using I-steel or square steel according to house desigh drawing.And pass through screw The auxiliary part needed for inside and outside wall board is connected on building structure framework.
2), framework surface spraying, the biomass-based polyurethane hard foam material of cast
During house frame structure is welded, in square steel inner space and I-steel surface spraying or cast biomass Based polyurethanes stiff foam material.
3), the installation of inside and outside wallboard
First the inside and outside wallboard of bottom is arranged on the auxiliary part on building structure framework.
4), spray, pour into a mould biomass-based polyurethane hard foam material
Biological polyol and isocyanates by volume 1 will be combined using spraying or casting type polyurethane foaming machine:0.9 is mixed It is to obtain biomass-based polyurethane hard foam material to be filled in the cavity of inside and outside wallboard to close, and is allowed to and inside and outside wallboard and this model House frame and connecting elements in enclosing form a closely knit entirety, i.e. lower wall body.
5), whole wall
After lower floor's wall is formed, then the inside and outside wallboard in middle part is installed, then recycles spraying or casting type polyurethane foaming Machine will combine biological polyol and isocyanates by volume 1:0.9 mixing obtains biomass-based polyurethane hard foam material and filled out Fill in the cavity of inside and outside wallboard, be allowed to lower wall body, the inside and outside wallboard in middle part, in the range of house frame, auxiliary connection structure Part etc. forms a closely knit entirety, i.e. wall segment.Then inside and outside wallboard is successively installed in such a way again, spray or pour Biomass-based polyurethane hard foam material is noted, until forming a complete closely knit Light Wall.
Embodiment 2
One), sheet material technique specific steps and parameter declaration:
1), raw material
In terms of mass fraction, waste material of stone from it is featured, crush 200 mesh color aggregate one or more, 80 Part;
32.5,20 parts of cement selection white portland cement P.W;
The thin river sand of dry matter after sand selection washing, 20 parts;
Resin-oatmeal is last from thermosetting phenol-formaldehyde resin powder, 8 parts.
2), mould
Required according to the sheet material of different size, make the 65Mn Carbon Steel Dies with cover of different size, all surface of mould by oneself Handled through sanding and polishing.In the wheat cangue paper or ox-hide of the appropriate specification in die bottom plate (12mm thickness 65Mn carbon steels) one layer of upper berth before cloth Paper, loading onto four detachable mould frames, (mould frame is 15*15mm 65Mn carbon steel square steel, according to the plate of different size Material thickness assembles the 15*15mm65Mn carbon steels square steel of the appropriate number of plies) on die bottom plate, it will be measured by special cloth system Mixed material afterwards is uniformly mated formation into mould, in the wheat cangue paper or brown paper of the one layer of appropriate specification in the material bed upper berth struck off, then (18mm thickness 65Mn carbon steels, suitable number of die cover plate, cover plate are assembled according to the sheet metal thickness of different size plus die cover plate Length and width size it is more each small 6mm than the length and width in effective interior space of band edge frame bottom plate).
3), precompressed
Pressure 20MPa under normal temperature, voltage stabilizing 10min.
4), hot-press solidifying
Temperature:160℃;
Pressure:30MPa;Voltage stabling control:60min.
5), cool down, mold, curing
After mould takes out from hot-pressing system, water cooled system is cooled to 80 DEG C, then is cooled to normal temperature through air cooling system, beats Covered on mold, remove bottom plate frame, take out the workblank sheet material after shaping, this workblank sheet material is stable by the curing of 10 days, i.e., Following process can be carried out.
6), deburring is cut
Workblank sheet material after shaping enters diced system and carries out four side surface trimmings, the excision 5mm per side.
7), fixed thick sanding
Workblank sheet material after deburring cutting carries out determining thick sanding into sanding system.The three-level abrasive band mesh number of sanding system point Not Wei 60 mesh, 80 mesh, 120 mesh, sand remove the upper and lower surface of sheet material ply of paper, sheet material is reached defined thickness.
8), polish
Sheet material after fixed thick sanding carries out regulation into polishing system and requires surface polishing, the three-level abrasive band mesh of polishing system Number is respectively 240 mesh, 320 mesh, 600 mesh, and the sheet material after polishing has higher flatness and finish.
9), finished product sheet material
1500~2600kg/m of this finished product sheet material density range3, length range≤3600mm, width range≤2000mm, Thickness range 4mm~150mm.The finished product sheet material of dimension can also be cut into again by different size requirement.
Two), biomass-based thermoplastic material technique specific steps and parameter declaration:
1), lignin, polyvinyl chloride resin, the mixing of the first auxiliary agent
Enter high temperature double-screw rod thermoplastic extruder after the lignin crushed after drying is mixed with polyvinyl chloride resin, the first auxiliary agent, By different moulds, the thermoplastic section bar of different size is produced.
Lignin requires moisture≤5%, and mesh number is more than 400 mesh, in terms of mass fraction, 90 parts of lignin, and polyvinyl chloride resin 25 Part, 5 parts of the first auxiliary agent.
2), high-temperature thermoplastic
The temperature in each area is at 140 DEG C~170 DEG C before and after twin (double) screw extruder, and between front and rear each area of twin (double) screw extruder Temperature difference be present.
3), finished product thermoplastic material
According to different target thermoplastic material requirements, corresponding mould is loaded onto in twin (double) screw extruder output section, you can Obtain the thermoplastic material of regulation requirement.
Three), biomass-based polyurethane hard foam material technology specific steps and parameter declaration:
1), raw material mixes
The polyethylene glycol 400 of formula ratio, glycerine, lignin, the concentrated sulfuric acid are added in reactor, wherein with mass fraction Meter, 50 parts of polyethylene glycol 400,25 parts of glycerine, 40 parts of lignin, 1 part of the concentrated sulfuric acid.
2), High-temperature Liquefaction
Mixed material is warming up to 160 DEG C, and normal pressure liquefaction 60min at this temperature.
3) dehydration, is neutralized
Material in the sodium hydrate particle and reactor of chemical equivalent reacting dose is added by the concentrated sulfuric acid amount in formula to neutralize After reaction, vacuum dehydration to condensation produces under vacuum 0.09MPa.
4), cool
Material is cooled to by the cooling system of reactor by normal temperature, that is, obtains biological polyol finished product.
5) biological polyol finished product, is combined
Added in refined biometric polyalcohol a certain amount of fire retardant, foam stabilizer, foaming agent it is well mixed combination biology Polyalcohol finished product.
6), biomass-based polyurethane hard foam material
When needing to use, biological polyol will be combined by spraying or casting type polyurethane foaming machine and press 1 with isocyanates: 1.0 ratio mixed at high speed obtain biomass-based polyurethane hard foam material.
Four), Light Wall technique specific steps and parameter declaration:
1), building structure framework and inside and outside wallboard connection auxiliary part
Building structure framework is gone out by welding production using I-steel or square steel according to house desigh drawing.And pass through screw The auxiliary part needed for inside and outside wallboard is connected on building structure framework.
2), framework surface spraying, the biomass-based polyurethane hard foam material of cast
During house frame structure is welded, in square steel inner space and I-steel surface spraying or cast biomass Based polyurethanes stiff foam material.
3), the installation of inside and outside wallboard
First the inside and outside wallboard of bottom is arranged on the auxiliary part on building structure framework.
4), spray, pour into a mould biomass-based polyurethane hard foam material
Biological polyol and isocyanates by volume 1 will be combined using spraying or casting type polyurethane foaming machine:It is 1.0 high Speed mixing obtains biomass-based polyurethane hard foam material and is filled in the cavity of inside and outside wallboard, be allowed to inside and outside wallboard and House frame and connecting elements in the range of this form a closely knit entirety, i.e. lower wall body.
5), whole wall
After lower floor's wall is formed, then the inside and outside wallboard in middle part is installed, then recycles spraying or casting type polyurethane foaming Machine will combine biological polyol and isocyanates by volume 1:1.0 mixed at high speed obtain biomass-based polyurethane hard foam material Material be filled in the cavity of inside and outside wallboard, be allowed to lower wall body, the inside and outside wallboard in middle part, in the range of house frame, auxiliary connect Connection member etc. forms a closely knit entirety, i.e. wall segment.Then inside and outside wallboard is successively installed in such a way again, sprayed Or the biomass-based polyurethane hard foam material of cast, until forming a complete closely knit Light Wall.
Embodiment 3
One), sheet material technique specific steps and parameter declaration:
1), raw material
In terms of mass fraction, waste material of stone from it is featured, crush 100 mesh color aggregate one or more, 65 Part;
32.5,15 parts of cement selection Portland cement P.O;
The thin river sand of dry matter after sand selection washing, 10 parts;
Mica powder from 120 mesh assorted colored mica powder one or more, 10 parts;
Resin-oatmeal is last from thermosetting phenol-formaldehyde resin powder, 7 parts.
2), mould
Required according to the sheet material of different size, make the 65Mn Carbon Steel Dies with cover of different size, all surface of mould by oneself Handled through sanding and polishing.In the wheat cangue paper or ox-hide of the appropriate specification in die bottom plate (12mm thickness 65Mn carbon steels) one layer of upper berth before cloth Paper, loading onto four detachable mould frames, (mould frame is 15*15mm 65Mn carbon steel square steel, according to the plate of different size Material thickness assembles the 15*15mm65Mn carbon steels square steel of the appropriate number of plies) on die bottom plate, it will be measured by special cloth system Mixed material afterwards is uniformly mated formation into mould, in the wheat cangue paper or brown paper of the one layer of appropriate specification in the material bed upper berth struck off, then (18mm thickness 65Mn carbon steels, suitable number of die cover plate, cover plate are assembled according to the sheet metal thickness of different size plus die cover plate Length and width size it is more each small 6mm than the length and width in effective interior space of band edge frame bottom plate).
3), precompressed
Pressure 20MPa under normal temperature, voltage stabilizing 7min.
4), hot-press solidifying
Temperature:150℃;
Pressure:28MPa;Voltage stabling control:90min.
5), cool down, mold, curing
After mould takes out from hot-pressing system, water cooled system is cooled to 70 DEG C, then is cooled to normal temperature through air cooling system, beats Covered on mold, remove bottom plate frame, take out the workblank sheet material after shaping, this workblank sheet material is stable by the curing of 9 days, you can Carry out following process.
6), deburring is cut
Workblank sheet material after shaping enters diced system and carries out four side surface trimmings, the excision 4mm per side.
7), fixed thick sanding
Workblank sheet material after deburring cutting carries out determining thick sanding into sanding system.The three-level abrasive band mesh number of sanding system point Not Wei 60 mesh, 80 mesh, 120 mesh, sand remove the upper and lower surface of sheet material ply of paper, sheet material is reached defined thickness.
8), polish
Sheet material after fixed thick sanding carries out regulation into polishing system and requires surface polishing, the three-level abrasive band mesh of polishing system Number is respectively 240 mesh, 320 mesh, 600 mesh, and the sheet material after polishing has higher flatness and finish.
9), finished product sheet material
1500~2600kg/m of this finished product sheet material density range3, length range≤3600mm, width range≤2000mm, Thickness range 4mm~150mm.The finished product sheet material of dimension can also be cut into again by different size requirement.
Two), biomass-based thermoplastic material technique specific steps and parameter declaration:
1), lignin, polyvinyl chloride resin, the mixing of the first auxiliary agent
By crush dry after lignin mixed with polyvinyl chloride resin, the first auxiliary agent, after under ultrasonic power 300W ultrasound 3min, then the microwave treatment 5min under microwave power 500W, finally enters high temperature double-screw rod thermoplastic extruder, by different Mould, produce the thermoplastic section bar of different size.
Lignin requires moisture≤5%, and mesh number is more than 400 mesh, in terms of mass fraction, 75 parts of lignin, and polyvinyl chloride resin 10 Part, 4 parts of the first auxiliary agent.
2), high-temperature thermoplastic
The temperature in each area is at 135~175 DEG C before and after twin (double) screw extruder, and is deposited between front and rear each area of twin (double) screw extruder In temperature difference.
3), finished product thermoplastic material
According to different target thermoplastic material requirements, corresponding mould is loaded onto in twin (double) screw extruder output section, you can Obtain the thermoplastic material of regulation requirement.
Three), biomass-based polyurethane hard foam material technology specific steps and parameter declaration:
1), raw material mixes
The polyethylene glycol 400 of formula ratio, glycerine, lignin, the concentrated sulfuric acid are added in reactor, wherein with mass fraction Meter, polyethylene glycol 400,45 parts, 22.5 parts of glycerine, 33 parts of lignin, 0.8 part of the concentrated sulfuric acid.
2), High-temperature Liquefaction
Mixed material is warming up to 150 DEG C, and normal pressure liquefaction 75min at this temperature.
3) dehydration, is neutralized
Material in the sodium hydrate particle and reactor of chemical equivalent reacting dose is added by the concentrated sulfuric acid amount in formula to neutralize After reaction, vacuum dehydration to condensation produces under vacuum 0.09MPa.
4), cool
Material is cooled to by the cooling system of reactor by normal temperature, that is, obtains biological polyol finished product.
5) biological polyol finished product, is combined
Added in refined biometric polyalcohol a certain amount of fire retardant, foam stabilizer, foaming agent it is well mixed combination biology Polyalcohol finished product.
6), biomass-based polyurethane hard foam material
When needing to use, body is pressed with isocyanates by biological polyol is combined by spraying or casting type polyurethane foaming machine Product ratio 1:1.1 mixed at high speed obtain biomass-based polyurethane hard foam material.
Four), Light Wall technique specific steps and parameter declaration:
1), building structure framework and inside and outside wallboard connection auxiliary part
Building structure framework is gone out by welding production using I-steel or square steel according to house desigh drawing.And pass through screw The auxiliary part needed for inside and outside wall board is connected on building structure framework.
2), framework surface spraying, the biomass-based polyurethane hard foam material of cast
During house frame structure is welded, in square steel inner space and I-steel surface spraying or cast biomass Based polyurethanes stiff foam material.
3), the installation of inside and outside wallboard
First the inside and outside wallboard of bottom is arranged on the auxiliary part on building structure framework.
4), spray, pour into a mould biomass-based polyurethane hard foam material
Biological polyol and isocyanates by volume 1 will be combined using spraying or casting type polyurethane foaming machine:1.1 than Example mixed at high speed obtains biomass-based polyurethane hard foam material and is filled in the cavity of inside and outside wallboard, is allowed to and inner, external wall Plate and house frame and connecting elements one closely knit entirety of formation in the range of this, i.e. lower wall body.
5), whole wall
After lower floor's wall is formed, then the inside and outside wallboard in middle part is installed, then recycles spraying or casting type polyurethane foaming Machine will combine biological polyol and isocyanates by volume 1:1.1 mixed at high speed obtain biomass-based polyurethane hard foam material Material be filled in the cavity of inside and outside wallboard, be allowed to lower wall body, the inside and outside wallboard in middle part, in the range of house frame, auxiliary connect Connection member etc. forms a closely knit entirety, i.e. wall segment.Then inside and outside wallboard is successively installed in such a way again, sprayed Or the biomass-based polyurethane hard foam material of cast, until forming a complete closely knit Light Wall.
Embodiment 4
One), sheet material technique specific steps and parameter declaration:
1), raw material
In terms of mass fraction, waste material of stone from it is featured, crush 150 mesh color aggregate one or more, 75 Part;
32.5,17 parts of cement selection white portland cement P.W;
The thin river sand of dry matter after sand selection washing, 8 parts;
Mica powder from 150 mesh assorted colored mica powder one or more, 12 parts;
Resin-oatmeal is last from thermosetting phenol-formaldehyde resin powder, 7 parts.
2), mould
Required according to the sheet material of different size, make the 65Mn Carbon Steel Dies with cover of different size, all surface of mould by oneself Handled through sanding and polishing.In the wheat cangue paper or ox-hide of the appropriate specification in die bottom plate (12mm thickness 65Mn carbon steels) one layer of upper berth before cloth Paper, loading onto four detachable mould frames, (mould frame is 15*15mm 65Mn carbon steel square steel, according to the plate of different size Material thickness assembles the 15*15mm65Mn carbon steels square steel of the appropriate number of plies) on die bottom plate, it will be measured by special cloth system Mixed material afterwards is uniformly mated formation into mould, in the wheat cangue paper or brown paper of the one layer of appropriate specification in the material bed upper berth struck off, then (18mm thickness 65Mn carbon steels, suitable number of die cover plate, cover plate are assembled according to the sheet metal thickness of different size plus die cover plate Length and width size it is more each small 6mm than the length and width in effective interior space of band edge frame bottom plate).
3), precompressed
Pressure 20MPa under normal temperature, voltage stabilizing 8min.
4), hot-press solidifying
Temperature:155℃;
Pressure:27MPa;Voltage stabling control:75min.
5), cool down, mold, curing
After mould takes out from hot-pressing system, water cooled system is cooled to 65 DEG C, then is cooled to normal temperature through air cooling system, beats Covered on mold, remove bottom plate frame, take out the workblank sheet material after shaping, this workblank sheet material is stable by the curing of 9 days, you can Carry out following process.
6), deburring is cut
Workblank sheet material after shaping enters diced system and carries out four side surface trimmings, the excision 5mm per side.
7), fixed thick sanding
Workblank sheet material after deburring cutting carries out determining thick sanding into sanding system.The three-level abrasive band mesh number of sanding system point Not Wei 60 mesh, 80 mesh, 120 mesh, sand remove the upper and lower surface of sheet material ply of paper, sheet material is reached defined thickness.
8), polish
Sheet material after fixed thick sanding carries out regulation into polishing system and requires surface polishing, the three-level abrasive band mesh of polishing system Number is respectively 240 mesh, 320 mesh, 600 mesh, and the sheet material after polishing has higher flatness and finish.
9), finished product sheet material
1500~2600kg/m of this finished product sheet material density range3, length range≤3600mm, width range≤2000mm, Thickness range 4mm~150mm.The finished product sheet material of dimension can also be cut into again by different size requirement.
Two), biomass-based thermoplastic material technique specific steps and parameter declaration:
1), lignin, polyvinyl chloride resin, the mixing of the first auxiliary agent
By crush dry after lignin mixed with polyvinyl chloride resin, the first auxiliary agent, after under ultrasonic power 400W ultrasound 3min, then the microwave treatment 2min under microwave power 800W, finally enters high temperature double-screw rod thermoplastic extruder, by different Mould, produce the thermoplastic section bar of different size.
Lignin requires moisture≤5%, and mesh number is more than 400 mesh, in terms of mass fraction, 80 parts of lignin, and polyvinyl chloride resin 15 Part, 5 parts of the first auxiliary agent.
2), high-temperature thermoplastic
The temperature in each area is at 140~160 DEG C before and after twin (double) screw extruder.
3), finished product thermoplastic material
According to different target thermoplastic material requirements, corresponding mould is loaded onto in twin (double) screw extruder output section, you can Obtain the thermoplastic material of regulation requirement.
Three), biomass-based polyurethane hard foam material technology specific steps and parameter declaration:
1), raw material mixes
The polyethylene glycol 400 of formula ratio, glycerine, lignin, the concentrated sulfuric acid are added in reactor, wherein with mass fraction Meter, 43 parts of polyethylene glycol 400,21 parts of glycerine, 35 parts of lignin, 0.9 part of the concentrated sulfuric acid.
2), High-temperature Liquefaction
Mixed material is warming up to 155 DEG C, and normal pressure liquefaction 80min at this temperature.
3) dehydration, is neutralized
Material in the sodium hydrate particle and reactor of chemical equivalent reacting dose is added by the concentrated sulfuric acid amount in formula to neutralize After reaction, vacuum dehydration to condensation produces under vacuum 0.09MPa.
4), cool
Material is cooled to by the cooling system of reactor by normal temperature, that is, obtains biological polyol finished product.
5) biological polyol finished product, is combined
Added in refined biometric polyalcohol a certain amount of fire retardant, foam stabilizer, foaming agent it is well mixed combination biology Polyalcohol finished product.
6), biomass-based polyurethane hard foam material
When needing to use, body is pressed with isocyanates by biological polyol is combined by spraying or casting type polyurethane foaming machine Product ratio 1:1.2 mixed at high speed obtain biomass-based polyurethane hard foam material.
Four), Light Wall technique specific steps and parameter declaration:
1), building structure framework and inside and outside wallboard connection auxiliary part
Building structure framework is gone out by welding production using I-steel or square steel according to house desigh drawing.And pass through screw The auxiliary part needed for inside and outside wallboard is connected on building structure framework.
2), framework surface spraying, the biomass-based polyurethane hard foam material of cast
During house frame structure is welded, in square steel inner space and I-steel surface spraying or cast biomass Based polyurethanes stiff foam material.
3), the installation of inside and outside wallboard
First the inside and outside wallboard of bottom is arranged on the auxiliary part on building structure framework.
4), spray, pour into a mould biomass-based polyurethane hard foam material
Biological polyol and isocyanates by volume 1 will be combined using spraying or casting type polyurethane foaming machine:It is 1.2 high Speed mixing obtains biomass-based polyurethane hard foam material and is filled in the cavity of inside and outside wallboard, be allowed to inside and outside wallboard and House frame and connecting elements in the range of this form a closely knit entirety, i.e. lower wall body.
5), whole wall
After lower floor's wall is formed, then the inside and outside wallboard in middle part is installed, then recycles spraying or casting type polyurethane foaming Machine will combine biological polyol and isocyanates by volume 1:1.2 mixed at high speed obtain biomass-based polyurethane hard foam material Material be filled in the cavity of inside and outside wallboard, be allowed to lower wall body, the inside and outside wallboard in middle part, in the range of house frame, auxiliary connect Connection member etc. forms a closely knit entirety, i.e. wall segment.Then inside and outside wallboard is successively installed in such a way again, sprayed Or the biomass-based polyurethane hard foam material of cast, until forming a complete closely knit Light Wall.
Module number and treatment scale described herein are the explanations for simplifying the present invention.To the light weight wall of the present invention The application of the preparation method of body, modifications and variations will be readily apparent to persons skilled in the art.
As described above, the leftover bits of the invention flood tide caused by exploitation lithotome are through screening, being ground into different rule The stone matter powder of lattice, as this sheet material of main material production, produce the building dress that there are more scope of applications than lithotome Exterior material, turn waste into wealth, undoubtedly with huge economic implications.And this problem that is made as thoroughly solving of this sheet material have found Outlet.Belong to the environmental protection and waste utilization industry of resource circulation utilization, develop this sheet material making industry do not consume directly in itself it is primary from Right resource, do not destroy natural environment, the industry make use of lithotome open a mine caused by it is substantial amounts of be difficult to effectively to handle it is useless Building stones resource, the mode of production of itself are environment-friendly types.Therefore, the making industry of this sheet material be one have boundless prospects new build Ornament materials industry to be built, there is wide development space, the condition for currently greatly developing the making industry of the sheet material has been provided with, Quick development will be obtained.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited In specific details and shown here as the legend with description.

Claims (10)

  1. A kind of 1. preparation method of Light Wall, it is characterised in that including:
    Step 1: according to building construction design, first, building structure main frame is produced using I-steel or square steel material, together When, in the I-steel or the spraying of square steel inner space or biomass-based polyurethane hard foam material is poured into a mould, afterwards using biomass Base thermoplastic material is as thin case frame;
    Step 2: the auxiliary part for connecting inside and outside wallboard is connected on building structure main frame first, afterwards by bottom Inside and outside wallboard is connected on the auxiliary part;
    Step 3: the biomass-based polyurethane hard foam material is poured into a mould or sprayed into the cavity of the inside and outside wallboard of the bottom, Its wallboard inside and outside with the bottom and building structure main frame herein and auxiliary part is set to form closely knit lower wall body;
    Step 4: after forming the lower wall body, the inside and outside wallboard in middle part is installed, afterwards also to the inside and outside wallboard in the middle part Pour into a mould in cavity or spray the biomass-based polyurethane hard foam material, make itself and the lower wall body, middle part inner, external wall Plate, building structure main frame and auxiliary part form closely knit wall segment herein;
    Step 5: each several part wall is successively formed according to the method for step 3 and step 4, until it is complete closely knit light to form one Matter wall.
  2. 2. the preparation method of Light Wall as claimed in claim 1, it is characterised in that the preparation method of the inside and outside wallboard Comprise the following steps:
    2.1) in terms of mass fraction, take 40~200 mesh 0~20 part of 10~20 parts of 50~80 parts of waste material of stone, cement, sand, 6~8 parts of mixing of 0~20 part of the mica powder of 40~200 mesh and resin-oatmeal;
    2.2) by mixed raw material in 2.1), 3~10min of voltage stabilizing carries out precompressed processing under normal temperature, pressure 20MPa;
    2.3) by the raw material after precompressed is handled at 140~160 DEG C of temperature and pressure 25MPa~30MPa voltage stabilizing 30~ 120min carries out hot-press solidifying processing, obtains workblank sheet material;
    2.4) workblank sheet material is processed as finished product sheet material, as the inside and outside wallboard.
  3. 3. the preparation method of Light Wall as claimed in claim 1, it is characterised in that the system of the biomass-based thermoplastic material Preparation Method comprises the following steps:
    Lignin is mixed with polyvinyl chloride resin and the first auxiliary agent first, is then fed into twin-screw thermoplastic extruder, in double spiral shells Corresponding mould is loaded onto in bar extruder output section, produces the biomass-based thermoplastic material of different size, wherein, with mass parts Meter, lignin is 75~90 parts, polyvinyl chloride resin is 10~25 parts and 3~5 parts of the first auxiliary agent.
  4. 4. the preparation method of Light Wall as claimed in claim 1, it is characterised in that the biomass-based polyurethane hard foam The preparation method of material comprises the following steps:
    1.1) raw material mixes:In terms of mass fraction, 400 40~50 parts of taking polyethylene glycol, 20~25 parts of glycerine, lignin 25 ~40 parts, 0.5~1 part of the concentrated sulfuric acid, it is placed in reactor;
    1.2) High-temperature Liquefaction:Mixed material is warming up to 140~160 DEG C, and 60~90min of normal pressure liquefaction at this temperature;
    1.3) dehydration is neutralized:The sodium hydroxide with the concentrated sulfuric acid chemistry equivalent reacting dose is added first into the reactor, Vacuum dehydration to condensation produces under vacuum 0.09MPa afterwards;
    1.4) cool:Normal temperature is cooled to, obtains biological polyol finished product;
    1.5) biological polyol finished product is combined:Add the second auxiliary agent in refined biometric polyalcohol, formed combination biological polyol into Product;
    1.6) biomass-based polyurethane hard foam material:By combination biological polyol and the isocyanates by volume 1:0.9 ~1.2 mixing, that is, obtain the biomass-based polyurethane hard foam material.
  5. 5. the preparation method of Light Wall as claimed in claim 2, it is characterised in that the waste material of stone is in color aggregate One or more, the cement is Portland cement P.O 32.5 or white portland cement P.W 32.5, the sand Son is the thin river sand of dry matter, and the mica powder is the one or more of assorted colored mica powder, and the resin-oatmeal is thermosetting phenolic Toner.
  6. 6. the preparation method of Light Wall as claimed in claim 2, it is characterised in that in step 2.2), after mixing first Raw material be placed in board mould, carry out the precompressed processing again afterwards;
    In step 2.3), after the hot-press solidifying processing, water cooled system is cooled to 60~80 DEG C, then is cooled down through air cooling system To normal temperature, the workblank sheet material is obtained.
  7. 7. the preparation method of Light Wall as claimed in claim 2, it is characterised in that in step 2.4), by workblank sheet material plus Work is that finished product sheet material specifically comprises the following steps:
    It is first that workblank sheet material is stable by the curing of 7~10 days, the workblank sheet material after shaping is placed in diced system afterwards Four side surface trimmings are carried out, then carries out determining thick sanding, is finally polished, obtains the finished product sheet material;
    Wherein, when carrying out four side surface trimmings, 4~5mm is cut off per side;
    When carrying out the fixed thick sanding, the three-level abrasive band mesh number of sanding system is respectively 60 mesh, 80 mesh and 120 mesh, and sand is except described The ply of paper of workblank sheet material upper and lower surface;
    When carrying out the polishing, the three-level abrasive band mesh number of polishing system is respectively 240 mesh, 320 mesh and 600 mesh.
  8. 8. the preparation method of Light Wall as claimed in claim 3, it is characterised in that the system of the biomass-based thermoplastic material In Preparation Method, the lignin requires moisture≤5%, and mesh number is more than 400 mesh, front and rear each area of the twin (double) screw extruder Temperature be 130~180 DEG C.
  9. 9. the preparation method of Light Wall as claimed in claim 4, it is characterised in that second auxiliary agent include fire retardant, Foam stabilizer and foaming agent;
    In step 1.6), the combination biological polyol is pressed by body with isocyanates by spraying or casting type polyurethane foaming machine Product ratio 1:0.9~1.2 mixing.
  10. 10. the preparation method of Light Wall as claimed in claim 3, it is characterised in that the biomass-based thermoplastic material It is ultrasonic first under 300~400W of ultrasonic power after lignin is mixed with polyvinyl chloride resin and the first auxiliary agent in preparation method 3min, after 2~5min of microwave treatment under 500~800W of microwave power, be then re-fed into the twin (double) screw extruder.
CN201710755986.7A 2017-08-29 2017-08-29 A kind of preparation method of Light Wall Pending CN107620406A (en)

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CN112048169A (en) * 2020-09-01 2020-12-08 四川童燊防水工程有限公司 Polymer filling type light material and method for manufacturing partition wall by using same

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CN2264774Y (en) * 1996-12-20 1997-10-15 刘欣凯 Monoblock-casting-type light wall
CN1353230A (en) * 2000-11-02 2002-06-12 陈平义 Assembled light refractory partition
CN102206320A (en) * 2011-04-22 2011-10-05 中国农业大学 Preparation method of biomass-base polyurethane foam material
CN102432240A (en) * 2011-09-26 2012-05-02 苏州金楠新能源墙体工程有限公司 Environment-friendly wallboard material and environment-friendly anti-seismic wall body containing same
CN202644783U (en) * 2012-05-10 2013-01-02 梁光溪 Prefabricated light wall
CN104441532A (en) * 2014-12-03 2015-03-25 松原光禾能源有限公司 Preparation method of lignin thermoplastic material
CN204590334U (en) * 2015-04-30 2015-08-26 威力(烟台)木业技术有限公司 A kind of wood composite structure wall
CN105317110A (en) * 2015-11-06 2016-02-10 中建钢构有限公司 Integrated assembly type steel structure building
CN106639140A (en) * 2017-02-21 2017-05-10 孔祥雨 High-strength biomass fiber insulation composite lightweight exterior wallboard and manufacture method thereof

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Publication number Priority date Publication date Assignee Title
CN2264774Y (en) * 1996-12-20 1997-10-15 刘欣凯 Monoblock-casting-type light wall
CN1353230A (en) * 2000-11-02 2002-06-12 陈平义 Assembled light refractory partition
CN102206320A (en) * 2011-04-22 2011-10-05 中国农业大学 Preparation method of biomass-base polyurethane foam material
CN102432240A (en) * 2011-09-26 2012-05-02 苏州金楠新能源墙体工程有限公司 Environment-friendly wallboard material and environment-friendly anti-seismic wall body containing same
CN202644783U (en) * 2012-05-10 2013-01-02 梁光溪 Prefabricated light wall
CN104441532A (en) * 2014-12-03 2015-03-25 松原光禾能源有限公司 Preparation method of lignin thermoplastic material
CN204590334U (en) * 2015-04-30 2015-08-26 威力(烟台)木业技术有限公司 A kind of wood composite structure wall
CN105317110A (en) * 2015-11-06 2016-02-10 中建钢构有限公司 Integrated assembly type steel structure building
CN106639140A (en) * 2017-02-21 2017-05-10 孔祥雨 High-strength biomass fiber insulation composite lightweight exterior wallboard and manufacture method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048169A (en) * 2020-09-01 2020-12-08 四川童燊防水工程有限公司 Polymer filling type light material and method for manufacturing partition wall by using same

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Application publication date: 20180123