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CN107576093A - The devices and methods therefor of solar energy absorption collection heating and cooling water purification integration - Google Patents

The devices and methods therefor of solar energy absorption collection heating and cooling water purification integration Download PDF

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CN107576093A
CN107576093A CN201710841777.4A CN201710841777A CN107576093A CN 107576093 A CN107576093 A CN 107576093A CN 201710841777 A CN201710841777 A CN 201710841777A CN 107576093 A CN107576093 A CN 107576093A
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heat
solar
adsorption
water
cooling
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马春元
刘岩
朱晓
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Shandong University
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Shandong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

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Abstract

The invention discloses a kind of solar energy to adsorb collection heating and cooling water purification integral system and its method.Wherein, the system includes solar thermal collector, it is respectively connected with leading to supplementary energy and pipeline pump, supplementary energy is connected with attemperater, pipeline pump is connected with condenser, and condenser is also connected with attemperater, and attemperater is connected with heating plant, solar thermal collector is also connected with evaporator, and evaporator is connected with regenerator;Wherein, adsorbent is equiped with solar thermal collector, it is used to adsorb the refrigerant in evaporator, and the purification to adsorbate is realized by adsorption-desorption process;Refrigerant evaporation endothermic in evaporator realizes refrigeration;Adsorbent in solar thermal collector realizes heating by discharging latent heat in the vapor liquefaction process of adsorption process heat release and desorption.

Description

太阳能吸附集供热供冷净水一体化的装置及其方法Device and method for integrating solar energy adsorption, heating, cooling, supply and water purification

技术领域technical field

本发明属于太阳能热利用和空调制冷技术领域,尤其涉及一种太阳能吸附集供热供冷净水一体化的装置及其方法。The invention belongs to the technical field of solar heat utilization and air-conditioning refrigeration, and in particular relates to a device and method for integrating solar energy adsorption, heat supply, cooling supply, cooling water and water purification.

背景技术Background technique

随着传统能源的减少,可再生能源如太阳能、风能、生物质能、潮汐能等迎来发展期,太阳能由于其独特的优势得到了迅速的发展,太阳能是一种取之不尽、用之不竭的可再生清洁能源,被公认为人类未来最安全、最理想和最绿色的能源,太阳能具有总量大、成本低等优点,太阳能制冷是太阳能应用的一个重要方面,氟碳作为传统的制冷系统的制冷剂向大气中释放大量的含氯氟烃气体,太阳能驱动制冷系统一般采用非氟烃类的物质作为制冷剂,不会破坏臭氧层,也不会对环境造成污染。在我国,夏季大部分地区气温过高,人们会大量使用空调、冰箱等制冷设备,这会导致夏季用电高峰期电不够用。太阳能制冷技术可以部分或全部取代传统的蒸汽压缩制冷机或室内空调,从而减少高峰期电网负荷,但是目前太阳能制冷系统存在制冷性能系数和能源利用率低,初投资成本较高的缺点。With the reduction of traditional energy sources, renewable energy sources such as solar energy, wind energy, biomass energy, and tidal energy are ushering in a period of development. Solar energy has developed rapidly due to its unique advantages. Solar energy is an inexhaustible and Inexhaustible renewable clean energy is recognized as the safest, most ideal and greenest energy for human beings in the future. Solar energy has the advantages of large total amount and low cost. Solar refrigeration is an important aspect of solar energy application. Fluorocarbon as a traditional The refrigerant in the refrigeration system releases a large amount of chlorofluorocarbon gas into the atmosphere. Solar-powered refrigeration systems generally use non-fluorocarbon substances as refrigerants, which will not damage the ozone layer and will not pollute the environment. In our country, the temperature in most areas in summer is too high, and people will use a lot of refrigeration equipment such as air conditioners and refrigerators, which will lead to insufficient electricity during peak electricity consumption in summer. Solar refrigeration technology can partially or completely replace traditional vapor compression refrigerators or indoor air conditioners, thereby reducing the load on the grid during peak periods. However, the current solar refrigeration system has the disadvantages of low refrigeration performance coefficient and energy utilization rate, and high initial investment costs.

目前,地球上水资源总量1.5×1018m3,其中97.3%的水都在海洋里,只有2.7%的淡水资源,在2.7%的淡水中,有很大一部分为冰山,分布在地球两极的冰雪地带,只有0.7%的淡水分布在江、河、湖泊中,供人类饮用及农作物灌溉使用,远远不能满足需要。国际上有“19世纪争煤,20世纪争油,21世纪争水”的说法。为了解决淡水资源缺乏的问题,世界各国的科学家都把目光投向了海水淡化领域,但是,传统的海水淡化技术投资高,能源消耗过大,制约了太阳能海水淡化技术的快速发展,太阳能海水淡化主要有两种方法:利用太阳所产生的热能驱动海水发生相变并进行分离,对分离的水蒸汽进行冷凝,产生淡水;利用太阳能产生的直流电场使海水中的离子定向迁移,通过离子交换膜实现溶质和溶剂的分离,实现海水淡化。吸附式制冷和海水淡化都需要太阳能提供能量,吸附式制冷系统通过吸附剂(硅胶、活性炭等)对制冷剂(水、甲醇等)的吸附和解吸实现制冷,所以考虑将太阳能吸附式制冷和海水淡化结合起来,以硅胶或活性炭为吸附剂,海水作为制冷剂,既可以实现制冷,又能实现海水淡化,解决淡水资源紧缺的问题。At present, the total amount of water resources on the earth is 1.5×10 18 m 3 , 97.3% of which are in the ocean, and only 2.7% of the fresh water resources, and a large part of the 2.7% of the fresh water are icebergs, which are distributed at the two poles of the earth Only 0.7% of fresh water is distributed in rivers, rivers, and lakes in China's ice and snow areas, which are used for human drinking and crop irrigation, which is far from meeting the needs. Internationally, there is a saying that "the struggle for coal in the 19th century, the struggle for oil in the 20th century, and the struggle for water in the 21st century". In order to solve the problem of lack of fresh water resources, scientists from all over the world have turned their attention to the field of seawater desalination. However, the traditional seawater desalination technology has high investment and excessive energy consumption, which restricts the rapid development of solar seawater desalination technology. Solar seawater desalination mainly There are two methods: use the thermal energy generated by the sun to drive the seawater to undergo phase change and separate, and condense the separated water vapor to produce fresh water; use the direct current electric field generated by solar energy to make the ions in the seawater migrate directionally, and achieve this through the ion exchange membrane. Separation of solute and solvent to achieve seawater desalination. Both adsorption refrigeration and seawater desalination require solar energy to provide energy. The adsorption refrigeration system achieves refrigeration through the adsorption and desorption of refrigerants (water, methanol, etc.) by adsorbents (silica gel, activated carbon, etc.), so consider solar adsorption refrigeration and seawater Combining desalination, using silica gel or activated carbon as the adsorbent and seawater as the refrigerant, it can not only achieve refrigeration, but also desalinize seawater to solve the problem of shortage of fresh water resources.

经过专利检索发现,现有的太阳能热泵空调系统主要用来实现供冷供热,没有利用太阳能吸附式制冷系统实现供冷供热净水的装置。专利CN204555309A,名称为一种复合吸附剂太阳能热泵热水器的专利提供了一种不仅利用太阳能自身的热能,还利用复合吸附剂的解吸吸附热量加热热水,提高了制热水的效率,降低了电能的消耗,但是该系统只能用来提供热水,功能单一,投资与产出不成正比。专利CN104501453A,名称为多能源取暖制冷及热水供应一体化系统的装置,该装置提供了一种太阳能与生物质锅炉结合的取暖制冷及热水供应一体化的方法,但是该装置在冬天供热时太阳能吸附式制冷系统不能被利用,造成资源的浪费;冬天利用太阳能加热冷水(0℃)需要的热量大,在太阳能不充足的地区很难利用太阳能将冷水加热到50℃。After a patent search, it was found that the existing solar heat pump air-conditioning system is mainly used for cooling and heating, and there is no device for cooling, heating, water purification using the solar adsorption refrigeration system. Patent CN204555309A, titled as a composite adsorbent solar heat pump water heater, provides a patent that not only utilizes the heat energy of solar energy itself, but also uses the desorption and adsorption heat of the composite adsorbent to heat hot water, which improves the efficiency of hot water production and reduces the electric energy. consumption, but the system can only be used to provide hot water, the function is single, and the investment is not directly proportional to the output. Patent CN104501453A, titled multi-energy heating, cooling and hot water supply integrated system device, the device provides a method of heating, cooling and hot water supply integration combined with solar energy and biomass boilers, but the device provides heating in winter Sometimes the solar adsorption refrigeration system cannot be used, resulting in a waste of resources; using solar energy to heat cold water (0°C) in winter requires a lot of heat, and it is difficult to use solar energy to heat cold water to 50°C in areas where solar energy is insufficient.

综上所述,现有的太阳能吸附式制冷系统存在:功能单一,制冷效率不高和海水淡化技术投资成本大,能源消耗过大的问题。To sum up, the existing solar adsorption refrigeration system has the problems of single function, low refrigeration efficiency, high investment cost of seawater desalination technology, and excessive energy consumption.

发明内容Contents of the invention

为了解决现有技术的不足,本发明实施例第一方面提供了一种太阳能吸附集供热供冷净水一体化系统,其结构简单,易于操作,节能环保,功能多效。In order to solve the deficiencies of the prior art, the first aspect of the embodiment of the present invention provides an integrated system of solar adsorption, heating, cooling, supply and water purification, which has a simple structure, easy operation, energy saving and environmental protection, and multiple functions.

本发明的一种太阳能吸附集供热供冷净水一体化系统,包括:太阳能集热器,其与辅助能源和管道泵分别相连通,辅助能源与保温水箱相连通,管道泵与冷凝器相连通,冷凝器还与保温水箱相连通,保温水箱与供热装置相连通,太阳能集热器还与蒸发器相连通,蒸发器与蓄冷器相连通;An integrated system of solar energy adsorption, heat supply, cooling, supply, and water purification of the present invention includes: a solar heat collector, which is connected to an auxiliary energy source and a pipeline pump, the auxiliary energy source is connected to a thermal insulation water tank, and the pipeline pump is connected to a condenser The condenser is also connected with the heat preservation water tank, the heat preservation water tank is connected with the heating device, the solar heat collector is also connected with the evaporator, and the evaporator is connected with the cold storage;

其中,太阳能集热器内装设有吸附剂,其用于吸附蒸发器中的制冷剂,通过吸附解吸过程实现对制冷剂的净化;蒸发器中的制冷剂蒸发吸热实现制冷;太阳能集热器内的吸附剂通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热。Among them, the solar collector is equipped with an adsorbent, which is used to absorb the refrigerant in the evaporator, and realize the purification of the refrigerant through the process of adsorption and desorption; the refrigerant in the evaporator evaporates and absorbs heat to achieve refrigeration; the solar collector The adsorbent in the adsorption process releases heat through the adsorption process and releases latent heat during the desorption process of water vapor liquefaction to achieve heat generation.

结合本发明实施例的第一方面,本发明实施例的第一方面的第一种实施方式中,所述吸附剂上铺设有真空玻璃板。With reference to the first aspect of the embodiments of the present invention, in the first implementation manner of the first aspect of the embodiments of the present invention, a vacuum glass plate is laid on the adsorbent.

其中,吸附剂为活性炭或硅胶。Wherein, the adsorbent is activated carbon or silica gel.

结合本发明实施例的第一方面,本发明实施例的第一方面的第二种实施方式中,所述太阳能集热器内部为隔栅结构。With reference to the first aspect of the embodiments of the present invention, in the second implementation manner of the first aspect of the embodiments of the present invention, the interior of the solar heat collector is a grid structure.

在该实施例中,将太阳能集热器内部设计成隔栅结构,使吸附剂(比如:硅胶)受热更均匀;由于吸附剂(比如:硅胶)吸附过程放热,该热量会使吸附剂(硅胶)温度升高,影响其吸附性能,所以在太阳能集热器内部通冷却管使吸附剂(比如:硅胶)保持低温下吸附。In this embodiment, the interior of the solar collector is designed as a grid structure, so that the adsorbent (such as: silica gel) is heated more evenly; due to the heat release during the adsorption process of the adsorbent (such as: silica gel), the heat will make the adsorbent (such as: silica gel) Silica gel) temperature increases, which affects its adsorption performance, so the cooling pipe is passed inside the solar collector to keep the adsorbent (such as: silica gel) at a low temperature for adsorption.

结合本发明实施例的第一方面,本发明实施例的第一方面的第三种实施方式中,所述保温水箱外部还设有保温层。With reference to the first aspect of the embodiments of the present invention, in a third implementation manner of the first aspect of the embodiments of the present invention, an insulation layer is further provided on the outside of the thermal insulation water tank.

在该实施例中,保温层可采用保温材料(比如:聚氨酯泡沫)来实现。In this embodiment, the insulation layer can be realized by using insulation materials (such as polyurethane foam).

这样能够防止热量或冷量的散失,使整个吸附制冷装置有较好的保温效果。This can prevent the loss of heat or cold, so that the entire adsorption refrigeration device has a better heat preservation effect.

结合本发明实施例的第一方面,本发明实施例的第一方面的第四种实施方式中,所述保温水箱内部还设置有温度传感器,所述温度传感器与微处理器。With reference to the first aspect of the embodiments of the present invention, in the fourth implementation manner of the first aspect of the embodiments of the present invention, a temperature sensor is further arranged inside the thermal insulation water tank, and the temperature sensor is connected with a microprocessor.

结合本发明实施例的第一方面,本发明实施例的第一方面的第五种实施方式中,所述供热装置包括厨房供水管道、浴室供水管道和地暖暖气管道。With reference to the first aspect of the embodiments of the present invention, in a fifth implementation manner of the first aspect of the embodiments of the present invention, the heating device includes kitchen water supply pipes, bathroom water supply pipes and floor heating pipes.

本发明实施例第二方面提供了一种太阳能吸附集供热供冷净水一体化系统的工作方法。The second aspect of the embodiment of the present invention provides a working method of an integrated system of solar energy adsorption, heating, cooling, supplying, cooling and water purification.

本发明实施例第二方面提供的太阳能吸附集供热供冷净水一体化系统的工作方法,包括:The working method of the integrated system of solar adsorption, heating, cooling, supply and water purification provided by the second aspect of the embodiment of the present invention includes:

供冷状态:蒸发器中的制冷剂蒸发吸热实现制冷;Cooling state: the refrigerant in the evaporator evaporates and absorbs heat to achieve cooling;

供热状态:太阳能集热器内的吸附剂通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热;Heating state: The adsorbent in the solar collector releases heat through the adsorption process and releases latent heat during the desorbed water vapor liquefaction process to achieve heating;

净化状态:太阳能集热器(比如吸附床)内的吸附剂吸附蒸发器中的制冷剂,通过吸附解吸过程实现对吸附质的净化。Purification state: The adsorbent in the solar collector (such as an adsorption bed) adsorbs the refrigerant in the evaporator, and the adsorbate is purified through the adsorption and desorption process.

结合本发明实施例的第二方面,本发明实施例的第二方面的第一种实施方式中,在供冷状态下,此时太阳能达不到预设值或夜间,太阳能集热器(比如吸附床)的温度降低,吸附剂开始吸附蒸发器中的制冷剂,吸附床中的吸附剂吸附制冷剂后放出吸附热使冷却水温度升高来对外供热;In combination with the second aspect of the embodiments of the present invention, in the first implementation of the second aspect of the embodiments of the present invention, in the cooling state, when the solar energy does not reach the preset value or at night, the solar collector (such as The temperature of the adsorption bed) decreases, and the adsorbent begins to adsorb the refrigerant in the evaporator, and the adsorbent in the adsorption bed absorbs the refrigerant and releases the heat of adsorption to increase the temperature of the cooling water to supply heat to the outside;

蒸发器中的吸附质在蒸发过程从环境中吸收大量热量,实现制冷过程;蓄冷器还储存部分冷量以供白天使用。The adsorbate in the evaporator absorbs a large amount of heat from the environment during the evaporation process to realize the refrigeration process; the cold storage also stores part of the cold energy for use during the day.

结合本发明实施例的第二方面,本发明实施例的第二方面的第二种实施方式中,在供热状态下,太阳能集热器中有吸附饱和的吸附剂,太阳能集热器吸收太阳能为吸附床加热,温度达到吸附剂的解吸温度,解吸后的水蒸气被管道泵抽出进入冷凝器冷凝为高温液态水,水蒸气在冷凝过程中释放大量的汽化潜热,这部分热量加热换热管中的冷却水对外提供热水,被冷凝的高温液态水进入保温水箱,保温水箱中的热水为净水,保温水箱为供热装置提供热水。In combination with the second aspect of the embodiments of the present invention, in the second implementation manner of the second aspect of the embodiments of the present invention, in the heating state, there is adsorbent saturated in the solar collector, and the solar collector absorbs solar energy To heat the adsorption bed, the temperature reaches the desorption temperature of the adsorbent, the desorbed water vapor is pumped out by the pipeline pump and enters the condenser to condense into high-temperature liquid water. The water vapor releases a large amount of latent heat of vaporization during the condensation process, and this part of heat heats the heat exchange tube The cooling water in the tank provides hot water to the outside, and the condensed high-temperature liquid water enters the heat preservation water tank. The hot water in the heat preservation water tank is clean water, and the heat preservation water tank provides hot water for the heating device.

结合本发明实施例的第二方面的第二种实施方式中,在供热状态下,当保温水箱中温度低于预设温度时,使用辅助能源为保温水箱中的水加热。In the second implementation manner combined with the second aspect of the embodiment of the present invention, in the heating state, when the temperature in the thermal insulation water tank is lower than the preset temperature, the auxiliary energy is used to heat the water in the thermal insulation water tank.

与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:

(1)本发明的一种太阳能吸附集供热供冷净水一体化系统总体成本低,而且是太阳能供热供冷净水三联供产品,同时可获得热能和冷能,与常规的太阳能制热制冷系统相比,总成本可下降30%左右;(1) The overall cost of the integrated system of solar adsorption, heating, cooling, cooling and water purification of the present invention is low, and it is a triple supply product of solar heating, cooling, water purification, and can obtain heat energy and cold energy at the same time, which is different from conventional solar energy systems. Compared with thermal cooling system, the total cost can be reduced by about 30%;

(2)本发明的一种太阳能吸附集供热供冷净水一体化系统功能齐全,一举三用。本发明一举三用,在供冷供热的同时,还能净化海水、污水;(2) The integrated system of solar energy adsorption, heating, cooling, cooling and water purification of the present invention has complete functions and serves three purposes at once. The invention serves three purposes at once, and can also purify seawater and sewage while supplying cooling and heating;

(3)本发明的一种太阳能吸附集供热供冷净水一体化系统清洁环保,利用可再生清洁能源太阳能提供能量,不污染环境,实现了低品位能源的高效利用。(3) The integrated system of solar adsorption, heating, cooling, water purification and water purification of the present invention is clean and environment-friendly, uses renewable clean energy solar energy to provide energy, does not pollute the environment, and realizes high-efficiency utilization of low-grade energy.

(4)本发明的一种太阳能吸附集供热供冷净水一体化系统占用空间小,结构紧凑,维修容易,操作便捷,制造容易,成本较低。(4) The integrated system of solar adsorption, heating, cooling, supply and water purification of the present invention occupies a small space, has a compact structure, is easy to maintain, easy to operate, easy to manufacture, and low in cost.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本申请的进一步理解,本申请的示意性实施例及其说明用于解释本申请,并不构成对本申请的不当限定。The accompanying drawings constituting a part of the present application are used to provide further understanding of the present application, and the schematic embodiments and descriptions of the present application are used to explain the present application, and do not constitute improper limitations to the present application.

图1是本发明的太阳能吸附集供热供冷净水一体化系统结构示意图;Fig. 1 is a schematic structural view of the integrated system of solar energy adsorption, heating, cooling, supply and water purification of the present invention;

图2是本发明的太阳能吸附集供热供冷净水一体化系统的应用实例图;Fig. 2 is the application example diagram of the integrated system of solar energy adsorption, heat supply, cooling, supply and water purification of the present invention;

图3是本发明的太阳能集热器(吸附床)内部结构示意图;Fig. 3 is a schematic diagram of the internal structure of a solar heat collector (adsorption bed) of the present invention;

图4是本发明的太阳能吸附集供热供冷净水一体化系统的应用实例图的测温点示意图。Fig. 4 is a schematic diagram of the temperature measuring points of the application example diagram of the integrated system of solar energy adsorption collection, heat supply, cooling, supply and water purification of the present invention.

其中,1、太阳能集热器,2、辅助能源,3、管道泵,4、冷凝器,5、保温水箱,6、蒸发器,7、蓄冷器,8、温度传感器,9、厨房供水管道,10、浴室供水管道,11、地暖暖气管道,12、第一阀门,13、第二阀门,14、第三阀门,15、第四阀门,16、第五阀门,17、第六阀门,18、第七阀门,19、第八阀门,20、第一管道,21、第二管道,22、第三管道,23、第四管道,24、第五管道,25、第六管道,26、第七管道,27、第八管道,28、保温层,29、制冷剂,30、隔热多孔材料,31、吸附剂,32、真空玻璃板,33、隔栅,34、冷却管,35、孔板。Among them, 1. Solar heat collector, 2. Auxiliary energy source, 3. Pipeline pump, 4. Condenser, 5. Insulated water tank, 6. Evaporator, 7. Cooler, 8. Temperature sensor, 9. Kitchen water supply pipeline, 10. Bathroom water supply pipe, 11. Floor heating and heating pipe, 12. First valve, 13. Second valve, 14. Third valve, 15. Fourth valve, 16. Fifth valve, 17. Sixth valve, 18. The seventh valve, 19, the eighth valve, 20, the first pipeline, 21, the second pipeline, 22, the third pipeline, 23, the fourth pipeline, 24, the fifth pipeline, 25, the sixth pipeline, 26, the seventh Pipeline, 27, eighth pipeline, 28, insulation layer, 29, refrigerant, 30, heat insulating porous material, 31, adsorbent, 32, vacuum glass plate, 33, grid, 34, cooling pipe, 35, orifice plate .

具体实施方式Detailed ways

应该指出,以下详细说明都是示例性的,旨在对本申请提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本申请所属技术领域的普通技术人员通常理解的相同含义。It should be pointed out that the following detailed description is exemplary and is intended to provide further explanation to the present application. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.

需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本申请的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terminology used here is only for describing specific implementations, and is not intended to limit the exemplary implementations according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural, and it should also be understood that when the terms "comprising" and/or "comprising" are used in this specification, they mean There are features, steps, operations, means, components and/or combinations thereof.

为了解决背景技术中,所提及的太阳能吸附式制冷系统的制冷系数和能源利用率低,只实现制冷的话会使整个系统的性能系数较低,投资与产出不成正比的问题,本发明考虑到海水淡化投资较高,采取将太阳能吸附式制冷系统与海水淡化相结合的方式,实现供热供冷净水多功能化;冬季或者阴天太阳能不充足时,可以使用辅助能源(生物质能)为吸附床加热,进而提供了一种太阳能吸附集供热供冷净水一体化系统。In order to solve the problem in the background technology that the refrigeration coefficient and energy utilization rate of the solar adsorption refrigeration system mentioned are low, the coefficient of performance of the entire system will be low if only refrigeration is realized, and the investment is not directly proportional to the output. The present invention considers When the investment in seawater desalination is relatively high, the method of combining solar adsorption refrigeration system with seawater desalination can realize the multi-function of heating, cooling, water purification; in winter or when solar energy is not sufficient on cloudy days, auxiliary energy (biomass energy) can be used ) to heat the adsorption bed, thereby providing an integrated system for solar adsorption, heating, cooling, water purification.

如图1所示,本发明的太阳能吸附集供热供冷净水一体化装置,包括:太阳能集热器1、辅助能源2、管道泵3、冷凝器4、保温水箱5、蒸发器6、蓄冷器7、温度传感器8、管道和节流阀。As shown in Figure 1, the integrated device for solar adsorption, heating, cooling, supply and water purification of the present invention includes: a solar collector 1, an auxiliary energy source 2, a pipeline pump 3, a condenser 4, an insulated water tank 5, an evaporator 6, Cold accumulator 7, temperature sensor 8, pipeline and throttle valve.

其中:太阳能集热器1通过第八管道27和第一管道20分别与辅助能源2和管道泵3对应相连通,冷凝器4分别通过第二管道21和第四管道23与管道泵3和保温水箱5对应相连通,辅助能源2通过第三管道22与保温水箱5对应相连通,保温水箱5通过第七管道26分别与厨房供水管道9、浴室供水管道10和地暖暖气管道11相连通,蒸发器6分别通过第五管道24和第六管道25与太阳能集热器1和蓄冷器7相连通。Wherein: the solar heat collector 1 communicates with the auxiliary energy source 2 and the pipeline pump 3 through the eighth pipeline 27 and the first pipeline 20 respectively, and the condenser 4 communicates with the pipeline pump 3 and the insulation through the second pipeline 21 and the fourth pipeline 23 respectively. The water tank 5 is correspondingly connected, the auxiliary energy source 2 is connected correspondingly with the thermal insulation water tank 5 through the third pipeline 22, and the thermal insulation water tank 5 is respectively connected with the kitchen water supply pipeline 9, the bathroom water supply pipeline 10 and the floor heating heating pipeline 11 through the seventh pipeline 26. The device 6 communicates with the solar heat collector 1 and the cool storage device 7 through the fifth pipeline 24 and the sixth pipeline 25 respectively.

而且在图1中,第八管道27上设置有第一阀门12,第一管道20上设置有第二阀门13,第三管道22上设置有第三阀门14,第四管道23上设置有第四阀门15,第五管道24上设置有第五阀门16,保温水箱5分别与厨房供水管道9、浴室供水管道10和地暖暖气管道11之间还串接有第六阀门17、第七阀门18和第八阀门19。And in Fig. 1, the first valve 12 is provided on the eighth pipeline 27, the second valve 13 is provided on the first pipeline 20, the third valve 14 is provided on the third pipeline 22, and the first valve 14 is provided on the fourth pipeline 23. Four valves 15, the fifth pipeline 24 is provided with a fifth valve 16, and the insulation water tank 5 is respectively connected with the kitchen water supply pipeline 9, the bathroom water supply pipeline 10 and the floor heating heating pipeline 11 with a sixth valve 17 and a seventh valve 18 connected in series. and an eighth valve 19 .

下面结合图2所给出的太阳能吸附集供热供冷净水一体化系统的应用实例图来对本发明的具体实施方式做出进一步说明:Below in conjunction with the application example diagram of the integrated system of solar energy adsorption, heating, cooling, supply and water purification given in Fig. 2, the specific implementation of the present invention is further described:

以整个体积为2×1×0.4m3的太阳能吸附集供热供冷净水一体化系统为例:Take the integrated system of solar adsorption collection, heating, cooling, water purification and water purification as an example:

其中,集热面积为2m2,该装置为长2m,宽1m,高0.4m的不锈钢长方体,底部15cm为蒸发器,蒸发器内装有海水或者污水。Among them, the heat collecting area is 2m 2 , the device is a stainless steel cuboid with a length of 2m, a width of 1m, and a height of 0.4m. The bottom 15cm is an evaporator, and the evaporator is filled with seawater or sewage.

如图2所示,保温水箱5外部还设有保温层28,保温水箱5内装有净水。As shown in Figure 2, the insulation layer 28 is also provided outside the insulation water tank 5, and clean water is housed in the insulation water tank 5.

所述保温水箱内部还设置有温度传感器,所述温度传感器与微处理器。The interior of the heat preservation water tank is also provided with a temperature sensor, and the temperature sensor is connected with a microprocessor.

在该实施例中,保温层可采用保温材料(比如:聚氨酯泡沫)来实现。In this embodiment, the insulation layer can be realized by using insulation materials (such as polyurethane foam).

这样能够防止热量或冷量的散失,使整个吸附制冷装置有较好的保温效果。This can prevent the loss of heat or cold, so that the entire adsorption refrigeration device has a better heat preservation effect.

太阳能集热器中设置有隔热多孔材料30,其中,隔热多孔材料30设计成百叶窗的结构,夜间吸附时打开百叶窗结构,保证蒸发的水蒸气可以通过该材料流向吸附剂,白天解吸时关闭百叶窗结构,吸附剂吸收的热量不能通过该材料加热蒸发器内的水;The solar heat collector is provided with heat-insulating porous material 30, wherein the heat-insulating porous material 30 is designed as a louver structure, and the louver structure is opened during adsorption at night to ensure that evaporated water vapor can flow to the adsorbent through the material, and it is closed during desorption during the day The louver structure, the heat absorbed by the adsorbent cannot pass through the material to heat the water in the evaporator;

太阳能集热器内装有吸附剂31,其中,吸附剂为活性炭或硅胶。The solar heat collector is equipped with an adsorbent 31, wherein the adsorbent is activated carbon or silica gel.

吸附剂31上铺设有真空玻璃板32。A vacuum glass plate 32 is laid on the adsorbent 31 .

具体地,如图3所示,所述太阳能集热器内部为隔栅33结构。Specifically, as shown in FIG. 3 , the inside of the solar heat collector is a grid 33 structure.

所述太阳能集热器还包括冷却管34和孔板35。The solar heat collector also includes a cooling pipe 34 and a perforated plate 35 .

在该实施例中,将太阳能集热器内部设计成隔栅结构,使吸附剂(硅胶)受热更均匀;由于吸附剂(硅胶)吸附过程放热,该热量会使吸附剂(硅胶)温度升高,影响其吸附性能,所以在太阳能集热器内部通冷却管使吸附剂(硅胶)保持低温下吸附。In this embodiment, the interior of the solar collector is designed as a grid structure, so that the adsorbent (silica gel) is heated more evenly; due to the heat release during the adsorption process of the adsorbent (silica gel), the heat will increase the temperature of the adsorbent (silica gel). High, affecting its adsorption performance, so the cooling pipe is passed inside the solar collector to keep the adsorbent (silica gel) adsorbed at a low temperature.

太阳能吸附集制冷供热净水一体化装置工作流程:Working process of solar adsorption, cooling, heating, water purification integrated device:

当无阳光暴晒加热时,吸附剂(硅胶)在低温低压下对制冷剂(海水或者污水)进行吸附,液态的制冷剂蒸发吸热,使蒸发器内的水温度下降,实现制冷,该过程一般在夜间进行;为了使蒸发器内的海水或者污水快速蒸发,在蒸发器内放约2cm厚度的海水或者污水,同时也使制冷剂温度迅速降低,当制冷剂温度降为15℃左右时,将制冷剂移至蓄冷箱内保存待用,蒸发器内更换新的制冷剂;当有阳光暴晒的加热状态时,夜间被吸附的气态制冷剂受热解吸,为了使解吸的水蒸气快速进入冷凝器,在吸附床和冷凝器之间安装管道泵,解吸的水蒸气通过冷凝器时凝结为液体流入保温箱实现净水和制热,在冷凝器中水蒸气液化过程中放出潜热加热冷却管中的水也实现制热。When heating without sunlight exposure, the adsorbent (silica gel) adsorbs the refrigerant (sea water or sewage) at low temperature and low pressure, and the liquid refrigerant evaporates and absorbs heat, reducing the water temperature in the evaporator to achieve refrigeration. This process is generally It is carried out at night; in order to quickly evaporate the seawater or sewage in the evaporator, put seawater or sewage with a thickness of about 2cm in the evaporator, and at the same time reduce the temperature of the refrigerant rapidly. When the temperature of the refrigerant drops to about 15°C, the The refrigerant is moved to the cold storage box for storage, and the evaporator is replaced with a new refrigerant; when there is a heating state exposed to sunlight, the gaseous refrigerant adsorbed at night is desorbed by heat. In order to make the desorbed water vapor quickly enter the condenser, A pipeline pump is installed between the adsorption bed and the condenser. When the desorbed water vapor passes through the condenser, it condenses into a liquid and flows into the insulation box to realize water purification and heating. During the liquefaction process of the water vapor in the condenser, latent heat is released to heat the water in the cooling pipe. Heating is also achieved.

整个过程中海水或者污水不进行循环,连续向蒸发器内通入海水或者污水,通过吸附剂对制冷剂的吸附解吸实现净水,通过制冷剂蒸发吸热实现制冷,通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热,该装置整个运行过程实现了集供热供冷净水一体化,利用可再生清洁能源太阳能等提供能量,不对环境造成污染,实现了低品位能源的高效利用。Seawater or sewage is not circulated throughout the process, and seawater or sewage is continuously fed into the evaporator, water purification is achieved through the adsorption and desorption of the refrigerant by the adsorbent, refrigeration is achieved through the evaporation and heat absorption of the refrigerant, and heat release and desorption are achieved through the adsorption process During the liquefaction process of water vapor, the latent heat is released to realize heating. The whole operation process of the device realizes the integration of heat supply, cooling, supply and water purification, and uses renewable clean energy such as solar energy to provide energy without polluting the environment and realizes the realization of low-grade energy. Efficient use of.

图4为该发明装置应用实例的测温点示意图,T1、T2、T3分别为吸附剂中上、中、下三个位置的测温点,T4、T5为吸附剂中解吸出的水蒸气的测温点,T6、T7为蒸发器上部水蒸气的温湿度测点,T8,T9为蒸发器中水面不同高度处的测温点。Fig. 4 is the temperature measurement point schematic diagram of this invention device application example, T1, T2, T3 are respectively the temperature measurement points of upper, middle and lower three positions in the adsorbent, T4, T5 are the temperature of the water vapor desorbed in the adsorbent Temperature measurement points, T6 and T7 are temperature and humidity measurement points of water vapor in the upper part of the evaporator, T8 and T9 are temperature measurement points at different heights of the water surface in the evaporator.

本发明的如图1所示太阳能吸附集供热供冷净水一体化系统的工作方法,包括:The working method of the integrated system of solar energy adsorption, heat supply, cooling, supply and water purification as shown in Figure 1 of the present invention includes:

供冷状态:蒸发器中的制冷剂蒸发吸热实现制冷;Cooling state: the refrigerant in the evaporator evaporates and absorbs heat to achieve cooling;

供热状态:太阳能集热器内的吸附剂通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热;Heating state: The adsorbent in the solar collector releases heat through the adsorption process and releases latent heat during the desorbed water vapor liquefaction process to achieve heating;

净化状态:太阳能集热器内的吸附剂吸附蒸发器中的制冷剂,通过吸附解吸过程实现对制冷剂的净化。Purification state: The adsorbent in the solar collector absorbs the refrigerant in the evaporator, and the refrigerant is purified through the process of adsorption and desorption.

具体地,供冷状态:夜间,吸附剂(硅胶)在低温低压下对制冷剂(海水或者污水)进行吸附,液态的制冷剂蒸发吸热,使蒸发器内的水温度下降,实现制冷。Specifically, the cooling state: at night, the adsorbent (silica gel) adsorbs the refrigerant (sea water or sewage) at low temperature and low pressure, and the liquid refrigerant evaporates and absorbs heat, reducing the temperature of the water in the evaporator to achieve refrigeration.

供热状态:白天,太阳能集热器(吸附床)中有吸附饱和的吸附剂(比如:硅胶),太阳能集热器吸收太阳能为吸附床加热,温度达到吸附剂(硅胶)的解吸温度,解吸后的水蒸气被管道泵抽出进入冷凝器冷凝为高温液态水,水蒸气在冷凝过程中释放大量的汽化潜热,这部分热量加热换热管中的冷却水对外提供热水,被冷凝的高温液态水通过第四管道进入保温水箱,保温水箱通过第七管道与厨房供水管道、浴室供水管道、地暖暖气管道相连接,提供生活热水;保温水箱中安装有温度传感器,当保温水箱中温度低于预设温度(比如50℃)时,使用辅助能源(比如:生物质能)为保温水箱中的水加热。Heating state: During the day, there is saturated adsorbent (such as silica gel) in the solar collector (adsorption bed), and the solar collector absorbs solar energy to heat the adsorption bed, and the temperature reaches the desorption temperature of the adsorbent (silica gel). The final water vapor is pumped out by the pipeline pump and enters the condenser to condense into high-temperature liquid water. The water vapor releases a large amount of latent heat of vaporization during the condensation process. This part of heat heats the cooling water in the heat exchange tube to provide hot water to the outside. The condensed high-temperature liquid The water enters the thermal insulation water tank through the fourth pipeline, and the thermal insulation water tank is connected with the kitchen water supply pipeline, bathroom water supply pipeline and floor heating heating pipeline through the seventh pipeline to provide domestic hot water; a temperature sensor is installed in the thermal insulation water tank, and when the temperature in the thermal insulation water tank is lower than When the preset temperature (such as 50° C.) is used, auxiliary energy (such as: biomass energy) is used to heat the water in the heat preservation water tank.

净水状态:太阳能吸附式制冷系统有吸附和解吸过程,通过吸附剂(比如:硅胶)对吸附质(比如:海水、污水)的吸附和解吸过程实现海水淡化过程和污水净化过程,将海水、污水净化为可饮用的淡水资源,缓解了淡水和净水资源紧张的压力。Water purification state: The solar adsorption refrigeration system has an adsorption and desorption process, through the adsorption and desorption process of the adsorbent (such as: silica gel) on the adsorbate (such as: seawater, sewage) to realize the seawater desalination process and sewage purification process, the seawater, Purification of sewage into drinkable fresh water resources relieves the pressure on fresh water and clean water resources.

整个过程中水不进行循环,源源不断的向蒸发器中供应海水、污水,连续的对海水、污水进行净化;当冬季温度低于0℃时,海水、污水有可能结冰,采取将地下水引入蒸发器进行蒸发吸附,地下水的温度为恒温,一般为当地的年平均温度。该装置可实现供热供冷净水一体化,夏天制取的冷量用于制冷空调,春秋季制取的冷量可用于低温储粮系统,冬季制取的冷量可用于制冷冰箱,全年提供生活热水。In the whole process, the water does not circulate, and the seawater and sewage are continuously supplied to the evaporator, and the seawater and sewage are continuously purified; when the temperature in winter is lower than 0°C, the seawater and sewage may freeze, and the groundwater is introduced into the The evaporator performs evaporation and adsorption, and the temperature of the groundwater is constant, generally the local annual average temperature. The device can realize the integration of heating, cooling, water purification. The cold energy produced in summer can be used for refrigeration and air conditioning, the cold energy produced in spring and autumn can be used for low-temperature grain storage system, and the cold energy produced in winter can be used for refrigeration refrigerators. Annual domestic hot water supply.

上述虽然结合附图对本发明的具体实施方式进行了描述,但并非对本发明保护范围的限制,所属领域技术人员应该明白,在本发明的技术方案的基础上,本领域技术人员不需要付出创造性劳动即可做出的各种修改或变形仍在本发明的保护范围以内。Although the specific implementation of the present invention has been described above in conjunction with the accompanying drawings, it does not limit the protection scope of the present invention. Those skilled in the art should understand that on the basis of the technical solution of the present invention, those skilled in the art do not need to pay creative work Various modifications or variations that can be made are still within the protection scope of the present invention.

Claims (10)

1.一种太阳能吸附集供热供冷净水一体化系统,其特征在于,包括:太阳能集热器,其与辅助能源和管道泵分别相连通,辅助能源与保温水箱相连通,管道泵与冷凝器相连通,冷凝器还与保温水箱相连通,保温水箱与供热装置相连通,太阳能集热器还与蒸发器相连通,蒸发器与蓄冷器相连通;1. An integrated system for solar energy absorption, heat supply, cooling, water purification, characterized in that it comprises: a solar heat collector, which communicates with an auxiliary energy source and a pipeline pump respectively; The condenser is connected, the condenser is also connected with the heat preservation water tank, the heat preservation water tank is connected with the heating device, the solar heat collector is also connected with the evaporator, and the evaporator is connected with the cold storage device; 其中,太阳能集热器内装设有吸附剂,其用于吸附蒸发器中的制冷剂,通过吸附解吸过程实现对制冷剂的净化;蒸发器中的制冷剂蒸发吸热实现制冷;太阳能集热器内的吸附剂通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热。Among them, the solar collector is equipped with an adsorbent, which is used to absorb the refrigerant in the evaporator, and realize the purification of the refrigerant through the process of adsorption and desorption; the refrigerant in the evaporator evaporates and absorbs heat to achieve refrigeration; the solar collector The adsorbent in the adsorption process releases heat through the adsorption process and releases latent heat during the desorption process of water vapor liquefaction to achieve heat generation. 2.如权利要求1所述的一种太阳能吸附集供热供冷净水一体化系统,其特征在于,所述吸附剂上铺设有真空玻璃板。2 . The integrated system of solar adsorption, heating, cooling, supply and water purification according to claim 1 , wherein a vacuum glass plate is laid on the adsorbent. 3 . 3.如权利要求1所述的一种太阳能吸附集供热供冷净水一体化系统,其特征在于,所述太阳能集热器内部为隔栅结构。3 . The integrated system of solar adsorption, heating, cooling, supply and water purification according to claim 1 , wherein the interior of the solar heat collector is a grid structure. 4 . 4.如权利要求1所述的一种太阳能吸附集供热供冷净水一体化系统,其特征在于,所述保温水箱外部还设有保温层。4 . The integrated system of solar energy absorption, heating, cooling, supply, and water purification according to claim 1 , wherein an insulation layer is provided outside the insulated water tank. 5 . 5.如权利要求1所述的一种太阳能吸附集供热供冷净水一体化系统,其特征在于,所述保温水箱内部还设置有温度传感器,所述温度传感器与微处理器。5 . The integrated system of solar adsorption, heating, cooling, supply, and water purification according to claim 1 , wherein a temperature sensor is also arranged inside the thermal insulation water tank, and the temperature sensor is connected with a microprocessor. 6 . 6.如权利要求1所述的一种太阳能吸附集供热供冷净水一体化系统,其特征在于,所述供热装置包括厨房供水管道、浴室供水管道和地暖暖气管道。6 . The integrated system of solar energy adsorption collection, heat supply, cooling, supply and water purification according to claim 1 , wherein the heating device includes kitchen water supply pipes, bathroom water supply pipes and floor heating pipes. 6 . 7.一种基于如权利要求1-6所述的太阳能吸附集供热供冷净水一体化系统的工作方法,其特征在于,包括:7. A working method based on the integrated system of solar energy adsorption, heat, supply, cooling, supply and water purification as claimed in claim 1-6, characterized in that it comprises: 供冷状态:蒸发器中的制冷剂蒸发吸热实现制冷;Cooling state: the refrigerant in the evaporator evaporates and absorbs heat to achieve cooling; 供热状态:太阳能集热器内的吸附剂通过吸附过程放热和解吸的水蒸气液化过程中释放潜热实现制热;Heating state: The adsorbent in the solar collector releases heat through the adsorption process and releases latent heat during the desorbed water vapor liquefaction process to achieve heating; 净化状态:太阳能集热器内的吸附剂吸附蒸发器中的制冷剂,通过吸附解吸过程实现对制冷剂的净化。Purification state: The adsorbent in the solar collector absorbs the refrigerant in the evaporator, and the refrigerant is purified through the process of adsorption and desorption. 8.如权利要求7所述的太阳能吸附集供热供冷净水一体化系统的工作方法,其特征在于,在供冷状态下,此时太阳能达不到预设值或夜间,太阳能集热器的温度降低,吸附剂开始吸附蒸发器中的制冷剂,太阳能集热器中的吸附剂吸附制冷剂后放出吸附热使吸附床内冷却水温度升高来对外供热;8. The working method of the integrated system of solar energy adsorption, heating, cooling, supplying, cooling and water purification as claimed in claim 7, characterized in that, in the state of cooling, when the solar energy does not reach the preset value or at night, the solar heat collecting As the temperature of the device decreases, the adsorbent begins to adsorb the refrigerant in the evaporator, and the adsorbent in the solar collector absorbs the refrigerant and releases the heat of adsorption to increase the temperature of the cooling water in the adsorption bed to supply heat to the outside; 蒸发器中的吸附质在蒸发过程从环境中吸收大量热量,实现制冷过程;蓄冷器还储存部分冷量以供白天使用。The adsorbate in the evaporator absorbs a large amount of heat from the environment during the evaporation process to realize the refrigeration process; the cold storage also stores part of the cold energy for use during the day. 9.如权利要求7所述的太阳能吸附集供热供冷净水一体化系统的工作方法,其特征在于,在供热状态下,太阳能集热器中有吸附饱和的吸附剂,太阳能集热器吸收太阳能为吸附床加热,温度达到吸附剂的解吸温度,解吸后的水蒸气被管道泵抽出进入冷凝器冷凝为高温液态水,水蒸气在冷凝过程中释放大量的潜热,这部分热量加热换热管中的冷却水对外提供热水,被冷凝的高温液态水进入保温水箱,保温水箱为供热装置提供净化热水。9. The working method of the integrated system of solar energy adsorption, heat supply, cooling, water purification as claimed in claim 7, characterized in that, in the heating state, there is an adsorbent with saturated adsorption in the solar heat collector, and the solar heat collection The absorber absorbs solar energy to heat the adsorption bed, and the temperature reaches the desorption temperature of the adsorbent. The desorbed water vapor is pumped out by the pipeline pump and enters the condenser to condense into high-temperature liquid water. The water vapor releases a large amount of latent heat during the condensation process. This part of heat is heated and exchanged The cooling water in the heat pipe provides hot water to the outside, and the condensed high-temperature liquid water enters the heat preservation water tank, and the heat preservation water tank provides purified hot water for the heating device. 10.如权利要求8所述的太阳能吸附集供热供冷净水一体化系统的工作方法,其特征在于,在供热状态下,当保温水箱中温度低于预设温度时,使用辅助能源为保温水箱中的水加热。10. The working method of the integrated system of solar energy adsorption, heat supply, cooling, water purification as claimed in claim 8, characterized in that, in the heating state, when the temperature in the heat preservation water tank is lower than the preset temperature, the auxiliary energy is used To heat the water in the insulated tank.
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