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CN107459965A - A kind of Environment-friendlyadhesive adhesive - Google Patents

A kind of Environment-friendlyadhesive adhesive Download PDF

Info

Publication number
CN107459965A
CN107459965A CN201710814154.8A CN201710814154A CN107459965A CN 107459965 A CN107459965 A CN 107459965A CN 201710814154 A CN201710814154 A CN 201710814154A CN 107459965 A CN107459965 A CN 107459965A
Authority
CN
China
Prior art keywords
parts
fire retardant
environment
accelerator
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710814154.8A
Other languages
Chinese (zh)
Inventor
郑小斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong He Sheng Garden Ancient Construction Engineering Co Ltd
Original Assignee
Nantong He Sheng Garden Ancient Construction Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong He Sheng Garden Ancient Construction Engineering Co Ltd filed Critical Nantong He Sheng Garden Ancient Construction Engineering Co Ltd
Priority to CN201710814154.8A priority Critical patent/CN107459965A/en
Publication of CN107459965A publication Critical patent/CN107459965A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00Adhesives based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Building Environments (AREA)

Abstract

A kind of Environment-friendlyadhesive adhesive, its innovative point are:Its main component has isocyanates, fire retardant, modified polydialkysiloxane, polyurethane prepolymer, resin, silicic acid, siloxane oligomer, accelerator and crosslinking agent;Its quality parts ratio is:35 parts of 35 parts of isocyanates, 35 parts of fire retardant, modified 5 10 parts of polydialkysiloxane, 6 10 parts of polyurethane prepolymer, 5 20 parts of resin, 58 parts of silicic acid, 35 parts of siloxane oligomer, 13 parts of accelerator and crosslinking agent.Advantages of the present invention is:The present invention adds the coordination synergistic effect between raw material, the adhesive of preparation is almost tasteless, applied widely, and is formulated simply, and preparation method is simple, is easy to grasp by adjusting the proportioning between each raw material.

Description

A kind of Environment-friendlyadhesive adhesive
Technical field
The invention belongs to field of material technology, and in particular to a kind of Environment-friendlyadhesive adhesive.
Background technology
Adhesive is one of most important auxiliary material, it is however generally that, adhesive is (also referred to as " pressure-sensitive adhesive ".) In the state of soft solid (viscoelastic body) within the temperature range of near room temperature, have easily gluing using pressure In the property of adherend.Wherein, acrylic adhesives are compared with rubber adhesive, generally light resistance, weatherability, oil resistant Property etc. it is excellent, therefore using acrylic adhesives in various fields in order to engage, it is fixed the purpose of and widely use.Bonding Agent is defined as can be by surface bonding and the nonmetallic materials of internal intensity combination adherend.Adhesive is the sticking thing of tool Matter, the material of two kinds of separation being linked together by its viscosity, the species of adhesive is a lot, existing adhesive smell weight, Containing noxious material, bonding effect is poor, and bonding article is single, is made troubles for industry and family etc..
The content of the invention
Glued in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide a kind of environmental protection tasteless, that use range is wide Mixture.
In order to solve the above technical problems, the technical scheme is that:A kind of Environment-friendlyadhesive adhesive, its innovative point are: Its main component has isocyanates, fire retardant, modified polydialkysiloxane, polyurethane prepolymer, resin, silicic acid, siloxanes Oligomer, accelerator and crosslinking agent;Its quality parts ratio is:Isocyanates 3-5 parts, fire retardant 3-5 parts, modified poly-diakyl silicon Oxygen alkane 5-10 parts, polyurethane prepolymer 6-10 parts, resin 5-20 parts, silicic acid 5-8 parts, siloxane oligomer 3-5 parts, accelerator 1- 3 parts and crosslinking agent 3-5 parts.
Further, a kind of Environment-friendlyadhesive adhesive, its quality parts ratio are:4 parts of isocyanates, 4 parts of fire retardant are modified poly- 8 parts of dialkylsiloxane, 8 parts of polyurethane prepolymer, 15 parts of resin, 6 parts of silicic acid, 4 parts of siloxane oligomer, 2 parts of accelerator and 4 parts of crosslinking agent.
Further, the fire retardant is one kind in tetrabromobutane, tetrabromobisphenol A or fire retardant DPA.
Advantages of the present invention is:By adjusting the proportioning between each raw material, the coordination added between raw material increases the present invention Effect acts on, and the adhesive of preparation is almost tasteless, applied widely, and is formulated simply, and preparation method is simple, is easy to grasp.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of Environment-friendlyadhesive adhesive, its quality parts ratio are:3 parts of isocyanates, 4 parts of fire retardant, modified polydialkysiloxane 7 4 parts of part, 8 parts of polyurethane prepolymer, 16 parts of resin, 6 parts of silicic acid, 4 parts of siloxane oligomer, 2 parts of accelerator and crosslinking agent.
Embodiment 2
A kind of Environment-friendlyadhesive adhesive, its quality parts ratio are:5 parts of isocyanates, 4 parts of fire retardant, modified polydialkysiloxane 7 4 parts of part, 8 parts of polyurethane prepolymer, 10 parts of resin, 7 parts of silicic acid, 4 parts of siloxane oligomer, 3 parts of accelerator and crosslinking agent.
Embodiment 3
A kind of Environment-friendlyadhesive adhesive, its quality parts ratio are:4 parts of isocyanates, 5 parts of fire retardant, modified polydialkysiloxane 9 5 parts of part, 8 parts of polyurethane prepolymer, 12 parts of resin, 7 parts of silicic acid, 5 parts of siloxane oligomer, 2 parts of accelerator and crosslinking agent.
Embodiment 4
A kind of Environment-friendlyadhesive adhesive, its quality parts ratio are:3 parts of isocyanates, 4 parts of fire retardant, modified polydialkysiloxane 7 4 parts of part, 9 parts of polyurethane prepolymer, 14 parts of resin, 8 parts of silicic acid, 4 parts of siloxane oligomer, 2 parts of accelerator and crosslinking agent.
The present invention adds the coordination synergistic effect between raw material, preparation is glued by adjusting the proportioning between each raw material Mixture is almost tasteless, applied widely, and is formulated simply, and preparation method is simple, is easy to grasp.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention Rights protection scope in.

Claims (3)

  1. A kind of 1. Environment-friendlyadhesive adhesive, it is characterised in that:Its main component has isocyanates, fire retardant, modified poly-diakyl silicon Oxygen alkane, polyurethane prepolymer, resin, silicic acid, siloxane oligomer, accelerator and crosslinking agent;Its quality parts ratio is:Isocyanic acid Ester 3-5 parts, fire retardant 3-5 parts, modified polydialkysiloxane 5-10 parts, polyurethane prepolymer 6-10 parts, resin 5-20 parts, silicon Sour 5-8 parts, siloxane oligomer 3-5 parts, accelerator 1-3 parts and crosslinking agent 3-5 parts.
  2. A kind of 2. Environment-friendlyadhesive adhesive according to claim 1, it is characterised in that:A kind of Environment-friendlyadhesive adhesive, its quality Portion rate is:4 parts of isocyanates, 4 parts of fire retardant, modified 8 parts of polydialkysiloxane, 8 parts of polyurethane prepolymer, resin 15 4 parts of part, 6 parts of silicic acid, 4 parts of siloxane oligomer, 2 parts of accelerator and crosslinking agent.
  3. A kind of 3. Environment-friendlyadhesive adhesive according to claim 1, it is characterised in that:The fire retardant is tetrabromobutane, four One kind in bromine bisphenol-A or fire retardant DPA.
CN201710814154.8A 2017-09-11 2017-09-11 A kind of Environment-friendlyadhesive adhesive Pending CN107459965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710814154.8A CN107459965A (en) 2017-09-11 2017-09-11 A kind of Environment-friendlyadhesive adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710814154.8A CN107459965A (en) 2017-09-11 2017-09-11 A kind of Environment-friendlyadhesive adhesive

Publications (1)

Publication Number Publication Date
CN107459965A true CN107459965A (en) 2017-12-12

Family

ID=60552147

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710814154.8A Pending CN107459965A (en) 2017-09-11 2017-09-11 A kind of Environment-friendlyadhesive adhesive

Country Status (1)

Country Link
CN (1) CN107459965A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993521A (en) * 2009-08-19 2011-03-30 赢创高施米特有限公司 Curable material comprising silylated polymers containing urethane groups, and use thereof in sealants and binders
CN101225173B (en) * 2007-01-17 2013-01-02 拜尔材料科学有限公司 Polyether-polysiloxane polyols
CN106318311A (en) * 2016-08-24 2017-01-11 张勇健 Adhesives

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101225173B (en) * 2007-01-17 2013-01-02 拜尔材料科学有限公司 Polyether-polysiloxane polyols
CN101993521A (en) * 2009-08-19 2011-03-30 赢创高施米特有限公司 Curable material comprising silylated polymers containing urethane groups, and use thereof in sealants and binders
CN106318311A (en) * 2016-08-24 2017-01-11 张勇健 Adhesives

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Application publication date: 20171212