CN107419866A - A kind of Dali stone ceramic tile with antibacterial functions - Google Patents
A kind of Dali stone ceramic tile with antibacterial functions Download PDFInfo
- Publication number
- CN107419866A CN107419866A CN201710472526.3A CN201710472526A CN107419866A CN 107419866 A CN107419866 A CN 107419866A CN 201710472526 A CN201710472526 A CN 201710472526A CN 107419866 A CN107419866 A CN 107419866A
- Authority
- CN
- China
- Prior art keywords
- antibacterial functions
- layer
- ceramic tile
- antibacterial
- dali stone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 48
- 239000000919 ceramic Substances 0.000 title claims abstract description 24
- 239000004575 stone Substances 0.000 title claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 24
- 230000003115 biocidal effect Effects 0.000 claims abstract description 24
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 15
- 230000000694 effects Effects 0.000 claims abstract description 8
- 239000011449 brick Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 230000000845 anti-microbial effect Effects 0.000 abstract description 5
- 230000001408 fungistatic effect Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 206010068052 Mosaicism Diseases 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000035568 catharsis Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000003013 cytotoxicity Effects 0.000 description 1
- 231100000135 cytotoxicity Toxicity 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 210000003765 sex chromosome Anatomy 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to architectural pottery field, more particularly to a kind of Dali stone ceramic tile with antibacterial functions.Include green body layer, intermediate layer, antibacterial functions layer successively from down to up；Nano anti-biotic material is evenly distributed with the antibacterial functions layer；The nano anti-biotic material is a kind of high-activity nano zinc oxide particles.The present invention is by the way that single high-activity nano zinc oxide particles are added in ceramic tile top layer, on the premise of product conventional physico-chemical properties are not influenceed, products obtained therefrom has stronger fungistatic effect in the case where there is light no light condition, antibiotic rate can reach more than 95%, and antibacterial durability test also meets relevant criterion requirement, has the advantages that non-discolouring, nontoxic, anti-microbial property is persistently reliable.
Description
Technical field
The invention belongs to architectural pottery field, more particularly to a kind of Dali stone ceramic tile with antibacterial functions.
Background technology
With the development and the improvement of people's living standards of society, requirement of the people for ceramic tile has been not content with simply
Fitting-up purposes, therefore the tile product of various additional functions is also increasing, and antibiotic ceramic tile also arises at the historic moment.Antibacterial
Ceramic tile is by the way that antibiotic effective ingredient to be added to the one kind for being allowed to increase antibacterial effect on the basis of original in tile product
Tile product.
The antiseptic that current antibiotic ceramic tile is selected is mostly silver-series antibacterial agent and photocatalyst-type anti-biotic agent, and silver-series antibacterial agent is more
Sintered to be added in ceramic tile blank or glaze together with ceramic tile, photocatalyst-type anti-biotic agent is led to due to the physicochemical property of its own
The mode of often selection spraying plated film is combined with ceramic tile, and the anti-microbial property of the two is more prominent, but for tile product, silver
The problems such as cost is high, easy to change, anti-microbial property is unstable, lacks to the sign of silver nano material stability be present in series antibacterial agent,
And with TiO2For the photocatalyst-type anti-biotic agent of representative, difficult degradation strong to ultraviolet light dependence, inconvenience recovery, plated film to be then present weather-proof
There is higher cytotoxicity after sex chromosome mosaicism, UV irradiations.
Active oxidation species anti-biotic material possesses good biocompatibility, security and long-term effect, increasingly by
Favor.Research for activating oxide anti-biotic material, people are concerned with zinc oxide at first（ZnO）, calcium oxide, magnesia
For the activating oxide of representative, it is found that they all have a good antibiotic property, in addition low concentration oxide in no light condition
Under also show excellent anti-microbial property.ZnO is a kind of broad stopband group Ⅱ-Ⅵ compound semiconductor material, is had regular
Hexagonal wurtzite structure, as white, stability is good for this, non-discolouring under high temperature, do not decompose, be cheap, aboundresources, oneself
One of focus as inorganic antiseptic research.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of Dali stone ceramic tile with antibacterial functions.
Technical solution of the present invention is as follows：
A kind of Dali stone ceramic tile with antibacterial functions, include green body layer, intermediate layer, antibacterial functions layer successively from down to up.
The intermediate layer is cover coat, and the antibacterial functions layer is protection glaze layer.
The intermediate layer is ground glaze layer, and the antibacterial functions layer is throwing glaze layer.
The intermediate layer is polished bricks precoat, and the antibacterial functions layer is super clean bright layers.
Nano anti-biotic material is evenly distributed with the antibacterial functions layer.
The nano anti-biotic material is a kind of high-activity nano zinc oxide particles.
Adding proportion of the nano anti-biotic material in the antibacterial functions layer is 3 ~ 10wt%.
The particle diameter of the nano zinc oxide particles is 5 ~ 40nm.
Compared with prior art, beneficial effect is the present invention：By the way that single high-activity nano zinc oxide particles are added
Into ceramic tile top layer, on the premise of product conventional physico-chemical properties are not influenceed, products obtained therefrom have in the case where there is light no light condition compared with
Strong fungistatic effect, antibiotic rate can reach more than 95%, and antibacterial durability test also meets relevant criterion requirement, have it is non-discolouring,
Nontoxic, the advantages that anti-microbial property is persistently reliable；Specific far-infrared transmitting function and photocatalytic activity, its normal emittance reach simultaneously
85% ~ 90%, there is catharsis for gaseous contaminants such as formaldehyde, toluene, ammonia, TVOC.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fig. 1 is the structural representation of the present invention.
Wherein, 1, green body layer；2nd, intermediate layer；3rd, antibacterial functions layer；4th, nano anti-biotic material.
Embodiment
The invention will now be described in further detail with reference to the accompanying drawings.
Embodiment 1：
A kind of marble with antibacterial functions ceramic tile modelled after an antique as shown in Figure 1, include green body layer 1, centre successively from down to up
Layer 2, antibacterial functions layer 3；The intermediate layer 2 is cover coat, and antibacterial functions layer 3 is protection glaze layer；It is uniformly distributed in protection glaze layer
There is nano anti-biotic material 4；The nano anti-biotic material 4 is a kind of high-activity nano zinc oxide particles；The nano anti-biotic material 4
Adding proportion in the antibacterial functions layer 3 is 6 ~ 8wt%；The particle diameter of the nano zinc oxide particles is 5 ~ 40nm.
Embodiment 2：
A kind of marble with antibacterial functions as shown in Figure 1 throws vitreous brick entirely, from down to up successively including green body layer 1, in
Interbed 2, antibacterial functions layer 3；The intermediate layer 2 is ground glaze layer, and antibacterial functions layer 3 is throwing glaze layer；In the antibacterial functions layer 3
It is even that nano anti-biotic material 4 is distributed with；The nano anti-biotic material 4 is a kind of high-activity nano zinc oxide particles；The nanometer resists
Adding proportion of the bacterium material 4 in the antibacterial functions layer 3 is 3 ~ 6wt%；The particle diameter of the nano zinc oxide particles be 5 ~
40nm。
Embodiment 3：
A kind of Dali polished glazed tile with antibacterial functions as shown in Figure 1, include green body layer 1, intermediate layer successively from down to up
2nd, antibacterial functions layer 3；The intermediate layer 2 is polished bricks precoat, and antibacterial functions layer 3 is super clean bright layers；The antibacterial functions layer 3
In be evenly distributed with nano anti-biotic material 4；The nano anti-biotic material 4 is a kind of high-activity nano zinc oxide particles；It is described to receive
Adding proportion of the nano antibacterial material 4 in the antibacterial functions layer 3 is 8 ~ 10wt%；The particle diameter of the nano zinc oxide particles is 5
~40nm。
The foregoing description of the disclosed embodiments, professional and technical personnel in the field are enable to realize or using the present invention,
General Principle defined herein can be realized in other embodiments without departing from the spirit or scope of the present invention.
The scope of the present invention is limited by claim and its equivalent.
Claims (8)
- A kind of 1. Dali stone ceramic tile with antibacterial functions, it is characterised in that：Include green body layer successively from down to up（1）, it is middle Layer（2）, antibacterial functions layer（3）.
- 2. the Dali stone ceramic tile according to claim 1 with antibacterial functions, it is characterised in that：The intermediate layer（2）For Cover coat, the antibacterial functions layer（3）To protect glaze layer.
- 3. the Dali stone ceramic tile according to claim 1 with antibacterial functions, it is characterised in that：The intermediate layer（2）For Ground glaze layer, the antibacterial functions layer（3）To throw glaze layer.
- 4. the Dali stone ceramic tile according to claim 1 with antibacterial functions, it is characterised in that：The intermediate layer（2）For Polished bricks precoat, the antibacterial functions layer（3）For super clean bright layers.
- 5. according to any described Dali stone ceramic tiles with antibacterial functions of claim 1-4, it is characterised in that：The antibacterial work( Ergosphere（3）In be evenly distributed with nano anti-biotic material（4）.
- 6. the Dali stone ceramic tile according to claim 5 with antibacterial functions, it is characterised in that：The nano anti-biotic material （4）For a kind of high-activity nano zinc oxide particles.
- 7. the Dali stone ceramic tile according to claim 5 with antibacterial functions, it is characterised in that：The nano anti-biotic material （4）In the antibacterial functions layer（3）In adding proportion be 3 ~ 10wt%.
- 8. the Dali stone ceramic tile according to claim 6 with antibacterial functions, it is characterised in that：The nano oxidized zinc granule The particle diameter of son is 5 ~ 40nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472526.3A CN107419866A (en) | 2017-06-21 | 2017-06-21 | A kind of Dali stone ceramic tile with antibacterial functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472526.3A CN107419866A (en) | 2017-06-21 | 2017-06-21 | A kind of Dali stone ceramic tile with antibacterial functions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107419866A true CN107419866A (en) | 2017-12-01 |
Family
ID=60427226
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710472526.3A Pending CN107419866A (en) | 2017-06-21 | 2017-06-21 | A kind of Dali stone ceramic tile with antibacterial functions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107419866A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109279918A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of sheen brick and preparation method thereof |
| CN109956705A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method with antibacterial and anion coating |
| CN110002794A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method with antibacterial effect |
| CN110002795A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of layering generates the antibacterial quartz and preparation method of anion |
| CN112645740A (en) * | 2020-12-23 | 2021-04-13 | 常州北化澳联环保科技有限公司 | Preparation method of anti-skid antibacterial ceramic tile |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2614234Y (en) * | 2003-04-13 | 2004-05-05 | 张元跃 | Nanometer antibiotic ceramic tile |
| CN201292634Y (en) * | 2008-09-22 | 2009-08-19 | 信益陶瓷(中国)有限公司 | Antibiotic ceramic tile |
| CN104876586A (en) * | 2015-04-20 | 2015-09-02 | 福罗尼陶瓷有限公司 | Production method of novel ceramic tile |
-
2017
- 2017-06-21 CN CN201710472526.3A patent/CN107419866A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2614234Y (en) * | 2003-04-13 | 2004-05-05 | 张元跃 | Nanometer antibiotic ceramic tile |
| CN201292634Y (en) * | 2008-09-22 | 2009-08-19 | 信益陶瓷(中国)有限公司 | Antibiotic ceramic tile |
| CN104876586A (en) * | 2015-04-20 | 2015-09-02 | 福罗尼陶瓷有限公司 | Production method of novel ceramic tile |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109279918A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of sheen brick and preparation method thereof |
| CN109956705A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method with antibacterial and anion coating |
| CN110002794A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method with antibacterial effect |
| CN110002795A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of layering generates the antibacterial quartz and preparation method of anion |
| CN112645740A (en) * | 2020-12-23 | 2021-04-13 | 常州北化澳联环保科技有限公司 | Preparation method of anti-skid antibacterial ceramic tile |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210923 Address after: 215300 Jinying international 2802-2810, No. 199, Zhujiang Middle Road, Kunshan Development Zone, Suzhou City, Jiangsu Province Applicant after: Seagull champion Ltd. Address before: 215301 No. 8, Yuanfeng Road, Kunshan City, Suzhou City, Jiangsu Province Applicant before: Sinyih Ceramic (China) Co.,Ltd. Applicant before: XINYI CERAMICS (PENGLAI) Co.,Ltd. Applicant before: CHAMPION BUILDING MATERIAL (ANHUI) Co.,Ltd. |
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| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171201 |
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| RJ01 | Rejection of invention patent application after publication |