CN107376185A - A kind of micro-nano fire extinguishing capsule and preparation method - Google Patents
A kind of micro-nano fire extinguishing capsule and preparation method Download PDFInfo
- Publication number
- CN107376185A CN107376185A CN201610326639.8A CN201610326639A CN107376185A CN 107376185 A CN107376185 A CN 107376185A CN 201610326639 A CN201610326639 A CN 201610326639A CN 107376185 A CN107376185 A CN 107376185A
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0021—Microcapsules
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0092—Gaseous extinguishing substances, e.g. liquefied gases, carbon dioxide snow
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention discloses a kind of micro-nano fire extinguishing capsule, the formula is made up of according to parts by weight the following raw material：10 50 parts of extinguishing chemical, 25 parts of covering material, 0.1 1 parts of organic silicone oil, 15 parts of nano-scale white carbon black,（1）Gas extinguishing agent and covering material are well mixed under 3Mpa pressure；（2）Organic silicone oil and nano-scale white carbon black are sequentially added；（3）Load packaging after stirring and obtain finished product.The present invention is with the main material of gas extinguishing agent, and extinguishing chemical and microcapsules are sufficiently mixed and add other auxiliary materials by other materials of absorption that can be stablized using microcapsules and the characteristics of beneficial to preserving.To solve the storage of extinguishing chemical and transportation problem, while synthesis the advantages of powder extinguishing agent and gas extinguishing agent is reached to the purpose for improving fire extinguishing effectiveness.
Description
Technical field
The present invention relates to a kind of micro-nano capsule extinguishing chemical, and in particular to coating, rubber slab field specially go out electric information fire
A kind of micro-nano fire extinguishing capsule and preparation method.
Background technology
The fire moment threaten country and people the securities of the lives and property, fire again often because live combustible not
Together, the complicated multifactor fire of a condition of a fire is developed into by single cause.
Extinguishing chemical is to refer to effectively destroy burning condition in combustion zone, reaches the thing for resisting burning or extinction
Matter.Extinguishing chemical species is more such as, water-based extinguishing agent, gas extinguishing agent, fire foam, powder extinguishing agent etc..
Although powder extinguishing agent low cost, simple production process, dust pollution is seriously to human body and one in fire extinguishing procedure
A little goods and materials have certain infringement, also without cooling and usage amount ratio when effect and the fire extinguishing of anti-resume combustion as gas extinguishing agent
It is larger.
Fire foam is mainly used in putting out non-water-soluble liquid fire, and mainly fire brigade is using.
Although water-based extinguishing agent fire extinguishing effectiveness is higher, blow-off velocity is fast, is not easy resume combustion, there is also for being not used to
Electrical fire is puted out a fire to save life and property.
So a storage of research and development is convenient, is had using the high appliance fire extinguishing chemical that specially goes out of simple, safety, fire extinguishing effectiveness
Important meaning.
For problem above, the invention provides a kind of micro-nano fire extinguishing capsule and preparation method, with gas extinguishing agent and
Microcapsule coated material is main material, controls high pressure production equipment using hyundai electronicses, solves existing all kinds of extinguishing chemicals and using
In run into electric information fire pollution or damage problem.
The content of the invention
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of micro-nano fire extinguishing capsule, the formula are made up of according to parts by weight the following raw material
Gas extinguishing agent 10-50 parts, covering material 2-5 parts, organic silicone oil 0.1-1 parts, nano-scale white carbon black 1-5 parts.
According to above-mentioned technical formula, described gas extinguishing agent is difluorodibromomethane, difluorochlobromo-methane, trifluoro
One or more in one bromomethane, dibromotetrafluoromethane, trifluoro propane, HFC-236fa, heptafluoro-propane, IG541.
According to above-mentioned technical formula, described covering material is methyl methacrylate, Methyl Methacrylate, 2- first
Base -2- methyl acrylates, polymethacrylates, methylmethacrylate, methyl methacrylate, methyl lose resin acid methyl esters, first
One or more in base methyl acrylate (MMA), Methyl metacrylate 99.
According to above-mentioned technical formula, described organic silicone oil is hydrophobic type organic silicone oil.
According to above-mentioned technical formula, described nano-scale white carbon black is gas-phase silica of the diameter in 50-100nm.
The other present invention have also been devised a kind of preparation method of micro-nano fire extinguishing capsule, comprise the following steps：
（1）Gas extinguishing agent and covering material are well mixed under 3Mpa pressure；
（2）Organic silicone oil and nano-scale white carbon black are sequentially added；
（3）Load packaging after stirring and obtain finished product.
The present invention can be used for a nanometer self-extinguishing film, filling fire extinguisher, automatic fire extinguisher, fire extinguishing coating, automatic
The medium use of fire extinguishing system, application place mainly includes：1：Electronics, communication place, such as the microwave machine in radio and television launching tower
Room, decimetric wave computer room, changed into switchhouse.The programme-controlled exchange computer room of telecommunications, Signalling Transfer Point room.According to carbon-dioxide fire engine, when
During sparging carbon dioxide so that ambient temperature substantially reduces, and the condensate moisture in air, turns into extremely dense water smoke, to high
It is serious caused by expensive electronic equipment to be stained, carbon dioxide and carbonic acid are dissolved in water, in computer room, communications equipment room
Integrated stamen piece, circuit have considerable influence, and can make electric equipment surface produce accumulation of static electricity.The present invention have to protection without
Mansion is lost, and certain protective effect is played for valuable, accurate instrument.And the present invention do not decompose at normal temperatures, be non-hygroscopic,
Do not lump.It is easy to deposit for a long time, and noresidue after fire extinguishing, it is of the invention in addition that also there is good mobility, dispersivity and electricity
Insulating properties, when a fire, the present invention will not cause the short circuit of electric equipment, and the generation of fire fighter's electric shock accidents.
2nd, can be in the non-renewable resources such as cultural heritage, finance data place, the collection in such as national, provincial library, archives
Treasure storehouse in storehouse, museum；The showroom of one-level paper thin,tough silk matter historical relic；The archive office of financial department, bill room, important money
Expect room and press center；Between the expensive facility in larger medical place etc..Water mists also cause while fire extinguishing to protection
Irremediable loss.Historical relic legacy is therefore a kind of single, non-renewable resource applies the present invention to go out in selection
During main material of being put out a fire in fiery system, it can accomplish that good extinguishing effect, blow-off velocity are fast, not have corrosion to historical relic legacy and destroy, have
Preserved beneficial to the long-term safety of historical relic.The present invention is a kind of new production for being different from common dry powder, foam, gas extinguishing agent completely
Product, through national departments concerned detection and it is substantial amounts of it is demonstrated experimentally that the extinguishing chemical it is corrosion-free to historical relic legacy, without destroy, without resume combustion
Deng effect.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, the present invention is carried out with reference to embodiments
It is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit
The present invention.
Embodiment 1：
The preparation method of the micro-nano fire extinguishing capsule, comprises the following steps：
（1）45 parts of heptafluoro-propanes and 3 parts of methyl methacrylates are mixed in the case where continuing the 3Mpa pressure of 1 hour
It is even；
（2）0.2 part of organic silicone oil and 2 parts of nano-scale white carbon blacks are sequentially added；
（3）Load packaging after stirring and obtain finished product.
Embodiment 2：
The preparation method of the micro-nano fire extinguishing capsule, comprises the following steps：
（1）50 parts of IG541 and 3.5 part of 2- methyl -2- methyl acrylates are mixed in the case where continuing the 3Mpa pressure of 1 hour
Uniformly；
（2）0.25 part of organic silicone oil and 2.5 parts of nano-scale white carbon blacks are sequentially added；
（3）Load packaging after stirring and obtain finished product.
Embodiment 3：
The preparation method of the micro-nano fire extinguishing capsule, comprises the following steps：
（1）By 40 parts of difluorochlobromo-methanes and 2 parts of Methyl Methacrylates the 3Mpa for continuing 1 hour pressure
It is lower well mixed；
（2）0.2 part of organic silicone oil and 2 parts of nano-scale white carbon blacks are sequentially added；
（3）Load packaging after stirring and obtain finished product.
Specifically：
The present invention relates to a kind of micro-nano capsule extinguishing chemical, and in particular to coating, rubber slab field specially go out electric information fire
A kind of micro-nano fire extinguishing capsule and preparation method.
Fluorine ion in the fire extinguishing agent molecule that micro-nano fire extinguishing capsule of the present invention contains contributes to the heat of extinguishing chemical
Stability and chemical inertness, bromide ion are then active ingredient of the extinguishing chemical in fire extinguishing procedure.The fire-fighting principle of extinguishing chemical, mainly
It is that bromide ion destruction fuel produces hydrionic chain chemical reaction in combustion, interrupts burning and reach the mesh of fire extinguishing
, by suppressing the chemical reaction process of burning, make flameout, effect is by the activity in combustion chain reaction of taking away
For material come what is completed, this process is referred to as chain breaking process and process of inhibition, similar to powder extinguishing agent effect.And have simultaneously
The physical action of cooling and the cooling of water system and fire foam.Suitable for put out a fire to save life and property various inflammable, combustible liquid fires and electrically
Equipment fire.
Mainly put out a fire in numerous extinguishing chemicals by two ways, first, by starvation come the physics side of fire smothering
Formula.Second, the chemical mode for making caused free radical be far smaller than the free radical to burn by cutting off pyric chain.Capsule of the present invention
Core extinguishing chemical unit volume fire-fighting efficiency is 1.5 times of other species extinguishing chemicals, and capsule core extinguishing chemical of the present invention contains in addition
There is 40% physics fire-extinguishing function concurrently, 60% is chemical mode fire extinguishing, is the optimal combination in extinguishing chemical, therefore in all extinguishing chemicals
Extinguishing effect be best.
Gas extinguishing agent be difluorodibromomethane, difluorochlobromo-methane, BTM, dibromotetrafluoromethane,
One or more in trifluoro propane, HFC-236fa, heptafluoro-propane, IG541.Above gas extinguishing agent is equal in fire extinguishing procedure
Noresidue is produced, and any physics and damage chemically will not be produced to the electrical and electronic component, antiques, ancient books of scene of fire
It is bad.
Covering material is methyl methacrylate, Methyl Methacrylate, 2- methyl -2- methyl acrylates, isobutene
Sour methyl esters, methyl lose the one or more in resin acid methyl esters, methyl methacrylate (MMA), Methyl metacrylate 99.It is more than use
The microcapsules with polymeric shell wall can by liquid or gas entrapment, seal up for safekeeping and turn into a kind of solia particle in microencapsulation
Product.So that gaseous state or the extinguishing chemical of liquid form the solid-state for being easier to store and carrying.
Organic silicone oil is hydrophobic type organic silicone oil, and hydrophobic type organic silicone oil can make have preferably flowing between microcapsules
Property, prevent from luming.
Nano-scale white carbon black is gas-phase silica of the diameter in 50-100nm, the sky that white carbon can be filled up between microcapsules
Gap reduces the friction between microcapsules, prevents microcapsules rupture.
Claims (6)
1. a kind of micro-nano fire extinguishing capsule, it is characterised in that the formula is made up of according to parts by weight the following raw material：
Gas extinguishing agent 10-50 parts, covering material 2-5 parts, organic silicone oil 0.1-1 parts, nano-scale white carbon black 1-5 parts.
2. a kind of micro-nano fire extinguishing capsule according to claim 1, it is characterised in that described gas extinguishing agent is difluoro
Methylene bromide, difluorochlobromo-methane, BTM, dibromotetrafluoromethane, trifluoro propane, HFC-236fa, seven fluorine third
One or more in alkane, IG541.
3. a kind of micro-nano fire extinguishing capsule according to claim 1, it is characterised in that described covering material is methyl-prop
E pioic acid methyl ester, Methyl Methacrylate, 2- methyl -2- methyl acrylates, methylmethacrylate, methyl methacrylate, first
Base loses the one or more in resin acid methyl esters, methyl methacrylate (MMA), Methyl metacrylate 99.
4. a kind of micro-nano fire extinguishing capsule according to claim 1, it is characterised in that described organic silicone oil is hydrophobic type
Organic silicone oil.
5. a kind of micro-nano capsule according to claim 1, it is characterised in that described nano-scale white carbon black is that diameter exists
50-100nm gas-phase silica.
6. a kind of preparation method of micro-nano capsule, it is characterised in that comprise the following steps：
（1）Gas extinguishing agent and covering material are well mixed under 3Mpa pressure；
（2）Organic silicone oil and nano-scale white carbon black are sequentially added；
（3）Load packaging after stirring and obtain finished product.
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|---|---|---|---|
| CN201610326639.8A CN107376185A (en) | 2016-05-17 | 2016-05-17 | A kind of micro-nano fire extinguishing capsule and preparation method |
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|---|---|---|---|
| CN201610326639.8A CN107376185A (en) | 2016-05-17 | 2016-05-17 | A kind of micro-nano fire extinguishing capsule and preparation method |
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| CN201610326639.8A Pending CN107376185A (en) | 2016-05-17 | 2016-05-17 | A kind of micro-nano fire extinguishing capsule and preparation method |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109350882A (en) * | 2018-09-26 | 2019-02-19 | 山东科技大学 | A kind of high building fire-proof unmanned plane based on flying wheel battery |
| CN109432685A (en) * | 2018-11-01 | 2019-03-08 | 深圳市安预认知技术有限公司 | Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device |
| CN110025918A (en) * | 2019-06-03 | 2019-07-19 | 辽宁大学 | A kind of preparation method of Thermo-sensitive extinguishing chemical |
| CN111068234A (en) * | 2019-12-26 | 2020-04-28 | 语路科技(深圳)有限公司 | Polymorphic preparation method and fire extinguishing patch of novel bionic nanocapsule fire extinguisher |
| CN112041035A (en) * | 2019-01-17 | 2020-12-04 | 株式会社Lg化学 | Flame-retardant composition, method for producing same, secondary battery, and battery pack |
| CN112043994A (en) * | 2020-09-14 | 2020-12-08 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
| CN113426059A (en) * | 2021-06-10 | 2021-09-24 | 中国科学技术大学 | Organic/inorganic hybrid core-shell structure fire extinguishing agent suitable for extinguishing lithium ion battery fire and preparation method thereof |
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2016
- 2016-05-17 CN CN201610326639.8A patent/CN107376185A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109350882B (en) * | 2018-09-26 | 2020-11-03 | 山东科技大学 | High-rise fire control unmanned aerial vehicle based on flywheel battery |
| CN109350882A (en) * | 2018-09-26 | 2019-02-19 | 山东科技大学 | A kind of high building fire-proof unmanned plane based on flying wheel battery |
| CN109432685A (en) * | 2018-11-01 | 2019-03-08 | 深圳市安预认知技术有限公司 | Nanometer fire extinguishing capsule preparation method thereof and fire extinguishing patch, fire extinguishing coating, intelligent extinguishing device |
| CN112041035B (en) * | 2019-01-17 | 2023-01-10 | 株式会社Lg新能源 | Process for preparing flame retardant compositions |
| CN112041035A (en) * | 2019-01-17 | 2020-12-04 | 株式会社Lg化学 | Flame-retardant composition, method for producing same, secondary battery, and battery pack |
| EP3769820A4 (en) * | 2019-01-17 | 2021-05-19 | Lg Chem, Ltd. | Fire-extinguishing composition, method for producing same, secondary battery, and battery pack |
| US11730993B2 (en) | 2019-01-17 | 2023-08-22 | Lg Energy Solution, Ltd. | Extinguishing composition, method for preparing the same, secondary battery and battery pack |
| CN110025918A (en) * | 2019-06-03 | 2019-07-19 | 辽宁大学 | A kind of preparation method of Thermo-sensitive extinguishing chemical |
| CN111068234A (en) * | 2019-12-26 | 2020-04-28 | 语路科技(深圳)有限公司 | Polymorphic preparation method and fire extinguishing patch of novel bionic nanocapsule fire extinguisher |
| CN112043994A (en) * | 2020-09-14 | 2020-12-08 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
| CN112043994B (en) * | 2020-09-14 | 2022-03-22 | 西安尚泰安全技术有限责任公司 | Temperature-control capsule type nano fire extinguishing tablet and temperature-control nano capsule fire extinguishing method |
| CN113426059B (en) * | 2021-06-10 | 2022-03-01 | 中国科学技术大学 | Organic/inorganic hybrid core-shell structure fire extinguishing agent suitable for extinguishing lithium ion battery fire and preparation method thereof |
| CN113426059A (en) * | 2021-06-10 | 2021-09-24 | 中国科学技术大学 | Organic/inorganic hybrid core-shell structure fire extinguishing agent suitable for extinguishing lithium ion battery fire and preparation method thereof |
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