CN107348580A - A kind of antiultraviolet farinfrared health-care material - Google Patents
A kind of antiultraviolet farinfrared health-care material Download PDFInfo
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- CN107348580A CN107348580A CN201710488623.1A CN201710488623A CN107348580A CN 107348580 A CN107348580 A CN 107348580A CN 201710488623 A CN201710488623 A CN 201710488623A CN 107348580 A CN107348580 A CN 107348580A
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- antiultraviolet
- health
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- care material
- farinfrared
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- 239000000463 material Substances 0.000 title claims abstract description 42
- 239000004744 fabric Substances 0.000 claims abstract description 40
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 34
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 230000006750 UV protection Effects 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 238000002074 melt spinning Methods 0.000 claims abstract description 5
- 238000002844 melting Methods 0.000 claims abstract description 5
- 230000008018 melting Effects 0.000 claims abstract description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 35
- 230000036541 health Effects 0.000 claims description 17
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000010791 quenching Methods 0.000 claims description 8
- 230000000171 quenching effect Effects 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 229920002396 Polyurea Polymers 0.000 claims description 7
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims 1
- HZBAVWLZSLOCFR-UHFFFAOYSA-N oxosilane Chemical compound [SiH2]=O HZBAVWLZSLOCFR-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 230000003115 biocidal effect Effects 0.000 abstract description 5
- 238000000227 grinding Methods 0.000 abstract description 3
- 230000036737 immune function Effects 0.000 abstract description 2
- 230000002085 persistent effect Effects 0.000 abstract description 2
- -1 polyethylene terephthalate Polymers 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 14
- 230000008569 process Effects 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 230000006378 damage Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- 235000014676 Phragmites communis Nutrition 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- 238000002513 implantation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 201000009030 Carcinoma Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/26—UV light protection
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of antiultraviolet farinfrared health-care material, the fabric is that with polyethylene terephthalate melting prepared by graphene and the modified auxiliary agent prepared of titanium dioxide grinding into master batch, through melt spinning, is weaved cotton cloth.Have the beneficial effect that：Fabric of the present invention has stronger UV resistance ability, and ultraviolet resistance is persistent, and clothing is than the ability still with higher absorption ultraviolet in the case of relatively thin；Far-infrared Absorption efficiency high, resonance effects and thermogenetic effect can be produced, penetrate to the skin deep layer, stimulates circulation, and improves immunologic function, reaches health-care effect；It is soft, smooth with antibiotic property, antistatic behaviour, it is harmless, fabric class, increase added value are improved, expands application, and preparation method is simple, compatibility is reasonable, has larger potentiality.
Description
Technical field
The present invention relates to Garment Technology field, a kind of antiultraviolet farinfrared health-care material.
Background technology
Clothes refers to the various clothes clothes worn with it, and clothes is intended that warming, the medium of flak jacket and in the modern times
Social clothes has gradually been evolved into the decorative article of human body, has signified the standard of living and society ground of a people when more
Position is simultaneously on the basis of clothes basic function is constant, and people more and more focus on clothing and the UV resistance of body is acted on, no
Various effects of different materials, are added in dress material, add clothing by the new material of disconnected research and development clothes using appropriate technique
The feature of clothes.The fabric of existing production clothes is typically made up of a kind of material, and feature is also relatively simple, especially for the summer
For season, due to the destruction of environment, the appearance of Ozone hole make it that the ultraviolet component of the sunshine of direct projection is more and more, and excessive
Irradiating ultraviolet can cause the lesions such as cutaneum carcinoma, it is therefore desirable to a kind of clothing with UV resistance function.It is common in existing market
The technological means for making ultraviolet-resistant fabric mainly has two kinds：One kind is that antiultraviolet material is mixed into spinning to reach anti-purple
The effect of outside line；Another kind is to carry out anti-uv finishing to fabric using the method for final finishing.It is most common in afterfinish method
Be using coating technology fabric face coat layer of material, coating material be generally black glue, elargol or other there is anti-purple
The material of outside line effect.Coating is utilized using the technological means of spin processes making ultraviolet-resistant fabric is restricted to fibrous raw material
In use, inevitably by raindrop erosion, easily there is UV resistance to the ultraviolet-resistant fabric of making in ultraviolet resistant layer
Wire material comes off, decomposes the problems such as producing the compound to human health.
Far infrared fabric refers to add a kind of suction that can be absorbed environment's heat and can be radiation infrared in process
Receive agent and then manufactured fiber.This far-infrared additive by absorb extraneous heat and to internal linchpin penetrate far infrared and then
The effect of body-sensing temperature rise.Because the far infrared that good fortune is penetrated easily penetrates to the skin deep layer, so as to stimulate circulation, reach antibacterial work(
Effect, it is a kind of to have insulation, the new chemical fiber of health care multiple functions concurrently.Far-infrared textiles processing mode is more and more at present
Sample, such as coating, implantation, various spin processes.Natural fiber is normally applied coating and implantation, regenerated fiber and chemistry
Fiber is normally applied spin processes, wherein it is coating and master batch spin processes that application is more.
Prior art such as Authorization Notice No. is the B of CN 103835140 Chinese invention patent, discloses a kind of antiultraviolet
Fabric, the fabric include fabric and the ultraviolet resistant layer coated in fabric nexine, and ultraviolet resistant layer is coffee
Thickness 0.05mm ~ 0.3mm of the blended layer of powder and polyester, wherein ultraviolet resistant layer, the particle diameter of coffee powder is 0.5 μm ~ 5 μ
The mass ratio of m, coffee powder and polyester is 2:10~5:10.The fabric has that UV resistance effect is good, do not decompose noxious material, anti-
The features such as bacterium eliminates the unusual smell, but the fabric does not possess far infrared health care effect.
The content of the invention
It is an object of the invention to provide a kind of antiultraviolet farinfrared health-care material, the material set antiultraviolet effect
With far infrared health care effect in one, the multifunctional novel of fabric is realized, pliability is high, harmless.
The present invention is directed to the problem of being mentioned in above-mentioned technology, and the technical scheme taken is：A kind of antiultraviolet far infrared is protected
Strong fabric, including prepared by auxiliary agent, prepared by master batch, prepared by antiultraviolet far infrared health care fiber, antiultraviolet far infrared health care face
Prepared by material, concrete operation step is：
It is prepared by auxiliary agent：It is 1 by mass ratio:2 ~ 3.8 graphene and titanium dioxide is put into 3 ~ 4h of grinding in ball mill, adds anhydrous
Ethanol be adjusted to it is solid containing being 13 ~ 17wt%, add the 3 ~ 5wt ‰ ethoxy silane of vinyl three, 3 ~ 5wt ‰ n-propylamine, 3 ~
5wt ‰ polyureas, it is well mixed, is spray-dried and produces auxiliary agent, the ethoxy silane of preparation process medium vinyl three, n-propylamine and poly-
The addition of urea can make graphene be not easy to reunite in ethanol solution, dispersed, form the less particle of particle diameter, ensure follow-up
Process is smoothed out so that the particle diameter of auxiliary agent is smaller, does not influence the continuity and spinnability of spinning production, and does not interfere with
The planarization of fiber and the comfortableness of fabric, auxiliary agent have good stability, can be as good ultraviolet screener and remote
Infrared dose of composition, while weaker wettability power can guarantee that the moisture of system is relatively low in following process, to improve fiber
Spinnability；
It is prepared by master batch：By 80 ~ 100 parts of PETP, 8 ~ 15 parts of auxiliary agent, rotating speed is put into as 70 ~ 90r/min, temperature
For 270 ~ 290 DEG C of double screw extruder melting extrusion, section, then at 110 ~ 130 DEG C of 22 ~ 26h of vacuum drying, master batch is produced,
The addition of auxiliary agent influences the antiultraviolet and far infrared health care performance of fabric, and within the specific limits, fabric performance is with auxiliary agent
Increase and improve, but auxiliary agent continues to increase, it may appear that agglomeration, cause fiber lousiness to increase, spinnability declines；
It is prepared by antiultraviolet far infrared health care fiber：Master batch is subjected to melt spinning, through ring wind quenching, oils, leads for the first time
To stretch, second of drawing-off, winding shaping obtains polyester fiber, and ring wind quenching temperature is 65 ~ 80 DEG C, and the first drawing temperature is 170 ~
180 DEG C, drafting multiple is 1.5 ~ 2.0 times, and second of drawing temperature is 135 ~ 145 DEG C, and drafting multiple is 3.0 ~ 4.0 times, the fibre
Dimension absorbs ultraviolet and makes molecule that energy level transition occur, and is converted to heat energy, reduces the transit dose of ultraviolet, can also shield ultraviolet
Line, reach uvioresistant purpose, meanwhile, fiber can absorb the heat in the external world and to internal radiation far infrared and then body-sensing
The effect of temperature rise, far infrared easily penetrate to the skin deep layer, so as to stimulate circulation, reach bacteriostasis efficacy；
It is prepared by antiultraviolet farinfrared health-care material：Boil 3 ~ 4h in the boiling water that fiber after twisting is placed on, through warping, wear it is vertical,
Plug in reed, upper machine, wefting insertion, shuttling produces antiultraviolet farinfrared health-care material, the fabric preventing ultraviolet effect is good, reduces ultraviolet
Injury to human body, Far-infrared Absorption efficiency high, stimulates circulation, while fabric has antibiotic property, antistatic behaviour, and feel
It is soft, smooth, it is harmless, fabric class, increase added value are improved, expands application, there are larger potentiality.
Compared with prior art, the advantage of the invention is that：1）Fabric of the present invention has stronger UV resistance ability, anti-purple
Outside line performance is persistent, and clothing is than the ability still with higher absorption ultraviolet in the case of relatively thin；2）Far-infrared Absorption
Efficiency high, resonance effects and thermogenetic effect can be produced, penetrate to the skin deep layer, stimulates circulation, and improves immunologic function, reaches
Health-care effect；3）It is soft, smooth with antibiotic property, antistatic behaviour, it is harmless, improve fabric class, increase it is attached
It is value added, expand application, and preparation method is simple, compatibility is reasonable, has larger potentiality.
Embodiment
The present invention program is described further below by embodiment：
Embodiment 1：
A kind of antiultraviolet farinfrared health-care material, including prepared by auxiliary agent, prepared by master batch, antiultraviolet far infrared health care fiber system
Prepared by standby, antiultraviolet farinfrared health-care material, concrete operation step is：
1）It is prepared by auxiliary agent：It is 1 by mass ratio:2.5 graphene and titanium dioxide is put into 3 ~ 4h of grinding in ball mill, adds anhydrous
Ethanol is adjusted to, admittedly containing being 14wt%, add 4wt ‰ the ethoxy silane of vinyl three, 3wt ‰ n-propylamine, 2wt ‰ polyureas,
It is well mixed, it is spray-dried and produces auxiliary agent, the addition of preparation process medium vinyl three the ethoxy silane, n-propylamine and polyureas can makes
Graphene is not easy to reunite in ethanol solution, dispersed, forms the less particle of particle diameter, ensures that follow-up process is smooth
Carry out so that the particle diameter of auxiliary agent is smaller, does not influence the continuity and spinnability of spinning production, and does not interfere with the planarization of fiber
With the comfortableness of fabric, auxiliary agent has good stability, can be as good ultraviolet screener and far-infrared additive composition, together
When weaker wettability power can guarantee that the moisture of system is relatively low in following process, to improve the spinnability of fiber；
2）It is prepared by master batch：By 90 parts of PETP, 12 parts of auxiliary agent, be put into rotating speed be 80r/min, temperature be 280 DEG C
Double screw extruder melting extrusion, section, then at 120 DEG C of vacuum drying 25h, produce master batch, the addition of auxiliary agent influences face
The antiultraviolet and far infrared health care performance of material, within the specific limits, fabric performance improves with the increase of auxiliary agent, but auxiliary agent
Continue to increase, it may appear that agglomeration, cause fiber lousiness to increase, spinnability declines；
3）It is prepared by antiultraviolet far infrared health care fiber：Master batch is subjected to melt spinning, through ring wind quenching, oiled, for the first time
Drawing-off, second of drawing-off, winding shaping obtain polyester fiber, and ring wind quenching temperature is 70 DEG C, and the first drawing temperature is 175 DEG C,
Drafting multiple is 1.8 times, and second drawing temperature is 140 DEG C, and drafting multiple is 3.5 times, and the fiber absorbs ultraviolet and made point
Son occur energy level transition, be converted to heat energy, reduce the transit dose of ultraviolet, also can shielding ultraviolet rays, reach uvioresistant purpose,
Meanwhile fiber can absorb the heat in the external world and to internal radiation far infrared and then the effect of body-sensing temperature rise, far infrared
Easily penetrate to the skin deep layer, so as to stimulate circulation, reaches bacteriostasis efficacy；
4）It is prepared by antiultraviolet farinfrared health-care material：Boil 3h in the boiling water that fiber after twisting is placed on, through warping, wear it is vertical,
Plug in reed, upper machine, wefting insertion, shuttling produces antiultraviolet farinfrared health-care material, the fabric preventing ultraviolet effect is good, reduces ultraviolet
Injury to human body, Far-infrared Absorption efficiency high, stimulates circulation, while fabric has antibiotic property, antistatic behaviour, and feel
It is soft, smooth, it is harmless, fabric class, increase added value are improved, expands application, there are larger potentiality.
Embodiment 2：
A kind of antiultraviolet farinfrared health-care material, including prepared by auxiliary agent, prepared by master batch, antiultraviolet far infrared health care fiber system
Prepared by standby, antiultraviolet farinfrared health-care material, concrete operation step is：
1）It is prepared by auxiliary agent：It is 1 by mass ratio:3 graphene and titanium dioxide, which is put into ball mill, grinds 4h, adds absolute ethyl alcohol
It is adjusted to, admittedly containing being 16wt%, add 4wt ‰ the ethoxy silane of vinyl three, 3wt ‰ n-propylamine, 5wt ‰ polyureas, mix
Uniformly, it is spray-dried and produces auxiliary agent, the addition of preparation process medium vinyl three the ethoxy silane, n-propylamine and polyureas can makes graphite
Alkene is not easy to reunite in ethanol solution, dispersed, forms the less particle of particle diameter, ensures that follow-up process is smoothly entered
OK so that the particle diameter of auxiliary agent is smaller, do not influence spinning production continuity and spinnability, and do not interfere with fiber planarization and
The comfortableness of fabric, auxiliary agent have good stability, can be as good ultraviolet screener and far-infrared additive composition, simultaneously
Weaker wettability power can guarantee that the moisture of system is relatively low in following process, to improve the spinnability of fiber；
2）It is prepared by master batch：By 100 parts of PETP, 13 parts of auxiliary agent, be put into rotating speed be 90r/min, temperature be 285 DEG C
Double screw extruder melting extrusion, section, then at 115 DEG C of vacuum drying 26h, produce master batch, the addition of auxiliary agent influences face
The antiultraviolet and far infrared health care performance of material, within the specific limits, fabric performance improves with the increase of auxiliary agent, but auxiliary agent
Continue to increase, it may appear that agglomeration, cause fiber lousiness to increase, spinnability declines；
3）It is prepared by antiultraviolet far infrared health care fiber：Master batch is subjected to melt spinning, through ring wind quenching, oiled, for the first time
Drawing-off, second of drawing-off, winding shaping obtain polyester fiber, and ring wind quenching temperature is 70 DEG C, and the first drawing temperature is 180 DEG C,
Drafting multiple is 2.0 times, and second drawing temperature is 135 DEG C, and drafting multiple is 3.0 times, and the fiber absorbs ultraviolet and made point
Son occur energy level transition, be converted to heat energy, reduce the transit dose of ultraviolet, also can shielding ultraviolet rays, reach uvioresistant purpose,
Meanwhile fiber can absorb the heat in the external world and to internal radiation far infrared and then the effect of body-sensing temperature rise, far infrared
Easily penetrate to the skin deep layer, so as to stimulate circulation, reaches bacteriostasis efficacy；
4）It is prepared by antiultraviolet farinfrared health-care material：Boil 4h in the boiling water that fiber after twisting is placed on, through warping, wear it is vertical,
Plug in reed, upper machine, wefting insertion, shuttling produces antiultraviolet farinfrared health-care material, the fabric preventing ultraviolet effect is good, reduces ultraviolet
Injury to human body, Far-infrared Absorption efficiency high, stimulates circulation, while fabric has antibiotic property, antistatic behaviour, and feel
It is soft, smooth, it is harmless, fabric class, increase added value are improved, expands application, there are larger potentiality.
Embodiment 3：
Antiultraviolet and far infrared performance test：
The fabric of embodiment 1, embodiment 2 is set to test group, the polyester fabric for not doing any processing is set to control group, enters respectively
Row antiultraviolet and far infrared performance test.Ultraviolet resistance test result is as shown in table 1, and data understand face of the present invention in table
The preventing ultraviolet effect of material is good, meets national regulation requirement.Far infrared the performance test results are as shown in table 1, and data are understood in table
Far infrared performance of the present invention meets the requirement of national regulation.
Table 1：Antiultraviolet and far infrared the performance test results
| Project | UPF | Near ultraviolet ray wave band transmitance（%） | Far infrared normal emittance（%） |
| Embodiment 1 | 63.7 | 3.4 | 85.2 |
| Embodiment 1 | 62.2 | 3.8 | 83.9 |
| Control group | 8.5 | 67.5 | ＜ 80 |
Routine operation in the operating procedure of the present invention is well known to those skilled in the art, herein without repeating.
Technical scheme is described in detail embodiment described above, it should be understood that it is described above only
For the specific embodiment of the present invention, it is not intended to limit the invention, all any modifications made in the spirit of the present invention,
Supplement or similar fashion replacement etc., should be included in the scope of the protection.
Claims (10)
- A kind of 1. antiultraviolet farinfrared health-care material, it is characterised in that：The preparation process of described fabric includes：Auxiliary agent system Prepared by standby, master batch, prepared by antiultraviolet far infrared health care fiber, prepared by antiultraviolet farinfrared health-care material.
- A kind of 2. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described auxiliary agent Step is to grind graphene and titanium dioxide, adds absolute ethyl alcohol and is adjusted to, admittedly containing being 13 ~ 17wt%, add the second of vinyl three Oxosilane, n-propylamine, polyureas, it is well mixed, is spray-dried and produces auxiliary agent.
- A kind of 3. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described auxiliary agent The mass ratio of graphene and titanium dioxide is 1 in step:2 ~ 3.8, grind 3 ~ 4h.
- A kind of 4. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described auxiliary agent The ethoxy silane addition of step medium vinyl three is 3 ~ 5wt ‰, n-propylamine is 3 ~ 5wt ‰, polyureas is 3 ~ 5wt ‰.
- A kind of 5. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described master batch Preparation process is：By 80 ~ 100 parts of PETP, 8 ~ 15 parts of auxiliary agent, melting extrusion, cut into slices, dry.
- A kind of 6. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described master batch The rotating speed of extruder is 70 ~ 90r/min in preparation process, and temperature is 270 ~ 290 DEG C.
- A kind of 7. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：It is prepared by described master batch Drying temperature is 110 ~ 130 DEG C in preparation process, and the time is 22 ~ 26h.
- A kind of 8. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：Described antiultraviolet Far infrared health care fiber preparation process is：Master batch is subjected to melt spinning, through ring wind quenching, oiled, first time drawing-off, second Secondary drawing-off, winding shaping obtain fiber.
- A kind of 9. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：Described antiultraviolet Ring wind quenching temperature is 65 ~ 80 DEG C in far infrared health care fiber preparation process, and the first drawing temperature is 170 ~ 180 DEG C, drawing-off Multiple is 1.5 ~ 2.0 times, and second of drawing temperature is 135 ~ 145 DEG C, and drafting multiple is 3.0 ~ 4.0 times.
- A kind of 10. antiultraviolet farinfrared health-care material according to claim 1, it is characterised in that：Described UV resistance Boiling water shaping time is 3 ~ 4h in prepared by line farinfrared health-care material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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|---|---|---|---|---|
| KR20130046530A (en) * | 2011-10-28 | 2013-05-08 | 이성균 | Polymer Carbon Nanotube Aramid Fiber and Polymer Graphene Aramid Fiber |
| CN103572395A (en) * | 2013-11-14 | 2014-02-12 | 东华大学 | Strengthened toughened regenerated silk fibers and preparation method thereof |
| CN103966835A (en) * | 2014-05-23 | 2014-08-06 | 青岛大学 | Method for preparing ultraviolet shielding textile composite fabric with graphene nanoplatelets |
| CN104748624A (en) * | 2013-12-30 | 2015-07-01 | 杨晓波 | Composite flexible bulletproof material |
| CN106065498A (en) * | 2016-06-04 | 2016-11-02 | 江苏启弘新材料科技有限公司 | The preparation method of antistatic fibre based on point discharge effect |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130046530A (en) * | 2011-10-28 | 2013-05-08 | 이성균 | Polymer Carbon Nanotube Aramid Fiber and Polymer Graphene Aramid Fiber |
| CN103572395A (en) * | 2013-11-14 | 2014-02-12 | 东华大学 | Strengthened toughened regenerated silk fibers and preparation method thereof |
| CN104748624A (en) * | 2013-12-30 | 2015-07-01 | 杨晓波 | Composite flexible bulletproof material |
| CN103966835A (en) * | 2014-05-23 | 2014-08-06 | 青岛大学 | Method for preparing ultraviolet shielding textile composite fabric with graphene nanoplatelets |
| CN106065498A (en) * | 2016-06-04 | 2016-11-02 | 江苏启弘新材料科技有限公司 | The preparation method of antistatic fibre based on point discharge effect |
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Denomination of invention: A UV and Far Infrared Protective Fabric Effective date of registration: 20231106 Granted publication date: 20190129 Pledgee: Bank of China Limited Nanxun District Branch Pledgor: Huzhou Yunfeng Silk Co.,Ltd. Registration number: Y2023980063991 |
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