A kind of single level battery and its manufacture method
Technical field
The application is related to battery technology field, more particularly to a kind of single level battery and its manufacture method.
Background technology
Traditional sealed lead acid battery, one of its shortcoming is:By the vertical of battery pole plates use in the inner
Electrolyte stratification phenomena caused by modes of emplacement;The polarization of electrolyte stratification phenomena, i.e. concentration of electrolyte difference
Phenomenon, this is the one of the main reasons of battery capacity decline and the lost of life.
By the improvement of this body structure of cell making process and battery, a kind of horizon battery is occurred in that now,
Horizon battery is due to that the battery pole plates in it are gained the name by the way of horizontal positioned.Horizon battery is due to it
Battery pole plates horizontal positioned, thus the problem of overcome conventional batteries electrolyte stratification.The pole plate of horizon battery
For horizontal quasi bipolar structure, it applies positive active material as positive plate in the half of lead fabric plate, herein
Second half of lead fabric plate applies negative electrode active material for negative plate, is stayed between the positive negative active material of double polarity plate
There is about 10mm space, isolated with spraying pitch, prevent short circuit.It is double in horizontal double pole lead-acid battery
Polarity pole plate is according to from left to right, from top to bottom, the order that the positive/negative plate on double polarity plate is staggeredly placed
Place, and every pole plate is coated by barrier film up and down, is assembled finally by some sheet materials and battery case
Come.After being completed, in addition it is also necessary to by acid filling, chemical conversion, and it is by filling wax that bipolar plates unit compartment is empty
Gap is filled, to increase the anti-shake performance of battery, while unit compartment acid solution and the vibration of acid gas are reduced, with
Reduce the self discharge amount of battery.
, there is problems with horizontal double pole lead-acid battery of the prior art:
1st, because positive active material and negative active material such as lead plaster are coated on same plate respectively, this causes can only
Weigh bipolar plates gross weight and can not accurately control unipolar plate weight respectively, it is impossible to keep battery with two side terminals, when
Positive negative active material proportional jitter on coated plate than it is larger when, the deep discharge that can have a strong impact on battery uses the longevity
Life;
2nd, in cell production process, it is melted into again after acid filling, needs to discharge acid more than needed after chemical conversion,
By the way of slant setting flows out naturally, inside battery is particularly connected to be had on the spongy lead between two pole groups
Remain acid solution.And need to inject high-temperature liquid state paraffin after the completion of the acid discharge, paraffin in battery after cooled and solidified,
Because expanding with heat and contract with cold in unit compartment formation shrinkage cavity, unit compartment is produced the interface channel of acid solution and acid gas, make
Forming micro cell into connection between cell causes self discharge, influences battery with two side terminals;
3rd, the sour problem of internal element lattice string:Such as, 12V horizon batteries have 6 internal single lattices, during discharge and recharge
The acid gas of inside generation, acid solution can all connect string lattice in several cells, cause reaction in 6 cells
Efficiency is inconsistent and self discharge is inconsistent, influences battery with two side terminals;
4th, existing level battery unit compartment is sealed by filling wax, and inside is unable to reach preferable sealing effectiveness,
During battery storing, in battery 6 units every self discharge because fill wax sealing effectiveness difference, unit compartment
Self discharge difference is larger, can produce large effect to battery consistency;
5th, horizontal double pole battery is because of structure design reason, it is impossible to produce larger capacity batteries.In Large Copacity
Application field, need to use multigroup cell parallel, but because of the inconsistent reason of horizontal double pole self-discharge of battery,
It is caused to be unable to reach great achievement pool-size life requirements.
The content of the invention
The application provides a kind of single level battery and its manufacture method, and it being capable of material saving, solution level
The positive and negative lead plaster ratio of bipolar battery pole plate is inconsistent and influences deep battery discharge service life, it is ensured that realize
The excellent sealing of cell compole group, reduces horizon battery self discharge, improve the standard battery consistency and battery
Life-span, while ensureing to keep other excellent properties such as high current charge-discharge of horizon battery unaffected.
According to the application's in a first aspect, the application provides a kind of single level battery, including:
Anode sub-pole plate, the anode sub-pole plate is a pole plate for scribbling positive cream, wherein, one side of pole plate
One section of region is not coated with positive cream, using the end line as anode sub-pole plate;
Negative terminal sub-pole plate, the negative terminal sub-pole plate is a pole plate for scribbling negative cream, wherein, one side of pole plate
One section of region is not coated with negative cream, using the end line as negative terminal sub-pole plate;
Barrier film, for inhaling acid, so that anode sub-pole plate and negative terminal sub-pole plate occur electrochemical reaction and produce electricity;
The anode sub-pole plate and negative terminal sub-pole plate, from the bottom up, alternately horizontal positioned, neighbouring
The barrier film is both provided between anode sub-pole plate and negative terminal sub-pole plate, wherein anode sub-pole plate has end line
While being all located at first orientation, there is negative terminal sub-pole plate one side of end line to be all located at second orientation, described first
Orientation and second orientation are adjacent or relative.
In one preferred embodiment, the single level battery also include be fixedly mounted connection upper pressure cover plate,
Lower pressure cover plate and two blocks of side plates, wherein the upper pressure cover plate and lower pressure cover plate are located at from the bottom up respectively
Above the pole plate that alternating horizontal is placed and following, two blocks of side plates are located at alternating horizontal from the bottom up respectively
The pole plate of placement does not have the two sides of end line.
In one preferred embodiment, the single level battery also includes two blocks of terminal casting, be respectively used to just
The end line electrical connection of the end line of terminal pole plate, negative terminal sub-pole plate, using as the single level battery
Positive pole and negative pole.
In one preferred embodiment, the single level battery also includes a battery case for being used to encapsulate, described
Battery case has is provided with a safety valve on a safe valve opening, the safe valve opening.
In one preferred embodiment, the battery case includes the unclosed battery case in lower surface, and one is used for
The battery cover of closing battery box lower surface, the battery case is sealed with battery cover and fixed;Wherein described safety valve
Hole is arranged at the upper surface of the battery case.
According to the second aspect of the application, the application provides a kind of manufacture method of single level battery, including
Following steps:
Manufacture anode sub-pole plate and negative terminal sub-pole plate;Wherein anode sub-pole plate is a pole plate for scribbling positive cream, pole
One section of region on one side of plate is not coated with positive cream, using the end line as anode sub-pole plate;Negative terminal sub-pole plate is a painting
There is the pole plate of negative cream, wherein, one section of region on one side of pole plate is not coated with negative cream, to be used as negative terminal sub-pole plate
End line;
The fixed pressure cover plate once in an assembling equipment, two blocks of side plates are placed in the both sides of lower pressure cover plate;
A piece of barrier film is placed on lower pressure cover plate by a manipulator, then again sequentially with one piece of plus end pole
Plate, a piece of barrier film, one piece of negative terminal sub-pole plate, repeat to place to certain amount a piece of barrier film, or again according to
Sequence with one piece of negative terminal sub-pole plate, a piece of barrier film, one piece of anode sub-pole plate, repeat to place to one a piece of barrier film
Fixed number amount, finally places on one pressure cover plate thereon again;Uppermost one piece is just in wherein all pole plates
Terminal pole plate or negative terminal sub-pole plate, the end line of all anode sub-pole plates is both facing to first orientation, all negative terminals
The end line of pole plate is both facing to second orientation, and the first orientation and second orientation are adjacent or relative, and not positions
Orientation where two blocks of side plates;
The upper pressure cover plate, lower pressure cover plate and two blocks of side plates are connected and fixed to obtain by a pressing machine
Battery;
The end line cast welding of two blocks of terminal casting end line respectively with anode sub-pole plate, negative terminal sub-pole plate is connected;
The battery for being welded with terminal casting is loaded in a battery case, there is a peace on the battery case
Full valve hole;
By the safe valve opening on battery case into battery case acid filling liquid;
The single level battery is melted into;Afterwards, it is then exhausted from unnecessary acid solution;
The safety valve of an adaptation is installed on safe valve opening on the battery case.
The beneficial effect of the application is:
According to the single level battery and its manufacture method of above-mentioned implementation, due to anode sub-pole plate and negative terminal sub-pole plate
All it is single pole plate, therefore both can be precisely weighed combo, makes positive cream above both and negative cream this class
Active material reaches unanimously, so as to greatly improve the deep discharge uniformity of battery;
According to the single level battery and its manufacture method of above-mentioned implementation, due to taking the design of cell, often
Individual single level battery is equipped with single battery case and safety valve, therefore in the absence of conventional flat bipolarity
Liquid leakage is collaborated problem inside battery unit compartment, improves the charge and discharge of the retention of charge and battery of battery
Electric uniformity, so as to substantially increase the actual life of battery;
According to the single level battery and its manufacture method of above-mentioned implementation, the battery of Large Copacity can be produced.
According to the single level battery and its manufacture method of above-mentioned implementation, it is not necessary to again to carrying out filling Lasaxing Oilfield in battery,
Therefore process is reduced, saves raw material paraffin.
Brief description of the drawings
Fig. 1 is the explosive view of the single level battery of the embodiment of the application one;
Fig. 2 is the structural representation of the longitudinal section of the single level battery of the embodiment of the application one;
Fig. 3 (a) and the front view and top view of the anode sub-pole plate that (b) is the embodiment of the application one;
Fig. 4 (a) and the front view and top view of the negative terminal sub-pole plate that (b) is the embodiment of the application one;
Fig. 5 is the structural representation of the lower pressure cover plate of the embodiment of the application one;
Fig. 6 is the structural representation of the upper pressure cover plate of the embodiment of the application one;
Fig. 7 is the structural representation of the side plate of the embodiment of the application one;
Fig. 8 is the structural representation of the terminal casting of the embodiment of the application one;
Fig. 9 uses schematic diagram for several single level battery combinations in the application;
Figure 10 is the schematic flow sheet of the manufacture method of the single level battery of the embodiment of the application one.
Embodiment
The application is described in further detail below by embodiment combination accompanying drawing.
The positive and negative active material matching ratio of bipolar plates for horizontal bipolar battery in solution conventional art is difficult to accurate one
Show and unit between acid gas acid solution string lattice problem, inventor consider bipolar plates are changed to single plus end pole
Plate and negative terminal sub-pole plate, and single battery case is designed it.
Embodiment one:
Refer to Fig. 1-4, present embodiment discloses a kind of single level battery, it include anode sub-pole plate 1,
Negative terminal sub-pole plate 2 and barrier film 9.In one embodiment, single level battery is 2V battery.Lower mask body
Explanation.
Anode sub-pole plate 1 is a pole plate for scribbling positive cream, wherein, one section of region on one side of pole plate is not coated with just
Cream, using the end line as anode sub-pole plate, for example, in one embodiment, one side of pole pole reserves 10 millimeters
Wide region is used as end line.
Negative terminal sub-pole plate 2 is a pole plate for scribbling negative cream, wherein, one section of region on one side of pole plate is not coated with bearing
Cream, using the end line as negative terminal sub-pole plate, for example, in one embodiment, one side of pole pole reserves 10 millimeters
Wide region is used as end line.Because anode sub-pole plate 1 and negative terminal sub-pole plate 2 are all single pole plates, therefore
Both can be precisely weighed combo, reach positive cream and negative cream this class active material above both consistent, from
And the deep discharge uniformity of battery can be greatly improved.
Barrier film 9 is used to inhale acid, so that anode sub-pole plate 1 and negative terminal sub-pole plate 2 occur electrochemical reaction and produced
Raw electricity.
Anode sub-pole plate 1 and negative terminal sub-pole plate 2, from the bottom up, alternately horizontal positioned, it is neighbouring just
Barrier film 9 is both provided between terminal pole plate 1 and negative terminal sub-pole plate 2, wherein anode sub-pole plate 1 has end line
While being all located at first orientation, one side that negative terminal sub-pole plate 2 has end line is all located at second orientation, first party
Position is adjacent or relative with second orientation.For example, anode sub-pole plate 1, negative terminal sub-pole plate 2 and barrier film 9 are from lower past
After upper horizontal positioned, there are four orientation all around, it is a left side that might as well make first orientation, then now second orientation
Can be the orientation with left bit phase, i.e. front position or back side;Second orientation can also be and left bit
Relative orientation, i.e. right bit.In one preferably embodiment, first orientation and second orientation are relative, example
Such as, first orientation is left bit, and second orientation is right bit.
Below for example, the position relationship of anode sub-pole plate 1, negative terminal sub-pole plate 2 and barrier film 9 is illustrated.
For example, in one embodiment, horizontal positioned anode sub-pole plate 1 first, then in horizontal positioned barrier film 9 thereon,
And above barrier film 9 horizontal positioned negative terminal sub-pole plate 2, then again this negative terminal sub-pole plate 2 place every
Film 9, and the horizontal positioned anode sub-pole plate 1 above this barrier film 9, then repeat said process again,
Barrier film 9 is placed in anode sub-pole plate 1, horizontal positioned negative terminal sub-pole plate 2 above barrier film 9 can such one
It is straight to repeat down, according to demand, can place the anode sub-pole plate 1 of certain amount, negative terminal sub-pole plate 2 and every
Film 9, this is related to the capacity of battery.The above embodiments are placed since anode sub-pole plate 1, real one
Apply in example, can also be placed since negative terminal sub-pole plate 2., can be with addition, in the above-described embodiment
Finally place a piece of barrier film 9 again on uppermost pole plate, placed again below nethermost pole plate it is a piece of every
Film 9.
Fig. 5-7 are refer to, in a preferred embodiment, single level battery can also include by upper pressure cover plate
4th, the pressure mount structure that lower pressure cover plate 3 and two blocks of side plates 5 are constituted, this can be avoided because vibratory impulse causes
Active matter on pole plate come off caused by battery failure, solve pole plate dilatancy and active material easily take off
The problem fallen, while substantially increasing the anti-vibration and impact capacity of battery.Specifically, upper pressure cover plate 4
It is located at respectively with lower pressure cover plate 3 above this entirety for the pole plate that alternating horizontal is placed from the bottom up with
Face, two blocks of side plates 5 are located at the pole plate that alternating horizontal is placed from the bottom up respectively does not have the two sides of end line, on
Pressure cover plate 4, lower pressure cover plate 3 are fixedly connected with two blocks of side plates 5, and in one embodiment, they are to pass through
Pressing machine clamping, press-fits design pressure up to 100kPa.
Fig. 8 is refer to, in a preferred embodiment, single level battery can also include two blocks of terminal casting 6,
It is respectively used to electrically connect with the end line of anode sub-pole plate 1, the end line of negative terminal sub-pole plate 2, using as list
The positive pole and negative pole of body horizon battery.Due to a terminal casting 6 and the end line electricity of all anode sub-pole plates 1
Connection, another terminal casting 6 is electrically connected with the end line of all negative terminal sub-pole plates 2, therefore can make monomer
The discharge current of horizon battery is very big.
In a preferred embodiment, single level battery is also included outside a battery case for being used to encapsulate, battery
Shell has is provided with a safety valve 10 on a safe valve opening, safe valve opening.In one embodiment, battery
Shell includes the unclosed battery case 7 in lower surface, and one is used for the battery cover 8 of the lower surface of closing battery box 7,
Battery case 7 is sealed with battery cover 8 and fixed;Wherein safe valve opening is arranged at the upper surface of battery case 7.By
In the design for taking cell, each single level battery is equipped with single battery case 7 and safety valve
10, therefore collaborated problem in the absence of liquid leakage inside conventional flat bipolar battery unit compartment, improve battery
Retention of charge and battery discharge and recharge uniformity, so as to substantially increase the actual use longevity of battery
Life.
The single level battery capacity of the present embodiment can be very big, and its battery with two side terminals is also very good, its
It can also be used in series, as shown in figure 9, providing 48V's after the single level battery series connection for 24 2V
Power supply.
Embodiment two
Figure 10 is refer to, present embodiment discloses a kind of manufacture method of single level battery, including following step
Suddenly.
Step S01:Anode sub-pole plate 1 and negative terminal sub-pole plate 2 are manufactured, wherein anode sub-pole plate 1 scribbles for one
The pole plate of positive cream, one section of region on one side of pole plate is not coated with positive cream, using the end line as anode sub-pole plate;It is negative
Terminal pole plate 2 is a pole plate for scribbling negative cream, wherein, one section of region on one side of pole plate is not coated with negative cream, with
It is used as the end line of negative terminal sub-pole plate.In one embodiment, specifically, in step S01, squeezed using solid-state
Press technique sheath to be covered glass fibre knitmesh after galvanized wire is made and grid is made;Positive cream is applied on grid, and in plate
One section of region on grid one side does not apply positive cream using as end line, then will scribble the grid of positive cream by cut-out, pickling
After dry solidification, Pork-pieces anode sub-pole plate 1 is obtained;Negative cream is applied on grid, and on grid one side
One section of region does not apply negative cream using as end line, then will scribble the grid of negative cream by cut-out, pickling and dry solid
After change, Pork-pieces negative terminal sub-pole plate 2 is obtained.
Step S03:The fixed pressure cover plate 3 once in an assembling equipment, the both sides of lower pressure cover plate 3 are placed
Two blocks of side plates 5.
Step S05:A piece of barrier film 9 is placed on lower pressure cover plate 3 by a manipulator, then again sequentially with
One piece of anode sub-pole plate 1, a piece of barrier film 9, one piece of negative terminal sub-pole plate 2, the ground of a piece of barrier film 9 repeat to place extremely
Certain amount, or again sequentially with one piece of negative terminal sub-pole plate 2, a piece of barrier film 9, one piece of anode sub-pole plate 1,
The a piece of ground of barrier film 9 is repeated to place to certain amount, and pressure cover plate 4 is finally placed on one again thereon;Wherein
In all pole plates uppermost one piece be anode sub-pole plate 1 or negative terminal sub-pole plate 2, all anode sub-pole plates 1
End line both facing to first orientation, the end lines of all negative terminal sub-pole plates 2 both facing to second orientation, first orientation and
Second orientation is adjacent or relative, and is not located at the orientation where two blocks of side plates 5.For example, two blocks of side plates 5
Positioned at former and later two orientation, and accordingly, first orientation is left bit, and second orientation is right bit.
Step S07:By a pressing machine by upper pressure cover plate 4, lower pressure cover plate 3 and two pieces of clampings of side plate 5
Fix to obtain battery.In one embodiment, by a pressing machine by upper pressure cover plate 4, lower pressure cover plate
3 and two blocks of side plates 5 connect and fix to obtain during battery, design pressure will be press-fited and be set as 100kPa.
Step S09:By two blocks of terminal casting 6 end line respectively with anode sub-pole plate 1, negative terminal sub-pole plate 2
End line cast welding connection.
Step S11:The battery for being welded with terminal casting 6 is loaded in a battery case, had on battery case
There is a safe valve opening.Specifically, battery is first loaded into the unclosed battery case 7 in a lower surface, then it is electric with one
The lower surface of 8 pairs of battery cases of pond lid is sealed, to complete the encapsulation to battery.
Step S13:By the safe valve opening on battery case into battery case acid filling liquid.
Step S15:Single level battery is melted into.Afterwards, it is then exhausted from above-mentioned unnecessary acid solution.
Step S17:The safety valve 10 of an adaptation is installed on safe valve opening on battery case.Certainly,
Other facility parts can also be installed on battery case, such as battery handle 11.
In addition, in a preferred embodiment, the manufacture method of single level battery also includes:Outside by battery
Safe valve opening on shell will first be evacuated into battery case before acid filling liquid in battery case;And to institute
State after single level battery is melted into, in addition to the sour step of a control.
According to above-mentioned manufacture method, it can produce the battery of Large Copacity, and it can be seen that it need not be again
To carrying out filling Lasaxing Oilfield in battery, therefore process is reduced, save raw material paraffin.
Single level battery and its manufacture method that the application is provided, enough material savings, solve horizontal double pole
The positive and negative lead plaster ratio of battery pole plates is inconsistent and influences deep battery discharge service life, it is ensured that realize cell
The excellent sealing of compole group, reduction horizon battery self discharge, improve the standard battery consistency and battery life,
Ensure to keep other excellent properties (such as high current charge-discharge) of horizon battery unaffected simultaneously.
Above content is to combine the further description that specific embodiment is made to the application, it is impossible to recognized
The specific implementation for determining the application is confined to these explanations.For the ordinary skill of the application art
For personnel, on the premise of the present application design is not departed from, some simple deductions can also be made or replaced
Change.