CN107298896A - A kind of preparation method of domestic ceramics Yellow ceramic ink - Google Patents
A kind of preparation method of domestic ceramics Yellow ceramic ink Download PDFInfo
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- CN107298896A CN107298896A CN201710478833.2A CN201710478833A CN107298896A CN 107298896 A CN107298896 A CN 107298896A CN 201710478833 A CN201710478833 A CN 201710478833A CN 107298896 A CN107298896 A CN 107298896A
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- yellow
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- zirconium
- ceramic ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
- C09C1/0012—Pigments for ceramics containing zirconium and silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/041—Grinding
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a kind of preparation method of domestic ceramics Yellow ceramic ink, simple production process of the present invention, Industry Control of being easy to, the zirconium pr-yellow material high temperature resistant of production, color developing effect are good, and the ceramic ink being made of it is not leaded, mercury, suspendability, colorant is uniformly dispersed, and develop the color excellent, the printing for colouring, the overglaze color of domestic ceramics, safety and environmental protection, hair color effect is good, while production efficiency is high, product quality is high.
Description
Technical field
The present invention relates to ceramic technology field, more particularly to a kind of domestic ceramics Yellow ceramic ink preparation method and
Its preparation method.
Background technology
The decoration of ceramic experienced after screen printing and rubber roll stamp, start the height of inkjet printing again in recent years
Tide.Inkjet technology has many unrivaled advantages compared with silk screen and rubber roll stamp：One is inkjet printing decoration
Product pattern exquisiteness true to nature, fine degree is close with high-resolution picture, and the pattern definition of traditional decoration is not enough, the line of pattern
Reason change is also without enriching that inkjet printing is decorated；Two be that inkjet technology can realize personalized designs and manufacture, its energy
The requirement of personalization is reached within the extremely short time, current decorating ceramic products fashion, personalization, small lot is more suitable for
Development trend；Three be that inkjet printing is a kind of contactless decorating method, due to being not in contact with ceramic, to ceramic
Almost do not damage, and traditional screen printing and rubber roll stamp is contacted with ceramic, is easily caused product breakage；
Four be that inkjet technology can realize the decoration in various male and fomale(M＆F)s and oblique angle face, can print out more life-like imitative oil painting, imitate
The products such as bark, imitation wood line, imitative high-grade rock, although rubber roll can also be decorated in some male and fomale(M＆F)s, but applicable surface
Concavo-convex degree is not so good as inkjet printing, and inkjet technology is that ceramic decoration brings bigger design space.
Application of the yellow colorant in ceramic product especially domestic ceramic product is a lot of, but is beaten preparing ceramic ink jet
During the ceramic ink of print, ceramic pigment particle will be by ultra-fine grinding to sub-micron rank, and vanadium zirconium Huang is with nickel titanium yellow through too high
The broken of intensity develops the color almost without method afterwards, and vanadium bismuth Huang is not suitable for preparing ceramic ink because its resistance to elevated temperatures is poor yet,
Only zirconium pr-yellow material possesses certain tone after ultra-fine grinding, it is adaptable to the preparation of ceramic ink.Traditional zirconium praseodymium yellow
Colorant is after Solid phase synthesis, and its crystal particle diameter is generally 20 μm or so, and the maximum particle diameter of aggregate is likely to be breached 50 μm, is
The requirement of ceramic ink particle diameter is reached, it is necessary to carry out ultra-fine grinding by speed lapping.Traditional zirconium pr-yellow material is through ultra-fine
When being crushed to less than 1 μm, its color development ability is greatly reduced, it is impossible to meet requirement of the people to tone.To improve yellow ink
Colorability, be attempted to solve by increasing the solid content and particle diameter of ink, but to improve tone effect not
Substantially, while also causing the bad stability of ink, the cost of production ink also accordingly increases.This is accomplished by the life to zirconium praseodymium yellow
Production. art makes corresponding modification, and to produce, particle diameter is small and coloring effect is good, and resistant to elevated temperatures ceramic pigment.
The content of the invention
There is provided a kind of domestic ceramics Yellow ceramic ink for the defect that makes up prior art for the object of the invention
Preparation method.
The present invention is achieved by the following technical solutions：
A kind of preparation method of domestic ceramics Yellow ceramic ink, including step in detail below：
（1）Raw material Zirconium dioxide powder is crushed using airflow milling equipment, micron level zirconium dioxide is obtained, then with fitting
Silica, the praseodymium oxide of amount, which are put into batch mixer, to carry out doing point mixing 30-40 minutes, continuously adds appropriate potassium chloride, after
Continuous dry grinding 20-30 minutes, obtains mixed raw material；
（2）Mixed raw material is fitted into porcelain crucible, after capping by kaolin add appropriate water stir into after purees carry out it is close
Crucible after sealing, is then put into electric furnace by envelope, and 920-960 DEG C, after insulation is calcined 6-7 hours is warming up to certain speed
Naturally cool to room temperature；
（3）By step（2）The zirconium pr-yellow material crude product after cooling is burnt till to be put into ball mill and roughly ground, using zirconia ball as
Ball-milling medium, controls certain pellet water ratio, and ball milling is dried after 60-90 minutes, obtains zirconium pr-yellow material and once roughly grind powder,
It is then fed into airflow milling equipment and carries out airflow milling 20-30 minutes, obtains yellow colorant；
（4）Yellow colorant, water, ethylene glycol, Sodium Polyacrylate are well mixed and form slurry, is then fed into sand mill, with two
Zirconium oxide is medium, and it is 75-80%, milled processed 90-120 minutes to control charge ratio of media.
A kind of preparation method of domestic ceramics Yellow ceramic ink, step（1）（3）Described in airflow milling equipment carry out
The condition of airflow milling is：Compressed air is controlled in 0.7-0.8MPa, 50 hertz of frequency.
A kind of preparation method of domestic ceramics Yellow ceramic ink, step（1）Described in micron grade ZrO 2 with
Silica, the amount ratio of the material of praseodymium oxide are 1:1:0.01；The addition of described potassium chloride be micron grade ZrO 2 with
The 1-1.5% of silica total amount.
A kind of preparation method of domestic ceramics Yellow ceramic ink, step（2）Described in heated up with certain speed
Refer to the speed heating with 8-10 DEG C/min.
A kind of preparation method of domestic ceramics Yellow ceramic ink, step（3）Described in the certain pellet water of control
Ratio refers to zirconium pr-yellow material crude product：Zirconium oxide：Water is 1:2:1.
A kind of preparation method of domestic ceramics Yellow ceramic ink, step（3）Described in Sodium Polyacrylate addition
Measure as the 1-1.5% of yellow colorant；Described yellow colorant：Water：The ratio of ethylene glycol is 2：5：3.
It is an advantage of the invention that：Raw material Zirconium dioxide powder is ground into micron level by the present invention using airflow milling first,
Compared with the ball-milling technology used in the prior art, production efficiency is improved, while the zirconium dioxide diameter of particle after airflow milling
More tiny, specific surface area increase, the scission of link quantity of plane of crystal is more, and the activity of Zirconium dioxide powder can also increase, and promote
The generation of zirconium silicate crystal；By adding properly mixed praseodymium oxide, praseodymium element can burning till by suitable temperature, it is solid first
It is dissolved in zirconium dioxide, activates the lattice of zirconium dioxide, promotes the formation of zirconium silicate；Simultaneously because silicic acid of the praseodymium element in generation
Zirconium plane of crystal does not have enrichment phenomenon, and the colorant synthesized tone difference after ultra-fine grinding will not be caused larger, and generation
Zirconium silicate crystal is full and uniform in size, and colour developing is obvious, and high temperature resistant；Zirconium pr-yellow material crude product is subjected to once thick ball milling again
And secondary gas flow mill is fully ground, and obtains that granularity is small, the big colorant of specific surface area；Finally it will add suitable in yellow colorant
The compositions such as ethylene glycol, the Sodium Polyacrylate of amount are compounded, and then carry out extra-fine grinding by the zirconium dioxide of vast scale, and general
Logical grinding improves production efficiency, simultaneously because the dispersion effect of ethylene glycol and Sodium Polyacrylate, is obtained compared to the time has been saved
To viscosity is suitable, suspension is good, evengranular ceramic ink.
Simple production process of the present invention, Industry Control of being easy to, the zirconium pr-yellow material high temperature resistant of production, color developing effect are good, use
Ceramic ink that it is made is not leaded, mercury, and suspendability, colorant is uniformly dispersed, and develops the color excellent, colouring for domestic ceramics,
The printing of overglaze color, safety and environmental protection, hair color effect is good, while production efficiency is high, product quality is high.
Embodiment
A kind of preparation method of domestic ceramics Yellow ceramic ink, including step in detail below：
（1）123g raw materials Zirconium dioxide powder is crushed using airflow milling equipment, micron level zirconium dioxide is obtained, then
It is put into batch mixer do dividing with 60g silica, 10.2g praseodymium oxides and mixes 30 minutes, continuously adds 1.83g potassium chloride,
Continue to dry grind 20 minutes, obtain mixed raw material；
（2）Mixed raw material is fitted into porcelain crucible, after capping by kaolin add appropriate water stir into after purees carry out it is close
Crucible after sealing, is then put into electric furnace by envelope, and 920 DEG C are warming up to 8 DEG C/min speed, is incubated after being calcined 6 hours certainly
So it is cooled to room temperature；
（3）By step（2）Burn till the zirconium pr-yellow material crude product after cooling and be put into and appropriate water is added in ball mill roughly ground,
Using zirconia ball as ball-milling medium, zirconium pr-yellow material crude product is controlled：Zirconium oxide：Water=1:2:1, ball milling is dried after 60 minutes, is obtained
Powder is once roughly ground to zirconium pr-yellow material, is then fed into airflow milling equipment and carries out airflow milling 20 minutes, obtain yellow colorant；
（4）Yellow colorant, 475g water, 285g ethylene glycol, 1.9g Sodium Polyacrylates are well mixed and form slurry, sand is then fed into
In grinding machine, using zirconium dioxide as medium, it is 75%, milled processed 90 minutes to control charge ratio of media.
Claims (6)
1. a kind of preparation method of domestic ceramics Yellow ceramic ink, it is characterised in that including step in detail below：
（1）Raw material Zirconium dioxide powder is crushed using airflow milling equipment, micron level zirconium dioxide is obtained, then with fitting
Silica, the praseodymium oxide of amount, which are put into batch mixer, to carry out doing point mixing 30-40 minutes, continuously adds appropriate potassium chloride, after
Continuous dry grinding 20-30 minutes, obtains mixed raw material；
（2）Mixed raw material is fitted into porcelain crucible, after capping by kaolin add appropriate water stir into after purees carry out it is close
Crucible after sealing, is then put into electric furnace by envelope, and 920-960 DEG C, after insulation is calcined 6-7 hours is warming up to certain speed
Naturally cool to room temperature；
（3）By step（2）The zirconium pr-yellow material crude product after cooling is burnt till to be put into ball mill and roughly ground, using zirconia ball as
Ball-milling medium, controls certain pellet water ratio, and ball milling is dried after 60-90 minutes, obtains zirconium pr-yellow material and once roughly grind powder,
It is then fed into airflow milling equipment and carries out airflow milling 20-30 minutes, obtains yellow colorant；
（4）Yellow colorant, water, ethylene glycol, Sodium Polyacrylate are well mixed and form slurry, is then fed into sand mill, with two
Zirconium oxide is medium, and it is 75-80%, milled processed 90-120 minutes to control charge ratio of media.
2. a kind of preparation method of domestic ceramics Yellow ceramic ink according to claim 1, it is characterised in that step
（1）（3）Described in airflow milling equipment carry out airflow milling condition be：Compressed air is controlled in 0.7-0.8MPa, 50 hertz of frequency
Hereby.
3. a kind of preparation method of domestic ceramics Yellow ceramic ink according to claim 1, it is characterised in that step
（1）Described in micron grade ZrO 2 and silica, the amount ratio of the material of praseodymium oxide be 1:1:0.01；Described potassium chloride
Addition for micron grade ZrO 2 and silica total amount 1-1.5%.
4. a kind of preparation method of domestic ceramics Yellow ceramic ink according to claim 1, it is characterised in that step
（2）Described in the speed heating referred to certain speed heating with 8-10 DEG C/min.
5. a kind of preparation method of domestic ceramics Yellow ceramic ink according to claim 1, it is characterised in that step
（3）Described in the certain pellet water ratio of control refer to zirconium pr-yellow material crude product：Zirconium oxide：Water is 1:2:1.
6. a kind of preparation method of domestic ceramics Yellow ceramic ink according to claim 1, it is characterised in that step
（3）Described in Sodium Polyacrylate addition be yellow colorant 1-1.5%；Described yellow colorant：Water：The ratio of ethylene glycol
It is worth for 2：5：3.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710478833.2A CN107298896A (en) | 2017-06-22 | 2017-06-22 | A kind of preparation method of domestic ceramics Yellow ceramic ink |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710478833.2A CN107298896A (en) | 2017-06-22 | 2017-06-22 | A kind of preparation method of domestic ceramics Yellow ceramic ink |
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| CN201710478833.2A Pending CN107298896A (en) | 2017-06-22 | 2017-06-22 | A kind of preparation method of domestic ceramics Yellow ceramic ink |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115572158A (en) * | 2022-11-18 | 2023-01-06 | 淄博坤阳陶瓷有限公司 | Ivory porcelain and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194493A (en) * | 2014-08-07 | 2014-12-10 | 淄博陶正陶瓷颜料有限公司 | Formula of special praseodymium yellow pigment for ink and production method of special praseodymium yellow pigment |
| CN105198493A (en) * | 2015-10-09 | 2015-12-30 | 秦威 | Yellow pigment composition of ceramic ink and preparation method thereof |
| CN105198495A (en) * | 2015-10-20 | 2015-12-30 | 佛山市华意陶瓷颜料有限公司 | Small-particle-diameter praseodymium zirconium yellow ceramic pigment and preparation method thereof |
| CN106715608A (en) * | 2014-09-19 | 2017-05-24 | 司马塞拉姆科公司 | Ceramic ink for inkjet printing |
-
2017
- 2017-06-22 CN CN201710478833.2A patent/CN107298896A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194493A (en) * | 2014-08-07 | 2014-12-10 | 淄博陶正陶瓷颜料有限公司 | Formula of special praseodymium yellow pigment for ink and production method of special praseodymium yellow pigment |
| CN106715608A (en) * | 2014-09-19 | 2017-05-24 | 司马塞拉姆科公司 | Ceramic ink for inkjet printing |
| CN105198493A (en) * | 2015-10-09 | 2015-12-30 | 秦威 | Yellow pigment composition of ceramic ink and preparation method thereof |
| CN105198495A (en) * | 2015-10-20 | 2015-12-30 | 佛山市华意陶瓷颜料有限公司 | Small-particle-diameter praseodymium zirconium yellow ceramic pigment and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115572158A (en) * | 2022-11-18 | 2023-01-06 | 淄博坤阳陶瓷有限公司 | Ivory porcelain and preparation method thereof |
| CN115572158B (en) * | 2022-11-18 | 2023-02-28 | 淄博坤阳陶瓷有限公司 | Ivory porcelain and preparation method thereof |
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Application publication date: 20171027 |
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