CN107236510A - A kind of beauty of architecture seam glue and preparation method thereof - Google Patents
A kind of beauty of architecture seam glue and preparation method thereof Download PDFInfo
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- CN107236510A CN107236510A CN201710558012.XA CN201710558012A CN107236510A CN 107236510 A CN107236510 A CN 107236510A CN 201710558012 A CN201710558012 A CN 201710558012A CN 107236510 A CN107236510 A CN 107236510A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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Abstract
A kind of beauty of architecture stitches glue, includes 100 parts of hybrid resin, 0~20 part of plasticizer, 100~400 parts of calcium carbonate, 0~3 part of ultra-violet absorber, 0~3 part of 2~12 parts of silane coupler, 3~10 parts of silane crosslinker and catalyst by quality component ratio.The invention has the advantages that：1st, environment-protecting and non-poisonous, Diamond Search, to environment and human body non-hazardous, belongs to green product；2nd, construction technology is simple, and extrudability good, sagging is not collapsed；3rd, it is good to caking property such as ceramic tile, marbles after solidifying, ceramic tile will not be polluted, flatness is high, and bright in color, with certain toughness, can guarantee that brickwork joint is concordant with brick face, prevent hollowing and loosening；4th, bright in colour fine and smooth, smooth after solidifying, color is well-balanced, and can arbitrarily arrange in pairs or groups multiple color as needed；5th, waterproof and dampproof, not blackening is not mouldy, does not shelter evil people and countenance evil practices, easy to clean, is especially suitable for the high shunting yard institute such as hotel, discotheque, luxurious house, meeting room.
Description
Technical field
The present invention relates to a kind of polymeric material field, more particularly to a kind of beauty of architecture seam glue and preparation method thereof, this is built
Build joint filling, sealing and waterproof that U.S. seam glue is mainly used in the places such as indoor decoration, hotel, meeting room.
Background technology
With social progress, the raising of resident living quality, the series of products such as traditional gap filler, gap-filling glue make for a long time
The phenomenon such as discoloration, mouldy, peculiar smell occurs after, many inconvenience to resident living band；More importantly hotel, discotheque,
The high shunting yard institute such as meeting room, does not reach that princely, warm luxurious finishing effect at all, has perplexed decoration row always yet
Industry personage.
In construction decoration industry, traditional gap-filling glue, gap filler are roughly divided into three kinds：The first is white cement base joint filling
Agent, it is stirred by white cement and fine sand, and simple production process is cheap, of poor quality, and shortcoming is apparent；It is for second
Mono-component aqueous joint trimming agent, it adds different powders and auxiliary agent point by the polymer such as acrylic emulsion or aqueous epoxy resins
Dissipate and form, such joint trimming agent is quickly grown, application surface is extensively, simple to operate, color variation, but solidification after-contraction is substantially,
Easily shelter evil people and countenance evil practices, the mouldy blackening of meeting influences attractive in appearance；The third is two-component or multicomponent oiliness U.S. seam glue, such joint trimming agent
Very hard after solidification, light bright in colour is not collapsed, and not mouldy, aesthetics is fine, but complicated construction technique, it is necessary to T-me line
Paper, it is easy to pollute ceramic tile, and curing agent is poisonous, not environmentally, has injury to human body.
Therefore, it is necessary to be further improved to existing joint trimming agent.
The content of the invention
It is funginert that the purpose of the present invention aims to provide a kind of good environment-protecting and non-poisonous, application property, light bright in colour, not blackening
Beauty of architecture seam glue and preparation method thereof, to overcome weak point of the prior art, it has overturned people to traditional joint trimming agent
View, solves the puzzlement of decoration industry personage, allows people preferably to enjoy the life of high-quality.
A kind of beauty of architecture designed by this purpose stitches glue, it is characterised in that：Include hybrid resin 100 by quality component ratio
Part, 0~20 part of plasticizer, 100~400 parts of calcium carbonate, 0~3 part of ultra-violet absorber, 2~12 parts of silane coupler, crosslinkable silane
Join 0~3 part of 3~10 parts of agent and catalyst.
The hybrid resin is that, with siloxane blocking, main chain is the molecular structure of polyethers, and structural formula is：(RO)3SiO
[(CH2) 3O] nSi (RO) 3, wherein R are C1~C2 alkyl, and n is main chain number of repeat unit.
The plasticizer be polyether polyols alcohols or phthalic ester plasticizer, including：The different nonyl of phthalic acid two
Ester, phthalic acid two (2- ethyl hexyls) ester, n-butyl phthalate, diisooctyl phthalate, phthalic acid
Bark mutter glycol, polypropylene glycol, phthalic acid two of diisobutyl ester, di-n-octyl phthalate, polyethylene glycol, poly- tetrahydrochysene is different pungent
One or more of mixing in ester, repefral, diamyl phthalate, molecular weight is 200~5000.
The calcium carbonate is surface aliphatic acid or stearic acid-treated nanometer grade calcium carbonate, coarse whiting, silicon powder, talcum
One or more of mixing in powder kaolin.
The ultra-violet absorber includes：The UV-3529 of BASF, UV-3581, UV-3346, UV-320, UV-326,
One or more combination in UV-329, UV-3583, UV-327, UV-328.
The silane coupler includes tetramethoxy-silicane, MTMS, MTES, ethene
One or more combination in base trimethoxy silane, VTES.
The silane crosslinker includes γ-aminopropyltrimethoxysilane, the γ-ethoxy of [oxygen of (2,3)-epoxy third] propyl group three
Base silane, aminophenyl trimethoxy silane, gamma-aminopropyl-triethoxy-silane, N- (β-aminoethyl)-γ-aminopropyltriethoxy two
Ethoxysilane, ureido-propyl trimethoxy silane, r-chloropropyl trimethoxyl silane, chloropropyl triethoxysilane, N- (β-ammonia
Ethyl)-γ-aminopropyltrimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, γ-[(2,3)-epoxy
Third oxygen] propyl trimethoxy silicane, aminophenyl second methoxy silane, N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxy silicon
One or more combination in alkane, ureidopropyltriethoxysilane.
The catalyst is organotin catalysts, including：Dibutyl tin laurate, dibutyltin diacetate, two octanoic acids
One or more combination in dibutyl tin, stannous octoate, butyric acid tin.
Above-mentioned beauty of architecture stitches the preparation method of glue, it is characterised in that：Comprise the following steps：
(1) hybrid resin, the silane coupler of part, plasticizer, ultra-violet absorber and calcium carbonate are added in batches
Double-planet power mixer high-speed stirred, vacuum be 0.085~0.099Mpa under be dehydrated 1~2 hour, rotating speed be 800~
1200rpm；
(2) remaining silane coupler is added in planet machine agitator, stirred in the case where vacuum is 0.085~0.099Mpa
30~40min is mixed, rotating speed is 300~800rpm；
(3) silane crosslinker and catalyst are added in planet machine agitator, in the case where vacuum is 0.085~0.099Mpa
30~45min is stirred, rotating speed is 300~800rpm, and packing discharging obtains the beauty of architecture seam glue.
The invention has the advantages that：
1st, this beauty of architecture seam glue is environment-protecting and non-poisonous, and Diamond Search, to environment and human body non-hazardous, belongs to green product；
2nd, this beauty of architecture seam glue construction technology is simple, and extrudability good, sagging is not collapsed；
3rd, it is good to caking property such as ceramic tile, marbles after the adhesive curing of this beauty of architecture seam, ceramic tile will not be polluted, flatness is high, color
Damp light, with certain toughness, can guarantee that brickwork joint is concordant with brick face, prevents hollowing and loosening；
4th, bright in colour fine and smooth, smooth after the adhesive curing of this beauty of architecture seam, color is well-balanced, can arbitrarily arrange in pairs or groups as needed a variety of
Color；
5th, this beauty of architecture seam glue is waterproof and dampproof, and not blackening is not mouldy, does not shelter evil people and countenance evil practices, easy to clean, is especially suitable for hotel, enlightening
The high shunting yard institute such as the Room, luxurious house, meeting room.
Embodiment
With reference to embodiment, the invention will be further described.
First embodiment
This beauty of architecture seam glue includes 100 parts of hybrid resin by quality component ratio, 3 parts of plasticizer, 200 parts of calcium carbonate, ultraviolet
0.5 part of light absorbers, 0.8 part of 3 parts of silane coupler, 3 parts of silane crosslinker and catalyst.
Furtherly, hybrid resin is that, with siloxane blocking, main chain is the molecular structure of polyethers, and structural formula is：(RO)
3SiO [(CH2) 3O] nSi (RO) 3, wherein R are C1~C2 alkyl, and n is main chain number of repeat unit.
Furtherly, calcium carbonate is that surface aliphatic acid or stearic acid-treated nanometer grade calcium carbonate, coarse whiting, silicon are micro-
One or more of mixing in powder, talcum powder kaolin.
Furtherly, plasticizer is polyethylene glycol, and molecular weight is 800；Ultra-violet absorber UV-328；Silane coupler is
MTES；Silane crosslinker is γ-aminopropyltrimethoxysilane；Catalyst is dibutyl tin laurate.
Its preparation method comprises the following steps：
(1) by hybrid resin, the MTES of part, polyethylene glycol, UV-328 and nano-calcium carbonate in batches
Secondary addition double-planet power mixer high-speed stirred, vacuum is is dehydrated 1 hour under 0.099Mpa, rotating speed is 800rpm；
(2) remaining MTES is added in planet machine agitator, stirred in the case where vacuum is 0.099Mpa
40min, rotating speed is 300rpm；
(3) γ-aminopropyltrimethoxysilane and dibutyl tin laurate are added in planet machine agitator, in vacuum
Spend to stir 45min under 0.099Mpa, rotating speed is 800rpm, packing discharging, obtain the beauty of architecture seam glue.
Second embodiment
This beauty of architecture seam glue includes 100 parts of hybrid resin by quality component ratio, 10 parts of plasticizer, 260 parts of calcium carbonate, ultraviolet
1 part of light absorbers, 1 part of 5 parts of silane coupler, 6 parts of silane crosslinker and catalyst.
Furtherly, plasticizer is that poly- tetrahydrochysene is barked glycol of muttering, and molecular weight is 2000；Ultra-violet absorber is UV-326；Silicon
Alkane coupling agent is vinyltrimethoxy silane；Silane crosslinker is N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxy silicon
Alkane；Catalyst is stannous octoate.
Its preparation method comprises the following steps：
(1) hybrid resin, part vinyltrimethoxy silane, poly- tetrahydrochysene are barked glycol, UV-326 and the nano-calcium carbonate of muttering
Calcium adds double-planet power mixer high-speed stirred in batches, and vacuum is is dehydrated 1.5 hours under 0.099Mpa, rotating speed is
1000rpm；
(2) remaining vinyltrimethoxy silane is added in planet machine agitator, in the case where vacuum is 0.099Mpa
30min is stirred, rotating speed is 400rpm；
(3) N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane and stannous octoate are added into planet machine agitator
It is interior, 35min is stirred in the case where vacuum is 0.099Mpa, rotating speed is 600rpm, packing discharging obtains the beauty of architecture seam glue.
Other not described same first embodiments in part, here no longer analytic explanation.
3rd embodiment
This beauty of architecture seam glue includes 100 parts of hybrid resin by quality component ratio, 16 parts of plasticizer, 280 parts of calcium carbonate, ultraviolet
1.2 parts of light absorbers, 1.2 parts of 7 parts of silane coupler, 9 parts of silane crosslinker and catalyst.
Furtherly, plasticizer is diisononyl phthalate；Ultra-violet absorber is UV-3583；Silane coupler
For VTES；Silane crosslinker is ureido-propyl trimethoxy silane；Catalyst is dibutyltin diacetate.
Its preparation method comprises the following steps：
(1) by hybrid resin, part VTES, diisononyl phthalate, UV-3583 and carbonic acid
Calcium adds double-planet power mixer high-speed stirred in batches, and vacuum is is dehydrated 2 hours under 0.099Mpa, rotating speed is
900rpm；
(2) remaining VTES is added in planet machine agitator, in the case where vacuum is 0.099Mpa
40min is stirred, rotating speed is 500rpm；
(3) ureido-propyl trimethoxy silane and dibutyltin diacetate are added in planet machine agitator, in vacuum
To stir 30min under 0.099Mpa, rotating speed is 700rpm, packing discharging, obtains the beauty of architecture seam glue.
Other not described same first embodiments in part, here no longer analytic explanation.
Fourth embodiment
This beauty of architecture seam glue includes 100 parts of hybrid resin, 150 parts of calcium carbonate, ultra-violet absorber 0.9 by quality component ratio
Part, 6 parts of 4 parts of silane coupler and silane crosslinker.
Furtherly, plasticizer is butyl benzyl phthalate；Ultra-violet absorber is UV-3583；Silane coupler
For tetramethoxy-silicane；Silane crosslinker is aminophenyl trimethoxy silane；Catalyst is two sad dibutyl tins.
Its preparation method comprises the following steps：
(1) by hybrid resin, part tetramethoxy-silicane, butyl benzyl phthalate, UV-3583 and calcium carbonate in batches
Secondary addition double-planet power mixer high-speed stirred, vacuum is is dehydrated 1 hour under 0.099Mpa, rotating speed is 1000rpm；
(2) remaining tetramethoxy-silicane is added in planet machine agitator, stirred in the case where vacuum is 0.099Mpa
30min, rotating speed is 700rpm；
(3) aminophenyl trimethoxy silane and two sad dibutyl tins are added in planet machine agitator, is in vacuum
35min is stirred under 0.099Mpa, rotating speed is 600rpm, packing discharging obtains the beauty of architecture seam glue.
Other not described same first embodiments in part, here no longer analytic explanation.
5th embodiment
This beauty of architecture seam glue includes 100 parts of hybrid resin by quality component ratio, 5 parts of plasticizer, 200 parts of calcium carbonate, ultraviolet
1.5 parts of light absorbers, 0.7 part of 5 parts of silane coupler, 5 parts of silane crosslinker and catalyst.
Furtherly, plasticizer is diisononyl phthalate；Ultra-violet absorber is UV-3583；Silane coupler
For VTES；Silane crosslinker is ureido-propyl trimethoxy silane；Catalyst is dibutyltin diacetate.
Its preparation method comprises the following steps：
(1) by hybrid resin, part VTES, diisononyl phthalate, UV-3583 and carbonic acid
Calcium adds double-planet power mixer high-speed stirred in batches, and vacuum is is dehydrated 2 hours under 0.099Mpa, rotating speed is
900rpm；
(2) remaining VTES is added in planet machine agitator, in the case where vacuum is 0.099Mpa
40min is stirred, rotating speed is 500rpm；
(3) ureido-propyl trimethoxy silane and dibutyltin diacetate are added in planet machine agitator, in vacuum
To stir 30min under 0.099Mpa, rotating speed is 700rpm, packing discharging, obtains the beauty of architecture seam glue.
Other not described same first embodiments in part, here no longer analytic explanation.
Raw material types, weight and technological parameter involved in the present invention is including but not limited to above-mentioned case study on implementation.
The present invention needs test architecture U.S. seam surface drying time of glue, sag, compression shear strength and to tile substrate
Caking property, tested according to following standard and method.
Surface drying time, sag, GB/T 13477-2002《Building sealant test method》
Compression shear strength, JC/T 547-2005《Ceramic wall and floor bricks adhesive》
Tile bonding, is conserved 28 days, or conserved 28 days under standard conditions in ceramic tile surface applying glue, and at the standard conditions
Progress is dried after soaked 7 days again and pulls peel test, the adhesive tape pulled open and the bond failure situation of ceramic tile surface is observed.If
Cohesional failure and tile substrate destruction are determined as that cementability is good；It is broken further according to interface if interfacial failure is judged to not being bonded
The area of bonding is gone bad to determine to be bonded percentage.
Following table is the testing result of the various embodiments described above：
The above-mentioned preferred scheme for the present invention, has been shown and described general principle, principal character and the present invention of the present invention
Advantage.Those skilled in the art should be recognized that the present invention is not limited to the above embodiments, above-described embodiment and specification
Described in merely illustrate the principles of the invention, without departing from the spirit and scope of the present invention the present invention also have it is various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent are defined.
Claims (9)
1. a kind of beauty of architecture stitches glue, it is characterised in that：By quality component ratio include 100 parts of hybrid resin, 0~20 part of plasticizer,
100~400 parts of calcium carbonate, 0~3 part of ultra-violet absorber, 2~12 parts of silane coupler, 3~10 parts of silane crosslinker and catalysis
0~3 part of agent.
2. beauty of architecture stitches glue according to claim 1, it is characterised in that：The hybrid resin is with siloxane blocking, main chain
For the molecular structure of polyethers, structural formula is：(RO) 3SiO [(CH2) 3O] nSi (RO) 3, wherein R are C1~C2 alkyl, based on n
Chain number of repeat unit.
3. beauty of architecture stitches glue according to claim 2, it is characterised in that：The plasticizer is polyether polyols alcohols or adjacent benzene two
Formate ester plasticizer, including：Diisononyl phthalate, phthalic acid two (2- ethyl hexyls) ester, phthalic acid two
N-butyl, diisooctyl phthalate, diisobutyl phthalate, di-n-octyl phthalate, polyethylene glycol, poly- four
Hydrogen, which is barked, mutters in glycol, polypropylene glycol, diisooctyl phthalate, repefral, diamyl phthalate
One or more mixing, molecular weight is 200~5000.
4. beauty of architecture stitches glue according to claim 3, it is characterised in that：The calcium carbonate is surface aliphatic acid or stearic acid
One or more of mixing in treated nanometer grade calcium carbonate, coarse whiting, silicon powder, talcum powder kaolin.
5. beauty of architecture stitches glue according to claim 4, it is characterised in that：The ultra-violet absorber includes：The UV- of BASF
3529th, the one or more in UV-3581, UV-3346, UV-320, UV-326, UV-329, UV-3583, UV-327, UV-328
Combination.
6. beauty of architecture stitches glue according to claim 5, it is characterised in that：The silane coupler include tetramethoxy-silicane,
One in MTMS, MTES, vinyltrimethoxy silane, VTES
Plant or several combinations.
7. beauty of architecture stitches glue according to claim 6, it is characterised in that：The silane crosslinker includes γ-aminopropyl front three
TMOS, γ-[oxygen of (2,3)-epoxy third] propyl-triethoxysilicane, aminophenyl trimethoxy silane, the second of γ-aminopropyl three
TMOS, N- (β-aminoethyl)-γ-aminopropyltriethoxy diethoxy silane, ureido-propyl trimethoxy silane, chloropropyl three
Methoxy silane, chloropropyl triethoxysilane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, N- (β-ammonia second
Base)-gamma-aminopropyl-triethoxy-silane, γ-[oxygen of (2,3)-epoxy third] propyl trimethoxy silicane, aminophenyl second methoxyl group
Silane, N- (β-aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, one kind in ureidopropyltriethoxysilane or several
Plant combination.
8. beauty of architecture stitches glue according to claim 7, it is characterised in that：The catalyst is organotin catalysts, including：Two
One or more of groups in dibutyl tin laurate, dibutyltin diacetate, two sad dibutyl tins, stannous octoate, butyric acid tin
Close.
9. the preparation method of glue is stitched according to any one of the claim 1-8 beauty of architecture, it is characterised in that：Comprise the following steps：
(1) hybrid resin, the silane coupler of part, plasticizer, ultra-violet absorber and calcium carbonate are added into duplicate rows in batches
Star power mixer high-speed stirred, vacuum be 0.085~0.099Mpa under be dehydrated 1~2 hour, rotating speed be 800~
1200rpm；
(2) remaining silane coupler is added in planet machine agitator, 30 is stirred in the case where vacuum is 0.085~0.099Mpa
~40min, rotating speed is 300~800rpm；
(3) silane crosslinker and catalyst are added in planet machine agitator, stirred in the case where vacuum is 0.085~0.099Mpa
30~45min, rotating speed is 300~800rpm, and packing discharging obtains the beauty of architecture seam glue.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603526A (en) * | 2017-11-02 | 2018-01-19 | 嘉善天胶装饰材料有限公司 | A kind of acrylate receives side glue and preparation method thereof |
| CN110845990A (en) * | 2019-11-21 | 2020-02-28 | 江门大光明粘胶有限公司 | Ceramic tile crack beautifying agent and preparation method thereof |
| CN111500241A (en) * | 2020-04-27 | 2020-08-07 | 上海善治环境技术有限公司 | Permeable adhesive applied to pipeline repair and preparation method thereof |
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| WO2011000737A1 (en) * | 2009-06-30 | 2011-01-06 | Wacker Chemie Ag | Adhesive or sealing compounds containing alkoxysilane-terminated polymers |
| CN102660214A (en) * | 2012-04-06 | 2012-09-12 | 江苏天辰硅材料有限公司 | Monocomponent flame-retardant silane modified polyether sealant and preparation method thereof |
| CN106590501A (en) * | 2016-12-26 | 2017-04-26 | 广东长鹿精细化工有限公司 | Single-component epoxy modified silicone sealant and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107603526A (en) * | 2017-11-02 | 2018-01-19 | 嘉善天胶装饰材料有限公司 | A kind of acrylate receives side glue and preparation method thereof |
| CN110845990A (en) * | 2019-11-21 | 2020-02-28 | 江门大光明粘胶有限公司 | Ceramic tile crack beautifying agent and preparation method thereof |
| CN111500241A (en) * | 2020-04-27 | 2020-08-07 | 上海善治环境技术有限公司 | Permeable adhesive applied to pipeline repair and preparation method thereof |
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Application publication date: 20171010 |