CN107212460A - The natural eutectic solvent humectant for smoke of lemon acid type and its application in cigarette - Google Patents
The natural eutectic solvent humectant for smoke of lemon acid type and its application in cigarette Download PDFInfo
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- CN107212460A CN107212460A CN201710545074.7A CN201710545074A CN107212460A CN 107212460 A CN107212460 A CN 107212460A CN 201710545074 A CN201710545074 A CN 201710545074A CN 107212460 A CN107212460 A CN 107212460A
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- eutectic solvent
- acid type
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- humectant
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
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Abstract
A kind of natural eutectic solvent humectant for smoke of lemon acid type and its preparation method and application, the humectant is mixed with by following components to be formed：The natural eutectic solvent of lemon acid type 10% 50%, preservative 0.1% 0.5%, defoamer 0.1% 0.5%, surplus is water.The humectant of the present invention is applied to cigarette humectation, the degrading resistance property of tobacco can not only be improved, reduce making for tobacco leaf broken, reduce the consumption of cigarette tobacco leaf in process, and the effects such as jealous and mouthfeel, reduction flue gas stimulation can also be improved, serve while improving the effect of the humectation of tobacco physics and sense organ humectation.It is an advantage of the invention that the natural eutectic solvent synthetic method of lemon acid type is simple, and it is non-volatile, it is nonflammable；Synthesis material is natural products, is also the composition contained in tobacco, environmental protection；Meanwhile, synthesis material is also flue gas latent aromatic substance, has certain effect to improving cigarette sense organ fragrance, with potential popularizing application prospect.
Description
Technical field
The present invention relates to a kind of tobacco additive agent technology, the specifically natural eutectic solvent tobacco humectation of lemon acid type
The preparation of agent and its application in cigarette, the humectant environmental protection are protected with improvement tobacco physics humectation simultaneously and sense organ
The double effectses of profit.
Background technology
Tobacco humectant can improve the physical property of tobacco, strengthen its humectation and wettability power, reduce tobacco leaf processed
Making in journey is broken.Meanwhile, also there is humectant reduction flue gas to stimulate, improve jealous and mouthfeel effect.At present, China tobacco row
It is main in industry that humectant is used as using polyhydroxy substances such as glycerine, propane diols, xylitol and sorbierites.But, propane diols is in volume
To produce acetaldehyde and acetone in cigarette aspiration procedure, harmful substances from flue gases content is caused to raise.Meanwhile, propane diols can also give flue gas
Bring penetrating odor.Therefore, with the development of modern science and technology, the exploitation to new type natural humectant at present turns into the heat of research
Point.
Eutectic solvent was reported first in 2003 by Abbott etc., referred to, by hydrogen bond donor and hydrogen bond receptor, pass through hydrogen
Binary or the eutectic mixture of ternary that key effect is combined.It is liquid under eutectic solvent normal temperature, is that a class is new
Ionic liquid.As ionic liquid, eutectic solvent volatility is low, fusing point is low, nonflammable；Meanwhile, eutectic solvent also has
There is the features such as non-toxic, synthesis is simple, biodegradable, environment-friendly.Natural eutectic solvent refers to by native compound（Such as
Sugar, amino acid, organic acid etc.）The eutectic solvent of composition, is widely present in plant.Because water can be molten with natural eutectic
Hydrogen bond action in agent, natural eutectic solvent has excellent water retention property.Meanwhile, natural eutectic solvent is basic by plant
Metabolome is the composition that tobacco contains in itself into, green natural, is important flavor precursor.Therefore, develop natural
Eutectic solvent has very strong practical value to improving tobacco physics humectation ability and improving cigarette taste, with wide popularization
Application prospect.
The content of the invention
A kind of new cheap, lemon of environmental protection that the purpose of the present invention is based on above-mentioned prior art situation and developed
Natural eutectic solvent tobacco humectant of lemon acid type and its preparation method and application, the humectant is with the natural eutectic of lemon acid type
Solvent is raw material, the double effects with improvement tobacco physics humectation and sense organ humectation simultaneously.
The purpose of the present invention is achieved through the following technical solutions：
A kind of natural eutectic solvent tobacco humectant of lemon acid type, be mixed with by following components in percentage by weight and
Into：The natural eutectic solvent 10%-50% of lemon acid type, preservative 0.1%-0.5%, defoamer 0.1%-0.5%, surplus are water, pH
It is worth for neutrality；
The natural eutectic solvent of lemon acid type includes following binary eutectic solvent：Citric acid-sucrose, citric acid-grape
Sugar, citric acid-D-MANNOSE, citric acid-sorbose, citric acid-galactolipin or citric acid-proline.
The synthetic method of the natural eutectic solvent of lemon acid type has following two：
Synthetic method one：Citric acid and another component are included into sucrose, glucose, D-MANNOSE, sorbose, galactolipin, dried meat ammonia
The solid powder of acid is according to mol ratio 1:3-1:1 is added in round-bottomed flask, and heating water bath stirring is until transparency liquid is formed；Water
It is 80 to bathe heating-up temperatureoC-90 oC, the reaction time is 2-3 h；
Synthetic method two：Citric acid and another component are included into sucrose, glucose, D-MANNOSE, sorbose, galactolipin, dried meat ammonia
The solid powder of acid is according to mol ratio 1:3-1:1 is added in round-bottomed flask, adds water, and the addition of water is total for two kinds of solid powders
The 10%-50% of weight, then heating water bath stirring is until transparency liquid is formed；Water bath heating temperature is 40oC-60 oC, reaction
Time is 2-3 h.
Compared with synthetic method one, synthetic method two is that water is added in building-up process, synthesis of natural eutectic solvent
Water-bath temperature is lower.
The preparation method of the natural eutectic solvent tobacco humectant of lemon acid type is as follows：By the citric acid of above-mentioned synthesis
The natural eutectic solvent of type is proportionally added into water, and pH is to neutrality for regulation, then adds 0.1%-0.5% preservative, 0.1%-
0.5% defoamer can be prepared by the natural eutectic solvent humectant of lemon acid type.
It is hydrochloric acid or sodium hydrate aqueous solution to adjust pH value agents useful for same, and aqueous hydrochloric acid solution concentration is that weight compares 0.5-5%；
Sodium hydrate aqueous solution concentration is that weight compares 0.5-10%.
The natural eutectic solvent tobacco humectant of lemon acid type is uniformly sprayed in pipe tobacco, with improvement tobacco simultaneously
The effect of humectation and sense organ humectation is managed, consumption is the 0.1%-1.5% of tobacco quality.
It is an advantage of the invention that raw materials used is the natural eutectic solvent of lemon acid type, environmental protection.Lemon acid type is natural
Eutectic solvent is non-volatile, nonflammable, and synthetic method is simple；Synthesis material is natural products, be also contain in tobacco into
Point, environmental protection；Meanwhile, synthesis material is also flue gas latent aromatic substance, has certain effect to improving cigarette sense organ fragrance.Cause
This, the natural eutectic solvent of lemon acid type not only has the effect of tobacco humectation, and smoke perfume harmony is good.Pass through addition
The natural eutectic solvent tobacco humectant of lemon acid type in the present invention, can improve the degrading resistance property of tobacco, reduce cigarette cigarette
Leaf in process make broken, while jealous, the mouthfeel of cigarette smoke can also be improved, improve the humectation of tobacco physics and sense organ
The effect of humectation.
Embodiment
Invention is described further with reference to embodiment, but the scope of the invention is not limited to these embodiments.
Embodiment 1. weighs citric acid and sucrose solids powder, according to mol ratio 1:1, total amount is 100g, is added to round bottom
In flask, 80oC water-baths are added and stirred, until transparency liquid is formed, the water-bath time is 2.5 hours.Will be synthesized
The water of 300 milliliters of addition in the natural eutectic solvent of citric acid-sucrose, the sodium hydroxide solution of mass fraction 5% regulation pH, which is added dropwise, is
It is neutral.Addition 1.2g preservatives and 1.2g defoamers can be prepared by the natural eutectic solvent humectant of lemon acid type.Weigh 10g guarantors
Moisten agent, be uniformly sprayed onto on 1000g pipe tobaccos, the consumption of humectant is quality of tobacco 1%.Cigarette sample is prepared with the pipe tobacco.
Embodiment 2. weighs citric acid and glucose solids powder, according to mol ratio 1:1, total amount is 100g, is added to circle
In the flask of bottom, 75oC water-baths are added and stirred, until transparency liquid is formed, the water-bath time is 3 hours.Will be synthesized
The water of 200 milliliters of addition in the natural eutectic solvent of citric acid-glucose, is added dropwise the sodium hydroxide solution of mass fraction 5% regulation pH
For neutrality.Addition 1.0g preservatives and 1.0g defoamers can be prepared by the natural eutectic solvent humectant of lemon acid type.Weigh 10g
Humectant, is uniformly sprayed onto on 1000g pipe tobaccos, and the consumption of humectant is quality of tobacco 1%.Cigarette sample is prepared with the pipe tobacco.
Embodiment 3. weighs citric acid and sorbose solid powder, according to mol ratio 1:2, total amount is 100g, is added simultaneously
30 milliliters of water, are added in round-bottomed flask, 50oC water-baths are added and stirred, until transparency liquid formed, and the water-bath time is
2 hours.300 milliliters of water will be added in the synthesized natural eutectic solvent of citric acid-sorbose, the hydrogen-oxygen of mass fraction 5% is added dropwise
It is neutrality to change sodium solution regulation pH.Addition 1.2g preservatives and 1.2g defoamers can be prepared by the natural eutectic solvent of lemon acid type
Humectant.10g humectants are weighed, are uniformly sprayed onto on 1000g pipe tobaccos, the consumption of humectant is quality of tobacco 1%.Use the pipe tobacco
Prepare cigarette sample.
Embodiment 4. weighs citric acid and proline solid powder, is 1 according to mol ratio:3, total amount is 100g, while plus
Enter 10 milliliters of water, be added in round-bottomed flask, 50oC water-baths are added and stirred, until transparency liquid is formed, the water-bath time
For 2.5 hours.300 milliliters of water will be added in the synthesized natural eutectic solvent of citric acid-proline, mass fraction is added dropwise
10% sodium hydroxide solution regulation pH is neutrality.It is naturally low that addition 1.2g preservatives and 1.2g defoamers can be prepared by lemon acid type
Congruent melting solvent humectant.10g humectants are weighed, are uniformly sprayed onto on 1000g pipe tobaccos, the consumption of humectant is quality of tobacco 1%.
Cigarette sample is prepared with the pipe tobacco.
The natural eutectic solvent of lemon acid type provided by the present invention is applied to cigarette industry production to be had preferably to cigarette
Physics humectation ability and sense organ humectation effect.Applicant is to inventing three kinds of provided embodiments with prior art in tobacco business
The propane diols mainly used has carried out the comparative evaluation of physics humectation ability, and evaluation result is shown in Table 1.Simultaneously to sense organ humectation effect
Contrast has been carried out using two kinds of different modes of smokeing panel test to smoke panel test, and 2 are seen by the evaluation result of tobacco additive agent sensory evaluating smoking's method.Press
The evaluation result of Sensory Quality of Cigarette evaluation method is shown in Table 3.
The physics humectation of the different humectants of table 1 is evaluated
Note：RH=relative humidity, pipe tobacco equilibration time is 48h
The sense organ humectation of the different humectants of table 2 is evaluated（Method one）
The sense organ humectation of table 3 is evaluated（Method two）
The natural eutectic solvent humectant for smoke of lemon acid type provided in four embodiments of the invention is protected as can be seen from Table 1
Outlet capacity is better than propane diols, there is preferable physics humectation effect to cigarette.In sensory evaluation, it is total that judging panel gives character property
Knot：Propane diols free from extraneous odour, perfume quantity is sufficient, and fragrance is sent out more thoroughly, and flue gas slightly shows coarse, slightly stimulates；Lemon acid type is natural low common
Molten solvent humectant for smoke free from extraneous odour, perfume quantity is sufficient, and fragrance is sent out more thoroughly, and flue gas is finer and smoother, soft, stimulates smaller, pleasant impression compared with
Totally, sweet tea is returned preferable.By table 2, table 3 it is also seen that the natural eutectic solvent humectant for smoke of lemon acid type can effectively change
The mouthfeel of kind flue gas, mitigates excitant and improves pleasant impression comfort level, sensory effects are better than propane diols, four used in prior art
Individual embodiment score is above propane diols.
Claims (6)
1. a kind of natural eutectic solvent tobacco humectant of lemon acid type, it is characterised in that：It is by the group of following percentage by weight
Divide to be mixed with and form：Lemon acid type natural eutectic solvent 10%-50%, preservative 0.1%-0.5%, defoamer 0.1%-0.5%,
Surplus is water, and pH value is neutrality；
The natural eutectic solvent of lemon acid type includes following binary eutectic solvent：Citric acid-sucrose, citric acid-grape
Sugar, citric acid-D-MANNOSE, citric acid-sorbose, citric acid-galactolipin or citric acid-proline.
2. the natural eutectic solvent tobacco humectant of lemon acid type according to claim 1, it is characterised in that：The lemon
The synthetic method of the natural eutectic solvent of acid type has following two：
Synthetic method one：Citric acid and another component are included into sucrose, glucose, D-MANNOSE, sorbose, galactolipin, dried meat ammonia
The solid powder of acid is according to mol ratio 1:3-1:1 is added in round-bottomed flask, and heating water bath stirring is until transparency liquid is formed；Water
Bath heating-up temperature is 80 oC-90 oC, and the reaction time is 2-3 h；
Synthetic method two：Citric acid and another component are included into sucrose, glucose, D-MANNOSE, sorbose, galactolipin, dried meat ammonia
The solid powder of acid is according to mol ratio 1:3-1:1 is added in round-bottomed flask, adds water, and the addition of water is total for two kinds of solid powders
The 10%-50% of weight, then heating water bath stirring is until transparency liquid is formed；Water bath heating temperature is 40 oC-60 oC, reaction
Time is 2-3 h.
3. a kind of preparation method of the natural eutectic solvent tobacco humectant of lemon acid type described in claim 1, its feature exists
In：The natural eutectic solvent of lemon acid type of above-mentioned synthesis is proportionally added into water, pH is to neutrality for regulation, then adds
0.1%-0.5% preservative, 0.1%-0.5% defoamer can be prepared by the natural eutectic solvent humectant of lemon acid type.
4. the preparation method of the natural eutectic solvent tobacco humectant of lemon acid type according to claim 3, its feature exists
In：It is hydrochloric acid or sodium hydrate aqueous solution to adjust pH value agents useful for same.
5. the preparation method of the natural eutectic solvent tobacco humectant of lemon acid type according to claim 3, its feature exists
In：The aqueous hydrochloric acid solution concentration is that weight compares 0.5-5%；Sodium hydrate aqueous solution concentration is that weight compares 0.5-10%.
6. a kind of application of natural eutectic solvent tobacco humectant of lemon acid type as claimed in claim 1 in cigarette, its
It is characterised by：The natural eutectic solvent tobacco humectant of lemon acid type is uniformly sprayed in pipe tobacco, with improvement tobacco simultaneously
Physics humectation and the effect of sense organ humectation, consumption are the 0.1%-1.5% of tobacco quality.
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Cited By (1)
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| CN116671663A (en) * | 2023-07-28 | 2023-09-01 | 内蒙古昆明卷烟有限责任公司 | Cigarette containing violet leaf absolute |
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| CN116671663A (en) * | 2023-07-28 | 2023-09-01 | 内蒙古昆明卷烟有限责任公司 | Cigarette containing violet leaf absolute |
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