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CN107208986A - Include the heat exchanger of liquid refrigerant distributor - Google Patents

Include the heat exchanger of liquid refrigerant distributor Download PDF

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Publication number
CN107208986A
CN107208986A CN201680007397.4A CN201680007397A CN107208986A CN 107208986 A CN107208986 A CN 107208986A CN 201680007397 A CN201680007397 A CN 201680007397A CN 107208986 A CN107208986 A CN 107208986A
Authority
CN
China
Prior art keywords
fin
overflow openings
heat exchanger
distributor
liquid refrigerant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201680007397.4A
Other languages
Chinese (zh)
Other versions
CN107208986B (en
Inventor
热罗姆·卡雷特
弗雷德里克·克雷萨克
马克·瓦格纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Publication of CN107208986A publication Critical patent/CN107208986A/en
Application granted granted Critical
Publication of CN107208986B publication Critical patent/CN107208986B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04636Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a hybrid air separation unit, e.g. combined process by cryogenic separation and non-cryogenic separation techniques
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F25J5/002Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
    • F25J5/005Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger in a reboiler-condenser, e.g. within a column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0062Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/027Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits in the form of distribution pipes
    • F28F9/0273Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits in the form of distribution pipes with multiple holes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/0278Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits in the form of stacked distribution plates or perforated plates arranged over end plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/22Arrangements for directing heat-exchange media into successive compartments, e.g. arrangements of guide plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/02Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/04Down-flowing type boiler-condenser, i.e. with evaporation of a falling liquid film
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/32Details on header or distribution passages of heat exchangers, e.g. of reboiler-condenser or plate heat exchangers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

This heat exchanger (2) includes:Parallel-plate (11,12), these parallel-plates limit the liquid refrigerant path (20) of (X) in a longitudinal direction, and the fin (21,22 extended on the horizontal direction (Y) orthogonal with the longitudinal direction (X) in each path (20), 23,24), each fin (21,22,23,24) having is used for the aperture that the liquid refrigerant flows.At least one low portion of at least one fin (21,22,23,24) defines the assignment channel for guiding the liquid refrigerant on the horizontal direction (Y) with the plate being fixed on the low portion.Aperture at least one described fin (21,22,23,24) is formed by the overflow openings in the upper part.When the hydraulically full refrigerant of the or each assignment channel, the liquid refrigerant flows through these overflow openings.

Description

Include the heat exchanger of liquid-refrigerant distributing device
The present invention relates to a kind of heat exchanger, the heat exchanger includes being arranged to liquid refrigerant distribution in heat friendship Distributor in parallel operation.The heat exchanger can be made in the post for carrying out air separation by low temperature distillation Evaporator, to ensure post liquid in containers (such as liquid by the heat exchange with heat production gas (such as air or nitrogen) Oxygen) evaporation.
The present invention is particularly used for cryogenic gas separation, particularly for the Cryogenic air point for the gaseous state oxygen for producing pressurization In field from (known for the acronym " ASU " of air gas separation unit).Especially, the present invention can be applied In the heat exchanger for evaporating liquid flow such as oxygen, nitrogen and/or argon by the heat exchange with gas.
If the heat exchanger is located in the container of distillation column, it may be constructed the evaporator run as thermal siphon (wherein immersing the exchanger in the liquid bath declined along the post) or by directly being supplied by the liquid fallen in the post Film evaporation and/or the evaporator that is run by recirculation pump.
Currently used for these phase transformation exchangers technology be the aluminium exchanger with brazing sheet and fin technology, this causes The device of the highly compact of big exchange area is provided.These exchangers include plate, and fin is inserted between the plates, is consequently formed The stacking of evaporation flow paths and condensation pass, first path is intended for evaporation liquid refrigerant and the alternate path is purport For condensing heat production gas.
WO-A-2011110782 describes a kind of distributor, and the distributor includes limiting for liquid refrigerant The parallel-plate of path, and extend and with the aperture for being used to distribute liquid refrigerant in a lateral direction in each path Several fins.
However, in the distributor of prior art, the distribution of liquid refrigerant in a lateral direction is not substantially uniformity 's.When the region of exchanger does not receive enough liquid refrigerants, due to dry blowing hair, the solid deposits of impurity may be sent out It is raw.The solid deposits of such impurity generate the risk of blast under some operating conditions of heat exchanger.
Known solution is by the puncture aperture group in the parallel-plate of distributor from document EP-A-0130122 Into to ensure rough predistribution of the liquid refrigerant along the path for the liquid.However, arranged along exchanger The quantity in aperture is limited, so as not to complicate production or structure is died down, and makes the effect of the allocation criterion of liquid Fruit is still not enough.
The purpose of the present invention completely or partially solves the above problems specifically by distributor is provided, in this point Distribution with liquid refrigerant in device is as uniform as possible.
For this purpose, the purpose of the present invention is a kind of heat exchanger, the heat exchanger is arranged to heat from least A kind of heat production fluid such as nitrogen is delivered at least one cryogenic fluid such as oxygen, and the heat exchanger at least includes peace parallel to each other The plate of row, to limit conduction liquid body on the longitudinal direction for being arranged to generally extend in vertical direction during operation The First Series path of refrigerant, each path is limited between two continuous slabs, and is arranged to generally at this Longitudinal direction uploads the second series path of artificial delivery hot fluid, and each path is limited between two continuous slabs, and this second is The path of row is inserted between the two paths of the First Series;At least one is used for the entrance of liquid refrigerant, the entrance It is configured as that only the liquid refrigerant is poured into the path of the First Series;And only exist in the upper end of the exchanger Distributor in the path of the First Series, the distributor includes
The fin generally extended in a lateral direction in one of the First Series or each path, the horizontal direction It is orthogonal and parallel with these plates with the longitudinal direction, each passageways houses of First Series phase each other on the longitudinal direction After several fins, each fin have is configured as allow liquid refrigerant flow aperture;
At least one fin has upper part and low portion, when the distributor is in operation and the longitudinal direction When extending on the vertical direction, the height of the upper part is more than the height of the low portion,
At least one described low portion and the plate being fixed at least one described low portion are limited at least One be arranged to the conduction liquid cryogen on the horizontal direction assignment channel,
The aperture of at least one fin is formed by the overflow openings at least one described upper part, these Overflow openings are configured such that the liquid refrigerant is via this when at least one described assignment channel hydraulically full refrigerant A little overflow openings flowings.
In other words, the or each assignment channel forms a type of groove, and the groove is in these overflow openings and the bottom Extend between part and the crosspoint for the plate being fixed on this low portion.When the distributor operation when, should or Each assignment channel is generally horizontal.
Therefore, the or each assignment channel allows in the transverse direction side with cooperating for the overflow openings of one or more fins The liquid refrigerant is distributed as homogeneously as possible upwards, and the solid deposits of impurity in the heat exchanger are restricted or prevented in this Risk.
Extend on two dimensions (length and width) of these plates respectively on the longitudinal direction and the horizontal direction.Every In individual path, these fins have elongated form and extended on the width (horizontal direction) of two continuous slabs.
When the distributor is in operation, the longitudinal direction is vertical.The liquid refrigerant is under gravity generally Flowed on the longitudinal direction.Therefore, the liquid refrigerant generally vertically flows on descent direction.
According to the variant of the present invention, the distributor can include the plate quantity more than 20 or even greater than 100.Therefore, These plate shapes are folded into sheetpile, and the path for the liquid refrigerant is defined between the plates, in some cases with for The conduit alternating of the heat production fluid.The distributor can have the liquid refrigerant number of vias more than 10 or even greater than 50 Amount.
In operation, the liquid refrigerant passes through the distributor.The distributor has:I) it is arranged to the liquid The upstream portion of the entrance of refrigerant, and ii) be arranged to the liquid refrigerant outlet downstream part.These fins exist Extend between the upstream portion and the downstream part.
According to the variant of the present invention, each path has flat parallelepiped form.Due to each path have it is flat Flat shape shape, so the distance between two continuous slabs is small compared with the length and width of each continuous slab.Preferably, These fins all or some extend to next plate from a plate.In other words, these fins are contacted with two plates.It is this Construction allows these fin brazeds to two plates, and which increase the mechanical strength of the distributor.
In this application, term " ... direction on " refer to it is substantially parallel or basic with another direction or plane Upper conllinear direction.
According to one embodiment of present invention, the volume of corresponding assignment channel be cumulative volume be less than 15%, it is preferably small In 10%, the cumulative volume is delimited by following item:
- i) there is the fin of overflow openings,
- ii) plate on the low portion of the fin with overflow openings is fixed to, and
- iii) fin of the fast upstream of the fin with overflow openings described in.
Consequently, because the volume of the assignment channel, there is the fin of overflow openings too big load can not be caused to damage for these Lose.Low-load loss avoids the flowing for reducing the liquid refrigerant by these fins with overflow openings, and this allows this The optimum apjustment of flowing.Therefore, there is the fin of overflow openings to complete to distribute the function of the liquid refrigerant for these, only produce low Load loss.Each assignment channel is by least one low portion and by being fixed at least one described low portion Plate is limited.
Embodiments in accordance with the present invention, these overflow openings are evenly distributed on fin on the horizontal direction.
Therefore, equally distributed overflow openings allow the maximum distributing uniformity of the liquid refrigerant.Alternately, certain A little overflow openings can unevenly be distributed on the horizontal direction.
According to one embodiment of present invention, aperture opening ratio, the aperture opening ratio has:
- be located at overflow openings fin in overflow openings the gross area as molecule, and
The gross area in the face of-fin with overflow openings as denominator,
It is between 10% and 50%, preferably between 20% and 40%.
Therefore, such a aperture opening ratio contributes to the load loss for producing the fin for having overflow openings by these minimum Change, while ensuring enough flowings in the distributor.
According to one embodiment of present invention, each overflow openings have in 1.5mm2With 10.0mm2Between, preferably exist 2.0mm2With 5.0mm2Between area.
Therefore, such a area is avoided floods each overflow openings completely, and this helps not reduce by each fin The flowing of liquid refrigerant.
According to the variant of the present invention, some overflow openings have the form of ellipse such as circle.Therefore, such a shape is carried Progressively increased overflow openings width is supplied, when the flowing increase of liquid refrigerant, which has limited the liquid refrigerant Highly.
According to the variant of the present invention, some overflow openings have the triangle shape for pointing at least one low portion Formula.Therefore, such a shape provides progressively increased overflow openings width, when the flowing increase of liquid refrigerant, this limit The height of the liquid refrigerant is made.
According to one embodiment of present invention, between being measured between two continuous overflow openings on the horizontal direction Every being between 1mm and 6mm.
Therefore, such a interval assists in ensuring that liquid refrigerant evenly distributing on the horizontal direction, while making by this The load loss that a little fins with overflow openings are produced is minimized.
According to the variant of the present invention, the interval is constant for the overflow openings of at least one fin.
Therefore, such a interval contributes to the distributing uniformity for making the liquid refrigerant on the horizontal direction to maximize.
In one embodiment of the invention, in i) overflow openings and ii) it is fixed at least one described low portion On plate between minimum range be located between 1mm and 4mm, for corresponding fin overflow openings it is most of or all, should Minimum range is preferably identical.
Therefore, such a minimum range allows assignment channel to have relatively large volume, and this allows to limit in the distributor The fin with overflow openings quantity.
According to one embodiment of present invention, several fins have the corresponding upper part with overflow openings.
In other words, there are several allocated phases of the liquid refrigerant, this help makes the uniformity of this distribution maximum Change.
According to one embodiment of present invention, it is present in these overflow openings in fin relative to being present in adjacent fins In these overflow openings on the horizontal direction offset orientation.
Therefore, such a skew between overflow openings helps to increase point of the liquid refrigerant on the horizontal direction With uniformity.
According to one embodiment of present invention, described between these overflow openings being present in two adjacent fins Skew is accounted between the 40% and 60% of the length at the interval.
In other words, the overflow openings for two continuous fins being arranged in being substantially offset from one another on the longitudinal direction.
Therefore, the value of such a skew between overflow openings helps point for making the liquid refrigerant on the horizontal direction Maximized with uniformity.
According to one embodiment of present invention, at least one fin has flat pattern and extended until described two Continuous slab and each in described two continuous slabs is obliquely run out to, so as to vertical with these plates and the horizontal direction Plane in section in form closed bevel, the oblique angle preferably between 30 ° and 60 °, further preferably at 40 ° and Between 50 °.
Therefore, such a flat inclined fin occupies relatively small space and is readily attached on these plates.
According to one embodiment of present invention, each fin have between 4mm and 10mm parallel to the longitudinal direction Length, and each fin has the width parallel to the horizontal direction between 4mm and 10mm, and each fin being capable of example Such as there is equal length and width.
Therefore, such a length and width allows substantial amounts of fin to combine in the distributor, and which increase the liquid system The distributing uniformity of cryogen.
According to the variant of the present invention, each fin has for example is fixed to the fixed part on plate by soldering.
Therefore, such a fixed part allows each fin to be attached in a straightforward manner on these plates.
According to the variant of the present invention, one and preferably each overflow openings are by openings (through orifice) Limit.Alternately, at least one overflow openings can be by extending until the recess at the edge of corresponding fin is limited.
According to one embodiment of present invention, the distributor includes at least one fin, and at least one fin has Aperture and the upstream for being placed on one or more fins with overflow openings, these apertures are distributed in the horizontal direction On, the quantity in aperture of the quantity than each fin of the overflow openings of each fin is big 3 times, preferably big 5 times.
Therefore, there is the fin in aperture can complete control into the distributor by producing high capacity loss for these The function of the flowing of liquid refrigerant, and these have the fin for overflowing opening conversely complete while generation only low-load is lost Into distribution function.Which has limited the quantity for the part being mounted in the distributor, because due to the fin with aperture, Perforation rod (as in WO-A-2011110782) need not be provided to produce high capacity loss.
According to the variant of the present invention, at least two fins have aperture, and the quantity in the aperture of each fin is being from upstream to Increase on the direction in downstream.
Therefore, these have the fin in aperture allow access into the distributor liquid refrigerant flowing optimal control System.
It is being measured on the horizontal direction positioned at the fin with aperture of most upstream, two according to the variant of the present invention Being located at interval between 40mm and 60mm between individual continuous aperture, and in the transverse direction of the fin with aperture positioned at most downstream Measured on direction, being located at interval between 6mm and 20mm between two continuous apertures.
Therefore, fin with aperture positioned at most upstream has minimum aperture, and has hole positioned at most downstream The fin of mouth has most apertures, and there is the fin of overflow openings to be in the fin with aperture positioned at most downstream for these Downstream.
Therefore, downstream is from upstream to by these load losses that there is the fin in aperture to produce to reduce, and the liquid refrigerating The distributing uniformity increase of agent.
According to the present invention variant, at least one fin, in addition to these overflow openings, can have at least one The purge hole arranged at the bottom of the low portion.Then, the assignment channel is by several part shapes being split into two halves by purge hole Into the liquid refrigerant can flow through the purge hole.Such a purge hole allows the emptying of the assignment channel.Advantageously, should Or the area of each purge hole is less than the area of overflow openings.Therefore, there is relatively low flow velocity by the flowing of the purge hole, The flowing that this avoidance breakout passes through each overflow openings close to the purge hole.
According to the variant of the present invention, for giving these openings of fin or the gross area of these overflow openings in the longitudinal direction Increase on direction, preferably increased by increasing the quantity and/or area of these openings.
By this way, the liquid decline in the distributor is more remote, and the spacing between these openings is smaller.Start When, if liquid is poorly distributed, it is forced laterally to circulate the adjacent apertures until same fin.It is open at two Between distance it is bigger, the reallocation on width is more effective.
Secondly, the purpose of the present invention is a kind of distribution method for being used to distribute liquid refrigerant in a heat exchanger, this point Method of completing the square comprises the following steps:
- implement according to distributor of the invention,
- liquid refrigerant is transmitted in each path and generally in a longitudinal direction,
- allow liquid refrigerant via the orifice flow of the fin with aperture,
The each assignment channel of-filling so that liquid refrigerant flows via these overflow openings.
The invention further relates to a kind of heat exchanger, the heat exchanger is configured as heat from least one heat production fluid (such as nitrous oxide) is delivered at least one cryogenic fluid (such as oxygen), and the heat exchanger includes at least one heat exchange list Member, at least one liquid refrigerant entrance, the heat exchanger are characterised by including according to any one of preceding claims institute The distributor stated, the distributor is arranged to liquid refrigerant being fed to the heat exchange unit.
Therefore, such a heat exchanger limits or avoided the risk of the solid deposits of impurity in the heat exchanger, with And the risk therefore exploded under some operating conditions.
Above-mentioned embodiment and variant can in isolation or with it is any technically can the combination of property use.
From the following description and refer to the attached drawing only provided as non-limiting examples, it will be clear that ground understand the present invention and Its advantage will appear from, in the drawings:
- Fig. 1 is a part for the distributor according to the first embodiment of the present invention perpendicular to the flat of horizontal direction Diagrammatic section view in face;
- Fig. 2 is the diagrammatic section view in the plane II of the distributor part in Fig. 1 in Fig. 1, and plane II is put down Row is in the longitudinal direction and horizontal direction;
- Fig. 3 is a part for the heat exchanger for including the distributor according to the first embodiment of the present invention vertical Diagrammatic section view in the plane of the horizontal direction;
- Fig. 4 is analogous to Fig. 1 view, shows the function of Fig. 3 distributor;
- Fig. 5 is analogous to Fig. 2 view, shows the function of Fig. 3 distributor;
- Fig. 6 and Fig. 7 are the views for being analogous respectively to Fig. 1 and Fig. 2, show point according to the second embodiment of the present invention A part with device;
- Fig. 8 and Fig. 9 are the views for being analogous respectively to Fig. 1 and Fig. 2, show point according to the third embodiment of the invention A part with device;
- Figure 10 is analogous to Fig. 1 view, shows one of distributor according to the fourth embodiment of the invention Point;
- Figure 11 is analogous to Figure 10 view, shows one of distributor according to the fifth embodiment of the invention Point;
- Figure 12 is analogous to Figure 10 view, shows one of distributor according to the sixth embodiment of the invention Point;
- Figure 13 is analogous to Fig. 1 view, shows one of distributor according to the seventh embodiment of the invention Point;
- Figure 14 is analogous to Fig. 1 view, shows one of the distributor according to the eighth embodiment of the present invention Point;And
- Figure 15 shows the distribution method according to the present invention.
Fig. 1,2 and 3 show distributor 1, and the distributor is arranged to liquid refrigerant F1 (in such case Lower liquid oxygen) it is assigned in heat exchanger 2.Heat exchanger 2 is arranged to heat from heat production fluid F2 (in this gaseous nitrogen atmosphere) It is delivered to the cryogenic fluid (in this oxygen).Before transmission heat, liquid refrigerant F1 (Fig. 3) is belonging to the appearance of heat exchanger 2 Receive in groove 3.
Distributor 1 includes the plate 11,12,13,14 and equivalent of arrangement parallel to each other.Distributor 1 includes being equal to greatly About 200 stacking plate quantity.Each in these plates 11,12,13,14 is prolonged on two dimensions (length and width) respectively Stretch, the two dimensions are respectively defined in longitudinal direction X and transverse direction Y.
Transverse direction Y is orthogonal and parallel with these plates 11,12,13,14 with longitudinal direction X.When distributor 1 is in operation When middle, longitudinal direction X is vertical.Liquid refrigerant F1 flows generally on longitudinal direction X under gravity.Therefore, liquid Refrigerant F1 generally vertically flows on descent direction.
These plates 11,12,13,14 are arranged to restriction and are arranged to the conduction liquid body generally on longitudinal direction X Refrigerant F1 path 20,30 and equivalent.Each path 20 or 30 is limited between two continuous slabs 11,12,13,14. Each path 20,30 has flat parallelepiped form.Distance between two continuous slabs 11 and 12 with it is each continuous It is small that the length (on the X of direction) of plate 11 or 12 is compared with width (in the Y direction).In heat exchanger 2, for liquid system Cryogen F1 path 20,30 replaces with the path (not shown) of the flat parallelepiped form for the heat production fluid.
Distributor 1 also includes fin 21,22,23,24 and 31,32,33,34, and these fins are respectively in each path 20 With 30 in generally in transverse direction Y extend.Fin 21,22,23,24 extends in path 20, and fin 31,32,33,34 Extend in path 30.In each path 20 or 30, fin 21,22,23,24,31,32,33 and 34 has elongated form simultaneously And extend in the transverse direction Y of two continuous slabs 11 and 12 or 13 and 14.
Each fin 21,22,23,24,31,32,33 or 34 has flat pattern and extended until two continuous slabs 11 and 12 or 13 and 14.Each fin 21 or equivalent obliquely run out to every in the two continuous slabs 11 and 12 or 13 and 14 One, to form closed bevel in the section in the plane (Fig. 1 plane herein) vertical with transverse direction Y with these plates A21.Oblique angle A21 is 45 ° herein.
Each fin 21 or equivalent have the length X21 parallel to longitudinal direction X, and the length is equal to 5mm herein.Each Fin 21 or equivalent have the width Y21 parallel to transverse direction Y, and the width is equal to 5mm and is therefore equal to length herein X21.Each fin 21 or equivalent have flat and are fixed to consolidating in respective plate 11 or equivalent by soldering herein Determine part 21.5.All fins 21,22,23,24 are from an extension of plate 11 until next plate 12.In other words, these wings Piece 21,22,23,24 is contacted with two plates 11 and 12.These fins 21,22,23,24 are soldered on the two plates 11 and 12.
Each path 20 or 30 accommodates four fins herein, is 21,22,23,24 and 31,32,33,34 respectively, these Fin follows one another on longitudinal direction X.Each fin 21 or equivalent have aperture 40, and these apertures are configured to permit liquid Cryogen F1 is flowed by corresponding fin 21 or equivalent.
In Fig. 1 to Fig. 5 example, each fin 21,22,23,24,31,32,33 or 34 has the and of upper part 21.1 Equivalent and low portion 21.2 and equivalent.(Fig. 4 and Fig. 5), upper part 21.1 when the distributor is in operation Height be more than low portion 21.2 height.
Each low portion 21.2 or equivalent, and the respective plate 11 or equivalent being fixed on low portion 21.2 Define the assignment channel 42 for being arranged to the conduction liquid cryogen F1 in transverse direction Y.
In Fig. 1 to Fig. 5 example, the aperture 40 of each fin 21 or equivalent is by positioned at each respective upper part 21.1 or equivalent in overflow openings 40 formed.All fins 21 and equivalent have corresponding upper with overflow openings 40 Portion part 21.1 and equivalent.All overflow openings 40 are not marked on reason, Fig. 1 to Fig. 5 for significantly understanding.
The overflow openings 40 of each fin 21 or equivalent are configured such that when the hydraulically full refrigerant of assignment channel 42 During F1, liquid refrigerant F1 flows via overflow openings 40.
All overflow openings 40, which all have, herein points to the triangular shaped of each respective lower part 21.2.These overflows Opening 40 is evenly distributed in transverse direction Y on corresponding fin 21 or equivalent herein.
The interval D 40 between two continuous overflow openings 40 measured on the horizontal direction be herein it is constant and And it is equal to 4mm for the overflow openings 40 of each fin 21 or equivalent.
In addition, in i) overflow openings 40 and ii) it is fixed to the most narrow spacing between the plate 11 on respective lower part 21.2 It is equal to 3mm from H40.This minimum range H40 is that identical is (permanent for all overflow openings 40 of corresponding fin 21 or equivalent Fixed).
In Fig. 1 to 5 example, it is present in these overflow openings 40 in fin 21 relative to being present in adjacent fins 22 In these offset orientations in transverse direction Y of overflow openings 40.Overflow in two adjacent fins 21 and 22 are present in is opened Skew D40/2 between mouth 40 accounts for the 50% of the length of interval D 40 herein.
Each overflow openings 40 have herein is equal to 4mm2Area.Aperture opening ratio, the aperture opening ratio has:
- it is used for molecule positioned at the fin 21 with overflow openings 40 or the gross area of the overflow openings 40 in equivalent, and And
The gross area in the face 21.0 of-this fin 21 is used for denominator,
It is equal to 20% herein.
The function of distributor 1 is illustrated in greater detail in Fig. 4 and Fig. 5.Liquid refrigerant F1 is shown as shade.Such as Fig. 4 Shown with Fig. 5, liquid refrigerant F1 by each overflow of overflow openings 40, and fill these fins 21,22,23,24,31, 32nd, 33 and 34 each assignment channel 42.
Such as Fig. 4 and Fig. 5 shows that the volume (being shown as shade on Fig. 4 or Fig. 5) of each assignment channel 42 is less than cumulative volume The 10% of (grid is shown as on Fig. 4), the cumulative volume is delimited by following item:
I) there is the corresponding fin 222 of overflow openings 240,
Ii the plate 11 on the low portion of this fin 222) is fixed to, and
Iii) it is located at the fin 221 of the fast upstream of fin 222.
Figure 15 is shown is used for the distribution method by liquid refrigerant F1 distribution in heat exchanger 2 according to the present invention. The distribution method especially comprises the following steps:
1001) distributor 1 is implemented,
1002) liquid refrigerant F1 is transmitted in path 20 and 30 and generally on longitudinal direction X,
1003) liquid refrigerant F1 is allowed by the fin 21 with opening 40 and the flowing in the aperture of equivalent,
1004) each assignment channel 42 is filled so that liquid refrigerant F1 flows through these overflow openings 40;Step 1004) mode of operation shown in Fig. 4 and Fig. 5 is produced.
When distributor 1 is in operation, each assignment channel 42 is generally horizontal.Each assignment channel 42 and this The cooperation of a little overflow openings 40 allows to distribute liquid refrigerant F1 as homogeneously as possible in transverse direction Y.
Such as Fig. 3 shows that heat exchanger 2 is included with the heat exchange unit shown partially of the reference number 4 in Fig. 3.In addition, heat is handed over Parallel operation 2 includes the entrance 8 for heat production fluid F2 entrance and for liquid refrigerant F1.Entrance 8 is at this in perforation rod 9 Perforation formed.
Heat exchanger 2 also includes the distributor 1 for being configured as liquid refrigerant F1 being fed to heat exchange unit 4. In this case, heat exchanger 2 includes holding tank 3, and before flow direction distributor 1, liquid is stored in the holding tank Refrigerant F1.In operation, liquid refrigerant F1 passes through distributor 1.
The second and third embodiments of the present invention have shared following characteristics, for given fin 121,122,123,124, The gross area of all overflow openings 140,240,241 increases from the top to the bottom.This can be by increasing these quantity being open And/or area is realized.
Fig. 6 and Fig. 7 show a part for distributor 101 according to the second embodiment of the present invention.In distributor In the case that 101 are similar to distributor 1, the description above with respect to Fig. 1 to Fig. 5 distributors 1 provided can be arrived by modulation On distributor 101, in addition to significant difference explained below.
The part of or corresponding distributor 101 identical with the part of distributor 1 has increase in structure or function 100 identical numeric reference number.Therefore, we have plate 111,112, fin 121,122,123,124, overflow openings 140 and assignment channel 142.
The difference of distributor 101 and distributor 1 is that these overflow openings 140 have elliptical shape.However, Such as in distributor 101, each aperture of each fin 121,122,123,124 forms overflow openings 140.
Overflow openings of these fins 121,123 with identical quantity, but the area of the opening 140 of lower fins 123 Less than the area of the opening 140 of upper fins 123.The opening 140 of fin 121 is less, but they have and lower fins 122 Shape identical shape.Opening for fin 123 and 124 is also such case.The gross area of these openings is in the exchange (i.e. downwards) increase is being from upstream on the direction (descent direction on Fig. 7) in downstream during the operation of device.
Fig. 8 and Fig. 9 show a part for distributor 201 according to the third embodiment of the invention.In distributor In the case that 201 are similar to distributor 101, the description above with respect to Fig. 6 and Fig. 7 distributor 101 provided can be turned It is transferred on distributor 201, in addition to significant difference explained below.
The part of or corresponding distributor 201 identical with the part of distributor 101, which has, in structure or function increases 100 identical numeric reference number is added.Therefore, we have plate 211,212, fin 221,222,223,224, overflow openings 240 and assignment channel 242.
Distributor 201 is different from distributor 101, because two fins 221 and 222, which have, does not form overflow openings 240 aperture 241.Only fin 223 and 224 has overflow openings 240.In fact, these apertures 241 are in fin 221 and 222 On quantity it is seldom so that when distributor 201 is in operation, these apertures 241 are submerged.
These fins 221 and 222 are placed on the upstream of these fins 223 and 224 with overflow openings 240.Aperture 241 are distributed on the horizontal direction.The quantity of the overflow openings 240 of each fin 223 or 224 is than each fin 221 or 222 The quantity in aperture 241 is big 5 times.
The quantity in the aperture 241 of each fin 221 or 222 is during the operation of the exchanger in the side for being from upstream to downstream Increase (i.e. downwards) on to (descent direction on Fig. 9).In the wing with aperture 241 positioned at most upstream (at Fig. 9 top) Interval D 241.1 being measured on the horizontal direction of piece 221, between two continuous apertures 241 is equal to 51mm herein.In fact, Spacing 11-12 between plate 11 and 12 is approximately equal to 51mm.In the horizontal stroke of the fin 222 with aperture 241 positioned at most downstream Interval D 241.2 being measured on to direction, between two continuous apertures 241 is equal to 20mm herein.
Compared with distributor 1, when distributor 201 is in operation, the fin 221 and 222 with aperture 241 can be with Control is completed into the function of the flow velocity of the liquid refrigerant of distributor 201 while high capacity loss is produced, and is had The fin 223 and 224 of overflow openings 240 is opposite to complete distribution function while low-load loss is only produced.
Figure 10 shows a part for distributor 301 according to the third embodiment of the invention.In the class of distributor 301 In the case of being similar to distributor 1, the description above with respect to Fig. 1 to Fig. 5 distributors 301 provided can be by modulation to distribution On device 301, in addition to significant difference explained below.
The part of or corresponding distributor 301 identical with the part of distributor 1 has increase in structure or function 300 identical numeric reference number.Therefore, we have a plate 311,312, path 320, and fin 321,322,323, 324。
Distributor 301 is different from distributor 101, because these fins 321,322,323,324 and these plates 311 and 312 are arranged in the region that wherein path 320 is relatively wide distributor 301, because the region is not used for heat production stream Body F2 conduit.In fact, each conduit for heat production fluid F2 is blocked by plug 350, and for heat production fluid F2's The outlet (not shown) of conduit is located on the side of distributor 301.
Therefore, at the level of these fins 321,322,323,324, these paths 320 can be arranged at distribution dress Put in the 301 whole height measured in a direction z, and these paths 20 and 30 are handed over the corresponding pipe for heat production fluid F2 Replace.For example, the spacing 311-312 between these plates 311 and 312 is approximately equal to 110mm, and between these plates 11 and 12 Spacing 11-12 is approximately equal to 51mm.
Therefore, the fixed part of each fin 321,322,323,324 is relatively small, and this reduce in the plate and the wing The stress in angle welding formed between piece.
In addition, these fins 321,322,323,324 can have such as first embodiment (Fig. 1 to 5:Constant number overflow Stream opening) or such as 3rd embodiment (Fig. 8 and Fig. 9:Orifice number is progressively increased) in configuration aperture and overflow openings.
Figure 11 shows a part for distributor 401 according to the fifth embodiment of the invention.Distributor 401 will
- the spacing wherein between plate 411 and 412 is big (for example:The fin 421 arranged in region 110mm) With 422,
- and path 420 is to shrink (for example wherein:55mm) (because the alternating for heat production fluid F2 conduit is deposited ) region in the fin 423,424 that arranges and equivalent combination.
Each conduit for heat production fluid F2 is blocked by plug 450, and the outlet of the conduit for heat production fluid F2 (not shown) is located on the side of distributor 301.
Aperture but a no overflow openings can be had by being arranged at fin 421,422 in the wide region of path 420, and by The fin 423,424 being arranged in the narrow region of path 420 can have overflow openings.
Figure 11 shows a part for distributor 501 according to the sixth embodiment of the invention.Distributor 501 is with dividing It is similar with device 1.Distributor 501 includes plate 511,512 and equivalent, for the entrance 508 of liquid refrigerant, fin 521 And equivalent, and for blocking the plug 550 of the conduit for heat production fluid F2.
Distributor 501 is different from distributor 1, because wherein arranging the region of holding tank 503 than wherein arranging to accommodate The region of groove 3 is wider, and this allows the increase of the distance between these plates 511 and 512 and each aperture is formed for liquid The entrance 508 of refrigerant.Therefore, it has been reduced or avoided due to each portion in these apertures of the capillarity from soldering The risk divided or blocked completely.In addition, this wider region allows to limit bigger aperture for the flowing of liquid refrigerant.
Naturally, the invention is not restricted to instantiation that is described herein and showing.Without departing from such as by appended In the case of the scope of the present invention that claims are limited, it is also contemplated that those skilled in the art's other changes in power Body or embodiment.
Therefore, as the alternative solution of embodiments described above, these fins can have except flat and inclination Outer profile.For example, Figure 13 shows a part for distributor 601, wherein these fins are flat and by oblique stripe And be horizontal Cross slat composition when the distributor is in operation.Similarly, Figure 13 shows the one of distributor 601 Part, these fins are flat and sinusoidal in the distributor.

Claims (14)

1. a kind of heat exchanger (2), the heat exchanger is arranged to heat from least one heat production fluid (F2) such as nitrogen Gas is delivered at least one cryogenic fluid (F1) such as oxygen, the plate of the heat exchanger (2) including arrangement parallel to each other (3,11,12, 13,14), conducted to limit on the longitudinal direction (X) for being arranged to generally extend in vertical direction during operation The First Series path (20,30) of liquid refrigerant (F1), each path (20,30) is limited at two continuous slabs (11,12- 13,14) between, and the second series that restriction is arranged to generally upload artificial delivery hot fluid in the longitudinal direction (X) lead to Road, each path is limited between two continuous slabs, and the paths of the second series be inserted in the First Series two are led to Between road;At least one is used for the entrance (8 of liquid refrigerant (F1);508), the entrance is configured as the liquid refrigerant only It is poured into the path of the First Series;And the distribution in the upper end of the exchanger only in the path of the First Series Device, the distributor is included generally on horizontal direction (Y) in one of the First Series or each path (20,30) The fin (21,22,23,24-31,32,33,34) of extension, the horizontal direction it is orthogonal with the longitudinal direction (X) and with these plates (11,12,13,14) are parallel, and each path (20,30) of the First Series is contained in what is followed one another on the longitudinal direction (X) Several fins (21-24,31-34),
Characterized in that,
Each fin (21-24,31-34) has the aperture for being configured as allowing the liquid refrigerant (F1) to flow;
At least one fin (21,22,23,24) has upper part (21.1) and low portion (21.2), when the distributor (1) when the in operation and longitudinal direction extends on the vertical direction, the height of the upper part (21.1) is more than under this The height of portion part (21.2),
At least one described low portion (21.2) and the plate being fixed at least one described low portion (21.2) (12) at least one assignment channel (42 for being arranged to the conduction liquid cryogen (F1) on the horizontal direction (Y) is limited; 142;242),
The aperture of at least one fin (21,22,23,24) is by overflowing at least one described upper part (21.1) Stream opening (40;140;240) formed, these overflow openings (40) are configured such that when at least one described assignment channel (42) During hydraulically full refrigerant (F1), the liquid refrigerant (F1) flows via these overflow openings (40).
2. heat exchanger as claimed in claim 1, wherein corresponding assignment channel (42;142;242) volume is cumulative volume Less than 15%, preferably less than 10%, the cumulative volume is delimited by following item:
I) there is the fin (22) of overflow openings (40),
Ii the plate (11) on the low portion of the fin (22) with overflow openings (40)) is fixed to, and
Iii) it is located at the fin (21) of the fast upstream of the fin (21) with overflow openings (40).
3. the heat exchanger as any one of preceding claims, wherein these overflow openings (40) are in the horizontal direction (Y) it is evenly distributed on fin (21,22,23,24).
4. the heat exchanger as any one of preceding claims, wherein aperture opening ratio, the aperture opening ratio have:
- the overflow openings (40 being located in the fin (21,22,23,24) with overflow openings;140;240) gross area conduct Molecule, and
- described with overflow openings (40;140;240) gross area in the face of fin (21,22,23,24) as denominator,
It is between 10% and 50%, preferably between 20% and 40%.
5. the heat exchanger as any one of preceding claims, wherein each overflow openings (40;140;240) have 1.5mm2With 10.0mm2Between, preferably in 2.0mm2With 5.0mm2Between area.
6. the heat exchanger as any one of preceding claims, wherein between two continuous overflow openings (40) The interval (D40) measured on the horizontal direction (Y) is between 1mm and 6mm.
7. the heat exchanger as any one of preceding claims, wherein in i) overflow openings (40) and ii) being fixed to The minimum range (H40) between the plate (12) at least one described low portion (21.2) is located between 1mm and 4mm, right In the most of or entirety of the overflow openings (40) of corresponding fin (21,22,23,24), the minimum range (H40) is preferably identical 's.
8. the heat exchanger as any one of preceding claims, wherein several fins (21,22,23,24) have accordingly The upper part (21.1) with overflow openings (40).
9. heat exchanger as claimed in claim 8, wherein these overflow openings (40) being present in fin (21) relative to It is present in the offset orientation (D40/2) on the horizontal direction (Y) of these overflow openings (40) in adjacent fins (22).
10. heat exchanger as claimed in claim 9, wherein these overflows in two adjacent fins (21,22) are present in The skew (D40/2) between opening (40) is accounted between the 40% and 60% of the length of the interval (D40).
11. the heat exchanger as any one of preceding claims, wherein at least one fin (21,22,23,24) has Flat pattern and extend until described two continuous slabs (11,12,13,14) and obliquely running out to described two continuous Each in plate (11,12,13,14), so as to vertical with the horizontal direction (Y) with these plates (11,12,13,14) flat Closed bevel (A21) is formed in section in face, the oblique angle (A21) is preferably between 30 ° and 60 °, further preferably existed Between 40 ° and 50 °.
12. the heat exchanger as any one of preceding claims, wherein each fin (21,22,23,24) has The length (X21) parallel to the longitudinal direction (X) between 4mm and 10mm, and wherein each fin (21,22,23,24) tool There is the width (Y21) parallel to the horizontal direction (Y) between 4mm and 10mm, each fin (21,22,23,24) being capable of example Such as there is equal length (X21) and width (Y21).
13. the heat exchanger as any one of preceding claims, the heat exchanger include at least one fin (121, 122;221,222), at least one fin has aperture (141;241) and it is placed on this and one or more is opened with overflow Mouth (140;240) fin (123,124;223,224) upstream, these apertures (141;241) it is distributed in the horizontal direction (Y) On, the overflow openings (140 of each fin;240) aperture (141 of the quantity than each fin;241) quantity is big 3 times, preferably Ground is big 5 times.
14. the heat exchanger (2) as any one of preceding claims, wherein for given fin (121,122,123, 124) these opening (40,140,240,241) or these overflow openings (140,240) the gross area in the longitudinal direction (X) Upper increase, is preferably increased by increasing the quantity and/or area of these openings.
CN201680007397.4A 2015-02-06 2016-02-05 Including liquid-refrigerant distributing device heat exchanger Active CN107208986B (en)

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FR1550960 2015-02-06
FR1550960A FR3032521B1 (en) 2015-02-06 2015-02-06 HEAT EXCHANGER COMPRISING A REFRIGERANT LIQUID DISPENSING DEVICE
PCT/EP2016/052524 WO2016124748A1 (en) 2015-02-06 2016-02-05 Heat exchanger comprising a liquid-refrigerant distribution device

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CN113670099A (en) * 2021-07-02 2021-11-19 广州华工机动车检测技术有限公司 Liquid cooling plate structure of power battery
CN115324280A (en) * 2022-08-24 2022-11-11 浙江高盛钢结构有限公司 Super-strength uniform-pressure-distribution positioning type steel structure column

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CN108088278A (en) * 2018-01-26 2018-05-29 上海交通大学 A kind of plate-fin heat exchanger fin component and heat exchanger for improving liquid distribution unevenness
CN108088278B (en) * 2018-01-26 2023-09-19 上海交通大学 Plate-fin heat exchanger fin assembly for improving uneven distribution of liquid and heat exchanger
CN113670099A (en) * 2021-07-02 2021-11-19 广州华工机动车检测技术有限公司 Liquid cooling plate structure of power battery
CN115324280A (en) * 2022-08-24 2022-11-11 浙江高盛钢结构有限公司 Super-strength uniform-pressure-distribution positioning type steel structure column
CN115324280B (en) * 2022-08-24 2023-12-05 中国建筑第五工程局有限公司 Super-strength uniform partial pressure positioning type steel structure column

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FR3032521B1 (en) 2017-02-17
CN107208986B (en) 2019-08-06
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FR3032521A1 (en) 2016-08-12
EP3254045B1 (en) 2019-01-02
WO2016124748A1 (en) 2016-08-11

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