CN107176823A - A kind of preparation technology of low water absorption ceramic tile - Google Patents
A kind of preparation technology of low water absorption ceramic tile Download PDFInfo
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- CN107176823A CN107176823A CN201710414104.0A CN201710414104A CN107176823A CN 107176823 A CN107176823 A CN 107176823A CN 201710414104 A CN201710414104 A CN 201710414104A CN 107176823 A CN107176823 A CN 107176823A
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- ceramic tile
- water absorption
- low water
- organic framework
- sintering
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- 239000000919 ceramic Substances 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000005516 engineering process Methods 0.000 title claims abstract description 13
- 238000005245 sintering Methods 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 239000012621 metal-organic framework Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 7
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 5
- 239000004927 clay Substances 0.000 claims abstract description 5
- 239000000428 dust Substances 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 5
- 239000002699 waste material Substances 0.000 claims abstract description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 5
- 239000010456 wollastonite Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000013110 organic ligand Substances 0.000 claims description 5
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 4
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000013384 organic framework Substances 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims description 2
- 230000010355 oscillation Effects 0.000 claims description 2
- 230000002085 persistent effect Effects 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 2
- 239000010931 gold Substances 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000002086 nanomaterial Substances 0.000 abstract description 3
- 238000005253 cladding Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62802—Powder coating materials
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of preparation technology of low water absorption ceramic tile, the present invention is with clay pit, waste ceramic material, glass dust, wollastonite, molybdic tailing etc. compounds the raw material as ceramic tile, obtained ceramic dense degree is high, sintering temperature is low, and it is used as sintering aid in the surface spraying cladding metal organic framework compound mixed with nano-silicon dioxide alkaline sol of raw material, this sintering aid high adsorption capacity, its unique structure makes its uniform and stable attachment and powder surface after being sprayed on raw material surface, realize the efficient introducing of metal ion and nano material, and improve the forming ability of raw material, element reaction in high-temperature sintering process in the sintering aid and powder of powder surface adhesion, generation is a variety of with fluxing, help the compound of sintering, high intensity is just obtained under relatively low sintering temperature, high-compactness, the high-quality ceramic tile of low water absorption.
Description
Technical field
The present invention relates to Ceramic Tiles technical field, more particularly to a kind of preparation technology of low water absorption ceramic tile.
Background technology
Water absorption rate is to directly affect tile paste and performance, is also the important indicator for evaluating Ceramic Tiles quality good or not,
The size of water absorption rate all has a great impact to performances such as the intensity of ceramic tile, linear expansion, frost resistance, impact resistances, water absorption rate
Relatively low ceramic tile sintering degree is good, and intensity is higher, and integrated performance index is more excellent, is more high-grade ceramic tile.《Material Leader》
The research knot of " nano-ZnO is to Shi ceramic tiles sintering character and the influence of phase transformation " one text that in May, 2012, the special edition 19 of volume 26 was published
Fruit shows that using the ZnO powders of nanometer scale the sintered density of Shi ceramic tiles can be improved as sintering aid, so as to significantly reduce
The water absorption rate of product, the intensity and sintering temperature of product are improved, it can be seen that, it is reduction porcelain to improve sintered density
Brick water absorption rate, the effective means for improving combination property.
Metal-organic framework materials are by being self-assembly of using the multiple tooth organic ligand such as oxygen-containing, nitrogen and metal ion
The high stability class zeolitic material with periodic network structure, with nano level regular porous structure and larger ratio table
Area, is a kind of good metal nano material carrier, can effectively prevent the reunion and leaching of metal nanoparticle.It is exactly golden
These unique molecular structures of category-organic framework material and performance, if using it for sintering aid by than traditional sintering aid
With higher dispersiveness and adhesive ability.
The content of the invention
There is provided a kind of preparation technology of low water absorption ceramic tile for the defect that makes up prior art by the present invention.
The present invention is achieved by the following technical solutions：
A kind of preparation technology of low water absorption ceramic tile, comprises the following steps：
（1）Take raw material in parts by weight：Clay pit 150-350, waste ceramic material 40-200, glass dust 10-50, wollastonite 25-80,
Molybdic tailing 25-75, carries out ball milling, except iron, drying, grinding, obtained powder particle size is after all raw materials are well mixed
10-100μm；
（2）Metal organic framework compound is added in the mixed solution being formulated by absolute ethyl alcohol, water and concentrated ammonia liquor, ultrasound
Tetraethyl orthosilicate is uniformly added dropwise in vibrating dispersion afterwards, and time for adding control is stirred, completion of dropping is follow-up in 30-50min when being added dropwise
Persistent oscillation reacts 4-5h, obtains metal organic framework compound mixed with nano-silicon dioxide alkaline sol；
（3）By step（1）The powder of preparation loads in sealing spray reactor lower layers of containers, and metal organic framework compound is mixed
Miscellaneous nano silicon alkaline sol loads in spray reactor fluid box, is then turned on powder stirring device, colloidal sol is atomized
Spray makes the uniform coated powder particle of colloidal sol on lower floor's powder surface, is discharged after being disposed, and resulting material is put into forming machine
It is compressing, obtain wet base；
（4）Wet base is dried in vacuo 12-25h under the conditions of 155-200 DEG C, be made dry body, then by gained dry body through surface at
Send into after being sintered in kiln and discharge after reason, produce, wherein sintering temperature is 950-1150 DEG C, and sintering time is 4-6h.
The step（2）In metal-organic framework materials be by metal ion or cluster and organic ligand by coordination from
It is main to fill the porous material with periodicity network structure formed；Described metal ion be it is a kind of in Zn, Cu, Co, Al or
A variety of, described organic ligand is terephthalic acid (TPA), trimesic acid or methylimidazole.
The step（2）In absolute ethyl alcohol, the volume ratio of three is 100 in the mixed solution prepared of water and concentrated ammonia liquor:
（5-20）:（1-5）.
The step（2）Middle metal organic framework compound and the weight of mixed solution ratio are 1:10-20.
The step（2）The mol ratio of middle metal organic framework compound and tetraethyl orthosilicate（0.1-0.5）：1.
The present invention compounds the raw material as ceramic tile using clay pit, waste ceramic material, glass dust, wollastonite, molybdic tailing etc., is made
Ceramic dense degree is high, sintering temperature is low, and in the surface spraying cladding metal organic framework compound dopen Nano two of raw material
Silica alkaline sol is as sintering aid, this sintering aid high adsorption capacity, its uniqueness after being sprayed on raw material surface
Structure makes its uniform and stable attachment and powder surface, realizes the efficient introducing of metal ion and nano material, and improves
The forming ability of raw material, the element reaction in high-temperature sintering process in the sintering aid and powder of powder surface adhesion, generation
It is a variety of that there is compound that is fluxing, helping sintering, high intensity is just obtained under relatively low sintering temperature, high-compactness, low
The high-quality ceramic tile of water absorption rate.
Embodiment
A kind of preparation technology of low water absorption ceramic tile, comprises the following steps：
（1）Take raw material in parts by weight：Clay pit 150, waste ceramic material 40, glass dust 10, wollastonite 25, molybdic tailing 25, by institute
Ball milling is carried out after having raw material well mixed, except iron, drying, grinding, obtained powder particle size is 10 μm；
（2）Metal organic framework compound is added in the mixed solution being formulated by absolute ethyl alcohol, water and concentrated ammonia liquor, ultrasound
Tetraethyl orthosilicate is uniformly added dropwise in vibrating dispersion afterwards, and time for adding control is stirred when being added dropwise, continued after completion of dropping in 30min
Oscillating reactions 4h, obtains metal organic framework compound mixed with nano-silicon dioxide alkaline sol；
（3）By step（1）The powder of preparation loads in sealing spray reactor lower layers of containers, and metal organic framework compound is mixed
Miscellaneous nano silicon alkaline sol loads in spray reactor fluid box, is then turned on powder stirring device, colloidal sol is atomized
Spray makes the uniform coated powder particle of colloidal sol on lower floor's powder surface, is discharged after being disposed, and resulting material is put into forming machine
It is compressing, obtain wet base；
（4）Wet base is dried in vacuo 12h under the conditions of 155 DEG C, dry body is made, will then be sent into after gained dry body surface treated
Discharge, produce after being sintered in kiln, wherein sintering temperature is 950 DEG C, and sintering time is 4h.
The step（2）In metal-organic framework materials be that the autonomous dress institute of coordination is passed through by Zn ions and 2-methylimidazole
The porous material with periodicity network structure formed.
The step（2）In absolute ethyl alcohol, the volume ratio of three is 100 in the mixed solution prepared of water and concentrated ammonia liquor:
5:1。
The step（2）Middle metal organic framework compound and the weight of mixed solution ratio are 1:10.
The step（2）Middle metal organic framework compound and the mol ratio of tetraethyl orthosilicate 0.1：1.
Claims (5)
1. a kind of preparation technology of low water absorption ceramic tile, it is characterised in that comprise the following steps：
（1）Take raw material in parts by weight：Clay pit 150-350, waste ceramic material 40-200, glass dust 10-50, wollastonite 25-80,
Molybdic tailing 25-75, carries out ball milling, except iron, drying, grinding, obtained powder particle size is after all raw materials are well mixed
10-100μm；
（2）Metal organic framework compound is added in the mixed solution being formulated by absolute ethyl alcohol, water and concentrated ammonia liquor, ultrasound
Tetraethyl orthosilicate is uniformly added dropwise in vibrating dispersion afterwards, and time for adding control is stirred, completion of dropping is follow-up in 30-50min when being added dropwise
Persistent oscillation reacts 4-5h, obtains metal organic framework compound mixed with nano-silicon dioxide alkaline sol；
（3）By step（1）The powder of preparation loads in sealing spray reactor lower layers of containers, and metal organic framework compound is mixed
Miscellaneous nano silicon alkaline sol loads in spray reactor fluid box, is then turned on powder stirring device, colloidal sol is atomized
Spray makes the uniform coated powder particle of colloidal sol on lower floor's powder surface, is discharged after being disposed, and resulting material is put into forming machine
It is compressing, obtain wet base；
（4）Wet base is dried in vacuo 12-25h under the conditions of 155-200 DEG C, be made dry body, then by gained dry body through surface at
Send into after being sintered in kiln and discharge after reason, produce, wherein sintering temperature is 950-1150 DEG C, and sintering time is 4-6h.
2. a kind of preparation technology of low water absorption ceramic tile as claimed in claim 1, it is characterised in that the step（2）In
Metal-organic framework materials are that had periodically by what the autonomous dress of coordination was formed with organic ligand by metal ion or cluster
The porous material of network structure；Described metal ion be one or more in Zn, Cu, Co, Al, described organic ligands for pair
Phthalic acid, trimesic acid or methylimidazole.
3. a kind of preparation technology of low water absorption ceramic tile as claimed in claim 1, it is characterised in that the step（2）In
The volume ratio of three is 100 in the mixed solution that absolute ethyl alcohol, water and concentrated ammonia liquor are prepared:（5-20）:（1-5）.
4. a kind of preparation technology of low water absorption ceramic tile as claimed in claim 1, it is characterised in that the step（2）Middle gold
The weight ratio for belonging to organic framework compounds and mixed solution is 1:10-20.
5. a kind of preparation technology of low water absorption ceramic tile as claimed in claim 1, it is characterised in that the step（2）Middle gold
Belong to the mol ratio of organic framework compounds and tetraethyl orthosilicate（0.1-0.5）：1.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111217588A (en) * | 2018-11-27 | 2020-06-02 | 大东产业株式会社 | Method for producing high-fluidity granular powder for ceramic tile and method for producing ceramic tile |
| CN115894088A (en) * | 2022-12-19 | 2023-04-04 | 佛山欧神诺陶瓷有限公司 | Preparation method of ceramic tile, ceramic tile and application of ceramic tile |
| CN116751042A (en) * | 2023-08-17 | 2023-09-15 | 佛山市东鹏陶瓷有限公司 | Low-temperature sintered ultralow-water-absorption ceramic tile and preparation method thereof |
| CN116768613A (en) * | 2023-08-17 | 2023-09-19 | 佛山市东鹏陶瓷有限公司 | Low-temperature sintered environment-friendly ceramic tile with ultralow water absorption rate and preparation method thereof |
| CN117105645A (en) * | 2023-10-23 | 2023-11-24 | 江苏三恒高技术窑具有限公司 | Corrosion-resistant brick for nitrogen kiln |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103350000A (en) * | 2013-07-22 | 2013-10-16 | 蚌埠学院 | Metal-organic framework/SiO2 composite nanomaterial with core/shell structure and its preparation method and application |
-
2017
- 2017-06-05 CN CN201710414104.0A patent/CN107176823A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103350000A (en) * | 2013-07-22 | 2013-10-16 | 蚌埠学院 | Metal-organic framework/SiO2 composite nanomaterial with core/shell structure and its preparation method and application |
Non-Patent Citations (5)
| Title |
|---|
| （美）布莱恩•泰勒: "《釉 釉料及陶瓷颜色配制手册》", 30 November 2015, 上海科学技术出版社 * |
| 张冬梅: "《岩石矿物分析》", 30 April 2014, 地质出版社 * |
| 李金惠: "《中国城市矿产开发利用实践与展望》", 31 December 2015, 中国环境出版社 * |
| 谢昆: "《纳米技术在水污染控制中的应用》", 30 June 2014, 武汉大学出版社 * |
| 马小鹏: "金钼尾矿用于陶瓷原料的研究与评价", 《陶瓷》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111217588A (en) * | 2018-11-27 | 2020-06-02 | 大东产业株式会社 | Method for producing high-fluidity granular powder for ceramic tile and method for producing ceramic tile |
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| CN116751042A (en) * | 2023-08-17 | 2023-09-15 | 佛山市东鹏陶瓷有限公司 | Low-temperature sintered ultralow-water-absorption ceramic tile and preparation method thereof |
| CN116768613A (en) * | 2023-08-17 | 2023-09-19 | 佛山市东鹏陶瓷有限公司 | Low-temperature sintered environment-friendly ceramic tile with ultralow water absorption rate and preparation method thereof |
| CN117105645A (en) * | 2023-10-23 | 2023-11-24 | 江苏三恒高技术窑具有限公司 | Corrosion-resistant brick for nitrogen kiln |
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Application publication date: 20170919 |