CN107163968B - Pyrolysis device and pyrolysis method for producing coke breeze and light tar - Google Patents
Pyrolysis device and pyrolysis method for producing coke breeze and light tar Download PDFInfo
- Publication number
- CN107163968B CN107163968B CN201710432714.3A CN201710432714A CN107163968B CN 107163968 B CN107163968 B CN 107163968B CN 201710432714 A CN201710432714 A CN 201710432714A CN 107163968 B CN107163968 B CN 107163968B
- Authority
- CN
- China
- Prior art keywords
- pyrolysis
- reactor
- pyrolysis reactor
- gas
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 361
- 239000000571 coke Substances 0.000 title claims abstract description 89
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000007789 gas Substances 0.000 claims description 94
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 54
- 239000003546 flue gas Substances 0.000 claims description 54
- 239000003921 oil Substances 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 35
- 239000004449 solid propellant Substances 0.000 claims description 32
- 239000003245 coal Substances 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 18
- 239000011343 solid material Substances 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 10
- 230000009471 action Effects 0.000 claims description 9
- 239000002028 Biomass Substances 0.000 claims description 3
- 239000004058 oil shale Substances 0.000 claims description 3
- 239000011269 tar Substances 0.000 description 43
- 239000000047 product Substances 0.000 description 16
- 238000002485 combustion reaction Methods 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 239000000428 dust Substances 0.000 description 3
- 239000003077 lignite Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003027 oil sand Substances 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011287 low-temperature tar Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- -1 steam Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
- C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
- C10B55/04—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/02—Multi-step carbonising or coking processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
技术领域technical field
本发明属于能源化工领域,具体地涉及到一种生产粉焦和轻质焦油的热解装置及方法。The invention belongs to the field of energy and chemical industry, and in particular relates to a pyrolysis device and method for producing powder coke and light tar.
背景技术Background technique
煤炭占中国能源消费结构的75%以上,其中80%以上用于直接燃烧,且50%以上供直接燃烧块煤的工业锅炉、工业窑炉及家用燃煤炉使用,但是,直接燃烧的利用方式造成煤炭利用效率低、污染物排放超标。另外,随着采煤机械化程度的提高,块煤产率由52~60%降至20~38%,加重了块煤短缺,而且还造成粉煤长期大量积压。尤其是大量的低阶煤粉煤,由于其水分含量高、热值低、以及易分化和不易运输等缺点,导致难以加工利用,因此,如何高效地利用低阶煤粉煤,成为目前煤炭利用领域急需解决的问题。而且,随着国内能源需求日益增大,对低阶煤,尤其是低阶煤粉煤的综合转化利用势必将成为未来能源需求的有力支撑。Coal accounts for more than 75% of China's energy consumption structure, of which more than 80% is used for direct combustion, and more than 50% is used for industrial boilers, industrial kilns and household coal-fired furnaces that directly burn lump coal. However, the utilization method of direct combustion Resulting in low coal utilization efficiency and excessive pollutant emissions. In addition, with the improvement of coal mining mechanization, the yield of lump coal dropped from 52-60% to 20-38%, which aggravated the shortage of lump coal and caused a large long-term backlog of pulverized coal. In particular, a large amount of low-rank pulverized coal is difficult to process and utilize due to its high moisture content, low calorific value, easy differentiation and difficult transportation. Therefore, how to efficiently utilize low-rank pulverized coal has become the current coal utilization problems in the field that need to be solved urgently. Moreover, with the increasing domestic energy demand, the comprehensive conversion and utilization of low-rank coal, especially low-rank pulverized coal, is bound to become a strong support for future energy demand.
利用热解方式将煤加工成半焦、低温焦油和焦炉气的化学过程,是目前低阶煤加工处理的有效途径之一。通过热解获得热解气、焦油以及半焦,热解气及焦油可直接作为清洁燃料燃烧,也可以通过后续加工处理,生产高附加值化工产品,实现煤炭分级利用与清洁高效转化。目前,工业上对于大颗粒(>6mm)煤的低温热解,普遍采用直立炉的工艺进行热解,例如,已成熟的兰炭生产工艺,它实现了固体能源向气体、液体能源以及固体化工原料的高效转化,对于资源利用来说,开辟了高效灵活利用资源的途径。但是,生产兰炭的原料为块状烟煤或块状褐煤,而粉煤原料导致物料层的透气性差,且容易堵塞花墙的气孔,影响正常生产,因此兰炭工艺限制了原料使用的范围。而且,针对6mm以下的粉煤热解,目前工业上也尚未有成熟的工艺。The chemical process of processing coal into semi-coke, low-temperature tar and coke oven gas by pyrolysis is one of the effective ways to process low-rank coal at present. Pyrolysis gas, tar, and semi-coke are obtained through pyrolysis. Pyrolysis gas and tar can be directly burned as clean fuels, and can also be processed to produce high value-added chemical products to achieve coal graded utilization and clean and efficient conversion. At present, for the low-temperature pyrolysis of large particle (>6mm) coal, the vertical furnace process is generally used for pyrolysis. For example, the mature semi-coke production process realizes the conversion of solid energy to gas, liquid energy and solid chemical industry The high-efficiency conversion of raw materials opens up a way to efficiently and flexibly utilize resources for resource utilization. However, the raw material for producing semi-coke is lumpy bituminous coal or lignite, and the pulverized coal raw material leads to poor air permeability of the material layer, and it is easy to block the pores of the flower wall, which affects normal production. Therefore, the semi-coke process limits the scope of raw material use. Moreover, for the pyrolysis of pulverized coal below 6mm, there is no mature process in industry at present.
发明内容Contents of the invention
本发明的目的之一在于提供一种生产粉焦和轻质焦油的热解装置,该装置可以实现粉末固体燃料的热解得到热解油气和热解半焦。本发明的另一目的在于提供一种生产粉焦和轻质焦油的热解方法,使用该方法可以获得洁净粉焦、蒸汽、以及轻质焦油,并实现反应中热量的回收。One of the objectives of the present invention is to provide a pyrolysis device for producing fine coke and light tar, which can realize pyrolysis of powdered solid fuel to obtain pyrolysis oil gas and pyrolysis semi-coke. Another object of the present invention is to provide a pyrolysis method for producing fine coke and light tar, which can be used to obtain clean fine coke, steam, and light tar, and to realize heat recovery in the reaction.
本发明以实现粉末固体燃料在多级强旋流热解反应器中被锅炉燃烧产生的热烟气快速加热发生热解反应,生成热解油气和热解半焦;热解油气中轻质组分通过焦油捕集,获得轻质焦油;热解油气中未被捕集的重质组分进入锅炉燃烧,产生热烟气和蒸汽;高温热烟气作为热载体与固体物料和热解半焦逆流接触换热,并将固体物料和热解半焦送入强旋流热解反应器进行热解;热解半焦通过冷却并回收热量,可获得粉焦。采用本发明技术的装置及方法,最终获得洁净粉焦、蒸汽、以及轻质焦油。The invention realizes that the powdered solid fuel is rapidly heated by the hot flue gas generated by boiler combustion in a multi-stage strong swirl pyrolysis reactor to generate pyrolysis oil gas and pyrolysis semi-coke; the light components in the pyrolysis oil gas The light tar is obtained through tar capture; the uncaptured heavy components in the pyrolysis oil gas enter the boiler for combustion to generate hot flue gas and steam; the high-temperature hot flue gas is used as a heat carrier to interact with solid materials and pyrolysis semi-coke Countercurrent contact heat exchange, and the solid material and pyrolysis semi-coke are sent to the strong swirling flow pyrolysis reactor for pyrolysis; the pyrolysis semi-coke can be cooled and heat recovered to obtain powder coke. By adopting the device and method of the technology of the present invention, clean powder coke, steam, and light tar are finally obtained.
本发明涉及的强旋流热解反应器,其特点是将燃烧后产生的烟气以高速射流的形式切向喷入高温热解器中,形成强烈的旋风涡流;固体物料在进入热解反应器前,在气体管道内悬浮于热烟气中,同时进行热交换,然后被热烟气带入热解反应器中;,固体物料进入热解器后,继续与高温烟气混合、加热、发生热解反应。The strong swirl flow pyrolysis reactor involved in the present invention is characterized in that the flue gas produced after combustion is sprayed tangentially into the high temperature pyrolysis device in the form of high-speed jet to form a strong whirlwind vortex; the solid material enters the pyrolysis reaction In front of the pyrolysis reactor, it is suspended in the hot flue gas in the gas pipeline, and heat exchange is performed at the same time, and then it is brought into the pyrolysis reactor by the hot flue gas; after the solid material enters the pyrolysis reactor, it continues to be mixed with high-temperature flue gas, heated, A pyrolysis reaction occurs.
为实现上述目的,本发明提供了一种生产粉焦和轻质焦油的热解装置,所述热解装置包括多级热解反应器、半焦冷却装置和半焦收集罐;To achieve the above object, the present invention provides a pyrolysis device for producing fine coke and light tar, the pyrolysis device includes a multi-stage pyrolysis reactor, a semi-coke cooling device and a semi-coke collection tank;
所述多级热解反应器包括若干热解反应器,除首级热解反应器和末级热解反应器外的热解气进口和下一级热解反应器的热解气出口连接,热解反应器的物料出口和下一级热解反应器的热解气进口管道连接,其热解气出口和上一级热解反应器的热解气进口连接;所述末级热解反应器的物料出口和所述半焦冷却装置连接,所述半焦冷却装置的物料出口和半焦收集罐连接。The multi-stage pyrolysis reactor includes several pyrolysis reactors, and the pyrolysis gas inlet except the first-stage pyrolysis reactor and the last-stage pyrolysis reactor is connected with the pyrolysis gas outlet of the next-stage pyrolysis reactor, The material outlet of the pyrolysis reactor is connected to the pyrolysis gas inlet pipeline of the next-stage pyrolysis reactor, and the pyrolysis gas outlet is connected to the pyrolysis gas inlet of the upper-stage pyrolysis reactor; the final pyrolysis reaction The material outlet of the device is connected to the semi-coke cooling device, and the material outlet of the semi-coke cooling device is connected to the semi-coke collecting tank.
上述装置中,所述多级热解反应器用于粉末固体燃料的热解,产生热解油气以及热解半焦;所述半焦冷却装置用于对产生的热解半焦进行冷却,并进行热量回收;所述半焦收集罐用于收集由末级热解反应器产生,并经半焦冷却装置冷却的粉末半焦产品;产生的热解半焦经和进入下一级热解反应器的热解气混合换热后被送入下一级热解反应器。In the above-mentioned device, the multi-stage pyrolysis reactor is used for pyrolysis of powdered solid fuel to produce pyrolysis oil gas and pyrolysis semi-coke; the semi-coke cooling device is used to cool the generated pyrolysis semi-coke, and perform Heat recovery; the semi-coke collection tank is used to collect the powder semi-coke products produced by the final pyrolysis reactor and cooled by the semi-coke cooling device; the generated pyrolysis semi-coke passes through and enters the next-stage pyrolysis reactor The pyrolysis gas is mixed and exchanged and then sent to the next stage pyrolysis reactor.
作为上述装置的一种更好选择,所述多级热解反应器的级数为3-6。As a better choice of the above device, the number of stages of the multistage pyrolysis reactor is 3-6.
作为上述装置的一种更好选择,所述首级热解反应器的热解气出口和焦油捕集装置的气体进口连接。所述焦油捕集系统用于捕集由多级强旋流热解反应器生成的热解油气中的轻质组分,获得轻质焦油。As a better choice of the above device, the pyrolysis gas outlet of the first stage pyrolysis reactor is connected to the gas inlet of the tar trapping device. The tar trapping system is used for trapping light components in the pyrolysis oil and gas generated by multi-stage strong swirling flow pyrolysis reactors to obtain light tar.
作为上述装置的一种更好选择,所述焦油捕集装置的气体出口和锅炉连接,所述锅炉的烟气出口和所述末级热解反应器的烟气入口连接。所述锅炉用于热解油气中重质组分的燃烧,同时产生热烟气和蒸汽;其中,热烟气为固体燃料在多级热解反应器中的热解提供所需热量。As a better choice of the above device, the gas outlet of the tar trapping device is connected to a boiler, and the flue gas outlet of the boiler is connected to the flue gas inlet of the final pyrolysis reactor. The boiler is used for burning heavy components in pyrolysis oil and gas, and simultaneously generates hot flue gas and steam; wherein, the hot flue gas provides the required heat for the pyrolysis of solid fuel in the multi-stage pyrolysis reactor.
作为上述装置的一种更好选择,所述首级热解反应器的热解气出口和锅炉连接,所述锅炉的烟气出口和所述末级热解反应器的烟气入口连接。所述锅炉用于热解油气中重质组分的燃烧,同时产生热烟气和蒸汽;其中,热烟气为固体燃料在多级热解反应器中的热解提供所需热量。As a better choice of the above device, the pyrolysis gas outlet of the first-stage pyrolysis reactor is connected to the boiler, and the flue gas outlet of the boiler is connected to the flue gas inlet of the last-stage pyrolysis reactor. The boiler is used for burning heavy components in pyrolysis oil and gas, and simultaneously generates hot flue gas and steam; wherein, the hot flue gas provides the required heat for the pyrolysis of solid fuel in the multi-stage pyrolysis reactor.
作为上述装置的一种更好选择,所述首级热解反应器的物料入口和料仓连接,所述料仓用于储存待处理的粉末固体物料。As a better choice of the above device, the material inlet of the primary pyrolysis reactor is connected to a silo, and the silo is used to store powdered solid materials to be processed.
本发明还提供了基于上述装置用于生产粉焦和轻质焦油的热解方法,包括:The present invention also provides a pyrolysis method for producing fine coke and light tar based on the above device, including:
粉末固体燃料先与来自下一级热解反应器的热解气逆流接触,并在热解气的作用下被送入多级热解反应器的首级热解反应器,并在首级热解反应器中继续被下一级的热解气加热,发生热解反应,生成热解油气和热解半焦,热解半焦进入下一级热解反应器;The powdered solid fuel is in countercurrent contact with the pyrolysis gas from the next pyrolysis reactor, and is sent to the first pyrolysis reactor of the multistage pyrolysis reactor under the action of the pyrolysis gas, and is heated in the first stage The pyrolysis reactor continues to be heated by the pyrolysis gas of the next stage, pyrolysis reaction occurs, and pyrolysis oil gas and pyrolysis semi-coke are generated, and the pyrolysis semi-coke enters the next stage pyrolysis reactor;
热解半焦首先与来自下两级热解反应器的热解气逆流接触,在热解气的作用下被送入除首级热解反应器和末级热解反应器外的热解反应器后,其被来自下两级热解反应器的热解油气混合换热,并继续热解,热解产生的热解油气进入上一级热解反应器,热解产生的热解半焦进入下一级热解反应器;The pyrolysis semi-coke is first contacted with the pyrolysis gas from the next two-stage pyrolysis reactor in countercurrent, and under the action of the pyrolysis gas, it is sent to the pyrolysis reaction except the first-stage pyrolysis reactor and the last-stage pyrolysis reactor. After the pyrolysis reactor, it is mixed with pyrolysis oil and gas from the lower two-stage pyrolysis reactor for heat exchange, and continues to pyrolyze. The pyrolysis oil and gas generated by pyrolysis enters the upper stage pyrolysis reactor, and the pyrolysis semi-coke Enter the next stage pyrolysis reactor;
末级热解反应器热解后的热解半焦经冷却后得到粉焦。The pyrolysis semi-coke after pyrolysis in the final pyrolysis reactor is cooled to obtain powder coke.
作为上述方法的一种更好选择,所述方法进一步包括:As a better choice of the above method, the method further includes:
首级热解反应器热解产生的热解油气经焦油捕集装置,获得轻质焦油。The pyrolysis oil gas produced by pyrolysis in the first stage pyrolysis reactor passes through the tar trapping device to obtain light tar.
作为上述方法的一种更好选择,所述方法进一步包括:As a better choice of the above method, the method further includes:
未被焦油捕集装置捕集的重质组分进入锅炉燃烧产生热烟气和蒸汽,所述热烟气用于固体物料和热解半焦的热解。The heavy components not captured by the tar capture device enter the boiler for combustion to generate hot flue gas and steam, and the hot flue gas is used for pyrolysis of solid materials and pyrolysis semi-coke.
作为上述方法的一种更好选择,所述方法进一步包括:As a better choice of the above method, the method further includes:
首级热解反应器热解产生的热解油气进入锅炉燃烧产生热烟气和蒸汽,所述热烟气用于固体物料和热解半焦的热解。The pyrolysis oil gas produced by the pyrolysis of the first-stage pyrolysis reactor enters the boiler for combustion to generate hot flue gas and steam, and the hot flue gas is used for pyrolysis of solid materials and pyrolysis semi-coke.
作为上述方法的一种更好选择,所述热解方法进一步包括:末级热解反应器排出的热解产生的热解半焦经半焦冷却装置冷却,并回收热量,同时得到粉焦产品。As a better choice of the above method, the pyrolysis method further includes: the pyrolysis semi-coke produced by the pyrolysis discharged from the final pyrolysis reactor is cooled by the semi-coke cooling device, and the heat is recovered, and the powder coke product is obtained at the same time .
作为上述方法的一种更好选择,所述的粉末固体燃料是煤炭、生物质、油页岩或者油砂。As a better choice of the above method, the powdered solid fuel is coal, biomass, oil shale or oil sand.
本发明生产粉焦和轻质焦油的热解方法,包括如下步骤:The present invention produces the pyrolysis method of fine coke and light tar, comprises the steps:
1)粉末固体燃料由料仓送入,并在热烟气的作用下,被送入多级强旋流热解反应器,并在热解反应器中继续被来自锅炉的热烟气加热,发生热解反应,生成热解油气和热解半焦;1) The powdered solid fuel is sent from the silo, and under the action of the hot flue gas, it is sent to the multi-stage strong swirl pyrolysis reactor, and is continuously heated by the hot flue gas from the boiler in the pyrolysis reactor. A pyrolysis reaction occurs to generate pyrolysis oil gas and pyrolysis semi-coke;
2)由热解产生的热解油气经焦油捕集装置,获得轻质焦油,可进一步精制得到高附加值产品;2) The pyrolysis oil gas produced by pyrolysis passes through the tar capture device to obtain light tar, which can be further refined to obtain high value-added products;
3)热解油气中未被焦油捕集装置捕集的重质组分进入锅炉燃烧,同时产生热烟气和蒸汽;其中,热烟气返回多级强旋流热解反应器为热解提供热量;3) The heavy components in the pyrolysis oil and gas that are not captured by the tar capture device enter the boiler for combustion, and generate hot flue gas and steam at the same time; among them, the hot flue gas returns to the multi-stage strong swirling flow pyrolysis reactor to provide pyrolysis. heat;
4)由热解产生的热解半焦经半焦冷却装置冷却,并进行热量回收,同时得到粉焦产品,利用半焦收集罐收集。4) The pyrolysis semi-coke produced by pyrolysis is cooled by the semi-coke cooling device, and the heat is recovered, and the powder coke product is obtained at the same time, which is collected by the semi-coke collection tank.
本发明可应用于通过热解反应从固体燃料中获得洁净粉焦、蒸汽、液体燃料以及高附加值化学产品。所涉及的固体燃料包括:煤炭、油页岩、油砂以及生物质等含碳固体燃料;所述粉末固体燃料的粒径低于10mm。而且,本发明中所涉及的固体燃料,可以是同一种类固体燃料或者不同种类固体燃料。The invention can be applied to obtain clean powder coke, steam, liquid fuel and high value-added chemical products from solid fuel through pyrolysis reaction. The involved solid fuels include: carbon-containing solid fuels such as coal, oil shale, oil sand, and biomass; the particle size of the powdered solid fuels is less than 10mm. Moreover, the solid fuel involved in the present invention may be the same type of solid fuel or different types of solid fuel.
本发明热解过程主要包括:固体燃料在多级强旋流热解反应器中被热烟气加热发生的热解反应,生成热解油气和热解半焦;高热值的热解油气中轻质组分经焦油捕集后,重质组分被送入锅炉中燃烧产生热烟气和蒸汽,热烟气返回强旋流反应器中为固体燃料的热解提供所需热量。The pyrolysis process of the present invention mainly includes: a pyrolysis reaction in which solid fuel is heated by hot flue gas in a multi-stage strong swirling flow pyrolysis reactor to generate pyrolysis oil gas and pyrolysis semi-coke; After the heavy components are captured by tar, the heavy components are sent to the boiler for combustion to generate hot flue gas and steam, and the hot flue gas returns to the strong swirl reactor to provide the required heat for the pyrolysis of solid fuels.
本发明涉及的热解过程还包括,在强旋流热解反应器中产生的热解半焦,在进入下一级反应器中继续发生热解反应。而且,为固体燃料以及热解半焦的热解反应提供热量的热载体,包括热烟气和热解产生的热解油气。The pyrolysis process involved in the present invention also includes that the pyrolysis semi-coke produced in the strong swirling flow pyrolysis reactor continues to undergo pyrolysis reaction in the next-stage reactor. Moreover, the heat carrier that provides heat for the pyrolysis reaction of solid fuel and pyrolysis semi-coke includes hot flue gas and pyrolysis oil gas produced by pyrolysis.
本发明实现了低阶煤粉煤的分级转化及高效利用,且同时解决粉煤热解工艺中细煤粉与煤焦油混合物难以分离、易堵塞设备管道等技术问题及难以工程化等现状,并保证热解过程中有较高的能量利用效率。本发明采用强旋流热解反应器,利用旋风流场旋流强度高、湍流混合强烈的特点,强化炉内传热传质过程,延长粉煤在炉内的停留时间,以提高炉内的热强度;而且,在强旋流热解器中,具有固体物料与热载体之间快速混合、快速加热、以及气固产物快速分离,有利于轻质焦油产生的特点。因此,本发明的装置采用多级强旋流热解反应器,以锅炉燃烧产生的热烟气作为热载体为热解反应提供热量,使固体燃料在强旋流热解反应器中与热烟气快速混合、且被快速加热,以发生热解反应,生成热解油气和热解半焦;热解油气中轻质组分经焦油捕集,获得轻质焦油,并经进一步加工处理,生产高附加值产品;热解油气中未被捕集的重质组分进入锅炉中燃烧,产生热烟气及蒸汽;高温热烟气返回强旋流热解器中作为热载体供热;热解半焦通过冷却并回收热量,可获得粉焦;通过本发明的实施,最终获得洁净粉焦、轻质焦油和蒸汽。The invention realizes the graded conversion and high-efficiency utilization of low-order pulverized coal, and at the same time solves the technical problems such as difficult separation of fine coal and coal tar mixture in the pulverized coal pyrolysis process, easy blockage of equipment pipelines, and difficulty in engineering. Ensure high energy utilization efficiency in the pyrolysis process. The invention adopts a strong swirl pyrolysis reactor, utilizes the characteristics of high swirl intensity and strong turbulent mixing in the cyclone flow field, strengthens the heat and mass transfer process in the furnace, prolongs the residence time of pulverized coal in the furnace, and improves the temperature of the furnace. Heat intensity; moreover, in the strong cyclone pyrolyzer, it has the characteristics of rapid mixing between solid materials and heat carrier, rapid heating, and rapid separation of gas-solid products, which is conducive to the production of light tar. Therefore, the device of the present invention adopts a multi-stage strong swirl pyrolysis reactor, and uses the hot flue gas produced by boiler combustion as a heat carrier to provide heat for the pyrolysis reaction, so that the solid fuel is mixed with the hot smoke in the strong swirl pyrolysis reactor. The gas is quickly mixed and heated to produce pyrolysis reaction to generate pyrolysis oil gas and pyrolysis semi-coke; the light components in the pyrolysis oil gas are captured by tar to obtain light tar, which is further processed to produce High value-added products; uncaptured heavy components in pyrolysis oil and gas enter the boiler for combustion to generate hot flue gas and steam; high-temperature hot flue gas returns to the strong swirling flow pyrolyzer as a heat carrier for heating; pyrolysis Coke powder can be obtained by cooling the semi-coke and recovering heat; through the implementation of the present invention, clean powder coke, light tar and steam can be finally obtained.
本发明相较于现有技术具有如下的优势:Compared with the prior art, the present invention has the following advantages:
1、与传统的固定床和流化床热解反应器相比,强旋流热解反应器展现了诸多优势,首先,运行过程中,固体物料进入联结管道后,随即便被上升气流冲散,使其均匀地悬浮于气流当中,气固快速混合且混合充分,固体物料随气流旋转运行;由于悬浮态时气、固之间的接触面积极大,对流传热系统比较高,因此换热速度极快,完成有效换热的时间只需0.02~0.04s;而且,热解气固产物很容易实现分离,最终热解油气被排出,固体半焦被收集;1. Compared with traditional fixed bed and fluidized bed pyrolysis reactors, strong swirling flow pyrolysis reactors have shown many advantages. First, during operation, after solid materials enter the connecting pipeline, they are immediately washed away by the updraft , so that it is evenly suspended in the air flow, the gas-solid mixes quickly and fully, and the solid material rotates with the air flow; due to the large contact area between the gas and the solid in the suspension state, the convection heat transfer system is relatively high, so the heat transfer The speed is extremely fast, and it only takes 0.02-0.04s to complete the effective heat exchange; moreover, the pyrolysis gas-solid products are easily separated, and finally the pyrolysis oil gas is discharged, and the solid semi-coke is collected;
2、本发明中,利用多级强旋流热解反应器的优势还在于,在单级强旋流热解反应器内部,固体物料与热载体以气固并流方式接触换热,而在多级强旋流热解器的各级反应器之间的管道中,以气固逆流方式接触换热,可延长固体燃料在逆流气中的停留时间,使固体燃料有更充分的受热过程,具有增强对流传热、提高燃料升温速率的作用,且更有利于提高轻质焦油的收率;2. In the present invention, the advantage of using the multi-stage strong swirl pyrolysis reactor is that, inside the single-stage strong swirl pyrolysis reactor, the solid material and the heat carrier are contacted and exchanged in a gas-solid co-current manner, while in the single-stage strong swirl pyrolysis reactor In the pipes between the reactors of the multi-stage strong swirl pyrolyzer, the gas-solid countercurrent contact heat exchange method can prolong the residence time of the solid fuel in the countercurrent gas, so that the solid fuel can have a more sufficient heating process. It has the effect of enhancing convective heat transfer, increasing the heating rate of fuel, and is more conducive to increasing the yield of light tar;
3、本发明中,由系统自身产生的热烟气和热解油气作为气体热载体,为热解反应过程提供热量,无需外部供热,提高了系统的运转负荷以及热效率;3. In the present invention, the hot flue gas and pyrolysis oil gas generated by the system itself are used as gas heat carriers to provide heat for the pyrolysis reaction process without external heat supply, which improves the operating load and thermal efficiency of the system;
4、在本发明中,热解反应器采用多级强旋流热解反应器,原料煤在进入热解器后,首先在第一级反应器中热解,产生的热解半焦进入第二级热解反应器中继续热解,以此方式在多级的强旋流热解反应器中反复热解,从而得到洁净的半焦产品;4. In the present invention, the pyrolysis reactor adopts a multi-stage strong swirling flow pyrolysis reactor. After the raw coal enters the pyrolysis device, it is firstly pyrolyzed in the first-stage reactor, and the pyrolysis semi-coke produced enters the second stage. Continue pyrolysis in the secondary pyrolysis reactor, and repeat pyrolysis in the multi-stage strong swirl pyrolysis reactor in this way, so as to obtain clean semi-coke products;
5、利用强旋流热解反应器,其炉内容积热强度较高,设计时可缩小炉内体积,简化系统结构;而且在热解器中就可实现对油气中飞灰颗粒的初步除尘;而且,对于热解油气中含尘高的重质组分被直接送入锅炉燃烧,因此,整个系统无需炉外除尘系统,可简化后续净化系统,进一步提高了系统的可靠性和稳定性;5. Using the strong swirling flow pyrolysis reactor, the thermal intensity of the furnace volume is relatively high, the furnace volume can be reduced during design, and the system structure can be simplified; and the preliminary dust removal of fly ash particles in oil and gas can be realized in the pyrolyzer ; Moreover, the heavy components with high dust content in pyrolysis oil and gas are directly sent to the boiler for combustion. Therefore, the whole system does not need an external dust removal system, which can simplify the subsequent purification system and further improve the reliability and stability of the system;
6、本发明中采用多级强旋流热解反应器对固体燃料进行热解,其中,强旋流热解反应器级数的设计,可根据研究目的、目标产品的纯度、以及热烟气在多级强旋流热解反应器出口、入口的温度来灵活决定。6. In the present invention, a multi-stage strong swirl pyrolysis reactor is used to pyrolyze the solid fuel, wherein the design of the stages of the strong swirl pyrolysis reactor can be based on the research purpose, the purity of the target product, and the hot flue gas The temperature at the outlet and inlet of the multi-stage strong swirl pyrolysis reactor can be flexibly determined.
综上所述,本发明采用多级强旋流热解反应器,并利用自身系统产生的热烟气作为气体热载体,为固体粉末燃料提供热解所需热量;而且利用强旋流热解反应器自身的优势,可在系统内实现固体物料与气体热载体的快速混合、物料的快速加热及快速热解、以及产物的快速分离,可简化系统结构;最终获得洁净粉焦、轻质焦油以及蒸汽。In summary, the present invention adopts a multi-stage strong swirl pyrolysis reactor, and uses the hot flue gas produced by its own system as a gas heat carrier to provide the heat required for pyrolysis of solid powder fuel; and utilizes strong swirl pyrolysis The advantages of the reactor itself can realize rapid mixing of solid materials and gas heat carriers, rapid heating and rapid pyrolysis of materials, and rapid separation of products in the system, which can simplify the system structure; finally obtain clean powder coke and light tar and steam.
附图说明Description of drawings
图1为本发明的一种生产粉焦和轻质焦油的装置与热解方法的示意图;Fig. 1 is a schematic diagram of a device and pyrolysis method for producing fine coke and light tar of the present invention;
图2为本发明的一种生产粉焦和轻质焦油的装置与热解方法的实施例示意图;Fig. 2 is a schematic diagram of an embodiment of a device and a pyrolysis method for producing fine coke and light tar of the present invention;
附图标识Reference sign
1、多级强旋流热解反应器;2、焦油捕集装置;3、锅炉;4、半焦冷却装置;5、半焦收集罐;6、料仓。1. Multi-stage strong swirling pyrolysis reactor; 2. Tar trapping device; 3. Boiler; 4. Semi-coke cooling device; 5. Semi-coke collection tank; 6. Stock bin.
具体实施方式Detailed ways
下面结合附图对本发明的装置作进一步说明。The device of the present invention will be further described below in conjunction with the accompanying drawings.
如图1所示,本发明涉及的主要装置有:用于实现固体燃料热解的多级强旋流热解反应器1、用于获得轻质焦油的焦油捕集装置2、用于提供热解所需热量以及获得产物蒸汽的锅炉3、用于将产物半焦冷却并进行热量回收的装置4、用于获得粉焦产品的半焦收集罐5、用于储存固体物料的料仓6。As shown in Figure 1, the main devices involved in the present invention include: a multi-stage strong swirling flow
所述多级热解反应器包括若干热解反应器,除首级热解反应器和末级热解反应器外的热解反应器的物料出口和下一级热解反应器的热解气进口管道连接,其热解气进口和下一级热解反应器的热解气出口连接,其热解气出口和上一级热解反应器的热解气进口连接;所述末级热解反应器的物料出口和所述半焦冷却装置连接,所述半焦冷却装置的物料出口和半焦收集罐连接。The multistage pyrolysis reactor includes several pyrolysis reactors, the material outlet of the pyrolysis reactor and the pyrolysis gas of the next stage pyrolysis reactor except the first stage pyrolysis reactor and the last stage pyrolysis reactor. The inlet pipeline is connected, and its pyrolysis gas inlet is connected to the pyrolysis gas outlet of the next-stage pyrolysis reactor, and its pyrolysis gas outlet is connected to the pyrolysis gas inlet of the upper-stage pyrolysis reactor; The material outlet of the reactor is connected with the semi-coke cooling device, and the material outlet of the semi-coke cooling device is connected with the semi-coke collecting tank.
上述装置中,所述多级热解反应器用于粉末固体燃料的热解,产生热解油气以及热解半焦;所述半焦冷却装置用于对产生的热解半焦进行冷却,并进行热量回收;所述半焦收集罐用于收集由末级热解反应器产生,并经半焦冷却装置冷却的粉末半焦产品。In the above-mentioned device, the multi-stage pyrolysis reactor is used for pyrolysis of powdered solid fuel to produce pyrolysis oil gas and pyrolysis semi-coke; the semi-coke cooling device is used to cool the generated pyrolysis semi-coke, and perform Heat recovery; the semi-coke collection tank is used to collect powder semi-coke products produced by the final pyrolysis reactor and cooled by the semi-coke cooling device.
所述多级热解反应器的级数可以选择3-6。The number of stages of the multistage pyrolysis reactor can be selected from 3-6.
所述首级热解反应器的热解气出口和焦油捕集装置的气体进口连接。所述焦油捕集系统用于捕集由多级强旋流热解反应器生成的热解油气中的轻质组分,获得轻质焦油。The pyrolysis gas outlet of the primary pyrolysis reactor is connected to the gas inlet of the tar trapping device. The tar trapping system is used for trapping light components in the pyrolysis oil and gas generated by multi-stage strong swirling flow pyrolysis reactors to obtain light tar.
请参见图1,所述焦油捕集装置的气体出口和锅炉连接,所述锅炉的烟气出口和所述末级热解反应器的烟气入口连接。所述锅炉用于热解油气中重质组分的燃烧,同时产生热烟气和蒸汽;其中,热烟气为固体燃料在多级热解反应器中的热解提供所需热量。Please refer to FIG. 1 , the gas outlet of the tar trapping device is connected to the boiler, and the flue gas outlet of the boiler is connected to the flue gas inlet of the final pyrolysis reactor. The boiler is used for burning heavy components in pyrolysis oil and gas, and simultaneously generates hot flue gas and steam; wherein, the hot flue gas provides the required heat for the pyrolysis of solid fuel in the multi-stage pyrolysis reactor.
请参见图2,该装置中也可以不设置焦油捕集装置,此时所述首级热解反应器的热解气出口和锅炉连接,所述锅炉的烟气出口和所述末级热解反应器的烟气入口连接。所述锅炉用于热解油气中重质组分的燃烧,同时产生热烟气和蒸汽;其中,热烟气为固体燃料在多级热解反应器中的热解提供所需热量。Please refer to Fig. 2, also can not be provided with tar collection device in this device, at this moment the pyrolysis gas outlet of described primary pyrolysis reactor is connected with boiler, and the flue gas outlet of described boiler is connected with described final stage pyrolysis gas outlet. The flue gas inlet connection to the reactor. The boiler is used for burning heavy components in pyrolysis oil and gas, and simultaneously generates hot flue gas and steam; wherein, the hot flue gas provides the required heat for the pyrolysis of solid fuel in the multi-stage pyrolysis reactor.
如下为利用上述装置进行轻质焦油热解的方法。The method for pyrolyzing light tar by using the above-mentioned device is as follows.
实施例1:热解系统包括四级强旋流热解反应器(图中,n为4)Embodiment 1: pyrolysis system comprises four stages of strong swirling flow pyrolysis reactors (in the figure, n is 4)
霍林河褐煤(粉煤),在来自二级强旋流热解器(1-2)的热解油气2和热烟气的作用下,被带入一级强旋流热解反应器(1-1)中,并在反应器中继续与来自二级强旋流热解器(1-2)的热解油气2混合、换热,发生热解反应,生成的热解油气1从一级反应器排出,热解半焦1在来自三级反应器(1-3)的热解油气3的作用下被送入二级热解器(1-2);在二级热解反应器(1-2)中继续与来自三级反应器(1-3)的热解油气3混合换热,继续热解,生成的热解油气2排出并进入热解反应器(1-1),产生的热解半焦在来自四级反应器(1-4)的热解油气4的作用下被送入三级热解器(1-3);在三级热解反应器(1-3)中,继续与来自四级热解器(1-4)的热解油气4混合、换热以进行热解,生成的热解油气3排出进入热解反应器(1-2),产生的热解半焦在来自锅炉燃烧产生的热烟气作用下被送入四级热解器(1-4);在四级热解器(1-4)中,继续与来自锅炉的热烟气混合换热进行热解反应,生成的热解油气4排出进入热解反应器(1-3),最终产物半焦4从四级强旋流热解反应器底部排出,经冷却以及热量回收,被半焦收集罐5收集;而最终由一级反应器(1-1)排出的热解油气1先经焦油捕集装置2捕集到热解油气1中的轻质组分,获得轻质焦油;热解油气2中未被捕集的重质组分进入锅炉燃烧,生成热烟气和蒸汽产品,热烟气作为热载体返回系统,由四级强旋流热解反应器(1-4)进入反应系统,与热解反应器中的固体物料混合、换热以发生热解反应;通过对霍林河褐煤粉煤的热解,最终获得了清洁的粉焦、轻质焦油和蒸汽产品。Huolinhe lignite (powdered coal), under the action of the pyrolysis oil gas 2 and hot flue gas from the secondary strong swirling flow pyrolyzer (1-2), is brought into the primary strong swirling flow pyrolysis reactor ( 1-1), and continue to mix and exchange heat with the pyrolysis oil gas 2 from the secondary strong swirling flow pyrolyzer (1-2) in the reactor, and the pyrolysis reaction occurs, and the pyrolysis oil gas 1 generated from a The primary reactor is discharged, and the pyrolysis semi-coke 1 is sent into the secondary pyrolysis device (1-2) under the action of the pyrolysis oil gas 3 from the tertiary reactor (1-3); in the secondary pyrolysis reactor In (1-2), continue to mix and exchange heat with the pyrolysis oil gas 3 from the three-stage reactor (1-3), continue pyrolysis, and the generated pyrolysis oil gas 2 is discharged and enters the pyrolysis reactor (1-1), The generated pyrolysis semi-coke is sent to the third-stage pyrolysis device (1-3) under the action of the pyrolysis oil gas 4 from the fourth-stage reactor (1-4); in the third-stage pyrolysis reactor (1-3 ), continue to mix and exchange heat with the pyrolysis oil gas 4 from the four-stage pyrolyzer (1-4) to carry out pyrolysis, and the generated pyrolysis oil gas 3 is discharged into the pyrolysis reactor (1-2), and the produced The pyrolysis semi-coke is sent to the fourth-stage pyrolyzer (1-4) under the action of the hot flue gas from the combustion of the boiler; Mixing heat exchange for pyrolysis reaction, the generated pyrolysis oil gas 4 is discharged into the pyrolysis reactor (1-3), and the final product semi-coke 4 is discharged from the bottom of the four-stage strong swirling flow pyrolysis reactor, cooled and heat recovery, Collected by the semi-coke collection tank 5; and finally the pyrolysis oil gas 1 discharged from the primary reactor (1-1) is first captured by the tar trapping device 2 into the light components in the pyrolysis oil gas 1 to obtain light Tar; uncaptured heavy components in the pyrolysis oil and gas 2 enter the boiler for combustion to generate hot flue gas and steam products, and the hot flue gas returns to the system as a heat carrier, which is produced by four-stage strong swirling flow pyrolysis reactors (1- 4) Enter the reaction system, mix with the solid material in the pyrolysis reactor, and exchange heat for pyrolysis reaction; through the pyrolysis of Huolinhe lignite pulverized coal, clean powder coke, light tar and steam are finally obtained product.
实施例2:热解系统包括四级强旋流热解反应器(图中n为4)Embodiment 2: pyrolysis system comprises four stages of strong swirling flow pyrolysis reactors (n is 4 in the figure)
本实施例,采用与实施例1相同的实验方法与步骤,采用的固体燃料为神木果园煤,主要差别在于由一级强旋流热解反应器(1-1)排出的热解油气1,全部进入进入锅炉燃烧(如图2所示),以产生热烟气作为热解的热量,最终获得洁净粉焦和蒸汽。In this embodiment, the same experimental method and steps as in Example 1 are adopted, and the solid fuel used is Shenmu orchard coal. The main difference is that the
实施例3:热解系统包括六级强旋流热解反应器(图中n为6)Embodiment 3: pyrolysis system comprises six stages of strong swirling flow pyrolysis reactors (n is 6 in the figure)
本实施例,采用与实施例1相同的实验方法与步骤,采用的固体燃料为鄂尔多斯烟煤,主要差别在于本实施例采用的多级强旋流热解反应器为六级。In this example, the same experimental method and steps as in Example 1 were adopted, and the solid fuel used was Ordos bituminous coal. The main difference is that the multi-stage strong swirling flow pyrolysis reactor used in this example has six stages.
最后所应说明的是,以上实施例仅用以说明本发明的技术方案而非限制。尽管参照实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,对本发明的技术方案进行修改或者等同替换,都不脱离本发明技术方案的精神和范围,其均应涵盖在本发明的权利要求范围当中。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention rather than limit them. Although the present invention has been described in detail with reference to the embodiments, those skilled in the art should understand that modifications or equivalent replacements to the technical solutions of the present invention do not depart from the spirit and scope of the technical solutions of the present invention, and all of them should be included in the scope of the present invention. within the scope of the claims.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710432714.3A CN107163968B (en) | 2017-06-09 | 2017-06-09 | Pyrolysis device and pyrolysis method for producing coke breeze and light tar |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710432714.3A CN107163968B (en) | 2017-06-09 | 2017-06-09 | Pyrolysis device and pyrolysis method for producing coke breeze and light tar |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107163968A CN107163968A (en) | 2017-09-15 |
CN107163968B true CN107163968B (en) | 2023-03-21 |
Family
ID=59824810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710432714.3A Active CN107163968B (en) | 2017-06-09 | 2017-06-09 | Pyrolysis device and pyrolysis method for producing coke breeze and light tar |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107163968B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108046261A (en) * | 2017-12-26 | 2018-05-18 | 神雾环保技术股份有限公司 | A kind of hot method calcium carbide production process raw material preheating system of oxygen and its application process |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105238425A (en) * | 2015-10-15 | 2016-01-13 | 陕西美斯林能源科技研究院 | Gas-solid mixed heat carrier quick pulverized coal pyrolysis process and device |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102465043B (en) * | 2010-11-01 | 2013-07-31 | 中国科学院过程工程研究所 | Multi-section fractional pyrolysis gasification device and method for solid fuel |
CN102839001B (en) * | 2011-06-20 | 2014-04-30 | 中国科学院过程工程研究所 | Pyrolysis apparatus and method for production of light tar |
CN103468322B (en) * | 2013-07-25 | 2015-08-12 | 易高环保能源研究院有限公司 | A method for producing hydrogen-rich gas by steam gasification of solid organic matter |
CN205974379U (en) * | 2016-06-22 | 2017-02-22 | 北京神雾环境能源科技集团股份有限公司 | Fine coal pyrolysis dust pelletizing system that formula grain bed can be selected separately to built -in cyclone and granule |
CN207002633U (en) * | 2017-06-09 | 2018-02-13 | 中国科学院过程工程研究所 | A kind of pyrolysis installation for producing coke breeze and tar light oil |
-
2017
- 2017-06-09 CN CN201710432714.3A patent/CN107163968B/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105238425A (en) * | 2015-10-15 | 2016-01-13 | 陕西美斯林能源科技研究院 | Gas-solid mixed heat carrier quick pulverized coal pyrolysis process and device |
Also Published As
Publication number | Publication date |
---|---|
CN107163968A (en) | 2017-09-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101624531B (en) | Device for preparing bio-oil by utilizing biomass spouted fluidized bed through pyrolysis and fractional condensation | |
CN102942943B (en) | Oil shale gas-solid heat carrier dry distillation and semicoke combustion electricity generation integral process | |
CN103013576A (en) | IGCC (Integrated Gasification Combined Cycle) poly-generation device and method based on pyrolysis and gasification of low metamorphic powdered coal | |
CN105062528B (en) | A kind of pyrolysis of coal multi-production process and its device suitable for coal-powder boiler | |
CN103980912B (en) | A kind of brown coal method for destructive distillation and device | |
CN102329628B (en) | Large-size low-temperature destructive distillation system for low-order lignite | |
CN102433166A (en) | Moving bed pulverized coal pyrolysis and fluidized bed coke breeze gasification coupling device and coupling method | |
CN103710037A (en) | Fluidized-bed low-rank coal upgrading utilization system and method | |
CN109136539A (en) | A kind of fluidized bed two stage gasification and flash light-calcined magnesite integral process | |
CN110117497A (en) | A kind of low temperature distillation pyrolytic process system of double heat source low-order coals | |
CN100545510C (en) | Circulating fluidized bed incineration system using wet oil shale semi-coke as fuel | |
CN102977903B (en) | Low-rank coal downward circulating fluidized bed pyrolysis quality improvement process | |
CN105400532A (en) | Poly-generation system and method with coal pyrolysis as guide | |
CN102977904B (en) | Oil shale synthesized utilization method | |
CN203048897U (en) | IGCC (integrated gasification combined cycle) polygeneration device based on low metamorphic coal pyrolysis and gasification | |
CN107163968B (en) | Pyrolysis device and pyrolysis method for producing coke breeze and light tar | |
CN203639416U (en) | Upgrading utilization system for low rank coal fluidized bed | |
CN207002633U (en) | A kind of pyrolysis installation for producing coke breeze and tar light oil | |
CN106147818A (en) | One utilizes biomass castoff to produce liquid fuel device and using method | |
CN203999501U (en) | A kind of coal destructive distillation device | |
CN104498070B (en) | Smoke mixed type heat carrier retorting process of oil shale | |
CN205188211U (en) | Use many cogeneration system s of pyrolysis of coal as guide | |
CN211284248U (en) | A coupling system of pulverized coal pyrolysis and coke powder combustion power generation | |
CN202953992U (en) | Integrated device of oil shale gas-solid heat carrier retorting and semi-coke combustion electricity generation | |
CN114719267A (en) | Recycling harmless treatment device and method for extracting tar from low-calorific-value fuel |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |