CN107141393A - A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof - Google Patents
A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof Download PDFInfo
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- CN107141393A CN107141393A CN201710349184.6A CN201710349184A CN107141393A CN 107141393 A CN107141393 A CN 107141393A CN 201710349184 A CN201710349184 A CN 201710349184A CN 107141393 A CN107141393 A CN 107141393A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of styrene-acrylic emulsion used for water color ink and preparation method thereof, including styrene 5 25%, acrylic acid 0 3%, methacrylic acid 0 8%, methyl methacrylate 1 25%, butyl acrylate 1 25%, ethyl acrylate 1 25%, NMA 3 5%, water 40 60%, emulsifying agent 1.05 4.5%, PH buffers 0.3%, protecting colloid 2.8% and initiator 0.3 0.7%；PH conditioning agents are used as using ammoniacal liquor；The emulsifying agent is made up of modified fatty alcohol polyethenoxy ether sulfate 1 4% and function emulsifying agent A0.05 0.5%, and the PH buffers are sodium acid carbonate, and the protecting colloid is polyvinyl alcohol, and the initiator is ammonium persulfate, potassium peroxydisulfate or sodium peroxydisulfate；The styrene-acrylic emulsion used for water color ink and preparation technology can solve the problem that the apparent stream adjustment problem of existing water-based system.
Description
Technical field
The present invention relates to emulsion polymerization field, specially a kind of styrene-acrylic emulsion used for water color ink and preparation method thereof.
Background technology
Water-based ink system has higher surface tension, it is difficult to realizes preferably wetting and levelling in substrate surface, needs
To improve levelling by adding surface active agent, but surface active agent has the side effect of stable foam, causes work progress
Middle foam increase is, it is necessary to add substantial amounts of defoamer, and the addition of a large amount of defoamers easilys lead to the generation of shrinkage cavity phenomenon, makes
Product is apparent to be deteriorated, it is impossible to reach the standard of qualified products.In the case where adding substantial amounts of auxiliary agent, even if without foam and contracting
Hole phenomenon, the apparent levelling effect of the apparent levelling effect of system still with solvent based coating differs greatly.
The content of the invention
The technical problems to be solved by the invention are that offer is a kind of and can solve the problem that the apparent levelling of existing water-based system is poor
Styrene-acrylic emulsion used for water color ink of problem and preparation method thereof.
To solve the above problems, the present invention is adopted the following technical scheme that：
A kind of styrene-acrylic emulsion used for water color ink, including styrene 5-25%, acrylic acid 0-3%, methacrylic acid 0-8%,
Methyl methacrylate 1-25%, butyl acrylate 1-25%, ethyl acrylate 1-25%, NMA 3-5%, water
40-60%, emulsifying agent 1.05-4.5%, PH buffer 0.3%, protecting colloid 2.8% and initiator 0.3-0.7%；With ammoniacal liquor
It is used as PH conditioning agents；The emulsifying agent is by modified fatty alcohol polyethenoxy ether sulfate 1-4% and function emulsifying agent A0.05-
0.5% composition, the PH buffers be sodium acid carbonate, the protecting colloid be polyvinyl alcohol, the initiator be ammonium persulfate,
Potassium peroxydisulfate or sodium peroxydisulfate.
Further, the function emulsifying agent A includes the non-ionic fluorocarbon surfactant of ethoxy base class and phosphoric acid salt
One or more and consumption in anionic type fluorocarbon surfactant are in 0.05-0.5%.
Further, the styrene-acrylic emulsion used for water color ink be used for aluminum foil composite paper table apply, print product oil polish or
Aqueous color paste grinds, disperseed.
The invention solves the problems that another technical problem to provide a kind of preparation method of styrene-acrylic emulsion used for water color ink, including
Following steps：
1) pre-emulsification monomer stage：The 60% of emulsifying agent total amount, the 40% of water inventory, all monomers, progress are weighed successively
Pre-emulsification, is made pre-emulsion；
2) primer solution：Weigh remaining emulsifying agent and 58% water be put into reactor, then sequentially add sodium acid carbonate,
Polyvinyl alcohol, and temperature of reaction kettle is set as 60 DEG C, heat while stirring, mixing speed is 100r/min；Weigh 70%
Initiator, is dissolved with 1% water；Weigh 5-10% step 1) in pre-emulsion be added in reactor, then add complete
The good initiator solution of the above-mentioned dissolving in portion；
3) temperature of reaction kettle is brought up to 85 DEG C, remaining initiator is dissolved with 1% water, in the backflow of reactor inwall
During disappearance, start that remaining pre-emulsion and initiator solution is added dropwise, and all added in 3-4 hours simultaneously；
4) after above-mentioned composition is all added, then temperature of reaction kettle brought up to 90 DEG C, and is incubated 60min；
5) under conditions of stirring, natural cooling is cooled to 40 DEG C；
6) the pH value 7-8 of synthetic emulsion is adjusted with ammoniacal liquor；
7) discharging both styrene-acrylic emulsion used for water color ink.
The beneficial effects of the invention are as follows：With with the preferable wetability of pigment, higher gloss and the transparency, without addition
Cosolvent (ethanol or isopropanol) is that preferably apparent levelling effect can be achieved, and production easily realizes that cost is relatively low.
Embodiment
Embodiment 1
A kind of styrene-acrylic emulsion used for water color ink, including styrene 19%, butyl acrylate 12%, acrylic acid 1%, methyl-prop
E pioic acid methyl ester 6%, NMA 3%, ammonium persulfate 0.2%, sodium acid carbonate 0.3%, polyvinyl alcohol 2.8% is fluorine-containing
Carbon surface active agent A0.5%, modified fatty alcohol polyethenoxy ether sulfate 1%, water 54.2%.By the way of emulsion polymerization
The emulsion of production, for the product without recoating, the table of such as aluminum foil composite paper is applied.
A kind of preparation method of styrene-acrylic emulsion used for water color ink, comprises the following steps：
1) pre-emulsification monomer stage：The 60% of emulsifying agent total amount, the 40% of water inventory, all monomers, progress are weighed successively
Pre-emulsification, is made pre-emulsion；
2) primer solution：Weigh remaining emulsifying agent and 58% water be put into reactor, then sequentially add sodium acid carbonate,
Polyvinyl alcohol, and temperature of reaction kettle is set as 60 DEG C, heat while stirring, mixing speed is 100r/min；Weigh 70%
Initiator, is dissolved with 1% water；Weigh 5-10% step 1) in pre-emulsion be added in reactor, then add complete
The good initiator solution of the above-mentioned dissolving in portion；
3) temperature of reaction kettle is brought up to 85 DEG C, remaining initiator is dissolved with 1% water.In the backflow of reactor inwall
During disappearance, start that remaining pre-emulsion and initiator solution is added dropwise, and all added in 3-4 hours simultaneously；
4) after above-mentioned composition is all added, then temperature of reaction kettle brought up to 90 DEG C, and is incubated 60min；
5) under conditions of stirring, natural cooling is cooled to 40 DEG C；
6) the pH value 7-8 of synthetic emulsion is adjusted with ammoniacal liquor；
7) discharging both styrene-acrylic emulsion used for water color ink.
Embodiment 2
A kind of styrene-acrylic emulsion used for water color ink, including styrene 10%, butyl acrylate 11%, methacrylic acid 2.7%,
Methyl methacrylate 11%, NMA 5%, ammonium persulfate 0.2%, sodium acid carbonate 0.3%, polyvinyl alcohol
2.8%, fluorine-containing surfactant A0.05%, modified fatty alcohol polyethenoxy ether sulfate 4%, water 52.95%, using emulsion
The emulsion that the mode of polymerization is produced, for print product oil polish, can again be printed, thermoprint on the basis of this gloss oil
Deng.
A kind of preparation method of styrene-acrylic emulsion used for water color ink, comprises the following steps：
1) pre-emulsification monomer stage：The 60% of emulsifying agent total amount, the 40% of water inventory, all monomers, progress are weighed successively
Pre-emulsification, is made pre-emulsion；
2) primer solution：Weigh remaining emulsifying agent and 58% water be put into reactor, then sequentially add sodium acid carbonate,
Polyvinyl alcohol, and temperature of reaction kettle is set as 60 DEG C, heat while stirring, mixing speed is 100r/min；Weigh 70%
Initiator, is dissolved with 1% water；Weigh 5-10% step 1) in pre-emulsion be added in reactor, then add complete
The good initiator solution of the above-mentioned dissolving in portion；
3) temperature of reaction kettle is brought up to 85 DEG C, remaining initiator is dissolved with 1% water.In the backflow of reactor inwall
During disappearance, start that remaining pre-emulsion and initiator solution is added dropwise, and all added in 3-4 hours simultaneously；
4) after above-mentioned composition is all added, then temperature of reaction kettle brought up to 90 DEG C, and is incubated 60min；
5) under conditions of stirring, natural cooling is cooled to 40 DEG C；
6) the pH value 7-8 of synthetic emulsion is adjusted with ammoniacal liquor；
7) discharging both styrene-acrylic emulsion used for water color ink.
Embodiment 3
A kind of styrene-acrylic emulsion used for water color ink, including styrene 5%, butyl acrylate 7%, methacrylic acid 2.7%, first
Base methyl acrylate 23%, NMA 3%, ammonium persulfate 0.2%, sodium acid carbonate 0.3%, polyvinyl alcohol 2.8%,
Fluorine-containing surfactant A0.2%, modified fatty alcohol polyethenoxy ether sulfate 2%, water 53.8%, using the side of emulsion polymerization
The emulsion of formula production, the grinding or scattered for aqueous color paste.
A kind of preparation method of styrene-acrylic emulsion used for water color ink, comprises the following steps：
1) pre-emulsification monomer stage：The 60% of emulsifying agent total amount, the 40% of water inventory, all monomers, progress are weighed successively
Pre-emulsification, is made pre-emulsion；
2) primer solution：Weigh remaining emulsifying agent and 58% water be put into reactor, then sequentially add sodium acid carbonate,
Polyvinyl alcohol, and temperature of reaction kettle is set as 60 DEG C, heat while stirring, mixing speed is 100r/min；Weigh 70%
Initiator, is dissolved with 1% water；Weigh 5-10% step 1) in pre-emulsion be added in reactor, then add complete
The good initiator solution of the above-mentioned dissolving in portion；
3) temperature of reaction kettle is brought up to 85 DEG C, remaining initiator is dissolved with 1% water.In the backflow of reactor inwall
During disappearance, start that remaining pre-emulsion and initiator solution is added dropwise, and all added in 3-4 hours simultaneously；
4) after above-mentioned composition is all added, then temperature of reaction kettle brought up to 90 DEG C, and is incubated 60min；
5) under conditions of stirring, natural cooling is cooled to 40 DEG C；
6) the pH value 7-8 of synthetic emulsion is adjusted with ammoniacal liquor；
7) discharging both styrene-acrylic emulsion used for water color ink.
The beneficial effects of the invention are as follows：With with the preferable wetability of pigment, higher gloss and the transparency, without addition
Cosolvent (ethanol or isopropanol) is that preferably apparent levelling effect can be achieved, and production easily realizes that cost is relatively low.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, should all cover within the scope of the present invention.
Claims (4)
1. a kind of styrene-acrylic emulsion used for water color ink, it is characterised in that：Including styrene 5-25%, acrylic acid 0-3%, metering system
Sour 0-8%, methyl methacrylate 1-25%, butyl acrylate 1-25%, ethyl acrylate 1-25%, NMA
3-5%, water 40-60%, emulsifying agent 1.05-4.5%, PH buffer 0.3%, protecting colloid 2.8% and initiator 0.3-
0.7%；PH conditioning agents are used as using ammoniacal liquor；The emulsifying agent is by modified fatty alcohol polyethenoxy ether sulfate 1-4% and function breast
Agent A0.05-0.5% is constituted, and the PH buffers are sodium acid carbonate, and the protecting colloid is polyvinyl alcohol, the initiator
For ammonium persulfate, potassium peroxydisulfate or sodium peroxydisulfate.
2. styrene-acrylic emulsion used for water color ink as claimed in claim 1, it is characterised in that：The function emulsifying agent A includes ethoxy
The non-ionic fluorocarbon surfactant of base class and one or more and use in phosphoric acid salt anionic type fluorocarbon surfactant
Amount is in 0.05-0.5%.
3. the application of styrene-acrylic emulsion used for water color ink as claimed in claim 1, it is characterised in that：The phenylpropyl alcohol used for water color ink
Emulsion is used for grinding, disperseing for table painting, print product oil polish or the aqueous color paste of aluminum foil composite paper.
4. a kind of preparation method of styrene-acrylic emulsion used for water color ink as claimed in claim 1, it is characterised in that including following step
Suddenly：
1) pre-emulsification monomer stage：The 60% of emulsifying agent total amount, the 40% of water inventory, all monomers, the pre- breast of progress are weighed successively
Change, pre-emulsion is made；
2) primer solution：Weigh remaining emulsifying agent and 58% water is put into reactor, then sequentially add sodium acid carbonate, poly- second
Enol, and temperature of reaction kettle is set as 60 DEG C, heat while stirring, mixing speed is 100r/min；Weigh 70% initiation
Agent, is dissolved with 1% water；Weigh 5-10% step 1) in pre-emulsion be added in reactor, then add whole on
State the initiator solution dissolved；
3) temperature of reaction kettle is brought up to 85 DEG C, remaining initiator is dissolved with 1% water, flows back and disappears in reactor inwall
When, start that remaining pre-emulsion and initiator solution is added dropwise, and all added in 3-4 hours simultaneously；
4) after above-mentioned composition is all added, then temperature of reaction kettle brought up to 90 DEG C, and is incubated 60min；
5) under conditions of stirring, natural cooling is cooled to 40 DEG C；
6) the pH value 7-8 of synthetic emulsion is adjusted with ammoniacal liquor；
7) discharging both styrene-acrylic emulsion used for water color ink.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710349184.6A CN107141393A (en) | 2017-05-17 | 2017-05-17 | A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710349184.6A CN107141393A (en) | 2017-05-17 | 2017-05-17 | A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107141393A true CN107141393A (en) | 2017-09-08 |
Family
ID=59777526
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710349184.6A Pending CN107141393A (en) | 2017-05-17 | 2017-05-17 | A kind of styrene-acrylic emulsion used for water color ink and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796815A (en) * | 2019-01-12 | 2019-05-24 | 福建师范大学 | A kind of preparation method of graphene modifying cinepazid emulsion |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN110951013A (en) * | 2019-12-05 | 2020-04-03 | 广州至然科技应用有限公司 | Covering emulsion with improved coloring and covering power performance and preparation method thereof |
| CN110982336A (en) * | 2019-12-05 | 2020-04-10 | 浙江特美新材料股份有限公司 | Aluminum foil paper water-based environment-friendly ink composition and preparation method thereof |
| CN114763442A (en) * | 2021-01-11 | 2022-07-19 | 天津科技大学 | Plastic base material-based water-based ink and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796815A (en) * | 2019-01-12 | 2019-05-24 | 福建师范大学 | A kind of preparation method of graphene modifying cinepazid emulsion |
| CN110951004A (en) * | 2019-12-04 | 2020-04-03 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN110951004B (en) * | 2019-12-04 | 2021-12-17 | 中国科学院化学研究所 | Water-based ink emulsion, water-based ink, and preparation method and application thereof |
| CN110951013A (en) * | 2019-12-05 | 2020-04-03 | 广州至然科技应用有限公司 | Covering emulsion with improved coloring and covering power performance and preparation method thereof |
| CN110982336A (en) * | 2019-12-05 | 2020-04-10 | 浙江特美新材料股份有限公司 | Aluminum foil paper water-based environment-friendly ink composition and preparation method thereof |
| CN114763442A (en) * | 2021-01-11 | 2022-07-19 | 天津科技大学 | Plastic base material-based water-based ink and preparation method thereof |
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Application publication date: 20170908 |
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