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CN107099208A - A kind of antifouling and easy cleaning interior wall coating and preparation method thereof - Google Patents

A kind of antifouling and easy cleaning interior wall coating and preparation method thereof Download PDF

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Publication number
CN107099208A
CN107099208A CN201710548943.1A CN201710548943A CN107099208A CN 107099208 A CN107099208 A CN 107099208A CN 201710548943 A CN201710548943 A CN 201710548943A CN 107099208 A CN107099208 A CN 107099208A
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parts
interior wall
antifouling
powder
wall coating
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CN201710548943.1A
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Inventor
吴道祥
吴道民
黄莹
张庆全
冯奋
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Foshan New Mdt Infotech Ltd
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Foshan New Mdt Infotech Ltd
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Priority to CN201710548943.1A priority Critical patent/CN107099208A/en
Publication of CN107099208A publication Critical patent/CN107099208A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of antifouling and easy cleaning interior wall coating, it is made up of the raw material below according to parts by weight:95 100 parts of acrylic emulsion, 35 40 parts of polyethylene glycol oxide, 28 32 parts of epoxy acrylate, 23 27 parts of wollastonite in powder, 30 35 parts of anatase thpe white powder, 20 25 parts of talcum powder, 25 parts of methyl benzoylformate, 36 parts of ethylene group bis-stearamides, 59 parts of dibenzoyl peroxide, 10 15 parts of nano-calcium carbonate, 8 12 parts of zinc naphthenate, 13 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 7 10 parts of succinimide, 36 parts of dimethylethanolamine.The invention also discloses the preparation method of described antifouling and easy cleaning interior wall coating.Interior wall coating prepared by the present invention has good antifouling property, and is readily cleaned, and greatly reduces the difficulty for maintaining indoor cleaning.

Description

A kind of antifouling and easy cleaning interior wall coating and preparation method thereof
Technical field
The present invention relates to wall covering technical field, specifically a kind of antifouling and easy cleaning interior wall coating and its preparation side Method.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or talcum powder.Chinese coating circle is more authoritative 's《Coating process》What one book was defined as:" coating is a kind of material, and this material can be coated with different construction technologies In object surface, formed and adhered to firmly, with some strength, continuous solid film.The film common name film so formed, also known as Paint film or coating." paint finishing can very well bond with matrix material in body surface and form the thing of complete and tough and tensile diaphragm Material, referred to as coating.Coating and paint are identical concepts.Paint is people's custom title used for a long time, is introduced after China, with regard to one It is straight to utilize in building trade.The effect of coating may be summarized to be three aspects:Protective effect, decoration function, specific function effect. The general composition of coating:Include film forming matter, color stuffing, solvent, auxiliary agent.
Wall covering includes interior wall coating and exterior coating two large divisions by building wall classification.Interior wall coating is to be applied to The coating of indoor wall.As modern society's life rhythm is constantly accelerated, people it is busy it is nervous after work, often do not have The cleaning that time enough and energy come in maintenance room, more usually thoroughly can not be cleared up and be fitted up to indoor, but simultaneously The problems such as due to operating pressure, people were but more and more stronger for the demand of clean and tidy comfortable life and rest environment.The opposing party Face, because the air pollution in living environment especially in big city etc. is increasingly severe, indoor wall is also easier to because ash Dirt deposition etc. reason and be contaminated, moreover, in daily life, due to the life activity of people, indoor wall can not also be kept away Grease, coloured dirt etc. are arrived in the meeting contamination exempted from, and these have all had a strong impact on inhabitations impression of the attractive in appearance and people of indoor environment.It is existing Some interior wall coatings, antifouling capacity is poor, and is stained with after spot not easy cleaning, and the life given people is made troubles.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of antifouling and easy cleaning interior wall coating and preparation method thereof The problem of being proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:Acrylic emulsion 95- 100 parts, 35-40 parts of polyethylene glycol oxide, 28-32 parts of epoxy acrylate, 23-27 parts of wollastonite in powder, anatase thpe white powder 30-35 Part, 20-25 parts of talcum powder, 2-5 parts of methyl benzoylformate, 3-6 parts of ethylene group bis-stearamides, dibenzoyl peroxide 5-9 Part, 10-15 parts of nano-calcium carbonate, 8-12 parts of zinc naphthenate, 1-3 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, succinimide 7-10 Part, 3-6 parts of dimethylethanolamine.
It is used as further scheme of the invention:It is made up of the raw material below according to parts by weight:96-99 parts of acrylic emulsion, 36-39 parts of polyethylene glycol oxide, 29-31 parts of epoxy acrylate, 24-26 parts of wollastonite in powder, 31-34 parts of anatase thpe white powder, cunning 21-24 parts of stone flour, 3-4 parts of methyl benzoylformate, 4-5 parts of ethylene group bis-stearamides, 6-8 parts of dibenzoyl peroxide, receive Rice 11-14 parts of calcium carbonate, 9-11 parts of zinc naphthenate, 1.5-2.5 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 8-9 parts of succinimide, 4-5 parts of dimethylethanolamine.
It is used as further scheme of the invention:It is made up of the raw material below according to parts by weight:It is 97 parts of acrylic emulsion, poly- 37 parts of ethylene oxide, 30 parts of epoxy acrylate, 25 parts of wollastonite in powder, 32 parts of anatase thpe white powder, 23 parts of talcum powder, benzoyl 4 parts of methyl formate, 5 parts of ethylene group bis-stearamides, 7 parts of dibenzoyl peroxide, 13 parts of nano-calcium carbonate, zinc naphthenate 10 Part, 2 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 8 parts of succinimide, 5 parts of dimethylethanolamine.
The preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 1-2h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, is carried out at 760-780 DEG C at calcining Reason, obtains the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 50-60min, then stirring mixing 1-2h, discharging, Obtain the 3rd mixture;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing 20- After 30min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 40-50min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2-3h, discharged, you can.
It is used as further scheme of the invention:Step 1) in, the addition of the water is succinimide gross weight 5-8 times.
It is used as further scheme of the invention:Step 4) in, the ultrasonication temperature is 55-60 DEG C.
It is used as further scheme of the invention:Step 4) in, the ultrasonication power is 80-90KHz.
Compared with prior art, the beneficial effects of the invention are as follows:
Interior wall coating prepared by the present invention has good antifouling property, is difficult to attach the spots such as dust, grease, even and if Coating surface has been stained with spot and has also been easily washable, and greatly reduces the difficulty for maintaining indoor cleaning, is conducive to keeping indoor It is clean and tidy comfortable, with wide market prospects.
Embodiment
Technical scheme is described in more detail with reference to embodiment.
Embodiment 1
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:95 parts of acrylic emulsion, 35 parts of polyethylene glycol oxide, 28 parts of epoxy acrylate, 23 parts of wollastonite in powder, 30 parts of anatase thpe white powder, 20 parts of talcum powder, benzene first 2 parts of acyl methyl formate, 3 parts of ethylene group bis-stearamides, 5 parts of dibenzoyl peroxide, 10 parts of nano-calcium carbonate, zinc naphthenate 8 Part, 1 part of polyoxyethylene polyoxy propyl alcohol amidogen ether, 7 parts of succinimide, 3 parts of dimethylethanolamine.
In the present embodiment, the preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With, wherein, the addition of the water is 5 times of succinimide gross weight;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 1h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 760 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 50min, then stirring mixing 1h, discharging, obtain the Three mixtures, wherein, the ultrasonication temperature is 55 DEG C, and the ultrasonication power is 80KHz;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing After 20min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 40min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2h, discharged, you can.
Embodiment 2
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:96 parts of acrylic emulsion, 36 parts of polyethylene glycol oxide, 29 parts of epoxy acrylate, 26 parts of wollastonite in powder, 34 parts of anatase thpe white powder, 24 parts of talcum powder, benzene first 3 parts of acyl methyl formate, 4 parts of ethylene group bis-stearamides, 6 parts of dibenzoyl peroxide, 14 parts of nano-calcium carbonate, zinc naphthenate 11 Part, 2.5 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 8 parts of succinimide, 5 parts of dimethylethanolamine.
In the present embodiment, the preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With, wherein, the addition of the water is 6 times of succinimide gross weight;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 1.5h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 765 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 52min, then stirring mixing 1h, discharging, obtain the Three mixtures, wherein, the ultrasonication temperature is 56 DEG C, and the ultrasonication power is 80KHz;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing After 24min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 42min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2h, discharged, you can.
Embodiment 3
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:97 parts of acrylic emulsion, 37 parts of polyethylene glycol oxide, 30 parts of epoxy acrylate, 25 parts of wollastonite in powder, 32 parts of anatase thpe white powder, 23 parts of talcum powder, benzene first 4 parts of acyl methyl formate, 5 parts of ethylene group bis-stearamides, 7 parts of dibenzoyl peroxide, 13 parts of nano-calcium carbonate, zinc naphthenate 10 Part, 2 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 8 parts of succinimide, 5 parts of dimethylethanolamine.
In the present embodiment, the preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With, wherein, the addition of the water is 7 times of succinimide gross weight;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 1.5h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 770 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 55min, then stirring mixing 1.5h, discharges, and obtains 3rd mixture, wherein, the ultrasonication temperature is 58 DEG C, and the ultrasonication power is 85KHz;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing After 25min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 45min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2.5h, discharged, you can.
Embodiment 4
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:99 parts of acrylic emulsion, 39 parts of polyethylene glycol oxide, 31 parts of epoxy acrylate, 24 parts of wollastonite in powder, 31 parts of anatase thpe white powder, 21 parts of talcum powder, benzene first 4 parts of acyl methyl formate, 5 parts of ethylene group bis-stearamides, 8 parts of dibenzoyl peroxide, 11 parts of nano-calcium carbonate, zinc naphthenate 9 Part, 1.5 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 9 parts of succinimide, 4 parts of dimethylethanolamine.
In the present embodiment, the preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With, wherein, the addition of the water is 7 times of succinimide gross weight;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 2h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 780 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 58min, then stirring mixing 1.5h, discharges, and obtains 3rd mixture, wherein, the ultrasonication temperature is 60 DEG C, and the ultrasonication power is 90KHz;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing After 25min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 47min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2.5h, discharged, you can.
Embodiment 5
A kind of antifouling and easy cleaning interior wall coating, is made up of the raw material below according to parts by weight:Acrylic emulsion 100 Part, 40 parts of polyethylene glycol oxide, 32 parts of epoxy acrylate, 27 parts of wollastonite in powder, 35 parts of anatase thpe white powder, 25 parts of talcum powder, 5 parts of methyl benzoylformate, 6 parts of ethylene group bis-stearamides, 9 parts of dibenzoyl peroxide, 15 parts of nano-calcium carbonate, aphthenic acids 12 parts of zinc, 3 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 10 parts of succinimide, 6 parts of dimethylethanolamine.
In the present embodiment, the preparation method of described antifouling and easy cleaning interior wall coating, step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby With, wherein, the addition of the water is 8 times of succinimide gross weight;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinyl that is obtained The imines aqueous solution is ball milling liquid, and ball milling mixing 2h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 780 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide Added together into the first mixture with the second mixture, ultrasonication 60min, then stirring mixing 2h, discharging, obtain the Three mixtures, wherein, the ultrasonication temperature is 60 DEG C, and the ultrasonication power is 90KHz;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing After 30min, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd are added Mixture, continues to stir mixing 50min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 3h, discharged, you can.
Interior wall coating prepared by the present invention has good antifouling property, is difficult to attach the spots such as dust, grease, even and if Coating surface has been stained with spot and has also been easily washable, and greatly reduces the difficulty for maintaining indoor cleaning, is conducive to keeping indoor It is clean and tidy comfortable, with wide market prospects.
The better embodiment to the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party , can also be on the premise of present inventive concept not be departed from formula, the knowledge that one skilled in the relevant art possesses Various changes can be made.

Claims (7)

1. a kind of antifouling and easy cleaning interior wall coating, it is characterised in that be made up of the raw material below according to parts by weight:Acrylic acid 95-100 parts of emulsion, 35-40 parts of polyethylene glycol oxide, 28-32 parts of epoxy acrylate, 23-27 parts of wollastonite in powder, anatase titanium dioxide 30-35 parts of powder, 20-25 parts of talcum powder, 2-5 parts of methyl benzoylformate, 3-6 parts of ethylene group bis-stearamides, diphenyl peroxide 5-9 parts of formyl, 10-15 parts of nano-calcium carbonate, 8-12 parts of zinc naphthenate, 1-3 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, succinyl are sub- 7-10 parts of amine, 3-6 parts of dimethylethanolamine.
2. according to claim 1 antifouling and easy cleaning interior wall coating, it is characterised in that by below according to parts by weight Raw material is constituted:96-99 parts of acrylic emulsion, 36-39 parts of polyethylene glycol oxide, 29-31 parts of epoxy acrylate, wollastonite in powder 24- 26 parts, 31-34 parts of anatase thpe white powder, 21-24 parts of talcum powder, 3-4 parts of methyl benzoylformate, ethylene group bis-stearamides 4- 5 parts, 6-8 parts of dibenzoyl peroxide, 11-14 parts of nano-calcium carbonate, 9-11 parts of zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether 1.5-2.5 parts, 8-9 parts of succinimide, 4-5 parts of dimethylethanolamine.
3. according to claim 2 antifouling and easy cleaning interior wall coating, it is characterised in that by below according to parts by weight Raw material is constituted:97 parts of acrylic emulsion, 37 parts of polyethylene glycol oxide, 30 parts of epoxy acrylate, 25 parts of wollastonite in powder, anatase titanium dioxide titanium 32 parts of white powder, 23 parts of talcum powder, 4 parts of methyl benzoylformate, 5 parts of ethylene group bis-stearamides, 7 parts of dibenzoyl peroxide, 13 parts of nano-calcium carbonate, 10 parts of zinc naphthenate, 2 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, 8 parts of succinimide, dimethyl ethanol 5 parts of amine.
4. a kind of preparation method of antifouling and easy cleaning interior wall coating as described in claim 1-3 is any, it is characterised in that Step is as follows:
1) succinimide is weighed, appropriate water is added, after being uniformly mixed, the succinimide aqueous solution is obtained, it is standby;
2) weigh anatase thpe white powder and nano-calcium carbonate, put into ball mill, with step 1) succinimide that is obtained The aqueous solution is ball milling liquid, and ball milling mixing 1-2h, discharging obtains the first mixture;
3) wollastonite in powder and talcum powder are weighed, after merging, puts into calcining furnace, calcination processing is carried out at 760-780 DEG C, is obtained Obtain the second mixture;
4) methyl benzoylformate and dibenzoyl peroxide are weighed, by methyl benzoylformate, dibenzoyl peroxide and Two mixtures are added into the first mixture together, ultrasonication 50-60min, and then stirring mixing 1-2h, discharges, and obtains 3rd mixture;
5) acrylic emulsion, polyethylene glycol oxide and epoxy acrylate are weighed, is put into agitator tank, stirring mixing 20-30min Afterwards, ethylene group bis-stearamides, zinc naphthenate, polyoxyethylene polyoxy propyl alcohol amidogen ether, dimethylethanolamine and the 3rd mixing are added Thing, continues to stir mixing 40-50min, discharging obtains the 4th mixture;
6) the 4th mixture is put into sand mill, sanded treatment 2-3h, discharged, you can.
5. the preparation method of according to claim 4 antifouling and easy cleaning interior wall coating, it is characterised in that step 1) In, the addition of the water is 5-8 times of succinimide gross weight.
6. the preparation method of according to claim 4 antifouling and easy cleaning interior wall coating, it is characterised in that step 4) In, the ultrasonication temperature is 55-60 DEG C.
7. the preparation method of according to claim 4 antifouling and easy cleaning interior wall coating, it is characterised in that step 4) In, the ultrasonication power is 80-90KHz.
CN201710548943.1A 2017-07-07 2017-07-07 A kind of antifouling and easy cleaning interior wall coating and preparation method thereof Pending CN107099208A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1485383A (en) * 2001-09-04 2004-03-31 青岛益群新型涂料有限公司 Water-repellent breathable nano coating for outer wall
CN1912031A (en) * 2006-08-18 2007-02-14 浙江中成建工集团有限公司 Super whether resistant high antipollution composite elastic construction paint
CN103073966A (en) * 2013-01-15 2013-05-01 贺佑康 Super anti-stain soft-light wall paint
CN105176283A (en) * 2015-09-14 2015-12-23 黄建丽 Water-based latex inner wall paint and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1485383A (en) * 2001-09-04 2004-03-31 青岛益群新型涂料有限公司 Water-repellent breathable nano coating for outer wall
CN1912031A (en) * 2006-08-18 2007-02-14 浙江中成建工集团有限公司 Super whether resistant high antipollution composite elastic construction paint
CN103073966A (en) * 2013-01-15 2013-05-01 贺佑康 Super anti-stain soft-light wall paint
CN105176283A (en) * 2015-09-14 2015-12-23 黄建丽 Water-based latex inner wall paint and preparation method

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