CN107098677B - Black-bottom red-spot oil-drop temmoku glaze ceramic and preparation process thereof - Google Patents
Black-bottom red-spot oil-drop temmoku glaze ceramic and preparation process thereof Download PDFInfo
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Abstract
The invention belongs to the field of ceramic products, and particularly relates to a red spot oil drop temmoku glaze ceramic with a black matrix and a preparation process thereof. The red spot oil drop temmoku glaze ceramic with the black matrix comprises an iron body blank and a red spot oil drop glaze. According to the black-bottom red-spot oil-drop temmoku glaze ceramic and the manufacturing method thereof, the fired ceramic has a purple black matrix, the red-spot oil-drop glaze material of the fired ceramic reacts to form dark red stripes from inside to outside, crystal particles are remained in a glaze layer, and the flowing sense of the glaze material during molding at high temperature can be obviously seen by using a magnifying glass; when the red spot oil drop glaze ceramic is fired, a reducing atmosphere is used, nitrogen is filled during firing for reaction, the red spot oil drop glaze and elements in the iron matrix blank are extracted for combustion supporting, so that the glaze raw materials can be changed and recombined, and the black-base red spot oil drop temmoku glaze ceramic is exquisite in color, mild in texture and high in appreciation value and artistic value.
Description
Technical Field
The invention belongs to the field of ceramic products, and particularly relates to a red spot oil drop temmoku glaze ceramic with a black matrix and a preparation process thereof.
Background
The Tianmu glaze is one of special black glaze varieties and is characterized in that round-point crystals with different metal luster are formed in a black glaze layer of a bowl, the large diameter is several millimeters, the small diameter is only a needle point, the small points are golden yellow and have silvery white metal luster, namely, the Tianmu glaze is like a twinkling star at night and is like glittering oil beads, so that the Tianmu glaze is named as 'oil drop glaze'.
The variety of oil drops has innumerable uneven and embossed crystal spots with different sizes on a black glaze surface in a kiln, the oil drops are called gold oil drops if the color is gold, the silver oil drops if the color is silver ash, and the oil drops are red Tianmu if the color is rare. The red temmoku firing technique has been lost for a long time, and the invention patent application No. 2005100349032 discloses a method for producing a temmoku ceramic of red obsidian by adding chemical raw materials such as ferric oxide, magnesium oxide, and phosphorus pentoxide as a color former to a base glaze and firing the mixture in an oxidizing flame atmosphere. From the aspect of glaze material proportion, although the chemical color former is cheap and easy to obtain, the effect of the produced Tianmu glaze is far different from that of the original mineral glaze, and the porcelain glaze surface using the chemical glaze has no flowing sense during molding at high temperature; from the aspect of firing process, the red temmoku glaze uses ferric oxide as a main color former, so the red temmoku glaze must be fired in an oxidizing flame atmosphere, otherwise, when the kiln temperature reaches over 1000 ℃, the red color glaze begins to decompose into ferric oxide and dissolve in the glaze, and red spots cannot be reflected, while the traditional temmoku glaze is fired by using a reduction glaze, and the glaze surface has no gorgeous color but has the texture of convergence and comfort. Although this method can produce the red obsidian day-mesh ceramic, the effect thereof is greatly different from the conventional red day-mesh, from both the glaze composition and the firing process, and needs to be further improved.
Therefore, if the limitation in the traditional process can be overcome, the erythema temmoku glaze ceramic which is safe to use and high in firing power is developed, the requirement of consumers can be met, and the development of temmoku glaze ceramic is promoted.
Disclosure of Invention
In order to solve the problems, the invention provides a red spot oil drop temmoku glaze ceramic with a black matrix and a preparation process thereof.
In order to achieve the purpose, the invention provides black-bottom red spot oil drop temmoku glaze ceramic which is characterized by comprising an iron body blank and red spot oil drop glaze, wherein the iron body blank comprises the following raw materials in parts by weight: 40-50 parts of water-logging clay, 20-30 parts of black mud, 10-20 parts of red clay, 10-20 parts of sericite, 1-5 parts of calcite and 1-3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron body blank is 5-8%; the erythema oil drop glaze comprises the following raw materials in parts by weight: 20-30 parts of water-bindered clay, 20-30 parts of quartz, 20-30 parts of feldspar, 5-10 parts of talc, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of hematite and 1-5 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 10-13%.
The optimized iron tire blank comprises the following raw materials in parts by weight: 43 parts of water-clay, 23 parts of black mud, 18 parts of laterite, 11 parts of sericite, 3 parts of calcite and 2 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank is 7%.
The optimized erythema oil drop glaze comprises the following raw materials in parts by weight: 28 parts of water-bindered clay, 24 parts of quartz, 27 parts of feldspar, 6 parts of talc, 7 parts of andalusite, 4 parts of wollastonite, 2 parts of hematite and 2 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 12%.
The optimized iron tire blank comprises the following raw materials in parts by weight: 48 parts of water-clay, 21 parts of black mud, 14 parts of laterite, 12 parts of sericite, 2 parts of calcite and 3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank body is 6%.
The optimized erythema oil drop glaze comprises the following raw materials in parts by weight: 24 parts of Shuiji clay, 29 parts of quartz, 23 parts of feldspar, 8 parts of talc, 6 parts of andalusite, 2 parts of wollastonite, 5 parts of hematite and 3 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil drop glaze is 11%.
The preparation process of the red spot oil drop temmoku glazed ceramic with the black matrix comprises the following specific steps:
step 1, respectively mixing materials according to the raw material formula of an iron matrix blank, and grinding the raw materials in a ball mill by a wet method to prepare iron matrix blank slurry;
step 2, sieving, dehydrating and drying the ground iron tire blank slurry to prepare an iron tire blank;
step 3, preparing materials according to the formula of the raw materials of the erythema oil drop glaze, grinding the raw materials in a ball mill by a wet method, and sieving to prepare the erythema oil drop glaze;
step 4, biscuit firing the iron tire blank in the step 2 to obtain an iron tire biscuit, and applying the erythema oil drop glaze material prepared in the step 3 on the iron tire biscuit;
and 5, putting the ceramic blank glazed in the step 4 into a kiln, heating the kiln to 900 ℃ in an oxidizing atmosphere for 1-2 hours, turning to a reducing atmosphere, heating to 1000 ℃ in 1-2 hours, preserving the heat for 1-2 hours, introducing nitrogen, continuously heating to 1280-1310 ℃ in a reducing atmosphere for 20-30 minutes to reach the firing temperature, removing the nitrogen, preserving the heat for 50-60 minutes, and naturally cooling to obtain the red-spotted Tianmu glazed ceramic with the black bottom and the oil drops.
Further, the iron tire blank slurry in the step 2 is sieved by a 150-mesh sieve.
Further, in the step 3, the erythema oil drop glaze material is sieved by a 180-mesh sieve.
Further, in the step 4, the temperature for biscuit firing the iron tire blank is 600-630 ℃, and the water content of the iron tire blank is 1.5-2%.
Further, the glazing thickness of the erythema oil drop glaze in the step 4 is 2-4mm, and the baume concentration of the erythema oil drop glaze is 55-60 degrees.
According to the description of the invention, the red spot oil drop temmoku glaze ceramic with the black bottom and the manufacturing method thereof, the raw ore raw materials are adopted to prepare the iron body blank and the red spot oil drop glaze, the fired ceramic has a purple black matrix, the red spot oil drop glaze reacts to form dark red stripes from inside to outside, crystal particles are remained in the glaze layer, and the flowing sense of the glaze during high-temperature molding can be obviously seen by using a magnifier; when the red spot oil drop sky-luster glaze ceramic is fired, a reducing atmosphere is used, nitrogen is filled during firing for reaction, the red spot oil drop glaze and elements in the iron matrix blank are extracted for combustion supporting, so that the glaze raw materials are changed and recombined, dark red stripes are reflected at places where iron is enriched, crystals are formed at places where other metal elements are enriched, and the black-bottom red spot oil drop sky-luster glaze ceramic is exquisite in color, warm and moist in texture and has high appreciation value and artistic value.
Detailed Description
The invention is further described below by means of specific embodiments.
The red spot oil drop temmoku glaze ceramic with the black matrix comprises an iron body blank and a red spot oil drop glaze material,
the iron tire blank comprises the following raw materials in parts by weight: 40-50 parts of water-logging clay, 20-30 parts of black mud, 10-20 parts of red clay, 10-20 parts of sericite, 1-5 parts of calcite and 1-3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron body blank is 5-8%;
the erythema oil drop glaze comprises the following raw materials in parts by weight: 20-30 parts of water-bindered clay, 20-30 parts of quartz, 20-30 parts of feldspar, 5-10 parts of talc, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of hematite and 1-5 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 10-13%.
The first embodiment is as follows:
the red spot oil drop temmoku glaze ceramic with the black matrix comprises an iron body blank and a red spot oil drop glaze material,
the iron matrix blank comprises the following raw materials in parts by weight: 43 parts of water-clay, 23 parts of black mud, 18 parts of laterite, 11 parts of sericite, 3 parts of calcite and 2 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank is 7%;
the erythema oil drop glaze comprises the following raw materials in parts by weight: 28 parts of water-bindered clay, 24 parts of quartz, 27 parts of feldspar, 6 parts of talc, 7 parts of andalusite, 4 parts of wollastonite, 2 parts of hematite and 2 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 12%.
The second embodiment is as follows:
the red spot oil drop temmoku glaze ceramic with the black matrix comprises an iron body blank and a red spot oil drop glaze material, and comprises the following raw materials in parts by weight:
the iron tire blank comprises the following raw materials in parts by weight: 48 parts of water-clay, 21 parts of black mud, 14 parts of laterite, 12 parts of sericite, 2 parts of calcite and 3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank body is 6%;
the erythema oil drop glaze comprises the following raw materials in parts by weight: 24 parts of Shuiji clay, 29 parts of quartz, 23 parts of feldspar, 8 parts of talc, 6 parts of andalusite, 2 parts of wollastonite, 5 parts of hematite and 3 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil drop glaze is 11%.
The preparation process of the red spot oil drop temmoku glazed ceramic with the black matrix comprises the following specific steps:
step 1, respectively mixing materials according to the raw material formula of an iron matrix blank, and grinding the raw materials in a ball mill by a wet method to prepare iron matrix blank slurry;
step 2, sieving the ground iron matrix blank slurry with a 150-mesh sieve, dehydrating and drying to prepare an iron matrix blank;
step 3, preparing materials according to the formula of the raw materials of the erythema oil drop glaze, grinding the raw materials in a ball mill by a wet method, and then sieving the ground raw materials by a 180-mesh sieve to prepare the erythema oil drop glaze;
step 4, biscuit firing the iron body blank in the step 2 at the temperature of 630 ℃ through 600-630 ℃ to prepare an iron body biscuit, wherein the water content of the iron body biscuit is 1.5-2%, applying the erythema oil drop glaze prepared in the step 3 on the iron body biscuit, and during glazing, the baume concentration of the erythema oil drop glaze is 55-60 ℃ and the glazing thickness is 2-4 mm;
and 5, putting the ceramic blank glazed in the step 4 into a kiln, heating the kiln to 900 ℃ in an oxidizing atmosphere for 1-2 hours, turning to a reducing atmosphere, heating to 1000 ℃ in 1-2 hours, preserving the heat for 1-2 hours, introducing nitrogen, continuously heating to 1280-1310 ℃ in a reducing atmosphere for 20-30 minutes to reach the firing temperature, removing the nitrogen, preserving the heat for 50-60 minutes, and naturally cooling to obtain the red-spotted Tianmu glazed ceramic with the black bottom and the oil drops.
Example three:
the preparation process of the red spot oil drop temmoku glazed ceramic with the black matrix comprises the following specific steps:
step 1, respectively mixing materials according to the raw material formula of an iron matrix blank, and grinding the raw materials in a ball mill by a wet method to prepare iron matrix blank slurry;
step 2, sieving the ground iron matrix blank slurry with a 150-mesh sieve, dehydrating and drying to prepare an iron matrix blank;
step 3, preparing materials according to the formula of the raw materials of the erythema oil drop glaze, grinding the raw materials in a ball mill by a wet method, and then sieving the ground raw materials by a 180-mesh sieve to prepare the erythema oil drop glaze;
step 4, biscuit firing the iron body blank in the step 2 at 620 ℃ to prepare an iron body biscuit, wherein the water content of the iron body biscuit is 1.5%, applying the erythema oil drop glaze prepared in the step 3 on the iron body biscuit, and during glazing, the baume concentration of the erythema oil drop glaze is 58 ℃ and the glazing thickness is 3 mm;
and 5, putting the ceramic body glazed in the step 4 into a kiln, heating the kiln to 900 ℃ in an oxidation atmosphere for 1.6 hours, turning to a reduction atmosphere, heating to 1000 ℃ in 1.5 hours, preserving the heat for 2 hours, introducing nitrogen, continuously heating to 1300 ℃ in the reduction atmosphere for 27 minutes to reach the firing temperature, removing the nitrogen, preserving the heat for 60 minutes, and naturally cooling to obtain the red spot oil drop temmoku glaze ceramic with the black bottom.
The invention provides a red spot oil drop temmoku glaze ceramic with black bottom and a manufacturing method thereof.A raw ore raw material is adopted to prepare an iron blank body and a red spot oil drop glaze material, the fired ceramic has a purplish black matrix, the red spot oil drop glaze material reacts to form dark red stripes from inside to outside, crystal particles are remained in a glaze layer, and the flowing sense of the glaze material during high-temperature molding can be obviously seen when a magnifier is used for watching; when the red spot oil drop sky-luster glaze ceramic is fired, a reducing atmosphere is used, nitrogen is filled during firing for reaction, the red spot oil drop glaze and elements in the iron matrix blank are extracted for combustion supporting, so that the glaze raw materials are changed and recombined, dark red stripes are reflected at places where iron is enriched, crystals are formed at places where other metal elements are enriched, and the black-bottom red spot oil drop sky-luster glaze ceramic is exquisite in color, warm and moist in texture and has high appreciation value and artistic value.
The above description is only three specific embodiments of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by using the design concept should fall within the scope of infringing the present invention.
Claims (10)
1. The red spot oil drop temmoku glaze ceramic with the black matrix is characterized by comprising an iron body blank and a red spot oil drop glaze material,
the iron tire blank comprises the following raw materials in parts by weight: 40-50 parts of water-logging clay, 20-30 parts of black mud, 10-20 parts of red clay, 10-20 parts of sericite, 1-5 parts of calcite and 1-3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron body blank is 5-8%;
the erythema oil drop glaze comprises the following raw materials in parts by weight: 20-30 parts of water-bindered clay, 20-30 parts of quartz, 20-30 parts of feldspar, 5-10 parts of talc, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of hematite and 1-5 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 10-13%.
2. The red-brown oil-drop temmoku glaze ceramic as claimed in claim 1, wherein the iron body blank comprises the following raw materials in parts by weight: 43 parts of water-clay, 23 parts of black mud, 18 parts of laterite, 11 parts of sericite, 3 parts of calcite and 2 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank is 7%.
3. The red-spotted eye glaze ceramic as claimed in claim 1 or 2, wherein: the erythema oil drop glaze comprises the following raw materials in parts by weight: 28 parts of water-bindered clay, 24 parts of quartz, 27 parts of feldspar, 6 parts of talc, 7 parts of andalusite, 4 parts of wollastonite, 2 parts of hematite and 2 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil-drop glaze is 12%.
4. The erythematous oil-drop temmoku glazed ceramic of claim 3, wherein: the iron tire blank comprises the following raw materials in parts by weight: 48 parts of water-clay, 21 parts of black mud, 14 parts of laterite, 12 parts of sericite, 2 parts of calcite and 3 parts of feldspar, wherein the total amount of iron oxide in the raw materials of the iron blank body is 6%.
5. The red-spotted eye glaze ceramic as claimed in claim 1 or 2, wherein: the erythema oil drop glaze comprises the following raw materials in parts by weight: 24 parts of Shuiji clay, 29 parts of quartz, 23 parts of feldspar, 8 parts of talc, 6 parts of andalusite, 2 parts of wollastonite, 5 parts of hematite and 3 parts of kaolin, wherein the total amount of iron oxide in the raw materials of the erythema oil drop glaze is 11%.
6. The preparation process of the black-bottom erythema oil drop temmoku glazed ceramic is characterized by preparing the black-bottom erythema oil drop temmoku glazed ceramic according to any one of claims 1 to 5, and comprises the following specific steps:
step 1, respectively mixing materials according to the raw material formula of an iron matrix blank, and grinding the raw materials in a ball mill by a wet method to prepare iron matrix blank slurry;
step 2, sieving, dehydrating and drying the ground iron tire blank slurry to prepare an iron tire blank;
step 3, preparing materials according to the formula of the raw materials of the erythema oil drop glaze, grinding the raw materials in a ball mill by a wet method, and sieving to prepare the erythema oil drop glaze;
step 4, biscuit firing the iron tire blank in the step 2 to obtain an iron tire biscuit, and applying the erythema oil drop glaze material prepared in the step 3 on the iron tire biscuit;
and 5, putting the ceramic blank glazed in the step 4 into a kiln, heating the kiln to 900 ℃ in an oxidizing atmosphere for 1-2 hours, turning to a reducing atmosphere, heating to 1000 ℃ in 1-2 hours, preserving the heat for 1-2 hours, introducing nitrogen, continuously heating to 1280-1310 ℃ in a reducing atmosphere for 20-30 minutes to reach the firing temperature, removing the nitrogen, preserving the heat for 50-60 minutes, and naturally cooling to obtain the red-spotted Tianmu glazed ceramic with the black bottom and the oil drops.
7. The process for preparing the erythematous black-matrix oil-drop temmoku glaze ceramic as claimed in claim 6, wherein the process comprises the following steps: and (3) sieving the iron tire blank slurry in the step (2) by a 150-mesh sieve.
8. The process for preparing the erythematous black-matrix oil-drop temmoku glaze ceramic as claimed in claim 7, wherein the process comprises the following steps: and (3) screening the erythema oil drop glaze material with a 180-mesh sieve in the step 3.
9. The process for preparing the erythematous black-matrix oil-drop temmoku glaze ceramic as claimed in claim 6, wherein the process comprises the following steps: and 4, biscuit firing the iron tire blank at the temperature of 600-630 ℃, wherein the water content of the iron tire blank is 1.5-2%.
10. The process for preparing the red-spotted eye glaze ceramic as claimed in claim 6 or 9, wherein the process comprises the following steps: the glazing thickness of the erythema oil drop glaze in the step 4 is 2-4mm, and the baume concentration of the erythema oil drop glaze is 55-60 degrees.
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| CN111499339B (en) * | 2020-03-13 | 2022-06-07 | 南平市曜变陶瓷研究院 | Firing method of color-bottom color-drop golden-edge building cup |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
| CN115849866A (en) * | 2022-11-17 | 2023-03-28 | 福建省德化县华达陶瓷有限公司 | Tianmu ceramic and preparation method thereof |
| CN116395963A (en) * | 2023-03-31 | 2023-07-07 | 厦门万仟堂陶业有限公司 | Green land black spot transmutation glaze and preparation method thereof |
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