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CN107063430A - MEMS based on piezoresistive effect is with the spherical oscillator vector hydrophone of the vibration shape - Google Patents

MEMS based on piezoresistive effect is with the spherical oscillator vector hydrophone of the vibration shape Download PDF

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CN107063430A
CN107063430A CN201710226797.0A CN201710226797A CN107063430A CN 107063430 A CN107063430 A CN 107063430A CN 201710226797 A CN201710226797 A CN 201710226797A CN 107063430 A CN107063430 A CN 107063430A
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spherical
resistance
vector hydrophone
frame
piezo
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CN107063430B (en
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丑修建
穆继亮
徐方良
高翔
胡磊
石树正
耿文平
薛晨阳
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North University of China
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01HMEASUREMENT OF MECHANICAL VIBRATIONS OR ULTRASONIC, SONIC OR INFRASONIC WAVES
    • G01H3/00Measuring characteristics of vibrations by using a detector in a fluid
    • G01H3/10Amplitude; Power
    • G01H3/12Amplitude; Power by electric means
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01HMEASUREMENT OF MECHANICAL VIBRATIONS OR ULTRASONIC, SONIC OR INFRASONIC WAVES
    • G01H11/00Measuring mechanical vibrations or ultrasonic, sonic or infrasonic waves by detecting changes in electric or magnetic properties
    • G01H11/06Measuring mechanical vibrations or ultrasonic, sonic or infrasonic waves by detecting changes in electric or magnetic properties by electric means
    • G01H11/08Measuring mechanical vibrations or ultrasonic, sonic or infrasonic waves by detecting changes in electric or magnetic properties by electric means using piezoelectric devices

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  • General Physics & Mathematics (AREA)
  • Transducers For Ultrasonic Waves (AREA)

Abstract

本发明公开了一种基于压阻效应的MEMS同振型球形振子矢量水听器,包括框型基座,所述框型基座上的四条边分别通过横梁连接环形连接体,所述环形连接体上安装球形拾振单元,所述球形拾振单元的密度为1g/cm3;四根横梁外侧分别设置有压敏电阻R11、压敏电阻R12、压敏电阻R13和压敏电阻R14,所述框型基座上设置有基准电阻R2、基准电阻R3和基准电阻R4;压敏电阻R11、R12、R13、R14串联后与基准电阻R2、R3和R4通过金属引线连接成惠斯通电桥结构。本发明从理论出发,设计并优化了一种微型化、良好低频特性、高灵敏度、宽工作频带、共模输出、差模抑制的同振型球形振子矢量水听器。

The invention discloses a MEMS co-vibration spherical vibrator vector hydrophone based on the piezoresistive effect, which comprises a frame-shaped base, and four sides on the frame-shaped base are respectively connected to an annular connecting body through beams, and the annular connecting A spherical vibration pickup unit is installed on the body, and the density of the spherical vibration pickup unit is 1g/cm 3 ; varistor R 11 , varistor R 12 , varistor R 13 and varistor R 14 , the frame-shaped base is provided with a reference resistor R2, a reference resistor R3 and a reference resistor R4; the piezoresistors R 11 , R 12 , R 13 , and R 14 are connected in series with the reference resistors R2, R3 and R4 through metal The leads are connected in a Wheatstone bridge configuration. Based on theory, the present invention designs and optimizes a co-vibration spherical oscillator vector hydrophone with miniaturization, good low-frequency characteristics, high sensitivity, wide operating frequency band, common-mode output and differential-mode suppression.

Description

基于压阻效应的MEMS同振型球形振子矢量水听器MEMS synchronous spherical vibrator vector hydrophone based on piezoresistive effect

技术领域technical field

本发明涉及MEMS传感器领域中的矢量水听器,具体是一种基于压阻效应的MEMS同振型球形振子矢量水听器。The invention relates to a vector hydrophone in the field of MEMS sensors, in particular to a MEMS co-vibration spherical vibrator vector hydrophone based on the piezoresistive effect.

背景技术Background technique

当前,国内外研制的矢量水听器总体上分为同振式和压差式两大类。对于压差性矢量水听器,由于其“8”字型余弦指向性凹点深度太浅,指向精度不高,从而限制了其水声领域的应用。对于同振式矢量水听器,根据质点振速水听器声波接收理论的不同可将同振型矢量水听器分为同振型柱体振子矢量水听器和同振型球形振子矢量水听器。常规同振型矢量水听器必须使用弹性悬挂元件(如橡胶绳或金属弹簧等)固定在刚性架上,悬挂原件的机械特性直接影响水听器的电声性能。该类矢量水听器都是在拾振单元中心或者是内部均匀布置一个或多个加速度传感器,来测量拾振单元振动的速度及加速度,从而得到声场中质点振速的相关信息。由于常规的设计及加工工艺带来的灵敏度低、质量大、声阻抗与水不匹配、难以在小体积平台上使用等问题。MEMS矢量水声传感器因其具有体积小、灵敏度高,矢量性和一致性好等一系列优点,同时,压阻传感器具有较好的低频甚至零频特性;基于此,本发明提出了一种基于压阻效应的MEMS同振型球形矢量水听器,以满足甚低频探测要求。At present, the vector hydrophones developed at home and abroad are generally divided into two categories: co-vibration type and differential pressure type. For the differential pressure vector hydrophone, because the depth of the "8" cosine directivity pit is too shallow, the pointing accuracy is not high, which limits its application in the field of underwater acoustics. For the co-vibration vector hydrophone, according to the different sound wave receiving theories of the particle velocity hydrophone, the co-vibration vector hydrophone can be divided into the co-vibration cylindrical oscillator vector hydrophone and the co-vibration spherical oscillator vector hydrophone device. Conventional co-vibration vector hydrophones must be fixed on a rigid frame with elastic suspension elements (such as rubber ropes or metal springs, etc.), and the mechanical characteristics of the suspension elements directly affect the electroacoustic performance of the hydrophone. This type of vector hydrophone is uniformly arranged with one or more acceleration sensors in the center or inside of the vibration pickup unit to measure the vibration velocity and acceleration of the vibration pickup unit, so as to obtain relevant information about the particle velocity in the sound field. Due to the problems of low sensitivity, large mass, mismatch between acoustic impedance and water, and difficulty in using on small-volume platforms due to conventional design and processing technology. The MEMS vector underwater acoustic sensor has a series of advantages such as small size, high sensitivity, good vector performance and consistency. At the same time, the piezoresistive sensor has better low-frequency or even zero-frequency characteristics; based on this, the present invention proposes a method based on MEMS co-vibration spherical vector hydrophone with piezoresistive effect to meet the requirements of very low frequency detection.

发明内容Contents of the invention

本发明为解决现有采用常规设计及加工工艺等技术方案带来的球形振子矢量水声传感器抗流噪声性能差、灵敏度低、抗冲击性能差、质量大、声阻抗与水不匹配以及低频特性差等问题,提供了一种基于压阻效应的MEMS同振型球形振子矢量水听器。The present invention solves the problem of poor anti-flow noise performance, low sensitivity, poor anti-shock performance, high quality, mismatch between acoustic impedance and water, and low-frequency characteristics of the spherical vibrator vector underwater acoustic sensor brought about by existing technical solutions such as conventional design and processing technology. In order to solve the poor problem, a MEMS co-vibration spherical vibrator vector hydrophone based on the piezoresistive effect is provided.

本发明是采用如下的技术方案实现的:The present invention is realized by adopting the following technical solutions:

一种基于压阻效应的MEMS同振型球形振子矢量水听器,包括框型基座,所述框型基座上的四条边分别通过横梁连接环形连接体,所述环形连接体上安装球形拾振单元,所述球形拾振单元密度为1g/cm3;四根横梁外侧分别设置有压敏电阻R11、压敏电阻R12、压敏电阻R13和压敏电阻R14,所述框型基座上设置有基准电阻R2、基准电阻R3和基准电阻R4;压敏电阻R11、R12、R13、R14串联后与基准电阻R2、R3和R4通过金属引线连接成惠斯通电桥结构。A MEMS co-vibration spherical vibrator vector hydrophone based on the piezoresistive effect, comprising a frame-shaped base, the four sides of the frame-shaped base are respectively connected to an annular connecting body through beams, and a spherical connecting body is installed on the annular connecting body. A vibration pickup unit, the density of the spherical vibration pickup unit is 1g/cm 3 ; piezoresistors R 11 , piezoresistors R 12 , piezoresistors R 13 and piezoresistors R 14 are arranged on the outside of the four beams respectively. The frame-shaped base is provided with reference resistor R2, reference resistor R3 and reference resistor R4; varistors R 11 , R 12 , R 13 , R 14 are connected in series with reference resistors R2, R3 and R4 through metal leads to form a Wheat bridge structure.

本发明采用微纳加工技术,实现了球形振子矢量水听器的微型化。并将信号采集压敏电阻布置于连接球形振子的四根横梁上,可检测垂直于横梁方向上的声信号分量。当该水听器受到来自于Z方向上的声信号作用时,每根横梁上应力分布以及变化完全相同,通过串联的方式将压敏电阻R11、R12、R13、R14连接,等效为一个压敏电阻R1。应变电阻R1与基准电阻R2、R3、R4阻值相等,且压敏电阻与基准电阻组成惠斯通电桥;基准电阻R2、R3、R4分别作为惠斯通电桥的单边基准桥臂,压敏电阻R1作为惠斯通电桥单边应变桥臂。The invention adopts the micro-nano processing technology to realize the miniaturization of the spherical vibrator vector hydrophone. And the signal acquisition piezoresistors are arranged on the four beams connected with the spherical vibrator, so that the acoustic signal component in the direction perpendicular to the beams can be detected. When the hydrophone is affected by the acoustic signal from the Z direction, the stress distribution and change on each beam are exactly the same, and the piezoresistors R 11 , R 12 , R 13 , and R 14 are connected in series, etc. Effective as a varistor R1. The strain resistance R1 is equal to the resistance of the reference resistors R2, R3, and R4, and the varistor and the reference resistor form a Wheatstone bridge; the reference resistors R2, R3, and R4 are respectively used as the unilateral reference bridge arm of the Wheatstone bridge. Resistor R1 acts as a unilateral strain bridge arm of a Wheatstone bridge.

本发明于XOY平面内的对称分布,在受到来自水平方向上的声信号作用时,同一方向上的两根横梁分别受到大小相等的拉应力和压应力(图4),该方向横梁上压敏电阻其中一个增大,另一个减小,且阻值变化相等;因而该矢量水听器等效压敏电阻R1阻值不变,电桥处于平衡状态。从而本结构可有效提高来自Z方向上的声信号分量输出,抑制来自X或Y方向上的声信号分量输出。The symmetrical distribution of the present invention in the XOY plane, when being subjected to the acoustic signal action from the horizontal direction, two crossbeams on the same direction are respectively subjected to tensile stress and compressive stress (Fig. 4) equal in size, and the pressure sensitive One of the resistors increases, the other decreases, and the resistance changes are equal; therefore, the resistance of the vector hydrophone equivalent piezoresistor R1 remains unchanged, and the bridge is in a balanced state. Therefore, this structure can effectively improve the output of the acoustic signal component from the Z direction, and suppress the output of the acoustic signal component from the X or Y direction.

根据质点振速水听器声波接收理论,当ka<<1时(k为声波的波数,a为拾振单元直径)时,拾振单元附近声场不发生明显畸变。当该矢量水听器的上限工作频率2000Hz时,由于a=1500μm,所以探测目标声波波数k<8.4(k=2πf/v,其中v为水中声速,取1500m/s)。本发明所设计的矢量水听器满足ka<<1(ka<0.0125)的条件,球形振子附近声场不会发生畸变;通过理论分析可知,该结构是合理的。According to the sound wave receiving theory of the particle velocity hydrophone, when ka << 1 (k is the wave number of the sound wave, a is the diameter of the vibration pickup unit), the sound field near the vibration pickup unit will not be significantly distorted. When the upper limit operating frequency of the vector hydrophone is 2000Hz, since a=1500μm, the detection target sound wave number k<8.4 (k=2πf/v, where v is the speed of sound in water, which is 1500m/s). The vector hydrophone designed by the present invention satisfies the condition of ka<<1 (ka<0.0125), and the sound field near the spherical vibrator will not be distorted; it can be known through theoretical analysis that the structure is reasonable.

利用COMSOL对该矢量水听器进行模态分析(图5),得到该矢量水听器固有频率为3.3KHz。根据压敏电阻计算公式ΔR=πrσrtσt来计算该水听器应变电阻,其中πr、πt为纵向和横向压阻系数,σr、σt为纵向和横向应力,该P型硅压阻条纵向压阻系数πr=71.8-11,该水听器压阻区纵向应力为线性分布,可采用纵向平均应力来替代σr,在Z方向施加1g的加速度载荷,可得到压阻区纵向平均应力计算得ΔR=1.4×10-4Ω;根据惠斯通电桥输出电压计算该水听器的输出灵敏度,R0采用离子注入的方式加工的等效压敏电阻R1、基准电阻R2、R3、R4的阻值,为200Ω,U0为惠斯通电桥供电电压,取U0=5V,该水听器输出灵敏度为3.5μV/g。在水平方向上(X或Y方向)施加1g的加速度,得到梁上压阻区纵向平均应力且一个为拉应力一个为压应力;等效压敏电阻R1阻值不变,从而电桥输出为0。仿真结果也说明本发明在竖直方向上四个共模信号相互叠加,水平方向上的差模信号相互抑制,充分体现了本水听器具有共模输出,差模抑制的工作性质,能很好的提高竖直方向上的灵敏度,抑制水平方向上的信号分量;从而本发明能很好的改善矢量水听器的分辨率及灵敏度。The modal analysis of the vector hydrophone is carried out by COMSOL (Fig. 5), and the natural frequency of the vector hydrophone is 3.3KHz. Calculate the strain resistance of the hydrophone according to the varistor calculation formula ΔR=π r σ rt σ t , where π r and π t are longitudinal and transverse piezoresistive coefficients, and σ r and σ t are longitudinal and transverse stresses , the longitudinal piezoresistive coefficient of the P-type silicon piezoresistive strip π r =71.8 -11 , the longitudinal stress in the piezoresistive region of the hydrophone is linearly distributed, and the longitudinal average stress can be used to replace σ r , apply an acceleration load of 1g in the Z direction, and the longitudinal average stress in the piezoresistive region can be obtained Calculated ΔR=1.4×10 -4 Ω; according to the output voltage of Wheatstone bridge Calculate the output sensitivity of the hydrophone, R 0 is the resistance value of the equivalent piezoresistor R1, reference resistors R2, R3, and R4 processed by ion implantation, which is 200Ω, and U 0 is the supply voltage of the Wheatstone bridge, which is taken as U 0 =5V, the output sensitivity of the hydrophone is 3.5μV/g. Apply an acceleration of 1g in the horizontal direction (X or Y direction) to obtain the longitudinal average stress of the piezoresistive area on the beam And one is tensile stress and the other is compressive stress; the resistance value of equivalent piezoresistor R1 remains unchanged, so the bridge output is 0. The simulation result also shows that the present invention superimposes four common-mode signals in the vertical direction, and the differential-mode signals in the horizontal direction are mutually suppressed, which fully demonstrates that the hydrophone has common-mode output and differential-mode suppression working properties, and can be easily The sensitivity in the vertical direction can be improved, and the signal component in the horizontal direction can be suppressed; thus, the invention can well improve the resolution and sensitivity of the vector hydrophone.

本发明从理论出发,设计并优化了一种微型化、良好低频特性、高灵敏度、宽工作频带、共模输出、差模抑制的同振型球形振子矢量水听器。Based on theory, the present invention designs and optimizes a co-vibration spherical oscillator vector hydrophone with miniaturization, good low-frequency characteristics, high sensitivity, wide operating frequency band, common-mode output and differential-mode suppression.

附图说明Description of drawings

图1表示基于压阻效应的MEMS同振型球形振子矢量水听器的结构示意图。Fig. 1 shows the structure diagram of MEMS co-vibration spherical vibrator vector hydrophone based on piezoresistive effect.

图2表示球形振子矢量水听器上的基准电阻和压敏电阻的分布以及连接示意图。Fig. 2 shows the distribution and connection schematic diagram of the reference resistance and piezoresistor on the spherical vibrator vector hydrophone.

图3表示该矢量水听器惠斯通电桥连接示意图。Figure 3 shows the schematic diagram of the Wheatstone bridge connection of the vector hydrophone.

图4表示该矢量水听器的一阶模态图。Figure 4 shows the first-order mode diagram of the vector hydrophone.

图5表示该矢量水听器在Z方向施加1g加速度得到结构的应力云图。Fig. 5 shows the stress nephogram of the structure obtained by applying 1g acceleration to the vector hydrophone in the Z direction.

图6表示该矢量水听器在X方向施加1g加速度得到X方向两根横梁上的应力分布曲线。Figure 6 shows the stress distribution curves on the two beams in the X direction obtained by applying a 1g acceleration to the vector hydrophone in the X direction.

图中:1-框型基座、2-横梁、3-环形连接体、4-球形拾振单元、5-金属引线、6-焊盘。In the figure: 1-frame base, 2-beam, 3-ring connector, 4-spherical vibration pickup unit, 5-metal lead, 6-welding pad.

具体实施方式detailed description

下面结合附图对本发明的具体实施例进行详细说明。Specific embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings.

一种基于压阻效应的MEMS同振型球形振子矢量水听器,包括框型基座、横梁、环形连接体、球形聚乙烯拾振单元、压敏电阻、基准电阻;具体连接关系如图1、2所示,所述框型基座1上的四条边分别通过横梁2连接环形连接体3,所述环形连接体3上安装球形拾振单元4,具体可以采用聚乙烯材料制备,球形聚乙烯拾振单元4的密度为1g/cm3;四根横梁2外侧分别设置有压敏电阻R11、压敏电阻R12、压敏电阻R13和压敏电阻R14,所述框型基座1上设置有基准电阻R2、基准电阻R3和基准电阻R4;压敏电阻R11、R12、R13、R14串联后与基准电阻R2、R3和R4通过金属引线5连接成惠斯通电桥结构,如图3所示。A MEMS co-oscillating spherical vibrator vector hydrophone based on the piezoresistive effect, including a frame-shaped base, a beam, a ring connector, a spherical polyethylene vibration pickup unit, a piezoresistor, and a reference resistor; the specific connection relationship is shown in Figure 1 , 2, the four sides on the frame-shaped base 1 are respectively connected to the annular connecting body 3 through the beam 2, and the spherical vibration pickup unit 4 is installed on the annular connecting body 3, which can be made of polyethylene material specifically. The density of vinyl pickup unit 4 is 1g/cm 3 ; piezoresistor R 11 , piezoresistor R 12 , piezoresistor R 13 and piezoresistor R 14 are set on the outside of four beams 2 respectively. The base 1 is provided with a reference resistor R2, a reference resistor R3 and a reference resistor R4; the piezoresistors R 11 , R 12 , R 13 , and R 14 are connected in series with the reference resistors R2, R3, and R4 through metal leads 5 to form Wheatstone conduction Bridge structure, as shown in Figure 3.

具体制备时,采用密度与水相同或接近的球形聚乙烯等拾振单元固定于环形连接体上;在框型基座上以及每根横梁的外侧采用离子注入技术注入硼离子形成压敏电阻;框型基座上基准电阻阻值为横梁上压敏电阻阻值的4倍;横梁上的压敏电阻以及框型基座上的基准电阻通过金属引线连接成惠斯通电桥结构,如图3所示;基准电阻之间及基准电阻和压敏电阻之间采用金属引线(焊盘连接)。During the specific preparation, the vibration pickup unit such as spherical polyethylene with the same or close density as water is fixed on the ring connector; boron ions are implanted on the frame-shaped base and the outside of each beam using ion implantation technology to form a piezoresistor; The resistance value of the reference resistor on the frame base is 4 times that of the piezoresistor on the beam; the piezoresistor on the beam and the reference resistor on the frame base are connected by metal leads to form a Wheatstone bridge structure, as shown in Figure 3 Shown; Metal leads (pad connection) are used between the reference resistors and between the reference resistors and the varistor.

框型基座、横梁和环形连接体采用SOI材料经现有的MEMS工艺加工而成;在横梁外侧制作压敏电阻,采用离子注入的方式制成沿<110>晶向布置的P型硅电阻条;在框型基座上制作基准电阻,采用离子注入的方式制成沿<110>晶向布置的P型硅电阻条。使用剥离的方式加工金属引线5和焊盘8;接下来使用ICP刻蚀出正面横梁和环形连接体以及使用DRIE刻蚀背腔;最后采用二次集成的方法将球形聚乙烯拾振单元粘接到环形连接体上。The frame-shaped base, the beam and the annular connector are made of SOI material through the existing MEMS process; the piezoresistor is fabricated on the outside of the beam, and the P-type silicon resistor arranged along the <110> crystal direction is made by ion implantation. Bar; make a reference resistor on a frame-shaped base, and use ion implantation to make a P-type silicon resistor bar arranged along the <110> crystal direction. Metal leads 5 and pads 8 are processed by stripping; next, ICP is used to etch the front beam and ring connector, and DRIE is used to etch the back cavity; finally, the spherical polyethylene pickup unit is bonded by the secondary integration method to the ring connector.

所述框型基座外边长5000μm、内边长3500μm;所述横梁长900μm、宽120μm、厚30μm;所述环形连接体外径1700μm、内径1500μm、厚度30μm;所述球形聚乙烯拾振单元直径1500μm。压敏电阻长100μm、宽20μm;基准电阻长400μm、宽20μm;金属引线宽度15μm;焊盘长200μm、宽200μm。The outer side length of the frame-shaped base is 5000 μm, and the inner side length is 3500 μm; the beam is 900 μm long, 120 μm wide, and 30 μm thick; the outer diameter of the annular connector is 1700 μm, the inner diameter is 1500 μm, and the thickness is 30 μm; the diameter of the spherical polyethylene vibration pickup unit is 1500μm. The varistor is 100 μm long and 20 μm wide; the reference resistor is 400 μm long and 20 μm wide; the metal lead is 15 μm wide; the pad is 200 μm long and 200 μm wide.

以上仅为本发明的具体实施例,但并不局限于此。任何以本发明为基础解决基本相同的技术问题,或实现基本相同的技术效果,所作出地简单变化、等同替换或者修饰等,均属于本发明的保护范围内。The above are only specific embodiments of the present invention, but are not limited thereto. Any simple changes, equivalent replacements or modifications based on the present invention to solve basically the same technical problems, or achieve basically the same technical effects, all fall within the protection scope of the present invention.

Claims (5)

1. a kind of MEMS based on piezoresistive effect is with the spherical oscillator vector hydrophone of the vibration shape, it is characterised in that:Including frame-type pedestal (1), the frame-type pedestal(1)On four edges pass through crossbeam respectively(2)Connect circular connector(3), the circular connector (3)It is upper that spherical pick-up unit is installed(4), the spherical pick-up unit(4)Density be 1g/cm3;Four crossbeams(2)Outside point Piezo-resistance R is not provided with11, piezo-resistance R12, piezo-resistance R13With piezo-resistance R14, the frame-type pedestal(1)On be provided with Reference resistance R2, reference resistance R3 and reference resistance R4;Piezo-resistance R11、R12、R13 、R14With reference resistance R2, R3 after series connection Pass through metal lead wire with R4(5)Connect into wheatstone bridge configuration.
2. the MEMS according to claim 1 based on piezoresistive effect exists with the spherical oscillator vector hydrophone of the vibration shape, its feature In:Frame-type pedestal(1)Upper reference resistance resistance is crossbeam(2)4 times of upper piezo-resistance resistance.
3. the MEMS according to claim 1 or 2 based on piezoresistive effect is with the spherical oscillator vector hydrophone of the vibration shape, its feature It is:Piezo-resistance is that edge is made by the way of ion implanting<110>The P-type silicon resistor stripe of crystal orientation arrangement, it is long 100 μm, wide 20μm;Reference resistance is that edge is made by the way of ion implanting<110>The P-type silicon resistor stripe of crystal orientation arrangement, it is long 400 μm, wide 20μm。
4. the MEMS according to claim 3 based on piezoresistive effect exists with the spherical oscillator vector hydrophone of the vibration shape, its feature In:The frame-type pedestal(1)Outer 5000 μm of the length of side, 3500 μm of the interior length of side;The crossbeam(2)Long 900 μm, wide 120 μm, thick 30 μ m;The circular connector(3)1700 μm of external diameter, 1500 μm of internal diameter, 30 μm of thickness;The spherical polyethylene pick-up unit(4)Directly 1500 μm of footpath.
5. the MEMS according to claim 1 based on piezoresistive effect exists with the spherical oscillator vector hydrophone of the vibration shape, its feature In:The spherical pick-up unit(4)Prepared using polythene material.
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