CN107006505A - A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin - Google Patents
A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin Download PDFInfo
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- CN107006505A CN107006505A CN201710255722.5A CN201710255722A CN107006505A CN 107006505 A CN107006505 A CN 107006505A CN 201710255722 A CN201710255722 A CN 201710255722A CN 107006505 A CN107006505 A CN 107006505A
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- Prior art keywords
- hydroxyquinolinate
- copper
- pyraclostrobin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of copper 8-hydroxyquinolinate and the composition pesticide of pyraclostrobin, a kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin includes acceptable excipient on active ingredient and agricultural chemicals, and active ingredient includes copper 8-hydroxyquinolinate and pyraclostrobin；In active ingredient, the mass ratio of copper 8-hydroxyquinolinate and pyraclostrobin is 0.5~10：1, the effect with preventing and treating crop fungal disease.
Description
Technical field
The present invention relates to agricultural bactericidal field, the composition pesticide of more particularly to a kind of copper 8-hydroxyquinolinate and pyraclostrobin.
Background technology
Agricultural chemicals is with a long history in use agriculturally, and it can ensure, promote the growth of plant and crops, can kill
Also played an important role during worm sterilization weeding, the fresh-keeping sale of accumulating and processing after agricultural product harvest etc..The research and development of agricultural chemicals
One of emphasis that always agricultural is researched and developed, the Chinese patent such as Publication No. CN1478393A, CN101779643A, CN1926983A
Disclose different agricultural chemicals.But in real process, the research and development of novel agrochemical are still with more important meaning.
The content of the invention
It is an object of the invention to provide a kind of copper 8-hydroxyquinolinate and the composition pesticide of pyraclostrobin, with preventing and treating crop fungi
The effect of venereal disease evil.
The present invention above-mentioned technical purpose technical scheme is that：A kind of copper 8-hydroxyquinolinate and pyrazoles ether bacterium
Acceptable excipient on the composition pesticide of ester, including active ingredient and agricultural chemicals, active ingredient includes copper 8-hydroxyquinolinate and pyrazoles ether
Bacterium ester；In active ingredient, the mass ratio of copper 8-hydroxyquinolinate and pyraclostrobin is 0.5~10：1.
More preferably：In active ingredient, the mass ratio of copper 8-hydroxyquinolinate and pyraclostrobin is 1.5：1；The agricultural chemicals group
Compound includes acceptable excipient on 20~80wt% active ingredient and 20~80wt% agricultural chemicals.
More preferably：The composition pesticide is acceptable excipient bag on water dispersible granules, the agricultural chemicals of use
Include the first wetting agent, the first dispersant and the first filler；First wetting agent is selected from anionic or non-ionic surface is lived
One or more in property agent, the one kind of the first dispersant in naphthalene sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether
Or a variety of, one or more of first filler in soluble starch, ammonium sulfate or kaolin or diatomite.
More preferably：In water dispersible granules, active ingredient, the first wetting agent, the first dispersant account for the agriculture respectively
40~60wt%, 1~5wt% and the 1~10wt% of drug composition total amount.
More preferably：In water dispersible granules, first filler includes soluble starch, and soluble starch accounts for described
10~20wt% of composition pesticide total amount；First wetting agent is lauryl sodium sulfate, and first dispersant is poly-
Carboxylate.
More preferably：The composition pesticide is acceptable excipient bag on wettable powder, the agricultural chemicals of use
The second wetting agent, the second dispersant, white carbon and the second filler are included, second wetting agent is selected from anionic or non-ionic
One or more in surfactant, the second dispersant is in naphthalene sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether
One or more, one or more of second filler choosing selected from kaolin or precipitated calcium carbonate.
More preferably：In wettable powder, active ingredient, the second wetting agent, the second dispersant, the difference of white carbon
Account for 40~60wt%, 1~3wt%, 1~5wt% and the 3~8wt% of the composition pesticide total amount；First wetting agent is
Lauryl sodium sulfate, first dispersant is naphthalenesulfonate formaldehyde condensation compound.
More preferably：The composition pesticide is suspending agent, and acceptable excipient includes the on the agricultural chemicals of use
Three wetting agents, the 3rd dispersant and propane diols；3rd wetting agent is in anionic or nonionic surface active agent
One or more, the one kind or many of the 3rd dispersant in naphthalene sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether
Kind.
More preferably：In suspending agent, active ingredient, the 3rd wetting agent, the 3rd dispersant, propane diols account for described respectively
40~60wt%, 2~5wt%, 1~6wt% and the 3~8wt% of composition pesticide total amount；3rd wetting agent is
TERSPERSE 4894, the 3rd dispersant is naphthalenesulfonate formaldehyde condensation compound.
More preferably：The composition pesticide also includes xanthans, mould inhibitor and defoamer；Xanthans, mould inhibitor
Account for 0.05~0.4wt%, 0.1~0.5wt%, the 0.1~0.5wt% of the composition pesticide total amount respectively with defoamer.
In summary, the invention has the advantages that：1st, with broad-spectrum：Copper 8-hydroxyquinolinate by 8-hydroxyquinoline with
Copper sulphate reaction generation, organic quinolines have double sterilization effect with mantoquita, can suppress the G- protein of getting up early cell expression
Synthesis, suppress the metabolism of germ spore, control cell divides and broken up again, has Multi-contact activity concurrently again, utilizes chela
The pathogen spore absorption that copper is sprouted is closed, spore cell is directly killed inside pathogen, so as to reach the work prevented and cured diseases
With；Pyraclostrobin, inhibitory action is played to mitochondrial respiratory, with protection, treatment, blade infiltration conduction；Research hair
Existing copper 8-hydroxyquinolinate and pyraclostrobin are with mass ratio 0.5~10：1 compounding has preferable bactericidal action, to crop by fungi, bacterium
Caused multiple diseases have it is significant kill and inhibitory action, wherein when copper 8-hydroxyquinolinate and pyraclostrobin are with mass ratio 1.5：1
Best results when being compounded, preventive effect is good；When the 2nd, being sterilized using the composition pesticide of the application, low dosage can be played efficiently
Bactericidal action；3rd, the application composition pesticide has preferable stability, its in sealed vial/shady and cool indoor, sealing
Vial in/it is shady and cool indoor long-term place after remain to keep preferable preventive effect；4th, low toxicity, to cucumber, banana safety, has no medicine
Evil occurs.
Embodiment
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
Member can make the modification without creative contribution to the present embodiment as needed after this specification is read, but as long as at this
All protected in the protection domain of invention by Patent Law.
Embodiment 1a-1f：A kind of active ingredient of the composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin：Quinoline is weighed by table 1
Quinoline copper and pyraclostrobin, mixing, are produced.
The embodiment 1a-1f of table 1 formula
Embodiment 2：The composition pesticide (water dispersible granules) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, it makes as follows
It is standby：Weigh active ingredient from embodiment 1c by the formula of table 2, acceptable excipient on agricultural chemicals, be mixed, then
Mixture is handled through air-flow crushing；Then add water, through mediating, granulating, dry and screening process, produce.
The formula (kg) of the embodiment 2 of table 2
| Component | Formula ratio |
| Active ingredient | 50 |
| Lauryl sodium sulfate | 3 |
| Polycarboxylate | 5 |
| Soluble starch | 15 |
| Kaolin | 27 |
Embodiment 3-7：The composition pesticide (water dispersible granules) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2
Difference is that embodiment 3-7 formula is as shown in table 3.
The embodiment 3-7 of table 3 formula (kg)
Embodiment 8：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, lauryl sodium sulfate is substituted with ethoxylated dodecyl alcohol (nonionic surface active agent).
Embodiment 9：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, lauryl sodium sulfate is substituted with PAMA (anionic surfactant).
Embodiment 10：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, polycarboxylate is substituted with naphthalene sulfonate.
Embodiment 11：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, polycarboxylate is substituted with lignin.
Embodiment 12：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, polycarboxylate is substituted with aliphatic alcohol polyether.
Embodiment 13：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, kaolin is substituted with diatomite.
Embodiment 14：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, kaolin is substituted with ammonium sulfate.
Embodiment 15-26：The composition pesticide (water dispersible granules) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2
Difference be that embodiment 3-7 formula is as shown in table 4.
The embodiment 15-26 of table 4 formula (kg)
Embodiment 27：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from embodiment 1a.
Embodiment 28：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from embodiment 1b.
Embodiment 29：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from embodiment 1d.
Embodiment 30：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from embodiment 1e.
Embodiment 31：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from embodiment 1f.
Embodiment 32：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, its preparation method is：The acceptable excipient on embodiment 1c active ingredient, agricultural chemicals is weighed, will
It is mixed, and then crushes mixture, then water spray, granulation, drying process in boiling granulator, then screening process, i.e.,
.
Embodiment 33：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, it is as follows
Prepare：Weigh active ingredient from embodiment 1c by the formula of table 5, acceptable excipient on agricultural chemicals, mixing produces.
The formula (kg) of the embodiment 33 of table 5
| Component | Formula ratio |
| Active ingredient | 50 |
| Lauryl sodium sulfate | 2 |
| Naphthalenesulfonate formaldehyde condensation compound | 3 |
| White carbon | 5 |
| Kaolin | 40 |
Embodiment 34-49：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference be that embodiment 34-49 formula is as shown in table 6.
The embodiment 34-49 of table 6 formula (kg)
Embodiment 50：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that lauryl sodium sulfate is substituted with ethoxylated dodecyl alcohol (nonionic surface active agent).
Embodiment 51：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that lauryl sodium sulfate is substituted with PAMA (anionic surfactant).
Embodiment 52：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that naphthalenesulfonate formaldehyde condensation compound is substituted with polycarboxylate.
Embodiment 53：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that naphthalenesulfonate formaldehyde condensation compound is substituted with lignin.
Embodiment 54：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that naphthalenesulfonate formaldehyde condensation compound is substituted with aliphatic alcohol polyether.
Embodiment 55：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that kaolin is substituted with precipitated calcium carbonate.
Embodiment 56：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that kaolin is substituted with diatomite.
Embodiment 57：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that kaolin is substituted with powdered whiting.
Embodiment 58：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from embodiment 1a.
Embodiment 59：A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin (wettable powder, with embodiment 33 not
It is with part, the active ingredient of use derives from embodiment 1b.
Embodiment 60：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from embodiment 1d.
Embodiment 61：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from embodiment 1e.
Embodiment 62：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from embodiment 1f.
Embodiment 63：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, it is prepared as follows：
Weigh active ingredient from embodiment 1c by the formula of table 7, acceptable excipient on agricultural chemicals, be mixed, cut at a high speed
Cut, wet method is sanded, homogeneous filtering is produced.
Embodiment 64-91：A kind of composition pesticide (suspending agent) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 63 not
It is with part, embodiment 64-91 formula is as shown in table 8.
The formula (kg) of the embodiment 63 of table 7
| Component | Formula ratio |
| Active ingredient | 50.0 |
| TERSPERSE 4894 | 3.0 |
| Naphthalenesulfonate formaldehyde condensation compound | 3.0 |
| Propane diols | 5.0 |
| Xanthans | 0.2 |
| Mould inhibitor | 0.3 |
| Defoamer | 0.3 |
| Water | 38.2 |
The embodiment 64-91 of table 8 formula (kg)
Embodiment 92：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that TERSPERSE 4894 is substituted with ethoxylated dodecyl alcohol (nonionic surface active agent).
Embodiment 93：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that TERSPERSE 4894 is substituted with PAMA (anionic surfactant).
Embodiment 94：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that naphthalenesulfonate formaldehyde condensation compound is substituted with polycarboxylate.
Embodiment 95：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that naphthalenesulfonate formaldehyde condensation compound is substituted with lignin.
Embodiment 96：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that naphthalenesulfonate formaldehyde condensation compound is substituted with aliphatic alcohol polyether.
Embodiment 97：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that kaolin is substituted with precipitated calcium carbonate.
Embodiment 98：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from embodiment 1a.
Embodiment 99：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from embodiment 1b.
Embodiment 100：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from embodiment 1d.
Embodiment 101：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from embodiment 1e.
Embodiment 102：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from embodiment 1f.
Performance characterization is tested
1st, the preparation of reference substance, reference substance 1a-1d：A kind of active ingredient of the composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin：
Copper 8-hydroxyquinolinate and pyraclostrobin are weighed by table 9, mixes, produces.
The reference substance 1a-1d of table 9 formula
Reference substance 2a：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from reference substance 1a.
Reference substance 2b：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from reference substance 1b.
Reference substance 2c：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from reference substance 1c.
Reference substance 2d：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, the active ingredient of use derives from reference substance 1d.
Reference substance 3a：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from reference substance 1a.
Reference substance 3b：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from reference substance 1b.
Reference substance 3c：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from reference substance 1c.
Reference substance 3d：The composition pesticide (wettable powder) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33
Difference is that the active ingredient of use derives from reference substance 1d.
Reference substance 4a：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from reference substance 1a.
Reference substance 4b：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from reference substance 1b.
Reference substance 4c：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from reference substance 1c.
Reference substance 4d：The composition pesticide (suspending agent) of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, the difference with embodiment 63
Part is that the active ingredient of use derives from reference substance 1d.
Reference substance 5：A kind of composition pesticide (water dispersible granules) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 2 not
It is with part, using the formula of table 10.
The formula (kg) of the reference substance 5 of table 10
| Component | Formula ratio |
| Copper 8-hydroxyquinolinate | 20.0 |
| Pyraclostrobin | 10.0 |
| Lauryl sodium sulfate | 2.0 |
| Sodium lignin sulfonate | 2.0 |
| White carbon | 20.0 |
| Bentonite | 46.0 |
Reference substance 6：A kind of composition pesticide (wettable powder) of copper 8-hydroxyquinolinate and pyraclostrobin, with embodiment 33 not
It is with part, using the formula of table 11.
The formula (kg) of the reference substance 6 of table 11
| Component | Formula ratio |
| Copper 8-hydroxyquinolinate | 40.0 |
| Pyraclostrobin | 10.0 |
| Lauryl sodium sulfate | 1.5 |
| Pull open powder | 2.0 |
| Sodium lignin sulfonate | 5.0 |
| NNO | 4.0 |
| White carbon | 10.0 |
| Bentonite | 27.5 |
Reference substance 7：A kind of composition pesticide (suspending agent) of copper 8-hydroxyquinolinate and pyraclostrobin, it is different from embodiment 63 it
It is in using the formula of table 12.
The formula (kg) of the reference substance 7 of table 12
| Component | Formula ratio |
| Copper 8-hydroxyquinolinate | 15.0 |
| Pyraclostrobin | 15.0 |
| 601 phosphate ester salts | 3.0 |
| NP-10# | 1.0 |
| Xanthans | 0.2 |
| Bentonite | 5.0 |
| Ethylene glycol | 4.0 |
| Water | 51.8 |
2nd, I is tested：Copper 8-hydroxyquinolinate and pyraclostrobin for different proportion composition pesticide (including water dispersible granules,
Wettable powder, suspending agent) prevent and treat late blight of potato efficacy testing
(1) test sample：Embodiment 2, embodiment 27-31, reference substance 2a-2d, reference substance 5；Embodiment 33, embodiment 58-62,
Reference substance 3a-3d, reference substance 6；Embodiment 63, embodiment 98-102, reference substance 4a-4d, reference substance 5-7.
(2) content is tested：Active ingredient total amount identical test sample (now making) is taken, is administered to and has investigated epidemic disease disease too late
(dispenser opportunity is state of an illness initial stage), altogether dispenser 2 times on the potato of feelings；7d, 14d and 30d investigate the state of an illness respectively after 2nd dispenser
Index simultaneously calculates preventive effect.Before test, same contrast groups are for the similar potato of the late blight state of an illness；Based on active ingredient total amount,
The dosage of dispenser be 0.5,2.0,4.0g/ mus.
(3) test result：As shown in table 13-21.Table 13-21 is shown, compared with reference substance, the preventive effect of the sample of embodiment
Significantly improve, i.e., in the case of the other conditions identical of the application, the mass ratio of copper 8-hydroxyquinolinate and azoles kresoxim-methyl is 0.5~10：1
Under, synergy high to the preventive effect of the late blight of potato substantially, wherein the mass ratio of copper 8-hydroxyquinolinate and azoles kresoxim-methyl is 1.5：1 is optimal；
In addition the best results that dosage is 2.0g/ mus are found from different dosage groups.
The test I results of table 13 statistics (water dispersible granules, dosage is 0.5g/ mus)
The test I results of table 14 statistics (water dispersible granules, dosage is 2.0g/ mus)
The test I results of table 15 statistics (water dispersible granules, dosage is 4.0g/ mus)
The test I results of table 16 statistics (wettable powder, dosage is 0.5g/ mus)
The test I results of table 17 statistics (wettable powder, dosage is 2.0g/ mus)
The test I results of table 18 statistics (wettable powder, dosage is 4.0g/ mus)
The test I results of table 19 statistics (suspending agent, dosage is 0.5g/ mus)
The test I results of table 20 statistics (suspending agent, dosage is 2.0g/ mus)
The test I results of table 21 statistics (suspending agent, dosage is 4.0g/ mus)
3rd, II is tested：Copper 8-hydroxyquinolinate and pyraclostrobin for different proportion composition pesticide (including water dispersible granules,
Wettable powder, suspending agent) prevent and treat apple mildew efficacy testing
(1) test sample：Embodiment 2, embodiment 27-31, reference substance 2a-2d, reference substance 5；Embodiment 33, embodiment 58-62,
Reference substance 3a-3d, reference substance 6；Embodiment 63, embodiment 98-102, reference substance 4a-4d, reference substance 7.
(2) content is tested：Active ingredient total amount identical test sample (now making) is taken, is administered to and had investigated powdery mildew disease
(dispenser opportunity is state of an illness initial stage), altogether dispenser 2 times on the apple tree of feelings；7d, 14d and 30d investigate the state of an illness respectively after 2nd dispenser
Index simultaneously calculates preventive effect.Before test, same contrast groups are for the similar apple tree of the powdery mildew state of an illness；Based on active ingredient total amount,
The dosage of dispenser be 0.4,1.5,3.0g/ mus.
(3) test result：There is similar rule with test I, do not do deploy herein.Compared with reference substance, embodiment
The preventive effect of sample is significantly improved, i.e., in the case of the other conditions identical of the application, the mass ratio of copper 8-hydroxyquinolinate and azoles kresoxim-methyl
For 0.5~10：Under 1 to apple mildew, synergy substantially, wherein the mass ratio of copper 8-hydroxyquinolinate and azoles kresoxim-methyl be 1.5：1 is
Most preferably；In addition the best results that dosage is 2.0g/ mus are found from different dosage groups.
4th, III is tested：Composition pesticide (including the water-dispersible grain of copper 8-hydroxyquinolinate and pyraclostrobin for different proportion
Agent, wettable powder, suspending agent) prevent and treat late blight of potato efficacy testing
(1) test sample：Embodiment 2-26,32-57,63-79,88-97, reference substance 5-7.
(2) content is tested：Respectively enchashment system, in sealed vial/shady and cool indoor placement 1 year (360d), in sealing
Vial in/shady and cool indoor placement 2 years (720d), in sealed PP bag/shady and cool interior placement 1 year (360d), in sealing
PP bags in/test sample of shady and cool indoor placement 2 years (720d), be administered to and investigated on the potato of the epidemic disease state of an illness too late
(dispenser opportunity is state of an illness initial stage), altogether dispenser 2 times；14d investigates disease index and calculates preventive effect after 2nd dispenser.Before test, together
One contrast groups are for the similar potato of the late blight state of an illness；Based on active ingredient total amount, the dosage of dispenser is 2.0g/ mus；Calculate
Preventive effect loss late, preventive effect loss late=(Xi-X0) × 100%/X0, wherein X0For existing system composition pesticide in one section of dispenser
Between after preventive effect, XiFor preventive effect of the existing composition pesticide processed after dispenser and dispenser for a period of time is used for after placing a period of time.
(3) test result：As shown in table 22-24.Table 22-24 is shown, when preventing and treating the late blight of potato, with compareing condition
Than the preventive effect loss late of the sample of embodiment is small；Research is found in addition：1. in water dispersible granules, in the other conditions of the application
In the case of identical, the first wetting agent preferably sodium dodecyl sulfate, the preferred polycarboxylate of the first dispersant, preferably effectively into
Point, the first wetting agent, the first dispersant, soluble starch account for respectively 40~60wt% of the composition pesticide total amount, 1~
5wt%, 1~10wt% and 10~20wt%；2. in wettable powder, in the case of the other conditions identical of the application, the
One wetting agent preferably sodium dodecyl sulfate, the preferably preferred naphthalenesulfonate formaldehyde condensation compound of the first dispersant, active ingredient, second
Wetting agent, the second dispersant, the 40~60wt% for accounting for the composition pesticide total amount respectively of white carbon, 1~3wt%, 1~
5wt% and 3~8wt%；3. in suspending agent, in the case of the other conditions identical of the application, preferably xanthans, mould inhibitor and
Defoamer accounts for 0.05~0.4wt%, 0.1~0.5wt%, the 0.1~0.5wt% of the composition pesticide total amount respectively, preferably
Active ingredient, the 3rd wetting agent, the 3rd dispersant, propane diols account for respectively 40~60wt% of the composition pesticide total amount, 2~
5wt%, 1~6wt% and 3~8wt%, the preferred TERSPERSE 4894 of the 3rd wetting agent, the 3rd preferred naphthalene sulfonate of dispersant
Formaldehyde condensation products.
The test III result statistics of table 22 (water dispersible granules)
The test III result statistics of table 23 (wettable powder)
The test III result statistics of table 24 (suspending agent)
5th, IV is tested：Copper 8-hydroxyquinolinate and pyraclostrobin for different proportion composition pesticide (including water dispersible granules,
Wettable powder, suspending agent) prevent and treat apple mildew efficacy testing
(1) test sample：Embodiment 2-26,32-57,63-79,88-97, reference substance 5-7.
(2) content is tested：Respectively enchashment system, in sealed vial/shady and cool indoor placement 1 year (360d), in sealing
Vial in/shady and cool indoor placement 2 years (720d), in sealed PP bag/shady and cool interior placement 1 year (360d), in sealing
PP bags in/test sample of shady and cool indoor placement 2 years (720d), be administered on the apple tree for having investigated the powdery mildew state of an illness
(dispenser opportunity is state of an illness initial stage), altogether dispenser 2 times；14d investigates disease index and calculates preventive effect after 2nd dispenser.Before test, together
One contrast groups are for the similar apple tree of the powdery mildew state of an illness；Based on active ingredient total amount, the dosage of dispenser is 2.0g/ mus；Calculate
Preventive effect loss late, preventive effect loss late=(Xi-X0) × 100%/X0, wherein X0For existing system composition pesticide in one section of dispenser
Between after preventive effect, XiFor preventive effect of the existing composition pesticide processed after dispenser and dispenser for a period of time is used for after placing a period of time.
(3) test result：There is similar rule with test III, do not do deploy herein.When preventing and treating apple mildew, with
Reference substance is compared, and the preventive effect loss late of the sample of embodiment is small；Research is found in addition：1. in water dispersible granules, the application's
In the case of other conditions identical, the first wetting agent preferably sodium dodecyl sulfate, the preferred polycarboxylate of the first dispersant, preferably
Active ingredient, the first wetting agent, the first dispersant, soluble starch account for respectively the composition pesticide total amount 40~
60wt%, 1~5wt%, 1~10wt% and 10~20wt%；2. in wettable powder, in the other conditions identical of the application
In the case of, the first wetting agent preferably sodium dodecyl sulfate, the preferred naphthalenesulfonate formaldehyde condensation compound of the first dispersant, preferably effectively
Composition, the second wetting agent, the second dispersant, the 40~60wt% for accounting for the composition pesticide total amount respectively of white carbon, 1~
3wt%, 1~5wt% and 3~8wt%；3. in suspending agent, in the case of the other conditions identical of the application, preferred xanthan
Glue, mould inhibitor and defoamer account for respectively 0.05~0.4wt% of the composition pesticide total amount, 0.1~0.5wt%, 0.1~
0.5wt%, preferably active ingredient, the 3rd wetting agent, the 3rd dispersant, propane diols account for the 40 of the composition pesticide total amount respectively
~60wt%, 2~5wt%, 1~6wt% and 3~8wt%, the preferred TERSPERSE 4894 of the 3rd wetting agent, the 3rd dispersant
It is preferred that naphthalenesulfonate formaldehyde condensation compound.
Claims (10)
1. the composition pesticide of a kind of copper 8-hydroxyquinolinate and pyraclostrobin, it is characterised in that including that can be connect in active ingredient and agricultural chemicals
The excipient received, active ingredient includes copper 8-hydroxyquinolinate and pyraclostrobin；In active ingredient, the quality of copper 8-hydroxyquinolinate and pyraclostrobin
Than for 0.5~10：1.
2. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 1 and pyraclostrobin, it is characterised in that effectively into
In point, the mass ratio of copper 8-hydroxyquinolinate and pyraclostrobin is 1.5：1；The composition pesticide includes 20~80wt% active ingredient
With acceptable excipient on 20~80wt% agricultural chemicals.
3. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 1 and pyraclostrobin, it is characterised in that the agriculture
Drug composition is that acceptable excipient includes the first wetting agent, the first dispersant and the on water dispersible granules, the agricultural chemicals of use
One filler；One or more of first wetting agent in anionic or nonionic surface active agent, first disperses
One or more of the agent in naphthalene sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether, first filler is selected from solvable
One or more in property starch, ammonium sulfate or kaolin or diatomite.
4. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 3 and pyraclostrobin, it is characterised in that moisture dissipates
In granula, active ingredient, the first wetting agent, the first dispersant account for respectively 40~60wt% of the composition pesticide total amount, 1~
5wt% and 1~10wt%.
5. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 4 and pyraclostrobin, it is characterised in that moisture dissipates
In granula, first filler includes soluble starch, and soluble starch accounts for 10~20wt% of the composition pesticide total amount；
First wetting agent is lauryl sodium sulfate, and first dispersant is polycarboxylate.
6. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 1 and pyraclostrobin, it is characterised in that the agriculture
Drug composition is that acceptable excipient includes the second wetting agent, the second dispersant, hard charcoal on wettable powder, the agricultural chemicals of use
Black and the second filler, one or more of second wetting agent in anionic or nonionic surface active agent, the
One or more of two dispersants in naphthalene sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether, the second filler choosing
One or more selected from kaolin or precipitated calcium carbonate.
7. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 6 and pyraclostrobin, it is characterised in that wettable
In pulvis, active ingredient, the second wetting agent, the second dispersant, white carbon account for respectively the composition pesticide total amount 40~
60wt%, 1~3wt%, 1~5wt% and 3~8wt%；First wetting agent is lauryl sodium sulfate, described first point
Powder is naphthalenesulfonate formaldehyde condensation compound.
8. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 1 and pyraclostrobin, it is characterised in that the agriculture
Drug composition is that acceptable excipient includes the 3rd wetting agent, the 3rd dispersant and propane diols on suspending agent, the agricultural chemicals of use；
One or more of 3rd wetting agent in anionic or nonionic surface active agent, the 3rd dispersant is selected from naphthalene
One or more in sulfonate, polycarboxylate, lignin or aliphatic alcohol polyether.
9. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 8 and pyraclostrobin, it is characterised in that suspending agent
In, active ingredient, the 3rd wetting agent, the 3rd dispersant, propane diols account for respectively the composition pesticide total amount 40~60wt%,
2~5wt%, 1~6wt% and 3~8wt%；3rd wetting agent is TERSPERSE 4894, and the 3rd dispersant is naphthalene
Sulfonate and formaldehyde condensation product.
10. the composition pesticide of a kind of copper 8-hydroxyquinolinate according to claim 9 and pyraclostrobin, it is characterised in that described
Composition pesticide also includes xanthans, mould inhibitor and defoamer；Xanthans, mould inhibitor and defoamer account for the pesticide combination respectively
0.05~0.4wt%, 0.1~0.5wt%, the 0.1~0.5wt% of thing total amount.
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| CN201710255722.5A CN107006505A (en) | 2017-04-19 | 2017-04-19 | A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin |
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| CN201710255722.5A CN107006505A (en) | 2017-04-19 | 2017-04-19 | A kind of composition pesticide of copper 8-hydroxyquinolinate and pyraclostrobin |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108308190A (en) * | 2017-12-25 | 2018-07-24 | 陕西嘉益蓝德生物工程有限公司 | The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone |
| CN111226923A (en) * | 2020-03-09 | 2020-06-05 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN112841210A (en) * | 2021-01-15 | 2021-05-28 | 上海生农生化制品股份有限公司 | Dispersing wetting agent composition |
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| CN102217599A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition containing oxine-copper and kresoxim-methyl |
| CN102626099A (en) * | 2012-03-28 | 2012-08-08 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing cupric nonyl phenolsulfonate and methoxy-acrylate bactericide |
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| CN101785464A (en) * | 2010-03-25 | 2010-07-28 | 青岛瀚生生物科技股份有限公司 | Oxine-copper composite bactericide |
| CN102217599A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition containing oxine-copper and kresoxim-methyl |
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| CN108308190A (en) * | 2017-12-25 | 2018-07-24 | 陕西嘉益蓝德生物工程有限公司 | The bactericidal composition and application thereof of pyraclostrobin-containing and quinolinone |
| CN111226923A (en) * | 2020-03-09 | 2020-06-05 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN111226923B (en) * | 2020-03-09 | 2022-04-22 | 上海生农生化制品股份有限公司 | Pyraclostrobin-oxine-copper microcapsule suspension-suspending agent and preparation method thereof |
| CN112841210A (en) * | 2021-01-15 | 2021-05-28 | 上海生农生化制品股份有限公司 | Dispersing wetting agent composition |
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Application publication date: 20170804 |