CN106986411A - A kind of use in waste water treatment Inorganic-organic Hybrid Material and preparation method thereof - Google Patents
A kind of use in waste water treatment Inorganic-organic Hybrid Material and preparation method thereof Download PDFInfo
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- CN106986411A CN106986411A CN201710420469.4A CN201710420469A CN106986411A CN 106986411 A CN106986411 A CN 106986411A CN 201710420469 A CN201710420469 A CN 201710420469A CN 106986411 A CN106986411 A CN 106986411A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of use in waste water treatment Inorganic-organic Hybrid Material and preparation method thereof, the hybrid material is prepared from by the component of following parts by weight：15 30 50 parts of mesopore silicon oxide SBA, 10 20 parts of PDDA, 15 25 parts of furfural activated carbon, 10 20 parts of sodium acid carbonate, 25 35 parts of poly- 3 butyric ester, 10 15 parts of cetyl pyridinium bromide, 189 13 17 parts of silane coupling A, 550 12 18 parts of silane coupler KH, 5 10 parts of catalyst, 36 parts of 2 bromine, 3 nitrotoleune, 48 parts of 3 cyano group, 5 flurophenyl boronic acid, 15 25 parts of organic solvent.The present invention is integrated with absorption, neutralization, the multiple effect decomposed, and using the superpower suction-operated of cleanser, improves neutralization purifying rate of the cleanser for organic pollution in water body.
Description
Technical field
The present invention relates to technical field of waste water processing, especially a kind of use in waste water treatment Inorganic-organic Hybrid Material and its system
Preparation Method.
Background technology
With continuing to develop for industrial technology, pollution of China's heavy metal ion to environment is increasingly aggravated, in order to solve this
One environmental problem, proposes a kind of preparation of novel hybride materials, i.e., an inorganic organic Hybrid Materials, the bear of this hybrid material
Electric group be direct grafting on the strand of polymer, rather than substep is carried out, therefore the molecular structure of prepared material
More stable, heat endurance is also significantly improved, while have stronger adsorption capacity to metal ion, thus in wastewater treatment etc.
There is wide application value in terms of environmental protection.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of use in waste water treatment Inorganic-organic Hybrid Material and its preparation side
Method.
In order to solve the above technical problems, the technical solution used in the present invention is as follows.
A kind of use in waste water treatment Inorganic-organic Hybrid Material, is prepared from by the component of following parts by weight：
30-50 parts of mesoporous SBA-15,10-20 parts of PDDA, furfural activated carbon 15-
25 parts, 10-20 parts of sodium acid carbonate, 25-35 parts of poly 3-hydroxy butyrate, 10-15 parts of cetyl pyridinium bromide, silane coupler
13-17 parts of A-189,12-18 parts of silane resin acceptor kh-550,5-10 parts of catalyst, 3-6 parts of 2- bromo- 3- nitrotoleunes, 3- cyanogen
4-8 parts of base -5- fluoro-phenyl boric acid, 15-25 parts of organic solvent.
Preferably, the catalyst includes the raw material of following mass percent.
22.5wt% 5 bromosalicylic acid methyl esters, 38wt% 3,4- dimethyl benzamides, 9wt% methyl -2- three
Chloromethyl phenyl ester, 18wt% polyethylene glycol, 6.5wt% 2-methyl-3-biphenylmethanol, 6wt% methyl phenyl carbinyl acetate.
Preferably, it is prepared from by the component of following parts by weight：
30 parts of mesoporous SBA-15,10 parts of PDDA, 15 parts of furfural activated carbon, carbonic acid
10 parts of hydrogen sodium, 25 parts of poly 3-hydroxy butyrate, 10 parts of cetyl pyridinium bromide, 13 parts of silane coupling A -189, silane are even
Join 12 parts of agent KH-550,5 parts of catalyst, 3 parts of the bromo- 3- nitrotoleunes of 2-, 4 parts of 3- cyano group -5- fluoro-phenyls boric acid, organic solvent
15 parts.
Preferably, it is prepared from by the component of following parts by weight：
50 parts of mesoporous SBA-15,20 parts of PDDA, 25 parts of furfural activated carbon, carbonic acid
20 parts of hydrogen sodium, 35 parts of poly 3-hydroxy butyrate, 15 parts of cetyl pyridinium bromide, 17 parts of silane coupling A -189, silane are even
Join 18 parts of agent KH-550,10 parts of catalyst, 6 parts of the bromo- 3- nitrotoleunes of 2-, 8 parts of 3- cyano group -5- fluoro-phenyls boric acid, You Jirong
25 parts of agent.
Preferably, it is prepared from by the component of following parts by weight：
40 parts of mesoporous SBA-15,15 parts of PDDA, 20 parts of furfural activated carbon, carbonic acid
15 parts of hydrogen sodium, 30 parts of poly 3-hydroxy butyrate, 12.5 parts of cetyl pyridinium bromide, 15 parts of silane coupling A -189, silane
15 parts of coupling agent KH-550,7.5 parts of catalyst, 4.5 parts of the bromo- 3- nitrotoleunes of 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, have
20 parts of machine solvent.
The preparation method of above-mentioned use in waste water treatment Inorganic-organic Hybrid Material, comprises the following steps：
S1, the formula as described in claim 1 weigh each component；
S2, addition PDDA, sodium acid carbonate, hexadecane bromide in mesoporous SBA-15
Change pyridine, 3- cyano group -5- fluoro-phenyls boric acid, the bromo- 3- nitrotoleunes of 2- and catalyst, be stirred, be sufficiently mixed, must mix
Expect A；
S3, silane coupling A -189 and silane resin acceptor kh-550 be placed in organic solvent, stirring reaction obtains compound
B；
S4, furfural activated carbon is processed into graininess, as kernel, outside parcel covering compound A, formed diameter 5~
10mm particle, wraps up compound B on the outside of particle, 8~15mm of diameter particle is formed, then in the poly- 3- hydroxyls of particle outer wrapping
Base butyrate, obtains hybrid material crude product；
S5, the hybrid material crude product of gained being heating and curing, heating-up temperature is 75~85 DEG C, the heat time is 20~
30min, is made hybrid material finished product.
The beneficial effect brought using above-mentioned technical proposal is：The present invention by improve cleanser carrier structure and
Active ingredient, not only reduces souring of the current to cleanser, improves the RT of active ingredient in the carrier, and
And cleanser is integrated with absorption, neutralization, the multiple effect decomposed, and using the superpower suction-operated of cleanser, improve net
Neutralization purifying rate of the agent for organic pollution in water body.
Embodiment
In order that objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further
Describe in detail.It should be appreciated that specific embodiment described herein is not intended to limit the present invention only to explain the present invention.
In following examples, used catalyst includes the raw material of following mass percent.
22.5wt% 5 bromosalicylic acid methyl esters, 38wt% 3,4- dimethyl benzamides, 9wt% methyl -2- three
Chloromethyl phenyl ester, 18wt% polyethylene glycol, 6.5wt% 2-methyl-3-biphenylmethanol, 6wt% methyl phenyl carbinyl acetate.
Embodiment 1
A kind of use in waste water treatment Inorganic-organic Hybrid Material, is prepared from by the component of following parts by weight：
30 parts of mesoporous SBA-15,10 parts of PDDA, 15 parts of furfural activated carbon, carbonic acid
10 parts of hydrogen sodium, 25 parts of poly 3-hydroxy butyrate, 10 parts of cetyl pyridinium bromide, 13 parts of silane coupling A -189, silane are even
Join 12 parts of agent KH-550,5 parts of catalyst, 3 parts of the bromo- 3- nitrotoleunes of 2-, 4 parts of 3- cyano group -5- fluoro-phenyls boric acid, organic solvent
15 parts.
Embodiment 2
A kind of use in waste water treatment Inorganic-organic Hybrid Material, is prepared from by the component of following parts by weight：
50 parts of mesoporous SBA-15,20 parts of PDDA, 25 parts of furfural activated carbon, carbonic acid
20 parts of hydrogen sodium, 35 parts of poly 3-hydroxy butyrate, 15 parts of cetyl pyridinium bromide, 17 parts of silane coupling A -189, silane are even
Join 18 parts of agent KH-550,10 parts of catalyst, 6 parts of the bromo- 3- nitrotoleunes of 2-, 8 parts of 3- cyano group -5- fluoro-phenyls boric acid, You Jirong
25 parts of agent.
Embodiment 3
A kind of use in waste water treatment Inorganic-organic Hybrid Material, is prepared from by the component of following parts by weight：
40 parts of mesoporous SBA-15,15 parts of PDDA, 20 parts of furfural activated carbon, carbonic acid
15 parts of hydrogen sodium, 30 parts of poly 3-hydroxy butyrate, 12.5 parts of cetyl pyridinium bromide, 15 parts of silane coupling A -189, silane
15 parts of coupling agent KH-550,7.5 parts of catalyst, 4.5 parts of the bromo- 3- nitrotoleunes of 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, have
20 parts of machine solvent.
The embodiment of the present invention additionally provides a kind of preparation method of use in waste water treatment Inorganic-organic Hybrid Material, including following
Step：
S1, the formula as described in embodiment 1- embodiments 3 weigh each component；
S2, addition PDDA, sodium acid carbonate, hexadecane bromide in mesoporous SBA-15
Change pyridine, 3- cyano group -5- fluoro-phenyls boric acid, the bromo- 3- nitrotoleunes of 2- and catalyst, be stirred, be sufficiently mixed, must mix
Expect A；
S3, silane coupling A -189 and silane resin acceptor kh-550 be placed in organic solvent, stirring reaction obtains compound
B；
S4, furfural activated carbon is processed into graininess, as kernel, outside parcel covering compound A, formed diameter 5~
10mm particle, wraps up compound B on the outside of particle, 8~15mm of diameter particle is formed, then in the poly- 3- hydroxyls of particle outer wrapping
Base butyrate, obtains hybrid material crude product；
S5, the hybrid material crude product of gained being heating and curing, heating-up temperature is 75~85 DEG C, the heat time is 20~
30min, is made hybrid material finished product.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of use in waste water treatment Inorganic-organic Hybrid Material, it is characterised in that be prepared from by the component of following parts by weight：
30-50 parts of mesoporous SBA-15,10-20 parts of PDDA, 15-25 parts of furfural activated carbon,
10-20 parts of sodium acid carbonate, 25-35 parts of poly 3-hydroxy butyrate, 10-15 parts of cetyl pyridinium bromide, silane coupling A -189
13-17 parts, 12-18 parts of silane resin acceptor kh-550,5-10 parts of catalyst, 3-6 parts of 2- bromo- 3- nitrotoleunes, 3- cyano group -5-
4-8 parts of fluoro-phenyl boric acid, 15-25 parts of organic solvent.
2. a kind of use in waste water treatment Inorganic-organic Hybrid Material as claimed in claim 1, it is characterised in that：The catalyst bag
Include the raw material of following mass percent.
22.5wt% 5 bromosalicylic acid methyl esters, 38wt% 3,4- dimethyl benzamides, the 9wt% chloromethanes of methyl -2- three
Base phenyl ester, 18wt% polyethylene glycol, 6.5wt% 2-methyl-3-biphenylmethanol, 6wt% methyl phenyl carbinyl acetate.
3. a kind of use in waste water treatment Inorganic-organic Hybrid Material as claimed in claim 1, it is characterised in that：By following parts by weight
Several components are prepared from：
30 parts of mesoporous SBA-15,10 parts of PDDA, 15 parts of furfural activated carbon, sodium acid carbonate
10 parts, 25 parts of poly 3-hydroxy butyrate, 10 parts of cetyl pyridinium bromide, 13 parts of silane coupling A -189, silane coupler
12 parts of KH-550,5 parts of catalyst, 3 parts of the bromo- 3- nitrotoleunes of 2-, 4 parts of 3- cyano group -5- fluoro-phenyls boric acid, organic solvent 15
Part.
4. a kind of use in waste water treatment Inorganic-organic Hybrid Material as claimed in claim 1, it is characterised in that：By following parts by weight
Several components are prepared from：
50 parts of mesoporous SBA-15,20 parts of PDDA, 25 parts of furfural activated carbon, sodium acid carbonate
20 parts, 35 parts of poly 3-hydroxy butyrate, 15 parts of cetyl pyridinium bromide, 17 parts of silane coupling A -189, silane coupler
18 parts of KH-550,10 parts of catalyst, 6 parts of the bromo- 3- nitrotoleunes of 2-, 8 parts of 3- cyano group -5- fluoro-phenyls boric acid, organic solvent 25
Part.
5. a kind of use in waste water treatment Inorganic-organic Hybrid Material as claimed in claim 1, it is characterised in that：By following parts by weight
Several components are prepared from：
40 parts of mesoporous SBA-15,15 parts of PDDA, 20 parts of furfural activated carbon, sodium acid carbonate
15 parts, it is 30 parts of poly 3-hydroxy butyrate, 12.5 parts of cetyl pyridinium bromide, 15 parts of silane coupling A -189, silane coupled
15 parts of agent KH-550,7.5 parts of catalyst, 4.5 parts of the bromo- 3- nitrotoleunes of 2-, 6 parts of 3- cyano group -5- fluoro-phenyls boric acid, You Jirong
20 parts of agent.
6. a kind of preparation method of the use in waste water treatment Inorganic-organic Hybrid Material described in claim 1-5 any one, it is special
Levy and be, comprise the following steps：
S1, the formula as described in claim 1 weigh each component；
S2, addition PDDA, sodium acid carbonate, cetyl bromination pyrrole in mesoporous SBA-15
Pyridine, 3- cyano group -5- fluoro-phenyls boric acid, the bromo- 3- nitrotoleunes of 2- and catalyst, are stirred, are sufficiently mixed, obtain compound A；
S3, silane coupling A -189 and silane resin acceptor kh-550 be placed in organic solvent, stirring reaction obtains compound B；
S4, furfural activated carbon is processed into graininess, is used as kernel, outside parcel covering compound A forms 5~10mm of diameter
Particle, compound B is wrapped up on the outside of particle, diameter 8~15mm particle is formed, then in the poly- 3- hydroxyls fourth of particle outer wrapping
Acid esters, obtains hybrid material crude product；
S5, the hybrid material crude product of gained being heating and curing, heating-up temperature is 75~85 DEG C, the heat time is 20~
30min, is made hybrid material finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107572618A (en) * | 2017-10-30 | 2018-01-12 | 周爱民 | A kind of water purification agent of purifying aquatic product cultivating water environment |
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| CN102634029A (en) * | 2011-02-14 | 2012-08-15 | 苏州巴米特信息科技有限公司 | Preparation method of sulfhydryl-containing hybrid material and method for adsorption property research |
| JP2015048297A (en) * | 2013-09-04 | 2015-03-16 | リコーイメージング株式会社 | Method of producing surface-modified mesoporous silica nanoparticle |
| CN104148021A (en) * | 2014-07-31 | 2014-11-19 | 桂林理工大学 | Method for preparing bifunctional mesoporous silica for adsorbing heavy metal ions in water |
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| CN107572618A (en) * | 2017-10-30 | 2018-01-12 | 周爱民 | A kind of water purification agent of purifying aquatic product cultivating water environment |
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Application publication date: 20170728 |
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