CN106967524A - A kind of without phosphorus cleaning agent - Google Patents
A kind of without phosphorus cleaning agent Download PDFInfo
- Publication number
- CN106967524A CN106967524A CN201710202004.1A CN201710202004A CN106967524A CN 106967524 A CN106967524 A CN 106967524A CN 201710202004 A CN201710202004 A CN 201710202004A CN 106967524 A CN106967524 A CN 106967524A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning agent
- phosphorus
- phosphorus cleaning
- oxirane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of without phosphorus cleaning agent, wherein, it is made up of following components by mass parts：Complexed surfactant：9 18 parts；Metasilicate pentahydrate sodium：24 parts；Sodium carbonate：23 parts；Butyl：13 parts；Ethanol：23 parts；Deionized water：Surplus；The complexed surfactant includes condensation product, the ethylenediamine tetra-acetic acid of polyethoxylated alcohols, AEO, fatty acid methyl ester and oxirane.A kind of without phosphorus cleaning agent that the present invention is provided, using complexed surfactant, effectively improves cleansing power；Phosphonate dispersants are substituted using environment-friendly materials；The addition of very little can just meet the requirement of cleaning.
Description
Technical field
The present invention relates to cleaning agent field, and in particular to a kind of without phosphorus cleaning agent.
Background technology
Industrial cleaning agent refers to that what is industrially used is used for removing the chemistry or biological agent of dirt, and common industry is clear
Lotion have ship cooler cleaning agent, leather polishing cleaning agent, Al-alloy parts oil-removing cleaning agent, carbon-steel parts oil-removing cleaning agent and
Various die cleaning agents.Industry cleaning link experienced chlorine class solvent, hydrocarbon cosolvent, the aqueous cleaning using interfacial agent
Agent, the development course of the strong basicity electrolysis water of strong basicity electrolysis wetting system production.Wherein, hydrocarbon cosolvent also needs to carry out
Technological processing for explosion protection feature, the waterborne cleaning agent cleaning waste liquid cost of interfacial agent is too high.
Industrial cleaning agent develops into today, has been able to substantially meet the demand of industry cleaning link, but with people's environmental protection
The raising of consciousness, during industry cleaning link is met, people also increasingly pay attention to cleaning agent pollution on the environment.Mesh
Preceding industrial cleaning agent also has quite a few to be phosphorous cleaning agent, and not phosphorous cleaning agent can run into cleaning in cleaning process
The big defect of ability, consumption.Phosphorous cleaning agent is in wastewater treatment process after being cleaned, and P elements can cause the richness of water body
Nutrient laden so that the algal bloom in water, whole water ecosystem is destroyed, so as to cause the pollution of environment.
Therefore, manufacture a kind of not phosphorous, while can realize that the strong industrial cleaning agent of low consumption cleansing power is raw to industry again
Production and environmental protection suffer from important meaning.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of without phosphorus cleaning agent, and strong with cleansing power, addition is small,
Low foam, improves production efficiency, without phosphoric acid salt material, the low good characteristic of cost.
To achieve these goals, the present invention is adopted the following technical scheme that：A kind of without phosphorus cleaning agent, wherein, by with the following group
Divide by mass parts composition：
Complexed surfactant：9-18 parts；
Metasilicate pentahydrate sodium：2-4 parts；
Sodium carbonate：2-3 parts；
Butyl：1-3 parts；
Ethanol：2-3 parts；
Deionized water：Surplus.
A kind of without phosphorus cleaning agent that the present invention is provided, wherein, the complexed surfactant includes polyethoxylated alcohols, fat
Condensation product, the ethylenediamine tetra-acetic acid of fat alcohol APEO, fatty acid methyl ester and oxirane.
A kind of without phosphorus cleaning agent that the present invention is provided, wherein, the composite surface activity presses mass parts group by following components
Into：
Polyethoxylated alcohols：5-7 parts；
AEO：1-3 parts；
The condensation product of fatty acid methyl ester and oxirane：2-5 parts；
Ethylenediamine tetra-acetic acid：1-2 parts；
A kind of without phosphorus cleaning agent that the present invention is provided, wherein, the polyethoxylated alcohols are modified polyethoxylated alcohols.
A kind of without phosphorus cleaning agent that the present invention is provided, is made up of following components by mass parts：
Modified polyethoxylated alcohols：5-7 parts；
AEO：1-3 parts；
The condensation product of fatty acid methyl ester and oxirane：2-5 parts；
Ethylenediamine tetra-acetic acid：1 part；
Metasilicate pentahydrate sodium：3.1 part；
Sodium carbonate：2-3 parts；
Butyl：1-2 parts；
Ethanol：2-3 parts；
Deionized water：Surplus.
The present invention having the beneficial effect that compared with prior art：This product uses complexed surfactant, effectively increases clear
Wash ability；Environment-friendly materials have been used as replacement phosphonate dispersants；The addition of very little can just meet wanting for cleaning
Ask.
Embodiment
Below with reference to the explanation present invention of specific embodiment in detail so that professional and technical personnel can be more fully
Understand this patent.
Embodiment 1
A kind of without phosphorus cleaning agent, is made up of following components by mass parts：
Modified polyethoxylated alcohols：5 parts；
AEO：3 parts；
The condensation product of fatty acid methyl ester and oxirane：2 parts；
Ethylenediamine tetra-acetic acid：3 parts；
Metasilicate pentahydrate sodium：2 parts；
Sodium carbonate：3 parts；
Butyl：1 part；
Ethanol：3 parts；
Deionized water：Surplus.
The without phosphorus cleaning agent being formulated using the present embodiment, with cleansing power is strong, cost is low, Phosphateless environmentally friendly, reduction enterprise
Usage amount, the characteristics of reducing cost.
Embodiment 2
A kind of without phosphorus cleaning agent, is made up of following components by mass parts：
Modified polyethoxylated alcohols：7 parts；
AEO：1 part；
The condensation product of fatty acid methyl ester and oxirane：5 parts；
Ethylenediamine tetra-acetic acid：1 part；
Metasilicate pentahydrate sodium：4 parts；
Sodium carbonate：2 parts；
Butyl：2 parts；
Ethanol：2 parts；
Deionized water：Surplus.
The without phosphorus cleaning agent being formulated using the present embodiment, with cleansing power is strong, cost is low, Phosphateless environmentally friendly, reduction enterprise
Usage amount, the characteristics of reducing cost.
Embodiment 3
A kind of without phosphorus cleaning agent, is made up of following components by mass parts：
Modified polyethoxylated alcohols：6 parts；
AEO：2 parts；
The condensation product of fatty acid methyl ester and oxirane：3 parts；
Ethylenediamine tetra-acetic acid：2 parts；
Metasilicate pentahydrate sodium：3 parts；
Sodium carbonate：2.5 part；
Butyl：1.5 part；
Ethanol：2.5 part；
Deionized water：Surplus.
The without phosphorus cleaning agent being formulated using the present embodiment, with cleansing power is strong, cost is low, Phosphateless environmentally friendly, reduction enterprise
Usage amount, the characteristics of reducing cost.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of without phosphorus cleaning agent, it is characterised in that be made up of following components by mass parts：
Complexed surfactant：9-18 parts；
Metasilicate pentahydrate sodium：2-4 parts；
Sodium carbonate：2-3 parts；
Butyl：1-3 parts；
Ethanol：2-3 parts；
Deionized water：Surplus.
2. a kind of without phosphorus cleaning agent according to claim 1, it is characterised in that the complexed surfactant includes poly- second
Epoxide alcohol, AEO, condensation product, the ethylenediamine tetra-acetic acid of fatty acid methyl ester and oxirane.
3. a kind of without phosphorus cleaning agent according to claim 2, it is characterised in that the composite surface activity is by following components
Constituted by mass parts：
Polyethoxylated alcohols：5-7 parts；
AEO：1-3 parts；
The condensation product of fatty acid methyl ester and oxirane：2-5 parts；
Ethylenediamine tetra-acetic acid：1-2 parts.
4. a kind of without phosphorus cleaning agent according to claim 2, it is characterised in that the polyethoxylated alcohols are modified poly- second
Epoxide alcohol.
5. a kind of without phosphorus cleaning agent according to claim 1, it is characterised in that be made up of following components by mass parts：
Modified polyethoxylated alcohols：5-7 parts；
AEO：1-3 parts；
The condensation product of fatty acid methyl ester and oxirane：2-5 parts；
Ethylenediamine tetra-acetic acid：1 part；
Metasilicate pentahydrate sodium：3.1 part；
Sodium carbonate：2-3 parts；
Butyl：1-2 parts；
Ethanol：2-3 parts；
Deionized water：Surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710202004.1A CN106967524A (en) | 2017-03-30 | 2017-03-30 | A kind of without phosphorus cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710202004.1A CN106967524A (en) | 2017-03-30 | 2017-03-30 | A kind of without phosphorus cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106967524A true CN106967524A (en) | 2017-07-21 |
Family
ID=59336257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710202004.1A Pending CN106967524A (en) | 2017-03-30 | 2017-03-30 | A kind of without phosphorus cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106967524A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597547A (en) * | 2009-05-21 | 2009-12-09 | 陈安友 | A kind of phosphate-free environment-friendly cleaning agent |
| CN104313622A (en) * | 2014-09-29 | 2015-01-28 | 合肥乾丰润滑科技有限公司 | Normal-temperature water-based non-phosphorus rust-proof cleaning agent for heavy oil |
| CN105623870A (en) * | 2015-12-23 | 2016-06-01 | 四川全丰新材料科技有限公司 | Industrial detergent |
-
2017
- 2017-03-30 CN CN201710202004.1A patent/CN106967524A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597547A (en) * | 2009-05-21 | 2009-12-09 | 陈安友 | A kind of phosphate-free environment-friendly cleaning agent |
| CN104313622A (en) * | 2014-09-29 | 2015-01-28 | 合肥乾丰润滑科技有限公司 | Normal-temperature water-based non-phosphorus rust-proof cleaning agent for heavy oil |
| CN105623870A (en) * | 2015-12-23 | 2016-06-01 | 四川全丰新材料科技有限公司 | Industrial detergent |
Non-Patent Citations (1)
| Title |
|---|
| 徐宝财等: "《洗涤剂配方设计6步》", 30 April 2010, 化学工业出版社 * |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170721 |
|
| RJ01 | Rejection of invention patent application after publication |