CN106592250A - Fireproof antibacterial cotton cloth and making method thereof - Google Patents
Fireproof antibacterial cotton cloth and making method thereof Download PDFInfo
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- CN106592250A CN106592250A CN201611143236.6A CN201611143236A CN106592250A CN 106592250 A CN106592250 A CN 106592250A CN 201611143236 A CN201611143236 A CN 201611143236A CN 106592250 A CN106592250 A CN 106592250A
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- cloth
- contton
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- layer
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- 239000004744 fabric Substances 0.000 title claims abstract description 170
- 238000000034 method Methods 0.000 title claims abstract description 13
- 229920000742 Cotton Polymers 0.000 title claims abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003063 flame retardant Substances 0.000 claims abstract description 18
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 claims abstract description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 11
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229960000304 folic acid Drugs 0.000 claims abstract description 9
- 235000019152 folic acid Nutrition 0.000 claims abstract description 9
- 239000011724 folic acid Substances 0.000 claims abstract description 9
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229960001149 dopamine hydrochloride Drugs 0.000 claims abstract description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 230000000845 anti-microbial effect Effects 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 20
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- 239000012530 fluid Substances 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 13
- 239000004793 Polystyrene Substances 0.000 claims description 11
- 229920002223 polystyrene Polymers 0.000 claims description 11
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000600 sorbitol Substances 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
- 239000008158 vegetable oil Substances 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 230000000149 penetrating effect Effects 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- -1 iso-octyl Chemical group 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000013461 design Methods 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 238000007731 hot pressing Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 3
- 239000010409 thin film Substances 0.000 abstract description 3
- 239000003242 anti bacterial agent Substances 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides fireproof antibacterial cotton cloth and a making method thereof. An outer cloth layer has hydrophility after going through hydrophilic treatment, and a hydrophobic thin film of a nano grading structure with a grid structure is formed on the surface of an inner cloth layer, so that the inner cloth layer has hydrophobicity. After the cloth is wetted, the hydrophobic thin film of the nano grading structure with the grid structure is arranged on the surface of the inner cloth layer through reticular-structure zinc oxide particles, dopamine hydrochloride and folic acid and can quickly discharge water entering the inner cloth layer to the outer cloth layer, so that the inner cloth layer is maintained dry and comfortable. In addition, the cloth is uniformly immersed with organosilicon quaternary ammonium salt antibacterial agent, thereby having good antibacterial performance; a fireproof layer is arranged on the surface of the cloth and made of CVC flame-retardant fabric, so that the cloth has good fireproof and flame-retardant performance, can prevent flame from burning clothes and provides good fireproof effect for human body.
Description
Technical field
The invention belongs to cloth processing technique field, more particularly to a kind of fire resisting antibacterial contton cloth and its preparation side
Method.
Background technology
Cloth is one of the most frequently used means of livelihood of people, people using cloth make medicated clothing, ornaments, packaging material etc. by
Come for a long time, the life that the utilization of cloth gives people brings great convenience.But be present a shortcoming in current cloth, exactly prevent
Aqueouss are not enough, such as medicated clothing etc. is often got wet by rainwater or other water, and people's life is brought inconvenience.When people utilize cloth bag
To contain during article, the problems referred to above can also cause the consequence that article is drenched in cloth bag.Also there is many in prior art with regard to cloth
The research report of material, CN100595373A discloses a kind of preparation method of ultra-hydrophobic cloth, selects the cotton containing 80-100%
The cloth of fiber, using being impregnated in gold chloride and citric acid mixed solution, then at once turns the cloth containing reactant liquor
Move on in baking oven and heat, 6-8 hours in the ethanol solution of lauryl mercaptan are immersed afterwards, ultra-hydrophobic cloth is obtained;
CN103669025A discloses a kind of strong water absorption cloth, described strong water absorption cloth by polyacrylonitrile, Zhu's flaxen fiber,
The four kinds of fiber blend braidings of cuprammonium silk fiber and cashmere fibres are formed;CN105734973A discloses a kind of waterproof cloth
Processing technique, first receives VAE emulsions, acrylic emulsion, gelatin Alumen, benzenesulfonic acid, balance of water, after heating 30 minutes or so
Natural cooling;Then cloth is soaked 30 minutes wherein after cleaning, and is dried after dehydration, finally one layer is arranged on cloth and is prevented
Water layer;CN102660870A discloses a kind of preparation method of oil-water separation cloth, first by sodium hydroxide and six nitric hydrates
Zinc granule is successively added to the water, magnetic agitation 12-24h at 75 ± 5 DEG C, washing, and centrifugation is dried;The Zinc oxide particles for obtaining,
Hydrophobically modified is carried out using stearic acid, the tetrahydrofuran solution of polystyrene is then prepared, and hydrophobic Zinc oxide particles are uniform
Dispersion wherein, is finally dipped in cloth in above-mentioned solution, takes out after 1-3min and is placed in the surface plate of cleaning, drying at room temperature, i.e.,
Obtain oil-water separation cloth;But more or less there is such or such shortcoming in above-mentioned cloth, there is one in actual applications
Fixed defect, needs to further improve.
In addition, at present people can wear clothes daily in the study of various occasions, work, life, will connect between not feeling in vain
Various antibacterials are contacted, long-term accumulated enrichment can produce harm to the health of human body.It is also and people's shape shadow in life moderate heat simultaneously
Not from, the class that fire can give people causes greatly loss, or even threat to life, and the loss caused by fire is inestimable, in order to
The safety of the protection public, reduces the loss that fire causes, it is necessary to provide a kind of cloth with fire protecting performance, when generation fire
Or the intensity of a fire is produced when threatening to personal safety and property safety, can play certain protective action, and injures and deaths and loss are reduced.
The content of the invention
To solve the above problems, the technical solution used in the present invention is:
A kind of preparation method of fire resisting antibacterial contton cloth, comprises the steps:(1) choose cotton fiber content be 80~
100% cloth, is cleaned by ultrasonic 3 minutes successively in second alcohol and water, and is dried;(2) it is taken as the cloth of outer bed of cloth, by cloth
Material impregnated in and carry out in hydrophilizing agent hydrophilic treated, takes out after 3~6min and is placed in the surface plate of cleaning, drying at room temperature;The parent
Water preparation is consisted of:Double type sulfonic group the moon/nonionic wetting and penetrating agent 30~40%, separates many subtype non-ionic surface actives
Agent 10~30%, slightly water-wet double type nonionic surfactant 30~40%;(3) it is taken as the cloth of interior bed of cloth, general
Cloth impregnated in the solution containing nano zine oxide and be processed, and takes out after 3~6min and is placed in the surface plate of cleaning, and room temperature is done
It is dry;The preparation method containing nano oxidized zinc solution is:By network structure Zinc oxide particles, Dopamine Hydrochloride and Folic Acid are placed in
Hydrophobically modified is carried out in the mixed solution of preparation, modification time is 4~8h, and temperature is 65 ± 5 DEG C, and alcohol is washed, and is dried;Then prepare
The tetrahydrofuran solution of polystyrene, the consumption of polystyrene is the 1~2% of tetrahydrofuran quality, and by hydrophobic Zinc Oxide
Grain is dispersed wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out into hot pressing and obtains final product contton cloth;(5) cotton
Cloth antimicrobial treatment, contton cloth is put in 38~42 DEG C of antimicrobial fluid and is soaked 30 minutes, cold wind drying afterwards;(6) in cotton
Matter design on fabric surface pastes one layer of flame retardant coating by adhesive.
Wherein, the cloth is made up of outer bed of cloth and interior bed of cloth, and the outer bed of cloth is connected to interior cloth
The upper and lower surface of layer;The outer bed of cloth has hydrophilic after hydrophilic treated, and the interior cloth layer surface defines one kind
Possesses the hydrophobic film of the nanometer hierarchy of network, with hydrophobicity.
The concentration of the Dopamine Hydrochloride is 0.5~2.0mgmL-1, folic acid concentration is 0.2~1.0mgmL-1。
It is described that to separate many subtype nonionic surfactants be polynary in many vegetable oil acid esters of polynary polyoxyethylenated alcohol
Alcohol includes ethylene glycol, glycerol, two polyglycereol, trimethylolpropane, tetramethylolmethane, Sorbitol, anhydrous sorbitol.
Described double type sulfonic group the moon/nonionic wetting and penetrating agent its structural formula is expressed as:
In formula:R is iso-octyl or isomery tridecyl, and n is 1~5.
Vegetable oil acid in the double wine polyoxyethylene ether of the vegetable oil acid polyhydric alcohol includes the C12~C18 from vegetable oil
Saturation or unsaturated fatty acid;Its polyhydric alcohol includes:Glycerol, two polyglycereol, Sorbitol, anhydrous sorbitol.
The city that processes in (3) is laid in cloth in the surface plate of cleaning, draws a certain amount of molten containing nano zine oxide
Liquid is uniformly applied to design on fabric surface, drying at room temperature, you can.
The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid.
The flame retardant coating adopts CVC inflaming retarding fabrics, and the flame retardant coating thickness is 0.lmm.
In addition, the present invention is also claimed the fire resisting antibacterial contton cloth that methods described is prepared.
The present invention technique effect be:(1) after cloth of the invention is soaked in water, cloth internal layer is aoxidized by network structure
Zinc granule, Dopamine Hydrochloride and Folic Acid are provided with a kind of hydrophobicity of the nanometer hierarchy for possessing network in design on fabric surface
Thin film, will can quickly be expelled to cloth outer layer into the water of internal layer, and internal layer keeps dry and comfortable;(2) cloth of the present invention is soaked with organic
Silicon season presses salt antibacterial so that garment panel has preferable anti-microbial property;Cloth upper surface is provided with flame retardant coating, it is described resistance to
Fire bed adopt CVC inflaming retarding fabrics, with good fire retardant performance, can prevent flame from burning clothes, give people body provide compared with
Good flameproof effect.
Specific embodiment
Technical scheme is further elaborated with reference to embodiment:
Embodiment 1
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute
State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated,
The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity;
The preparation method of the contton cloth comprises the steps:(1) cloth that cotton fiber content is 100% is chosen, successively in ethanol
It is cleaned by ultrasonic 3 minutes with water, and is dried;(2) it is taken as the cloth of outer bed of cloth, cloth impregnated in and carry out in hydrophilizing agent parent
Water process, takes out after 3min and is placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group
The moon/nonionic wetting and penetrating agent 30%, separates many subtype nonionic surfactants 30%, slightly water-wet double type nonionic table
Face activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being located
Reason, takes out after 3min and is placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will
Network structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, modification time
For 4h, temperature is 655 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is four
The 1% of hydrogen furan quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) by above-mentioned outer bed of cloth and interior cloth
Layer carries out hot pressing and obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth
It is put in 40 DEG C of antimicrobial fluid and soaks 30 minutes, cold wind drying afterwards;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6)
One layer of flame retardant coating is pasted by adhesive on contton cloth surface;The flame retardant coating adopts CVC inflaming retarding fabrics, the fire resisting thickness
Spend for 0.lmm.
Embodiment 2
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute
State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated,
The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity;
The preparation method of the contton cloth comprises the steps:(1) choose the cloth that cotton fiber content is 80%, successively in ethanol and
It is cleaned by ultrasonic 3 minutes in water, and is dried;(2) be taken as the cloth of outer bed of cloth, cloth impregnated in carry out in hydrophilizing agent it is hydrophilic
Process, take out after 6min and be placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group the moon/
Nonionic wetting and penetrating agent 40%, separates many subtype nonionic surfactants 20%, slightly water-wet double type non-ionic surface
Activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being processed,
Take out after 6min and be placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will be netted
Structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, and modification time is 8h,
Temperature is 70 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is tetrahydrofuran
The 2% of quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out
Hot pressing obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth 38 are put into
DEG C antimicrobial fluid in soak 30 minutes, afterwards cold wind drying;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6) in cotton
Design on fabric surface pastes one layer of flame retardant coating by adhesive;The flame retardant coating adopts CVC inflaming retarding fabrics, and the flame retardant coating thickness is
0.lmm。
Embodiment 3
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute
State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated,
The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity;
The preparation method of the contton cloth comprises the steps:(1) choose the cloth that cotton fiber content is 90%, successively in ethanol and
It is cleaned by ultrasonic 3 minutes in water, and is dried;(2) be taken as the cloth of outer bed of cloth, cloth impregnated in carry out in hydrophilizing agent it is hydrophilic
Process, take out after 3~6min and be placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group
The moon/nonionic wetting and penetrating agent 35%, separates many subtype nonionic surfactants 25%, slightly water-wet double type nonionic table
Face activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being located
Reason, takes out after 5min and is placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will
Network structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, modification time
For 6h, temperature is 68 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is tetrahydrochysene
The 1.5% of furan quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) by above-mentioned outer bed of cloth and interior cloth
Layer carries out hot pressing and obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth
It is put in 42 DEG C of antimicrobial fluid and soaks 30 minutes, cold wind drying afterwards;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6)
One layer of flame retardant coating is pasted by adhesive on contton cloth surface;The flame retardant coating adopts CVC inflaming retarding fabrics, the fire resisting thickness
Spend for 0.lmm.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, the present invention is not limited to,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
To modify to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in the present invention's
Within protection domain.
Claims (10)
1. a kind of preparation method of fire resisting antibacterial contton cloth, it is characterised in that comprise the steps:(1) choose cotton fiber to contain
The cloth for 80~100% is measured, is cleaned by ultrasonic 3 minutes in second alcohol and water successively, and be dried;(2) it is taken as outer bed of cloth
Cloth, cloth impregnated in and carry out in hydrophilizing agent hydrophilic treated, takes out after 3~6min and is placed in the surface plate of cleaning, and room temperature is done
It is dry;The hydrophilizing agent is consisted of:Double type sulfonic group the moon/nonionic wetting and penetrating agent 30~40%, separate many subtypes it is non-from
Sub- surfactant 10~30%, slightly water-wet double type nonionic surfactant 30~40%;(3) it is taken as interior bed of cloth
Cloth, cloth impregnated in the solution containing nano zine oxide and processed, take out after 3~6min and be placed in the surface plate of cleaning
In, drying at room temperature;The preparation method containing nano oxidized zinc solution is:By network structure Zinc oxide particles, hydrochloric acid is placed in many
Hydrophobically modified is carried out in the mixed solution that bar amine and Folic Acid are prepared, modification time is 4~8h, and temperature is 65 ± 5 DEG C, and alcohol is washed, and is done
It is dry;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is the 1~2% of tetrahydrofuran quality, and will be dredged
Water Zinc Oxide even particulate dispersion is wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out into hot pressing and obtains final product cotton cloth
Material;(5) contton cloth antimicrobial treatment, contton cloth is put in 38~42 DEG C of antimicrobial fluid and is soaked 30 minutes, cold wind baking afterwards
It is dry;(6) one layer of flame retardant coating is pasted by adhesive on contton cloth surface.
2. the preparation method of contton cloth according to claim 1, it is characterised in that:The cloth is by outer bed of cloth and Nei Bu
The bed of material is constituted, and the outer bed of cloth is connected to the upper and lower surface of interior bed of cloth;The outer bed of cloth is through hydrophilic treated
There is afterwards hydrophilic, it is thin that the interior cloth layer surface defines a kind of hydrophobicity of the nanometer hierarchy for possessing network
Film, with hydrophobicity.
3. the preparation method of contton cloth according to claim 1, it is characterised in that:The concentration of the Dopamine Hydrochloride is
0.5~2.0mgmL-1, folic acid concentration is 0.2~1.0mgmL-1。
4. the preparation method of contton cloth according to claim 1, it is characterised in that:The double type sulfonic group is cloudy/it is non-from
Sub- wetting and penetrating agent its structural formula is expressed as:
In formula:R is iso-octyl or isomery tridecyl, and n is 1~5.
5. the preparation method of contton cloth according to claim 1, it is characterised in that:It is described to separate many subtype non-ionic surfaces
Activating agent is that the polyhydric alcohol in many vegetable oil acid esters of polynary polyoxyethylenated alcohol includes ethylene glycol, glycerol, two polyglycereol, three hydroxyl first
Base propane, tetramethylolmethane, Sorbitol, anhydrous sorbitol.
6. the preparation method of contton cloth according to claim 1, it is characterised in that:The double wine polyoxy second of vegetable oil acid polyhydric alcohol
Vegetable oil acid in alkene ether includes satisfying and/or unsaturated fatty acid from the C12~C18 of vegetable oil;Its polyhydric alcohol includes:It is sweet
Oil, two polyglycereol, Sorbitol, anhydrous sorbitol.
7. the preparation method of contton cloth according to claim 1, it is characterised in that:Process in (3) is by cloth
In being laid in the surface plate of cleaning, draw it is a certain amount of be uniformly applied to design on fabric surface containing nano oxidized zinc solution, drying at room temperature, i.e.,
Can.
8. the preparation method of contton cloth according to claim 1, it is characterised in that:The antimicrobial fluid is organosilicon quaternary ammonium salt
Antimicrobial fluid.
9. the preparation method of contton cloth according to claim 1, it is characterised in that:The flame retardant coating adopts the fire-retardant faces of CVC
Material, the flame retardant coating thickness is 0.lmm.
10. the fire resisting antibacterial contton cloth that a kind of any one of claim 1-9 methods described is prepared.
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CN109098002A (en) * | 2018-08-17 | 2018-12-28 | 深圳市南硕明泰科技有限公司 | A kind of fire resisting antibacterial contton cloth and preparation method thereof |
CN110644239A (en) * | 2019-10-31 | 2020-01-03 | 南昌大学附属口腔医院(江西省口腔医院) | Antibacterial polylactic acid nanofiber and preparation method and application thereof |
CN113604965A (en) * | 2021-08-25 | 2021-11-05 | 郑广翔 | Non-woven fabric and preparation method thereof |
CN115434158A (en) * | 2021-06-05 | 2022-12-06 | 海宁德易遮阳科技有限公司 | Preparation method of antibacterial shading curtain fabric |
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CN113604965B (en) * | 2021-08-25 | 2022-08-23 | 辽宁洁花环保科技装备有限公司 | Non-woven fabric and preparation method thereof |
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