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CN106592250A - Fireproof antibacterial cotton cloth and making method thereof - Google Patents

Fireproof antibacterial cotton cloth and making method thereof Download PDF

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Publication number
CN106592250A
CN106592250A CN201611143236.6A CN201611143236A CN106592250A CN 106592250 A CN106592250 A CN 106592250A CN 201611143236 A CN201611143236 A CN 201611143236A CN 106592250 A CN106592250 A CN 106592250A
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cloth
contton
preparation
bed
layer
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不公告发明人
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Foshan Jucheng Biochemical Technology Research and Development Co Ltd
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Priority to CN201611143236.6A priority Critical patent/CN106592250A/en
Publication of CN106592250A publication Critical patent/CN106592250A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention provides fireproof antibacterial cotton cloth and a making method thereof. An outer cloth layer has hydrophility after going through hydrophilic treatment, and a hydrophobic thin film of a nano grading structure with a grid structure is formed on the surface of an inner cloth layer, so that the inner cloth layer has hydrophobicity. After the cloth is wetted, the hydrophobic thin film of the nano grading structure with the grid structure is arranged on the surface of the inner cloth layer through reticular-structure zinc oxide particles, dopamine hydrochloride and folic acid and can quickly discharge water entering the inner cloth layer to the outer cloth layer, so that the inner cloth layer is maintained dry and comfortable. In addition, the cloth is uniformly immersed with organosilicon quaternary ammonium salt antibacterial agent, thereby having good antibacterial performance; a fireproof layer is arranged on the surface of the cloth and made of CVC flame-retardant fabric, so that the cloth has good fireproof and flame-retardant performance, can prevent flame from burning clothes and provides good fireproof effect for human body.

Description

A kind of fire resisting antibacterial contton cloth and preparation method thereof
Technical field
The invention belongs to cloth processing technique field, more particularly to a kind of fire resisting antibacterial contton cloth and its preparation side Method.
Background technology
Cloth is one of the most frequently used means of livelihood of people, people using cloth make medicated clothing, ornaments, packaging material etc. by Come for a long time, the life that the utilization of cloth gives people brings great convenience.But be present a shortcoming in current cloth, exactly prevent Aqueouss are not enough, such as medicated clothing etc. is often got wet by rainwater or other water, and people's life is brought inconvenience.When people utilize cloth bag To contain during article, the problems referred to above can also cause the consequence that article is drenched in cloth bag.Also there is many in prior art with regard to cloth The research report of material, CN100595373A discloses a kind of preparation method of ultra-hydrophobic cloth, selects the cotton containing 80-100% The cloth of fiber, using being impregnated in gold chloride and citric acid mixed solution, then at once turns the cloth containing reactant liquor Move on in baking oven and heat, 6-8 hours in the ethanol solution of lauryl mercaptan are immersed afterwards, ultra-hydrophobic cloth is obtained; CN103669025A discloses a kind of strong water absorption cloth, described strong water absorption cloth by polyacrylonitrile, Zhu's flaxen fiber, The four kinds of fiber blend braidings of cuprammonium silk fiber and cashmere fibres are formed;CN105734973A discloses a kind of waterproof cloth Processing technique, first receives VAE emulsions, acrylic emulsion, gelatin Alumen, benzenesulfonic acid, balance of water, after heating 30 minutes or so Natural cooling;Then cloth is soaked 30 minutes wherein after cleaning, and is dried after dehydration, finally one layer is arranged on cloth and is prevented Water layer;CN102660870A discloses a kind of preparation method of oil-water separation cloth, first by sodium hydroxide and six nitric hydrates Zinc granule is successively added to the water, magnetic agitation 12-24h at 75 ± 5 DEG C, washing, and centrifugation is dried;The Zinc oxide particles for obtaining, Hydrophobically modified is carried out using stearic acid, the tetrahydrofuran solution of polystyrene is then prepared, and hydrophobic Zinc oxide particles are uniform Dispersion wherein, is finally dipped in cloth in above-mentioned solution, takes out after 1-3min and is placed in the surface plate of cleaning, drying at room temperature, i.e., Obtain oil-water separation cloth;But more or less there is such or such shortcoming in above-mentioned cloth, there is one in actual applications Fixed defect, needs to further improve.
In addition, at present people can wear clothes daily in the study of various occasions, work, life, will connect between not feeling in vain Various antibacterials are contacted, long-term accumulated enrichment can produce harm to the health of human body.It is also and people's shape shadow in life moderate heat simultaneously Not from, the class that fire can give people causes greatly loss, or even threat to life, and the loss caused by fire is inestimable, in order to The safety of the protection public, reduces the loss that fire causes, it is necessary to provide a kind of cloth with fire protecting performance, when generation fire Or the intensity of a fire is produced when threatening to personal safety and property safety, can play certain protective action, and injures and deaths and loss are reduced.
The content of the invention
To solve the above problems, the technical solution used in the present invention is:
A kind of preparation method of fire resisting antibacterial contton cloth, comprises the steps:(1) choose cotton fiber content be 80~ 100% cloth, is cleaned by ultrasonic 3 minutes successively in second alcohol and water, and is dried;(2) it is taken as the cloth of outer bed of cloth, by cloth Material impregnated in and carry out in hydrophilizing agent hydrophilic treated, takes out after 3~6min and is placed in the surface plate of cleaning, drying at room temperature;The parent Water preparation is consisted of:Double type sulfonic group the moon/nonionic wetting and penetrating agent 30~40%, separates many subtype non-ionic surface actives Agent 10~30%, slightly water-wet double type nonionic surfactant 30~40%;(3) it is taken as the cloth of interior bed of cloth, general Cloth impregnated in the solution containing nano zine oxide and be processed, and takes out after 3~6min and is placed in the surface plate of cleaning, and room temperature is done It is dry;The preparation method containing nano oxidized zinc solution is:By network structure Zinc oxide particles, Dopamine Hydrochloride and Folic Acid are placed in Hydrophobically modified is carried out in the mixed solution of preparation, modification time is 4~8h, and temperature is 65 ± 5 DEG C, and alcohol is washed, and is dried;Then prepare The tetrahydrofuran solution of polystyrene, the consumption of polystyrene is the 1~2% of tetrahydrofuran quality, and by hydrophobic Zinc Oxide Grain is dispersed wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out into hot pressing and obtains final product contton cloth;(5) cotton Cloth antimicrobial treatment, contton cloth is put in 38~42 DEG C of antimicrobial fluid and is soaked 30 minutes, cold wind drying afterwards;(6) in cotton Matter design on fabric surface pastes one layer of flame retardant coating by adhesive.
Wherein, the cloth is made up of outer bed of cloth and interior bed of cloth, and the outer bed of cloth is connected to interior cloth The upper and lower surface of layer;The outer bed of cloth has hydrophilic after hydrophilic treated, and the interior cloth layer surface defines one kind Possesses the hydrophobic film of the nanometer hierarchy of network, with hydrophobicity.
The concentration of the Dopamine Hydrochloride is 0.5~2.0mgmL-1, folic acid concentration is 0.2~1.0mgmL-1
It is described that to separate many subtype nonionic surfactants be polynary in many vegetable oil acid esters of polynary polyoxyethylenated alcohol Alcohol includes ethylene glycol, glycerol, two polyglycereol, trimethylolpropane, tetramethylolmethane, Sorbitol, anhydrous sorbitol.
Described double type sulfonic group the moon/nonionic wetting and penetrating agent its structural formula is expressed as:
In formula:R is iso-octyl or isomery tridecyl, and n is 1~5.
Vegetable oil acid in the double wine polyoxyethylene ether of the vegetable oil acid polyhydric alcohol includes the C12~C18 from vegetable oil Saturation or unsaturated fatty acid;Its polyhydric alcohol includes:Glycerol, two polyglycereol, Sorbitol, anhydrous sorbitol.
The city that processes in (3) is laid in cloth in the surface plate of cleaning, draws a certain amount of molten containing nano zine oxide Liquid is uniformly applied to design on fabric surface, drying at room temperature, you can.
The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid.
The flame retardant coating adopts CVC inflaming retarding fabrics, and the flame retardant coating thickness is 0.lmm.
In addition, the present invention is also claimed the fire resisting antibacterial contton cloth that methods described is prepared.
The present invention technique effect be:(1) after cloth of the invention is soaked in water, cloth internal layer is aoxidized by network structure Zinc granule, Dopamine Hydrochloride and Folic Acid are provided with a kind of hydrophobicity of the nanometer hierarchy for possessing network in design on fabric surface Thin film, will can quickly be expelled to cloth outer layer into the water of internal layer, and internal layer keeps dry and comfortable;(2) cloth of the present invention is soaked with organic Silicon season presses salt antibacterial so that garment panel has preferable anti-microbial property;Cloth upper surface is provided with flame retardant coating, it is described resistance to Fire bed adopt CVC inflaming retarding fabrics, with good fire retardant performance, can prevent flame from burning clothes, give people body provide compared with Good flameproof effect.
Specific embodiment
Technical scheme is further elaborated with reference to embodiment:
Embodiment 1
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated, The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity; The preparation method of the contton cloth comprises the steps:(1) cloth that cotton fiber content is 100% is chosen, successively in ethanol It is cleaned by ultrasonic 3 minutes with water, and is dried;(2) it is taken as the cloth of outer bed of cloth, cloth impregnated in and carry out in hydrophilizing agent parent Water process, takes out after 3min and is placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group The moon/nonionic wetting and penetrating agent 30%, separates many subtype nonionic surfactants 30%, slightly water-wet double type nonionic table Face activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being located Reason, takes out after 3min and is placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will Network structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, modification time For 4h, temperature is 655 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is four The 1% of hydrogen furan quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) by above-mentioned outer bed of cloth and interior cloth Layer carries out hot pressing and obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth It is put in 40 DEG C of antimicrobial fluid and soaks 30 minutes, cold wind drying afterwards;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6) One layer of flame retardant coating is pasted by adhesive on contton cloth surface;The flame retardant coating adopts CVC inflaming retarding fabrics, the fire resisting thickness Spend for 0.lmm.
Embodiment 2
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated, The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity; The preparation method of the contton cloth comprises the steps:(1) choose the cloth that cotton fiber content is 80%, successively in ethanol and It is cleaned by ultrasonic 3 minutes in water, and is dried;(2) be taken as the cloth of outer bed of cloth, cloth impregnated in carry out in hydrophilizing agent it is hydrophilic Process, take out after 6min and be placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group the moon/ Nonionic wetting and penetrating agent 40%, separates many subtype nonionic surfactants 20%, slightly water-wet double type non-ionic surface Activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being processed, Take out after 6min and be placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will be netted Structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, and modification time is 8h, Temperature is 70 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is tetrahydrofuran The 2% of quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out Hot pressing obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth 38 are put into DEG C antimicrobial fluid in soak 30 minutes, afterwards cold wind drying;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6) in cotton Design on fabric surface pastes one layer of flame retardant coating by adhesive;The flame retardant coating adopts CVC inflaming retarding fabrics, and the flame retardant coating thickness is 0.lmm。
Embodiment 3
A kind of hydrophobic contton cloth of outer layer hydrophilic inner layer, the cloth is made up of outer bed of cloth and interior bed of cloth, institute State the upper and lower surface that outer bed of cloth is connected to interior bed of cloth;The outer bed of cloth has hydrophilic after hydrophilic treated, The interior cloth layer surface defines a kind of hydrophobic film of the nanometer hierarchy for possessing network, with hydrophobicity; The preparation method of the contton cloth comprises the steps:(1) choose the cloth that cotton fiber content is 90%, successively in ethanol and It is cleaned by ultrasonic 3 minutes in water, and is dried;(2) be taken as the cloth of outer bed of cloth, cloth impregnated in carry out in hydrophilizing agent it is hydrophilic Process, take out after 3~6min and be placed in the surface plate of cleaning, drying at room temperature;The hydrophilizing agent is consisted of:Double type sulfonic group The moon/nonionic wetting and penetrating agent 35%, separates many subtype nonionic surfactants 25%, slightly water-wet double type nonionic table Face activating agent 40%;(3) it is taken as the cloth of interior bed of cloth, cloth impregnated in the solution containing nano zine oxide and being located Reason, takes out after 5min and is placed in the surface plate of cleaning, drying at room temperature;The preparation method containing nano oxidized zinc solution is:Will Network structure Zinc oxide particles, being placed in the mixed solution that Dopamine Hydrochloride and Folic Acid are prepared carries out hydrophobically modified, modification time For 6h, temperature is 68 DEG C, and alcohol is washed, and is dried;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is tetrahydrochysene The 1.5% of furan quality, and hydrophobic Zinc oxide particles are dispersed wherein;(4) by above-mentioned outer bed of cloth and interior cloth Layer carries out hot pressing and obtains final product the hydrophobic contton cloth of the outer layer hydrophilic inner layer;(5) contton cloth antimicrobial treatment, by contton cloth It is put in 42 DEG C of antimicrobial fluid and soaks 30 minutes, cold wind drying afterwards;The antimicrobial fluid is organosilicon quaternary ammonium salt antimicrobial fluid;(6) One layer of flame retardant coating is pasted by adhesive on contton cloth surface;The flame retardant coating adopts CVC inflaming retarding fabrics, the fire resisting thickness Spend for 0.lmm.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, the present invention is not limited to, Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used To modify to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic. All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in the present invention's Within protection domain.

Claims (10)

1. a kind of preparation method of fire resisting antibacterial contton cloth, it is characterised in that comprise the steps:(1) choose cotton fiber to contain The cloth for 80~100% is measured, is cleaned by ultrasonic 3 minutes in second alcohol and water successively, and be dried;(2) it is taken as outer bed of cloth Cloth, cloth impregnated in and carry out in hydrophilizing agent hydrophilic treated, takes out after 3~6min and is placed in the surface plate of cleaning, and room temperature is done It is dry;The hydrophilizing agent is consisted of:Double type sulfonic group the moon/nonionic wetting and penetrating agent 30~40%, separate many subtypes it is non-from Sub- surfactant 10~30%, slightly water-wet double type nonionic surfactant 30~40%;(3) it is taken as interior bed of cloth Cloth, cloth impregnated in the solution containing nano zine oxide and processed, take out after 3~6min and be placed in the surface plate of cleaning In, drying at room temperature;The preparation method containing nano oxidized zinc solution is:By network structure Zinc oxide particles, hydrochloric acid is placed in many Hydrophobically modified is carried out in the mixed solution that bar amine and Folic Acid are prepared, modification time is 4~8h, and temperature is 65 ± 5 DEG C, and alcohol is washed, and is done It is dry;Then the tetrahydrofuran solution of polystyrene is prepared, the consumption of polystyrene is the 1~2% of tetrahydrofuran quality, and will be dredged Water Zinc Oxide even particulate dispersion is wherein;(4) above-mentioned outer bed of cloth and interior bed of cloth are carried out into hot pressing and obtains final product cotton cloth Material;(5) contton cloth antimicrobial treatment, contton cloth is put in 38~42 DEG C of antimicrobial fluid and is soaked 30 minutes, cold wind baking afterwards It is dry;(6) one layer of flame retardant coating is pasted by adhesive on contton cloth surface.
2. the preparation method of contton cloth according to claim 1, it is characterised in that:The cloth is by outer bed of cloth and Nei Bu The bed of material is constituted, and the outer bed of cloth is connected to the upper and lower surface of interior bed of cloth;The outer bed of cloth is through hydrophilic treated There is afterwards hydrophilic, it is thin that the interior cloth layer surface defines a kind of hydrophobicity of the nanometer hierarchy for possessing network Film, with hydrophobicity.
3. the preparation method of contton cloth according to claim 1, it is characterised in that:The concentration of the Dopamine Hydrochloride is 0.5~2.0mgmL-1, folic acid concentration is 0.2~1.0mgmL-1
4. the preparation method of contton cloth according to claim 1, it is characterised in that:The double type sulfonic group is cloudy/it is non-from Sub- wetting and penetrating agent its structural formula is expressed as:
In formula:R is iso-octyl or isomery tridecyl, and n is 1~5.
5. the preparation method of contton cloth according to claim 1, it is characterised in that:It is described to separate many subtype non-ionic surfaces Activating agent is that the polyhydric alcohol in many vegetable oil acid esters of polynary polyoxyethylenated alcohol includes ethylene glycol, glycerol, two polyglycereol, three hydroxyl first Base propane, tetramethylolmethane, Sorbitol, anhydrous sorbitol.
6. the preparation method of contton cloth according to claim 1, it is characterised in that:The double wine polyoxy second of vegetable oil acid polyhydric alcohol Vegetable oil acid in alkene ether includes satisfying and/or unsaturated fatty acid from the C12~C18 of vegetable oil;Its polyhydric alcohol includes:It is sweet Oil, two polyglycereol, Sorbitol, anhydrous sorbitol.
7. the preparation method of contton cloth according to claim 1, it is characterised in that:Process in (3) is by cloth In being laid in the surface plate of cleaning, draw it is a certain amount of be uniformly applied to design on fabric surface containing nano oxidized zinc solution, drying at room temperature, i.e., Can.
8. the preparation method of contton cloth according to claim 1, it is characterised in that:The antimicrobial fluid is organosilicon quaternary ammonium salt Antimicrobial fluid.
9. the preparation method of contton cloth according to claim 1, it is characterised in that:The flame retardant coating adopts the fire-retardant faces of CVC Material, the flame retardant coating thickness is 0.lmm.
10. the fire resisting antibacterial contton cloth that a kind of any one of claim 1-9 methods described is prepared.
CN201611143236.6A 2016-12-12 2016-12-12 Fireproof antibacterial cotton cloth and making method thereof Pending CN106592250A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109098002A (en) * 2018-08-17 2018-12-28 深圳市南硕明泰科技有限公司 A kind of fire resisting antibacterial contton cloth and preparation method thereof
CN110644239A (en) * 2019-10-31 2020-01-03 南昌大学附属口腔医院(江西省口腔医院) Antibacterial polylactic acid nanofiber and preparation method and application thereof
CN113604965A (en) * 2021-08-25 2021-11-05 郑广翔 Non-woven fabric and preparation method thereof
CN115434158A (en) * 2021-06-05 2022-12-06 海宁德易遮阳科技有限公司 Preparation method of antibacterial shading curtain fabric

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CN102660870A (en) * 2012-05-24 2012-09-12 东北林业大学 Preparation method of oil-water separation fabric
CN103522636A (en) * 2013-10-21 2014-01-22 哈建薇 Anti-static fireproof antibacterial warm-keeping cloth material
CN105316944A (en) * 2015-11-26 2016-02-10 常州市灵达化学品有限公司 Longitudinal permeation type multiple-time hydrophilc agent of polyolefin non-woven fabric

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CN1973081B (en) * 2004-05-21 2010-10-06 广东溢达纺织有限公司 Abnormal pure cotton quick-drying fabric at inner layer and outer layer, and process for producing the same
US7807589B2 (en) * 2006-10-25 2010-10-05 Chian Yu Technologies Company Ltd. Method for manufacturing polyacrylonitrile fiber cloth and fireproof cloth made of such cloth
CN102660870A (en) * 2012-05-24 2012-09-12 东北林业大学 Preparation method of oil-water separation fabric
CN103522636A (en) * 2013-10-21 2014-01-22 哈建薇 Anti-static fireproof antibacterial warm-keeping cloth material
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109098002A (en) * 2018-08-17 2018-12-28 深圳市南硕明泰科技有限公司 A kind of fire resisting antibacterial contton cloth and preparation method thereof
CN110644239A (en) * 2019-10-31 2020-01-03 南昌大学附属口腔医院(江西省口腔医院) Antibacterial polylactic acid nanofiber and preparation method and application thereof
CN115434158A (en) * 2021-06-05 2022-12-06 海宁德易遮阳科技有限公司 Preparation method of antibacterial shading curtain fabric
CN115434158B (en) * 2021-06-05 2023-11-10 海宁德易遮阳科技有限公司 Preparation method of antibacterial shading curtain fabric
CN113604965A (en) * 2021-08-25 2021-11-05 郑广翔 Non-woven fabric and preparation method thereof
CN113604965B (en) * 2021-08-25 2022-08-23 辽宁洁花环保科技装备有限公司 Non-woven fabric and preparation method thereof

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Application publication date: 20170426