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CN106577709A - Pesticide compound containing cyhalodiamide and hexaflumuron - Google Patents

Pesticide compound containing cyhalodiamide and hexaflumuron Download PDF

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Publication number
CN106577709A
CN106577709A CN201510680598.8A CN201510680598A CN106577709A CN 106577709 A CN106577709 A CN 106577709A CN 201510680598 A CN201510680598 A CN 201510680598A CN 106577709 A CN106577709 A CN 106577709A
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pesticidal combination
agent
hexaflumuron
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insecticide
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袁静
董德臻
朱冰春
郁季平
孔小林
陈杰
邢家华
许勇华
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Zhejiang Chemical Industry Research Institute Co Ltd
Sinochem Lantian Co Ltd
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Zhejiang Chemical Industry Research Institute Co Ltd
Sinochem Lantian Co Ltd
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Abstract

本发明提供了一种用于农业害虫的含有氯氟氰虫酰胺和氟铃脲的杀虫组合物,且氯氟氰虫酰胺与氟铃脲的重量比为50:1~1:50。本发明提供的杀虫组合物高效、低毒且持效期长,可有效防治农作物鳞翅目害虫。The invention provides an insecticidal composition containing cyantraniliprole and hexaflumuron for agricultural pests, and the weight ratio of cyantraniliprole to hexaflumuron is 50:1-1:50. The insecticidal composition provided by the invention has high efficiency, low toxicity and long duration, and can effectively prevent and control crop Lepidoptera pests.

Description

一种含氯氟氰虫酰胺和氟铃脲的杀虫组合物A kind of insecticidal composition containing cyantraniliprole and hexaflumuron

技术领域technical field

本发明属于农药领域,具体涉及一种含氯氟氰虫酰胺和氟铃脲的杀虫组合物。The invention belongs to the field of pesticides, in particular to an insecticidal composition containing cyantraniliprole and hexaflumuron.

背景技术Background technique

农业害虫的抗性问题是一个全球性的问题。随着害虫化学防治的的延续、农药使用量的增加以及不科学使用农药,害虫抗性日益严重,产生抗性的害虫种类不断增多。特别是对农业生产为害严重的鳞翅目类害虫,抗性程度较高,抗性发展速度相对较快。同时,高强度的使用农药,导致农产品农药残留超标、环境污染和农民用药成本增加等,不利于农业可持续发展。因此,研究开发高效、低毒、环保的杀虫剂农药对农业可持续发展具有积极意义。The problem of resistance to agricultural pests is a global problem. With the continuation of chemical control of pests, the increase in the use of pesticides, and the unscientific use of pesticides, the resistance of pests is becoming more and more serious, and the types of resistant pests are increasing. Especially the lepidopteran pests that seriously damage agricultural production have a high degree of resistance and relatively fast development of resistance. At the same time, the high-intensity use of pesticides leads to excessive pesticide residues in agricultural products, environmental pollution and increased costs of pesticides for farmers, which is not conducive to the sustainable development of agriculture. Therefore, the research and development of high-efficiency, low-toxicity, and environmental-friendly insecticides and pesticides has positive significance for the sustainable development of agriculture.

氟铃脲(Hexaflumuron)是苯甲酰脲类昆虫生长调节剂,通过抑制昆虫几丁质合成而杀死害虫。具有杀虫活性高、杀虫谱较广、击倒力强等特点。Hexaflumuron is a benzoylurea insect growth regulator that kills pests by inhibiting insect chitin synthesis. It has the characteristics of high insecticidal activity, wide insecticidal spectrum and strong knockdown power.

氯氟氰虫酰胺是浙江省化工研究院自行研制的新型杀虫剂,代号ZJ4042,化学名称为:3-氯-N1-(2-甲基-4-七氟异丙基苯基)-N2-(1-甲基-1-氰基乙基)邻苯二甲酰胺,结构式如下(I)所示:Cyantraniliprole is a new type of insecticide developed by Zhejiang Research Institute of Chemical Industry, code ZJ4042, chemical name: 3-chloro-N 1 -(2-methyl-4-heptafluoroisopropylphenyl)- N 2 -(1-methyl-1-cyanoethyl)phthalamide, the structural formula is as shown in (I):

该杀虫剂属新型邻苯二甲酰胺类杀虫剂,通过激活兰尼碱受体细胞内钙释放通道,导致贮存钙离子的失控性释放,是目前为数不多的作用于昆虫细胞兰尼碱(Ryanodine)受体的化合物。对鳞翅目害虫有广谱防效。The insecticide is a new type of phthalamide insecticide. It activates the intracellular calcium release channel of the ryanodine receptor, leading to the uncontrolled release of stored calcium ions. Alkaline (Ryanodine) receptor compounds. It has broad-spectrum control effect on Lepidoptera pests.

氯氟氰虫酰胺单独使用时用药成本较高,在一定程度上限制了其推广应用。氟铃脲用量较大,长期单独使用容易造成害虫抗性程度不断增加。因此,将氯氟氰虫酰胺和氟铃脲进行混配,是一种防治农业抗性害虫的有效方法。The cost of cyantraniliprole alone is relatively high, which limits its popularization and application to a certain extent. The dosage of hexaflumuron is large, and long-term single use will easily lead to the continuous increase of pest resistance. Therefore, mixing cyantraniliprole and hexaflumuron is an effective method to control agricultural resistant pests.

发明内容Contents of the invention

本发明要解决的技术问题是提供一种高效、低毒且持效期长、可有效防治农作物鳞翅目害虫的杀虫组合物,有利于害虫的综合治理。The technical problem to be solved by the present invention is to provide a high-efficiency, low-toxicity and long-lasting insecticidal composition that can effectively prevent and control crop Lepidoptera pests, which is beneficial to the comprehensive management of pests.

为解决上述问题,本发明所采用的技术方案是:In order to solve the above problems, the technical solution adopted in the present invention is:

一种用于农业害虫的杀虫组合物,其特征在于所述杀虫组合物含有氯氟氰虫酰胺和氟铃脲,且氯氟氰虫酰胺与氟铃脲的重量比为50:1~1:50。An insecticidal composition for agricultural pests, characterized in that the insecticidal composition contains cyantraniliprole and hexaflumuron, and the weight ratio of cyantraniliprole and hexaflumuron is 50:1~ 1:50.

本发明使用的氯氟氰虫酰胺,即为上述结构式(I)所示的化合物。The cyantraniliprole used in the present invention is the compound shown in the above structural formula (I).

本发明所述杀虫组合物,氯氟氰虫酰胺和氟铃脲作为活性成分。优选的是,氯氟氰虫酰胺与氟铃脲的重量比为20:1~1:20。进一步优选的是,氯氟氰虫酰胺与氟铃脲的重量比为5:1~1:9。In the insecticidal composition of the present invention, cyantraniliprole and hexaflumuron are used as active ingredients. Preferably, the weight ratio of cyantraniliprole to hexaflumuron is 20:1-1:20. More preferably, the weight ratio of cyantraniliprole to hexaflumuron is 5:1-1:9.

本发明还提供了一种用于农业害虫的杀虫剂,以重量计含有0.5~80%上述杀虫组合物,其余为农业上可接受的载体和助剂。作为优选的实施方式,杀虫剂中优选含有5~40%的上述杀虫组合物。The present invention also provides an insecticide for agricultural pests, which contains 0.5-80% of the above-mentioned insecticidal composition by weight, and the rest are agriculturally acceptable carriers and assistants. As a preferred embodiment, the insecticide preferably contains 5 to 40% of the above insecticidal composition.

本发明所述的载体可以是固体或液体,通常用于配制杀虫剂组合物的任何载体均能使用。The carrier of the present invention can be solid or liquid, and any carrier commonly used for preparing pesticide compositions can be used.

合适的固体载体包括:矿物类,植物类,合成填料类和无机盐类。其中矿物类包括硅酸盐类,碳酸盐类,硫酸盐类和氧化物类。硅酸盐类例如高岭土,海泡石,珍珠陶土,蒙脱土,云母,蛭石,叶蜡石,滑石。碳酸盐类例如:碳酸钙,白云石。硫酸盐类如硫酸铵,硫酸钠,硫酸钙。氧化物类如生石灰,镁石灰,硅藻土。植物类例如:柑橘渣,玉米棒芯,谷壳粉,稻壳,大豆秸粉,烟草粉,胡桃壳,锯木粉。合成填料类如沉淀碳酸钙水合物,沉淀碳酸钙,白炭黑。无机盐类例如氯化钾,氯化钠。Suitable solid carriers include: minerals, plants, synthetic fillers and inorganic salts. The minerals include silicates, carbonates, sulfates and oxides. Silicates such as kaolin, sepiolite, nacrite, montmorillonite, mica, vermiculite, pyrophyllite, talc. Carbonates such as: calcium carbonate, dolomite. Sulfates such as ammonium sulfate, sodium sulfate, calcium sulfate. Oxides such as quicklime, magnesium lime, diatomaceous earth. Vegetables such as: citrus pomace, corn cob, chaff powder, rice husk, soybean straw powder, tobacco powder, walnut shell, sawdust. Synthetic fillers such as precipitated calcium carbonate hydrate, precipitated calcium carbonate, white carbon black. Inorganic salts such as potassium chloride, sodium chloride.

液体载体包括水和有机溶剂。当有效成分为水乳剂或悬乳剂时,有机溶剂起到增溶和防冻作用。合适的有机溶剂包括芳烃,例如苯、二甲苯、甲苯、烷基苯、烷基萘和氯代芳烃;氯代脂肪烃,例如氯乙烯、三氯甲烷、二氯甲烷、氯仿、四氯化碳和多氯乙烷;脂肪烃,例如石油馏分、环己烷、轻质矿物油和石蜡。醇类例如甲醇,乙醇,异丙醇、丁醇、异丁醇,乙二醇、丙二醇、丙三醇、脂肪醇等;醚类例如甲基乙二醇醚,乙基乙二醇醚,石油醚。酮类例如丙酮、甲乙酮、甲基异丁基酮、环己酮以及异氟尔酮、N-甲基-吡咯烷酮;特种溶剂还有二甲基甲酰胺,二甲基亚砜,聚乙二醇,已腈;植物油及甲基化植物油。上述有机溶剂既可以单独使用,也可以混合使用,还可以与水一起混合使用。Liquid carriers include water and organic solvents. When the active ingredient is water emulsion or suspoemulsion, the organic solvent plays the role of solubilization and antifreeze. Suitable organic solvents include aromatics such as benzene, xylene, toluene, alkylbenzenes, alkylnaphthalenes, and chlorinated aromatics; chlorinated aliphatics such as vinyl chloride, chloroform, methylene chloride, chloroform, carbon tetrachloride and polychloroethanes; aliphatic hydrocarbons such as petroleum distillates, cyclohexane, light mineral oils and paraffins. Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, propylene glycol, glycerol, fatty alcohols, etc.; ethers such as methyl glycol ether, ethyl glycol ether, petroleum ether. Ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and isophorone, N-methyl-pyrrolidone; special solvents also include dimethylformamide, dimethyl sulfoxide, polyethylene glycol , has been nitrile; vegetable oil and methylated vegetable oil. The above-mentioned organic solvents may be used alone, or in combination, or in combination with water.

本发明所述助剂可以根据需要包括表面活性剂、消泡剂、增稠剂、助悬剂和防冻剂中的一种或几种,还可以根据需要包括本行业常用的其他助剂。The auxiliary agent of the present invention may include one or more of surfactants, defoamers, thickeners, suspending agents and antifreezing agents as required, and may also include other auxiliary agents commonly used in this industry as required.

表面活性剂可以是乳化剂、分散剂、稳定剂或湿润剂;可以是离子型的或非离子型的。合适的表面活性剂包括:聚丙烯酸和木质素磺酸的钠盐和钙盐;分子中含有至少12个碳原子的脂肪酸或脂肪胺与环氧乙烷和/环氧丙烷的缩聚产物;甘油、十二烷醇-1、十四烷醇-1、山梨醇、蔗糖或季戊四醇的脂肪酸酯;及它们与环氧乙烷和/或环氧丙烷的缩聚产物;它们的缩聚产物的硫酸盐或磺酸盐;在分子中至少含有10个碳原子的硫酸或磺酸的碱金属或碱土金属盐,较佳的为钠盐,如十二烷基硫酸钠、仲烷基硫酸钠、磺化蓖麻油的钠盐、烷芳基磺酸钠和十二烷基苯磺酸钠;环氧乙烷的聚合物、环氧乙烷和环氧丙烷的共聚物。Surfactants can be emulsifiers, dispersants, stabilizers or wetting agents; can be ionic or nonionic. Suitable surfactants include: sodium and calcium salts of polyacrylic acid and lignosulfonic acid; polycondensation products of fatty acids or fatty amines having at least 12 carbon atoms in the molecule with ethylene oxide and/or propylene oxide; glycerol, Fatty acid esters of 1-lauryl alcohol, 1-myristyl alcohol, sorbitol, sucrose or pentaerythritol; and their polycondensation products with ethylene oxide and/or propylene oxide; sulfate salts or Sulfonates; alkali or alkaline earth metal salts, preferably sodium, of sulfuric or sulfonic acids containing at least 10 carbon atoms in the molecule, such as sodium lauryl sulfate, sodium secondary alkyl sulfate, ricinium sulfonate Sodium salt of sesame oil, sodium alkylarylsulfonate and sodium dodecylbenzenesulfonate; polymer of ethylene oxide, copolymer of ethylene oxide and propylene oxide.

乳化剂包括非离子型乳化剂和市售的乳化剂。非离子型乳化剂优选聚氧乙烯脂肪酸脂、聚氧乙烯脂肪醇醚和聚氧乙烯脂肪氨,例如乙氧基化蓖麻油、聚氧乙烯(n20)苯乙基酚基醚油酸酯、烷基芳基聚氧乙烯聚氧丙烯醚、烷基芳基甲醛树脂聚氧乙烯醚、三苯乙烯基酚聚氧乙烯(n20),醚磷酸化三乙醇胺盐、二苯乙基酚基聚氧乙烯醚(n18)甲醛缩合物、二苯基酚聚氧乙烯(n18)聚氧丙烯醚(n20)等。市售的乳化剂包括:农乳0201B、农乳0203B、农乳100#、农乳500#、农乳600#、农乳600-2#、农乳1601、农乳2201、农乳NP-10、农乳NP-15、农乳507#、农乳OX-635、农乳OX-622、农乳OX-653、农乳OX-667、农乳CS-7、宁乳36#Emulsifiers include nonionic emulsifiers and commercially available emulsifiers. Nonionic emulsifiers are preferably polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers and polyoxyethylene fatty ammonia, such as ethoxylated castor oil, polyoxyethylene (n 20 ) phenethylphenol ether oleate, Alkylaryl polyoxyethylene polyoxypropylene ether, alkylaryl formaldehyde resin polyoxyethylene ether, tristyrylphenol polyoxyethylene (n 20 ), ether phosphorylated triethanolamine salt, diphenylethylphenol polyoxyethylene Oxyethylene ether (n 18 ) formaldehyde condensate, diphenylphenol polyoxyethylene (n 18 ) polyoxypropylene ether (n 20 ), etc. Commercially available emulsifiers include: Agricultural Milk 0201B, Agricultural Milk 0203B, Agricultural Milk 100 # , Agricultural Milk 500 # , Agricultural Milk 600 # , Agricultural Milk 600-2 # , Agricultural Milk 1601, Agricultural Milk 2201, Agricultural Milk NP-10 , Nongru NP-15, Nongru 507 # , Nongru OX-635, Nongru OX-622, Nongru OX-653, Nongru OX-667, Nongru CS-7, Ningru 36 # .

本发明所述的分散剂包括:木质素磺酸钠、拉开粉、木质素磺酸钙、甲基萘磺酸甲醛缩合物、萘磺酸甲醛缩合物、亚甲基萘磺酸钠、油酸甲基氨基乙基磺酸钠、环氧聚醚、对叔丁基醚、二丁基萘磺酸甲醛缩合物、磷酸盐如六偏磷酸钠、烷基酚聚氧乙烯基磷酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、N-甲基-脂肪酰基-牛磺酸钠烷基酚聚氧乙烯醚甲醛缩合物、芳烷基酚聚氧乙烯醚磷酸酯烷基酚聚氧乙烯醚、蓖麻油环氧乙烷加成物、环氧乙烷-环氧丙烷嵌段共聚物烷基酚聚氧乙烯醚甲醛缩合物、烷基酚聚氧乙烯聚氧丙烯醚和甲基纤维素。The dispersant of the present invention includes: sodium lignosulfonate, pull-open powder, calcium lignosulfonate, methylnaphthalenesulfonic acid formaldehyde condensate, naphthalenesulfonic acid formaldehyde condensate, sodium methylenenaphthalenesulfonate, oil Sodium acid methyl amino ethyl sulfonate, epoxy polyether, p-tert-butyl ether, dibutyl naphthalene sulfonic acid formaldehyde condensate, phosphates such as sodium hexametaphosphate, alkylphenol polyoxyethylene phosphate, alkanes Alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, N-methyl-fatty acyl-taurine sodium alkylphenol polyoxyethylene ether formaldehyde condensate, aralkylphenol polyoxyethylene ether phosphate ester alkylphenol poly Oxyethylene ether, castor oil ethylene oxide adduct, ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene ether formaldehyde condensate, alkylphenol polyoxyethylene polyoxypropylene ether and methyl cellulose.

本发明所述的湿润剂包括:月桂醇硫酸钠、烷基醇聚氧乙烯基醚硫酸钠、辛基酚聚氧乙烯基醚硫酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、烷基磺酸钠、十二烷基苯磺酸钠、烷基萘磺酸钠、烷基丁二酸磺酸盐、月桂醇聚氧乙烯基醚磺酸钠、烷酰胺基牛磺酸钠、脂肪醇聚氧乙烯基醚、烷基酚聚氧乙烯基醚、聚氧乙烯聚氧丙烯嵌段聚合物、失水山梨醇脂肪酸酯聚氧乙烯基醚等。The wetting agent of the present invention includes: sodium lauryl sulfate, sodium alkyl alcohol polyoxyethylene ether sulfate, octylphenol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, Sodium Alkyl Sulfonate, Sodium Dodecyl Benzene Sulfonate, Sodium Alkyl Naphthalene Sulfonate, Alkyl Succinate Sulfonate, Sodium Lauryl Polyoxyethylene Ether Sulfonate, Sodium Alkylamide Taurate, Fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty acid ester polyoxyethylene ether, etc.

本发明所述的增稠剂,既可以是人工合成的,例如羧甲基醇、聚乙烯醇或聚乙酸乙烯酯;也可以是天然的水溶性聚合物,例如黄原胶、明胶、阿拉伯树胶、聚乙烯吡咯烷酮、硅酸铝镁、聚乙烯醇、聚乙二醇、酚醛树脂、虫胶、羧甲基纤维素和海藻酸钠等。The thickener of the present invention can be artificially synthesized, such as carboxymethyl alcohol, polyvinyl alcohol or polyvinyl acetate; it can also be a natural water-soluble polymer, such as xanthan gum, gelatin, gum arabic , polyvinylpyrrolidone, aluminum magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resin, shellac, carboxymethyl cellulose and sodium alginate, etc.

本发明所述的消泡剂优选为:泡敌、硅酮类、C8~10脂肪醇、C10~20饱和脂肪酸类及酰胺等。The defoaming agent described in the present invention is preferably: foam enemy, silicones, C 8 ~ 10 fatty alcohols, C 10 ~ 20 saturated fatty acids and amides, etc.

本发明所述的杀虫组合物可以按照本领域通用的方法配制成可湿性粉剂、悬浮剂、微乳剂、水乳剂、乳油或水分散性颗粒剂。The pesticidal composition of the present invention can be formulated into wettable powder, suspension, microemulsion, water emulsion, emulsifiable concentrate or water dispersible granule according to the common methods in the art.

本发明所述的杀虫组合物被配制成可湿性粉剂时,优选的是,所述可湿性粉剂以重量计含有以下组分:杀虫组合物0.5%~80%、湿润剂2%~10%、分散剂5%~10%、填料8~90%;进一步优选的是,所述可湿性粉剂以重量计含有以下组分:杀虫组合物0.5%~40%、湿润剂2%~10%、分散剂5%~10%、填料8~90%。制备方法可以是:按配方要求,将原药、各种助剂及填料等充分混合,经超细粉碎机粉碎后,即得到加工产品。When the insecticidal composition of the present invention is formulated into a wettable powder, preferably, the wettable powder contains the following components by weight: 0.5% to 80% of the insecticidal composition, 2% to 10% of the wetting agent %, 5% to 10% of dispersant, 8 to 90% of filler; more preferably, the wettable powder contains the following components by weight: insecticidal composition 0.5% to 40%, wetting agent 2% to 10% %, dispersant 5% to 10%, filler 8 to 90%. The preparation method can be as follows: according to the formula requirements, the original drug, various auxiliary agents and fillers are fully mixed, and after being pulverized by an ultrafine pulverizer, the processed product is obtained.

本发明所述的杀虫组合物被配制成悬浮剂时,优选的是,所述悬浮剂以重量计含有以下组分:杀虫组合物0.5%~80%、湿润剂1%~5%、分散剂1%~8%、增稠剂0.1%~1%、防冻剂2%~5%、水补齐至100%;进一步优选的是,所述悬浮剂以重量计含有以下组分:杀虫组合物0.5~60%、湿润剂1%~5%、分散剂1%~8%、增稠剂0.1%~1%、防冻剂2%~5%、水补齐至100%。制备方法可以是:按配方要求,以水为介质,将原药、分散剂、润湿剂、助悬剂和防冻剂等混合均匀再加入砂磨机中砂磨至一定粒径,过滤后加入增稠剂剪切搅拌均匀,配制所需浓度的悬浮剂即可。When the insecticidal composition of the present invention is formulated into a suspension, preferably, the suspension contains the following components by weight: 0.5% to 80% of the insecticidal composition, 1% to 5% of a wetting agent, 1% to 8% of dispersant, 0.1% to 1% of thickener, 2% to 5% of antifreeze, and 100% water; more preferably, the suspension contains the following components by weight: 0.5-60% of insect composition, 1%-5% of wetting agent, 1%-8% of dispersant, 0.1%-1% of thickener, 2%-5% of antifreeze, and 100% of water. The preparation method can be: according to the requirements of the formula, use water as the medium, mix the original drug, dispersant, wetting agent, suspending agent and antifreeze evenly, then add it to a sand mill and grind it to a certain particle size, filter and add The thickener is sheared and stirred evenly, and the suspending agent of the required concentration can be prepared.

本发明所述的杀虫组合物被配制成微乳剂时,优选的是,所述微乳剂以重量计含有以下组分:杀虫组合物0.5%~80%、乳化剂1%~12%、助溶剂2%~10%、稳定剂0.1%~5%、有机溶剂5%~40%、水补齐至100%;进一步优选的是,所述微乳剂以重量计含有以下组分:杀虫组合物0.5~40%、乳化剂1%~12%、助溶剂2%~10%、稳定剂0.1%~5%、有机溶剂5%~40%、水补齐至100%。制备方法可以是:按配方要求,将各组分一起加入到反应釜中,搅拌均匀并完全溶解,慢慢加入纯净水,边加边搅拌,混合搅拌制得微乳剂。When the pesticidal composition of the present invention is formulated into a microemulsion, preferably, the microemulsion contains the following components by weight: 0.5% to 80% of the pesticidal composition, 1% to 12% of an emulsifier, 2% to 10% of cosolvent, 0.1% to 5% of stabilizer, 5% to 40% of organic solvent, and 100% water; more preferably, the microemulsion contains the following components by weight: insecticidal Composition 0.5-40%, emulsifier 1%-12%, co-solvent 2%-10%, stabilizer 0.1%-5%, organic solvent 5%-40%, and water make up to 100%. The preparation method may be as follows: according to the formula requirement, all the components are added together into the reaction kettle, stirred evenly and completely dissolved, slowly added with pure water, stirred while adding, and mixed and stirred to obtain the microemulsion.

本发明所述的杀虫组合物被配制成水乳剂时,优选的是,所述水乳剂以重量计含有以下组分:杀虫组合物0.5%~80%、乳化剂1%~20%、助溶剂2%~15%、稳定剂0.1%~5%、有机溶剂10%~40%、水补齐至100%;进一步优选的是,所述水乳剂以重量计含有以下组分:杀虫组合物0.5~40%、乳化剂1%~20%、助溶剂2%~15%、稳定剂0.1%~5%、有机溶剂10%~40%、水补齐至100%。制备方法可以是:按配方要求,将各组分一起加入到反应釜中,搅拌均匀并完全溶解,慢慢加入纯净水,边加边搅拌,混合搅拌制得水乳剂。When the insecticidal composition of the present invention is formulated into an emulsion in water, preferably, the emulsion in water contains the following components by weight: 0.5% to 80% of the insecticidal composition, 1% to 20% of the emulsifier, 2% to 15% of cosolvent, 0.1% to 5% of stabilizer, 10% to 40% of organic solvent, and 100% water; more preferably, the water emulsion contains the following components by weight: insecticidal Composition 0.5-40%, emulsifier 1%-20%, co-solvent 2%-15%, stabilizer 0.1%-5%, organic solvent 10%-40%, and water to 100%. The preparation method may be as follows: according to the formula requirements, all the components are added together into the reaction kettle, stirred evenly and completely dissolved, slowly added with pure water, stirred while adding, and mixed and stirred to obtain the water emulsion.

本发明所述的杀虫组合物被配制成乳油时,优选的是,所述乳油以重量计含有以下组分:杀虫组合物0.5%~80%、乳化剂1%~20%、有机溶剂补齐至100%;进一步优选的是,所述乳油以重量计含有以下组分:杀虫组合物0.5~50%、乳化剂1%~20%、有机溶剂补齐至100%。制备方法可以是:按配方要求,分别加入溶剂、原药、乳化剂,混合均匀,必要时用水浴加热溶解,即得到透明状乳油。When the insecticidal composition of the present invention is formulated into emulsifiable concentrate, preferably, the emulsifiable concentrate contains the following components by weight: 0.5% to 80% of insecticidal composition, 1% to 20% of emulsifier, organic solvent make up to 100%; further preferably, the emulsifiable concentrate contains the following components by weight: 0.5-50% of insecticidal composition, 1%-20% of emulsifier, and make up to 100% of organic solvent. The preparation method may be as follows: according to the formula requirement, respectively add solvent, original drug and emulsifier, mix uniformly, and if necessary, heat and dissolve in a water bath to obtain a transparent emulsifiable oil.

本发明所述的杀虫组合物被配制成水分散性颗粒剂时,优选的是,所述水分散颗粒剂以重量计含有以下组分:杀虫组合物0.5%~80%、表面活性剂0.1%~2%、湿润剂1%~15%、分散剂1%~15%、崩解剂1%~10%、稳定剂0.1%~5%、填料补齐至100%;进一步优选的是,所述水分散颗粒剂以重量计含有以下组分:杀虫组合物0.5%~40%、表面活性剂0.1%~2%、湿润剂1%~15%、分散剂1%~15%、崩解剂1%~10%、稳定剂0.1%~5%、填料补齐至100%。制备方法可以是:将原药和粉状载体、分散剂、润湿剂及填料等进行混合粉碎,再加水捏合后,加入装有一定规格筛网的造粒机中进行造粒,然后再经干燥、筛分(按筛网范围)即得颗粒状产品。When the insecticidal composition of the present invention is formulated into water-dispersible granules, preferably, the water-dispersible granules contain the following components by weight: 0.5% to 80% of the insecticidal composition, surfactant 0.1% to 2%, wetting agent 1% to 15%, dispersant 1% to 15%, disintegrating agent 1% to 10%, stabilizer 0.1% to 5%, filler to 100%; more preferably , the water-dispersible granule contains the following components by weight: insecticidal composition 0.5%-40%, surfactant 0.1%-2%, wetting agent 1%-15%, dispersant 1%-15%, 1% to 10% of disintegrant, 0.1% to 5% of stabilizer, and 100% filler. The preparation method can be as follows: mixing and pulverizing the original drug, powdery carrier, dispersant, wetting agent and filler, adding water and kneading, adding to a granulator equipped with a certain size screen for granulation, and then passing through Dry and sieve (according to the range of the sieve) to obtain granular products.

本发明所述的杀虫组合物和杀虫剂适合用于防治鳞翅目害虫,尤其适合防治以下植物中的鳞翅目害虫:甘蓝、花椰菜、白菜、小麦、棉花、玉米、菜豆、豇豆、韭菜、莴苣、向日葵、荔枝、柑橘、甘蔗、烟草、橡胶和一些花卉、草坪等。所述鳞翅目害虫选自棉铃虫、斜纹夜蛾、甜菜夜蛾、小菜蛾、菜青虫、烟青虫、潜叶蛾和卷叶蛾中的一种、两种或三种以上。The insecticidal composition and insecticide described in the present invention are suitable for controlling Lepidoptera pests, especially suitable for controlling Lepidoptera pests in the following plants: cabbage, cauliflower, Chinese cabbage, wheat, cotton, corn, kidney bean, cowpea, Leek, lettuce, sunflower, lychee, citrus, sugar cane, tobacco, rubber and some flowers, lawn, etc. The Lepidoptera pests are selected from one, two or more of cotton bollworm, Spodoptera litura, Beet Spodoptera, diamondback moth, cabbage caterpillar, tobacco budworm, leafminer and leaf tortrix.

本发明所述的杀虫组合物的施用场所为农田、蔬菜地、果园或仓库等。The application site of the insecticidal composition of the present invention is farmland, vegetable field, orchard or warehouse.

本发明所述的杀虫组合物可以按普通的方法施用,如浇注、喷射、喷雾。施用量随气候条件或作物状态变化,施用时间可以在害虫危害之前或之后。保护作用的持续时间通常与组合物中单个化合物的含量有关,也与外界因素相关,例如气候,但通过使用适当的剂型可以减缓气候的影响。The insecticidal composition of the present invention can be applied by common methods, such as pouring, spraying, spraying. The amount of application varies with climatic conditions or crop status, and the application time can be before or after pest damage. The duration of the protective effect is usually related to the content of the individual compounds in the composition, but also to external factors, such as climate, which can be mitigated by using appropriate formulations.

本发明所述的杀虫组合物也可以与其它具有除草、杀菌性能的化合物混合使用,也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合使用。The insecticidal composition of the present invention can also be used in combination with other compounds with herbicidal and bactericidal properties, and can also be used in combination with nematicides, protective agents, growth regulators, plant nutrients or soil regulators.

本发明所述的杀虫组合物相比现有技术具有如下优势:Compared with the prior art, the insecticidal composition of the present invention has the following advantages:

(1)组合物中两种活性成分复配在一定配比范围内表现出优良的增效作用,混合后的组合物的杀虫效果较其单剂有明显的提高,而且具有速效性好和持效性长的特点;(1) The combination of the two active ingredients in the composition shows excellent synergistic effect within a certain proportion range, and the insecticidal effect of the mixed composition is significantly improved compared with its single agent, and has good quick-acting and Long-lasting characteristics;

(2)组合物具有杀卵和幼虫特点,扩大了防治范围;(2) The composition has the characteristics of killing eggs and larvae, which expands the scope of control;

(3)降低了使用剂量,减少农民用药成本;(3) Reduced dosage and reduced farmers' medication costs;

(4)利用两种活性成分对害虫不同的作用方式、不同的作用机理进行合理地混配,既延长了农药使用寿命,又延缓害虫抗药性的产生。(4) The two active ingredients are used to rationally mix different modes of action and different mechanisms of action of pests, which not only prolongs the service life of pesticides, but also delays the generation of pest resistance.

具体实施方式detailed description

下面结合具体实施例来对本发明进行进一步说明,但并不将本发明局限于这些具体实施方式。本领域技术人员应该认识到,本发明涵盖了权利要求书范围内所可能包括的所有备选方案、改进方案和等效方案。The present invention will be further described below in conjunction with specific examples, but the present invention is not limited to these specific implementations. Those skilled in the art will realize that the present invention covers all alternatives, modifications and equivalents as may be included within the scope of the claims.

下述实施例中,固体制剂的配比为重量百分比,液体制剂的配比为体积百分比,生物活性部分的处理剂量为有效含量。In the following examples, the ratio of the solid preparation is weight percentage, the ratio of liquid preparation is volume percentage, and the treatment dose of the biologically active part is the effective content.

一、生物活性测定1. Determination of biological activity

试验参照杀虫剂农药室内生物测定试验准则(农业行业标准NY/T1154.7-2006)和创制农药生物活性评价SOP(杀虫剂卷),采用浸渍法。The test refers to the Indoor Bioassay Test Guidelines for Insecticides and Pesticides (Agricultural Industry Standard NY/T1154.7-2006) and the SOP for the Evaluation of Bioactivity of Pesticides (Insecticide Volume), using the dipping method.

联合作用采用下述方法进行计算:The combined effect is calculated using the following method:

理论混用毒力指数(TTI)=A的毒力指数×A在混用中的含量(%)Theoretical mixed toxicity index (TTI) = Toxicity index of A × A content in mixed use (%)

+B的毒力指数×B在混用中的含量(%)Toxicity index of +B × B content in the mixture (%)

共毒系数若大于120,表明有增效作用;若小于80,表明为拮抗作用;若大于80小于120,表明为相加作用。If the co-toxicity coefficient is greater than 120, it indicates a synergistic effect; if it is less than 80, it indicates an antagonistic effect; if it is greater than 80 but less than 120, it indicates an additive effect.

实施例1:氯氟氰虫酰胺与氟铃脲的组合物Embodiment 1: Composition of cyantraniliprole and hexaflumuron

表1 氯氟氰虫酰胺和氟铃脲的组合物对甜菜夜蛾(Spodoptera exigua)的联合增效作用Table 1 The combined synergistic effect of the combination of cyantraniliprole and hexaflumuron on the beet armyworm (Spodoptera exigua)

处理deal with 配比Proportion LC50(mg/L) LC50 (mg/L) 实测毒力指数measured toxicity index 理论毒力指数theoretical virulence index 共毒系数co-toxicity coefficient ZJ4042ZJ4042 -- 0.3780.378 100.00100.00 -- -- 氟铃脲Hexaflumuron -- 3.7823.782 9.419.41 -- -- ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:501:50 2.4852.485 14.3714.37 11.2211.22 128.10128.10 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:201:20 2.0142.014 17.7317.73 13.7513.75 128.90128.90 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:91:9 1.3521.352 26.4126.41 18.5018.50 142.77142.77 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:71:7 1.0941.094 32.6332.63 20.7620.76 157.19157.19 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:31:3 0.6840.684 52.1952.19 32.0832.08 162.70162.70 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:21:2 0.5380.538 66.3666.36 39.6339.63 167.46167.46 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 1:11:1 0.3740.374 95.4595.45 54.7254.72 174.44174.44 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 3:13:1 0.3380.338 105.62105.62 77.3677.36 136.53136.53 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 5:15:1 0.3090.309 115.53115.53 84.9184.91 136.07136.07 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 20:120:1 0.3030.303 117.82117.82 95.6995.69 123.13123.13 ZJ4042:氟铃脲ZJ4042: Hexaflumuron 50:150:1 0.3010.301 118.60118.60 98.2298.22 120.75120.75

从表1中可以看出,氯氟氰虫酰胺和氟铃脲的组合物对供试靶标甜菜夜蛾均有很高的杀虫活性,氯氟氰虫酰胺与氟铃脲混配后均表现出显著的增效作用,混剂的活性显著高于对照单剂。其中氯氟氰虫酰胺与氟铃脲配比为1:9~5:1的增效作用大于其他配比。As can be seen from Table 1, the composition of cyantraniliprole and hexaflumuron all has very high insecticidal activity to the tested target beet armyworm, and both cyantraniliprole and hexaflumuron showed high insecticidal activity after mixing. There was a significant synergistic effect, and the activity of the mixture was significantly higher than that of the single agent. Among them, the synergistic effect of cyantraniliprole and hexaflumuron at a ratio of 1:9 to 5:1 is greater than that of other ratios.

二、制剂配制2. Preparation

实施例2、10%乳油Embodiment 2, 10% emulsifiable concentrate

ZJ40422.5%,氟铃脲7.5%,农乳2201#7.5%,农乳600#4.5%,二甲基甲酰胺8%,S-200(主要成份为辛烷及庚烷,江苏扬州华伦化工有限公司)补足至100%。ZJ404 22.5%, hexaflumuron 7.5%, Nongru 2201 # 7.5%, Nongru 600 # 4.5%, dimethylformamide 8%, S-200 (the main ingredients are octane and heptane, Jiangsu Yangzhou Hualun Chemical Co., Ltd.) to 100%.

实施例3、15%乳油Embodiment 3, 15% emulsifiable concentrate

ZJ40425%,氟铃脲10%,农乳500#5%,农乳0201B 10%,二甲基甲酰胺12%,S-200(主要成份为辛烷及庚烷,江苏扬州华伦化工有限公司)补足至100%。ZJ404 25%, hexaflumuron 10%, Nongru 500 # 5%, Nongru 0201B 10%, dimethylformamide 12%, S-200 (main components are octane and heptane, Jiangsu Yangzhou Hualun Chemical Co., Ltd. ) to make up to 100%.

实施例4、20%乳油Embodiment 4, 20% emulsifiable concentrate

ZJ404210%,氟铃脲10%,农乳0203B 6%,农乳0201B 9%,环己酮8%,S-200(主要成份为辛烷及庚烷,江苏扬州华伦化工有限公司)补足至100%。ZJ404210%, hexaflumuron 10%, Nongru 0203B 6%, Nongru 0201B 9%, cyclohexanone 8%, S-200 (mainly octane and heptane, Jiangsu Yangzhou Hualun Chemical Co., Ltd.) 100%.

实施例5、75%可湿性粉剂Embodiment 5,75% wettable powder

ZJ404225%,氟铃脲50%,十二烷基苯磺酸钠2.0%,白碳黑10%,木质素磺酸钠10%,轻质碳酸钙补足至100%。ZJ404225%, hexaflumuron 50%, sodium dodecylbenzene sulfonate 2.0%, white carbon black 10%, sodium lignosulfonate 10%, light calcium carbonate supplemented to 100%.

实施例6、50%可湿性粉剂Embodiment 6,50% wettable powder

ZJ404210%,氟铃脲40%,十二烷基苯磺酸钠1.8%,对叔丁基醚2%,白碳黑12%,木质素磺酸钠10%,轻质碳酸钙补足至100%。ZJ404210%, hexaflumuron 40%, sodium dodecylbenzenesulfonate 1.8%, p-tert-butyl ether 2%, white carbon black 12%, sodium lignosulfonate 10%, light calcium carbonate to 100% .

实施例7、70%水分散性颗粒剂Embodiment 7, 70% water dispersible granules

ZJ404220%,氟铃脲50%,木质素磺酸钠15%,甲基萘磺酸钠甲醛缩合物5%,环氧聚醚5%,白炭黑20%,高岭土补足至100%。ZJ404220%, hexaflumuron 50%, sodium lignin sulfonate 15%, sodium methylnaphthalene sulfonate formaldehyde condensate 5%, epoxy polyether 5%, white carbon black 20%, kaolin supplemented to 100%.

实施例8、60%水分散性颗粒剂Embodiment 8, 60% water dispersible granules

ZJ404220%,氟铃脲40%,木质素磺酸钠3%,甲基萘磺酸钠甲醛缩合物5%,拉开粉2%,硫酸钠2%,羧甲基纤维素1.5%,高岭土补足至100%。ZJ404220%, hexaflumuron 40%, sodium lignosulfonate 3%, sodium methylnaphthalenesulfonate formaldehyde condensate 5%, pull-off powder 2%, sodium sulfate 2%, carboxymethylcellulose 1.5%, kaolin supplement to 100%.

实施例9、40%水分散性颗粒剂Embodiment 9, 40% water dispersible granules

ZJ404220%,氟铃脲20%,木质素磺酸钠3%,萘磺酸类分散剂6%,十二烷基硫酸钠3%,氯化钙2%,羧甲基纤维素1.5%,高岭土补足至100%。ZJ404220%, hexaflumuron 20%, sodium lignosulfonate 3%, naphthalenesulfonic acid dispersant 6%, sodium lauryl sulfate 3%, calcium chloride 2%, carboxymethyl cellulose 1.5%, kaolin Top up to 100%.

实施例10、70%水分散性颗粒剂Embodiment 10, 70% water dispersible granules

ZJ404210%,氟铃脲60%,烷基酚聚氧乙烯嘧3%,十二烷基苯磺酸2%,氯化钙2%,羧甲基纤维素1.5%,淀粉20%,硅藻土补足至100%。ZJ404210%, hexaflumuron 60%, alkylphenol polyoxyethylene 3%, dodecylbenzenesulfonic acid 2%, calcium chloride 2%, carboxymethyl cellulose 1.5%, starch 20%, diatomaceous earth Top up to 100%.

实施例11、20%悬浮剂Embodiment 11, 20% suspending agent

ZJ4042 10%,氟铃脲10%,拉开粉1.5%,Soproplot SC 3%,黄原胶0.15%,硅酸镁铝1.5%,418G 0.3%,BIT 0.05%,水补足至100%。ZJ4042 10%, hexaflumuron 10%, pull open powder 1.5%, Soproplot SC 3%, xanthan gum 0.15%, magnesium aluminum silicate 1.5%, 418G 0.3%, BIT 0.05%, water to 100%.

实施例12、30%悬浮剂Embodiment 12, 30% suspending agent

ZJ404210%,氟铃脲20%,聚羧酸盐5%,白碳黑0.3%,凹凸棒土1.0%,磷酸二氢钾0.2%,乙二醇4%,黄元酸胶0.2%,水补足至100%。ZJ404210%, hexaflumuron 20%, polycarboxylate 5%, white carbon black 0.3%, attapulgite 1.0%, potassium dihydrogen phosphate 0.2%, ethylene glycol 4%, xanthate gum 0.2%, water to make up to 100%.

实施例13、25%悬浮剂Embodiment 13, 25% suspending agent

ZJ40425%,氟铃脲20%,聚羧酸盐2.5%,凹凸棒土1.0%,乙二醇3%,磷酸三丁酯0.2%,水补足至100%。ZJ404 25%, hexaflumuron 20%, polycarboxylate 2.5%, attapulgite 1.0%, ethylene glycol 3%, tributyl phosphate 0.2%, water to make up to 100%.

实施例14、40%悬浮剂Embodiment 14, 40% suspending agent

ZJ40425%,氟铃脲35%,聚羧酸盐4%,无患子粉5%,乙二醇2%,羟乙基纤维素0.1%,水补足至100%。ZJ404 25%, hexaflumuron 35%, polycarboxylate 4%, Sapinberry powder 5%, ethylene glycol 2%, hydroxyethyl cellulose 0.1%, water to make up to 100%.

实施例15、10%水乳剂Embodiment 15, 10% water emulsion

ZJ40422.5%,氟铃脲7.5%,N-甲基吡咯烷酮8%,十二烷基磺酸钠6%,聚乙烯醇4%,乳化剂500#5%,消泡剂0.5%,余量为去离子水。ZJ4042 2.5%, hexaflumuron 7.5%, N-methylpyrrolidone 8%, sodium dodecylsulfonate 6%, polyvinyl alcohol 4%, emulsifier 500# 5%, defoamer 0.5%, balance for deionized water.

实施例16、7.5%微乳剂Embodiment 16, 7.5% microemulsion

ZJ40422.5%,氟铃脲5%,乳化剂NP-105%,木质素磺酸钠10%,环乙酮5%,二甲苯5%,余量为去离子水。ZJ404 2.5%, hexaflumuron 5%, emulsifier NP-105%, sodium lignosulfonate 10%, cyclohexanone 5%, xylene 5%, and the balance is deionized water.

三、田间药效试验3. Field drug efficacy test

实施例17、防治小菜蛾田间药效试验Embodiment 17, control diamondback moth field efficacy test

供试药剂:Drugs for testing:

实施例3(15%ZJ4042·氟铃脲乳油),30g a.i./hm2Example 3 (15% ZJ4042 hexaflumuron EC), 30g ai/hm 2 ;

实施例6(50%ZJ4042·氟铃脲可湿性粉剂),30g a.i./hm2Embodiment 6 (50% ZJ4042 · hexaflumuron wettable powder), 30g ai/hm 2 ;

实施例8(60%ZJ4042·氟铃脲水分散粒剂),30g a.i./hm2Example 8 (60% ZJ4042. Hexaflumuron water dispersible granules), 30g ai/hm 2 ;

实施例14(40%ZJ4042·氟铃脲悬浮剂),45g a.i./hm2Example 14 (40% ZJ4042 hexaflumuron suspension), 45g ai/hm 2 ;

实施例15(10%ZJ4042·氟铃脲水乳剂),30g a.i./hm2Example 15 (10% ZJ4042 hexaflumuron water emulsion), 30g ai/hm 2 ;

对照药剂:Comparative drug:

20%ZJ4042悬浮剂,45g a.i./hm2;5%氟铃脲乳油,45g a.i./hm220% ZJ4042 suspension concentrate, 45g ai/hm 2 ; 5% hexaflumuron emulsifiable concentrate, 45g ai/hm 2 .

防治对象为小菜蛾,施药时为甘蓝包心前期,小菜蛾虫态为幼虫,以低龄幼虫为主。总计施药一次,施药量为450kg/hm2。试验调查依据农业部药检所“农药田间药效试验准则(一)——杀虫剂防治十字花科蔬菜的鳞翅目幼虫”规定进行,每试验小区采用5点取样,每点调查2株,共调查10株甘蓝,调查每株上所有活虫数。The control object is diamondback moth. When the pesticide is applied, it is in the early stage of cabbage core, and the insect state of diamondback moth is larvae, mainly young larvae. Apply once in total, and the application rate is 450kg/hm 2 . The test investigation was carried out in accordance with the provisions of the "Pesticide Field Efficacy Test Guidelines (1) - Insecticides Control Lepidoptera Larvae of Cruciferous Vegetables" by the Institute for Drug Control of the Ministry of Agriculture. Each test plot was sampled at 5 points, and 2 plants were investigated at each point. A total of 10 cabbage plants were investigated, and the number of live insects on each plant was investigated.

试验结果表明,供试药剂药后3d的防效为79.7%~85.5%,药后7d防效为95.3%~98.2%,药后14d防效仍达84.2%~87.1%。防治效果均好于对照药剂5%氟铃脲乳油和20%ZJ4042悬浮剂。The test results showed that the control effect of the test agent was 79.7%-85.5% after 3 days of application, 95.3%-98.2% after 7 days of application, and 84.2%-87.1% after 14 days of application. The control effects were better than those of 5% hexaflumuron emulsifiable concentrate and 20% ZJ4042 suspension concentrate.

表2 防治小菜蛾田间药效试验结果Table 2 Results of field efficacy tests on controlling Plutella xylostella

实施例18、防治斜纹夜蛾田间药效试验Embodiment 18, control field efficacy test of Spodoptera litura

供试药剂:Drugs for testing:

实施例4(20%ZJ4042·氟铃脲乳油),30g a.i./hm2Example 4 (20% ZJ4042 hexaflumuron EC), 30g ai/hm 2 ;

实施例5(75%ZJ4042·氟铃脲可湿性粉剂),30g a.i./hm2Example 5 (75% ZJ4042. Hexaflumuron wettable powder), 30g ai/hm 2 ;

实施例9(40%ZJ4042·氟铃脲水分散粒剂),30g a.i./hm2Example 9 (40% ZJ4042. Hexaflumuron water dispersible granules), 30g ai/hm 2 ;

实施例12(30%ZJ4042·氟铃脲悬浮剂),30g a.i./hm2Example 12 (30% ZJ4042 hexaflumuron suspension), 30g ai/hm 2 ;

对照药剂:Comparative drug:

20%ZJ4042悬浮剂,30g a.i./hm2;5%氟铃脲乳油,45g a.i./hm220% ZJ4042 suspension concentrate, 30g ai/hm 2 ; 5% hexaflumuron EC, 45g ai/hm 2 .

防治对象斜纹夜蛾,施药时为甘蓝包心前期,斜纹夜蛾以低龄幼虫为主。总计施药一次,施药量为450kg/hm2。试验调查依据农业部药检所“农药田间药效试验准则(一)——杀虫剂防治十字花科蔬菜的鳞翅目幼虫”规定进行,每试验小区采用5点取样,每点调查2株,共调查10株甘蓝,调查每株上所有活虫数。The control object Spodoptera litura is in the early stage of cabbage core when the pesticide is applied, and Spodoptera litura is mainly young larvae. Apply once in total, and the application rate is 450kg/hm 2 . The test investigation was carried out in accordance with the provisions of the "Pesticide Field Efficacy Test Guidelines (1) - Insecticides Control Lepidoptera Larvae of Cruciferous Vegetables" by the Institute for Drug Control of the Ministry of Agriculture. Each test plot was sampled at 5 points, and 2 plants were investigated at each point. A total of 10 cabbage plants were investigated, and the number of live insects on each plant was investigated.

试验结果表明,供试药剂药后3d的防效为70.2%~77.5%,药后7d防效为93.4%~98.6%,药后14d防效仍达87.2%~89.4%,防治效果均好于对照药剂5%氟铃脲乳油和20%ZJ4042悬浮剂防效,持效期长。The test results show that the control effect of the test agent is 70.2% to 77.5% after 3 days of application, 93.4% to 98.6% after 7 days of application, and 87.2% to 89.4% after 14 days of application. The control effects of 5% hexaflumuron EC and 20% ZJ4042 suspending agent of the control agent were long-lasting.

表3 防治斜纹夜蛾田间药效试验结果Table 3 Results of field efficacy tests on controlling Spodoptera litura

实施例19、防治柑橘潜叶蛾田间药效试验Embodiment 19, control field efficacy test of citrus leaf miner

供试药剂:Drugs for testing:

实施例5(75%ZJ4042·氟铃脲可湿性粉剂),60g a.i./hm2Example 5 (75% ZJ4042 hexaflumuron wettable powder), 60g ai/hm 2 ;

实施例8(60%ZJ4042·氟铃脲水分散粒剂),60g a.i./hm2Example 8 (60% ZJ4042. Hexaflumuron water dispersible granules), 60g ai/hm 2 ;

实施例9(40%ZJ4042·氟铃脲水分散粒剂),60g a.i./hm2Example 9 (40% ZJ4042. Hexaflumuron water dispersible granules), 60g ai/hm 2 ;

实施例13(25%ZJ4042·氟铃脲悬浮剂),60g a.i./hm2Example 13 (25% ZJ4042 hexaflumuron suspension concentrate), 60g ai/hm 2 ;

对照药剂:Comparative drug:

20%ZJ4042悬浮剂,60g a.i.//hm2;5%氟铃脲乳油,90g a.i.//hm220% ZJ4042 suspension concentrate, 60g ai//hm 2 ; 5% hexaflumuron emulsifiable concentrate, 90g ai//hm 2 .

防治对象为柑橘潜叶蛾,在盛发期施药一次,喷液量1500kg/hm2。试验调查依据农业部药检所“农药田间药效试验准则(二)——杀虫剂防治柑桔潜叶蛾”规定进行。The control object is citrus leaf miner, and the pesticide is applied once in the blooming period, and the spray volume is 1500kg/hm 2 . The test investigation was carried out in accordance with the provisions of "Pesticide Field Efficacy Test Guidelines (2) - Insecticides Control Citrus Leaf Miner" by the Institute for Drug Control of the Ministry of Agriculture.

试验结果:见表4,供试药剂药后3d的防效为79.3%~81.2%,药后7d防效为92.3%~95.5%,药后14d防效仍达84.4%~86.7%,防治效果均好于对照药剂5%氟铃脲乳油和20%ZJ4042悬浮剂防效,持效期长。Test results: See Table 4, the control effect of the test agent after 3 days of application is 79.3% to 81.2%, the control effect of 7 days after application is 92.3% to 95.5%, and the control effect of 14 days after application still reaches 84.4% to 86.7%. Both are better than the control effects of 5% hexaflumuron emulsifiable concentrate and 20% ZJ4042 suspending agent of the control agents, and the duration of effect is long.

表4 防治柑橘潜叶蛾田间药效试验结果Table 4 Results of field efficacy tests on the control of citrus leaf miner

实施例20、防治棉铃虫田间药效试验Embodiment 20, control field efficacy test of cotton bollworm

供试药剂:Drugs for testing:

实施例2(10%ZJ4042·氟铃脲乳油),30g a.i.//hm2Example 2 (10% ZJ4042 hexaflumuron EC), 30g ai//hm 2 ;

实施例5(75%ZJ4042·氟铃脲可湿性粉剂),30g a.i./hm2Example 5 (75% ZJ4042. Hexaflumuron wettable powder), 30g ai/hm 2 ;

实施例7(70%ZJ4042·氟铃脲水分散粒剂),30g a.i./hm2Example 7 (70% ZJ4042. Hexaflumuron water dispersible granules), 30g ai/hm 2 ;

实施例11(20%ZJ4042·氟铃脲悬浮剂),30g a.i./hm2Example 11 (20% ZJ4042 hexaflumuron suspension concentrate), 30g ai/hm 2 ;

实施例16(7.5%ZJ4042·氟铃脲微乳剂),30g a.i./hm2 Example 16 (7.5% ZJ4042 hexaflumuron microemulsion), 30g ai/hm 2

对照药剂:Comparative drug:

20%ZJ4042悬浮剂,30g a.i.//hm2;5%氟铃脲乳油,50g a.i.//hm220% ZJ4042 suspension concentrate, 30g ai//hm 2 ; 5% hexaflumuron emulsifiable concentrate, 50g ai//hm 2 .

防治对象为棉铃虫,施药时为卵孵化高峰期,虫态以低龄幼虫为主。施药一次,施药量为750kg/hm2。试验调查依据农药田间药效试验准则(一)——杀虫剂防治棉铃虫”规定进行,每小区中间行数随机取5点,每点调查5株,共调查25株,药前调查虫口基数。The control object is cotton bollworm, when the pesticide is applied, it is the peak period of egg hatching, and the insect state is mainly young larvae. Spray once, and the spray rate is 750kg/hm 2 . The experimental survey was carried out according to the regulations of pesticide field efficacy test guidelines (1) - control of cotton bollworm with insecticides, 5 points were randomly selected in the middle row of each plot, 5 plants were investigated at each point, and a total of 25 plants were investigated. .

试验结果表明,供试药剂药后3d的防效为70.6%~76.2%,药后7d防效为93.2%~97.4%,药后14d防效仍达87.6%~90.4%,防治效果均好于对照药剂5%氟铃脲乳油和20%ZJ4042悬浮剂防效,持效期长。The test results show that the control effect of the test agent is 70.6% to 76.2% after 3 days of application, 93.2% to 97.4% after 7 days of application, and 87.6% to 90.4% after 14 days of application. The control effects of 5% hexaflumuron EC and 20% ZJ4042 suspending agent of the control agent were long-lasting.

表5 防治棉铃虫田间药效试验结果Table 5 Results of field efficacy tests on cotton bollworm control

Claims (10)

1. a kind of Pesticidal combination for agricultural pests, it is characterised in that the Pesticidal combination contains chlorine fluorine cyanogen insect amide and fluorine bell Urea, and chlorine fluorine cyanogen insect amide and the weight ratio of HEXAFLUMURON are 50:1~1:50.
2. according to the Pesticidal combination described in claim 1, it is characterised in that the chlorine fluorine cyanogen insect amide is with the weight ratio of HEXAFLUMURON 20:1~1:20.
3. according to the Pesticidal combination described in claim 2, it is characterised in that the chlorine fluorine cyanogen insect amide is with the weight ratio of HEXAFLUMURON 5:1~1:9.
4. a kind of insecticide for agricultural pests, it is characterised in that the insecticide is by weight containing 0.5~80% Insecticidal combinations Thing, remaining is agriculturally acceptable carrier and auxiliary agent.
5. according to the insecticide for agricultural pests described in claim 5, it is characterised in that the insecticide by weight containing 5~ 40% Pesticidal combination.
6. according to the insecticide for agricultural pests described in claim 4, it is characterised in that the insecticide be wettable powder, Suspending agent, microemulsion, aqueous emulsion, cream or water-dispersible granules.
7. according to the insecticide for agricultural pests described in claim 6, it is characterised in that
The wettable powder contains by weight following components:Pesticidal combination 0.5%~80%, wetting agent 2%~10%, dispersion Agent 5%~10%, filler 8~90%;
The suspending agent contains by weight following components:Pesticidal combination 0.5%~80%, wetting agent 1%~5%, dispersant 1%~ 8%th, thickening agent 0.1%~1%, antifreezing agent 2%~5%, water polishing to 100%;
The microemulsion contains by weight following components:Pesticidal combination 0.5%~80%, emulsifying agent 1%~12%, cosolvent 2%~10%, stabilizer 0.1%~5%, organic solvent 5%~40%, water polishing to 100%;
The aqueous emulsion contains by weight following components:Pesticidal combination 0.5%~80%, emulsifying agent 1%~20%, cosolvent 2%~15%, stabilizer 0.1%~5%, organic solvent 10%~40%, water polishing to 100%;
The cream contains by weight following components:Pesticidal combination 0.5%~80%, emulsifying agent 1%~20%, organic solvent are mended Together to 100%;
The water dispersion granule contains by weight following components:Pesticidal combination 0.5%~80%, surfactant 0.1%~ 2%th, wetting agent 1%~15%, dispersant 1%~15%, disintegrating agent 1%~10%, stabilizer 0.1%~5%, filler polishing to 100%.
8. according to the insecticide for agricultural pests described in claim 7, it is characterised in that
The wettable powder contains by weight following components:Pesticidal combination 0.5%~40%, wetting agent 2%~10%, dispersion Agent 5%~10%, filler 8~90%;
The suspending agent contains by weight following components:Pesticidal combination 0.5~60%, wetting agent 1%~5%, dispersant 1%~ 8%th, thickening agent 0.1%~1%, antifreezing agent 2%~5%, water polishing to 100%;
The microemulsion contains by weight following components:Pesticidal combination 0.5~40%, emulsifying agent 1%~12%, cosolvent 2%~ 10%th, stabilizer 0.1%~5%, organic solvent 5%~40%, water polishing to 100%;
The aqueous emulsion contains by weight following components:Pesticidal combination 0.5~40%, emulsifying agent 1%~20%, cosolvent 2%~ 15%th, stabilizer 0.1%~5%, organic solvent 10%~40%, water polishing to 100%;
The cream contains by weight following components:Pesticidal combination 0.5~50%, emulsifying agent 1%~20%, organic solvent are mended Together to 100%;
The water dispersion granule contains by weight following components:Pesticidal combination 0.5%~40%, surfactant 0.1%~ 2%th, wetting agent 1%~15%, dispersant 1%~15%, disintegrating agent 1%~10%, stabilizer 0.1%~5%, filler polishing to 100%.
9. according to the Pesticidal combination described in claim 1, it is characterised in that the Pesticidal combination is used to prevent and treat lepidoptera pest.
10. according to the Pesticidal combination described in claim 9, it is characterised in that the lepidoptera pest selected from bollworm, Prodenia litura, One kind in beet armyworm, diamondback moth, Pieris rapae, oriental tobacco budworm, leaf miner and leaf roller, more than two or three.
CN201510680598.8A 2015-10-20 2015-10-20 Pesticide compound containing cyhalodiamide and hexaflumuron Pending CN106577709A (en)

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Application publication date: 20170426