CN106489971A

CN106489971A - A kind of Herbicidal combinations

Info

Publication number: CN106489971A
Application number: CN201510563001.1A
Authority: CN
Inventors: 罗昌炎; 詹姆斯·T·布里斯托
Original assignee: Jiangsu Rotam Chemical Co Ltd
Current assignee: Jiangsu Rotam Chemical Co Ltd
Priority date: 2015-09-07
Filing date: 2015-09-07
Publication date: 2017-03-15

Abstract

The present invention relates to a kind of Herbicidal combinations.The invention further relates to a kind of method for controlling undesirable plant.The present invention provides a kind of Herbicidal combinations, and active component is made up of compound (A) and compound (B), and wherein (A) is the compound described by formula (I)：And (B) is the compound described by formula (II) (I)：(II) compound (A) is 1 with the weight ratio of (B):1-1:100.

Description

A kind of Herbicidal combinations

Technical field

The present invention relates to a kind of Herbicidal combinations.The invention further relates to a kind of method for controlling undesirable plant.

Background technology

Weeds in paddy field species is a lot, and paddy field weeding is a great problem in production.Chemical method weeding is the Main Means for controlling weeds.But in recent years, already lead to a lot of weeds and develop immunity to drugs as some herbicide kind large area are used alone.Meanwhile, grass when weeds occur is mutually complicated, and the mixed life of grassy weed, broad leaved weed, dried tuber multiclass weeds, the use of single variety herbicide can not solve farmland weed, can show defect in a certain respect and limitation.

Promazine Sulfometuron Methyl（Propyrisulfuron）It is by the pyrimidine radicals sulfonylurea herbicide of SUMITOMO CHEMICAL chemistry exploitation, is mainly used in rice terrace and prevents and kill off the grass family such as barnyard grass and broad leaved weed.The product consumption is low, has good preventive effect to the weeds that sulfonylurea herbicide known to some produces resistance.Promazine Sulfometuron Methyl has good preventive effect to annual and perennial paddy field weed, such as barnyard grass and ticklish Corm Eleocharitiss, Rhizoma sagittariae sagittifoliae etc..Though promazine Sulfometuron Methyl belongs to sulfonylurea herbicide, which still has good activity to the weeds that sulfonylurea herbicide known to some produces resistance.Promazine Sulfometuron Methyl is mainly used for the herbicide that early metaphase is disposably killed, and can be used to make the pesticidal preparations product such as suspending concentrate or large-scale tablet, is directly thrown to field.Promazine Sulfometuron Methyl, molecular formula are C₁₆H₁₈O₅N₇SCl, its molecular structure are as follows：

(I)

Molinate（Molinate）, molecular formula is C₉H₁₇NOS, its structural formula is：

Molinate is a kind of low toxicity herbicide of thiocarbamates of Shi Duofu chemical companies of U.S. research.Molinate is applied in rice terrace, as relative density is more than water, is deposited in the interface of water and mud, forms the medicine layer of high concentration, when weeds pass through medicine layer, aggrieved for nascent root absorption rapidly.Molinate is applied to rice seedling bed, live field and transplant field, especially has specially good effect to barnyard grass and Herba Eleocharitis aciculariies.

Sulfonylurea herbicide is selective inner-adsorption conduction-type herbicide, can be absorbed by weeds root and blade, be conducted in plant body rapidly, and after suppressing cell division and growth, susceptible weeds to absorb medicament, plumelet and root are stopped growing rapidly, and tender tissue turns to be yellow, subsequently withered.But sulfonylurea herbicide still suffers from some difficult problems in application process, wherein most prominent is the resistance problem of its herbicide carryover and weeds to sulfonylurea herbicide.

Content of the invention

The present invention seeks to a kind of Herbicidal combinations are provided for above-mentioned weak point, so that those skilled in the art control multiple weeds or a certain unmanageable weeds species after applying these herbicides once or several times in rice crops.

The present invention obtains the Weeds distribution level needed for technical staff by promazine Sulfometuron Methyl and molinate to be combined, in a particularly advantageous manner, or even including some weeds species unmanageable.And, the amount of application that the present composition can significantly reduce single component in combination is applied, the phytotoxicity to crop is reduced.

It is an object of the invention to provide a kind of Herbicidal combinations, active component is made up of compound (A) and compound (B), and wherein (A) is the compound promazine Sulfometuron Methyl described by formula (I),

(I)

(B) it is the compound molinate that described by formula (II),

(II)

Compound (A) is 1 with the weight ratio of (B):1-1:100, preferably 1:1-1:50, further preferably 1:1-1:30, more preferably 1:1-1:20, further preferably 1:1-1:15, further preferably 1:1-1:10.

A kind of Herbicidal combinations, active component is made up of compound (A) and compound (B), filler and/or surfactant.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 1%-90% of the Herbicidal combinations.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 5%-80% of the Herbicidal combinations.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 10%-70% of the Herbicidal combinations.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 20%-70% of the Herbicidal combinations.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 30%-70% of the Herbicidal combinations.

In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 40%-60% of the Herbicidal combinations.

The dosage form of the Herbicidal combinations is wettable powder, cream, suspending agent, microcapsule, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, aqueous emulsion, ultra low volume liquids, tablet, low capacity dispersible granule, pill, microcapsule.

A kind of purposes of Herbicidal combinations in undesirable plant growing is prevented and treated.

A kind of Herbicidal combinations are preventing and treating the purposes of broad-leaved section weeds, sedge weed, the undesirable plant growing of grassy weed.

A kind of Herbicidal combinations are used for the purposes for preventing and treating undesirable plant growing in useful crop.The Herbicidal combinations can be used to prevent and treat broad-leaved section weeds, sedge weed, the purposes of the undesirable plant growing of grassy weed in Semen Tritici aestivi, corn and soybean, sugar beet, Caulis Sacchari sinensis, Cotton Gossypii, Oryza sativa L., beans, Caulis et Folium Lini, Fructus Hordei Vulgaris, Herba bromi japonici, rye (Secale cereale L.), black Semen Tritici aestivi, Brassica campestris L, Rhizoma Solani tuber osi, broomcorn millet, herbage, greenery patches or lawn, in the Zhong Huofei crop areas of fruit plantation.Can be especially useful for preventing and treating Oryza sativa L., broad-leaved section weeds, sedge weed, the purposes of the undesirable plant growing of grassy weed in lawn.

A kind of Herbicidal combinations are used for the purposes for preventing and treating undesirable plant growing in useful crop, and the Herbicidal combinations are tolerated by the useful crop.

A kind of method for preventing and treating undesirable plant growing, including：（i）Before undesirable plant germination（Before bud）;（ii）After undesirable plant germination（After bud）, or（iii）?（i）With（ii）When, the Herbicidal combinations of the present invention of herbicidally effective amount are applied to undesirable plant or which grows place.

A kind of method of the undesirable plant growing of preventing and treating, the plant that would not want to or its grow place contact with the Herbicidal combinations of the present invention of herbicidally effective amount or in water the present invention of administration herbicidally effective amount Herbicidal combinations.

The compound (A) and compound (B) of the Herbicidal combinations of the present invention collectively or individually are applied to undesirable plant or which grow place by a kind of method for preventing and treating undesirable plant growing.

A kind of method for preventing and treating undesirable plant growing, including applying the Herbicidal combinations of the present invention in the presence of other reproductive parts of the plant, the seed of useful crop or useful crop of useful crop.

A kind of reduction prevents method of the promazine Sulfometuron Methyl to the infringement caused by other reproductive parts of plant, the seed of useful crop or useful crop with its useful crop for processing, including other reproductive parts of plant, the seed of useful crop or useful crop with the described useful plant of Herbicidal combinations of the present invention process.

A kind of Herbicidal combinations of the present invention obtain the Weeds distribution level needed for technical staff by promazine Sulfometuron Methyl and molinate to be combined, in a particularly advantageous manner, or even including some weeds species unmanageable.And, the amount of application that the present composition can significantly reduce single component in combination is applied, the phytotoxicity to crop is reduced.Compound (A) of the Herbicidal combinations of the present invention comprising effective dose and compound (B) have synergistic function.

Specific embodiment

The present invention provides a kind of Herbicidal combinations, and active component is made up of compound (A) and compound (B), and wherein (A) is the compound promazine Sulfometuron Methyl described by formula (I),

(I)

(B) it is the compound molinate that described by formula (II),

(II)

The weight ratio of compound (A) and compound (B) is 1:1-1:100, preferably 1:1-1:50, further preferably 1:1-1:30, more preferably 1:1-1:20, further preferably 1:1-1:15, further preferably 1:1-1:10.

Synergistic function reduces can the rate of application of single herbicide, the effectiveness under identical rate of application is higher, prevent and treat also not controlled kind, preventing and treating to single herbicide or multiple herbicide tolerants or the kind with resistance, administration phase extend and/or the required number of times that is administered alone is reduced；And for user, obtain control of weeds system advantageously in economic and ecology.

The Herbicidal combinations of the present invention cause the activity of compound (A) and compound (B) with unexpected mode Synergistic, beyond using single compound (A) and the accessible activity of compound (B).

The rate of application of compound (A) can change in a wide range, such as 0.1g to 500g A.I./ha (hereinafter, A.I./ha represents the reactive compound meter of " active substance/hectare "=based on 100% purity).When being applied with the rate of application of 0.1 g to 500g A.I./ha, when prior to seeding, plantation before or bud before and bud after used in compound (A) when, which has relatively wide noxious plant spectrum to be prevented and treated, for example annual and perennial unifacial leaf or dicotyledonous broad leaved weed, grassy weed and sedge, and undesirable crop plants.

The rate of application of compound (B) can change in a wide range, such as 1g to 5000g A.I./ha, and which has relatively wide noxious plant spectrum to be prevented and treated.

Depending on compound (A) for example can be by reference to the rate of application of mentioned single compound with (B) suitable proportion.In the Herbicidal combinations of the present invention, rate of application can be generally reduced.In the Herbicidal combinations of the present invention, compound (A) is 1 with the weight ratio of (B):1-1:100；

Preferably, compound (A) is 1 with the weight ratio of (B):1-1:50；

Particularly, compound (A) is 1 with the weight ratio of (B):1-1:30；

More special, compound (A) is 1 with the weight ratio of (B):1-1:20.

More special, compound (A) is 1 with the weight ratio of (B):1-1:15.

More special, compound (A) is 1 with the weight ratio of (B):1-1:10.

The Herbicidal combinations of the present invention can also include one or more other reactive compound that are different from compound (A) and (B) and also serving as selective herbicide.

The Herbicidal combinations of the present invention can also include the various reactive compounds of other components, be selected from safener, antifungal, insecticide, acaricide, nematicide, bird repellent, soil conditioner, nutrient for plants (fertilizer) and structure different from compound (A) and the herbicide and plant growth regulator of (B).

Preferably，The different types of agrochemically active compound includes Acetochlor (acetochlor)、Acibenzolar (acibenzolar)、Diazosulfide (acibenzolar-S-methyl)、Acifluorfen (acifluorfen)、Aclonifen (aclonifen)、Alachlor (alachlor)、Allidochlor (allidochlor)、Alloxydimsodium (alloxydim)、Ametryn (ametryn)、Amicarbazone (amicarbazone)、Amidosulfuron (amidosulfuron)、Chlorine Fampridine acid (aminopyralid)、Amrol (amitrole)、Ammonium sulfamate (ammonium sulfamate)、Ancymidol (ancymidol)、Anilofos (anilofos)、Sulphur grass spirit (asulam)、Atrazine (atrazine)、Azafenidin (azafenidin)、Azimsulfuron (azimsulfuron)、Benfuresate (benfuresate)、Bensulfuron-methyl (bensulfuron)、Bentazone (bentazone)、Benzfendizone (benzfendizone)、Benzobicylon (benzobicyclon)、Benzofenap (benzofenap)、Fluorine sulfanilamide grass (benzofluor)、Fluorine benzofenap (bicyclopyrone)、Bispyribac-sodium (bispyribac-sodium)、Brominal (bromoxynil)、Butachlor (butachlor)、Butafenacil (butafenacil)、Butralin (butralin)、Cafenstrole (cafenstrole)、Carbetamide (carbetamide)、Carfentrazone (carfentrazone)、Chlorimuronethyl (chlorimuron，chlorimuron-ethyl)、Chlorocholine chloride (chlormequat chloride)、Chlortoluron (chlorotoluron)、Chlorine sulphur grand (chlorsulfuron)、Cinmethylin (cinmethylin)、Cinosulfuron (cinosulfuron)、Clethodim (clethodim)、Different grass pine (clomazone)、Clomeprop (clomeprop)、Clopyralid (clopyralid)、Cyanazine (cyanazine)、Cyclanilide (cyclanilide)、AC322140 (cyclosulfamuron)、Cycloxydim (cycloxydim)、Ring cafenstrole (cyprazole)、Daimuron (daimuron/dymron)、Mediben (dicamba)、Diclofop-methyl (diclofop-methyl)、Smart diclofop-methyl (diclofop-P-methyl)、Diclosulam (diclosulam)、Acetyl alachlor (diethatyl，diethatyl-ethyl)、Diflufenican (diflufenican)、Diflufenzopyr (diflufenzopyr，diflufenzopyr-sodium)、Azoles grand (dimefuron)、Dimepiperate (dimepiperate)、Dimethachlor (dimethachlor)、Dimethametryn (dimethametryn)、Diphenamide (diphenamid)、Dipropetryn (dipropetryn)、Diquat dibromide (diquat)、Diuron (diuron)、Ethametsulfuron (ethametsulfuron、ethametsulfuron-methyl)、Ethephon (ethephon)、Ethidimuron (ethidimuron)、Ethoxysulfuron (ethoxysulfuron)、Ethobenzanid (etobenzanid)、Azoles diclofop-methyl (fenoxaprop)、Fenoxaprop-P-ethyl (fenoxaprop-P)、Azoles diclofop-methyl (fenoxaprop-ethyl)、Fentrazamide (fentrazamide)、Flazasulfuron (flazasulfuron)、Florasulam (florasulam)、Fluazifop (fluazifop)、Efficient fluazifop (fluazifop-P)、Fluazifop-P-butyl (fluazifop-butyl)、Efficient fluazifop butyl ester (fluazifop-P-butyl)、Fluazolate (fluazolate)、Flucarbazonesodium (flucarbazone，flucarbazone-sodium)、Flucetosulfuron (flucetosulfuron)、Flufenacet (flufenacet)、Flumetralim (flumetralin)、Flumetsulam (flumetsulam)、Flumioxazin (flumioxazin)、Alkynes grass amine (flumipropyn)、Fluometuron (fluometuron)、Fluorodifen (fluorodifen)、Fluoroglycofen-ethyl (fluoroglycofen，fluoroglycofen-ethyl)、Flupoxam (flupoxam)、Flupyrsulfuron-methyl-sodium (flupyrsulfuron)、Fluridone (fluridone)、Fluorochloridone (flurochloridone)、Fluroxypyr (fluroxypyr)、Flurtamone (flurtamone)、Thiazole oxamide (fluthiamide)、Fomesafen (fomesafen)、Glufosinate (glufosinate，glufosinate-ammonium)、Glufosinate-P (glufosinate-P，glufosinate-P-ammonium)、Glufosinate-P- sodium salts (glufosinate-P-sodium)、Glyphosate (glyphosate)、Glyphosate-isopropylammonium (glyphosate-isopropylammonium)、Fluorine nitre sulfonamide (halosafen)、Halosulfuronmethyl (halosulfuron，halosulfuron-methyl)、Fluazifop-butyl (haloxyfop)、Smart fluazifop-butyl (haloxyfop-P)、Fluorine pyrrole second standing grain spirit (haloxyfop-ethoxyethyl)、Smart fluorine pyrrole second standing grain spirit (haloxyfop-P-ethoxyethyl)、Haloxyfop-P-methyl (haloxyfop-methyl)、Haloxyfop-methyl (haloxyfop-P-methyl)、Hexazinone (hexazinone)、Miaow oxalic acid (imazamethabenz，imazamethabenz-methyl)、Imazamox (imazamox，imazamox-ammonium)、AC 263222 (imazapic)、Imazapyr (imazapyr，imazapyr-isopropylammonium)、Imazaquin (imazaquin，imazaquin-ammonium)、Imazethapyr (imazethapyr，imazethapyr-ammonium)、Imazosulfuron (imazosulfuron)、Inabenfide (inabenfide)、Iodine metsulfuron-methyl (iodosulfuron，iodosulfuron-methyl-sodium)、Ioxynil (ioxynil)、Isoproturon (isoproturon)、Different acyl grass amine (isoxaben)、Different chlorine oxadiazon (isoxachlortole)、Isoxazole oxadiazon (isoxaflutole)、Different careless ether (isoxapyrifop)、Lactofen (lactofen)、Lenacil (lenacil)、Mefenacet (mefenacet)、Chlorine sulphonyl grass amine (mefluidide)、Methyl piperidine (mepiquat-chloride)、Mesosulfuronmethyl (mesosulfuron，mesosulfuron-methyl)、Mesotrione (mesotrione)、Methabenzthiazuron (methabenzthiazuron)、Azole amide (metamifop)、Metamitron (metamitron)、Metazachlor (metazachlor)、Methazole (methazole)、Sulfonylurea (methiopyrsulfuron)、Methoxyphenone (methoxyphenone)、Methyldymron (methyldymron)、Isopropyl methoxalamine (metolachlor)、S-metolachlor (S-metolachlor)、Metosulam (metosulam)、Metoxuron (metoxuron)、Metribuzin (metribuzin)、Metsulfuron-methyl (metsulfuron，metsulfuron-methyl)、Molinate (molinate)、Monosulfmeturon (monosulfuron)、Monosulfmeturon ester (monosulfuron ester)、1,1-dimethyl-3-(p-chlorophenyl)urea (monuron)、Napropamide (napropamide)、Nicosulfuron (nicosulfuron)、Oxadiargyl (oxadiargyl)、Oxadiazon (oxadiazon)、Oxasulfuron (oxasulfuron)、Metribuzin (oxaziclomefone)、Oxyfluorfen (oxyfluorfen)、Paclobutrazol (paclobutrazol)、N,N'-dimethyl-.gamma..gamma.'-dipyridylium (paraquat，paraquat dichloride)、Pendimethalin (pendimethalin)、Penta oxadiazon of ring (pentoxazone)、Pethoxamid (pethoxamid)、Picloram (picloram)、Fluorine pyrrole acyl grass amine (picolinafen)、Pinoxaden (pinoxaden)、Piperophos (piperophos)、Pretilachlor (pretilachlor)、Probenazole (probenazole)、Profluazol (profluazol)、Profluralin (prifluraline)、Clefoxidim (profoxydim)、Prometryn (prometryn)、Propanil (propanil)、Propazine (propazine)、N-phenyl isopropyl carbamate (propham)、Propisochlor (propisochlor)、The phonetic sulphur of piperazine imidazoles (propyrisulfuron)、Propyzamide (propyzamide)、Prosulfocarb (prosulfocarb)、Prosulfuron (prosulfuron)、Prynachlor (prynachlor)、Pyraclonil (pyraclonil)、Pyraflufen-ethyl (pyraflufen，pyraflufen-ethyl)、Pyrazosulfuron (pyrazosulfuron、pyrazosulfuron-ethyl))、Iso-propyl-ester nitrofen (pyribambenz-isopropyl)、Propyl-ester nitorfen (pyribambenz-propyl)、Pyribenzoxim (pyribenzoxim)、Pyributicarb (pyributicarb)、Pyriftalid (pyriftalid)、KIH 6127 (pyriminobac，pyriminobac-methyl)、Nylar (pyrimisulfan)、Pyrithiobacsodium (pyrithiobac，pyrithiobac-sodium)、pyroxasulfone、Pyroxsulam (pyroxsulam)、Dichloro quinolinic acid (quinchlorac)、Quinmerac (quinmerac)、Quizalofop-ethyl (quizalofop)、Quizalotop-ethyl (quizalofop-P)、Quizalotop-ethyl ethyl ester (quizalofop-P-ethyl)、Rimsulfuron (rimsulfuron)、Benzene flumetsulam (saflufenacil)、Zhong Dingtong (secbumeton)、Sethoxydim (sethoxydim)、Tupersan (siduron)、Sulphur oxadiazon (sulcotrione)、Sulfentrazone (sulfentrazone)、Sulfometuronmethyl (sulfometuron，sulfometuron-methyl)、Thidiazuron (thidiazuron)、Thifensulfuronmethyl (thifensulfuron，thifensulfuron-methyl)、Benthiocarb (thiobencarb)、Tiocarbazil (tiocarbazil)、Triasulfuron (triasulfuron)、Triaziflam (triaziflam)、Tribenuron-methyl (tribenuron，tribenuron-methyl)、Trichloroacetic acid (TCA)、Trichlopyr (triclopyr)、Tridiphane (tridiphane)、Trifloxysulfuron (trifloxysulfuron，trifloxysulfuron-sodium)、Trefanocide (trifluralin)、Triflusulfuronmethyl (triflusulfuron)、Triflusulfuronmethyl methyl ester (triflusulfuron-methyl)、Trimeturon (trimeturon)、TrinexAN_SNacethyl (trinexapac，trinexapac-ethyl)、Tritosulfuron (tritosulfuron)、tsitodef、Uniconazole P (uniconazole).

Although compound (A) and (B) have shown good or even enough selectivitys in a large amount of crops, in principle, in some crops, when particularly also mixing with the less herbicide of other selectivitys, it is possible that the phytotoxicity to crop plants.So the compositionss comprising Herbicidal combinations and one or more safener according to the present invention are particularly advantageous.The safener is with effective dose use of detoxifying, such as economically important crop or the plant toxicity side effect in herbicide used by fruit plantation (plantation crops) middle minimizing.The economically important crop such as frumentum (Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), Herba bromi japonici, Semen Maydiss, Oryza sativa L. and broomcorn millet), sugar beet, Caulis Sacchari sinensis, Brassica campestris L, Cotton Gossypii and Semen sojae atricolor, preferably frumentum, specifically for Oryza sativa L..

Hereinafter the compound (including possible stereoisomer and agriculturally conventional ester or salt) of safener is for example suitable for：Benoxacor (benoxacor)、Cloquitocet_mexyl (cloquintocet (- mexyl))、Cyometrinil (cyometrinil)、cyprosulfamide、Dichlormide (dichlormid)、dicyclonon、O- phenyl phosphoric acid o，O- diethyl esters (dietholate)、Fenchlorazole (fenchlorazole (- ethyl))、Fenclorim (fenclorim)、The careless amine (flurazole) of solution、Fluxofenim (fluxofenim)、Fenchlorazole (furilazole)、Double benzene azoles acid (isoxadifen (- ethyl))、Mefenpyrdiethyl (mefenpyr (- diethyl))、Methyl carbamic acid 4- chlorobenzene base esters (mephenate)、Naphthalic anhydride and oxabetrinil (oxabetrinil).

Some safeners known are used as herbicide, and correspondingly, in addition to there is herbicide effect to noxious plant, also act as the effect of cover crop plant.

Herbicidal combinations and the weight of safener are than generally depending on the effect of the rate of application and the safener of herbicide, and can change in a wide range, such as 90000: 1-1: 5000, preferably 7000: 1-1: 1600, especially 3000: 1-1: 500, particularly 1:100-20:In the range of 1.Safener can with compound (A) and (B) with finished product preparation prepare or with the tank mix of the Herbicidal combinations in the form of supply and use.

The present invention provides a kind of purposes of Herbicidal combinations in undesirable plant growing is prevented and treated.

The present invention provides a kind of Herbicidal combinations in the purposes for preventing and kill off broad-leaved section weeds, sedge weed, the undesirable plant growing of grassy weed.

Economically important unifacial leaf and dicotyledonous harmful plants such as broad leaved weed, grassy weed or sedge of the Herbicidal combinations of the present invention to wide range, species including having resistance to weeding active compound has excellent activity of weeding, and the weeding active compound is such as glyphosate, Glufosinate, atrazine, imidazolinone herbicide and sulfonylurea.

The monocotyledon weed and some representational instantiations of dicotyledonous weed flora group of the Herbicidal combinations preventing and treating of Tong Guo the present invention that can be mentioned that, but it is not limited to some kinds.

The example of the weed species of the herbicidal composition useful effect is, such as in monocotyledon weed with subordinate, such as Echinochloa (Echinochloa Spp.), Panicum (Panicum spp.), Poa L. (Poa spp)., Sprangletop (Leptochloa Spp.), Brachiaria (Brachiaria spp.), knotgrass (Digitaria spp.), setaria (Setaria Spp.), Cyperus (Cyperus), Monochoria (Monochoria Spp.), genus fimbristylis, Sagittaria (Sagittaria spp.), Eleocharis (Eleocharis spp.), Scirpus (Scirpus Spp.), Waterplantain (Alisma spp.), Folium Bambusae Lepidium (Aneilema spp.), water screening spp (Blyxa Spp.), eriocaulon buergerianum (Eriocaulon spp.), Potamogeton (Potamogeton spp.) etc. all prevent and treat very well, particularly following kind：Water barnyard grass (Echinochloa Oryzicola), Herba monochoriae vaginaliss (Monochoria vaginalis), yak grass (Eleocharis acicularis), Herba Equiseties Hiemalis shape Corm Eleocharitiss (Eleocharis Kuroguwai), Herba Cyperi Difformiss (Cyperus difformis), Herba Cyperi Glomerati (Cyperus serotinus), short Rhizoma sagittariae sagittifoliae (Sagittaria Pygmaea), alisma canaliculatum (Alisma canaliculatum), firefly Lin (Scirpus juncoides).In the case of broadleaf weed, activity profile is extended to subordinate, such as Polygonum (Polygonum Spp.), section section Lepidium (Rotala spp.), Vandellia (Lindernia spp.), Bidens (Bidens Spp.), sphenoclea (Sphenoclea spp.), horsefly eye category (Dopatrium spp.), Eclipta prostrata category (Eclipta Spp.), Elatine ambigua (Elatine spp.), Gratiola (Gratiola spp.), Vandellia (Lindernia Spp.), ludwigia (Ludwigia spp.), Oenanthe (Oenanthe spp.), Ranunculus (Ranunculus Spp.), damp chilly category (Deinostema spp.) etc..Particularly such as following kind：Mexicana (Rotala indica), cusp flower (Sphenoclea zeylanica), Lindernia procumbens (Krock.) Phillcox. (Lindernia Procumbens), Herba Ludwigiae Prostratae (Ludwigia prostrate), Herba potamogetonis distincti (Potamogeton distinctus), waterwort (Elatine ) and Herba Oenanthes Javanicae (Oenanthe javanica) triandra.

The present invention also provides the purposes that a kind of Herbicidal combinations are used for preventing and treating undesirable plant growing in useful crop.

The Herbicidal combinations of the present invention can be used on the farmland of useful crop below such as cultivation:

Cereal crops, for example, include：

Cereal (granule corn) such as Semen Tritici aestivi (Triticum aestivum) and little wheat crops such as durum wheat (T.durum), one grained wheat (T.monococcum), emmer wheat (T.dicoccon) With spelt (T.spelta), rye (Secale cereale L.) (Secale Cereale), Triticale hexaploide Lart. (Tritiosecale), Fructus Hordei Vulgaris (Hordeum vulgare)；

Semen Maydiss (Zea mays)；

Sorghum vulgare Pers. (such as sugar grass (Sorghum bicolour)) ；

Rice (Oryza (Oryza) such as Oryza sativa L. (Oryza sativa) and African Oryza sativa L. (Oryzaglaberrima)；

Caulis Sacchari sinensis；

Beans (Legumes (pulse family (Fabaceae))), for example, include Semen sojae atricolor (Glycine max.), Semen arachidis hypogaeae (Arachis ) and legume crop such as Semen Pisi sativi is (including Semen Pisi sativi (Pisum hypogaea Sativum), Semen Cajani and Semen vignae sinensiss), Kidney bean (including Semen Viciae fabae (Vicia faba), black mixed coloured cowpea category (Vigna) and black Phaseolus (Phaseolus)) and Seem Lablab Album (Lens culinaris Medic. (lens culinaris var.))；

Cruciferae, for example, include Canola (cabbage type rape (Brassica Napus)), Brassica campestris L (Brassica napus), Brassica oleracea L.var.capitata L. (B.oleracea var.), Caulis et Folium Brassicae junceae such as Caulis et Folium Brassicae junceae (B.juncea), Chinese cabbage (B.campestris), broadbeaked mustard (B.narinosa), black mustard (B.nigra) and Mediterranean open country brassica rapa (B.tournefortii)；And Radix Brassicae rapae (Brassica rapa var.)；

Other broad leaf crops, for example, include Helianthi, Cotton Gossypii, Caulis et Folium Lini, Semen Lini, sugar beet, Rhizoma Solani tuber osi and Fructus Lycopersici esculenti；

TNV crop (TNV：Tree, kernel and rattan), for example include Fructus Vitis viniferae, Citrus, such as a kind of fruit, such as apple, pear, etc., Fructus Mali pumilae and pears, coffee, Fructus Pistaciae Verae and Elaeis guineensis Jacq., drupe, such as Fructus Persicae, Semen Armeniacae Amarum, Semen Juglandiss, Fructus Canarii albi, Fructus Pruni pseudocerasi, Li Hexing；

Turf, herbage and pasture；

Bulbus Allii Cepae and Bulbus Allii；

Bulb ornamental plant such as Flos Tulipae Gesnerianae and narcissus；

Coniferous tree and deciduous tree such as Pinus (Pinus), fir, Oak Tree, maple, Fructus Corni, Fructus Crataegi, Caulis et folium euphorbiae milii and Rhamnuss (Rhamnus) (Fructus rhamni (Rhamnus davurica Pall.))；

Garden ornamental plant such as petunia, Flos Tagetis Erectae, Flos Rosae Rugosae and Antirrhinum majus L..

The Herbicidal combinations of the present invention are particluarly suitable for Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), Triticale hexaploide Lart., durum wheat, rice, Semen Maydiss, Caulis Sacchari sinensis, Sorghum vulgare Pers., Semen sojae atricolor, legume crop such as Semen Pisi sativi, Kidney bean and Seem Lablab Album, Semen arachidis hypogaeae, Helianthi, sugar beet, Rhizoma Solani tuber osi, Cotton Gossypii, Brassicas crop, such as Brassica campestris L, Canola, Caulis et Folium Brassicae junceae, Brassica oleracea L.var.capitata L. and Radix Brassicae rapae, turf, Fructus Vitis viniferae, core fruit, such as Fructus Mali pumilae and pears, drupe, such as Fructus Persicae, Semen Armeniacae Amarum, Semen Juglandiss, Fructus Canarii albi, Fructus Pruni pseudocerasi, Lee and Fructus Pruni, Citrus, coffee, Fructus Pistaciae Verae, garden ornamental plant, such as Flos Rosae Rugosae, petunia, Flos Tagetis Erectae, Antirrhinum majus L., bulb ornamental plant such as Flos Tulipae Gesnerianae and narcissus, coniferous tree and deciduous tree such as Pinus, fir, Oak Tree, maple, Fructus Corni, Fructus Crataegi, the growth of undesirable plant is prevented and kill off/is prevented and treated in Caulis et folium euphorbiae milii.

The Herbicidal combinations of the present invention are best suitable in Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), Triticale hexaploide Lart., durum wheat, Oryza sativa L., Semen Maydiss, Caulis Sacchari sinensis, Sorghum vulgare Pers., Semen sojae atricolor, legume crop such as Semen Pisi sativi, Kidney bean and Seem Lablab Album, Semen arachidis hypogaeae, Helianthi, sugar beet, Rhizoma Solani tuber osi, Cotton Gossypii, Brassicas crop, such as Brassica campestris L, Canola, Caulis et Folium Brassicae junceae, Brassica oleracea L.var.capitata L. and Radix Brassicae rapae, turf, Fructus Vitis viniferae, drupe, such as Fructus Persicae, Semen Armeniacae Amarum, Semen Juglandiss, Fructus Canarii albi, Fructus Pruni pseudocerasi, Li Hexing, the growth of undesirable plant in Citrus and Fructus Pistaciae Verae, is prevented and kill off/prevents and treats.

Especially in crop such as Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), Oryza sativa L., Semen Maydiss, Caulis Sacchari sinensis, Sorghum vulgare Pers., legume crop, Semen arachidis hypogaeae, Helianthi, sugar beet, Rhizoma Solani tuber osi, Cotton Gossypii, Brassicas crop, turf, Fructus Vitis viniferae, a kind of fruit, such as apple, pear, etc., drupe, Citrus, coffee, Fructus Pistaciae Verae, garden ornamental plant, coniferous tree and deciduous tree, they can effectively prevent and treat broad leaved weed, grassy weed and sedge weed, and produce injury essentially without to crop.

The Herbicidal combinations of the present invention also can admirably prevent and treat the growth of the undesirable plant in non-crop area.Non- crop area Ru Lu, railway, meadow, utility line, especially undesirable plant growing in the region for exist trees.

The Herbicidal combinations of the present invention can also be used for following crop plants, the crop plants are resistant to one or more herbicide due to genetic engineering or breeding, due to genetic engineering or breeding and to one or more pathogen, such as plant pathogenic fungi is resistant or resistant to insect infestations due to genetic engineering or breeding.The suitable crops for being, for example, to tolerate synthetic auxin, preferably Semen Maydiss, Semen Tritici aestivi, Helianthi, rice, Canola, Brassica campestris L, Semen sojae atricolor, Cotton Gossypii and Caulis Sacchari sinensis, or due to introducing the crops that gene tolerates some insect infestations by genetic modification to Bt toxin.

If active component can not be well tolerable by some crops, can by spraying apparatus directed spraying Herbicidal combinations so that they reach be grown in the following leaf for being not intended to plant or exposed soil when tactiosensible crops as few as possible.

The present invention also provide a kind of reduce or prevent method of the compound (A) to the infringement caused by other reproductive parts of plant, the seed of useful crop or useful crop with its useful crop for processing, including other reproductive parts of plant, the seed of useful crop or useful crop with the useful crop of Herbicidal combinations of the present invention process.

The amount of application of herbicide can change in very large range, and optimised quantity depends on described herbicide, noxious plant spectrum and crop spectrum.The consumption level of required herbicide depends on specific weed infestation, weeds spectrum to be controlled, auxiliary agent etc..Most preferably using relatively low amounts of herbicide.There is synergistic function in expected summation of the activity of the Herbicidal combinations of the present invention higher than each herbicidal activity that applies, compound (A) and compound (B).

Synergistic function reduces the rate of application of single herbicide, the effectiveness under identical rate of application is higher.In the Herbicidal combinations of the present invention, the rate of application of single compound is reduced and Herbicidal combinations maintain good exposure level；Secondly, in the case that the independent material in the range of low rate of application has become useless from the point of view of agronomic point, compositionss obtain high-caliber Weeds distribution.

Thus, the amount of application that Herbicidal combinations of the present invention can significantly reduce single component in compositionss is applied, so as to reduce the phytotoxicity to crop.

The compound (A) and compound (B) of the Herbicidal combinations of the present invention collectively or individually are applied to undesirable plant or which grow place by the method that the present invention provides a kind of undesirable plant growing of preventing and treating.

A kind of method for preventing and treating undesirable plant growing, including：（i）Before undesirable plant germination（Before bud）;（ii）After undesirable plant germination（After bud）, or（iii）?（i）With（ii）When, the Herbicidal combinations of the present invention of herbicidally effective amount are applied to undesirable plant or which grows place.It is preferred that the undesirable plant (such as broad leaved weed, grassy weed, sedge or undesirable crop plants) also to having germinateed before undesirable plant germination is administered, and unrelated with the trophophase of the crop of sowing/plantation.

Compound (A) of the Herbicidal combinations of the present invention comprising effective dose and compound (B) have synergistic function.When common or synergism can be observed when compound (A) and compound (B) is administered simultaneously almost；When compound (A) and compound (B) being applied respectively in the different time, also observe that synergism；Can also sequential application (A) and (B), such as apply before first bud then bud after apply, or apply after first early stage bud, then apply after mid-term or later stage bud.Here is preferably common or compound (A) and compound (B), and particularly preferably common use is almost administered simultaneously.

If the Herbicidal combinations of the present invention are applied to soil surface before germination, entirely prevent weeds seedling to germinate, or weed growth is to cotyledon period, but then which just stops growing, and final completely dead after two weeks to surrounding.

If the reactive compound to be applied to the green parts of plant after germination, just drastically stop in the suitable short time that growth equally can be after treatment, and trophophase of ruderal plant when being maintained at time of application point, or which is completely dead after some time, relatively early by this way and constantly eliminate by the competition of the weeds generation for being harmful to crop plants.For Oryza sativa L., also the Herbicidal combinations can be applied in water, then which passes through soil, bud and root and is absorbed.

When compound (A) or compound (B) common use, there is chemiluminescence.Here, expected summation of the activity of the compositionss higher than each herbicidal activity that applies.Synergism makes rate of application reduce, the preventing and treating broad leaved weed of more wide range, grassy weed and sedge, herbicide effect work faster, the persistent period is longer, more preferable prevent and treat and can widen the administration phase by applying only once or several times just to have noxious plant.The effective dose of dosage and compound (A) and (B) used in the Herbicidal combinations is all adjustable to relatively low level, so that its effect to soil is reduced to minimum degree.This causes the Herbicidal combinations of the present invention be applied to sensitive crop, also almost avoids underground water pollution.Herbicidal combinations of the present invention cause rate of application needed for active component to significantly decrease.

Above-mentioned characteristic and advantage for control of weeds is to keep agricultural/forestry/garden crop or greenery patches/meadow from undesirable competitive plant, so as to guaranteeing from the angle of quality and quantity and/or increasing what useful crop yield level was a need for.For the characteristic, this Herbicidal combinations have significantly surmounted the state of the art of this area.

The method that the present invention also provides a kind of undesirable plant growing of preventing and treating, including applying the Herbicidal combinations of the present invention in the presence of other reproductive parts of the plant, the seed of useful crop or useful crop of useful crop.

The method that the present invention also provides a kind of undesirable plant of preventing and treating, it is preferred that in useful crop plants, undesirable plant is particularly prevented and treated in rice crop, the method is included the compound (A) and compound (B) as Herbicidal combinations of the present invention, plant (for example undesirable plant is for example applied to collectively or individually, such as unifacial leaf or dicotyledonous broad leaved weed, grassy weed, sedge or undesirable crop plants), seed (such as caryopsis, seed or asexual propagation organ, such as tuber and the branch portion with bud), or it is applied to the region (region that for example cultivates of plant growing, which also can be covered with water).A kind of herbicide can be before another kind of herbicide, be applied to the region (region that for example cultivates) of plant, seed or plant growing afterwards or concurrently.

The Herbicidal combinations of the present invention can be applied in a usual manner by using technology well known to those skilled in the art.Suitable technology includes spraying, is atomized, dusting, broadcast sowing or pour.Apply type and depend on desired purpose in a well-known manner；The technology is, it is ensured that the most preferably possible distribution of active component of the present invention under any circumstance.

The present invention is most preferably for undesirable plant or which grows place preventing and treating plant growth area or the weeds that will be used in the region of long-term cropping.When for plant growth area, amount of application should be enough to control weed growth but will not produce serious permanent injury to crop.

" undesirable plant " is understood to mean that and is grown in being not intended to its all plant where growing.These can be, for example, noxious plant (such as unifacial leaf or broadleaf weed, grassy weed, sedge or undesired crop plants), including those plants for example to some weeding active compounds (such as glyphosate, Glufosinate, atrazine, imidazolinone herbicide and sulfonylurea) with resistance.

The Herbicidal combinations of the present invention can be applied by being usually used in the various application processes of rice herbicide.It is particularly preferred which is applied by spraying and/or is applied by impregnating administration.In dipping is applied, during administration, the water in paddy field had covered ground and had been up to 3-20cm.Then the Herbicidal combinations of the present invention are placed directly within the water in paddy field.Worldwide, the Oryza sativa L. for being mainly used in direct sowing is applied in spraying, and impregnates and apply the Oryza sativa L. for being mainly used in transplanting.

The method that the present invention also provides a kind of undesirable plant growing of preventing and treating, the plant that would not want to or its grow place contact with the Herbicidal combinations of the present invention of herbicidally effective amount or in water the present invention of administration herbicidally effective amount Herbicidal combinations.

The present invention also provides a kind of Herbicidal combinations, and active component is made up of compound (A) and compound (B), filler and/or surfactant.In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 1%-90% of the Herbicidal combinations, preferably 5%-80%, more preferably 10%-70%, further preferably 20%-70%, further preferably 30%-70%, further preferably 40%-60%.

The Herbicidal combinations of the present invention can be converted into conventional formulation, such as wettable powder, cream, suspending agent, microcapsule, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, aqueous emulsion, ultra low volume liquids, tablet, low capacity dispersible granule, pill, microcapsule.

According to the present invention, term " filler " refers to can be combined with active component or combines to make it easier for being administered to object（Such as plant, crop or careless class）Naturally occurring or synthetic organic or inorganic compound.Therefore, the filler is preferably inert, at least should be agricultural acceptable.The filler can be solid or liquid.

Applicable solid carrier is：Such as phyteral powdery type（The granule of such as Semen sojae atricolor powder, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem, extracts residue after plant essence etc.）, clay class（Such as Kaolin, Bentonite, acid china clay etc.）, Pulvis Talci class.Silica（Such as kieselguhr, silica sand, Muscovitum, aqueous silicic acid, calcium silicates）, activated carbon, natural mineral matter class（Pumex, attapulgite and zeolite etc.）, fire kieselguhr, sand, plastics medium etc.（Such as polyethylene, polypropylene, polyvinylidene chloride etc.）, potassium chloride, Calcium Carbonate, the inorganic mineral powder of calcium phosphate etc., ammonium sulfate, ammonium phosphate, carbamide, the chemical fertilizer of ammonium chloride etc., clay fertilizer, these materials can be used alone or two or more is mixed.

Applicable liquid-carrier can be selected in llowing group of materials, such as water, alcohol type（Such as methanol, ethanol, isopropanol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, Ketohexamethylene etc.）, ethers（Such as ether, dioxane, methylcellulose, tetrahydrofuran etc.）, aliphatic hydrocarbon class（Such as kerosene, mineral oil etc.）, aromatic hydrocarbonses class（Such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene etc.）, halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide, mineral and vegetable oil, animal oil etc..

Applicable surfactant has emulsifying agent with ion or non-ionic nature, dispersant or wetting agent, or the mixture of these surfactants.The suitable of these surfactants has fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol or the phosphate ester of phenol, the fatty acid ester of polyhydric alcohol, alkylaryl sodium sulfonate, naphthalene sulfonic acid polymer, lignosulfonates, the dendritic copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonatess, sodium alkylsulfosuccinates, oils and fatss, fatty alcohol and ethylene oxide condensate, the polyacrylates such as alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, for example based on single vinyl monomer, acrylic acid, Polyethylene oxide or polyoxypropylene or its with for example（Polynary）Alcohol or（Polynary）The combination of amine.When a kind of water insoluble in the one kind in reactive compound and/or inert carrier and when applying in water, it is necessary to there is surfactant.The ratio of surfactant is the 5%-40% of the Herbicidal combinations of the present invention.

If appropriate, can also there are other addO-on therapies, such as protecting colloid, binding agent, adhesive, thickening agent, thixotropic agent, penetrating agent, stabilizer, screening agent, sequestering agent, complex-forming agents in Herbicidal combinations of the invention.Generally, described active component can be combined with any solid or liquid additive that are conventionally used for preparation purpose.

The active component can be mixed with least one in following material by the Herbicidal combinations of the present invention by known way：Liquid-carrier or solid carrier, emulsifying agent, dispersant, wetting agent and/or protecting colloid, binding agent, adhesive, thickening agent, thixotropic agent, penetrating agent, stabilizer, screening agent, sequestering agent, complex-forming agents, water and other processing aids.

In the Herbicidal combinations, compound（A) and the content of (B) accounts for the big 1%-90% of the Herbicidal combinations, preferably 5%-80%, more preferably 10%-70%, further preferably 20%-70%, further preferably 30%-70%, further preferably 40%-60%..

The Herbicidal combinations of the present invention can be formulated as example single component-if appropriate by known method, with other reactive compounds, additive and/or common dosage forms auxiliary agent-mix preparation, then will apply after said composition in a usual manner dilute with water；Or a barrel mix formulation is formulated as by the common dilution of each component water that is individually prepared or part is individually prepared.Can individually be prepared with separate administration or the independent each component for preparing in part.Many parts can also be divided using the herbicide or Herbicidal combinations (sequential application), for example first seed dressing apply or sowing before/plantation pre-treatment or bud before apply followed by carry out apply after bud or early stage bud after apply, apply after then carrying out mid-term or later stage bud.Here is preferably used in conjunction with or almost while using the reactive compound of the compositionss, particularly preferred common use.

According to formulation properties, can with it is anticipated that object and popular environment are selecting application process, such as blade face, be impregnated with, spray, dusting, scattering and selected.

Compound (A) and (B) can with itself, its dosage form or applied by further diluting type of service prepared therefrom, such as ready to use solution, suspending agent, emulsion, powder, unguentum and granule.Can with usual manner-such as by pouring, spray, be atomized or broadcast sowing-applying them.

The Herbicidal combinations of the present invention have the form for being more easy to use, because the amount of the component has been optimal proportion.Additionally, the auxiliary agent in preparation can be adjusted each other and be optimized.

Example of formulations

Embodiment 1：+ 4% molinate suspending agent of 1% promazine Sulfometuron Methyl

Promazine Sulfometuron Methyl 1%

Molinate 4%

Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%

Sorbitan aliphatic ester 5%

Bentonite 1%

Glycerol 5%

Water complements to 100%

By each components such as active component, dispersant, wetting agent and water according to the ratio mix homogeneously of formula ,+4% molinate suspending agent of 1% promazine Sulfometuron Methyl after ground and/or high speed shear, is obtained.

+ 10% molinate wettable powder of 2 1% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 1%

Molinate 10%

Sodium butylnaphthalenesulfonate 5%

Polyoxyethylene lauryl ether carboxylic acid sodium 5%

White carbon 5%

Kaolin complements to 100%

By active component, various auxiliary agents and filler etc. by formula proportional components mix, through ultra-fine pulverizer disintegrating after, that is, obtain+10% molinate wettable powder of 1% promazine Sulfometuron Methyl.

+ 8% molinate wettable powder of 3 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 8%

Glycerine fatty acid polyoxyethylene ether 1%

Sodium lignin sulfonate 2%

White carbon supply is to 100%

By active component, various auxiliary agents and filler etc. by formula proportional components mix, through ultra-fine pulverizer disintegrating after, that is, obtain+8% molinate wettable powder of 2% promazine Sulfometuron Methyl.

+ 18% molinate water dispersible granules of 4 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 18%

To methoxyl group fatty acyl amido benzene sulfonate 6%

Sodium lauryl sulphate 5%

Ammonium sulfate 5%

Kaolin complements to 100%

By active component, dispersant, wetting agent, disintegrating agent and filler in the ratio mix homogeneously of formula, through comminution by gas stream into wettable powder, add a certain amount of water mixing extruding and make material.+ 18% molinate water dispersible granules of 2% promazine Sulfometuron Methyl are obtained after drying screening.

+ 38% molinate cream of 5 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 38%

Ethoxylated castor oil 5%

Calcium dodecyl benzene sulfonate 3%

N-Methyl pyrrolidone complements to 100%

Mentioned component is proportionally prepared, homogeneous phase is uniformly mixing to obtain.

+ 50% molinate suspension emulsion of 6 10% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 10%

Molinate 50%

Methyl naphthalene sulfonate formaldehyde condensate 5%

Ethoxylated castor oil 3%

Bentonite 1%

N-Methyl pyrrolidone 20%

Water complements to 100%

Promazine Sulfometuron Methyl suspending agent will be obtained after ground to promazine Sulfometuron Methyl, methyl naphthalene sulfonate formaldehyde condensate, water and/or high speed shear；The cream that molinate, N-Methyl pyrrolidone, ethoxylated castor oil mixing and stirring are obtained molinate；The molinate cream for obtaining is added in promazine Sulfometuron Methyl suspending agent ,+50% molinate suspension emulsion of 10% promazine Sulfometuron Methyl is obtained.

+ 20% molinate wettable powder of 7 10% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 10%

Molinate 20%

Sodium lauryl sulphate 6%

Sodium metnylene bis-naphthalene sulfonate 3%

White carbon 20%

Kaolin complements to 100%

Said components are mixed in proportion, and are ground, crushed, be prepared into wettable powder.

+ 60% molinate water dispersible granules of 8 10% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 10%

Molinate 60%

MODIFIED LIGNOSULPHONATE 5%

Sodium lauryl sulphate 3%

Sodium chloride 1%

Kaolin complements to 100%

By promazine Sulfometuron Methyl, molinate active component, dispersant, wetting agent, disintegrating agent and filler in formula ratio mix homogeneously, through comminution by gas stream into wettable powder；Add a certain amount of water mixing extruding and make material.+ 60% molinate water dispersible granules of 10% promazine Sulfometuron Methyl are obtained after drying screening.

+ 0.5% molinate aqueous emulsion of 9 0.5% promazine Sulfometuron Methyl of embodiment

Oil phase：

Promazine Sulfometuron Methyl 0.5%

Molinate 0.5%

SOLVESSO^TM 100 10%

Ethoxylated castor oil 5%

Water phase：

The sodium salt of the LOMAR PWA EINECS 246-676-2-formaldehyde condensation products of sulfonation 1%

Water complements to 100%

Promazine Sulfometuron Methyl, molinate are dissolved in methyl oleate, add ethoxylated castor oil to obtain oil phase；According to formula by the sodium salt of the LOMAR PWA EINECS 246-676-2-formaldehyde condensation products of sulfonation, water, mix homogeneously obtain water phase；Oil phase addition water is mutually obtained aqueous emulsion under agitation.

+ 45% molinate wettable powder of 10 5% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 5%

Molinate 45%

Octylphenol polyethylene oxyethylene group ether sulfate 1%

Sodium lauryl sulfate 2%

The silicic acid of high degree of dispersion 1%

Sodium carbonate 10%

Kaolin complements to 100%

+ 50% molinate granule of 11 5% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 5%

Molinate 50%

Polyethylene Glycol 3%

The silicic acid of high degree of dispersion 1%

Calcium Carbonate complements to 100%

In a mixer, by levigate active component even spread on by the carrier of Polyethylene Glycol moistening.Granule can be obtained in this way.

+ 30% molinate wettable powder of 12 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 30%

Sodium lauryl sulphate 5%

Sodium lignin sulfonate 5%

Attapulgite complements to 100%

+ 40% molinate of 13 2% promazine Sulfometuron Methyl of embodiment extrudes granule

Promazine Sulfometuron Methyl 2%

Molinate 40%

Sodium lignin sulfonate 4%

Carboxymethyl cellulose 2%

Kaolin complements to 100%

Active component is mixed with auxiliary agent and is ground, mixture water-wet.By the mixture extrusion, then dry in the air stream.

+ 5% molinate seed coat agent of 14 0.5% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 0.5%

Molinate 5%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthan gum 1%

Bentonite 1%

Glycerol 5%

PVP-K30 1%

Water complements to 100%

Above-mentioned each component is mixed in proportion, and through sand milling, is prepared into seed coat agent.

+ 36% molinate microcapsule suspension-suspendinagent agent of 15 9% promazine Sulfometuron Methyl of embodiment

Synperonic PE/64 5%

Citric acid 0.05%

Catalyst 0.1%

Water 10%

Molinate 36%

PAPI 1.35%

SOLVESSO^TM 100 5%

Synperonic PE/64 5%

Dispersant LFH 0.15%

Defoamer 0.16%

Carbamide 4%

Promazine Sulfometuron Methyl 9%

Water complements to 100%

By PAPI, molinate, SOLVESSO^TM 100 oil phases for being formed are added in the aqueous solution containing Synperonic PE/64, form emulsion.Then heat and be incubated 50^oCatalyst reaction is added 2 hours under C.The microcapsule of molinate is obtained after cooling.

Synperonic PE/64, dispersant LFH, defoamer, carbamide, promazine Sulfometuron Methyl and water are mixed in proportion, and through sand milling, are prepared into suspending agent.

The molinate microcapsule for obtaining is added in the suspending agent of promazine Sulfometuron Methyl ,+36% molinate microcapsule suspension-suspendinagent agent of 9% promazine Sulfometuron Methyl is uniformly mixing to obtain.

+ 30% molinate suspended emulsion of 16 1% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 1%

Molinate 30%

SOLVESSO^TM 200 10%

Ethoxylated castor oil 4%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 5%

MODIFIED LIGNOSULPHONATE 5%

Xanthan gum 1%

Bentonite 1%

Glycerol 5%

Water complements to 100%

Molinate is dissolved in SOLVESSO^TMIn 200, ethoxylated castor oil is added, the cream of molinate is obtained；

By promazine Sulfometuron Methyl, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component is mixed in proportion, and through sand milling, is prepared into suspending agent.

Oil phase containing molinate is added in the suspending agent of Sulfometuron Methyl containing promazine, suspended emulsion is obtained.

+ 88% molinate cream of 17 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 88%

Ethoxylated castor oil 2%

Calcium dodecyl benzene sulfonate 2%

SOLVESSO^TM200 Complement to 100%

Above-mentioned each component is mixed, is stirred to obtaining transparent homogeneous phase.

+ 60% molinate of 19 40% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 40%

Molinate 60%

By promazine Sulfometuron Methyl, molinate proportionally mix homogeneously.

+ 38% pair of benzene azoles acid of+60% molinate of 20 2% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 60%

Double benzene azoles acid 38%

By promazine Sulfometuron Methyl, molinate, the sour proportionally mix homogeneously of double benzene azoles.

+ 91% molinate of 21 9% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 9%

Molinate 91%

By promazine Sulfometuron Methyl, molinate proportionally mix homogeneously.

+ 80% molinate wettable powder of 222% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 2%

Molinate 80%

White Carbon black 18%

By promazine Sulfometuron Methyl, molinate, White Carbon black proportionally mix homogeneously.

+ 30% cloquitocet_mexyl of+60% molinate of 23 10% promazine Sulfometuron Methyl of embodiment

Promazine Sulfometuron Methyl 10%

Molinate 60%

Cloquitocet_mexyl 30%

By promazine Sulfometuron Methyl, molinate, cloquitocet_mexyl proportionally mix homogeneously.

Above example per distribution ratio is weight per distribution ratio.

Biological Examples

Pre-emergence test：

Under greenhouse experiment, test plant is seeded in Seedling alms bowl.Standard soil is used as cultivation matrix.In the bud last stage, herbicide is administered to individually or in combination soil surface.Soil surface keeps certain water yield to simulate the water yield under field test in rice terrace.The consumption of herbicide depends on optium concentration determined by under field or greenhouse experiment.Test in post-evaluation in 2 ~ 4 weeks（100% effect=plant is completely dead；0% effect=plant-less toxicity is acted on）.The combination of promazine Sulfometuron Methyl and molinate shows, than more preferable preventive effect is administered alone, to show obvious potentiation in this test.

When the Herbicidal combinations of the present invention are applied before rudiment, can entirely prevent that weeds emerge or weed growth to cotyledon period and then stops growing and completely death after 3 ~ 4 weeks.

After seedling is tested

Using potted plant cauline leaf process method (NY/T 1155.4-2006)：In the built-in quantitative soil of the polypots of high 6cm, diameter 9cm, by 15 ~ 20 sowings of seed of unifacial leaf and dicots weeds in polypots, warm indoor cultivation is placed on after the thick fine earths of 0.5 ~ 1cm of lid, treat that weeds length carries out stem and leaf spraying treatment to 2 ~ 4 leaf phases, per alms bowl spraying liquid 1mL, often process and be repeated 4 times, and process without medicament is set for compareing.Warm indoor cultivation, the growing state of routine observation target weeds, range estimation target damage symptoms and growth inhibited situation after 21d being placed in after process, and claiming aerial partss fresh weight or strain fresh weight, toxicity action of the medicament to target weeds is evaluated with target fresh weight inhibition.

Three kinds of reagents are prepared according to constant weight percentage ratio：1st, promazine Sulfometuron Methyl；2nd, molinate；3rd, promazine Sulfometuron Methyl+molinate.Afterwards by above-mentioned each reagent dilute with water, medicament diluent is obtained.

Investigation method：

Range estimation target damage symptoms and growth inhibited situation after test process 21d, and claim aerial partss fresh weight, calculate fresh weight inhibition (%).

" CalculationSynergistic is based on to the evaluation of the mixed potentiation for applying middle display of two or more herbicidal active components Colby ' s methods described in and Antagonistic Response of Herbicide Combinations " (Weeds 15/1 (1967), S.R.Colby) determine.

In formula, X is fresh weight inhibition of the promazine Sulfometuron Methyl with certain dosage when alone to target weeds；

Y is fresh weight inhibition of the molinate with certain dosage when alone to target weeds；

E₀For promazine Sulfometuron Methyl and theoretical value during two kinds of pharmacy mix of molinate to target weeds fresh weight inhibition；

E is promazine Sulfometuron Methyl and measured value during two kinds of pharmacy mix of molinate to target weeds fresh weight inhibition.

If the control of weeds rate (E) of the reality that observes in biologic test exceedes uses the calculated desired value (E of Colby ' s methods₀), then it represents that summation of the effect of Herbicidal combinations more than each agent effectiveness, it means that compositionss have potentiation.

Important noxious plant of the Herbicidal combinations of the present invention for following wide spectrum（Grassy weed, broad leaved weed, sedge weed) tested：Rice barnyard grass (Echinochloa oryzicola), Herba Digitariae (Digitaria Spp.) Herba stellariae mediae (Stellaria media), Amaranthus retroflexus (Amaranthus retroflexus), volume stem smartweed (Fallopia (ex Polygonum) Convolvulus), Herba Abutili (Abuthilon Theophrasti), the Sagittaria trifolia L. Var. Angusti-folia(Sieb.) Kitag.(Sagittaria sagittifolia L.) of anti-sulfonylureas（Sagittariatrifolia）, Rhizoma Alismatis（Oriental Waterplantain Rhizome）, anti-sulfonylureas Herba monochoriae vaginaliss（Herb of Pygmy Arrowhead）, Monochoria korsakowii（Monochoria korsakowii）, Lindernia procumbens (Krock.) Phillcox.（Lindernia procumbens）, Herba Solani Nigri (Solanum nigrum L.), firefly Lin（Scirpus juncoides Roxb）, anti-sulfonylureas Herba Cyperi Difformiss（Cyperus Difformis L.）, Herba chenopodii（Chenopodium alum L.）, wild oat（Avena fatua L.）, Herba Galii Teneri（Galium aparine L. var. tenerum Gren.et (Godr.) Rebb.）.

Activity to rice barnyard grass

Activity to Semen Euphorbiae

The activity of the Sagittaria trifolia L. Var. Angusti-folia(Sieb.) Kitag.(Sagittaria sagittifolia L.) of antagonism sulfonylureas

The activity of the Herba Cyperi Difformiss of antagonism sulfonylureas

Result of the test shows：Promazine Sulfometuron Methyl and molinate are 1:1-1:In the range of 100, prevent and kill off grassy weed, the broad leaved weed of anti-sulfonylureas, anti-sulfonylureas sedge weed and show obvious potentiation, which effectively ensure that the preventing and treating of the weeds to the anti-sulfonylurea herbicide in current part, improve the effect of antagonism weed control

Summary, the Herbicidal combinations of the present invention, activity when preventive effect is administered alone better than each component, the test of pesticide effectiveness verifies which is combined with potentiation, expands control of weeds spectrum, a dispenser and prevents and kill off the crop fields grass family, broad leaved weed and sedge weed, reduces spraying times, reduce cost accounting, slow down the generation of Weed Resistance, good to crop safety, meet the security requirement of pesticidal preparations.Can be used for rice field, corn and soybean, corn, Helianthi, Rhizoma Solani tuber osi, Semen arachidis hypogaeae, the closing weeding of Cotton Fields before seedling or postemergence weed control.

Safety effect

Under greenhouse experiment, test plant rice paddy seed is planted in plastic tank, the 4- leaf phases are grown in plastic tank.In this stage, by single promazine Sulfometuron Methyl, molinate, promazine Sulfometuron Methyl+molinate compositionss, be administered to test plant.After applying 3 weeks, evaluation phytotoxicity of the herbicide to crop is measured using percentage rate.100% represents that test plant is completely dead, and 0% represents plant-less toxicity effect.

It can be seen that, promazine Sulfometuron Methyl and the combination of molinate, the compatibility of promazine Sulfometuron Methyl and crops is improved, reduces or prevent promazine Sulfometuron Methyl to the infringement caused by other reproductive parts of plant, the seed of useful crop or useful crop with its useful crop for processing.

Claims

1. a kind of Herbicidal combinations, it is characterised in that active component is made up of compound (A) and compound (B), and wherein (A) is the compound described by formula (I)：

(I)

And (B) is the compound described by formula (II)：

(II)

2. Herbicidal combinations according to claim 1, it is characterised in that also include filler and/or surfactant.

3. Herbicidal combinations according to claim 1, characterized in that, dosage form is wettable powder, cream, suspending agent, microcapsule, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, aqueous emulsion, ultra low volume liquids, tablet, low capacity dispersible granule, pill, microcapsule.

4. Herbicidal combinations according to claim 1, it is characterised in that the content of compound (A) and (B) accounts for the 1%-90% of the Herbicidal combinations, it is preferred that 5%-80%, more preferably 10%-70%, further preferably 20%-70%, further preferably 30%-70%, further preferably 40%-60%.

5. purposes of the Herbicidal combinations of claim 1 in undesirable plant growing is prevented and treated.

6. purposes of the Herbicidal combinations of claim 1 in preventing and treating broad-leaved section weeds, sedge weed, undesirable plant growing of grassy weed.

7. the purposes of the Herbicidal combinations of claim 1 broad-leaved section weeds, sedge weed, undesirable plant growing of grassy weed in preventing and treating Semen Tritici aestivi, corn and soybean, sugar beet, Caulis Sacchari sinensis, Cotton Gossypii, Oryza sativa L., beans, Caulis et Folium Lini, Fructus Hordei Vulgaris, Herba bromi japonici, rye (Secale cereale L.), black Semen Tritici aestivi, Brassica campestris L, Rhizoma Solani tuber osi, broomcorn millet, herbage, greenery patches or lawn, in the Zhong Huofei crop areas of fruit plantation.

8. the method for the undesirable plant growing of a kind of preventing and treating, it is characterised in that include：（i）Before undesirable plant germination（Before bud）;（ii）After undesirable plant germination（After bud）, or（iii）?（i）With（ii）When, the Herbicidal combinations described in claim 1 are applied to undesirable plant or which grows place.

9. the method for the undesirable plant of a kind of preventing and treating, it is characterised in that the compound (A) and (B) of the Herbicidal combinations described in claim 1 collectively or individually are applied to undesirable plant or its growth place.

10. the method for the undesirable plant growing of a kind of preventing and treating, it is characterised in that include applying the Herbicidal combinations described in claim 1 in the presence of other reproductive parts of the plant, the seed of useful crop or useful crop of useful crop.

A kind of 11. methods for preventing and treating undesirable plant growing, characterized in that, the plant or its growth place including would not want to is contacted with the Herbicidal combinations described in the claim 1 of herbicidally effective amount or applies the Herbicidal combinations described in the claim 1 of herbicidally effective amount in water.

A kind of 12. reductions prevent method of the promazine Sulfometuron Methyl to the infringement caused by other reproductive parts of plant, the seed of useful crop or useful crop with its useful crop for processing, characterized in that, other reproductive parts of the plant, the seed of useful crop or useful crop including processing useful plant with the Herbicidal combinations described in claim 1.