CN106430974B - A kind of ox blood color copper red ceramic glaze and preparation method thereof - Google Patents
A kind of ox blood color copper red ceramic glaze and preparation method thereof Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 88
- 239000008280 blood Substances 0.000 title claims abstract description 57
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 50
- 239000010949 copper Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 210000004369 blood Anatomy 0.000 title claims description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000002994 raw material Substances 0.000 claims abstract description 66
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 52
- 239000000843 powder Substances 0.000 claims abstract description 35
- 239000000440 bentonite Substances 0.000 claims abstract description 34
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 34
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 34
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 30
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229940116318 copper carbonate Drugs 0.000 claims abstract description 27
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract description 27
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 27
- 239000011787 zinc oxide Substances 0.000 claims abstract description 27
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 17
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 17
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 17
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000292 calcium oxide Substances 0.000 claims abstract description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000498 ball milling Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000010304 firing Methods 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 241000276489 Merlangius merlangus Species 0.000 claims 6
- 239000010433 feldspar Substances 0.000 claims 5
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 3
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- OVFCVRIJCCDFNQ-UHFFFAOYSA-N carbonic acid;copper Chemical compound [Cu].OC(O)=O OVFCVRIJCCDFNQ-UHFFFAOYSA-N 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 33
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 25
- 241000283690 Bos taurus Species 0.000 abstract description 13
- 239000000126 substance Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 238000002474 experimental method Methods 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Glass Compositions (AREA)
Abstract
一种牛血色铜红陶瓷釉及其制备方法，属于陶瓷技术领域。该牛血色铜红陶瓷釉，包含的各个原料组分质量百分比为：熔块13.8～18.2％、钾长石粉53.1～55％、二氧化硅19～21％、白垩粉3.8～6.8％、氧化锌3.9～4.2％、氧化锡0.5～1.5％、碳酸铜0.5～0.8％和膨润土1～1.9％。熔块，包含的各个原料组分质量百分比为：氧化钾1.5～2.5％、氧化钠15.5～16.5％、氧化钙6.9～7.9％、氧化钡2.1～3.1％、三氧化二铝2.4～2.9％和二氧化硅65～71.6％。制备牛血色铜红陶瓷釉的釉色具有特有的陶瓷釉料艺术效果，其釉面厚重，红色发色效果浓重，制备方法可以让陶瓷釉的物理和化学性质稳定，在‑35℃的温度条件下长时间实验，未出现釉面裂纹或脱落现象，能够耐普通酸碱腐蚀。A bovine blood-colored copper red ceramic glaze and a preparation method thereof belong to the technical field of ceramics. The bovine blood-colored copper-red ceramic glaze contains the following mass percentages of raw material components: frit 13.8-18.2%, potassium feldspar powder 53.1-55%, silicon dioxide 19-21%, chalk powder 3.8-6.8%, zinc oxide 3.9-4.2%, tin oxide 0.5-1.5%, copper carbonate 0.5-0.8% and bentonite 1-1.9%. The frit contains the mass percentage of each raw material component: potassium oxide 1.5-2.5%, sodium oxide 15.5-16.5%, calcium oxide 6.9-7.9%, barium oxide 2.1-3.1%, aluminum oxide 2.4-2.9% and Silica 65 to 71.6%. The glaze color of the ox-blood copper red ceramic glaze has a unique artistic effect of the ceramic glaze. The glaze surface is thick and the red coloring effect is strong. The preparation method can stabilize the physical and chemical properties of the ceramic glaze. Under the temperature condition of ‑35℃ After long-term experiments, there is no glaze crack or peeling phenomenon, and it can resist common acid and alkali corrosion.
Description
技术领域technical field
本发明涉及陶瓷技术领域，特别涉及一种牛血色铜红陶瓷釉及其制备方法。The invention relates to the technical field of ceramics, in particular to a bovine blood-colored copper red ceramic glaze and a preparation method thereof.
背景技术Background technique
陶瓷釉是陶瓷制作生产时必须使用的一种重要原料，对陶瓷的坯体有很强的保护作用，同时硅酸盐的物理特性，使得陶瓷表面的玻璃釉质可以有效的抗酸碱的腐蚀，有很好抗菌性。牛血色铜红陶瓷釉烧制的陶瓷产品，具有色釉自身的艺术美感和高温烧制过程中产生的特殊艺术效果。牛血色铜红陶瓷釉有效的克服了陶瓷釉在色彩肌理效果单一方面的不足，产生自然的纹理艺术效果，同时物理和化学性质稳定。牛血色铜红陶瓷釉应用范围为十分广泛：可以应用在建筑外墙陶瓷、室内装饰陶瓷、器皿餐具陶瓷上，不含有铅、铬等重金属，绿色环保，对人体没有伤害。在制备工艺上先将部分矿物质原料制作成熔块，然后在和其他原料以及有色金属原料区分开球磨的时间，有色金属的发色效果更好、物理性能更加稳定。Ceramic glaze is an important raw material that must be used in the production of ceramics. It has a strong protective effect on the body of the ceramic. At the same time, the physical properties of silicate make the glass enamel on the ceramic surface can effectively resist acid and alkali corrosion. Has good antibacterial properties. The ceramic products fired by the ox blood copper red ceramic glaze have the artistic beauty of the color glaze and the special artistic effect produced in the high temperature firing process. The ox blood copper red ceramic glaze effectively overcomes the deficiency of the ceramic glaze in the single aspect of color and texture effect, and produces a natural texture and artistic effect, and at the same time, the physical and chemical properties are stable. The application range of ox blood copper red ceramic glaze is very wide: it can be used in building exterior wall ceramics, interior decoration ceramics, utensils and tableware ceramics. It does not contain heavy metals such as lead and chromium. It is green and environmentally friendly and does not harm the human body. In the preparation process, some mineral raw materials are first made into frit, and then the ball milling time is distinguished from other raw materials and non-ferrous metal raw materials. The color development effect of non-ferrous metals is better and the physical properties are more stable.
发明内容SUMMARY OF THE INVENTION
本发明的目的是提供一种牛血色铜红陶瓷釉及其制备方法，要解决的技术问题是让陶瓷釉质呈现牛血红色表面效果，同时达到陶瓷釉的物理和化学性质稳定。该牛血色铜红陶瓷釉原料组成经过了长时间的实验和多次的调整，最终制备的陶瓷釉性能稳定。The purpose of the present invention is to provide a bovine blood-colored copper-red ceramic glaze and a preparation method thereof, and the technical problem to be solved is to make the ceramic enamel present a bovine-blood red surface effect, while achieving stable physical and chemical properties of the ceramic glaze. The composition of the raw material of the ox-blood copper-red ceramic glaze has undergone long-term experiments and multiple adjustments, and the final prepared ceramic glaze has stable performance.
本发明采用了以下的技术方案：The present invention adopts the following technical scheme:
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块13.8～18.2％、钾长石粉53.1～55％、二氧化硅19～21％、白垩粉3.8～6.8％、氧化锌3.9～4.2％、氧化锡0.5～1.5％、碳酸铜0.5～0.8％和膨润土1～1.9％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 13.8-18.2%, potassium feldspar powder 53.1-55%, silica 19-21%, chalk powder 3.8-6.8%, zinc oxide 3.9-4.2%, tin oxide 0.5-1.5%, copper carbonate 0.5-0.8% and bentonite 1 to 1.9%.
其中，所述的熔块，其原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾1.5～2.5％、氧化钠15.5～16.5％、氧化钙6.9～7.9％、氧化钡2.1～3.1％、三氧化二铝2.4～2.9％和二氧化硅65～71.6％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 1.5-2.5%, Sodium oxide 15.5-16.5%, calcium oxide 6.9-7.9%, barium oxide 2.1-3.1%, aluminum oxide 2.4-2.9% and silicon dioxide 65-71.6%.
作为优选，所述的牛血色铜红陶瓷釉，包含的各个原料组分的质量百分比为：As preferably, the described ox blood copper red ceramic glaze, the mass percent of each raw material component that comprises is:
熔块14.5％、钾长石粉53.1％、二氧化硅19.3％、白垩粉5.8％、氧化锌3.9％、氧化锡1％、碳酸铜0.5％和膨润土1.9％。Frit 14.5%, potassium feldspar powder 53.1%, silica 19.3%, chalk powder 5.8%, zinc oxide 3.9%, tin oxide 1%, copper carbonate 0.5% and bentonite 1.9%.
作为优选，所述的牛血色铜红陶瓷釉，包含的各个原料组分的质量百分比为：As preferably, the described ox blood copper red ceramic glaze, the mass percent of each raw material component that comprises is:
熔块14.5％、钾长石粉53.1％、二氧化硅19％、白垩粉5.8％、氧化锌3.9％、氧化锡1％、碳酸铜0.8％和膨润土1.9％。Frit 14.5%, potassium feldspar powder 53.1%, silica 19%, chalk powder 5.8%, zinc oxide 3.9%, tin oxide 1%, copper carbonate 0.8% and bentonite 1.9%.
作为优选，所述的熔块，包含的各个原料组分的质量百分比为：Preferably, described frit, the mass percentage of each raw material component that comprises is:
氧化钾1.5％、氧化钠15.5％、氧化钙6.9％、氧化钡2.1％、三氧化二铝2.4％和二氧化硅71.6％。Potassium oxide 1.5%, sodium oxide 15.5%, calcium oxide 6.9%, barium oxide 2.1%, aluminum oxide 2.4% and silicon dioxide 71.6%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加热至760～800℃，烧制25～35min后，熔成玻璃状物，水冷，制得熔块；According to the raw material composition of the frit, the ingredients are prepared, and the raw material of the frit is heated to 760-800 ° C, and after firing for 25-35 minutes, it is melted into a glass-like substance, and water-cooled to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入水，混合后，加入到球磨机内，球磨机转速为450～550rpm，球磨时间4～4.5h，过滤，去除未精磨的杂质；其中，按质量比，水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝(1.2～1)∶1；(1) Carry out ingredients according to the raw material composition of ox blood copper red ceramic glaze, add frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite, add water, after mixing, add into the ball mill, the ball mill rotating speed is 450～550rpm , ball milling time 4～4.5h, filter, remove the impurity that is not finely ground; Wherein, by mass ratio, water: (frit + potassium feldspar powder + silicon dioxide + chalk powder + bentonite) = (1.2 ~ 1): 1 ;
(2)向球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速450～550rpm，球磨时间为0.5～1h，制得牛血色铜红陶瓷釉。(2) Add zinc oxide, tin oxide, and copper carbonate to the ball mill, and continue ball milling at a speed of 450-550 rpm, and the ball-milling time is 0.5-1 h to obtain a ox-blood copper-red ceramic glaze.
所述的步骤1中，熔块的原料放入坩埚中，用明火进行加热烧制。In the step 1, the raw material of the frit is put into a crucible, and heated and fired with an open flame.
所述的步骤1中，小规模制作熔块，采用坩埚水冷；大规模制作熔块，采用窑炉水冷，该方法可以有效排除原料中的挥发物和有效分解气体，从而减少烧成釉面起泡。In the described step 1, small-scale production of frit, using crucible water cooling; large-scale production of frit, using kiln water cooling, this method can effectively remove the volatiles in the raw materials and effectively decompose the gas, thereby reducing the glaze from firing. Bubble.
所述的步骤2中，所述的水为纯净水；所述的球磨机为快速球磨机。In the step 2, the water is pure water; the ball mill is a fast ball mill.
所述的步骤2(1)中，采用400目筛子进行过滤。In the described step 2 (1), 400 mesh sieves are used to filter.
所述的步骤2(1)中，所述的球磨机的球磨参数优选为：球磨转速450rpm，球磨时间4～4.5h；所述的步骤2(2)中，所述的球磨机的球磨参数优选为：球磨转速450rpm，球磨时间1h。In the step 2(1), the ball milling parameters of the ball mill are preferably: the ball milling speed is 450rpm, and the ball milling time is 4-4.5h; in the step 2(2), the ball milling parameters of the ball mill are preferably: : Ball milling speed 450rpm, ball milling time 1h.
本发明的一种牛血色铜红陶瓷釉及其制备方法，与现有技术相比，具有如下有益效果：Compared with the prior art, a bovine blood-colored copper red ceramic glaze and a preparation method thereof of the present invention have the following beneficial effects:
本发明制备的牛血色铜红陶瓷釉，该陶瓷釉色具有特有的陶瓷釉料艺术效果，其釉面厚重，红色发色效果浓重，经过多次实验证明牛血色铜红陶瓷釉性能稳定。牛血色铜红陶瓷釉具有良好物理性，在-35℃的温度条件下长时间实验，未出现釉面裂纹或脱落现象。牛血色铜红陶瓷釉化学性能稳定，能够耐普通酸碱腐蚀，氢氟酸除外。牛血色铜红陶瓷釉用途广泛，不含有铅、铬等重金属，绿色环保，对人体没有伤害。The ox-blood copper-red ceramic glaze prepared by the invention has the unique artistic effect of ceramic glaze, the glaze surface is thick and the red coloring effect is strong, and the performance of the ox-blood copper-red ceramic glaze is proved to be stable through many experiments. The ox-blood copper red ceramic glaze has good physical properties, and no glaze cracks or shedding appeared in the long-term experiment under the temperature of -35 °C. The ox blood copper red ceramic glaze has stable chemical properties and is resistant to common acid and alkali corrosion, except for hydrofluoric acid. The ox-blood copper-red ceramic glaze has a wide range of uses, does not contain heavy metals such as lead and chromium, is green and environmentally friendly, and does not harm the human body.
由于使用了熔块的制作，在釉的工艺上更加复杂，但是减少了由于原料中的气体造成的釉面烧成后出现针孔和低温釉面脱落的现象。碳酸铜，在饱和状态下，经过还原火焰烧制，可以出现牛血红色现象。钾长石粉和二氧化硅，使得陶瓷玻璃釉相表面的物理和化学性质稳定，烧制成功率高，既适合艺术陶瓷配制少量的釉，又适合大型陶瓷生产企业大量加工规模生产。Due to the use of frit, the glaze process is more complicated, but the phenomenon of pinholes and low-temperature glaze falling off after the glaze is fired due to the gas in the raw material is reduced. Copper carbonate, in the saturated state, can appear bovine blood red after being fired in a reducing flame. Potassium feldspar powder and silica make the physical and chemical properties of the ceramic glass glaze surface stable, and the firing rate is high. It is not only suitable for artistic ceramics to prepare a small amount of glaze, but also suitable for large-scale ceramic production enterprises to process large-scale production.
本发明的牛血色铜红陶瓷釉的制作方法具有以下的优点：首先，制作了熔块，该熔块的配比，对防止釉的表面出现气泡起到关键的作用；其次，制作工艺调整了原料的球磨时间顺序：先球磨熔块、钾长石粉、二氧化硅、白垩粉、膨润土，再球磨氧化锌、氧化锡、碳酸铜等金属氧化物，该制作工艺，有效的保证了牛血色铜红陶瓷釉的颜色稳定性。The preparation method of the ox-blood copper red ceramic glaze of the present invention has the following advantages: first, a frit is produced, and the proportion of the frit plays a key role in preventing bubbles from appearing on the surface of the glaze; secondly, the production process adjusts The time sequence of ball milling of raw materials: first ball mill frit, potassium feldspar powder, silicon dioxide, chalk powder, bentonite, and then ball mill metal oxides such as zinc oxide, tin oxide, copper carbonate, etc. This production process effectively guarantees bovine blood copper Color stability of red ceramic glazes.
具体实施方式Detailed ways
下面结合具体的实施对本发明作进一步的详细说明。The present invention will be further described in detail below in conjunction with specific implementation.
实施例1Example 1
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块14.5％、钾长石粉53.1％、二氧化硅19.3％、白垩粉5.8％、氧化锌3.9％、氧化锡1％、碳酸铜0.5％和膨润土1.9％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 14.5%, potassium feldspar powder 53.1%, silica 19.3%, chalk powder 5.8%, zinc oxide 3.9%, tin oxide 1%, copper carbonate 0.5% and bentonite 1.9%.
其中，熔块的原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾1.5％、氧化钠15.5％、氧化钙6.9％、氧化钡2.1％、三氧化二铝2.4％和二氧化硅71.6％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 1.5%, sodium oxide 15.5%, oxide Calcium 6.9%, barium oxide 2.1%, aluminum oxide 2.4% and silicon dioxide 71.6%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加入坩埚中，用明火加热至760℃，烧制30min后，熔成玻璃状物，水冷，制得熔块；According to the composition of the raw materials of the frit, the raw materials of the frit are added into the crucible, heated to 760 ° C with an open fire, and after firing for 30 minutes, it is melted into a glass-like substance, and cooled with water to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入纯净水，混合后，加入到快速球磨机内，球磨机转速为450rpm，球磨时间4.5h，用400目的筛子进行过滤，去除未精磨的杂质；其中，按质量比，纯净水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝1.2∶1；(1) Carry out ingredients according to the raw material composition of the ox blood copper red ceramic glaze, add the frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite into pure water, after mixing, add it into a fast ball mill, and the ball mill rotating speed is 450rpm , the ball milling time is 4.5h, filter with a 400-mesh sieve to remove impurities that are not refined; wherein, by mass ratio, pure water: (frit + potassium feldspar powder + silicon dioxide + chalk powder + bentonite) = 1.2: 1 ;
(2)向快速球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速450rpm，球磨时间为1h，制得牛血色铜红陶瓷釉。(2) Add zinc oxide, tin oxide and copper carbonate to the rapid ball mill, and continue ball milling at 450 rpm and 1 hour for ball milling time to obtain ox-blood copper red ceramic glaze.
实施例2Example 2
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块14.5％、钾长石粉53.1％、二氧化硅19％、白垩粉5.8％、氧化锌3.9％、氧化锡1％、碳酸铜0.8％和膨润土1.9％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 14.5%, potassium feldspar powder 53.1%, silica 19%, chalk powder 5.8%, zinc oxide 3.9%, tin oxide 1%, copper carbonate 0.8% and bentonite 1.9%.
其中，熔块的原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾1.5％、氧化钠15.5％、氧化钙6.9％、氧化钡2.1％、三氧化二铝2.4％和二氧化硅71.6％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 1.5%, sodium oxide 15.5%, oxide Calcium 6.9%, barium oxide 2.1%, aluminum oxide 2.4% and silicon dioxide 71.6%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加入坩埚中，用明火加热至780℃，烧制25min后，熔成玻璃状物，水冷，制得熔块；According to the composition of the raw materials of the frit, the raw materials of the frit are added into the crucible, heated to 780 ° C with an open fire, after firing for 25 minutes, melted into a glass-like substance, and cooled with water to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入纯净水，混合后，加入到快速球磨机内，球磨机转速为450rpm，球磨时间4.5h，用400目的筛子进行过滤，去除未精磨的杂质；其中，按质量比，纯净水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝1.2∶1；(1) Carry out ingredients according to the raw material composition of the ox blood copper red ceramic glaze, add the frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite into pure water, after mixing, add it into a fast ball mill, and the ball mill rotating speed is 450rpm , the ball milling time is 4.5h, filter with a 400-mesh sieve to remove impurities that are not refined; wherein, by mass ratio, pure water: (frit + potassium feldspar powder + silicon dioxide + chalk powder + bentonite) = 1.2: 1 ;
(2)向快速球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速450rpm，球磨时间为1h，制得牛血色铜红陶瓷釉。(2) Add zinc oxide, tin oxide and copper carbonate to the rapid ball mill, and continue ball milling at 450 rpm and 1 hour for ball milling time to obtain ox-blood copper red ceramic glaze.
实施例3Example 3
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块13.8％、钾长石粉55％、二氧化硅21％、白垩粉3.8％、氧化锌4.2％、氧化锡0.5％、碳酸铜0.7％和膨润土1％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 13.8%, potassium feldspar powder 55%, silica 21%, chalk powder 3.8%, zinc oxide 4.2%, tin oxide 0.5%, copper carbonate 0.7% and bentonite 1%.
其中，熔块的原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾2.5％、氧化钠16.5％、氧化钙7.9％、氧化钡3.1％、三氧化二铝2.9％和二氧化硅65％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 2.5%, sodium oxide 16.5%, oxide Calcium 7.9%, barium oxide 3.1%, aluminum oxide 2.9% and silicon dioxide 65%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加入坩埚中，用明火加热至780℃，烧制35min后，熔成玻璃状物，水冷，制得熔块；According to the raw material composition of the frit, the ingredients are added into the crucible, heated to 780 ° C with an open fire, and after firing for 35 minutes, melted into a glass-like substance, and cooled with water to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入纯净水，混合后，加入到快速球磨机内，球磨机转速为550rpm，球磨时间4h，用400目的筛子进行过滤，去除未精磨的杂质；其中，按质量比，纯净水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝1∶1；(1) Carry out ingredients according to the raw material composition of ox blood copper red ceramic glaze, add the frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite into pure water, after mixing, add into the fast ball mill, the ball mill rotating speed is 550rpm , ball milling time 4h, filter with 400 mesh sieves, remove the impurity that is not finely ground; Wherein, by mass ratio, pure water: (frit+potassium feldspar powder+silicon dioxide+chalk+bentonite)=1:1;
(2)向快速球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速550rpm，球磨时间为0.5h，制得牛血色铜红陶瓷釉。(2) Zinc oxide, tin oxide and copper carbonate were added to the rapid ball mill, and the ball-milling was continued at a rotational speed of 550 rpm and a ball-milling time of 0.5h to obtain a ox-blood copper-red ceramic glaze.
实施例4Example 4
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块18.2％、钾长石粉53.1％、二氧化硅19％、白垩粉3.8％、氧化锌3.9％、氧化锡0.5％、碳酸铜0.5％和膨润土1％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 18.2%, potassium feldspar powder 53.1%, silica 19%, chalk powder 3.8%, zinc oxide 3.9%, tin oxide 0.5%, copper carbonate 0.5% and bentonite 1%.
其中，熔块的原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾2.5％、氧化钠16.5％、氧化钙7.9％、氧化钡3.1％、三氧化二铝2.9％和二氧化硅65％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 2.5%, sodium oxide 16.5%, oxide Calcium 7.9%, barium oxide 3.1%, aluminum oxide 2.9% and silicon dioxide 65%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加入坩埚中，用明火加热至780℃，烧制35min后，熔成玻璃状物，水冷，制得熔块；According to the raw material composition of the frit, the ingredients are added into the crucible, heated to 780 ° C with an open fire, and after firing for 35 minutes, melted into a glass-like substance, and cooled with water to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入纯净水，混合后，加入到快速球磨机内，球磨机转速为550rpm，球磨时间4h，用400目的筛子进行过滤，去除未精磨的杂质；其中，按质量比，纯净水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝1∶1；(1) Carry out ingredients according to the raw material composition of ox blood copper red ceramic glaze, add the frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite into pure water, after mixing, add into the fast ball mill, the ball mill rotating speed is 550rpm , ball milling time 4h, filter with 400 mesh sieves, remove the impurity that is not finely ground; Wherein, by mass ratio, pure water: (frit+potassium feldspar powder+silicon dioxide+chalk+bentonite)=1:1;
(2)向快速球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速550rpm，球磨时间为0.5h，制得牛血色铜红陶瓷釉。(2) Zinc oxide, tin oxide and copper carbonate were added to the rapid ball mill, and the ball-milling was continued at a rotational speed of 550 rpm and a ball-milling time of 0.5h to obtain a ox-blood copper-red ceramic glaze.
实施例5Example 5
一种牛血色铜红陶瓷釉，其原料组成包含：熔块、钾长石粉、二氧化硅、白垩粉、氧化锌、氧化锡、碳酸铜和膨润土；各个原料组分的质量百分比为：熔块13.8％、钾长石粉53.1％、二氧化硅19％、白垩粉6.8％、氧化锌3.9％、氧化锡1.5％、碳酸铜0.5％和膨润土1.4％。A bovine blood-colored copper-red ceramic glaze, the raw material composition of which comprises: frit, potassium feldspar powder, silicon dioxide, chalk powder, zinc oxide, tin oxide, copper carbonate and bentonite; the mass percentage of each raw material component is: frit 13.8%, potassium feldspar powder 53.1%, silica 19%, chalk powder 6.8%, zinc oxide 3.9%, tin oxide 1.5%, copper carbonate 0.5% and bentonite 1.4%.
其中，熔块的原料组成包含：氧化钾、氧化钠、氧化钙、氧化钡、三氧化二铝和二氧化硅；各个原料组分的质量百分比为：氧化钾1.5％、氧化钠15.5％、氧化钙6.9％、氧化钡2.1％、三氧化二铝2.4％和二氧化硅71.6％。Wherein, the raw material composition of the frit includes: potassium oxide, sodium oxide, calcium oxide, barium oxide, aluminum oxide and silicon dioxide; the mass percentage of each raw material component is: potassium oxide 1.5%, sodium oxide 15.5%, oxide Calcium 6.9%, barium oxide 2.1%, aluminum oxide 2.4% and silicon dioxide 71.6%.
一种牛血色铜红陶瓷釉的制备方法，包括以下步骤：A preparation method of ox blood copper red ceramic glaze, comprising the following steps:
步骤1，熔块的制备Step 1, Preparation of Frit
按照熔块的原料组成进行配料，将熔块的原料加入坩埚中，用明火加热至760℃，烧制30min后，熔成玻璃状物，水冷，制得熔块；According to the composition of the raw materials of the frit, the raw materials of the frit are added into the crucible, heated to 760 ° C with an open fire, and after firing for 30 minutes, it is melted into a glass-like substance, and cooled with water to obtain a frit;
步骤2，牛血色铜红陶瓷釉的制备Step 2, preparation of ox blood copper red ceramic glaze
(1)按照牛血色铜红陶瓷釉的原料组成进行配料，将熔块、钾长石粉、二氧化硅、白垩粉和膨润土，加入纯净水，混合后，加入到快速球磨机内，球磨机转速为450rpm，球磨时间4h，用400目的筛子进行过滤，去除未精磨的杂质；其中，按质量比，纯净水∶(熔块+钾长石粉+二氧化硅+白垩粉+膨润土)＝1∶1；(1) Carry out ingredients according to the raw material composition of the ox blood copper red ceramic glaze, add the frit, potassium feldspar powder, silicon dioxide, chalk powder and bentonite into pure water, after mixing, add it into a fast ball mill, and the ball mill rotating speed is 450rpm , ball milling time 4h, filter with 400 mesh sieves, remove the impurity that is not finely ground; Wherein, by mass ratio, pure water: (frit+potassium feldspar powder+silicon dioxide+chalk+bentonite)=1:1;
(2)向快速球磨机中，再加入氧化锌、氧化锡、碳酸铜，继续球磨，转速450rpm，球磨时间为1h，制得牛血色铜红陶瓷釉。(2) Add zinc oxide, tin oxide and copper carbonate to the rapid ball mill, and continue ball milling at 450 rpm and 1 hour for ball milling time to obtain ox-blood copper red ceramic glaze.
将上述实施例制备的牛血色铜红陶瓷釉喷涂在坯体上，进行煅烧，煅烧后牛血色铜红陶瓷釉，釉面厚重，红色发色效果浓重，陶瓷釉表面无气泡，质地均匀。The ox-red copper-red ceramic glaze prepared in the above embodiment is sprayed on the green body and calcined. After calcination, the ox-blood copper-red ceramic glaze has a thick glaze surface, strong red color development effect, no bubbles on the surface of the ceramic glaze, and uniform texture.
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