CN106381089A - Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof - Google Patents
Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof Download PDFInfo
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- CN106381089A CN106381089A CN201610794141.4A CN201610794141A CN106381089A CN 106381089 A CN106381089 A CN 106381089A CN 201610794141 A CN201610794141 A CN 201610794141A CN 106381089 A CN106381089 A CN 106381089A
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- oryza glutinosa
- glue composition
- starch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cereal-Derived Products (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
The invention relates to the technical field of wallpaper auxiliary materials, and especially relates to an edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and a production method thereof. The glutinous rice glue composition used for pasting wallpapers, which can be produced in a high temperature packing manner, is produced from, by mass, 5-8% of modified starch A, 3-8% of modified starch B, 4-10% of glutinous rice starch, 5-15% of waxy maize starch, 0.5-1% of a cross-linking agent, 0.6-3% of an antiseptic anti-mildew agent, 0.1-0.5% of monostearin, 1-3% of glucolactone, 0.2-1.5% of sorbitol, 2-6% of a thickener, 0.1-1.2% of citric acid, 0.01-0.15% of a stabilizer, and the balance of water. The glutinous rice glue composition obtained through compounding safe edible raw materials according to the above improved formula has the advantages of good stability, good safety and environmental protection, and has better viscosity than similar products.
Description
Technical field
The present invention relates to wallpaper adjuvant technical field, particularly to a kind of edible level environment protection type wallpaper stickup Oryza glutinosa glue group
Compound and preparation method thereof.
Background technology
At present, wallpaper, because of multiple advantages such as its material environment friendly, bright-colored, sound-insulation and heat-insulation and short construction periods, is
The main trend of wall surfacing at present.When pasting wallpaper, Glutinous rice wet glue is because its environmental protection, cohesion are strong, lower-cost spy
Point, obtains more and more widely using.Oryza glutinosa glue is mainly agent based on each kind of starch, is aided with various adjuvants, by suitable
The highly viscous amylan of a kind of environment-friendly water-soluble that after proportioning, temperature reaction is obtained in a kettle., then cooling discharge carry out
It has been packaged to be finished product Oryza glutinosa glue.It is often necessary to add some adjuvants or auxiliary agent during producing Oryza glutinosa glue, to improve product
Viscosity or the index such as stability, and the general environmental protection grade of these auxiliary agents is inadequate.
Content of the invention
The present invention provides a kind of edible level environment protection type wallpaper to paste and uses Oryza glutinosa glue composition, and its formula natural environmental-protective is edible
With viscosity is high, and stability is strong.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of wallpaper paste with can the Oryza glutinosa glue composition that produces of high temperature subpackage, this Oryza glutinosa glue composition is mainly by as follows
Component in terms of mass fraction is made：Modified starch A 5-8%, modified starch B 3-8%, glutinous rice starch 4-10%, Glutinous Semen Maydis
Starch 5-15%, cross-linking agent 0.5-1%, Antisepticize and mildew preventive 0.6-3%, monoglyceride 0.1-0.5%, gluconic acid lactone 1-3%,
Sorbitol 0.2-1.5%, thickening agent 2-6%, citric acid 0.1-1.2%, stabilizer 0.01-0.15%, balance of water.This Oryza glutinosa
Glue composition using safety edible with raw material compounded, obtained good stability through the improvement of formula, safety and environmental protection
Product, viscosity is also superior to like product simultaneously.
The Sorbitol increasing in the component of the present invention, solves the problems, such as high temperature subpackage, pins the moisture under high temperature system,
Avoid flowing out, it is to avoid in cooling procedure, produce condensed water.Increased the application of several stabilizers, aging time of starch can be delayed
Raw, protect product sensory color and luster, maintain stablizing of formulation product system.
Preferably, described cross-linking agent is sodium trimetaphosphate.
Preferably, described modified starch A refers to rice, Oryza glutinosa, Glutinous Semen Maydis, Rhizoma Solani tuber osi, Maninot esculenta crantz., Semen Tritici aestivi, Semen Maydiss etc.
Starch is the PURE COTE PURE COTE B790 of raw material.Preferably, described modified starch B refers to rice, Oryza glutinosa, Glutinous Semen Maydis, Ma Ling
Potato, Maninot esculenta crantz., Semen Tritici aestivi, corn and other starches are the carboxymethyl modified starch of raw material.
Preferably, described stabilizer be ring diand monoglycerides, acetylation fatty acid monoglyceride, glycerol monolaurate,
One or more of EDTA- disodium, EDTA- tetra- sodium compositionss.
Preferably, described Antisepticize and mildew preventive be potassium sorbate, calcium propionate, sodium benzoate, shitosan, the two of natamycin
Plant or multiple complex composition.Further, described Antisepticize and mildew preventive includes potassium sorbate 0.1～0.5%, calcium propionate 0.1-
0.5%, sodium benzoate 0.2-0.5%, natamycin 0.1-0.6%, shitosan 0.1～1.5%.
Preferably, described thickening agent is acetylation diacid pair Starch Sodium, PURE COTE PURE COTE B790, carboxymethyl modified starch
One or more combination thing.
A kind of edible level environment protection type wallpaper pastes the preparation method with Oryza glutinosa glue composition, and the method comprises the steps：
Step A：Raw material is sized mixing according to proportioning, after stirring, is heated slowly to 80 DEG C～95 DEG C, keep 30-45min；Step B：
The glue automatic filling machine fill finished product fractional pack that step A obtains, packaged fractional pack glue is air-dried and can proceed to
In finished packaging box, obtain product.The water of weight such as take to be diluted with Oryza glutinosa glue product during use, make Oryza glutinosa glue after dilution
Viscosity is in the range of 60000-120000mPa.S.
The production link of the present invention passes through high temperature packing technique, directly Oryza glutinosa glue product is passed through 80 DEG C～95 DEG C high temperature rings
Border is packed, and on the one hand achieves energy-saving, the purpose of improve production efficiency；On the other hand, available material itself
High temperature kills substantial amounts of microorganism, reduces the stabilizer addition in formula for a product, the feature of environmental protection of further improving product, extends
The shelf-life of product, is the beneficial means of the secondary pollution defect that energy effectively solving production exists；The third aspect, using height
Warm subpackage can lift the tightness of Oryza glutinosa glue material and packing container, reduce the breakage rate of finished products, be an up product quality
And the good product benefited the nation and the people of brand image.
Compared with prior art, the present invention has advantages below：1st, relatively conventional technique, product high temperature of the present invention directly wraps
Dress, the step eliminating cooling, energy loss greatly reduces, improves the service efficiency of reactor.2nd, the present invention produces
Technique in 80 DEG C～95 DEG C of high temperature direct blowing it is achieved that the purpose of high temperature sterilization, it is possible to decrease the addition of stabilizer, save
Production cost.3rd, raw materials for production are reproducible plant amylum raw material, and environmental protection index is high, the feature of environmental protection of further improving product.
4th, the product that the present invention provides has long shelf-life, and freeze-thaw stability is strong, the high advantage of storage stability.5th, product of the present invention
Preparation method has the characteristics that process is simple, low production cost.
Specific embodiment
Below by specific embodiment, technical scheme is described in further detail.It should be appreciated that this
Bright enforcement is not limited to the following examples, and any pro forma flexible and/or change that the present invention is made all will fall
Enter the scope of the present invention.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, the equipment being adopted and raw material etc.
All it is commercially available or commonly used in the art.Method in following embodiments, if no special instructions, is the normal of this area
Rule method.In the present invention, each raw material sources are as follows：
Described modified starch A, modified starch B, glutinous rice starch, waxy corn starch producer are that National Starch industry (Shanghai) has
Limit company.
Embodiment 1
A kind of edible level environment protection type wallpaper pastes the preparation method with Oryza glutinosa glue composition, and detailed process is as follows：
Step A：Add raw materials in reactor and size mixing, after stirring, 95 DEG C will be heated slowly in reactor, now
Glue is in slight gelatinizing state, then keeping temperature 30min；
Composition of raw materials is (gross weight is 100%)：Modified starch A 5%, modified starch B 8%, glutinous rice starch 8%, glutinous
Corn starch 10%, sodium trimetaphosphate 1%, Antisepticize and mildew preventive 2%, monoglyceride 0.3%, gluconic acid lactone 2%, Sorbitol
1%, thickening agent 2%, citric acid 0.6%, stabilizer 0.15%, balance of deionized water.Described stabilizer is that lauric acid list is sweet
Fat 0.1%, EDTA- disodium 0.05%.Described Antisepticize and mildew preventive is potassium sorbate 0.5%, calcium propionate 0.5%, sodium benzoate
0.2%, natamycin 0.6%, shitosan 0.2%.
Step B：Now Oryza glutinosa glue good fluidity, stirring, conveying power consumption are low, directly with automatic filling machine fill finished product
Fractional pack, packaged fractional pack glue is air-dried and can proceed in finished packaging box within 5 minutes, take during use etc. the water of weight with
Oryza glutinosa glue product is diluted, and the viscosity making Oryza glutinosa glue after dilution is in the range of 60000-120000mPaS.
Embodiment 2
A kind of edible level environment protection type wallpaper pastes the preparation method with Oryza glutinosa glue composition, and detailed process is as follows：
Step A：Add raw materials in reactor and size mixing, after stirring, 85 DEG C will be heated slowly in reactor, now
Glue is in slight gelatinizing state, then keeping temperature 30min；
Composition of raw materials is (gross weight is 100%)：Modified starch A 8%, modified starch B 3%, glutinous rice starch 10%, glutinous
Corn starch 5%, sodium trimetaphosphate 0.5%, Antisepticize and mildew preventive 0.9%, monoglyceride 0.1%, gluconic acid lactone 3%, Pyrusussuriensiss
Alcohol 0.2%, thickening agent 2%, citric acid 1.2%, stabilizer 0.03%, balance of deionized water.Described stabilizer is acetylation
Fatty acid monoglyceride.Described Antisepticize and mildew preventive includes potassium sorbate 0.5%, natamycin 0.2%, shitosan 0.2%.
Step B：Now Oryza glutinosa glue good fluidity, stirring, conveying power consumption are low, directly with automatic filling machine fill finished product
Fractional pack, packaged fractional pack glue is air-dried and can proceed in finished packaging box within 5 minutes, take during use etc. the water of weight with
Oryza glutinosa glue product is diluted, and the viscosity making Oryza glutinosa glue after dilution is in the range of 60000-120000mPaS.
Embodiment 3
A kind of edible level environment protection type wallpaper pastes the preparation method with Oryza glutinosa glue composition, and detailed process is as follows：
Step A：Add raw materials in reactor and size mixing, after stirring, 90 DEG C will be heated slowly in reactor, now
Glue is in slight gelatinizing state, then keeping temperature 30min；
Composition of raw materials is (gross weight is 100%)：Modified starch A 6%, modified starch B 6%, glutinous rice starch 46%, glutinous
Corn starch 15%, sodium trimetaphosphate 0.5%, Antisepticize and mildew preventive 3%, monoglyceride 0.5%, gluconic acid lactone 1%, Sorbitol
0.6%, thickening agent 2%, citric acid 0.5%, stabilizer 0.10%, balance of deionized water.Described stabilizer is lauric acid list
Sweet fat 0.05%, EDTA- tetra- sodium 0.05%.Described Antisepticize and mildew preventive includes potassium sorbate 0.5%, calcium propionate 0.5%, benzoic acid
Sodium 0.5%, natamycin 0.6%, shitosan 0.9%.
Step B：Now Oryza glutinosa glue good fluidity, stirring, conveying power consumption are low, directly with automatic filling machine fill finished product
Fractional pack, packaged fractional pack glue is air-dried and can proceed in finished packaging box within 5 minutes, take during use etc. the water of weight with
Oryza glutinosa glue product is diluted, and the viscosity making Oryza glutinosa glue after dilution is in the range of 60000-120000mPaS.
The edible level environment protection type wallpaper that the slurry of the present invention produces pastes the master with tradition glutinous rice glue with Oryza glutinosa glue composition
Want technical specification contrast as shown in table 1.
Table 1
By table 1 it can clearly be seen that 3 cases being made using present invention process method, its Oryza glutinosa glue is either glutinous
Degree or peel strength aspect, will be better than traditional Oryza glutinosa glue；Simultaneously organic in formaldehyde, toluene-xylene and general volatile
Thing content all well below tradition glutinous rice glue, has absolutely proved the feature of environmental protection of this product, and this is also the advantage of Oryza glutinosa glue of the present invention
It is located.This technique can effectively shorten Oryza glutinosa glue production time 1h/ and criticize, and reduction by 20～30 DEG C of gelatinization point of production/batch, by 5 tons/batches
Production calculation, after process modification produce Oryza glutinosa glue can 30～35 degree of using electricity wisely/criticize.
Detection of Stability is tested：
Applicant determines freeze-thaw stability and the height of embodiment 1～3 Oryza glutinosa glue composition according to GB/T 9268-2008
Temperature stability, the results are shown in Table 2.
Table 2
Within Oryza glutinosa glue freeze-thaw stability on market is typically maintained in 5 circulations, high-temperature stability basic guarantee 7 days with
Interior invariant color, thinning, as can be seen from Table 2, the Oryza glutinosa glue of the present invention does not have substantially preferably freeze-thaw stability and height
Temperature stability.
The present invention selects based on all kinds of modified starches and glutinous rice flour, is aided with the various food stage adjuvant such as stabilizer, thickening agent,
By suitable proportioning, obtain a kind of high thick glue of environment-friendly water-soluble.The good environmental protection of product of the present invention, raw material is all edible
With product viscosity is high, big using the amount of being watered, and for wallpaper construction, rate of drying is fast, good stability；Simple production process energy-conservation,
And high temperature packaging reduces content of microorganisms, extends the shelf-life of product.
Compared with prior art, first passage high temperature packing technique of the present invention, decrease traditional cooling link it is achieved that
The purpose of energy-saving consumption-reducing；The equal edible of the raw material of Glutinous rice wet glue simultaneously, is Renewable resource, and the feature of environmental protection is very strong.With respect to market
Upper others Oryza glutinosa glue product, this product cohesive force is strong, and content of microorganisms is low, and the shelf-life is longer, and freeze-thaw stability is strong, and storage is steady
Qualitative height；Meanwhile, product of the present invention possesses high temperature packaging character, energy-saving.
The above is only 3 reasonable case study on implementation in the present invention, thus all according to the side in the scope of the claims of the present invention
Change or decoration that the Oryza glutinosa glue of the high temperature direct discharging packaging that method is joined is made, are all contained in the protection of present patent application
In the range of.
Claims (9)
1. a kind of edible level environment protection type wallpaper stickup with Oryza glutinosa glue composition it is characterised in that this Oryza glutinosa glue composition mainly by
Following component in terms of mass fraction is made：
Modified starch A 5-8%,
Modified starch B 3-8%,
Glutinous rice starch 4-10%,
Waxy corn starch 5-15%,
Cross-linking agent 0.5-1%,
Antisepticize and mildew preventive 0.6-3%,
Monoglyceride 0.1-0.5%,
Gluconic acid lactone 1-3%,
Sorbitol 0.2-1.5%,
Thickening agent 2-6%,
Citric acid 0.1-1.2%,
Stabilizer 0.01-0.15%,
Balance of water.
2. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described change
Property starch A refers to the hydroxypropyl modified shallow lake with rice, Oryza glutinosa, Glutinous Semen Maydis, Rhizoma Solani tuber osi, Maninot esculenta crantz., Semen Tritici aestivi, corn and other starches as raw material
Powder.
3. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described change
Property starch B refers to the carboxymethyl modified shallow lake with rice, Oryza glutinosa, Glutinous Semen Maydis, Rhizoma Solani tuber osi, Maninot esculenta crantz., Semen Tritici aestivi, corn and other starches as raw material
Powder.
4. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described friendship
Connection agent is sodium trimetaphosphate.
5. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described steady
Determine agent be ring diand monoglycerides, acetylation fatty acid monoglyceride, glycerol monolaurate, EDTA- disodium, in EDTA- tetra- sodium
One or more combination thing.
6. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described anti-
Rotten antifungus agent is potassium sorbate, calcium propionate, sodium benzoate, shitosan, two or more complex compositions of natamycin.
7. edible level environment protection type wallpaper according to claim 6 paste with Oryza glutinosa glue composition it is characterised in that：Described anti-
Rotten antifungus agent includes potassium sorbate 0.1 ~ 0.5%, calcium propionate 0.1-0.5%, sodium benzoate 0.2-0.5%, natamycin 0.1-
0.6%, shitosan 0.1 ~ 1.5%.
8. edible level environment protection type wallpaper according to claim 1 paste with Oryza glutinosa glue composition it is characterised in that：Described increasing
Thick dose is acetylation diacid double Starch Sodium, PURE COTE PURE COTE B790, the one or more combination thing of carboxymethyl modified starch.
9. the edible level environment protection type wallpaper described in a kind of claim 1 pastes the preparation method with Oryza glutinosa glue composition, its feature
It is that the method comprises the steps：
Step A：Raw material is sized mixing according to proportioning, after stirring, is heated slowly to 80 DEG C ~ 95 DEG C, keep 30-45 min；
Step B：The glue automatic filling machine fill finished product fractional pack that step A obtains, by packaged fractional pack glue wind
Do and can proceed in finished packaging box, obtain product.
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| CN201610794141.4A CN106381089A (en) | 2016-08-31 | 2016-08-31 | Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof |
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| CN201610794141.4A CN106381089A (en) | 2016-08-31 | 2016-08-31 | Edible environmentally-friendly glutinous rice glue composition used for pasting wallpapers, and production method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107722869A (en) * | 2017-09-26 | 2018-02-23 | 望江县红和木业灯饰有限公司 | A kind of paper lantern is modified glutinous rice glue with high bond strength |
| CN107760227A (en) * | 2017-09-26 | 2018-03-06 | 望江县红和木业灯饰有限公司 | A kind of height for paper lantern bonds glutinous rice glue |
| CN107815269A (en) * | 2017-09-26 | 2018-03-20 | 望江县红和木业灯饰有限公司 | A kind of high adhesion strength glutinous rice glue preparation method for paper lantern |
| CN108774478A (en) * | 2018-06-29 | 2018-11-09 | 安吉欧也钣金科技有限公司 | Glutinous rice glue and preparation method thereof for pasting wallpaper |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| CN109438775A (en) * | 2018-10-10 | 2019-03-08 | 江苏银杏湖生物科技有限公司 | A kind of preparation method of agricultural product antimicrobial preservative film |
| CN111139001A (en) * | 2019-12-20 | 2020-05-12 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
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| CN105838283A (en) * | 2016-03-03 | 2016-08-10 | 桐乡嘉力丰实业股份有限公司 | Glutinous rice adhesive subpackagable at high temperature and used for wallpaper, and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722869A (en) * | 2017-09-26 | 2018-02-23 | 望江县红和木业灯饰有限公司 | A kind of paper lantern is modified glutinous rice glue with high bond strength |
| CN107760227A (en) * | 2017-09-26 | 2018-03-06 | 望江县红和木业灯饰有限公司 | A kind of height for paper lantern bonds glutinous rice glue |
| CN107815269A (en) * | 2017-09-26 | 2018-03-20 | 望江县红和木业灯饰有限公司 | A kind of high adhesion strength glutinous rice glue preparation method for paper lantern |
| CN108774478A (en) * | 2018-06-29 | 2018-11-09 | 安吉欧也钣金科技有限公司 | Glutinous rice glue and preparation method thereof for pasting wallpaper |
| CN109181635A (en) * | 2018-07-26 | 2019-01-11 | 合肥广民建材有限公司 | A kind of dedicated antibacterial glutinous rice glue of wallpaper and preparation method thereof |
| CN109438775A (en) * | 2018-10-10 | 2019-03-08 | 江苏银杏湖生物科技有限公司 | A kind of preparation method of agricultural product antimicrobial preservative film |
| CN111139001A (en) * | 2019-12-20 | 2020-05-12 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
| CN111139001B (en) * | 2019-12-20 | 2021-05-14 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
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Address after: 314500 Tongxiang Economic Development Zone, Zhejiang City, West Ring Road, No. 106, No. Applicant after: Polytron Technologies Inc Address before: Jiaxing City, Zhejiang province 314500 Tongxiang Wutong Street Huancheng West Road No. 106 building 4 floor 1 Applicant before: Tongxiang Jialifeng Industry Co., Ltd. |
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Application publication date: 20170208 |