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CN106337144A - Composite material for ceramic teeth and preparation method of composite material - Google Patents

Composite material for ceramic teeth and preparation method of composite material Download PDF

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Publication number
CN106337144A
CN106337144A CN201610822421.1A CN201610822421A CN106337144A CN 106337144 A CN106337144 A CN 106337144A CN 201610822421 A CN201610822421 A CN 201610822421A CN 106337144 A CN106337144 A CN 106337144A
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CN
China
Prior art keywords
mixture
composite material
nickel
preparation
manganese
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Pending
Application number
CN201610822421.1A
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Chinese (zh)
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不公告发明人
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Individual
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Individual
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Priority to CN201610822421.1A priority Critical patent/CN106337144A/en
Priority claimed from CN201410626305.3A external-priority patent/CN104451255B/en
Publication of CN106337144A publication Critical patent/CN106337144A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/84—Preparations for artificial teeth, for filling teeth or for capping teeth comprising metals or alloys
    • A61K6/844—Noble metals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/829—Preparations for artificial teeth, for filling teeth or for capping teeth comprising cermet composites
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/84—Preparations for artificial teeth, for filling teeth or for capping teeth comprising metals or alloys
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
    • A61L27/02—Inorganic materials
    • A61L27/04—Metals or alloys
    • A61L27/06—Titanium or titanium alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/10—Alloys containing non-metals
    • C22C1/1036—Alloys containing non-metals starting from a melt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/10—Alloys containing non-metals
    • C22C1/1036—Alloys containing non-metals starting from a melt
    • C22C1/1047—Alloys containing non-metals starting from a melt by mixing and casting liquid metal matrix composites
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C14/00—Alloys based on titanium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Medicinal Chemistry (AREA)
  • Transplantation (AREA)
  • Composite Materials (AREA)
  • Dental Prosthetics (AREA)
  • Dental Preparations (AREA)

Abstract

The invention discloses a composite material for ceramic teeth and a preparation method of the composite material. The composite material is formed by mixing straw, nickel, molybdenum, nano silver, iron, manganese and titanium. The preparation method comprises the steps that 1, the straw, nickel, molybdenum, iron, manganese and titanium are taken according to the mass percent and added into a ball mill to be mixed, stirring and grinding are conducted simultaneously, and a mixture I is obtained; 2, the mixture I is crushed with ultrasonic waves for 1-3 hours, and a mixture II is obtained; and 3, the mixture II is placed in a crucible to be stirred and mixed, then the nano silver is added into the crucible, stirred and heated to the temperature of 1400-1700 DEG C, heat preservation is conducted for 3-5 hours, melt is guided into a mold, cooling is conducted for 1-3 min at the speed of 5-10 DEG C/min, then cooling is conducted at the speed of 10-15 DEG C/min, a cast block is formed, and then surface finishing is conducted. The composite material is durable and has great prospects.

Description

A kind of baking-ceramic tooth composite and preparation method thereof
Technical field
The present invention relates to ceramic tooth material field is and in particular to a kind of baking-ceramic tooth composite and preparation method thereof.
Background technology
Tooth prevalence is higher, and in China, tooth patient reaches as many as 800,000,000, and scarce the splitting of tooth defect, denture lacks with denture Mistake is the common disease in odontopathy again, is generally repaired using artificial tooth.Composite material intensity, hardness, wearability, durable The good mechanical performance such as property and toughness, has become main repair materials.
Metal-porcelain is to melt porcelain powders through high temperature to be attached to the mouth mending material formed on composite ground, described Baking-ceramic tooth is exactly one layer of glaze class material of coating on metal dental crown, makes frit material melt formation by high-temperature calcination and is similar to The color of dermal tooth and the denture prosthesis of gloss, had both had the advantages that Strength of Metallic Materials height, good toughness, had had ceramic material again Corrosion resistance and the features such as preferable biocompatibility.
At present, Metal-porcelain odontodes is in the majority with common nickel chromium triangle composite baking-ceramic tooth, may occur with human body after use Anaphylaxiss, so needing to research and develop new composite material, or calcination parameter, seek high-quality baking-ceramic tooth.
Content of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of baking-ceramic tooth composite and its preparation side Method, gained baking-ceramic tooth is durable in use.
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 10-15%, nickel 16- 22%, molybdenum 1-6%, nanometer silver 6-8%, ferrum 0.5-1.2%, manganese 2-6%, balance of titanium.
As preferably, above-mentioned baking-ceramic tooth composite, including following raw material by mass percentage: powder of straw 12-14%, nickel 18-20%, molybdenum 2-5%, nanometer silver 6-8%, ferrum 0.8-1.0%, manganese 4-6%, balance of titanium.
The above-mentioned baking-ceramic tooth preparation method of your composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Obtain mixture afterwards；
Step 2, mixture ultrasonic disruption 1-3 hour is obtained mixture；
Step 3, then mixture is placed in stirring mixing in crucible, add nanometer silver and stir and be heated to 1400-1700 DEG C, Insulation 3-5 hour, liquation is imported in mould, is formed with being lowered the temperature with 10-15 DEG C/min after 5-10 DEG C/min cooling 1-3min again Casting is fast, after surface dressing.
As the preparation method of above-mentioned baking-ceramic tooth composite, step 1, ball milling 4-5h.
As the preparation method of above-mentioned baking-ceramic tooth composite, step 2, ultrasonic power is 30-45w.
As the preparation method of above-mentioned baking-ceramic tooth composite, step 3, mixing speed is 120-240rpm.
Beneficial effect
It is raw material that composite of the present invention utilizes straw, makes composite in conjunction with noble metal, hardness is high, high temperature resistant, acid and alkali-resistance, And there is antibacterial effect, improve that ceramic material is frangible, difference of hardness problem, in addition, the price of straw is low, reduce roasting The cost of porcelain tooth.
Specific embodiment
Embodiment 1
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 10%, nickel 16%, molybdenum 1%, nanometer Silver 6%, ferrum 0.5%, manganese 2%, balance of titanium.
The preparation method of above-mentioned baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Mixture is obtained after 4h；
Step 2, mixture is obtained mixture in 1 hour with 30w ultrasonic disruption；
Step 3, then mixture is placed in stirring mixing in crucible, add nanometer silver to stir with 120rpm and be heated to 1400 DEG C, it is incubated 3 hours, liquation is imported in mould, form casting with after 10 DEG C/min cooling again with after 5 DEG C/min cooling 1-3min Hurry up, after surface dressing.
Embodiment 2
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 12%, nickel 18%, molybdenum 2%, nanometer Silver 6%, ferrum 0.8%, manganese 4%, balance of titanium.
The preparation method of above-mentioned baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Mixture is obtained after 4.5h；
Step 2, mixture is obtained mixture in 1.8 hours with 38w ultrasonic disruption；
Step 3, then mixture is placed in stirring mixing in crucible, add nanometer silver and stirred with 160rpm and be heated to 1500 DEG C, it is incubated 4 hours, liquation is imported in mould, fast to form casting with 12 DEG C/min after lowering the temperature again after 7 DEG C/min cooling 2min, After surface dressing.
Embodiment 3
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 14%, nickel 20%, 5%, nanometer silver 8%, ferrum 1.0%, manganese 6%, balance of titanium.
The preparation method of above-mentioned baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Mixture is obtained after 5h；
Step 2, mixture is obtained mixture in 2.4 hours with 40w ultrasonic disruption；
Step 3, then mixture is placed in stirring mixing in crucible, stir and be heated to 1600 DEG C with 200rpm, insulation 4.8 is little When, liquation is imported in mould, fast to be cast with formation after 14 DEG C/min cooling again after 8 DEG C/min cooling 3min, after surface dressing ?.
Embodiment 4
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 15%, nickel 22%, molybdenum 6%, nanometer Silver 8%, ferrum 1.2%, manganese 6%, balance of titanium.
The preparation method of above-mentioned baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Mixture is obtained after 5h；
Step 2, mixture is obtained mixture in 3 hours with 45w ultrasonic disruption；
Step 3, then mixture is placed in stirring mixing in crucible, stir and be heated to 1700 DEG C with 240rpm, insulation 5 is little When, liquation is imported in mould, so that after 10 DEG C/min cooling 3min, to be formed after 15 DEG C/min cooling cooling, casting is fast again, surface is whole After reason.
Comparative example
A kind of baking-ceramic tooth composite, including following raw material by mass percentage: straw 10%, nickel 16%, molybdenum 1%, ferrum 0.5%, manganese 2%, balance of titanium.
The preparation method of above-mentioned baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring Mixture is obtained after 4h；
Step 2, mixture is obtained mixture in 1 hour with 30w ultrasonic disruption；
Step 3, then mixture is placed in stirring mixing in crucible, add nanometer silver to stir with 120rpm and be heated to 1400 DEG C, it is incubated 3 hours, liquation is imported in mould, form casting with after 10 DEG C/min cooling again with after 5 DEG C/min cooling 1-3min Hurry up, after surface dressing.
Performance test
Composite prepared by the present invention is compared with comparative example, and the data obtained is as shown in the table.
By comparing embodiment 1-4 and comparative example, the composite of the present invention improves the performance of ceramic material, hardness High, high temperature resistant, resistance to acids and bases is good, in addition has antibacterial ability, as the matter that can preferably take care of one's teeth of material of ceramic tooth Amount, extends use time.

Claims (1)

1. a kind of baking-ceramic tooth composite is it is characterised in that include following raw material by mass percentage: straw 10- 15%, nickel 16-22%, molybdenum 1-6%, nanometer silver 6-8%, ferrum 0.5-1.2%, manganese 2-6%, balance of titanium；
The preparation method of described baking-ceramic tooth composite, comprises the following steps:
Step 1, takes straw, nickel, molybdenum, ferrum, manganese and titanium by mass percentage, adds in ball mill and mixes, grinds while stirring, Mixture is obtained after ball milling 4-5h；
Step 2, mixture ultrasonic disruption 1-3 hour is obtained mixture；Ultrasonic power is 30-45w；
Step 3, then mixture is placed in stirring mixing in crucible, add nanometer silver and stir and be heated to 1400-1700 DEG C, Insulation 3-5 hour, liquation is imported in mould, is formed with being lowered the temperature with 10-15 DEG C/min after 5-10 DEG C/min cooling 1-3min again Casting is fast, after surface dressing.
CN201610822421.1A 2014-11-10 2014-11-10 Composite material for ceramic teeth and preparation method of composite material Pending CN106337144A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610822421.1A CN106337144A (en) 2014-11-10 2014-11-10 Composite material for ceramic teeth and preparation method of composite material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410626305.3A CN104451255B (en) 2014-11-10 A kind of baking-ceramic tooth composite and preparation method thereof
CN201610822421.1A CN106337144A (en) 2014-11-10 2014-11-10 Composite material for ceramic teeth and preparation method of composite material

Related Parent Applications (1)

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Application Number Title Priority Date Filing Date
CN201610822416.0A Pending CN106191486A (en) 2014-11-10 2014-11-10 A kind of preparation method of baking-ceramic tooth composite
CN201610822421.1A Pending CN106337144A (en) 2014-11-10 2014-11-10 Composite material for ceramic teeth and preparation method of composite material
CN201610822360.9A Withdrawn CN106333863A (en) 2014-11-10 2014-11-10 Preparation method of composite material for ceramic teeth
CN201610822467.3A Withdrawn CN106265088A (en) 2014-11-10 2014-11-10 A kind of hardness is high, have the baking-ceramic tooth composite of fungistatic effect
CN201610822359.6A Pending CN106319284A (en) 2014-11-10 2014-11-10 Ceramic-tooth-used composite high in hardness and capable of inhibiting bacteria

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CN201610822360.9A Withdrawn CN106333863A (en) 2014-11-10 2014-11-10 Preparation method of composite material for ceramic teeth
CN201610822467.3A Withdrawn CN106265088A (en) 2014-11-10 2014-11-10 A kind of hardness is high, have the baking-ceramic tooth composite of fungistatic effect
CN201610822359.6A Pending CN106319284A (en) 2014-11-10 2014-11-10 Ceramic-tooth-used composite high in hardness and capable of inhibiting bacteria

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107858557A (en) * 2017-11-17 2018-03-30 梁乔保 A kind of gear division antibacterial porcelain alloy and preparation method thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110870836A (en) * 2018-08-31 2020-03-10 柳州市佛冠齿科数字化研发有限公司 Metal porcelain tooth and preparation method thereof
CN110917043A (en) * 2018-08-31 2020-03-27 柳州市佛冠齿科数字化研发有限公司 Composite material for porcelain teeth
CN110917042A (en) * 2018-08-31 2020-03-27 柳州市佛冠齿科数字化研发有限公司 Antibacterial porcelain tooth composite material
CN110870837A (en) * 2018-08-31 2020-03-10 柳州市佛冠齿科数字化研发有限公司 Metal ceramic tooth composite material

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CN101003901A (en) * 2006-09-12 2007-07-25 宁波浙东精密铸造有限公司 Composite material of metal / ceramic metal, manufacturing method and application
CN101519738A (en) * 2009-04-09 2009-09-02 绵阳美之牙正畸材料有限公司 Beta titanium alloy material for orthodontic treatment
JP2012052219A (en) * 2010-08-03 2012-03-15 Kobe Steel Ltd α-β TITANIUM ALLOY EXTRUDED MATERIAL EXCELLENT IN FATIGUE STRENGTH, AND METHOD FOR PRODUCING THE α-β TITANIUM ALLOY EXTRUDED MATERIAL

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Publication number Priority date Publication date Assignee Title
CN1893906A (en) * 2003-12-17 2007-01-10 贺利氏古萨有限公司 Antimicrobial nano silver additive for polymerizable dental materials
CN101003901A (en) * 2006-09-12 2007-07-25 宁波浙东精密铸造有限公司 Composite material of metal / ceramic metal, manufacturing method and application
CN101519738A (en) * 2009-04-09 2009-09-02 绵阳美之牙正畸材料有限公司 Beta titanium alloy material for orthodontic treatment
JP2012052219A (en) * 2010-08-03 2012-03-15 Kobe Steel Ltd α-β TITANIUM ALLOY EXTRUDED MATERIAL EXCELLENT IN FATIGUE STRENGTH, AND METHOD FOR PRODUCING THE α-β TITANIUM ALLOY EXTRUDED MATERIAL

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107858557A (en) * 2017-11-17 2018-03-30 梁乔保 A kind of gear division antibacterial porcelain alloy and preparation method thereof

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Publication number Publication date
CN106319284A (en) 2017-01-11
CN106265088A (en) 2017-01-04
CN106333863A (en) 2017-01-18
CN104451255A (en) 2015-03-25
CN106191486A (en) 2016-12-07

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Application publication date: 20170118