CN106307792B - Antibacterial massage playshoes based on microcapsules technology - Google Patents
Antibacterial massage playshoes based on microcapsules technology Download PDFInfo
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- CN106307792B CN106307792B CN201610658877.9A CN201610658877A CN106307792B CN 106307792 B CN106307792 B CN 106307792B CN 201610658877 A CN201610658877 A CN 201610658877A CN 106307792 B CN106307792 B CN 106307792B
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- sole
- antibacterial
- massage bead
- microcapsules technology
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 45
- 239000003094 microcapsule Substances 0.000 title claims abstract description 37
- 238000005516 engineering process Methods 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 53
- 239000011324 bead Substances 0.000 claims abstract description 42
- 230000003115 biocidal effect Effects 0.000 claims abstract description 36
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 23
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 23
- 230000000694 effects Effects 0.000 claims abstract description 13
- 210000002683 foot Anatomy 0.000 claims abstract description 8
- 210000004744 fore-foot Anatomy 0.000 claims abstract description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 14
- 206010011732 Cyst Diseases 0.000 claims description 11
- 208000031513 cyst Diseases 0.000 claims description 11
- 239000004952 Polyamide Substances 0.000 claims description 10
- 229920002647 polyamide Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 7
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 7
- 241001330002 Bambuseae Species 0.000 claims description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 7
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 7
- 239000011425 bamboo Substances 0.000 claims description 7
- 239000003292 glue Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- 238000009958 sewing Methods 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- AHLWZBVXSWOPPL-RGYGYFBISA-N 20-deoxy-20-oxophorbol 12-myristate 13-acetate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(C=O)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C AHLWZBVXSWOPPL-RGYGYFBISA-N 0.000 claims description 4
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 4
- 241001602688 Pama Species 0.000 claims description 4
- 229930003268 Vitamin C Natural products 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 235000019154 vitamin C Nutrition 0.000 claims description 4
- 239000011718 vitamin C Substances 0.000 claims description 4
- 239000003610 charcoal Substances 0.000 claims 1
- 244000005700 microbiome Species 0.000 abstract description 9
- 230000035699 permeability Effects 0.000 abstract description 6
- 201000004647 tinea pedis Diseases 0.000 abstract description 5
- 210000004243 sweat Anatomy 0.000 abstract description 4
- 201000010099 disease Diseases 0.000 description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 230000002421 anti-septic effect Effects 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000005354 coacervation Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 210000003734 kidney Anatomy 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- YWNYZQTZOONLGU-UHFFFAOYSA-N C(CC)Cl.[O] Chemical compound C(CC)Cl.[O] YWNYZQTZOONLGU-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 208000008017 Hypohidrosis Diseases 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 241001314279 Zoopagales Species 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H39/00—Devices for locating or stimulating specific reflex points of the body for physical therapy, e.g. acupuncture
- A61H39/04—Devices for pressing such points, e.g. Shiatsu or Acupressure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/335—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin
- A61K31/35—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin having six-membered rings with one oxygen as the only ring hetero atom
- A61K31/352—Heterocyclic compounds having oxygen as the only ring hetero atom, e.g. fungichromin having six-membered rings with one oxygen as the only ring hetero atom condensed with carbocyclic rings, e.g. methantheline
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/24—Heavy metals; Compounds thereof
- A61K33/30—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/24—Heavy metals; Compounds thereof
- A61K33/38—Silver; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/44—Elemental carbon, e.g. charcoal, carbon black
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2205/00—Devices for specific parts of the body
- A61H2205/12—Feet
- A61H2205/125—Foot reflex zones
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical & Material Sciences (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Rehabilitation Therapy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Pain & Pain Management (AREA)
- Physical Education & Sports Medicine (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Finger-Pressure Massage (AREA)
Abstract
A kind of antibacterial massage playshoes based on microcapsules technology, including sole and sew the upper of a shoe on sole, the sole is made up of anti-biotic material, the sole upper surface is provided with the small massage bead of projection, it is located at heel, arch of the foot and forefoot in sole upper surface and is respectively equipped with a big massage bead, massage effect can be played to these three regions；Anti-biotic material is directly used in making sole, shoe-pad need not be padded, pin is directly contacted with soles, and eliminates the growth environment of microorganism in footwear, reduces harm of the microorganism to people's pin, it can suppress and treat tinea pedis, foot odour, cooperated simultaneously using size massage bead, increase the gas permeability of shoe cavity, more recover from fatigue when making to wear, comfortably, sweat discharge is reduced, keeps sole to dry.
Description
Technical field
The present invention relates to household articles technical field, and in particular to a kind of antibacterial massage leisure based on microcapsules technology
Footwear.
Background technology
Shoes are that institute is indispensable in people's daily life, be as the saying goes：A thousand miles begins with a single step.Therefore, footwear are produced
Son producer it is also very numerous, miscellaneous shoes are complete, and can according to user need produce difference at any time
The footwear of style, to meet the needs of different age group, different operating property and men and women.Conventional footwear are not easy to breathe freely, and are also easy to produce different
Taste, it is poor to wear Jiu Liao foots comfort.Biological hologram medical evidence, it is tens of that vola arranges the heart of human body, lung, liver, kidney, stomach and intestine etc.
The specific reflection area of individual organ, Yongquan acupoint, Acupoint Xingjian, Lineiting cave, qiuxu acupoint etc., stimulate these corresponding by massaging
Echo area, just can dredging the channel, adjust internal organs function, promote qi and blood smooth, adjust body de-synchronization state, reach treatment, diseases prevention,
The purpose of health care.This requires sole not only to have good warmth retention property, but also there is gas permeability, thermal diffusivity, massage to protect
Health-care function.
Existing antibiosis and health-care shoes are substantially made using medicine or nano material on domestic and international market at present, and all
Simply made an issue of on the surfacing of shoe-pad, be either equipped with antibacterial decoction medicinal powder in shoe lining or pass through the special system to sole
Work reaches ventilative circulation etc., so does, not only security is low for the antibacterial footwear of production, persistence, water-wash resistance and antibacterial wide spectrum
Property is poor, and does not meet the more and more extensive development trend of following health shoes.
The content of the invention
The technical problems to be solved by the invention be to provide it is a kind of simple in construction, it is novel in design, safety and sanitation based on
The antibacterial massage playshoes of microcapsules technology.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of antibacterial massage playshoes based on microcapsules technology, including upper of a shoe on sole of sole and sewing, it is described
Sole is made up of anti-biotic material, the sole upper surface is provided with the small massage bead of projection, after sole upper surface is located at pin
A big massage bead is respectively equipped with, arch of the foot and forefoot, massage effect can be played to these three regions；By anti-biotic material
Making sole is directly used in, without padding shoe-pad, pin is directly contacted with soles, and can be suppressed and be treated tinea pedis, reduce microorganism
Harm to people's pin, while cooperated using size massage bead, increase the gas permeability of shoe cavity, it is more comfortable when making to wear, subtract
Hypohidrosis liquid is discharged.
For the diameter of the small massage bead in 0.5-1.5cm, the diameter of the big massage bead, can be to human body in 2-3cm
Sole acupoint carry out effective stimulus, reach prevent and cure diseases, the purpose of body building.
Center line word order of the described three big massage bead along sole.It is main to sole three by three big massage beads
Massage effect is played in region, stimulates sole acupoint such as Yongquan acupoint, Acupoint Xingjian, Lineiting cave, qiuxu acupoint etc., can play it is calm,
Calm the nerves, alleviate stress, support kidney, the effect of reinforcing the kidney, treatment hypertension, insomnia, climacteric metancholia etc., in human health-preserving, prevent
Disease, cure the disease, health care etc. can be played the effect of certain.
The big massage bead surface sets micropore, contains the microcapsules of antimicrobial component in big massage bead lumen loading, is expert at
Walk or wearing process in, sole produces extruding to big massage bead, and internal antibacterial microcapsule slowly discharges active ingredient, reach anti-
Zoopagales.
The antibacterial microcapsule average grain diameter is in 40-60 μ ms.
The antibacterial microcapsule includes capsule-core and cyst wall.
The capsule-core composition includes PAMA and vitamin C is formulated in any proportion.
The cyst wall material includes AKD emulsions and Arabic gum.
The method that the capsule-core and cyst wall are prepared into antibacterial microcapsule includes complex coacervation.
The anti-biotic material is made up of the composition of following weight：Thermoplastic elastomer (TPE) 100g, PLA 20g, polyamide gather
Epichlorohydrin resin 15g, AKD emulsion 20g, plasticizer 2g, silver ion 0.3g, OPC 1g, oxide nano rare earth 2g,
Surfactant 1.5g, zinc oxide 0.6g, nano bamboo powdered carbon 3g, dry cow glue powder 2g；
The preparation method of above-mentioned anti-biotic material is as follows：
(1) polyamide Hydrin resin and nano bamboo powdered carbon are added first in thermoplastic elastomer (TPE), is being mediated
It is kneaded in machine uniform；
(2) AKD emulsions are warming up to 60 DEG C or so, add OPC, dry cow glue powder and silver ion, continuously stir 10
Minute or so, then take out, be put into mixing 15-20 minutes in the kneader in step (1)；
(3) PLA, polyamide Hydrin resin and oxidation are added in the raw material being kneaded in step (2)
Zinc, heat is mixed 2 hours at 130-180 DEG C, then adds surfactant and plasticizer, is made into sizing material injection molding.
Coordinated using thermoplastic elastomer (TPE) and PLA, it is nonirritant, have no toxic side effect, to human height's safety,
Environmentally friendly, plasticity is good, and stability is strong；It is generally acknowledged that anti-biotic material is only used for material surface, not in view of some
Anti-biotic material possesses great penetrating power, that is to say, that can penetrate some materials, its antibiotic effect is by material barrier film
In the case of can show possess powerful penetration in material surface through material.The application add microcapsules, be exactly in order to
The raw material such as its slow-release capability and powerful infiltration function, auxiliary AKD emulsions, oxide nano rare earth and zinc oxide is given full play to, more
Add raising antibiotic effect, reach antibacterial, biocidal efficacies, meet demand of the people to antibiosis and health-care shoes boots, expand antiseptic
Application in footwear material field.
The beneficial effects of the invention are as follows：The present invention is reasonable in design, and practicality is good, changes conventional soles material, and utilize micro-
The slow releasing function of capsule so that antibacterial shoe material is safe to use, lasting, function admirable；The sanitation performance of footwear material is substantially improved,
Value-added content of product is added, and has reached the durability for improving antiseptic, water-wash resistance, broad-spectrum antibacterial property and has reduced antibacterial
Purpose of the agent to skin irritatin.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Conjunction is specifically illustrating, and the present invention is expanded on further.
Embodiment 1
As shown in figure 1, a kind of antibacterial massage playshoes based on microcapsules technology, including sole 1 and sewing are on sole 1
Upper of a shoe 2, sole 1 is made up of anti-biotic material, the small massage bead 4 of projection is provided with the upper surface of sole 1, in the upper surface of sole 1
A big massage bead 3 is respectively equipped with positioned at heel, arch of the foot and forefoot, massage effect can be played to these three regions；
In 0.5-1.5cm, the diameter of big massage bead 3 can have in 2-3cm the diameter of small massage bead 4 to the sole acupoint of human body
Effect stimulate, reach prevent and cure diseases, the purpose of body building, center line word order of the three big massage bead 3 along sole.By antibacterial material
Material is directly used in making sole, and without padding shoe-pad, pin is directly contacted with soles, and can be suppressed and be treated tinea pedis, eliminate in footwear
The growth environment of microorganism, reduce harm of the microorganism to people's pin, while cooperated using size massage bead, increase shoe cavity
Gas permeability, it is more comfortable when making to wear, reduce sweat discharge.
Anti-biotic material is made up of the composition of following weight：Thermoplastic elastomer (TPE) 100g, PLA 20g, polyamide polycyclic oxygen
Chloropropane resin 15g, AKD emulsion 20g, plasticizer 2g, silver ion 0.3g, OPC 1g, oxide nano rare earth 2g, surface
Activating agent 1.5g, zinc oxide 0.6g, nano bamboo powdered carbon 3g, dry cow glue powder 2g；
The preparation method of above-mentioned anti-biotic material is as follows：
(1) polyamide Hydrin resin and nano bamboo powdered carbon are added first in thermoplastic elastomer (TPE), is being mediated
It is kneaded in machine uniform；
(2) AKD emulsions are warming up to 60 DEG C or so, add OPC, dry cow glue powder and silver ion, continuously stir 10
Minute or so, then take out, be put into mixing 15-20 minutes in the kneader in step (1)；
(3) PLA, polyamide Hydrin resin and oxidation are added in the raw material being kneaded in step (2)
Zinc, heat is mixed 2 hours at 130-180 DEG C, then adds surfactant and plasticizer, is made into sizing material injection molding.
Coordinated using thermoplastic elastomer (TPE) and PLA, it is nonirritant, have no toxic side effect, to human height's safety,
Environmentally friendly, plasticity is good, and stability is strong；It is generally acknowledged that anti-biotic material is only used for material surface, not in view of some
Anti-biotic material possesses great penetrating power, that is to say, that can penetrate some materials, its antibiotic effect is by material barrier film
In the case of can show possess powerful penetration in material surface through material.The application adds AKD emulsions, Nano Rare
The raw materials such as native oxide and zinc oxide, the slow releasing function of microcapsules is played, can slowly discharge its antibiotic effect, penetration
By force, sole can be directly acted on, reaches antibacterial, biocidal efficacies, demand of the people to antibiosis and health-care shoes boots is met, expands
Application of the antiseptic in footwear material field.
Embodiment 2
As shown in figure 1, a kind of antibacterial massage playshoes based on microcapsules technology, including sole 1 and sewing are on sole 1
Upper of a shoe 2, sole 1 is made up of anti-biotic material, the small massage bead 4 of projection is provided with the upper surface of sole 1, in sole upper surface position
A big massage bead 3 is respectively equipped with heel, arch of the foot and forefoot, massage effect can be played to these three regions；It is small
The diameter of massage bead 4 is effective in 2-3cm, sole acupoint progress that can be to human body in 0.5-1.5cm, the diameter of big massage bead 3
Stimulate, reach prevent and cure diseases, the purpose of body building.Center line word order of the three big massage bead 3 along sole.Big massage bead 3
Surface sets micropore, has antibacterial microcapsule in the big lumen loading of massage bead 3, and in walking or wearing process, sole is to big massage
Pearl produces extruding, and internal antibacterial microcapsule slowly discharges active ingredient, reaches antibacterial purpose.Antibacterial microcapsule average grain diameter exists
In 40-60 μ ms, antibacterial microcapsule includes capsule-core and cyst wall, and capsule-core composition includes PAMA and vitamin C
It is formulated in any proportion, cyst wall material includes AKD emulsions and Arabic gum, and capsule-core and cyst wall are prepared into antibacterial microcapsule
Method includes complex coacervation.Anti-biotic material is directly used in making sole, without padding shoe-pad, pin is directly contacted with soles, can be with
Suppress and treat tinea pedis, eliminate the growth environment of microorganism in footwear, reduce harm of the microorganism to people's pin, while use size
Massage bead cooperates, and increases the gas permeability of shoe cavity, more comfortable when making to wear, and reduces sweat discharge.
Embodiment 3
As shown in figure 1, a kind of antibacterial massage playshoes based on microcapsules technology, including sole 1 and sewing are on sole 1
Upper of a shoe 2, sole 1 is made up of anti-biotic material, the small massage bead 4 of projection is provided with the upper surface of sole 1, in sole upper surface position
A big massage bead 3 is respectively equipped with heel, arch of the foot and forefoot, massage effect can be played to these three regions；It is small
The diameter of massage bead 4 is effective in 2-3cm, sole acupoint progress that can be to human body in 0.5-1.5cm, the diameter of big massage bead 3
Stimulate, reach prevent and cure diseases, the purpose of body building.Center line word order of the three big massage bead 3 along sole.Big massage bead 3
Surface sets micropore, has antibacterial microcapsule in the big lumen loading of massage bead 3, and in walking or wearing process, sole is to big massage
Pearl produces extruding, and internal antibacterial microcapsule slowly releases active ingredient, reaches antibacterial purpose.Antibacterial microcapsule average grain diameter exists
In 40-60 μ ms, antibacterial microcapsule includes capsule-core and cyst wall, and capsule-core composition includes PAMA and vitamin C
It is formulated in any proportion, cyst wall material includes AKD emulsions and Arabic gum, and capsule-core and cyst wall are prepared into antibacterial microcapsule
Method includes complex coacervation.Anti-biotic material is directly used in making sole, without padding shoe-pad, pin is directly contacted with soles, can be with
Suppress and treat tinea pedis, eliminate the growth environment of microorganism in footwear, reduce harm of the microorganism to people's pin, while use size
Massage bead cooperates, and increases the gas permeability of shoe cavity, more comfortable when making to wear, and reduces sweat discharge.
Anti-biotic material is made up of the composition of following weight：Thermoplastic elastomer (TPE) 100g, PLA 20g, polyamide polycyclic oxygen
Chloropropane resin 15g, AKD emulsion 20g, plasticizer 2g, silver ion 0.3g, OPC 1g, oxide nano rare earth 2g, surface
Activating agent 1.5g, zinc oxide 0.6g, nano bamboo powdered carbon 3g, dry cow glue powder 2g；
The preparation method of above-mentioned anti-biotic material is as follows：
(1) polyamide Hydrin resin and nano bamboo powdered carbon are added first in thermoplastic elastomer (TPE), is being mediated
It is kneaded in machine uniform；
(2) AKD emulsions are warming up to 60 DEG C or so, add OPC, dry cow glue powder and silver ion, continuously stir 10
Minute or so, then take out, be put into mixing 15-20 minutes in the kneader in step (1)；
(3) PLA, polyamide Hydrin resin and oxidation are added in the raw material being kneaded in step (2)
Zinc, heat is mixed 2 hours at 130-180 DEG C, then adds surfactant and plasticizer, is made into sizing material injection molding.
Coordinated using thermoplastic elastomer (TPE) and PLA, it is nonirritant, have no toxic side effect, to human height's safety,
Environmentally friendly, plasticity is good, and stability is strong；It is generally acknowledged that anti-biotic material is only used for material surface, not in view of some
Anti-biotic material possesses great penetrating power, that is to say, that can penetrate some materials, its antibiotic effect is by material barrier film
In the case of can show possess powerful penetration in material surface through material.The application adds AKD emulsions, Nano Rare
The raw materials such as native oxide and zinc oxide, the slow releasing function of microcapsules is played, can slowly discharge its antibiotic effect, penetration
By force, sole can be directly acted on, reaches antibacterial, biocidal efficacies, demand of the people to antibiosis and health-care shoes boots is met, expands
Application of the antiseptic in footwear material field.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (7)
1. a kind of antibacterial massage playshoes based on microcapsules technology, including sole and sewing the upper of a shoe on sole, described
Sole upper surface is provided with the small massage bead of projection, is located at heel, arch of the foot and forefoot in sole upper surface and sets respectively
There is a big massage bead, can play massage effect to these three regions, the diameter of the small massage bead is described in 0.5-1.5cm
The diameter of big massage bead is in 2-6cm, it is characterised in that the sole is made up of anti-biotic material, and the anti-biotic material is by following weight
Composition be made：Thermoplastic elastomer (TPE) 100g, PLA 20g, polyamide Hydrin resin 15g, AKD emulsion 20g, increasing
Mould agent 2g, silver ion 0.3g, OPC 1g, oxide nano rare earth 2g, surfactant 1.5g, zinc oxide 0.6g, nanometer
Bamboo charcoal powder 3g, dry cow glue powder 2g.
2. the antibacterial massage playshoes according to claim 1 based on microcapsules technology, it is characterised in that：It is described three big
Center line word order of the massage bead along sole.
3. the antibacterial massage playshoes according to claim 1 based on microcapsules technology, it is characterised in that：The big massage
Bead surface sets micropore, has antibacterial microcapsule in big massage bead lumen loading.
4. the antibacterial massage playshoes according to claim 3 based on microcapsules technology, it is characterised in that：The antibacterial is micro-
Capsule average grain diameter is in 40-60 μ ms.
5. the antibacterial massage playshoes according to claim 4 based on microcapsules technology, it is characterised in that：The antibacterial is micro-
Capsule includes capsule-core and cyst wall.
6. the antibacterial massage playshoes according to claim 5 based on microcapsules technology, it is characterised in that：The capsule-core into
Point include PAMA and vitamin C is formulated in any proportion.
7. the antibacterial massage playshoes according to claim 5 based on microcapsules technology, it is characterised in that：The cyst wall material
Matter includes AKD emulsions and Arabic gum.
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| CN201610658877.9A CN106307792B (en) | 2016-08-11 | 2016-08-11 | Antibacterial massage playshoes based on microcapsules technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610658877.9A CN106307792B (en) | 2016-08-11 | 2016-08-11 | Antibacterial massage playshoes based on microcapsules technology |
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| CN106307792A CN106307792A (en) | 2017-01-11 |
| CN106307792B true CN106307792B (en) | 2018-01-12 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108514186B (en) | 2018-05-09 | 2020-08-11 | 温州中熙进出口有限公司 | Production method of antibacterial damping shoes |
| CN108741397A (en) * | 2018-05-15 | 2018-11-06 | 福建省足康生物科技有限公司 | The antibacterial playshoes of base microcapsules technology |
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| CN2599953Y (en) * | 2002-12-10 | 2004-01-21 | 上海蓝戈科技发展有限公司 | Multifunctional health-care slippers with bactericidal and deodorization function |
| CN201691145U (en) * | 2010-06-07 | 2011-01-05 | 阮航 | Magnetic therapy body-keeping cloth shoe |
| CN201758876U (en) * | 2010-09-15 | 2011-03-16 | 姚丽珍 | Massage sole |
| CN201938480U (en) * | 2011-03-23 | 2011-08-24 | 刘道矩 | Magnetic therapy slippers |
| CN105400039A (en) * | 2015-11-18 | 2016-03-16 | 吴江市风尚鞋厂 | Antibacterial and mildewproof rubber-plastic shoe material and preparation method thereof |
| CN205321395U (en) * | 2016-01-18 | 2016-06-22 | 温州特依伽鞋材有限公司 | Deodorant sole |
| CN205358414U (en) * | 2016-02-24 | 2016-07-06 | 陈合明 | Novel bathroom massage shoes |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2599953Y (en) * | 2002-12-10 | 2004-01-21 | 上海蓝戈科技发展有限公司 | Multifunctional health-care slippers with bactericidal and deodorization function |
| CN201691145U (en) * | 2010-06-07 | 2011-01-05 | 阮航 | Magnetic therapy body-keeping cloth shoe |
| CN201758876U (en) * | 2010-09-15 | 2011-03-16 | 姚丽珍 | Massage sole |
| CN201938480U (en) * | 2011-03-23 | 2011-08-24 | 刘道矩 | Magnetic therapy slippers |
| CN105400039A (en) * | 2015-11-18 | 2016-03-16 | 吴江市风尚鞋厂 | Antibacterial and mildewproof rubber-plastic shoe material and preparation method thereof |
| CN205321395U (en) * | 2016-01-18 | 2016-06-22 | 温州特依伽鞋材有限公司 | Deodorant sole |
| CN205358414U (en) * | 2016-02-24 | 2016-07-06 | 陈合明 | Novel bathroom massage shoes |
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| CN106307792A (en) | 2017-01-11 |
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Effective date of registration: 20240430 Address after: 551700 small and medium sized Enterprise Incubation Park in qixingguan experimental area, Bijie City, Guizhou Province Patentee after: Bijie qixingguan xinmailun Shoes Co.,Ltd. Country or region after: China Address before: 236500 Dongcheng garden, economic development zone, Jieshou City, Fuyang, Anhui Patentee before: JIESHOU MOUTAINTOP LEISURE GOODS Co.,Ltd. Country or region before: China |
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