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CN106298984A - Solar cell - Google Patents

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Publication number
CN106298984A
CN106298984A CN201510254798.7A CN201510254798A CN106298984A CN 106298984 A CN106298984 A CN 106298984A CN 201510254798 A CN201510254798 A CN 201510254798A CN 106298984 A CN106298984 A CN 106298984A
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electrodes
solar cell
electrode
microns
receiving surface
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严国艺
郑韦志
陈怀宗
黄俊瑞
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Motech Industries Inc
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Motech Industries Inc
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • H10F77/211Electrodes for devices having potential barriers for photovoltaic cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

A solar cell comprises a silicon substrate, an emitter layer, a plurality of first electrodes, a passivation layer and a plurality of second electrodes. The silicon substrate has a light receiving surface and a back surface. The emitter layer is formed under the light receiving surface. The plurality of first electrodes are positioned on the light receiving surface. The passivation layer is located on the back surface and provided with a plurality of linear openings. The second electrodes are respectively positioned in the linear openings and contact the back surface. The plurality of second electrodes are arranged in a plurality of columns along the extending direction and in a plurality of rows along an arrangement direction perpendicular to the extending direction. Each second electrode has a length a in the extending direction. The first distance B is maintained between any two adjacent second electrodes in the same row. 200 microns < B < 1400 microns, and 2 < A/B < 5. And maintaining a second spacing P between any two adjacent rows of second electrodes, wherein P is less than or equal to 1000 microns.

Description

太阳能电池Solar battery

技术领域technical field

本发明是有关于一种太阳能电池,且特别是有关于一种射极钝化及背电极太阳能电池(PERC)。The present invention relates to a solar cell, and more particularly to an emitter passivated and rear electrode solar cell (PERC).

背景技术Background technique

在石化能源短缺以及能源需求量与日俱增的情况下,再生能源(Renewable energy)的开发成为近年来非常重要的课题之一。再生能源泛指永续且无污染的天然能源,例如太阳能、风能、水利能、潮汐能或是生质能等,其中太阳能的开发更是近几年来在能源开发的研究上相当重要且受欢迎的一环。Under the circumstances of the shortage of petrochemical energy and the increasing demand for energy, the development of renewable energy (Renewable energy) has become one of the very important topics in recent years. Renewable energy generally refers to sustainable and non-polluting natural energy, such as solar energy, wind energy, water conservancy energy, tidal energy or biomass energy, among which the development of solar energy is very important and popular in the research of energy development in recent years part of the

太阳能电池是一种能量转换的光电组件(photovoltaic device),其中射极钝化及背电极太阳能电池以其高转换效率而备受关注。射极钝化及背电极太阳能电池相较于传统太阳能电池的主要差异在于:射极钝化及背电极太阳能电池利用钝化技术将正面的射极与背面钝化,以减少表面缺陷。正面射极一般是选择氧化硅(SiO2)作为钝化层,而背面一般是选择氧化硅或氧化铝(Al2O3)作为钝化层。A solar cell is a photovoltaic device for energy conversion, among which emitter passivated and back electrode solar cells have attracted much attention due to their high conversion efficiency. The main difference between emitter passivation and back electrode solar cells compared with traditional solar cells is that emitter passivation and back electrode solar cells use passivation technology to passivate the front emitter and back to reduce surface defects. The front emitter generally chooses silicon oxide (SiO 2 ) as the passivation layer, while the back side generally chooses silicon oxide or aluminum oxide (Al 2 O 3 ) as the passivation layer.

详细而言,射极钝化及背电极太阳能电池的背电极形成的方式,通常是先以激光等方式对钝化层开孔以形成电极接触位置,再于背面网印非穿透性铝胶或者是通过物理气相沉积(PVD)镀上铝,最后与正面网印银胶共烧结后形成电极,其与传统太阳能电池在背面以铝浆整面印刷并烧结,从而形成全面的背面电场(BSF)有所不同。由于射极钝化及背电极太阳能电池的制作仅是在背面进行局部开孔,因此最终能形成局部背电场(Local BSF)并保留大面积的钝化层。另一方面,相较于传统电池而言,射极钝化及背电极太阳能电池增加了其背面的钝化层钝化的面积,因此可有效减少载子在背面再复合的速率。In detail, the method of emitter passivation and back electrode formation of the back electrode of solar cells is usually to open holes in the passivation layer by means of laser to form electrode contact positions, and then screen print non-penetrating aluminum glue on the back Or it is plated with aluminum by physical vapor deposition (PVD), and finally it is co-sintered with silver screen printing on the front side to form an electrode, which is printed and sintered with aluminum paste on the back side of the traditional solar cell to form a comprehensive backside electric field (BSF ) are different. Since emitter passivation and back electrode solar cells are only partially opened on the back, a local back electric field (Local BSF) can eventually be formed and a large area of passivation layer can be retained. On the other hand, compared with conventional solar cells, emitter passivation and back electrode solar cells increase the area of the passivation layer passivation on the back side, thus effectively reducing the rate of carrier recombination on the back side.

由于射极钝化及背电极太阳能电池的背面的钝化层为局部开孔的设计,且背电极通过所述多个开孔与基板背面接触,因此可达到传导电流的目的。虽然背电极与基板的背面的局部接触的设计可使钝化层的钝化面积增加、减少载子的复合,但也同时衍生出背电极与基板的背面接触面积减少,进而造成电阻增加的问题。因此,如何取得较佳的平衡点,以有效地提升光电转换效率,便成为当前亟待解决的问题之一。Since the passivation layer on the back of the emitter passivation and back electrode solar cell is designed with partial openings, and the back electrode is in contact with the back of the substrate through the plurality of openings, the purpose of conducting current can be achieved. Although the design of the local contact between the back electrode and the back of the substrate can increase the passivation area of the passivation layer and reduce the recombination of carriers, it also leads to the reduction of the contact area between the back electrode and the back of the substrate, which in turn causes the problem of increased resistance. . Therefore, how to obtain a better balance point to effectively improve the photoelectric conversion efficiency has become one of the problems to be solved urgently.

发明内容Contents of the invention

本发明提供一种太阳能电池,其能有效地提高光电转换效率。The invention provides a solar cell, which can effectively improve the photoelectric conversion efficiency.

本发明提出一种太阳能电池,其包括硅基材、射极层、多个第一电极、钝化层以及多个第二电极。硅基材具有受光面以及相对于受光面的背面。射极层形成于受光面处。所述多个第一电极位于受光面上。钝化层位于背面上,并具有多个线状开孔。所述多个第二电极分别位于所述多个线状开孔中,并接触背面。每个第二电极具有延伸方向。所述多个第二电极沿着延伸方向排列成多列,并沿着垂直于延伸方向的排列方向排列成多行。每个第二电极在延伸方向上的长度为A。同一行的任两相邻的所述多个第二电极之间维持第一间距B,其中200微米≦B≦1400微米,且2≦A/B≦5。任两行相邻的所述多个第二电极之间维持第二间距P,其中P≦1000微米。The invention provides a solar cell, which includes a silicon substrate, an emitter layer, a plurality of first electrodes, a passivation layer, and a plurality of second electrodes. The silicon substrate has a light-receiving surface and a back surface opposite to the light-receiving surface. The emitter layer is formed on the light receiving surface. The plurality of first electrodes are located on the light receiving surface. The passivation layer is located on the back side and has a plurality of linear openings. The plurality of second electrodes are respectively located in the plurality of linear openings and contact the back surface. Each second electrode has an extension direction. The plurality of second electrodes are arranged in multiple columns along the extending direction, and arranged in multiple rows along the arrangement direction perpendicular to the extending direction. The length of each second electrode in the extending direction is A. A first distance B is maintained between any two adjacent second electrodes in the same row, wherein 200 μm≦B≦1400 μm, and 2≦A/B≦5. A second distance P is maintained between any two adjacent rows of the plurality of second electrodes, wherein P≦1000 microns.

在本发明的一实施例中,A:B=4:1,且800微米≦B≦1000微米,P≦800微米。In an embodiment of the present invention, A:B=4:1, and 800 μm≦B≦1000 μm, and P≦800 μm.

在本发明的一实施例中,上述的任两行相邻的所述多个第二电极与所述多个第一间距在排列方向上彼此相互交错。In an embodiment of the present invention, any two adjacent rows of the plurality of second electrodes and the plurality of first spacings are staggered with each other in the arrangement direction.

在本发明的一实施例中,上述的太阳能电池还包括形成于背面处的多个重掺杂区域。所述多个重掺杂区域与所述多个第二电极的位置分别一一对应。In an embodiment of the present invention, the above solar cell further includes a plurality of heavily doped regions formed on the back side. The positions of the plurality of heavily doped regions correspond to the positions of the plurality of second electrodes respectively.

在本发明的一实施例中,上述的太阳能电池还包括形成于钝化层上的连接电极。连接电极电性连接所述多个多个第二电极。In an embodiment of the present invention, the above-mentioned solar cell further includes a connecting electrode formed on the passivation layer. The connecting electrodes are electrically connected to the plurality of second electrodes.

本发明还提出一种太阳能电池,其包括硅基材、射极层、多个第一电极、钝化层以及背电极。硅基材具有受光面以及相对于受光面的背面。射极层形成于受光面处。所述多个第一电极位于受光面上。钝化层位于背面上,并具有多个线状开孔。每个线状开孔具有延伸方向。所述多个线状开孔沿着延伸方向排列成多列,并沿着垂直于延伸方向的排列方向排列成多行。每个线状开孔在延伸方向上的长度为A。同一行的任两相邻的所述多个线状开孔之间维持第一间距B,其中200微米≦B≦1400微米,且2≦A/B≦5。任两行相邻的所述多个线状开孔之间维持第二间距P,其中P≦1000微米。背电极位于钝化层上,并延伸到所述多个线状开孔中与所述背面接触。The invention also proposes a solar cell, which includes a silicon substrate, an emitter layer, a plurality of first electrodes, a passivation layer, and a back electrode. The silicon substrate has a light-receiving surface and a back surface opposite to the light-receiving surface. The emitter layer is formed on the light receiving surface. The plurality of first electrodes are located on the light receiving surface. The passivation layer is located on the back side and has a plurality of linear openings. Each linear opening has an extending direction. The plurality of linear openings are arranged in multiple rows along the extending direction, and arranged in multiple rows along the arrangement direction perpendicular to the extending direction. The length of each linear opening is A in the extending direction. A first interval B is maintained between any two adjacent linear openings in the same row, wherein 200 μm≦B≦1400 μm, and 2≦A/B≦5. A second pitch P is maintained between any two adjacent rows of the plurality of linear openings, wherein P≦1000 microns. The back electrode is located on the passivation layer and extends into the plurality of linear openings to contact the back.

在本发明的一实施例中,上述的任两行相邻的所述多个线状开孔与所述多个第一间距在排列方向上彼此相互交错。In an embodiment of the present invention, any two adjacent rows of the plurality of linear openings and the plurality of first pitches are staggered with each other in the arrangement direction.

在本发明的一实施例中,上述的太阳能电池还包括形成于背面的多个重掺杂区域。所述多个重掺杂区域与所述多个线状开孔的位置分别一一对应。In an embodiment of the present invention, the above-mentioned solar cell further includes a plurality of heavily doped regions formed on the back side. The positions of the plurality of heavily doped regions correspond to the positions of the plurality of linear openings respectively.

基于上述,本发明的太阳能电池的第二电极采用虚线局部电极的配置方式,其中第二电极具有延伸方向。第二电极沿着所述延伸方向排列成多列并沿着垂直于所述延伸方向的排列方向排列成多行,其中每个第二电极在所述延伸方向上的长度为A。同一行的任两相邻的第二电极之间维持第一间距B,任两行相邻的第二电极之间维持第二间距P。Based on the above, the second electrode of the solar cell of the present invention adopts the arrangement of dotted line local electrodes, wherein the second electrode has an extension direction. The second electrodes are arranged in multiple columns along the extending direction and in multiple rows along the arrangement direction perpendicular to the extending direction, wherein the length of each second electrode in the extending direction is A. A first distance B is maintained between any two adjacent second electrodes in the same row, and a second distance P is maintained between any two adjacent second electrodes in the same row.

详细而言,200微米≦B≦1400微米,且长度A与第一间距B符合关系式:2≦A/B≦5。另一方面,P≦1000微米,因此藉由调整第一间距B的大小来决定长度A的数值范围,并且在藉由调整第一间距B的大小来决定长度A的数值范围的同时,改变第二间距P的大小,藉以得到长度A、第一间距B以及第二间距P等参数设计的较佳范围,便能有效地提升太阳能电池的光电转换效率。Specifically, 200 μm≦B≦1400 μm, and the length A and the first distance B conform to the relationship: 2≦A/B≦5. On the other hand, P≦1000 microns, so by adjusting the size of the first distance B to determine the value range of the length A, and while determining the value range of the length A by adjusting the size of the first distance B, change the value range of the length A The size of the two distances P can be used to obtain a better range of parameter design such as the length A, the first distance B, and the second distance P, so as to effectively improve the photoelectric conversion efficiency of the solar cell.

为让本发明的上述特征和优点能更明显易懂,下文特举实施例,并配合所附图式作详细说明如下。In order to make the above-mentioned features and advantages of the present invention more comprehensible, the following specific embodiments are described in detail together with the accompanying drawings.

附图说明Description of drawings

图1是本发明一实施例的太阳能电池的局部底视图;1 is a partial bottom view of a solar cell according to an embodiment of the present invention;

图2是图1的太阳能电池沿I-I剖线的剖面示意图;Fig. 2 is the schematic cross-sectional view of the solar cell of Fig. 1 along the line I-I;

图3是本发明另一实施例的太阳能电池的局部剖面示意图。FIG. 3 is a schematic partial cross-sectional view of a solar cell according to another embodiment of the present invention.

附图标记说明Explanation of reference signs

100: 太阳能电池100: solar cell

130: 第二电极130: second electrode

150: 钝化层150: passivation layer

151: 线状开孔151: linear opening

A: 长度A: Length

B: 第一间距B: first spacing

D1: 延伸方向D1: Extension direction

D2: 排列方向D2: Arrangement direction

P: 第二间距P: second pitch

具体实施方式detailed description

图1是本发明一实施例的太阳能电池的局部底视图。图2是图1的太阳能电池沿I-I剖线的剖面示意图。请参考图1与图2,在本实施例中,太阳能电池100例如是射极钝化及背电极太阳能电池,其可包括光电转换层110、多个第一电极120以及多个第二电极130。光电转换层110可以是由P型半导体层及N型半导体层堆栈形成的PN接面的半导体堆栈结构,或是由P型半导体层、本质层、N型半导体层堆栈形成的PIN接面的半导体堆栈结构。FIG. 1 is a partial bottom view of a solar cell according to an embodiment of the present invention. FIG. 2 is a schematic cross-sectional view of the solar cell in FIG. 1 along line I-I. Please refer to FIG. 1 and FIG. 2. In this embodiment, the solar cell 100 is, for example, an emitter-passivated and back-electrode solar cell, which may include a photoelectric conversion layer 110, a plurality of first electrodes 120, and a plurality of second electrodes 130. . The photoelectric conversion layer 110 may be a semiconductor stack structure of a PN junction formed by stacking a P-type semiconductor layer and an N-type semiconductor layer, or a semiconductor layer of a PIN junction formed by stacking a P-type semiconductor layer, an essential layer, and an N-type semiconductor layer. stack structure.

详细而言,光电转换层110可包括硅基材111以及射极层112。硅基材111具有受光面111a以及相对于受光面111a的背面111b。第一电极120位于受光面111a上,且第二电极130位于背面111b上。另一方面,射极层112形成于受光面111a处。硅基材111例如是由P型硅晶所构成,并且在受光面111a对硅基材111掺杂有磷扩散掺杂层以作为射极层112。于本实施例中,射极层112位于硅基材111内,且靠近受光面111a的所在处。意即,射极层112位于硅基材111的受光面111a之下,但本发明不以此为限。举例来说,在其他实施例中,射极层也可采用沉积的方式形成于硅基材之上。意即,射极层位于硅基材的受光面之上。在另一实施例中,硅基材也可以是由N型硅晶所构成,并且在硅基材的受光面上掺杂有硼扩散掺杂层以作为射极层。In detail, the photoelectric conversion layer 110 may include a silicon substrate 111 and an emitter layer 112 . The silicon substrate 111 has a light-receiving surface 111a and a back surface 111b opposite to the light-receiving surface 111a. The first electrode 120 is located on the light receiving surface 111a, and the second electrode 130 is located on the back surface 111b. On the other hand, the emitter layer 112 is formed at the light receiving surface 111a. The silicon substrate 111 is made of, for example, P-type silicon crystal, and the silicon substrate 111 is doped with a phosphorus doped layer on the light receiving surface 111 a as the emitter layer 112 . In this embodiment, the emitter layer 112 is located in the silicon substrate 111 and is close to the light receiving surface 111a. That is, the emitter layer 112 is located under the light-receiving surface 111 a of the silicon substrate 111 , but the invention is not limited thereto. For example, in other embodiments, the emitter layer can also be formed on the silicon substrate by deposition. That is, the emitter layer is located on the light-receiving surface of the silicon substrate. In another embodiment, the silicon substrate may also be made of N-type silicon crystal, and a boron doped layer is doped on the light-receiving surface of the silicon substrate as the emitter layer.

在本实施例中,太阳能电池100还包括抗反射层140。抗反射层140位于受光面111a的上方,并连接射极层112。抗反射层140的材料可包括氮化硅、氧化硅、二氧化钛、氟化镁或上述材料的组合,且通过例如物理气相沉积、化学气相沉积或其他适当的制程而形成于射极层112上。In this embodiment, the solar cell 100 further includes an anti-reflection layer 140 . The anti-reflection layer 140 is located above the light receiving surface 111 a and connected to the emitter layer 112 . The material of the anti-reflection layer 140 may include silicon nitride, silicon oxide, titanium dioxide, magnesium fluoride, or a combination thereof, and is formed on the emitter layer 112 by, for example, physical vapor deposition, chemical vapor deposition, or other suitable processes.

在抗反射层140形成于射极层112上之后,可通过例如电镀、网印或物理气相沉积等方式形成第一电极120。以采用电镀或物理气相沉积等方式来制作第一电极120为例,为使第一电极120接触射极层112,则于制作第一电极120之前,需预先通过例如雷射等方式于抗反射层140形成可供第一电极120穿过且容纳的开口。还以采用网印方式来制作第一电极120为例,则形成于抗反射层140上的导电浆(可用以形成第一电极120之材料)可在高温烧结时烧穿抗反射层140。最后,固化成型的第一电极120便能与射极层112接触。一般而言,第一电极120的材质可为银、铝或银铝混合物,而本实施例的第一电极120例如是由导电银浆所构成。After the anti-reflection layer 140 is formed on the emitter layer 112, the first electrode 120 may be formed by, for example, electroplating, screen printing or physical vapor deposition. Taking electroplating or physical vapor deposition as an example to make the first electrode 120, in order to make the first electrode 120 contact the emitter layer 112, before making the first electrode 120, it is necessary to use anti-reflection methods such as laser in advance. The layer 140 forms an opening through which the first electrode 120 can pass and be accommodated. Taking the first electrode 120 made by screen printing as an example, the conductive paste formed on the anti-reflection layer 140 (the material that can be used to form the first electrode 120 ) can burn through the anti-reflection layer 140 during high-temperature sintering. Finally, the cured first electrode 120 can be in contact with the emitter layer 112 . Generally speaking, the material of the first electrode 120 can be silver, aluminum or silver-aluminum mixture, and the first electrode 120 of this embodiment is made of conductive silver paste, for example.

如图2所示,太阳能电池100更包括钝化层150。钝化层150位于背面111b上。意即,钝化层150与抗反射层140位于光电转换层110的相对两侧。在本实施例中,钝化层150可以是非晶硅层或至少一层以上的介电层所组成。以多层介电层构成钝化层150为例,所述多个介电层所选用的材料可各不相同、部分相同或完全相同。通常而言,介电层的材料可为二氧化硅、氮化硅、氧化铝、二氧化钛或上述材料的组合。钝化层150的形成可采用例如是物理气相沉积、化学气相沉积或其他适当的制程而形成于硅基材111的背面111b上。在钝化层150形成于硅基材111上后,可通过雷射开孔或画线在钝化层150上形成多个平行排列线状开孔151,而所述多个线状开孔151会暴露出部分的背面111b。之后,例如是透过电镀、网印或物理气相沉积等方式在线状开孔151所暴露出的背面111b上形成第二电极130。换个角度来说,第二电极130会对应设置在线状开孔151内,并接触硅基材111的背面111b,其中第二电极130的材质可为银、铝或银铝混合物。在本实施例中,当硅基材111例如是由P型硅晶所构成时,用以制作第二电极130的材质例如是铝浆。因此,在进行完烧结制程后,对应所述多个线状开孔151的硅基材111的背面111b处可同步形成有多个铝硅合金的P型的重掺杂区域170,藉由所述多个重掺杂区域170与硅基材111之间产生电位差,从而可形成多个局部背电场(LBSF)的效果。其中所述多个重掺杂区域170和局部背电场的位置皆与所述多个第二电极130的位置分别一一对应,如图2所示。而在另一实施例中,当硅基材111例如是由N型硅晶所构成时,可先利用扩散掺杂工艺并采用例如磷等其他相关材质来掺杂,在硅基材111的背面111b形成多个间隔分布的N型的重掺杂区域,而所述多个磷掺杂的N型的重掺杂区域会与硅基材之间产生电位差,从而形成多个局部背电场的效果,此时第二电极130的材质可为银、铝或银铝混合物或其他材质。上述第一电极120或第二电极130可使用网版印刷或CVD、PVD等沉积技术来完成。As shown in FIG. 2 , the solar cell 100 further includes a passivation layer 150 . A passivation layer 150 is located on the rear surface 111b. That is, the passivation layer 150 and the anti-reflection layer 140 are located on opposite sides of the photoelectric conversion layer 110 . In this embodiment, the passivation layer 150 may be composed of an amorphous silicon layer or at least one dielectric layer. Taking the passivation layer 150 formed by multiple dielectric layers as an example, the materials selected for the multiple dielectric layers may be different, partially or completely the same. Generally, the material of the dielectric layer can be silicon dioxide, silicon nitride, aluminum oxide, titanium dioxide or a combination of the above materials. The passivation layer 150 can be formed on the back surface 111b of the silicon substrate 111 by using, for example, physical vapor deposition, chemical vapor deposition or other suitable processes. After the passivation layer 150 is formed on the silicon substrate 111, a plurality of linear openings 151 arranged in parallel can be formed on the passivation layer 150 by laser drilling or drawing lines, and the plurality of linear openings 151 A portion of the rear surface 111b is exposed. Afterwards, the second electrode 130 is formed on the back surface 111 b exposed by the linear opening 151 , for example, by means of electroplating, screen printing, or physical vapor deposition. To put it another way, the second electrode 130 is correspondingly disposed in the linear opening 151 and contacts the back surface 111b of the silicon substrate 111 , wherein the material of the second electrode 130 can be silver, aluminum or a silver-aluminum mixture. In this embodiment, when the silicon substrate 111 is made of P-type silicon, for example, the material used to make the second electrode 130 is, for example, aluminum paste. Therefore, after the sintering process is completed, a plurality of P-type heavily doped regions 170 of Al-Si alloy can be formed synchronously on the back surface 111b of the silicon substrate 111 corresponding to the plurality of linear openings 151. A potential difference is generated between the plurality of heavily doped regions 170 and the silicon substrate 111 , thereby forming a plurality of local back electric field (LBSF) effects. The positions of the plurality of heavily doped regions 170 and the local back electric field are in one-to-one correspondence with the positions of the plurality of second electrodes 130 , as shown in FIG. 2 . In another embodiment, when the silicon substrate 111 is made of N-type silicon crystal, it can be doped with other related materials such as phosphorus by using the diffusion doping process, and the back surface of the silicon substrate 111 111b forms a plurality of N-type heavily doped regions distributed at intervals, and the plurality of phosphorus-doped N-type heavily doped regions will generate a potential difference with the silicon substrate, thereby forming a plurality of local back electric fields. As a result, the material of the second electrode 130 can be silver, aluminum or silver-aluminum mixture or other materials. The above-mentioned first electrode 120 or second electrode 130 can be completed using screen printing or CVD, PVD and other deposition techniques.

如图1所示,每个第二电极130例如是条状电极,且具有延伸方向D1。所述多个第二电极130沿着延伸方向D1排列成多列,并沿着垂直于延伸方向D1的排列方向D2排列成多行。每个第二电极130在延伸方向D1上的长度为A。同一行的任两相邻的第二电极130之间维持第一间距B。在本实施例中,200微米≦B≦1400微米,且2≦A/B≦5。另一方面,任两行相邻的第二电极130之间维持第二间距P,其中P≦1000微米。As shown in FIG. 1 , each second electrode 130 is, for example, a strip electrode and has an extending direction D1. The plurality of second electrodes 130 are arranged in a plurality of columns along the extending direction D1, and arranged in a plurality of rows along an arrangement direction D2 perpendicular to the extending direction D1. The length of each second electrode 130 in the extending direction D1 is A. A first distance B is maintained between any two adjacent second electrodes 130 in the same row. In this embodiment, 200 μm≦B≦1400 μm, and 2≦A/B≦5. On the other hand, any two rows of adjacent second electrodes 130 maintain a second pitch P, where P≦1000 microns.

具体来说,任两行相邻的所述多个第二电极130与所述多个第一间距B于排列方向D2上彼此相互交错。也即,其中一行中的一个第二电极130与相邻的另一行中的一个第一间距B的位置对应。如此一来,相邻的不同行中的两个第一间距B的位置将不会直接对应紧邻,藉以避免造成硅基材111内靠近第一间距B处的载子要移动到第二电极130的距离过远而衍生电流收集不顺的问题,因而有利于发电效率的提升。Specifically, any two adjacent rows of the plurality of second electrodes 130 and the plurality of first intervals B are staggered with each other in the arrangement direction D2. That is, one second electrode 130 in one row corresponds to the position of one first interval B in another adjacent row. In this way, the positions of the two first distances B in different adjacent rows will not be directly adjacent to each other, so as to prevent the carriers in the silicon substrate 111 near the first distance B from moving to the second electrode 130 If the distance is too long, the problem of current collection is not smooth, which is conducive to the improvement of power generation efficiency.

简言之,第二电极130例如是采用虚线局部电极的配置方式。由于长度A与第一间距B符合关系式:2≦A/B≦5,因此可藉由调整第一间距B的大小来决定长度A的数值范围。此外,本实施例也可在藉由调整第一间距B的大小来决定长度A的数值范围的同时改变第二间距P的大小,藉以得到长度A、第一间距B以及第二间距P等参数设计的较佳范围。如此一来,便能有效地提升太阳能电池100的光电转换效率。In short, the second electrodes 130 are, for example, arranged in a dotted-line local electrode configuration. Since the length A and the first distance B conform to the relational expression: 2≦A/B≦5, the value range of the length A can be determined by adjusting the size of the first distance B. In addition, in this embodiment, the value range of the length A can be determined by adjusting the size of the first distance B, and at the same time, the size of the second distance P can be changed, so as to obtain parameters such as the length A, the first distance B, and the second distance P. better range of design. In this way, the photoelectric conversion efficiency of the solar cell 100 can be effectively improved.

为更加明确地阐述本发明的意思,本发明所提出的参数设计也可以通过形成在钝化层150上的多个线状开孔151来定义,这是由于第二电极130分别填充在线状开孔151中,因此前述两者的形状与轮廓实质上是相吻合的。In order to illustrate the meaning of the present invention more clearly, the parameter design proposed by the present invention can also be defined by a plurality of linear openings 151 formed on the passivation layer 150, because the second electrodes 130 respectively fill the linear openings. In the hole 151, the shapes and contours of the aforementioned two are substantially coincident.

如图1所示,每个线状开孔151具有延伸方向D1。所述多个线状开孔151沿着延伸方向D1排列成多列,并沿着垂直于延伸方向D1的排列方向D2排列成多行。每个线状开孔151在延伸方向D1上的长度为A。同一行的任两相邻的线状开孔151之间维持第一间距B。200微米≦B≦1400微米,且2≦A/B≦5。任两行相邻的线状开孔151之间维持第二间距P,其中P≦1000微米。As shown in FIG. 1 , each linear opening 151 has an extending direction D1. The plurality of linear openings 151 are arranged in a plurality of rows along the extending direction D1 and arranged in a plurality of rows along an arrangement direction D2 perpendicular to the extending direction D1. The length of each linear opening 151 in the extending direction D1 is A. As shown in FIG. A first distance B is maintained between any two adjacent linear openings 151 in the same row. 200 microns≦B≦1400 microns, and 2≦A/B≦5. A second pitch P is maintained between any two rows of adjacent linear openings 151 , wherein P≦1000 μm.

具体而言,任两行相邻的所述多个线状开孔151与所述多个第一间距B于排列方向D2上彼此相互交错。意即,其中一行中的一个线状开孔151与相邻的另一行中的一个第一间距B的位置对应,藉以提升填充于所述多个线状开孔151中的所述多个第二电极130的电流收集的效果。在前述线状开孔151的布局下,相邻的不同行中的两个第一间距B的位置将不会直接对应紧邻,藉以避免造成硅基材111内靠近第一间距B处的载子要移动到第二电极130的距离过远而衍生电流收集不顺的问题,因而有利于发电效率的提升。Specifically, any two adjacent rows of the plurality of linear openings 151 and the plurality of first intervals B are staggered with each other along the arrangement direction D2. That is, one linear opening 151 in one row corresponds to the position of a first distance B in another adjacent row, so as to enhance the plurality of first spacings B filled in the plurality of linear openings 151. The effect of the current collection of the two electrodes 130 . Under the layout of the aforementioned linear openings 151, the positions of the two first distances B in different adjacent rows will not directly correspond to each other, so as to avoid causing carriers near the first distance B in the silicon substrate 111 If the distance to be moved to the second electrode 130 is too far, the problem of current collection will not be smooth, which is beneficial to the improvement of power generation efficiency.

以下将列举数个实验例来验证本发明的功效。下列实验数据的比较基础是以传统上非虚线形式的电极(意即,在延伸方向上为纯粹直线的电极或在延伸方向上为单一直线的线状开孔的形式的电极),且第二间距P分别设计为1000微米以及800微米来进行。Several experimental examples will be listed below to verify the effectiveness of the present invention. The comparison basis of the following experimental data is based on electrodes in the form of traditional non-dashed lines (that is, electrodes that are purely straight lines in the direction of extension or electrodes in the form of linear openings that are single straight lines in the direction of extension), and the second The pitches P are designed to be 1000 microns and 800 microns respectively.

实验例一:在第二间距P等于1000微米,且长度A与第一间距B之间的比例分别为2:1、4:1以及5:1等参数设计条件下,太阳能电池100的光电转换效率,其结果如下表一所示。Experimental Example 1: Under the design conditions of the second spacing P equal to 1000 microns, and the ratio between the length A and the first spacing B being 2:1, 4:1, and 5:1, the photoelectric conversion of the solar cell 100 efficiency, and the results are shown in Table 1 below.

表一Table I

实验例二:在第二间距P等于800微米,且长度A与第一间距B之间的比例分别为2:1、4:1以及5:1等参数设计条件下,太阳能电池100的光电转换效率,其结果如下表二所示。Experimental Example 2: The photoelectric conversion of the solar cell 100 under the design conditions that the second pitch P is equal to 800 microns, and the ratios between the length A and the first pitch B are 2:1, 4:1, and 5:1, respectively. efficiency, and the results are shown in Table 2 below.

表二Table II

由表一与表二可得知,当长度A与第一间距B之间的比例(即A:B)由2:1增加到4:1时,太阳能电池100的光电转换效率可获得明显地提升。然而,当长度A与第一间距B之间的比例(即A:B)持续增加到5:1时,太阳能电池100的光电转换效率便约略回复到A:B=2:1时的水平。此外,当第一间距B自200微米增加至1600微米时,实验例一的太阳能电池100的光电转换效率可在第一间距B大于等于400微米且小于等于1200微米的区间范围内逼近峰值,而实验例二的太阳能电池100的光电转换效率可在第一间距B大于等于400微米且小于等于1000微米的区间范围内逼近峰值,在第一间距B大于1400微米后,长度A与第一间距B之间的比例分别为2:1、4:1以及5:1的太阳能电池100的光电转换效率便约略回复到第一间距B等于200微米时的水平。因此,藉由将第二电极130的配置的参数设计制定为P≦1000微米、200微米≦B≦1400微米以及2≦A/B≦5,可有效地提升太阳能电池100的光电转换效率。It can be seen from Table 1 and Table 2 that when the ratio between the length A and the first distance B (ie A:B) is increased from 2:1 to 4:1, the photoelectric conversion efficiency of the solar cell 100 can be significantly improved. promote. However, when the ratio between the length A and the first distance B (ie, A:B) continues to increase to 5:1, the photoelectric conversion efficiency of the solar cell 100 is approximately restored to the level when A:B=2:1. In addition, when the first distance B is increased from 200 microns to 1600 microns, the photoelectric conversion efficiency of the solar cell 100 of Experimental Example 1 can approach the peak within the interval range of the first distance B greater than or equal to 400 microns and less than or equal to 1200 microns, while The photoelectric conversion efficiency of the solar cell 100 of Experimental Example 2 can approach the peak value within the range of the first distance B greater than or equal to 400 microns and less than or equal to 1000 microns. After the first distance B is greater than 1400 microns, the length A and the first distance B The photoelectric conversion efficiencies of the solar cells 100 with the ratios of 2:1, 4:1 and 5:1 are roughly restored to the level when the first distance B is equal to 200 micrometers. Therefore, the photoelectric conversion efficiency of the solar cell 100 can be effectively improved by designing the configuration parameters of the second electrode 130 as P≦1000 μm, 200 μm≦B≦1400 μm, and 2≦A/B≦5.

以下将列举其他实施例以作为说明。在此必须说明的是,下述实施例沿用前述实施例的组件标号与部分内容,其中采用相同的标号来表示相同或近似的组件,并且省略了相同技术内容的说明。关于省略部分的说明可参考前述实施例,下述实施例不再重复赘述。Other embodiments are listed below for illustration. It must be noted here that the following embodiments use the component numbers and partial content of the previous embodiments, wherein the same numbers are used to denote the same or similar components, and descriptions of the same technical content are omitted. For the description of omitted parts, reference may be made to the foregoing embodiments, and the following embodiments will not be repeated.

图3是本发明另一实施例的太阳能电池的局部剖面示意图。请参考图3,图3的太阳能电池100A与图2的太阳能电池100大致相似,前述两者的主要差异在于:本实施例的太阳能电池100A还包括形成于钝化层150上的连接电极160。连接电极160电性连接所述多个第二电极130,其中连接电极160与所述多个第二电极130可构成背电极180。此图3是为了说明一般在图2的背面仍是会有设置连接电极160,从而构成可将电力全面地向外传输的背电极180。FIG. 3 is a schematic partial cross-sectional view of a solar cell according to another embodiment of the present invention. Please refer to FIG. 3 , the solar cell 100A shown in FIG. 3 is substantially similar to the solar cell 100 shown in FIG. 2 . The connection electrode 160 is electrically connected to the plurality of second electrodes 130 , wherein the connection electrode 160 and the plurality of second electrodes 130 can form a back electrode 180 . This FIG. 3 is for explaining that the connecting electrodes 160 are generally still provided on the back of FIG. 2 , so as to constitute the back electrodes 180 that can fully transmit power outward.

由于连接电极160例如是全面覆盖于钝化层150上以与各个线状开孔151内的第二电极130接触,因此各个线状开孔151内的第二电极130可通过连接电极160而彼此电性连接,藉以从硅基材111内收集光生载子并向外传递。一般而言,连接电极160的材质可为银、铝或银铝混合物,而本实施例的连接电极160的材质例如是选用铝浆。Since the connecting electrode 160 is, for example, fully covered on the passivation layer 150 to contact the second electrode 130 in each linear opening 151, the second electrodes 130 in each linear opening 151 can be connected to each other through the connecting electrode 160. Electrically connected, so as to collect photo-generated carriers from the silicon substrate 111 and transmit them to the outside. Generally speaking, the material of the connecting electrode 160 can be silver, aluminum or silver-aluminum mixture, and the material of the connecting electrode 160 in this embodiment is, for example, aluminum paste.

在另一实施例中,连接电极160并未全面覆盖在钝化层150上,进而可暴露出钝化层150的一部分。换言之,只要能使各个第二电极130彼此电性连接,连接电极160也可采用带状、条状或树枝状等态样形成于钝化层150上,藉以节省制作连接电极160的材料成本。在又一实施例中,也可在硅基材111的背面111b形成有背银电极(图中未示出),背银电极的数量视实际需求而定。背银电极的配置可采用仅位于钝化层150之上的完全浮接(floating)形式。意即,背银电极未接触到硅基材111的背面111b,或者是有接触到硅基材111的背面111b的形式,其中背银电极主要作为供焊带焊接所用。In another embodiment, the connection electrode 160 does not entirely cover the passivation layer 150 , and thus a part of the passivation layer 150 may be exposed. In other words, as long as the second electrodes 130 can be electrically connected to each other, the connection electrodes 160 can also be formed on the passivation layer 150 in strips, strips, or dendrites, so as to save material costs for making the connection electrodes 160 . In yet another embodiment, back silver electrodes (not shown in the figure) may also be formed on the back surface 111 b of the silicon substrate 111 , and the number of back silver electrodes depends on actual needs. The configuration of the back silver electrode can be fully floating only on the passivation layer 150 . That is, the back silver electrode is not in contact with the back surface 111b of the silicon substrate 111, or is in contact with the back surface 111b of the silicon substrate 111, wherein the back silver electrode is mainly used for ribbon welding.

综上所述,本发明的太阳能电池的第二电极采用虚线局部电极的配置方式,其中第二电极具有延伸方向。第二电极沿着前述延伸方向排列成多列并沿着垂直于前述延伸方向的排列方向排列成多行,其中每个第二电极在前述延伸方向上的长度为A。同一行的任两相邻的第二电极之间维持第一间距B,任两行相邻的第二电极之间维持第二间距P。To sum up, the second electrode of the solar cell of the present invention adopts the arrangement of dotted line local electrodes, wherein the second electrode has an extension direction. The second electrodes are arranged in multiple columns along the extending direction and in multiple rows along the arrangement direction perpendicular to the extending direction, wherein the length of each second electrode in the extending direction is A. A first distance B is maintained between any two adjacent second electrodes in the same row, and a second distance P is maintained between any two adjacent second electrodes in the same row.

详细而言,200微米≦B≦1400微米,且长度A与第一间距B符合关系式:2≦A/B≦5。另一方面,P≦1000微米。因此,藉由调整第一间距B的大小来决定长度A的数值范围,并且在藉由调整第一间距B的大小来决定长度A的数值范围的同时改变第二间距P的大小,藉以得到长度A、第一间距B以及第二间距P等参数设计的较佳范围,便能有效地提升太阳能电池的光电转换效率。较佳的,当P≦800微米时,其各组参数下的结果通常都优于P≦1000。此外,当A:B=4:1,且第一间距B分别等于800微米和1000微米时,在实验上分别有次高0.16%和最高0.2%的效率提升。因此,当满足A:B=4:1、800微米≦B≦1000微米以及P≦800微米等条件时,太阳能电池能具有良好的发电效果。Specifically, 200 μm≦B≦1400 μm, and the length A and the first distance B conform to the relationship: 2≦A/B≦5. On the other hand, P≦1000 μm. Therefore, the value range of the length A is determined by adjusting the size of the first distance B, and while the value range of the length A is determined by adjusting the size of the first distance B, the size of the second distance P is changed to obtain the length The optimal ranges of parameter design such as A, the first distance B and the second distance P can effectively improve the photoelectric conversion efficiency of the solar cell. Preferably, when P≦800 microns, the results under each set of parameters are usually better than P≦1000. In addition, when A:B=4:1, and the first spacing B is equal to 800 μm and 1000 μm, respectively, the second highest 0.16% and the highest 0.2% increase in efficiency are obtained experimentally. Therefore, when the conditions such as A:B=4:1, 800 μm≦B≦1000 μm, and P≦800 μm are satisfied, the solar cell can have a good power generation effect.

虽然本发明已通过上述实施例披露,但是其并非用以限定本发明,任何所属技术领域中具有通常知识的技术人员,在不脱离本发明的精神和范围内,当可作些许的更动与修改,所以本发明的保护范围当视后附的权利要求所界定的范围为准。Although the present invention has been disclosed through the above-mentioned embodiments, it is not intended to limit the present invention. Any skilled person in the technical field with common knowledge may make some changes and modifications without departing from the spirit and scope of the present invention. modification, so the scope of protection of the present invention shall prevail as defined by the appended claims.

Claims (9)

1.一种太阳能电池,该太阳能电池包括:1. A solar cell comprising: 硅基材,具有受光面以及相对于所述受光面的背面;A silicon substrate having a light-receiving surface and a back surface opposite to the light-receiving surface; 射极层,形成于所述受光面处;an emitter layer formed at the light-receiving surface; 多个第一电极,位于所述受光面上;a plurality of first electrodes located on the light-receiving surface; 钝化层,位于所述背面上并具有多个线状开孔;以及a passivation layer on the back surface and having a plurality of linear openings; and 多个第二电极,分别位于所述多个线状开孔中并接触所述背面,每个所述第二电极具有延伸方向,所述多个第二电极沿着所述延伸方向排列成多列,并沿着垂直于所述延伸方向的排列方向排列成多行,其中每个所述第二电极在所述延伸方向上的长度为A,A plurality of second electrodes are respectively located in the plurality of linear openings and contact the back surface, each of the second electrodes has an extension direction, and the plurality of second electrodes are arranged in a plurality of rows along the extension direction. and arranged in multiple rows along the arrangement direction perpendicular to the extension direction, wherein the length of each second electrode in the extension direction is A, 同一行的任两相邻的所述多个第二电极之间维持第一间距B,其中200微米≦B≦1400微米,且2≦A/B≦5,A first distance B is maintained between any two adjacent second electrodes in the same row, wherein 200 microns≦B≦1400 microns, and 2≦A/B≦5, 任两行相邻的所述多个第二电极之间维持第二间距P,其中P≦1000微米。A second distance P is maintained between any two adjacent rows of the plurality of second electrodes, wherein P≦1000 microns. 2.根据权利要求1所述的太阳能电池,其中A:B=4:1,且800微米≦B≦1000微米,P≦800微米。2 . The solar cell according to claim 1 , wherein A:B=4:1, and 800 μm≦B≦1000 μm, and P≦800 μm. 3.根据权利要求1和2中任一项权利要求所述的太阳能电池,其中任两行相邻的所述多个第二电极与所述多个第一间距在所述排列方向上彼此相互交错。3. The solar cell according to any one of claims 1 and 2, wherein any two adjacent rows of the plurality of second electrodes and the plurality of first spacings are mutually mutual in the arrangement direction staggered. 4.根据权利要求1和2中任一项权利要求所述的太阳能电池,该太阳能电池还包括:4. The solar cell according to any one of claims 1 and 2, further comprising: 形成于所述背面的多个重掺杂区域,所述多个重掺杂区域与所述多个第二电极的位置分别一一对应。A plurality of heavily doped regions are formed on the back surface, and the positions of the plurality of heavily doped regions correspond to the positions of the plurality of second electrodes respectively. 5.根据权利要求1和2中任一项权利要求所述的太阳能电池,该太阳能电池还包括:5. The solar cell according to any one of claims 1 and 2, further comprising: 形成于所述钝化层上的连接电极,所述连接电极电性连接所述多个第二电极。A connection electrode formed on the passivation layer, the connection electrode is electrically connected to the plurality of second electrodes. 6.一种太阳能电池,该太阳能电池包括:6. A solar cell comprising: 硅基材,具有受光面以及相对于所述受光面的背面;A silicon substrate having a light-receiving surface and a back surface opposite to the light-receiving surface; 射极层,形成于所述受光面处;an emitter layer formed at the light-receiving surface; 多个第一电极,位于所述受光面上;a plurality of first electrodes located on the light-receiving surface; 钝化层,位于所述背面上并具有多个线状开孔,每个所述线状开孔具有延伸方向,所述多个线状开孔沿着所述延伸方向排列成多列,并沿着垂直于所述延伸方向的排列方向排列成多行,其中每个所述线状开孔在所述延伸方向上的长度为A,The passivation layer is located on the back surface and has a plurality of linear openings, each of the linear openings has an extending direction, and the plurality of linear openings are arranged in multiple rows along the extending direction, and Arranging in multiple rows along the arrangement direction perpendicular to the extension direction, wherein the length of each linear opening in the extension direction is A, 同一行的任两相邻的所述多个线状开孔之间维持第一间距B,其中200微米≦B≦1400微米,且2≦A/B≦5,A first distance B is maintained between any two adjacent linear openings in the same row, wherein 200 microns≦B≦1400 microns, and 2≦A/B≦5, 任两行相邻的所述多个线状开孔之间维持第二间距P,其中P≦1000微米;以及A second pitch P is maintained between any two rows of adjacent linear openings, where P≦1000 microns; and 背电极,位于所述钝化层上并延伸到所述多个线状开孔中与所述背面接触。The back electrode is located on the passivation layer and extends into the plurality of linear openings to contact the back surface. 7.根据权利要求6所述的太阳能电池,其中A:B=4:1,且800微米≦B≦1000微米,P≦800微米。7 . The solar cell according to claim 6 , wherein A:B=4:1, and 800 μm≦B≦1000 μm, and P≦800 μm. 8.根据权利要求6和7中任一项权利要求所述的太阳能电池,其中任两行相邻的所述多个线状开孔与所述多个第一间距于所述排列方向上彼此相互交错。8. The solar cell according to any one of claims 6 and 7, wherein any two adjacent rows of the plurality of linear openings and the plurality of first distances are mutually separated in the arrangement direction intertwined. 9.根据权利要求6和7中任一项权利要求所述的太阳能电池,该太阳能电池还包括:9. The solar cell according to any one of claims 6 and 7, further comprising: 形成于所述背面的多个重掺杂区域,所述多个重掺杂区域与所述多个线状开孔的位置分别一一对应。A plurality of heavily doped regions are formed on the back surface, and the positions of the plurality of heavily doped regions correspond to the positions of the plurality of linear openings respectively.
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