CN106279243A - 一种草铵膦复配草甘膦的水剂助剂及其制备方法 - Google Patents
一种草铵膦复配草甘膦的水剂助剂及其制备方法 Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 28
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000005562 Glyphosate Substances 0.000 title claims abstract description 24
- 229940097068 glyphosate Drugs 0.000 title claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 title claims abstract description 21
- 238000013329 compounding Methods 0.000 title description 3
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 title 1
- ZBMRKNMTMPPMMK-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid;azane Chemical compound [NH4+].CP(O)(=O)CCC(N)C([O-])=O ZBMRKNMTMPPMMK-UHFFFAOYSA-N 0.000 claims abstract description 27
- 125000002252 acyl group Chemical group 0.000 claims abstract description 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 14
- -1 aminoethyl 3 aminopropyltriethoxy dimethoxysilane mono succinate Chemical compound 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 6
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- QMMBZOSZCYBCDC-UHFFFAOYSA-N NCCNCCC[SiH](OC(OCC)(OCC)OCC)OC Chemical compound NCCNCCC[SiH](OC(OCC)(OCC)OCC)OC QMMBZOSZCYBCDC-UHFFFAOYSA-N 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- 239000001384 succinic acid Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 239000013530 defoamer Substances 0.000 claims 1
- UXFBJATYVZPQTG-UHFFFAOYSA-N dimethoxysilicon Chemical compound CO[Si]OC UXFBJATYVZPQTG-UHFFFAOYSA-N 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 description 8
- 230000002363 herbicidal effect Effects 0.000 description 8
- 239000004009 herbicide Substances 0.000 description 8
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- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 244000074881 Conyza canadensis Species 0.000 description 2
- 235000004385 Conyza canadensis Nutrition 0.000 description 2
- 244000052363 Cynodon dactylon Species 0.000 description 2
- 235000007351 Eleusine Nutrition 0.000 description 2
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- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
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- 150000001412 amines Chemical class 0.000 description 1
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- RENRQMCACQEWFC-UGKGYDQZSA-N lnp023 Chemical compound C1([C@H]2N(CC=3C=4C=CNC=4C(C)=CC=3OC)CC[C@@H](C2)OCC)=CC=C(C(O)=O)C=C1 RENRQMCACQEWFC-UGKGYDQZSA-N 0.000 description 1
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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Abstract
本发明公开了一种草铵膦复配草甘膦的水剂助剂,其特性在于,所述的水剂助剂为N‑氨乙基‑3‑氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠,其结构如下：
Description
技术领域
本发明涉及一种草铵膦复配草甘膦的水剂助剂及其制备方法。
背景技术
草甘膦（glyphosate），是由美国孟山都公司开发的除草剂。又称：镇草宁、农达（Roundup）、草干膦、膦甘酸，分子式C3H8NO5P,分子量169.08,外观为白色固体,不溶于有机溶剂,属芽后内吸非选择性高效广谱灭生性除草剂,通过溶解杂草的叶直径表面蜡质层,药效迅速进入植物传导系统产生作用,使杂草枯竭死亡,具有广谱、低毒、无残留、内吸传导和优良的灭生性等特点,对植物无选择性,一般所有绿色植物,无论是作物还是杂草,着药后即被杀伤。草甘膦一直是全球产量最大的农药原药除草剂品种,也是世界第一大转基因作物耐受除草剂。目前国内使用的草甘膦助剂主要包括：牛脂胺聚氧乙烯醚、烷基糖苷、甜菜碱等化合物。
草铵膦 (Glufosinate ammonium)属有机磷类除草剂，是谷氨酰胺合成抑制剂，非选择性触杀型除草剂，也是世界第二大转基因作物耐受除草剂。它的作用比草甘膦迅速，具有杀草谱广、在土壤中降解快、毒性低、对环境友好等优点，是继草甘膦之后又一个性能优良的灭生性除草剂品种，目前国内仅登记用于果园、非耕地杂草的防除。随着国内外对百草枯的禁用，草铵膦作为触杀型除草剂的代表，市场份额必将越来越大。目前国内外比较认可的草铵膦水剂助剂主要包括AES、烷基糖苷、烷基聚醚等化合物。
目前草甘膦和草铵膦这两周除草剂在单独使用时都有一些缺陷，草甘膦杀根，但是速效性差，对于抗性杂草，如小飞蓬、狗牙根、牛筋草等防效差；草铵膦则是速效性好但部分杂草容易返青。如何将两者的特点结合在一起成为研发人员头疼的问题，经过研究我们发现这个问题主要落在助剂开发上面。
发明内容
本发明的目的旨在开发提供一种草铵膦复配草甘膦的水剂助剂,本发明开发的草铵膦复配草甘膦的水剂助剂为N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠, 其结构如下：
。
本发明的N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠的制备方法如下：
步骤一、使用N-氨乙基-3-氨丙基甲基二甲氧基硅烷与琥珀酸按照物质的量比为1:1~1.2，常压并在80~100℃条件下反应，反应时间1~3h，得到N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰；
所述N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰分子式为：CH3Si(OCH3)2CH2CH2CH2NHCH2CH2CH2NHOCCH=CHCOOH;
步骤二、将步骤一所得N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰与亚硫酸钠按物质的量之比1∶1~1.2在80~100℃的水中混合进行反应，反应时间3~5h，得分子式如下的N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠：
。
从上述描述可知，本发明的有益效果在于：本发明的草铵膦复配草甘膦的水剂助剂经过N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠由于具有含N、Si、磺酸盐、羧酸盐等结构，同时满足了含N化合物对草甘膦增效、含Si化合物渗透好和磺酸盐、羧酸盐对草铵膦的增效等条件，对于草甘膦复配草铵膦体系具有很好的增效作用。
具体实施方式
以下通过具体实施例进一步说明本发明。
实施例1
本发明N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠的制备方法，包括如下步骤：
步骤1、使用N-氨乙基-3-氨丙基甲基二甲氧基硅烷与琥珀酸按照物质的量比为1:1~1.2，常压并在80~100℃条件下反应，反应时间1~3h，得到N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰；
所述N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰分子式为：CH3Si(OCH3)2CH2CH2CH2NHCH2CH2CH2NHOCCH=CHCOOH;
步骤2、将步骤1所得N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰与亚硫酸钠按物质的量之比1∶1~1.2在80~100℃的水中混合进行反应，反应时间3~5h，得分子式如下的N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠：
。
上述将所得水剂助剂N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠, 应用于配制10%草铵膦复配41%草甘膦异丙胺盐水剂，配制过程为：10%草铵膦原药、41%草甘膦异丙胺盐，20%N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠，0.3%消泡剂，余量用水补足至100%，搅拌均匀后得到10%草铵膦复配41%草甘膦异丙胺盐水剂成品。
将上述制剂与农达和保试达进行药效对比试验, 验证效果:
其中1号为农达（41%草甘膦异丙胺盐水剂）、2号为保试达（200g/L草铵膦水剂）、3分别对应助剂为本发明N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠配制的10%草铵膦复配41%草甘膦异丙胺盐水剂，具体除草效果见表1~3（表中a、b、c代表药效评价级别，其中效果从优到劣依次为：a、ab、b、bc、c）。
从上述表中可以看出使用本发明产品配制的10%草铵膦复配41%草甘膦异丙胺盐水剂具有自己独特的优势，对比7天速效性和保试达差不多，在牛筋草、小飞蓬和狗牙根上明显好于农达，对比30天持效性上则表现出全体最优，所以本发明的助剂很适合草铵膦复配草甘膦的体系, 本发明的助剂既能够发挥草铵膦速效性，又能对草甘膦的内吸传导起到很好作用。
Claims (3)
1.一种草铵膦复配草甘膦的水剂助剂, 其特性在于, 所述的水剂助剂为N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠, 其结构如下：
。
2.根据权利要求1所述的草铵膦复配草甘膦的水剂助剂的制备方法, 其特性在于, 所述的水剂助剂N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠的制备方法如下：
步骤一、使用N-氨乙基-3-氨丙基甲基二甲氧基硅烷与琥珀酸按照物质的量比为1:1~1.2，常压并在80~100℃条件下反应，反应时间1~3h，得到N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰；
所述N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰分子式为：CH3Si(OCH3)2CH2CH2CH2NHCH2CH2CH2NHOCCH=CHCOOH;
步骤二、将步骤一所得N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰与亚硫酸钠按物质的量之比1∶1~1.2在80~100℃的水中混合进行反应，反应时间3~5h，得分子式如下的N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠：
。
3.根据权利要求1所述的草铵膦复配草甘膦的水剂助剂的应用, 其特性在于, 所述的所述的草铵膦复配草甘膦的水剂助剂应用于配制10%草铵膦复配41%草甘膦异丙胺盐水剂，配制过程为：10%草铵膦原药、41%草甘膦异丙胺盐，20%N-氨乙基-3-氨丙基甲基二甲氧基硅烷琥珀酸单酰磺酸二钠，0.3%消泡剂，余量用水补足至100%，搅拌均匀后得到10%草铵膦复配41%草甘膦异丙胺盐水剂成品。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101773143A (zh) * | 2010-02-18 | 2010-07-14 | 浙江新安化工集团股份有限公司 | 草甘膦和草铵膦的复配除草剂 |
| CN103168798A (zh) * | 2012-10-30 | 2013-06-26 | 肇庆市真格生物科技有限公司 | 一种除草剂组合物及其制备方法 |
| CN105394080A (zh) * | 2015-12-24 | 2016-03-16 | 安徽美兰农业发展股份有限公司 | 一种草甘膦异丙胺盐和草铵膦复配水剂及其制备方法 |
| CN105707071A (zh) * | 2016-01-21 | 2016-06-29 | 威尔（福建）生物有限公司 | 一种农药制剂润湿剂及其制备方法和在农药制剂中的应用 |
-
2016
- 2016-08-09 CN CN201610644911.7A patent/CN106279243A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101773143A (zh) * | 2010-02-18 | 2010-07-14 | 浙江新安化工集团股份有限公司 | 草甘膦和草铵膦的复配除草剂 |
| CN103168798A (zh) * | 2012-10-30 | 2013-06-26 | 肇庆市真格生物科技有限公司 | 一种除草剂组合物及其制备方法 |
| CN105394080A (zh) * | 2015-12-24 | 2016-03-16 | 安徽美兰农业发展股份有限公司 | 一种草甘膦异丙胺盐和草铵膦复配水剂及其制备方法 |
| CN105707071A (zh) * | 2016-01-21 | 2016-06-29 | 威尔（福建）生物有限公司 | 一种农药制剂润湿剂及其制备方法和在农药制剂中的应用 |
Non-Patent Citations (8)
| Title |
|---|
| 倪素美: "480g/L毒死蜱水乳剂的配方研究", 《世界农药》 * |
| 刘程等: "《表面活性剂性质理论与应用》", 30 June 2003, 北京工业大学出版社 * |
| 张跃军等: "磺基琥珀酸酯盐类表面活性剂的研究进展", 《江苏化工》 * |
| 戴宝江等: "GSS462的性能及应用研究", 《南通职业大学学报》 * |
| 胡啸林等: "聚硅氧烷基琥珀酸酰胺磺酸钠的研制与应用", 《丝绸》 * |
| 范鸿华等: "200g/L草铵膦水剂对柑橘园杂草的防效", 《现代农业科技》 * |
| 范鸿华等: "41%草甘膦异丙胺盐水剂防除柑橘园杂草药效研究", 《现代农业科技》 * |
| 许澎等: "有机硅聚氧乙烯醚琥珀酸单酯二钠盐的合成与性能", 《有机硅材料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12144351B2 (en) | 2017-08-09 | 2024-11-19 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in corn cultures |
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