CN106247614A - A kind of solid, gas multi-fuel water stove - Google Patents
A kind of solid, gas multi-fuel water stove Download PDFInfo
- Publication number
- CN106247614A CN106247614A CN201610651390.8A CN201610651390A CN106247614A CN 106247614 A CN106247614 A CN 106247614A CN 201610651390 A CN201610651390 A CN 201610651390A CN 106247614 A CN106247614 A CN 106247614A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000000446 fuel Substances 0.000 title claims abstract description 25
- 239000007787 solid Substances 0.000 title claims abstract description 25
- 239000002893 slag Substances 0.000 claims abstract description 8
- 239000011521 glass Substances 0.000 claims description 63
- 239000007789 gas Substances 0.000 claims description 52
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 46
- 239000000975 dye Substances 0.000 claims description 42
- 239000002245 particle Substances 0.000 claims description 33
- 238000002360 preparation method Methods 0.000 claims description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 24
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 23
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 21
- 230000009466 transformation Effects 0.000 claims description 21
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- 230000008878 coupling Effects 0.000 claims description 13
- 238000010168 coupling process Methods 0.000 claims description 13
- 238000005859 coupling reaction Methods 0.000 claims description 13
- 230000003287 optical effect Effects 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000003292 glue Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 12
- 239000005357 flat glass Substances 0.000 claims description 7
- 238000003306 harvesting Methods 0.000 claims description 7
- 239000010410 layer Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 6
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 238000002513 implantation Methods 0.000 claims description 6
- 239000011229 interlayer Substances 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 6
- 239000006210 lotion Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000007711 solidification Methods 0.000 claims description 6
- 230000008023 solidification Effects 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
- 239000012498 ultrapure water Substances 0.000 claims description 6
- 230000007423 decrease Effects 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 230000005622 photoelectricity Effects 0.000 claims 1
- 239000010453 quartz Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000005540 biological transmission Effects 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000005284 excitation Effects 0.000 description 5
- 239000007850 fluorescent dye Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000005693 optoelectronics Effects 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 210000004127 vitreous body Anatomy 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/22—Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating
- F24H1/44—Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating with combinations of two or more of the types covered by groups F24H1/24 - F24H1/40 , e.g. boilers having a combination of features covered by F24H1/24 - F24H1/40
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C4/00—Flame traps allowing passage of gas but not of flame or explosion wave
- A62C4/02—Flame traps allowing passage of gas but not of flame or explosion wave in gas-pipes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H9/00—Details
- F24H9/20—Arrangement or mounting of control or safety devices
- F24H9/2007—Arrangement or mounting of control or safety devices for water heaters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1876—Particular processes or apparatus for batch treatment of the devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- Public Health (AREA)
- Photovoltaic Devices (AREA)
Abstract
The application relates to a kind of solid, gas multi-fuel water stove, including body of heater；Flue, gas burner and slag notch it is provided with in described body of heater；The top of described body of heater and bottom are respectively arranged with water inlet and outlet；One end of described gas burner is placed in furnace interior, and the other end of gas burner extends horizontally to outside body of heater along the length direction of body of heater, and the free end connection of this end has a spark arrester, and the other end of described spark arrester connects low pressure automatic-closing valve.
Description
Technical field
The application relates to tire pressure detection field, particularly relates to a kind of solid, gas multi-fuel water stove.
Background technology
There is techniques below problem in the heating furnace used in correlation technique, need burning when in use due to heating furnace
Gas produces heat, and in combustion process, and the potential danger such as the too high easy initiation fire of temperature.
Summary of the invention
For overcoming problem present in correlation technique, the application provides a kind of solid, gas multi-fuel water stove.
The application is achieved through the following technical solutions:
Embodiments herein relates to a kind of solid, gas multi-fuel water stove, including body of heater；Arrange in described body of heater
There are flue, gas burner and slag notch；The top of described body of heater and bottom are respectively arranged with water inlet and outlet；Described gas
One end of body burner is placed in furnace interior, and the other end of gas burner extends horizontally to outside body of heater along the length direction of body of heater
Portion, and the free end of this end connects and has a spark arrester, the other end of described spark arrester connects low pressure automatic-closing valve.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
Accompanying drawing herein is merged in description and constitutes the part of this specification, it is shown that meet the enforcement of the present invention
Example, and for explaining the principle of the present invention together with description.
Fig. 1 is the structural representation of the present invention.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention.
Fig. 3 is the fluorescence concentrated solar energy photovoltaic cell structure schematic top plan view of the present invention.
Fig. 4 is the preparation technology flow chart of the fluorescence collection solar-energy photo-voltaic cell of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Following disclosure provides many different embodiments or example for realizing the different structure of the application.For letter
Changing disclosure herein, hereinafter parts and setting to specific examples are described.Certainly, they are the most merely illustrative, and
It is not intended to limit the application.Additionally, the application can in different examples repeat reference numerals and/or letter.This heavy
It is for purposes of simplicity and clarity again, itself is more than the relation between various embodiment being discussed and/or arranging.This
Outward, the various specific technique that this application provides and the example of material, but those of ordinary skill in the art it can be appreciated that
The applicability of other techniques and/or the use of other materials.It addition, fisrt feature described below Second Eigenvalue " on "
Structure can include that the first and second features are formed as the embodiment directly contacted, it is also possible to include that other feature is formed at
Embodiment between first and second features, such first and second features are not likely to be directly contact.
In the description of the present application, it should be noted that unless otherwise prescribed and limit, term " is installed ", " being connected ",
" connect " and should be interpreted broadly, for example, it may be mechanically connected or electrical connection, it is also possible to be the connection of two element internals, can
Being to be joined directly together, it is also possible to be indirectly connected to by intermediary, for the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term.
Fluorescence concentrated solar energy photovoltaic device is by fluorescent material, transparent optical waveguide medium and solaode three part group
Become.Fluorescent material it is dispersed in flat board transparent medium (such as plate glass) or is coated on transparent medium surface, in side
Coupled solar battery, can form LSC (fluorescence concentrated solar energy photovoltaic device, luminescent solar
concentrator).Fluorescent material re-emits fluorescence after absorbing incident sunlight, escapes less than the fluorescence of the cirtical angle of total reflection
Go out transparent medium, form an escape light cone；Then can produce total reflection more than the fluorescence of critical angle, be constrained on transparent medium
In, arrive the solaode of side through multiple total reflection, to realize gathering large-area sunlight the little area sun
Purpose on energy battery.
The problem that presently, there are: the loss that the fiber waveguide medium that LSC device exists causes so that the opto-electronic conversion effect of LSC
Rate does not has relatively quantum jump.When the fluorescence that fluorescent material is launched runs into dust, bubble etc. during fiber waveguide medium transmission, due to
Defect refractive index is different from fiber waveguide medium, produces scattering of light, and a part of light escapes out fiber waveguide medium.
For overcoming problem present in correlation technique, the application provides a kind of solid, gas multi-fuel water stove.
The following examples describe the implementation of the present invention in detail.
Application scenarios 1:
Fig. 1 is the structural representation of the present invention, and a kind of solid as shown in Figure 1, gas multi-fuel water stove, including stove
Body 10；Flue 23, gas burner 34 and slag notch 12 it is provided with in described body of heater 10；Top and the bottom of described body of heater 10 are divided
It is not provided with water inlet 21 and outlet 22；It is internal that one end of described gas burner 34 is placed in body of heater 10, gas burner 34
The other end to extend horizontally to body of heater 10 along the length direction of body of heater 10 outside, and the free end of this end connects and has a spark arrester
33, the other end of described spark arrester 33 connects low pressure automatic-closing valve 32.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Preferably, the side of described spark arrester 33 connects a supply unit 35.
Preferably, the outside of described supply unit 35 is provided with fluorescence concentrated solar energy photovoltaic cell.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention；Fig. 3 is the fluorescence collection of the present invention
Light solar-energy photo-voltaic cell structure schematic top plan view.The folder of described fluorescence concentrated solar energy photovoltaic cell as shown in Figures 2 and 3
Rotating fields is that two-layer quartz glass 1 constitutes housing, and centre is marked with fluorescent solutions 3；Microcavity knot it is provided with inside described quartz glass
Structure 2, described interlayer both sides are coupled with reflecting mirror 5, and another both sides are pasted with the commodity monocrystaline silicon solar cell 6 of efficiency 17%；Institute
State the nano-Ag particles 4 being added with concentration 23～40ppm in fluorescent solutions 3.
Preferably, Fig. 4 is the preparation technology flow chart of fluorescence collection solar-energy photo-voltaic cell of the present invention.As shown in Figure 4, institute
The preparation process stating fluorescence concentrated solar energy photovoltaic cell is as follows:
S1, the hydrophobization of quartz glass (1) process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then warp
2%HF soaks 2 hours, and 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Its
In, the size of quartz glass is 5cm × 2cm × 1cm；
S2,100mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and be the air of 1 ± 0.1MPa in negative pressure
In pressure, obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is revolved
Turn and be coated on quartz glass plate, after drying in drying baker, obtain ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as
Continuous half cavity-like of middle part epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass
The length of 0.5～1cm is respectively left at glass two ends；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions (3): take indole dicarbocyanine dyes and Red305 that mass ratio is 3:1 so that it is the most mixed
Close, indole dicarbocyanine dyes and Red 305 are mixed, then with the concentration of 0.5%wt indole two carbon cyanines by molten for mixture dyestuff
In hexamethylene, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles (4) and make it
Concentration reaches 23～40ppm, the most ultrasonic 10min, and wherein nano-Ag particles particle diameter is 50nm；；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: the glass edge side processed through step S3 is placed a piece of
Thickness is the microscope slide of 0.5mm, makes to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived,
Utilize syringe the microcavity of glass will to be made to be completely filled with dyestuff be between the dye solution implantation glass that step (4) have configured
Only, then take out microscope slide, re-use solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, so
After remaining dual-side coupled mirrors (5), reflecting mirror reflective are faced outwardly, finally use ultra-violet curing glue in sandwich two
The commodity monocrystaline silicon solar cell (6) of four side sticking efficiencies 17%, by circuit board extraction electrode, completes the fluorescence light harvesting sun
The preparation of energy photovoltaic cell.
Preferably, dyestuff Red305 is 360nm with the excitation wavelength of the mixing fluorescent dye of indole dicarbocyanine dyes.In order to
Compare, made the glass fluorescence concentrated solar energy device not having microcavity；Result is as shown in table 1, finds after tested, the most micro-
The device side in chamber is collected fluorescence intensity and is increased with the distance of light source and reduce, and its loss factor is 0.039cm-1, has microcavity
Device loss coefficient be 0.010cm-1.There is the fluorescence intensity of microcavity more than the device without microcavity, and the decay speed of fluorescence intensity
Rate is slower.(it is uniformly dispersed mainly due to the fluorescence centre having microcavity, and the total reflection effect of microcavity is strong, and be placed on full
Prepare device on the work top of nitrogen, effectively avoid the impact of dust, bubble and other environmental factorss, therefore, preparation
The photovoltaic device fluorescence loss gone out is little, and fluorescence efficiency of transmission is high.)
Table 1 has microcavity and without micro chamber device side detection fluorescence intensity and light source distance changing value
Using solar simulator light source, peak power output Pmax of solaode is: Pmax=Voc × Isc ×
FF, wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC system effectiveness η panel is: η panel=
Pmax (LSC)/(ApanelPin), wherein, Apanel and Pin is respectively area and the incident optical power density (100mW/ of LSC
cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=Pmax (coupling battery)/Pmax (institute's electricity consumption
Pond), wherein, Pmax (coupling battery) is the peak power output being coupled in LSC battery, and Pmax (battery used) is the electricity used
Pond peak power output under standard light source, power gain G represents that battery is coupled in the ratio of the output before and after LSC.
Test finds, when nanometer silver concentration is 35ppm, has the photoelectric transformation efficiency of microcavity to reach 9.15%, without microcavity
Photoelectric transformation efficiency be 4.05%.
By test, by the synergism of microcavity Yu nanometer silver, the efficiency utilizing solar energy is higher, photoelectric transformation efficiency
Height, and make simple, maintenance cost is low, and capacity of resisting disturbance is strong, can provide enough power supply for spark arrester, prevent in power-off
Time body of heater burning produce danger, therefore the present invention possesses certain application prospect.
Application scenarios 2:
Fig. 1 is the structural representation of the present invention, and a kind of solid as shown in Figure 1, gas multi-fuel water stove, including stove
Body 10；Flue 23, gas burner 34 and slag notch 12 it is provided with in described body of heater 10；Top and the bottom of described body of heater 10 are divided
It is not provided with water inlet 21 and outlet 22；It is internal that one end of described gas burner 34 is placed in body of heater 10, gas burner 34
The other end to extend horizontally to body of heater 10 along the length direction of body of heater 10 outside, and the free end of this end connects and has a spark arrester
33, the other end of described spark arrester 33 connects low pressure automatic-closing valve 32.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Preferably, the side of described spark arrester 33 connects a supply unit 35.
Preferably, the outside of described supply unit 35 is provided with fluorescence concentrated solar energy photovoltaic cell.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention；Fig. 3 is the fluorescence collection of the present invention
Light solar-energy photo-voltaic cell structure schematic top plan view.The folder of described fluorescence concentrated solar energy photovoltaic cell as shown in Figures 2 and 3
Rotating fields is that two-layer quartz glass 1 constitutes housing, and centre is marked with fluorescent solutions 3；Microcavity knot it is provided with inside described quartz glass
Structure 2, described interlayer both sides are coupled with reflecting mirror 5, and another both sides are pasted with the commodity monocrystaline silicon solar cell 6 of efficiency 17%；Institute
State the nano-Ag particles 4 being added with concentration 23～40ppm in fluorescent solutions 3.
Preferably, Fig. 4 is the preparation technology flow chart of fluorescence collection solar-energy photo-voltaic cell of the present invention.As shown in Figure 4, institute
The preparation process stating fluorescence concentrated solar energy photovoltaic cell is as follows:
S1, the hydrophobization of quartz glass (1) process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then warp
2%HF soaks 2 hours, and 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Its
In, the size of quartz glass is 5cm × 2cm × 1cm；
S2,80mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and be the air of 1 ± 0.1MPa in negative pressure
In pressure, obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is revolved
Turn and be coated on quartz glass plate, after drying in drying baker, obtain ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as
Continuous half cavity-like of middle part epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass
The length of 0.5～1cm is respectively left at glass two ends；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions (3): take indole dicarbocyanine dyes and Red305 that mass ratio is 3:1 so that it is the most mixed
Close, indole dicarbocyanine dyes and Red 305 are mixed, then with the concentration of 0.5%wt indole two carbon cyanines by molten for mixture dyestuff
In hexamethylene, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles (4) and make it
Concentration reaches 23～40ppm, the most ultrasonic 10min, and wherein nano-Ag particles particle diameter is 40nm；；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: the glass edge side processed through step S3 is placed a piece of
Thickness is the microscope slide of 0.5mm, makes to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived,
Utilize syringe the microcavity of glass will to be made to be completely filled with dyestuff be between the dye solution implantation glass that step (4) have configured
Only, then take out microscope slide, re-use solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, so
After remaining dual-side coupled mirrors (5), reflecting mirror reflective are faced outwardly, finally use ultra-violet curing glue in sandwich two
The commodity monocrystaline silicon solar cell (6) of four side sticking efficiencies 17%, by circuit board extraction electrode, completes the fluorescence light harvesting sun
The preparation of energy photovoltaic cell.
Preferably, dyestuff Red305 is 360nm with the excitation wavelength of the mixing fluorescent dye of indole dicarbocyanine dyes.In order to
Compare, made the glass fluorescence concentrated solar energy device not having microcavity；Result is as shown in table 1, finds after tested, the most micro-
The device side in chamber is collected fluorescence intensity and is increased with the distance of light source and reduce, and its loss factor is 0.039cm-1, has microcavity
Device loss coefficient be 0.010cm-1.There is the fluorescence intensity of microcavity more than the device without microcavity, and the decay speed of fluorescence intensity
Rate is slower.(it is uniformly dispersed mainly due to the fluorescence centre having microcavity, and the total reflection effect of microcavity is strong, and be placed on full
Prepare device on the work top of nitrogen, effectively avoid the impact of dust, bubble and other environmental factorss, therefore, preparation
The photovoltaic device fluorescence loss gone out is little, and fluorescence efficiency of transmission is high.)
Table 1 has microcavity and without micro chamber device side detection fluorescence intensity and light source distance changing value
Using solar simulator light source, peak power output Pmax of solaode is: Pmax=Voc × Isc ×
FF, wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC system effectiveness η panel is: η panel=
Pmax (LSC)/(ApanelPin), wherein, Apanel and Pin is respectively area and the incident optical power density (100mW/ of LSC
cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=Pmax (coupling battery)/Pmax (institute's electricity consumption
Pond), wherein, Pmax (coupling battery) is the peak power output being coupled in LSC battery, and Pmax (battery used) is the electricity used
Pond peak power output under standard light source, power gain G represents that battery is coupled in the ratio of the output before and after LSC.
Test finds, when nanometer silver concentration is 32ppm, has the photoelectric transformation efficiency of microcavity to reach 8.97%, without microcavity
Photoelectric transformation efficiency be 3.89%.
By test, by the synergism of microcavity Yu nanometer silver, the efficiency utilizing solar energy is higher, photoelectric transformation efficiency
Height, and make simple, maintenance cost is low, and capacity of resisting disturbance is strong, can provide enough power supply for spark arrester, prevent in power-off
Time body of heater burning produce danger, therefore the present invention possesses certain application prospect.
Application scenarios 3:
Fig. 1 is the structural representation of the present invention, and a kind of solid as shown in Figure 1, gas multi-fuel water stove, including stove
Body 10；Flue 23, gas burner 34 and slag notch 12 it is provided with in described body of heater 10；Top and the bottom of described body of heater 10 are divided
It is not provided with water inlet 21 and outlet 22；It is internal that one end of described gas burner 34 is placed in body of heater 10, gas burner 34
The other end to extend horizontally to body of heater 10 along the length direction of body of heater 10 outside, and the free end of this end connects and has a spark arrester
33, the other end of described spark arrester 33 connects low pressure automatic-closing valve 32.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Preferably, the side of described spark arrester 33 connects a supply unit 35.
Preferably, the outside of described supply unit 35 is provided with fluorescence concentrated solar energy photovoltaic cell.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention；Fig. 3 is the fluorescence collection of the present invention
Light solar-energy photo-voltaic cell structure schematic top plan view.The folder of described fluorescence concentrated solar energy photovoltaic cell as shown in Figures 2 and 3
Rotating fields is that two-layer quartz glass 1 constitutes housing, and centre is marked with fluorescent solutions 3；Microcavity knot it is provided with inside described quartz glass
Structure 2, described interlayer both sides are coupled with reflecting mirror 5, and another both sides are pasted with the commodity monocrystaline silicon solar cell 6 of efficiency 17%；Institute
State the nano-Ag particles 4 being added with concentration 23～40ppm in fluorescent solutions 3.
Preferably, Fig. 4 is the preparation technology flow chart of fluorescence collection solar-energy photo-voltaic cell of the present invention.As shown in Figure 4, institute
The preparation process stating fluorescence concentrated solar energy photovoltaic cell is as follows:
S1, the hydrophobization of quartz glass (1) process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then warp
2%HF soaks 2 hours, and 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Its
In, the size of quartz glass is 5cm × 2cm × 1cm；
S2,90mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and be the air of 1 ± 0.1MPa in negative pressure
In pressure, obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is revolved
Turn and be coated on quartz glass plate, after drying in drying baker, obtain ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as
Continuous half cavity-like of middle part epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass
The length of 0.5～1cm is respectively left at glass two ends；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions (3): take indole dicarbocyanine dyes and Red305 that mass ratio is 3:1 so that it is the most mixed
Close, indole dicarbocyanine dyes and Red 305 are mixed, then with the concentration of 0.5%wt indole two carbon cyanines by molten for mixture dyestuff
In hexamethylene, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles (4) and make it
Concentration reaches 23～40ppm, the most ultrasonic 10min, and wherein nano-Ag particles particle diameter is 60nm；；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: the glass edge side processed through step S3 is placed a piece of
Thickness is the microscope slide of 0.5mm, makes to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived,
Utilize syringe the microcavity of glass will to be made to be completely filled with dyestuff be between the dye solution implantation glass that step (4) have configured
Only, then take out microscope slide, re-use solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, so
After remaining dual-side coupled mirrors (5), reflecting mirror reflective are faced outwardly, finally use ultra-violet curing glue in sandwich two
The commodity monocrystaline silicon solar cell (6) of four side sticking efficiencies 17%, by circuit board extraction electrode, completes the fluorescence light harvesting sun
The preparation of energy photovoltaic cell.
Preferably, dyestuff Red305 is 360nm with the excitation wavelength of the mixing fluorescent dye of indole dicarbocyanine dyes.In order to
Compare, made the glass fluorescence concentrated solar energy device not having microcavity；Result is as shown in table 1, finds after tested, the most micro-
The device side in chamber is collected fluorescence intensity and is increased with the distance of light source and reduce, and its loss factor is 0.039cm-1, has microcavity
Device loss coefficient be 0.010cm-1.There is the fluorescence intensity of microcavity more than the device without microcavity, and the decay speed of fluorescence intensity
Rate is slower.(it is uniformly dispersed mainly due to the fluorescence centre having microcavity, and the total reflection effect of microcavity is strong, and be placed on full
Prepare device on the work top of nitrogen, effectively avoid the impact of dust, bubble and other environmental factorss, therefore, preparation
The photovoltaic device fluorescence loss gone out is little, and fluorescence efficiency of transmission is high.)
Table 1 has microcavity and without micro chamber device side detection fluorescence intensity and light source distance changing value
Using solar simulator light source, peak power output Pmax of solaode is: Pmax=Voc × Isc ×
FF, wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC system effectiveness η panel is: η panel=
Pmax (LSC)/(ApanelPin), wherein, Apanel and Pin is respectively area and the incident optical power density (100mW/ of LSC
cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=Pmax (coupling battery)/Pmax (institute's electricity consumption
Pond), wherein, Pmax (coupling battery) is the peak power output being coupled in LSC battery, and Pmax (battery used) is the electricity used
Pond peak power output under standard light source, power gain G represents that battery is coupled in the ratio of the output before and after LSC.
Test finds, when nanometer silver concentration is 29ppm, has the photoelectric transformation efficiency of microcavity to reach 8.75%, without microcavity
Photoelectric transformation efficiency be 3.68%.
By test, by the synergism of microcavity Yu nanometer silver, the efficiency utilizing solar energy is higher, photoelectric transformation efficiency
Height, and make simple, maintenance cost is low, and capacity of resisting disturbance is strong, can provide enough power supply for spark arrester, prevent in power-off
Time body of heater burning produce danger, therefore the present invention possesses certain application prospect.
Application scenarios 4:
Fig. 1 is the structural representation of the present invention, and a kind of solid as shown in Figure 1, gas multi-fuel water stove, including stove
Body 10；Flue 23, gas burner 34 and slag notch 12 it is provided with in described body of heater 10；Top and the bottom of described body of heater 10 are divided
It is not provided with water inlet 21 and outlet 22；It is internal that one end of described gas burner 34 is placed in body of heater 10, gas burner 34
The other end to extend horizontally to body of heater 10 along the length direction of body of heater 10 outside, and the free end of this end connects and has a spark arrester
33, the other end of described spark arrester 33 connects low pressure automatic-closing valve 32.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Preferably, the side of described spark arrester 33 connects a supply unit 35.
Preferably, the outside of described supply unit 35 is provided with fluorescence concentrated solar energy photovoltaic cell.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention；Fig. 3 is the fluorescence collection of the present invention
Light solar-energy photo-voltaic cell structure schematic top plan view.The folder of described fluorescence concentrated solar energy photovoltaic cell as shown in Figures 2 and 3
Rotating fields is that two-layer quartz glass 1 constitutes housing, and centre is marked with fluorescent solutions 3；Microcavity knot it is provided with inside described quartz glass
Structure 2, described interlayer both sides are coupled with reflecting mirror 5, and another both sides are pasted with the commodity monocrystaline silicon solar cell 6 of efficiency 17%；Institute
State the nano-Ag particles 4 being added with concentration 23～40ppm in fluorescent solutions 3.
Preferably, Fig. 4 is the preparation technology flow chart of fluorescence collection solar-energy photo-voltaic cell of the present invention.As shown in Figure 4, institute
The preparation process stating fluorescence concentrated solar energy photovoltaic cell is as follows:
S1, the hydrophobization of quartz glass (1) process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then warp
2%HF soaks 2 hours, and 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Its
In, the size of quartz glass is 5cm × 2cm × 1cm；
S2,120mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and be the air of 1 ± 0.1MPa in negative pressure
In pressure, obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is revolved
Turn and be coated on quartz glass plate, after drying in drying baker, obtain ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as
Continuous half cavity-like of middle part epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass
The length of 0.5～1cm is respectively left at glass two ends；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions (3): take indole dicarbocyanine dyes and Red305 that mass ratio is 3:1 so that it is the most mixed
Close, indole dicarbocyanine dyes and Red 305 are mixed, then with the concentration of 0.5%wt indole two carbon cyanines by molten for mixture dyestuff
In hexamethylene, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles (4) and make it
Concentration reaches 23～40ppm, the most ultrasonic 10min, and wherein nano-Ag particles particle diameter is 70nm；；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: the glass edge side processed through step S3 is placed a piece of
Thickness is the microscope slide of 0.5mm, makes to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived,
Utilize syringe the microcavity of glass will to be made to be completely filled with dyestuff be between the dye solution implantation glass that step (4) have configured
Only, then take out microscope slide, re-use solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, so
After remaining dual-side coupled mirrors (5), reflecting mirror reflective are faced outwardly, finally use ultra-violet curing glue in sandwich two
The commodity monocrystaline silicon solar cell (6) of four side sticking efficiencies 17%, by circuit board extraction electrode, completes the fluorescence light harvesting sun
The preparation of energy photovoltaic cell.
Preferably, dyestuff Red305 is 360nm with the excitation wavelength of the mixing fluorescent dye of indole dicarbocyanine dyes.In order to
Compare, made the glass fluorescence concentrated solar energy device not having microcavity；Result is as shown in table 1, finds after tested, the most micro-
The device side in chamber is collected fluorescence intensity and is increased with the distance of light source and reduce, and its loss factor is 0.039cm-1, has microcavity
Device loss coefficient be 0.010cm-1.There is the fluorescence intensity of microcavity more than the device without microcavity, and the decay speed of fluorescence intensity
Rate is slower.(it is uniformly dispersed mainly due to the fluorescence centre having microcavity, and the total reflection effect of microcavity is strong, and be placed on full
Prepare device on the work top of nitrogen, effectively avoid the impact of dust, bubble and other environmental factorss, therefore, preparation
The photovoltaic device fluorescence loss gone out is little, and fluorescence efficiency of transmission is high.)
Table 1 has microcavity and without micro chamber device side detection fluorescence intensity and light source distance changing value
Using solar simulator light source, peak power output Pmax of solaode is: Pmax=Voc × Isc ×
FF, wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC system effectiveness η panel is: η panel=
Pmax (LSC)/(ApanelPin), wherein, Apanel and Pin is respectively area and the incident optical power density (100mW/ of LSC
cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=Pmax (coupling battery)/Pmax (institute's electricity consumption
Pond), wherein, Pmax (coupling battery) is the peak power output being coupled in LSC battery, and Pmax (battery used) is the electricity used
Pond peak power output under standard light source, power gain G represents that battery is coupled in the ratio of the output before and after LSC.
Test finds, when nanometer silver concentration is 38ppm, has the photoelectric transformation efficiency of microcavity to reach 8.93%, without microcavity
Photoelectric transformation efficiency be 3.88%.
By test, the tire pressure alarm device of the present invention, by the synergism of microcavity with nanometer silver, utilizes solar energy
Efficiency is higher, and photoelectric transformation efficiency is high, and makes simple, and maintenance cost is low, and capacity of resisting disturbance is strong, before possessing certain application
Scape.
The photoelectric transformation efficiency having microcavity reaches 7.85%, and the photoelectric transformation efficiency without microcavity is 4.05%.
By test, by the synergism of microcavity Yu nanometer silver, the efficiency utilizing solar energy is higher, photoelectric transformation efficiency
Height, and make simple, maintenance cost is low, and capacity of resisting disturbance is strong, can provide enough power supply for spark arrester, prevent in power-off
Time body of heater burning produce danger, therefore the present invention possesses certain application prospect.
Application scenarios 5:
Fig. 1 is the structural representation of the present invention, and a kind of solid as shown in Figure 1, gas multi-fuel water stove, including stove
Body 10；Flue 23, gas burner 34 and slag notch 12 it is provided with in described body of heater 10；Top and the bottom of described body of heater 10 are divided
It is not provided with water inlet 21 and outlet 22；It is internal that one end of described gas burner 34 is placed in body of heater 10, gas burner 34
The other end to extend horizontally to body of heater 10 along the length direction of body of heater 10 outside, and the free end of this end connects and has a spark arrester
33, the other end of described spark arrester 33 connects low pressure automatic-closing valve 32.
A kind of solid of embodiments of the invention offer, gas multi-fuel water stove, internal structure is arranged rationally, and
The end of gas burner is provided with the spark arrester being automatically switched off, and solves the problems referred to above.
Preferably, the side of described spark arrester 33 connects a supply unit 35.
Preferably, the outside of described supply unit 35 is provided with fluorescence concentrated solar energy photovoltaic cell.
Fig. 2 is the fluorescence concentrated solar energy photovoltaic cell structure schematic cross-section of the present invention；Fig. 3 is the fluorescence collection of the present invention
Light solar-energy photo-voltaic cell structure schematic top plan view.The folder of described fluorescence concentrated solar energy photovoltaic cell as shown in Figures 2 and 3
Rotating fields is that two-layer quartz glass 1 constitutes housing, and centre is marked with fluorescent solutions 3；Microcavity knot it is provided with inside described quartz glass
Structure 2, described interlayer both sides are coupled with reflecting mirror 5, and another both sides are pasted with the commodity monocrystaline silicon solar cell 6 of efficiency 17%；Institute
State the nano-Ag particles 4 being added with concentration 23～40ppm in fluorescent solutions 3.
Preferably, Fig. 4 is the preparation technology flow chart of fluorescence collection solar-energy photo-voltaic cell of the present invention.As shown in Figure 4, institute
The preparation process stating fluorescence concentrated solar energy photovoltaic cell is as follows:
S1, the hydrophobization of quartz glass 1 process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then through 2%
HF soaks 2 hours, and 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Wherein, stone
The size of English glass is 5cm × 2cm × 1cm；
S2,140mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and be the air of 1 ± 0.1MPa in negative pressure
In pressure, obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is revolved
Turn and be coated on quartz glass plate, after drying in drying baker, obtain ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as
Continuous half cavity-like of middle part epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass
The length of 0.5～1cm is respectively left at glass two ends；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions 3: take indole dicarbocyanine dyes and Red 305 that mass ratio is 3:1 so that it is the most mixed
Close, indole dicarbocyanine dyes and Red 305 are mixed, then with the concentration of 0.5%wt indole two carbon cyanines by molten for mixture dyestuff
In hexamethylene, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles (4) and make it
Concentration reaches 23～40ppm, the most ultrasonic 10min, and wherein nano-Ag particles particle diameter is 80nm；；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: the glass edge side processed through step S3 is placed a piece of
Thickness is the microscope slide of 0.5mm, makes to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived,
Utilize syringe the microcavity of glass will to be made to be completely filled with dyestuff be between the dye solution implantation glass that step (4) have configured
Only, then take out microscope slide, re-use solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, so
After remaining dual-side coupled mirrors (5), reflecting mirror reflective are faced outwardly, finally use ultra-violet curing glue in sandwich two
The commodity monocrystaline silicon solar cell (6) of four side sticking efficiencies 17%, by circuit board extraction electrode, completes the fluorescence light harvesting sun
The preparation of energy photovoltaic cell.
Preferably, dyestuff Red305 is 360nm with the excitation wavelength of the mixing fluorescent dye of indole dicarbocyanine dyes.In order to
Compare, made the glass fluorescence concentrated solar energy device not having microcavity；Result is as shown in table 1, finds after tested, the most micro-
The device side in chamber is collected fluorescence intensity and is increased with the distance of light source and reduce, and its loss factor is 0.039cm-1, has microcavity
Device loss coefficient be 0.010cm-1.There is the fluorescence intensity of microcavity more than the device without microcavity, and the decay speed of fluorescence intensity
Rate is slower.(it is uniformly dispersed mainly due to the fluorescence centre having microcavity, and the total reflection effect of microcavity is strong, and be placed on full
Prepare device on the work top of nitrogen, effectively avoid the impact of dust, bubble and other environmental factorss, therefore, preparation
The photovoltaic device fluorescence loss gone out is little, and fluorescence efficiency of transmission is high.)
Table 1 has microcavity and without micro chamber device side detection fluorescence intensity and light source distance changing value
Using solar simulator light source, peak power output Pmax of solaode is: Pmax=Voc × Isc ×
FF, wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC system effectiveness η panel is: η panel=
Pmax (LSC)/(ApanelPin), wherein, Apanel and Pin is respectively area and the incident optical power density (100mW/ of LSC
cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=Pmax (coupling battery)/Pmax (institute's electricity consumption
Pond), wherein, Pmax (coupling battery) is the peak power output being coupled in LSC battery, and Pmax (battery used) is the electricity used
Pond peak power output under standard light source, power gain G represents that battery is coupled in the ratio of the output before and after LSC.
Test finds, when nanometer silver concentration is 40ppm, has the photoelectric transformation efficiency of microcavity to reach 8.58%, without microcavity
Photoelectric transformation efficiency be 3.53%.
By test, by the synergism of microcavity Yu nanometer silver, the efficiency utilizing solar energy is higher, photoelectric transformation efficiency
Height, and make simple, maintenance cost is low, and capacity of resisting disturbance is strong, can provide enough power supply for spark arrester, prevent in power-off
Time body of heater burning produce danger, therefore the present invention possesses certain application prospect.
The technical scheme that embodiments herein provides can include following beneficial effect:
1. the fluorescence collection solar photovoltaic device used in the present invention, micro-owing to being prepared in glass in preparation process
Cavity configuration, light is constantly totally reflected by microcavity surface, constrains light in the equatorial surface of microcavity and along microcavity maximum
Detouring at diameter, due to the effect of total reflection, it is the faintest to ooze out the light beyond microcavity spheroid, can well be constrained in by light
In microcavity, almost without any loss, can well use and store energy；Owing to microcavity is in full nitrogen in preparation process
In the work platforms of gas, and microcavity periphery also has vitreous body to be coated with, therefore in microcavity by inject fluorescent material launched glimmering
Light avoids the interference of dust, bubble and other environmental factorss in the transmitting procedure of ultra-white photovoltaic glass, subtracts to greatest extent
The light having lacked incidence scatters, and then avoids the situation that light is escaped.Enhance the opto-electronic conversion performance of photovoltaic device.
2. adding the nano-Ag particles of 23～40ppm in the fluorescent solutions of the present invention, this nano-Ag particles divides with dyestuff
Son mixing, due to nano-Ag particles surface phasmon coupling, suitable concentration, can be greatly increased dye molecule in addition
Fluorescent effect, thus strengthen the photoelectric transformation efficiency of this photovoltaic device；In terms of for the reflection of sunlight, the present invention is at fluorescence
The both sides of concentrated solar energy photovoltaic cell are coupled with reflecting mirror, and it can ensure that sunlight is fully accumulated in micro-cavity structure,
Further avoid the excessive phenomenon of sunlight, improve photoelectric transformation efficiency.
The most further described nanometer silver concentration produces synergism with described microcavity size, when microcavity diameters is 500 μm
Time, along with the increase of nanometer silver concentration, opto-electronic conversion performance first increases and then decreases, nanometer silver optium concentration is 35ppm.
4. very simple due to the preparation process of the present invention, therefore save substantial amounts of man power and material, have potential
The potential promoted the use on a large scale.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (8)
1. a solid, gas multi-fuel water stove, it is characterised in that include body of heater；Flue, gas it is provided with in described body of heater
Body burner and slag notch；The top of described body of heater and bottom are respectively arranged with water inlet and outlet；Described gas burner
One end be placed in furnace interior, the other end of gas burner extends horizontally to outside body of heater along the length direction of body of heater, and should
The free end of end connects a spark arrester, and the other end of described spark arrester connects low pressure automatic-closing valve.
A kind of solid, gas multi-fuel water stove the most according to claim 1, it is characterised in that described spark arrester
Side connects a supply unit.
A kind of solid, gas multi-fuel water stove the most according to claim 1, it is characterised in that described supply unit
Outside be provided with fluorescence concentrated solar energy photovoltaic cell.
A kind of solid, gas multi-fuel water stove the most according to claim 3, it is characterised in that described fluorescence light harvesting
The sandwich of solar-energy photo-voltaic cell is that two-layer quartz glass constitutes housing.
A kind of solid, gas multi-fuel water stove the most according to claim 4, it is characterised in that described two-layer quartz
The centre of glass is marked with fluorescent solutions；Being provided with micro-cavity structure inside described quartz glass, described interlayer both sides are coupled with reflection
Mirror, another both sides are pasted with the commodity monocrystaline silicon solar cell of efficiency 17%.
A kind of solid, gas multi-fuel water stove the most according to claim 5, it is characterised in that described fluorescent solutions
In be added with the nano-Ag particles of concentration 23～40ppm.
A kind of solid, gas multi-fuel water stove the most according to claim 4, it is characterised in that described fluorescence light harvesting
The preparation process of solar-energy photo-voltaic cell is as follows:
S1, the hydrophobization of quartz glass process: many pieces of quartz glass be immersed in chromic acid lotion overnight, then soak through 2%HF
Steeping 2 hours, 5%H2O2 soaks 1 hour, clean with ultrapure water after finally using second distillation water soaking；Wherein, quartz glass
The size of glass is 5cm × 2cm × 1cm；
S2,100mg PVC, 5.0mg ECCH and 10ml tetrahydrofuran solution are mixed, and in the atmospheric pressure that negative pressure is 1 ± 0.1MPa
Obtained solution A after 10min is put in leaching, is placed in THF atmosphere by the quartz glass processed through step (1), and solution A is rotated painting
It is overlying on quartz glass plate, after drying in drying baker, obtains ground floor light-sensitive surface；
Prepared by S3, the micro-cavity structure of glass: by process through step S2 glass water hydrogen flame machine heat under, be prepared as middle part
Continuous half cavity-like of epirelief and semicircular in shape forms continuous print micro-cavity structure, and the quantity of described microcavity is 50～100, glass two
End respectively leaves the length of 0.5～1cm；The half chamber glass made is put in the workbench of full nitrogen standby；
S4, the configuration of fluorescent solutions: take indole dicarbocyanine dyes and Red 305 that mass ratio is 3:1 so that it is be sufficiently mixed, will
Indole dicarbocyanine dyes and Red 305 mix, and then with the concentration of 0.5%wt indole two carbon cyanines, mixture dyestuff are dissolved in hexamethylene
In alkane, it is configured to 500ml solution, this solution is placed in water-bath 80 degrees Celsius, be subsequently added nano-Ag particles and make its concentration reach
23～40ppm, the most ultrasonic 10min, wherein nano-Ag particles particle diameter is 50nm；Nano-Ag particles；
S5, the preparation of fluorescence concentrated solar energy photovoltaic cell: a piece of thickness is placed in the glass edge side processed through step S3
For the microscope slide of 0.5mm, make to be formed between two sheet glass the gap of 0.5mm, then its excess-three side sealing of glass is lived, utilize
Syringe will be between the dye solution implantation glass that step (4) have configured, till making the microcavity of glass be completely filled with dyestuff, so
Rear taking-up microscope slide, re-uses solidification glue and microscope slide side sealing is lived, form fluorescence concentrated solar energy photovoltaic device, then by it
Remaining dual-side coupled mirrors, reflecting mirror reflective faces outwardly, and finally uses ultra-violet curing glue viscous in the other both sides of sandwich
The commodity monocrystaline silicon solar cell of patch efficiency 17%, by circuit board extraction electrode, completes fluorescence concentrated solar energy photovoltaic electric
The preparation in pond.
8. according to the arbitrary described fluorescence concentrated solar energy photovoltaic cell of claim 3～7, it is characterised in that for described glimmering
In the test process of light concentrated solar energy photovoltaic cell, use solar simulator light source, the maximum work output of solaode
Rate Pmax is: Pmax=Voc × Isc × FF, and wherein Voc is open-circuit voltage, and Isc is short circuit current, and FF is fill factor, curve factor；LSC
System effectiveness η panel is: η panel=Pmax (LSC)/(ApanelPin), and wherein, Apanel and Pin is respectively the face of LSC
Amass and incident optical power density (100mW/cm2).Additionally, also define power gain G to weigh the collection optical property of LSC: G=
Pmax (coupling battery)/Pmax (battery used), wherein, Pmax (coupling battery) is the maximum work output being coupled in LSC battery
Rate, Pmax (battery used) is the battery used peak power output under standard light source, and power gain G represents that battery couples
The ratio of the output before and after LSC；During a diameter of 500 μm of described micro-cavity structure, along with the increase of nanometer silver concentration, photoelectricity turns
Transsexual energy first increases and then decreases, when corresponding described nanometer silver concentration is 35ppm, photoelectric transformation efficiency reaches 9.15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610651390.8A CN106247614A (en) | 2016-08-10 | 2016-08-10 | A kind of solid, gas multi-fuel water stove |
Applications Claiming Priority (1)
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Citations (1)
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| CN102966978A (en) * | 2012-12-18 | 2013-03-13 | 刘盛林 | Solid and gas multi-fuel water stove |
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| CN102966978A (en) * | 2012-12-18 | 2013-03-13 | 刘盛林 | Solid and gas multi-fuel water stove |
Non-Patent Citations (4)
| Title |
|---|
| [比]JEF POORTMANS，[俄]VLADIRNIR ARKHIPOV: "《薄膜太阳能电池》", 31 August 2014 * |
| 张义: "荧光集光太阳能光伏器件制备工艺改进及新型器件结构研究", 《中国科学技术大学博士学位论文》 * |
| 焦晨旭等: "咔唑腙为荧光指示剂的亚硝酸根传感器", 《中北大学学报》 * |
| 葛羽屏等: "实施圆球微腔特性试验的优化方案探索", 《光散射学报》 * |
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