CN106223564A - A kind of fiber reinforcement high-impact ceramic tile - Google Patents
A kind of fiber reinforcement high-impact ceramic tile Download PDFInfo
- Publication number
- CN106223564A CN106223564A CN201610812973.4A CN201610812973A CN106223564A CN 106223564 A CN106223564 A CN 106223564A CN 201610812973 A CN201610812973 A CN 201610812973A CN 106223564 A CN106223564 A CN 106223564A
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- China
- Prior art keywords
- carbon fiber
- parts
- ceramic tile
- fibre reinforced
- impact
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- 239000000919 ceramic Substances 0.000 title claims abstract description 82
- 239000000835 fiber Substances 0.000 title claims abstract description 54
- 230000002787 reinforcement Effects 0.000 title description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 131
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 113
- 239000004917 carbon fiber Substances 0.000 claims abstract description 113
- 239000007789 gas Substances 0.000 claims abstract description 48
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 36
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 36
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 239000011159 matrix material Substances 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 14
- 238000001764 infiltration Methods 0.000 claims abstract description 13
- 230000008595 infiltration Effects 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052656 albite Inorganic materials 0.000 claims abstract description 12
- VKJLWXGJGDEGSO-UHFFFAOYSA-N barium(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Ba+2] VKJLWXGJGDEGSO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000151 deposition Methods 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 12
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 12
- 239000010434 nepheline Substances 0.000 claims abstract description 12
- 229910052903 pyrophyllite Inorganic materials 0.000 claims abstract description 12
- 239000010453 quartz Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010435 syenite Substances 0.000 claims abstract description 12
- 238000000053 physical method Methods 0.000 claims abstract description 6
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002737 fuel gas Substances 0.000 claims abstract description 5
- 229920001778 nylon Polymers 0.000 claims description 48
- 239000004677 Nylon Substances 0.000 claims description 23
- 238000005859 coupling reaction Methods 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 9
- 229920002292 Nylon 6 Polymers 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 7
- 238000010168 coupling process Methods 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003607 modifier Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 5
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 2
- 229960002415 trichloroethylene Drugs 0.000 claims description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 238000005728 strengthening Methods 0.000 claims 1
- 239000004566 building material Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- 238000002604 ultrasonography Methods 0.000 description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 6
- 238000005660 chlorination reaction Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 229910052580 B4C Inorganic materials 0.000 description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- RHFLVCTUYKRSDV-UHFFFAOYSA-N formamide;methanol Chemical group OC.NC=O RHFLVCTUYKRSDV-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/142—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3215—Barium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3293—Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO]
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Architecture (AREA)
- Dispersion Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Reinforced Plastic Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Ceramic Products (AREA)
Abstract
The invention discloses a kind of fibre reinforced high-impact ceramic tile, belong to Domestic building material field, aim to solve the problem that existing ceramic tile toughness is not enough, problem easy to crack, including ceramic matrix and enhanced carbon fiber, preparation method is as follows: step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer: 20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, magnesium carbonate 5 parts, forms mixture；Step 2: enhanced carbon fiber is carried out surface coated treatment with chemical vapor infiltration, described unstripped gas is the mixed gas of fuel gas, boron chloride, hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min 200ml/min, and depositing temperature is 900 DEG C 1200 DEG C；Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to mix it；Step 4: prepare ceramic tile.
Description
Technical field
The present invention relates to ceramic tile, be specifically a kind of fibre reinforced high-impact ceramic tile.
Background technology
Along with the raising of people's living standard, the requirement to residential environment is more and more higher, and the resource of consumption the most about arrives the most,
Causing serious environmental pollution, wherein in construction material and goods thereof, ceramic tile occupies the biggest ratio, annual digestion amount
The hugest.But existing ceramic tile is mainly prepared by inorganic material such as Kaolin, although the rigidity of material is bigger, when
Time material fragility big, toughness is not enough, permanent uses and be easy under the collision of enormous power cracking, damaged, needs further exist for
Change, cause the waste of resource.
Summary of the invention
It is an object of the invention to: for the problem of above-mentioned existence, it is provided that a kind of fibre reinforced high-impact ceramic tile,
The method adding enhanced carbon fiber material in existing ceramic tile, described enhanced carbon fiber material is used to use fibre reinforced
Prepared by nylon material, it is best that the precondition in cost economy is issued to the toughening effect to pottery, solves existing domestic
The problem that ceramic tile toughness is not enough.
The technical solution used in the present invention is as follows:
The invention discloses a kind of fibre reinforced high-impact ceramic tile, it is characterised in that described fibre reinforced height is resistance to
Impact ceramic tile includes ceramic matrix and enhanced carbon fiber.
Further, described enhanced carbon fiber (2) is carbon fiber reinforced nylon fiber, carbon fiber and nylon fiber
Mass ratio is 1:1-1:3.
The highest to the requirement of strength of carbon fibre reinforcement in tile base, if so use pure carbon fiber prepare time
Wait, will cause high cost, after multiple enhanced carbon fiber material is made a service test by inventor and cost is considered,
Bright carbon fiber reinforced nylon fiber can be in the case of lower-cost, and its ceramic tile made has preferable performance.
Further, the preparation method of described fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be fuel gas,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min-
200ml/min, depositing temperature is 900 DEG C-1200 DEG C；
Why the ceramic tile of carbon fiber and ceramic matrix material synthesis has preferable toughness, and it is mainly due to carbon fiber
With ceramic matrix interface phase, interface can be good at coupling together carbon fiber and ceramic matrix mutually, and can be by suffered by material
Stress well transmits, and increases the resistance to impact of product, by chemical vapor infiltration at enhanced carbon fiber material and ceramic base
Forming the cross section phase containing boron carbide between body material, when stress is delivered in interface phase in the product when, interface is formed mutually
Boron carbide coating to surrounding crack occurs, dispersive stress, increase the toughness of product.
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to it
Mix；
Step 4: prepare ceramic tile, the described technique preparing ceramic tile uses conventional methods, but in the middle of the process of preparation, can
With the situation according to raw material, the concrete technology preparing ceramic tile is carried out suitable adjustment.
Further, described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed.
As preferably, described organic solvent is Methanamide, trifluoroacetic acid, DMSO, DMF, hexamethyl-phosphoramide, first
Alcohol, ethanol, acetic acid, trichloro ethylene, n-butyl alcohol, ether, n-butyl ether, carbon tetrachloride, hexamethylene, the one of hexane.
As preferentially, above-mentioned physical method includes high speed shear, ultrasonic blending, aiming at enhancing in mixed thing
Carbon fibre material and preferably mixing, prevents from occurring between carbon fiber being wound around and mixing uneven problem, as mixed
Close the preferred of physical method, use the method for high speed shear or ultrasonic blending to can be good at allowing each component be sufficiently mixed.
As preferably, above-mentioned fuel gas is methane or acetylene.
As preferably, the carbon fiber of described carbon fiber reinforced nylon fiber is chopped carbon fiber.
As preferably, the described nylon talking fiber reinforced nylon fiber uses nylon 6.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows:
One. the present invention provides carbon fibre reinforcement to be used for preparing in the middle of the preparation technology of ceramic tile particularly domestic ceramic tile, made
Standby ceramic tile has the rigidity of excellence, is difficult to the situations such as cut occur when in use；
Two. special interface characteristics by being formed between enhanced carbon fiber material and ceramic matrix, it is possible to well dispersion
Suffered stress, greatly increases the toughness of ceramic tile under the precondition not changing respective performances, is receiving the work of external force
The situations such as cracking, fracture it are difficult under with.
Accompanying drawing explanation
Fig. 1 is the cross-sectional view of the ceramic tile that the present invention provides；
Labelling in figure: 1-ceramic matrix, 2-enhanced carbon fiber.
Detailed description of the invention
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, right
The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, and
It is not used in the restriction present invention.
Specific embodiment 1: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, it is special
Levying and be, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhancing carbon
Fiber is carbon fiber reinforced nylon fiber, and the mass ratio with nylon of described carbon fiber is 1:1, and described carbon fiber reinforced nylon is fine
The carbon fiber of dimension is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide.
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It is 900 DEG C DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Step 4: prepare ceramic tile.
Specific embodiment 2: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, it is special
Levying and be, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhancing carbon
Fiber is carbon fiber reinforced nylon fiber, and the mass ratio with nylon of described carbon fiber is 1:1, and described carbon fiber reinforced nylon is fine
The carbon fiber of dimension is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide n-butyl alcohol.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, deposition
Temperature is 1200 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 3: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is ether.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 150ml/min, deposition
Temperature 1000 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 4: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, depositing temperature
It is 900 DEG C DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 5: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:2, described carbon fiber reinforced nylon fiber
Carbon fiber is filament carbon fibre, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture, and described magnesium carbonate is the magnesium carbonate of coupling agent modified mistake, and magnesium carbonate is added by method of modifying as follows
In coupling reaction tank, opening agitating device, stirring makes magnesium carbonate rotate, by silane coupler with water, organic solvent according to 1:
After 1:0.5 is configured to solution, being sprayed directly in magnesium carbonate, the rotary speed controlling agitating device is 4000 rev/min-6000
Rev/min so that the temperature of mixture reaches 120 degrees Celsius, after reacting 10-20 minute, dries 10-30 at 100-150 DEG C
The magnesium carbonate that minute prepared coupling modifier is crossed, described organic solvent is Methanamide methanol.
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be methane,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, deposition
Temperature is 900 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 6: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 200ml/min, depositing temperature
It it is 1000 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 7: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1.5, described carbon fiber reinforced nylon fiber
Carbon fiber be chopped carbon fiber, nylon use nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It it is 90 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 8: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:3, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon 6.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is methane, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min, depositing temperature
It it is 1100 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
Specific embodiment 9: as it is shown in figure 1, present embodiment discloses a kind of fibre reinforced high-impact ceramic tile, its feature exists
In, described fibre reinforced high-impact ceramic tile includes ceramic matrix 1 and enhanced carbon fiber 2, described enhanced carbon fiber
For carbon fiber reinforced nylon fiber, the mass ratio with nylon of described carbon fiber is 1:1, described carbon fiber reinforced nylon fiber
Carbon fiber is chopped carbon fiber, and nylon uses nylon66 fiber.
Disclosed in the present embodiment, the preparation method of fibre reinforced high-impact ceramic tile is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: with chemical vapor infiltration, enhanced carbon fiber being carried out surface coated treatment, described unstripped gas is acetylene, chlorination
Boron, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100/min, and depositing temperature is
90℃；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses high speed shear, ultrasound wave
It is blended and it is mixed；
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Any amendment, equivalent and the improvement etc. made within principle, should be included within the scope of the present invention.
Claims (9)
1. a fibre reinforced high-impact ceramic tile, it is characterised in that described fibre reinforced high-impact ceramic tile
Including ceramic matrix (1) and enhanced carbon fiber (2).
Fibre reinforced high-impact ceramic tile the most according to claim 1, it is characterised in that described enhanced carbon fiber
(2) being carbon fiber reinforced nylon fiber, the mass ratio with nylon fiber of carbon fiber is 1:1-1:3.
Fibre reinforced high-impact ceramic tile the most according to claim 2, it is characterised in that preparation method is as follows:
Step 1: the principle of following weight portion is carried out mixed preparing and is sufficiently mixed in mixer:
20 parts of quartz, 10 parts of nepheline syenite, albite 40 parts, stannum oxide 5 parts, pyrophyllite 20 parts, Barium metatitanate. 5 parts, carbonic acid
5 parts of magnesium, forms mixture；
Step 2: enhanced carbon fiber carried out surface coated treatment with chemical vapor infiltration, described unstripped gas be fuel gas,
Boron chloride, the mixed gas of hydrogen, the volume ratio of above-mentioned three kinds of gases is 2:1:1, and gas overall flow rate is 100ml/min-
200ml/min, depositing temperature is 900 DEG C-1200 DEG C；
Step 3: the enhanced carbon fiber after step 2 joined in the mixture described in step 1, uses physical method to carry out it
Mixing；
Step 4: prepare ceramic tile.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that described magnesium carbonate is
The magnesium carbonate of coupling agent modified mistake, magnesium carbonate is joined in coupling reaction tank by method of modifying as follows, opens agitating device, stirring
Make magnesium carbonate rotate, after silane coupler and water, organic solvent are configured to solution according to 1:1:0.5, be sprayed directly on carbonic acid
In magnesium, the rotary speed controlling agitating device is 4000 revs/min-6000 revs/min so that the temperature of mixture reaches 120
Degree Celsius, after reacting 10-20 minute, at 100-150 DEG C, dry the magnesium carbonate that 10-30 minute prepared coupling modifier is crossed.
Fibre reinforced high-impact ceramic tile the most according to claim 4, it is characterised in that described organic solvent
For Methanamide, trifluoroacetic acid, DMSO, DMF, hexamethyl-phosphoramide, methanol, ethanol, acetic acid, trichloro ethylene, n-butyl alcohol, second
Ether, n-butyl ether, carbon tetrachloride, hexamethylene, the one of hexane.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that physical method include
High speed shear, ultrasonic blending.
Fibre reinforced high-impact ceramic tile the most according to claim 3, it is characterised in that described fuel gas is
Methane or acetylene.
8. according to the fibre reinforced high-impact ceramic tile one of right 1-5 to be gone Suo Shu, it is characterised in that described carbon fiber
The carbon fiber strengthening nylon fiber is chopped carbon fiber.
9. according to the fibre reinforced high-impact ceramic tile one of right 1-5 to be gone Suo Shu, it is characterised in that described what is said or talked about is fine
Dimension strengthens the nylon of nylon fiber and uses nylon 6.
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| CN201610812973.4A CN106223564A (en) | 2016-09-09 | 2016-09-09 | A kind of fiber reinforcement high-impact ceramic tile |
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| CN108558379A (en) * | 2018-04-11 | 2018-09-21 | 南安市创培电子科技有限公司 | A kind of processing method of ceramic tile |
| CN112536909A (en) * | 2020-11-19 | 2021-03-23 | 唐玉明 | Preparation method of large-size ultrathin high-strength ceramic large plate |
| CN112851384A (en) * | 2021-01-29 | 2021-05-28 | 中南大学 | Preparation method of low-temperature sintered ceramic matrix composite based on silicon carbide fiber reinforcement |
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