CN106147688A - A kind of antistatic protection film glue and a kind of antistatic protection film - Google Patents
A kind of antistatic protection film glue and a kind of antistatic protection film Download PDFInfo
- Publication number
- CN106147688A CN106147688A CN201510149316.1A CN201510149316A CN106147688A CN 106147688 A CN106147688 A CN 106147688A CN 201510149316 A CN201510149316 A CN 201510149316A CN 106147688 A CN106147688 A CN 106147688A
- Authority
- CN
- China
- Prior art keywords
- protection film
- antistatic protection
- antistatic
- glue
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003292 glue Substances 0.000 title claims abstract description 34
- 239000002216 antistatic agent Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 150000005846 sugar alcohols Polymers 0.000 claims description 12
- 230000002101 lytic effect Effects 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- -1 lithium class sulfonate Chemical class 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002799 BoPET Polymers 0.000 claims description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 3
- 239000005041 Mylar™ Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000003925 fat Substances 0.000 claims description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical group 0.000 claims description 3
- 150000002641 lithium Chemical class 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 229920006289 polycarbonate film Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims 1
- 239000002985 plastic film Substances 0.000 abstract 1
- 229920006255 plastic film Polymers 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000013022 venting Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a kind of antistatic protection film glue and a kind of antistatic protection film.By adding liquid antistatic agent, solve the problem that antistatic agent separates out from glue-line.Glue the most provided by the present invention has good tack, excellent venting quality to plastic film substrates such as PET, PE, PC so that protecting film, on the basis of having excellent electrostatic-proof function, also has good product stability and the characteristic without cull.
Description
Technical field
The present invention relates to antistatic protection film field, particularly to a kind of antistatic protection film glue and
A kind of antistatic protection film.
Background technology
Electronic apparatus series products is during carrying or production and application, and its surface is highly prone to contact staining
Or produce polishing scratch to scratch, need to use protecting film that its surface carries out covering and make it from getting dirty or being subject to
Damage.And protecting film used by electronics or electric type product must also have a characteristic: can not produce when removing
Electrostatic, in order to avoid causing damage to electronic apparatus series products.
The mode of production of antistatic protection film in the market mainly has three kinds: (one) is at protecting film base material
The back side be coated with one layer of antistatic backing.The protecting film anti-static effect of this kind of method production is poor, leads simultaneously
Cause production process and production cost increases.(2) on protecting film base material, antistatic bottom first it is coated with,
It is coated glue.There is the situation that anti-static effect weakens with bondline thickness increase in this kind of method, and
And the attachment of glue-line and antistatic backing is loosely, there is also production process simultaneously and production cost increases asks
Topic.(3) in glue, conductive agent is added.The method is current main stream approach, both can lower production
Operation and cost, can reach again good anti-static effect, but exist under extreme climate antistatic agent from
Glue-line separates out, the problem polluting protected object.How to solve this problem and become PU antistatic protection
One major subjects in film research and development field.
Summary of the invention
For overcoming the deficiencies in the prior art, the invention provides a kind of antistatic protection film glue and one
Plant antistatic protection film.By adding the antistatic agent of liquid in glue, solve antistatic agent from
The problem separated out in glue-line.
Antistatic protection film glue provided by the present invention, is 30%-60%'s by percentage by weight
After host, and the lytic agent mixing that percentage by weight is 30%-60%, adding percentage by weight is
The firming agent of 5%-20%, adds the liquid antistatic agent that percentage by weight is 0.5%-3% and makes.
It is further preferred that described antistatic agent is the fluorine system conductive material being dissolved in described lytic agent.
It is further preferred that described fluorine system conductive material is metal ion is potassium, sodium, lithium class sulfonate
Or potassium, sodium, lithium class sulfimide salt.
It is further preferred that described host is polyhydric alcohol, described polyhydric alcohol is fats polyhydric alcohol or virtue
The one or more of which mixture of fragrant class polyhydric alcohol.
It is further preferred that described lytic agent is ethyl acetate, butyl acetate, toluene, acetone, fourth
One or more mixture of ketone.
It is further preferred that described firming agent is isocyanates firming agent.
It is further preferred that the molecular weight of the polyurethane of described antistatic protection film glue is
90000-160000。
The antistatic protection film of the carried offer of the present invention, is coated with according to any one of claim 1-9 institute
The antistatic protection film glue stated.
It is further preferred that the thickness of coated antistatic protection film glue is 4-50um.
It is further preferred that described protecting film be mylar, polycarbonate film, polyethylene film,
Any one in polyvinyl chloride film.
Beneficial effects of the present invention is as follows:
Antistatic protection film glue provided by the present invention, uses suitable proportioning raw materials, levelability
Good, coating difficulty is low, and Painting effect is good, and film forming final vacuum is excellent, tears rear noresidue;Simultaneously
Owing to the addition of the antistatic agent of liquid, there is excellent anti-static effect.
Antistatic protection film provided by the present invention above-mentioned with the addition of liquid antistatic agent owing to being coated with
Glue, its anti-static effect will not be affected by coating layer thickness, and this antistatic agent is extremely
Under weather the most extremely stable, will not from glue-line separate out cause protected object be contaminated.
Detailed description of the invention
Below the present invention is described in further detail.
Antistatic protection film glue provided by the present invention, is the master of 30%-60% by percentage by weight
Agent, and after the lytic agent that percentage by weight is 30%-60% is sufficiently mixed, adding percentage by weight is
The firming agent of 5%-20% is sufficiently mixed, then is added immediately the liquid that percentage by weight is 0.5%-3% and prevents quiet
Electricity agent prepares after stirring.
Described antistatic agent is the fluorine system conductive material being dissolved in described lytic agent, includes but not limited to metal
Ion is potassium, sodium, lithium class sulfonate, potassium, sodium, lithium class sulfimide salt.
Described host is polyhydric alcohol, and described polyhydric alcohol is its of fats polyhydric alcohol or aromatics polyhydric alcohol
In one or more mixtures.Described lytic agent be ethyl acetate, butyl acetate, toluene, acetone,
One or more mixture of butanone.Described firming agent is isocyanates firming agent.Described anti-
The molecular weight of the polyurethane of electrostatic protection film glue is 90000-160000.
Antistatic protection film provided by the present invention, coats by above-mentioned antistatic protection film glue, and
The thickness of coating is 4-50um.
Described antistatic protection film can be mylar, polycarbonate film, polyethylene film or poly-
Vinyl chloride film.
Embodiment one
Antistatic protection film glue provided by the present invention, is the host of 30% by percentage by weight,
After being sufficiently mixed with the lytic agent that percentage by weight is 64%, adding percentage by weight is the firming agent of 5%
It is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 1% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue
Water, coating thickness is 45um.
Embodiment two
Antistatic protection film glue provided by the present invention, is the host of 40% by percentage by weight,
After being sufficiently mixed with the lytic agent that percentage by weight is 48%, adding percentage by weight is the solidification of 10%
Agent is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 2% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue
Water, coating thickness is 15um.
Embodiment three
Antistatic protection film glue provided by the present invention, is the host of 40% by percentage by weight,
After being sufficiently mixed with the lytic agent that percentage by weight is 37%, adding percentage by weight is the solidification of 20%
Agent is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 3% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue
Water, coating thickness is 8um.
Following table is antistatic protection film provided by the present invention and common antistatic polyurethane protective film
Data Comparison table, therefrom visible compared to prior art, antistatic protection film provided by the present invention is prevented
Electrostatic efficiency is good, without cull, and is antistatic agent rather than the conducting particles of liquid due to add,
Thus antistatic agent also will not separate out from glue-line under extreme climate, pollution protected object will not be produced
Problem.
Antistatic protection film Data Comparison catalog
Note: 1, JP001/002/003/004/005/006 is the common antistatic polyurethane protective film sold on market
2, CH001/002 is antistatic protection film provided by the present invention
Antistatic protection film provided by the present invention can be used for the electronic apparatus such as display screen, touch screen and produces
Product are it can also be used to the process during electrical type other products manufactures is protected.
It is of the art it will be recognized by the skilled artisan that above example of the present invention is only this
One of preferred embodiment of invention, limits for length, can not enumerate all embodiments here one by one,
Any enforcement that can embody the claims in the present invention technical scheme, all in protection scope of the present invention
In.
It should be noted that above content be combine specific embodiment made for the present invention enter one
Step describes in detail, it is impossible to assert that the detailed description of the invention of the present invention is only limitted to this, above-mentioned in the present invention
Under guidance, those skilled in the art can carry out various improvement and change on the basis of above-described embodiment
Shape, and these improve or deformation is within the scope of the present invention.
Claims (10)
1. an antistatic protection film glue, is the host of 30%-60% by percentage by weight, and
After percentage by weight is the lytic agent mixing of 30%-60%, adding percentage by weight is the solidification of 5%-20%
Agent, adds the liquid antistatic agent that percentage by weight is 0.5%-3% and makes.
Antistatic protection film glue the most according to claim 1, it is characterised in that: described anti-
Electrostatic agent is the fluorine system conductive material being dissolved in described lytic agent.
Antistatic protection film glue the most according to claim 1, it is characterised in that: described fluorine
Be conductive material be metal ion be potassium, sodium, lithium class sulfonate or potassium, sodium, lithium class sulfimide salt.
4., according to the antistatic protection film glue described in any one of claim 1-3, its feature exists
In: described host is polyhydric alcohol, and described polyhydric alcohol is its of fats polyhydric alcohol or aromatics polyhydric alcohol
In one or more mixtures.
Antistatic protection film glue the most according to claim 4, it is characterised in that: described molten
Solution agent is one or more mixture of ethyl acetate, butyl acetate, toluene, acetone, butanone.
Antistatic protection film glue the most according to claim 5, it is characterised in that: described solid
Agent is isocyanates firming agent.
Antistatic protection film glue the most according to claim 7, it is characterised in that: described anti-
The molecular weight of the polyurethane of electrostatic protection film glue is 90000-160000.
8. an antistatic protection film, it is characterised in that: it is coated with according to claim 1-9 arbitrary
Antistatic protection film glue described in Xiang.
Antistatic protection film the most according to claim 8, it is characterised in that: coated is anti-
The thickness of electrostatic protection film glue is 4-50um.
Antistatic protection film the most according to claim 9, it is characterised in that: described protecting film
For any one in mylar, polycarbonate film, polyethylene film, polyvinyl chloride film.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510149316.1A CN106147688A (en) | 2015-04-01 | 2015-04-01 | A kind of antistatic protection film glue and a kind of antistatic protection film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510149316.1A CN106147688A (en) | 2015-04-01 | 2015-04-01 | A kind of antistatic protection film glue and a kind of antistatic protection film |
Publications (1)
Publication Number | Publication Date |
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CN106147688A true CN106147688A (en) | 2016-11-23 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201510149316.1A Pending CN106147688A (en) | 2015-04-01 | 2015-04-01 | A kind of antistatic protection film glue and a kind of antistatic protection film |
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CN (1) | CN106147688A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590460A (en) * | 2016-12-30 | 2017-04-26 | 东莞市尼的科技股份有限公司 | Anti-static protective film |
CN109705769A (en) * | 2018-12-31 | 2019-05-03 | 上海精珅新材料有限公司 | A kind of preparation method and products thereof that can tear off screen process film at a high speed |
CN110951436A (en) * | 2019-12-09 | 2020-04-03 | 深圳盛得莱防静电设备有限公司 | Anti-static adhesive and preparation method thereof |
CN112029405A (en) * | 2020-08-19 | 2020-12-04 | 江苏斯瑞达材料技术股份有限公司 | Anti-static polyurethane protective film and preparation method thereof |
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CN1696230A (en) * | 2004-05-14 | 2005-11-16 | 日东电工株式会社 | Adhesive composition, adhesive sheet and surface protection film |
CN101796439A (en) * | 2007-09-03 | 2010-08-04 | 住友化学株式会社 | Optical film with adhesive and optical laminate |
CN102070990A (en) * | 2009-11-16 | 2011-05-25 | 琳得科株式会社 | Adhesive composition, adhesive and adhesive sheet |
CN103571360A (en) * | 2012-07-31 | 2014-02-12 | 日东电工株式会社 | Surface protective film, optical member, and electronic member |
CN104531039A (en) * | 2014-12-29 | 2015-04-22 | 宁波大榭开发区综研化学有限公司 | Preparation method of polyurethane pressure-sensitive adhesive composition and polyurethane protective film |
-
2015
- 2015-04-01 CN CN201510149316.1A patent/CN106147688A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1696230A (en) * | 2004-05-14 | 2005-11-16 | 日东电工株式会社 | Adhesive composition, adhesive sheet and surface protection film |
CN101796439A (en) * | 2007-09-03 | 2010-08-04 | 住友化学株式会社 | Optical film with adhesive and optical laminate |
CN102070990A (en) * | 2009-11-16 | 2011-05-25 | 琳得科株式会社 | Adhesive composition, adhesive and adhesive sheet |
CN103571360A (en) * | 2012-07-31 | 2014-02-12 | 日东电工株式会社 | Surface protective film, optical member, and electronic member |
CN104531039A (en) * | 2014-12-29 | 2015-04-22 | 宁波大榭开发区综研化学有限公司 | Preparation method of polyurethane pressure-sensitive adhesive composition and polyurethane protective film |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106590460A (en) * | 2016-12-30 | 2017-04-26 | 东莞市尼的科技股份有限公司 | Anti-static protective film |
CN109705769A (en) * | 2018-12-31 | 2019-05-03 | 上海精珅新材料有限公司 | A kind of preparation method and products thereof that can tear off screen process film at a high speed |
CN110951436A (en) * | 2019-12-09 | 2020-04-03 | 深圳盛得莱防静电设备有限公司 | Anti-static adhesive and preparation method thereof |
CN112029405A (en) * | 2020-08-19 | 2020-12-04 | 江苏斯瑞达材料技术股份有限公司 | Anti-static polyurethane protective film and preparation method thereof |
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TA01 | Transfer of patent application right |
Effective date of registration: 20190523 Address after: Nine Blocks 288 Jinhe Road, Jinshan Industrial Zone, Jinshan District, Shanghai Applicant after: Shanghai Jingjing New Materials Co., Ltd. Address before: 201316 Three Blocks 118 Hangtou Road, Hangtou Town, Pudong New Area, Shanghai Applicant before: SHANGHAI PLUSCO TECH CO., LTD. |
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Application publication date: 20161123 |