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CN106116433A - A kind of high-strength fire-retardant precoated plate and production technology thereof - Google Patents

A kind of high-strength fire-retardant precoated plate and production technology thereof Download PDF

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Publication number
CN106116433A
CN106116433A CN201610503613.6A CN201610503613A CN106116433A CN 106116433 A CN106116433 A CN 106116433A CN 201610503613 A CN201610503613 A CN 201610503613A CN 106116433 A CN106116433 A CN 106116433A
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precoated plate
retardant
cement
binding agent
strength fire
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CN201610503613.6A
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CN106116433B (en
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唐兴彦
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/42Glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0625Polyalkenes, e.g. polyethylene
    • C04B16/0633Polypropylene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)

Abstract

The present invention relates to a kind of precoated plate, specifically disclose a kind of high-strength fire-retardant precoated plate, including following components: cement, flyash, magnesium chloride, magnesium oxide, glass fibre, polypropylene fibre, Gypsum Fibrosum, attapulgite, binding agent and water.The invention also discloses the production technology of this precoated plate.Using technical scheme, prepared precoated plate has good weight capacity, and intensity is high, and fireproof heat insulating is functional.

Description

A kind of high-strength fire-retardant precoated plate and production technology thereof
Technical field
The present invention relates to a kind of precoated plate, particularly relate to a kind of high-strength fire-retardant precoated plate and production technology thereof.
Background technology
Precoated plate of a great variety, traditional is essentially all with polystyrene resin for raw material plus other supplementary material With poly-inclusion, it is injected simultaneously into catalyst by adding hot mixing, then extrusion molding extrusion molding and the rigid foam plate that manufactures, its Have the features such as lightweight, moistureproof, waterproof, but this warming plate does not the most have fireproof function.Fire resistant pre-fabricated plate because of its material, Kind, specification use value are more and more abundanter, and its insulation, heat insulation, lightweight, high-strength, fire-resistant, fire-retardant characteristic, in society On be widely used in the fields such as interior decoration, furniture, kitchen cabinet, laboratory face and exterior wall.
Document CN104975659A discloses a kind of inorganic heat-insulating fireproof plate, by protective plate, substrate and its built-in sandwich Constituting, the component of sandwich is magnesium chloride 8%~15% according to percentage by weight, magnesium oxide 5%~10%, expanded and vitrified small ball 10%~20%, calcium-silicate 3%~6%, alumina cement 10%~18%, organosilicon moisture repellent 0.05%~0.1%, poly-third Alkene fiber 0.1%~0.25%, binding agent 2%~4%, water 40%~45%.Use technique scheme, improve wet mixing and close In the viscosity of material, effectively reduction goods, lightweight aggregate is broken, and the heat-insulating property of goods is greatly improved.Document CN102503337A Disclose a kind of prefabricated panels, prepare raw material and include cement, flyash, insulation material aggregate, become stone agent and water;Described cement with The mass ratio of flyash is 2.0~3.5: 1.0;It is 1.0~1.2: 1.0 that water and cement add the mass ratio of flyash;Cement adds powder Coal ash is 2.0~3.0: 1.0 with the mass ratio of described insulation material aggregate;Described one-tenth stone agent is polymer, and component includes alkyl Sulfonate, lauryl alcohol, starch, sodium cellulosate, Gypsum Fibrosum, sodium sulfate, it is 1.0 that cement adds flyash with the mass ratio becoming stone agent: 0.03~0.05.This prefabricated panels has a good weight capacity, insulation, heat insulation, prevent fires, insulate against sound, impervious, antiseptic property is good Good;There is venting of dust explosion characteristic;Processability is good, can saw, can follow closely, can dig, can bore, can be coated with, can paste, pollution-free, zero-emission, and this plate without Steel frame, will not occur " cold bridge " effect, it is possible to meet higher building requirements.PLASTIC LAMINATED or precoated plate in above-mentioned document exist Heat insulation, fire prevention aspect has reasonable effect, but the production technology of PLASTIC LAMINATED is more complicated, and intensity has much room for improvement.
Summary of the invention
The present invention is directed to defect of the prior art, it is provided that a kind of high-strength fire-retardant precoated plate and production technology thereof.
The technical scheme is that a kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Described cement is sulphate aluminium cement and portland cement, and the mass ratio of the two is 4-5:1.
Described binding agent is polyvinyl alcohol, politef, carboxymethyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl One or more in sodium cellulosate, methyl hydroxyethylcellulose ether, preferably politef and methyl hydroxyethylcellulose Ether, the mass ratio of the two is 2-3:1, uses politef and two kinds of adhesive complexes of methyl hydroxyethylcellulose ether, utilizes Difference on two kinds of adhesive structures and performance, improves the intensity of precoated plate.
The fineness of described Gypsum Fibrosum is 120-130 mesh.
Preferably, a kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
The production technology of a kind of high-strength fire-retardant precoated plate, comprises the following steps:
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 15-30min is ground, Obtain modified abrasive slurry;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir;
(4) add the mixture that step (2) obtains, stir;
(5) discharging is in mould, and the thermostatic chamber maintenance 30-45h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Preferably, the mixing time in described step (3) is 5-10min, and mixing speed is 1200-1300r/min.
Preferably, the mixing speed in described step (4) is 500-600r/min, and mixing time is 10-15min.
The precoated plate of the present invention uses sulphate aluminium cement and two kinds of cement of portland cement to compound, flyash and stone in addition Cream, improves hardness and the intensity of precoated plate;While magnesium chloride, magnesium oxide and attapulgite improve component dispersibility, promote material The viscosity of material;Use compound binding agent to add the cohesive force of each component, glass fibre and the interpolation of polypropylene fibre, enter one Step promotes the mechanical properties such as the intensity of material.There is between each component of the present invention synergism, improve precoated plate Mechanics and fireproof heat insulating performance.The production technology of the present invention, by glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite Being modified processing, substep adds the methods such as component, improves the intensity of precoated plate further.The precoated plate that the present invention provides has Good weight capacity, intensity is high, and fireproof heat insulating is functional.
Detailed description of the invention
Embodiment 1
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, binding agent is politef and methyl hydroxyethylcellulose ether, and the mass ratio of the two is 2:1;Gypsum Fibrosum Fineness is 125 mesh.
Make to prepare as follows by said ratio:
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 20min is ground, Modified abrasive is starched;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir 8min, and mixing speed is 1250r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 550r/min, and mixing time is 12min;
(5) discharging is in mould, and the thermostatic chamber maintenance 36h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Embodiment 2
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, cement is sulphate aluminium cement and portland cement, and the mass ratio of the two is 4:1;Binding agent is polytetrafluoro Ethylene and methyl hydroxyethylcellulose ether, the mass ratio of the two is 3:1;The fineness of Gypsum Fibrosum is 120 mesh.
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 15min is ground, Modified abrasive is starched;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir 10min, and mixing speed is 1200r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 500r/min, and mixing time is 15min;
(5) discharging is in mould, and the thermostatic chamber maintenance 30h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Embodiment 3
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, cement is sulphate aluminium cement and portland cement, and the mass ratio of the two is 5:1;Binding agent is polytetrafluoro Ethylene and methyl hydroxyethylcellulose ether, the mass ratio of the two is 2:1;The fineness of Gypsum Fibrosum is 130 mesh.
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 30min is ground, Modified abrasive is starched;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir 5min, and mixing speed is 1300r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 600r/min, and mixing time is 10min;
(5) discharging is in mould, and the thermostatic chamber maintenance 45h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Comparative example 1
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, binding agent is politef and methyl hydroxyethylcellulose ether, and the mass ratio of the two is 2:1;Gypsum Fibrosum Fineness is 125 mesh.
Make to prepare as follows by said ratio:
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 20min is ground, Modified abrasive is starched;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir 8min, and mixing speed is 1250r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 550r/min, and mixing time is 12min;
(5) discharging is in mould, and the thermostatic chamber maintenance 36h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Comparative example 2
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, binding agent is politef and methyl hydroxyethylcellulose ether, and the mass ratio of the two is 1:2;Gypsum Fibrosum Fineness is 125 mesh.
Make to prepare as follows by said ratio:
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, 20min is ground, Modified abrasive is starched;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), in homogenizer Stir 8min, and mixing speed is 1250r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 550r/min, and mixing time is 12min;
(5) discharging is in mould, and the thermostatic chamber maintenance 36h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Comparative example 3
A kind of high-strength fire-retardant precoated plate, including the component of following mass fraction,
Wherein, binding agent is politef and methyl hydroxyethylcellulose ether, and the mass ratio of the two is 2:1;Gypsum Fibrosum Fineness is 125 mesh.
Make to prepare as follows by said ratio:
(1) by proportioning, glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously must be premixed material;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the premix material in step (1), stir in homogenizer Mixing uniform 8min, mixing speed is 1250r/min;
(4) adding the mixture that step (2) obtains, mixing speed is 550r/min, and mixing time is 12min;
(5) discharging is in mould, and the thermostatic chamber maintenance 36h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Precoated plate prepared by embodiment 1-3 and comparative example 1-3 is carried out performance test, and test result is shown in Table 1.
Table 1
As it can be seen from table 1 the tensile strength of precoated plate, dimensional stability and combustibility etc. prepared by the present invention are square Face, hence it is evident that higher than the performance of precoated plate prepared in comparative example, illustrate that the precoated plate of the present invention has more preferable weight capacity, Intensity is high, and fireproof heat insulating is functional.
A kind of high-strength fire-retardant precoated plate provided the embodiment of the present invention above and production technology thereof, carried out in detail Introducing, principle and the embodiment of the present invention are set forth by specific case used herein, the explanation of above example It is only intended to help to understand method and the core concept thereof of the present invention;Simultaneously for one of ordinary skill in the art, according to this The thought of invention, the most all will change, and in sum, this specification content should not It is interpreted as limitation of the present invention.

Claims (9)

1. a high-strength fire-retardant precoated plate, it is characterised in that include the component of following mass fraction,
Precoated plate the most according to claim 1, it is characterised in that described cement is sulphate aluminium cement and silicate cement Mud, the mass ratio of the two is 4-5:1.
Precoated plate the most according to claim 1, it is characterised in that described binding agent is polyvinyl alcohol, politef, carboxylic One or more in methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose, methyl hydroxyethylcellulose ether.
Precoated plate the most according to claim 3, it is characterised in that described binding agent is politef and dimethyl hydroxyethyl Cellulose ether, the mass ratio of the two is 2-3:1.
Precoated plate the most according to claim 1, it is characterised in that the fineness of described Gypsum Fibrosum is 120-130 mesh.
Precoated plate the most according to claim 1, it is characterised in that a kind of high-strength fire-retardant precoated plate, including following quality The component of number,
7. a production technology for high-strength fire-retardant precoated plate, comprises the following steps:
(1) by proportioning by after glass fibre, polypropylene fibre, Gypsum Fibrosum and attapulgite mix homogeneously, grind 15-30min, must change Property slurry;
(2) mixture is obtained after taking cement, flyash, magnesium chloride and magnesium oxide Vibratory Mixing;
(3) take binding agent and be added to the water mix homogeneously, add the modified abrasive slurry in step (1), stir in homogenizer Uniformly;
(4) add the mixture that step (2) obtains, stir;
(5) discharging is in mould, and the thermostatic chamber maintenance 30-45h of the demoulding to 30-40 DEG C, natural drying solidifies to obtain finished product.
Technique the most according to claim 7, it is characterised in that the mixing time in described step (3) is 5-10min, stirs Mixing speed is 1200-1300r/min.
Technique the most according to claim 7, it is characterised in that the mixing speed in described step (4) is 500-600r/ Min, mixing time is 10-15min.
CN201610503613.6A 2016-06-30 2016-06-30 A kind of high-strength fire-retardant prefabricated board and its production technology Expired - Fee Related CN106116433B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106588103A (en) * 2016-12-16 2017-04-26 侯风光 Autoclaved aerated concrete block doped with water-retaining polypropylene fiber and preparation method of autoclaved aerated concrete block
CN107372205A (en) * 2017-08-31 2017-11-24 株洲县德云养蜂专业合作社 The cultivation beehive and body making method of cement paint are coated in a kind of foam body
CN111117310A (en) * 2020-01-19 2020-05-08 北京天佐消防产品有限公司 Non-expansive gypsum fire-retardant coating and preparation method thereof
CN114368934A (en) * 2020-10-14 2022-04-19 湖南康瑞涂料科技有限公司 Production and processing technology of novel material refractory plate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503337A (en) * 2011-11-08 2012-06-20 北京天基新材料股份有限公司 Prefabricated panels and preparation method thereof
CN102826823A (en) * 2011-06-17 2012-12-19 大庆华夏绿垣建材科技开发有限公司 Production method of novel lightweight high-strength shock-resistant fireproofing inner wall board
CN103570313A (en) * 2013-10-24 2014-02-12 上海古猿人石材有限公司 Modified attapulgite clay composite artificial stone material and production method thereof
CN104975659A (en) * 2014-04-11 2015-10-14 张家港市盛港防火板业科技有限公司 Inorganic heat insulation fireproof board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826823A (en) * 2011-06-17 2012-12-19 大庆华夏绿垣建材科技开发有限公司 Production method of novel lightweight high-strength shock-resistant fireproofing inner wall board
CN102503337A (en) * 2011-11-08 2012-06-20 北京天基新材料股份有限公司 Prefabricated panels and preparation method thereof
CN103570313A (en) * 2013-10-24 2014-02-12 上海古猿人石材有限公司 Modified attapulgite clay composite artificial stone material and production method thereof
CN104975659A (en) * 2014-04-11 2015-10-14 张家港市盛港防火板业科技有限公司 Inorganic heat insulation fireproof board

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106588103A (en) * 2016-12-16 2017-04-26 侯风光 Autoclaved aerated concrete block doped with water-retaining polypropylene fiber and preparation method of autoclaved aerated concrete block
CN107372205A (en) * 2017-08-31 2017-11-24 株洲县德云养蜂专业合作社 The cultivation beehive and body making method of cement paint are coated in a kind of foam body
CN107372205B (en) * 2017-08-31 2021-04-27 株洲县德云养蜂专业合作社 Breeding beehive with cement coating coated on foam main body and main body manufacturing method
CN111117310A (en) * 2020-01-19 2020-05-08 北京天佐消防产品有限公司 Non-expansive gypsum fire-retardant coating and preparation method thereof
CN111117310B (en) * 2020-01-19 2023-08-18 北京天佐消防产品有限公司 Non-expansion type gypsum fireproof coating and preparation method thereof
CN114368934A (en) * 2020-10-14 2022-04-19 湖南康瑞涂料科技有限公司 Production and processing technology of novel material refractory plate

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