CN106086283A - A kind of molten point of stove reduction system and method for schreyerite - Google Patents
A kind of molten point of stove reduction system and method for schreyerite Download PDFInfo
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- CN106086283A CN106086283A CN201610638784.XA CN201610638784A CN106086283A CN 106086283 A CN106086283 A CN 106086283A CN 201610638784 A CN201610638784 A CN 201610638784A CN 106086283 A CN106086283 A CN 106086283A
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- shaft furnace
- stove
- reduction shaft
- breeze
- reduction
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/14—Multi-stage processes processes carried out in different vessels or furnaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0066—Preliminary conditioning of the solid carbonaceous reductant
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- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
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- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The present invention relates to a kind of molten point of stove reduction system and method for schreyerite.Described system includes reduction shaft furnace, molten point of stove and oxygen coal gun, wherein, described reduction shaft furnace includes breeze and flux feeding mouth, feed opening, smoke inlet, is provided with the baffle plate of adjustable inclination in the burner hearth of described reduction shaft furnace, and it is hollow structure with the rotating shaft supported;A described molten point stove includes feeding mouth, exhanst gas outlet and discharging opening, and described feeding mouth connects the feed opening of described reduction shaft furnace, and described exhanst gas outlet connects the smoke inlet of described reduction shaft furnace;The lance head of described oxygen coal gun is located in described molten point of stove, and described oxygen coal gun stretches in described molten point of stove from the furnace roof of described molten point of stove.The molten point of stove reduction system and method for schreyerite of the present invention passes through speed and the residence time that the baffle plate arranging adjustable inclination in described reduction shaft furnace declines with control breeze, it is ensured that the reduction effect of breeze.
Description
Technical field
Present invention relates generally to a kind of molten point of stove reduction system and method, be specifically related to a kind of molten point of stove for schreyerite
Reduction system and method.
Background technology
Non-blast furnace ironmaking is a direction of Iron & Steel Development, and main purpose is to realize low cost smelting and difficult reduced ore
Utilization, and for realize cleanly production.In recent years molten point of technology of coal-base fusing reduction and direct-reduction+electric furnace with
And the molten point technology of coal-based direct reduction+gas furnace progressively develops into for one of iron-smelting process technology, this technique had with coal generation
Burnt, reduction temperature high, the duration of heat is short, energy consumption is low, environmental pollution is little and the feature such as reduced investment, meets china natural resources, the energy
Current situation, becomes one of focus of iron and steel circle research the most both at home and abroad.Melting and reducing and direct-reduction technique do not use coke,
It is not required to build coke oven and chemical industry facility, sintering facility can not be built when using lump ore and part pellet, decrease more polluter,
In order to realize, steel plant's cleaning produces, energy-conserving and environment-protective create condition.
Prior art one is COREX (smelting iron the ultimate aim as it with coal) technology.The agent set of this technology is
Reduction shaft furnace and melting gasification furnace.By joining in shaft furnace by lump ore and pelletizing, reducing gas is utilized ore reduction to be arrived
The metallized pellet of more than 90%, then feed them into melting gasification furnace and reduce further and melt, final production goes out qualified molten iron.
The shortcoming of this technology is to directly utilize powder, needs first powder to be pressed into pelletizing recycling, or directly utilize lump ore, this skill
What art was difficult in smelting process in regulation raw material joins charcoal ratio, it is impossible to accurately control the reduction effect of Ore.
Prior art two is FINEX (direct fine ore and non-coking coal dust smelting molten iron) technology, is at COREX technology base
The new technology grown up further on plinth, COREX technology uses lump ore, pelletizing, and FINEX technology all uses fine ore.FINEX
Technical matters replaces the reduction shaft furnace in COREX technique with Finmet (the hot wafering direct-reduction iron processes) technique of 4 grades of fluid beds,
Becoming briquette iron by hot molding to add melting gasification furnace with fluid bed reduction fine ore, briquetting, specially fine ore and limestone, dolomite etc. melts
Agent is put into a series of fluidized-bed reactor together.Fine ore in a downward direction by four reactors, in this course by
Heating, and it is reduced into DRI by the reducibility gas produced by coal gasification of reverse flow therewith.Anti-from last
The DRI answering device heat out is compressed into hot-pressed iron compact (HCI:hot compacted iron), and hot-pressed iron compact is transported afterwards
To fusion and gasification furnace roof, put into melting gasification furnace, be melted.Last out molten iron and slag.
The shortcoming of prior art two is: fluid bed needs level Four to reduce, and structure is complicated;Briquetting is needed before entering molten point of stove
Generate hot pressing ball and enter back into molten point stove.
Higher due to the direct-reduction temperature of the Ores such as schreyerite again, the highest reduction temperature reaches 1350 DEG C, and this is to it also
The internal structure of former stove has higher requirement.
Therefore, in shaft furnace, complete direct reduction reactor to be able to directly utilize the powders such as breeze, coal dust, pulverized limestone, and
Simplify multi-stage fluidized bed process, and transporting velocity and the residence time of breeze can be controlled, it is ensured that the reduction effect of breeze, having must
A kind of molten point of new stove reduction system and method is proposed.
Summary of the invention
It is an object of the invention to provide a kind of molten point of stove reduction system and method for schreyerite so that this technique energy
Enough directly utilize the powders such as breeze, coal dust, pulverized limestone in shaft furnace, complete direct reduction reactor, and simplify multistage fluidized bed work
Skill, it is ensured that the high-temperature-resistant structure in reduction shaft furnace, and transporting velocity and the residence time of breeze can be controlled, to ensure breeze
Reduction effect.
The invention provides a kind of molten point of stove also original system for schreyerite, described system includes reduction shaft furnace, melts and divide
Stove and oxygen coal gun, wherein, described reduction shaft furnace includes breeze and flux feeding mouth, feed opening, smoke inlet, and described breeze is with molten
Agent feeding mouth is located at the top of described reduction shaft furnace, and described feed opening and smoke inlet are located at the bottom of described reduction shaft furnace;Institute
The baffle plate of adjustable inclination it is provided with in stating the burner hearth of reduction shaft furnace, described baffle plate is located under described breeze and flux feeding mouth,
On described feed opening and described smoke inlet;Described baffle plate leaves gap, on described baffle plate with the inwall of described reduction shaft furnace
It is disposed with aperture;The surfacing of described baffle plate is heat-stable ceramic;Described baffle plate is by the rotating shaft through described reduction shaft furnace furnace wall
It is supported on described reduction shaft furnace;Described rotating shaft and described baffle plate are hollow structure;A described molten point stove includes that feeding mouth, flue gas go out
Mouth and discharging opening, described feeding mouth connects the feed opening of described reduction shaft furnace, and described exhanst gas outlet connects described reduction shaft furnace
Smoke inlet;The lance head of described oxygen coal gun is located in described molten point of stove, and described oxygen coal gun stretches into from the furnace roof of described molten point of stove
In described molten point of stove.
Above-mentioned system, is sequentially provided with multiple gear with described inclination angle from top to bottom in the burner hearth of described reduction shaft furnace
Plate, the vertical centrage of the most described reduction shaft furnace in inclination angle of adjacent described baffle plate is arranged symmetrically with.
Above-mentioned system, described baffle plate is adjustable as 30 °-60 ° with the angle of horizontal plane;Hole diameter on described baffle plate
For 10mm-30mm.
Above-mentioned system, described reduction shaft furnace can be block furnace, described baffle plate length along the incline direction at described inclination angle
Degree is 0.5-0.95 times of the described reduction shaft furnace length of side, and the rotary shaft of adjacent described baffle plate is at the vertical direction of described reduction shaft furnace
0.2-1.5 times that distance is the described reduction shaft furnace length of side.
Above-mentioned system, it is heat-resistance stainless steel that described baffle plate is positioned at the main material under described surfacing;Described gear
Plate is provided with sealing device with the junction of described reduction shaft furnace;Described rotating shaft is provided with rotation drive rod.
Above-mentioned system, the exhanst gas outlet of the described molten point of stove flue gas by reduction shaft furnace described in high-temperature flue gas pipeline communication
Import, described high-temperature flue gas pipe interior is provided with water-cooled flue.
Above-mentioned system, the feed opening of described reduction shaft furnace is provided with radar level gauge or capacitance material level meter;Described reduction vertical
Breeze and the flux feeding mouth of stove are connected with speed governing batcher.
Above-mentioned system, the structure of described oxygen coal gun is telescopic water cooled lance, the material of the lance head of described oxygen coal gun
For copper, the sleeve internal layer of described oxygen coal gun is breeze blowing layer, and intermediate layer is blowing oxygen layer, and outermost is cooling circulating water
Layer.
The invention provides a kind of method utilizing said system to carry out molten point of stove reduction, described method includes step: will
Breeze and flux are sent into described reduction shaft furnace and are carried out reduction reaction, generate reduction breeze;Described reduction breeze is sent into described molten
Divide stove, melt point stove coal injection and oxygen by described oxygen coal gun to described and make described coal dust and oxygen combustion, being reduced
Reacted ore deposit liquid and slag;The described molten point of high-temperature flue gas that stove produces is passed through described reduction shaft furnace;In described rotating shaft and institute
State the cooling of baffle interior blowing air.
Above-mentioned method, described method may further comprise the step of: by speed governing batcher governing speed to control described breeze
Feeding amount with flux;By regulating the proportioning of the coal dust of described oxygen coal gun and oxygen to regulate the quantity of unburned coal powder so that
Unreduced breeze reacts further;By promoting the heating-up temperature of described oxygen coal gun to realize ore deposit liquid and slag separation in stove,
The outer ore deposit liquid of stove and slag separation is realized by peripheral slag skimmer;During by regulating the stop in described reduction shaft furnace of the described breeze
Between with control described breeze reduction degree;Described reduction vertical is entered to control flue gas by controlling the water yield in high-temperature flue gas pipeline
Temperature in stove;Come by the delivery rate controlling described breeze after the feed opening of described reduction shaft furnace detects material position further
The feeding amount of regulation breeze, to prevent described feed opening from blocking.
The beneficial effects of the present invention is, it is possible to use breeze at a low price and the higher lump ore of coal dust fictitious hosts and pelletizing
Ore deposit;The present invention can be by the quantity of the proportioning regulation unburned coal powder of regulation coal dust and oxygen, according to smelting in smelting process
Situation utilizes unburned coal powder to adjust in real time to join charcoal ratio;The present invention uses pure oxygen burning, and the high temperature of generation can meet vanadium ferrotianium
Ore deposits etc. are difficult smelts the needs that ore deposit is melted point;The high-temperature flue gas of molten point of stove can supply direct reduction furnace with heating reduction breeze.This
Controllable register in bright takes high temperature resistant measure, can meet the condition of high temperature reduction.
Additionally, regulating measure of the present invention is the most, including delivery rate regulation, the regulation of blanking speed, amount of oxygen and coal dust
Amount regulation, unburned coal powder amount regulation etc., multiple regulating measure and the various state modulator in smelting process and adjustment adapt, and protect
Demonstrate,prove the reduction effect of breeze.
Accompanying drawing explanation
Fig. 1 is the system structure sketch of the embodiment of the present invention;
Fig. 2 is the reduction shaft furnace interior panelling front view structural representation of the embodiment of the present invention;And
Fig. 3 be in Fig. 2 the A of reduction shaft furnace interior panelling to structural representation.
Detailed description of the invention
Below in conjunction with drawings and Examples, the detailed description of the invention of the present invention is explained in more detail, in order to energy
The advantage being enough more fully understood that the solution of the present invention and its various aspects.But, specific embodiments described below and reality
Executing example is only descriptive purpose rather than limitation of the present invention.
Below in conjunction with accompanying drawing 1, embodiments of the invention are described in further detail.For vanadium titanium in the present embodiment
The molten point stove also original system in ore deposit includes: 1, raw material hopper;2, speed governing batcher;3, smoke evacuation system;4, reduction shaft furnace;5, baffle plate;
6, high-temperature flue gas pipeline;7, feed opening;8, oxygen coal gun;9 molten points of stoves;10, tapping hole.Wherein, raw material hopper, speed governing batcher etc.
Can arrange or be replaced by other device according to actual needs.
Described reduction shaft furnace 4 includes breeze and flux feeding mouth, feed opening 7, smoke inlet, described breeze and flux pan feeding
Mouth is located at the top of described reduction shaft furnace 4, and described feed opening 7 and smoke inlet are located at the bottom of described reduction shaft furnace;Described also
Being provided with the baffle plate 5 of adjustable inclination in the burner hearth of former shaft furnace 4, described baffle plate 5 is located under described breeze and flux feeding mouth, institute
State on feed opening and described smoke inlet;Described baffle plate 5 leaves gap, on described baffle plate 5 with the inwall of described reduction shaft furnace 4
It is disposed with aperture;Described baffle plate 5 is supported on described reduction shaft furnace 4 by the rotating shaft 51 through described reduction shaft furnace 4 furnace wall.Baffle plate
Front view in the reduction shaft furnace 4 of the concrete structure of 5 such as Fig. 2 and the A direction view of Fig. 3.
Owing to the temperature of schreyerite direct-reduction is higher, up to 1350 DEG C, baffle plate 5 material in reduction furnace is generally
Rustless steel such as 2520, its upper limit temperature of heat tolerance only has 1200 DEG C, so have the baffle plate of higher reduction temperature for this kind, needs
Consider that its rational structure designs.The present invention verifies according to the combination of repeatedly theory and practice, is designed by the surfacing of baffle plate 5
Internal according to hollow design for heat-stable ceramic, rotating shaft 51 and baffle plate 5, internal blowing air cools down.Solve the most well
Baffle plate resistant to elevated temperatures confinement problems.
A described molten point stove 9 includes feeding mouth, exhanst gas outlet and discharging opening, and described feeding mouth connects described reduction shaft furnace 4
Feed opening 7, described exhanst gas outlet connects the smoke inlet of described reduction shaft furnace 4.
The lance head of described oxygen coal gun 8 is located in described molten point of stove 9, and described oxygen coal gun 8 is stretched from the furnace roof of described molten point of stove 9
Enter in described molten point of stove 9.
Multiple baffle plate 5 with described inclination angle it is sequentially provided with from top to bottom in the burner hearth of described reduction shaft furnace 4, adjacent described
The vertical centrage of the most described reduction shaft furnace in inclination angle 4 of baffle plate 5 is arranged symmetrically with.
The present invention utilizes breeze at a low price and coal dust to instead of the higher lump ore of price and pellet.
Breeze and flux in raw material hopper 1 can send into direct-reduction shaft furnace by speed governing batcher 2 according to a certain percentage
4, speed governing batcher 2 may be designed as spiral speed regulation batcher, ensures direct-reduction shaft furnace 4 and raw material hopper 1 while feed
Between sealing.
The delivery rate of speed governing batcher 2 depends on the response speed of molten point of stove, and specific targets can be produced by molten point of stove
CO in the flow of raw CO reducing gases and outlet reducing gas2Content determine.Reducing gas flow is big, CO2Content is little, then
Increase feeding coal, otherwise, reduce feeding coal.Generally, the CO that direct-reduction shaft furnace 4 exit detects2Volume contain
Amount is between 15-25%, and the volume content of CO is between 70%-80%, and remaining gas is the minimum gas such as nitrogen, hydrogen.
The baffle plate 5 of adjustable inclination is set in shaft furnace, after breeze enters direct-reduction shaft furnace 4, along baffle plate 5 to dirty
Dynamic, the design principle of controllable register is the longest principle in material path, ensures again the flue gas resistance in direct-reduction shaft furnace 4 simultaneously
Power can not be the biggest.
According to above principle, simultaneously according to baffle plate 5 and the coefficient of friction of breeze, for foursquare reduction shaft furnace, design
0.5-0.95 times of the baffle plate 5 a length of reduction shaft furnace length of side along the incline direction at described inclination angle, preferably about 0.75 times.
Difference in height between the rotary shaft of adjacent screen is 0.2-1.5 times of the reduction shaft furnace length of side, preferably about 0.5 times.Baffle plate 5 with
The range of accommodation of the angle of horizontal plane is defined as 30 °-60 °.The structure of instantiation and size are as shown in Fig. 2 and Fig. 3.In figure
Concrete structure and size are exemplary illustration.Certainly reduction shaft furnace can also be other shape as circular.When reduction shaft furnace is other
Shape time, be also according to the longest principle in material path and consider can not be too big to the flue gas resistance in direct-reduction shaft furnace 4, come
The structure of design baffle plate and arrangement form.
When the angle of baffle plate 5 with horizontal plane is 36 °, total distance of stream is about 2.1 times of reduction shaft furnace 4 height.
Due to frictional force and the impact of collision, material falls to being become the reciprocal downglide motion of low speed by the movement of falling object, with whole process is
The situation (being not provided with baffle plate) of free-falling is compared, and breeze fall time is 5-12 times of free-fall time.Below specifically join
Number can make the appropriate adjustments according to the wind speed in reduction shaft furnace 4 and powder particle size scope.The material of baffle plate 5 is heat-resistance stainless steel.Gear
Plate is disposed with the aperture of diameter 10mm-30mm, and reducibility gas is flow through aperture and reduction shaft furnace and gear by the lower section of reduction shaft furnace 4
Gap between plate 5 flows up, to ensure the contact of breeze and reducibility gas.
Baffle plate 5 have the rotating shaft 51 that baffle plate can be made movable and and reduction shaft furnace between sealing device.Can be on baffle plate 5
If reinforcement 52 is to ensure intensity and the rigidity of baffle plate 5.The rotation of baffle plate 5 can hand-turning also can drive, on baffle plate 5 by machine
Rotation drive rod 53 can be designed with.
Reducibility gas reverse flow in breeze and shaft furnace, breeze is reduced into directly under conditions of high temperature reductive gas
Reduced iron powder, enters molten point of stove 9 by feed opening 7.The high-temperature flue gas outlet of molten point of stove 9 enters after high-temperature flue gas pipeline 6
Direct-reduction shaft furnace 4, high-temperature flue gas pipeline 6 is internal arranges water-cooled flue, enters directly also to control flue gas by controlling the water yield
The temperature of former shaft furnace 4.Associated temperature is different according to the difference of Ore kind, and general range is between 1100 DEG C to 1350 DEG C.
Through direct-reduction furnace rear, passing through and breeze heat exchange, temperature drops between 620 DEG C to 850 DEG C.
The feed opening 7 of direct-reduction shaft furnace 4 is by arranging the facility such as radar level gauge or capacitance material level meter sensing blanking feelings
Condition, prevents feed opening 7 from blocking.If it find that feed opening 7 gathers materials too much, reduce blanking by the delivery rate controlling top
Amount, prevents blocking.
Oxygen coal powder spray gun structure is telescopic water cooled lance, and wherein, middle coal injection, periphery is oxygen, outermost
For cooling circulating water, the head material of oxygen coal gun 8 is copper lance head.
Breeze is during falling to bottom from direct-reduction shaft furnace 4 top, and progressively classification reduction, by regulation breeze
The time of staying in direct-reduction shaft furnace, reduction shaft furnace exit breeze degree of metalization can reach 80% to control its reduction degree
Left and right.Remain unreduced breeze and carry out drastic reduction in molten point of stove 9.
Molten point of stove 9 utilizes the heat of oxygen coal injection burning generation to make metal mining powder melt.Slag and flux shape in the reaction
Become foamed slag.The direct-reduction iron powder that foamed slag charge capture enters, oxygen coal gun 8 immerses in foamed slag simultaneously, makes oxygen, coal dust
Combustion reaction in foamed slag, is used for providing heat.
Oxygen coal gun 8 controls coal combustion rate by the ratio controlling coal dust and oxygen, produces one by improving coal dust ratio
Part unburned coal powder, reacts further with the unreduced breeze of part in unburned coal powder enters foamed slag, makes breeze the most thorough
Reduction.
Molten iron and slag are got rid of from tapping hole 10, realize the outer slag sluicing system of stove through peripheral slag skimmer.Foamed slag leads to simultaneously
Crossing and make the heating-up temperature of oxygen coal gun 8 raise, in finally realizing stove, scum separates.
The present invention can be by the quantity of the proportioning regulation unburned coal powder of regulation coal dust and oxygen, basis in smelting process
Smelting situation utilizes unburned coal powder to adjust in real time to join charcoal ratio.
The present invention uses pure oxygen burning, and the high temperature of generation can meet difficult needs smelting Ore such as schreyerite.
The high-temperature flue gas of molten point of stove 9 can supply direct-reduction shaft furnace 4 with heating reduction breeze, thus realizes waste gas again
Utilize.
It addition, reduced iron must be compressed into hot-pressed iron compact in prior art, it is to prevent pruinescence air-flow from blowing away, and makes smelting
Stove has certain breathability;Present invention utilizes generation foamed slag in molten point of stove and solve problem above.Because available foam
Slag catches powder, utilizes the bigger serface of foamed slag as reflecting carrier and solving the breathability of material.
The regulating measure of the present invention is the most, adjusts including delivery rate regulation, the regulation of blanking speed, amount of oxygen and coal dust amount
Joint, unburned coal powder amount regulation etc., multiple regulating measure has adapted to various state modulator and the adjustment of smelting process, it is ensured that reduction
Effect.
The adjustable baffle plate of the present invention takes high temperature resistant measure, meets the needs of high temperature reduction.
Embodiment
Raw material hopper 1 put into by breeze and a small amount of flux pulverized limestone, is sent by the speed governing batcher 2 of raw material hopper 1 bottom
Entering to be reduced directly shaft furnace 4, whereabouts of progressively sliding above the baffle plate 5 of inclination fallen by breeze.From molten point of stove 9 high temperature CO gas out
Direct-reduction shaft furnace 4 is entered by high-temperature flue gas pipeline 6.High temperature CO gas and breeze reaction, breeze generates direct-reduction iron powder,
Iron powder enters molten point of stove 9 through feed opening 7.Oxygen coal gun 8 burns in stove provides heat and the temperature of reaction needs.Reaction completes
Rear ore deposit liquid and slag are discharged by tapping hole 10 is intermittent.Erect the complete gas of reaction in furnace to be got rid of, under entrance by smoke discharging pipe 3
Road treatment process.
Hereinafter it is specifically described step by step.
The schreyerite powder of particle diameter about 0-1mm is put into hopper according to the part by weight of 10:1 with addition of part pulverized limestone.Ore deposit
The composition of powder such as following table:
Table 1
Element | TFe | Fe<sub>2</sub>O<sub>3</sub> | FeO | V<sub>2</sub>O<sub>5</sub> | TiO<sub>2</sub> |
Content % | 37 | 37.74 | 14.00 | 0.40 | 45.00 |
According to the speed of 2 ton hour, breeze is sent into direct-reduction shaft furnace by the speed governing batcher under hopper.
Baffle plate 5 in regulation shaft furnace so that it is between Angle ambiguity to 40 °-60 °.
In molten point of stove 9, its temperature is controlled to about 1350 DEG C by high-temperature flue gas out by water-cooled flue, subsequently into
Direct-reduction shaft furnace 4, and breeze mixing.CO reaction in breeze and flue gas is reduced into iron powder, enters molten point of stove by feed opening 7
9, DRI meal component such as following table:
Table 2
TFe | MFe | FeO | V<sub>2</sub>O<sub>5</sub> | TiO<sub>2</sub> |
40-42 | 37.31-28 | 5.33-15.62 | 0.45 | 50.38 |
Wherein, the TFe in table 2 refers to total ferrum or full ferrum, and MFe refers to Armco magnetic iron.
Coal dust and pure oxygen spray into molten point of stove 9 by oxygen coal gun, and coal powder blowing amount is set as 1.6 ton hour, and amount of oxygen is
1200Nm3/h.Coal dust composition such as following table:
Table 3
Wherein, the M in table 3adRepresent air-dried moisture;AadRepresent and be dried base ash;VadRepresent air-dried basis to wave
Send out and divide;FCadRepresent air-dried basis fixed carbon.
S in tablet,adRepresent air-dried basis total sulphur content;C represents air-dried basis carbon content;H represents air and is dried
Base hydrogen content;N represents air-dried basis nitrogen content;O represents air-dried basis oxygen content;Qnet.v.arFor higher calorific value.
The ferrum oxide of not thoroughly reduction is reduced by part unburned coal powder further;Control oxygen amount and coal amount, it is ensured that
A molten point in-furnace temperature is 1750 DEG C.
Open tapping hole 10 according to reaction in furnace situation to tap a blast furnace and slag tap in good time.
Hot metal composition such as following table:
Table 4
Fe | C | Si | Mn | P | S | Molten iron temperature |
92.9 | 4.11 | 0.45 | 0.21 | 0.04 | 0.03 | ~1600 |
The composition of slag such as following table:
Table 5
Element | TFe | Fe<sub>2</sub>O<sub>3</sub> | FeO | V<sub>2</sub>O<sub>5</sub> | TiO<sub>2</sub> |
Content % | ~2 | - | - | 0.40 | 85-90 |
As seen from the above-described embodiment, schreyerite powder effectively can be reduced to the ferrum that iron-holder is higher by technical scheme
Water.
It is last that it is noted that obviously above-described embodiment is only for clearly demonstrating example of the present invention, and also
The non-restriction to embodiment.For those of ordinary skill in the field, can also do on the basis of the above description
Go out change or the variation of other multi-form.Here without also cannot all of embodiment be given exhaustive.And thus drawn
What Shen went out obviously changes or changes among still in protection scope of the present invention.
Claims (10)
1., for a molten point of stove also original system of schreyerite, described system includes reduction shaft furnace, molten point of stove and oxygen coal gun, its
In,
Described reduction shaft furnace includes that breeze and flux feeding mouth, feed opening, smoke inlet, described breeze and flux feeding mouth are located at
The top of described reduction shaft furnace, described feed opening and smoke inlet are located at the bottom of described reduction shaft furnace;Described reduction shaft furnace
Be provided with the baffle plate of adjustable inclination in burner hearth, described baffle plate is located under described breeze and flux feeding mouth, described feed opening and
On described smoke inlet;Described baffle plate leaves gap with the inwall of described reduction shaft furnace, and described baffle plate is disposed with aperture;Institute
The surfacing stating baffle plate is heat-stable ceramic;Described baffle plate by the rotating shaft support through described reduction shaft furnace furnace wall in described reduction
On shaft furnace;Described rotating shaft and described baffle plate are hollow structure;
A described molten point stove includes feeding mouth, exhanst gas outlet and discharging opening, and described feeding mouth connects the feed opening of described reduction shaft furnace,
Described exhanst gas outlet connects the smoke inlet of described reduction shaft furnace;
The lance head of described oxygen coal gun is located in described molten point of stove, and described oxygen coal gun stretches into described molten from the furnace roof of described molten point of stove
In dividing stove.
System the most according to claim 1, it is characterised in that be sequentially provided with from top to bottom in the burner hearth of described reduction shaft furnace
Multiple baffle plates with described inclination angle, the vertical centrage symmetry cloth of the most described reduction shaft furnace in inclination angle of adjacent described baffle plate
Put.
System the most according to claim 1, it is characterised in that the angle of described baffle plate and horizontal plane be adjustable as 30 °-
60°;Hole diameter on described baffle plate is 10mm-30mm.
System the most according to claim 1, it is characterised in that described reduction shaft furnace is block furnace, and described baffle plate is along described
0.5-0.95 times of a length of described reduction shaft furnace length of side on the incline direction at inclination angle, the rotary shaft of adjacent described baffle plate is in institute
The distance of the vertical direction stating reduction shaft furnace is 0.2-1.5 times of the described reduction shaft furnace length of side.
System the most according to claim 1, it is characterised in that described baffle plate is positioned at the main body material under described surfacing
Matter is heat-resistance stainless steel;Described baffle plate is provided with sealing device with the junction of described reduction shaft furnace;Described rotating shaft is provided with rotation
Drive rod.
System the most according to claim 1, it is characterised in that the exhanst gas outlet of described molten point of stove is by high-temperature flue gas pipeline
Connecting the gas approach of described reduction shaft furnace, described high-temperature flue gas pipe interior is provided with water-cooled flue.
System the most according to claim 1, it is characterised in that the feed opening of described reduction shaft furnace be provided with radar level gauge or
Capacitance material level meter;Breeze and the flux feeding mouth of described reduction shaft furnace are connected with speed governing batcher.
System the most according to claim 1, it is characterised in that the structure of described oxygen coal gun is telescopic water cooled lance, institute
The material of the lance head stating oxygen coal gun is copper, and the sleeve internal layer of described oxygen coal gun is breeze blowing layer, and intermediate layer is blowing oxygen
Layer, outermost is cooling circulating water layer.
9. utilizing the method that system described in any one of claim 1 to 8 carries out molten point of stove reduction, described method includes step
Rapid:
Breeze and flux are sent into described reduction shaft furnace and carries out reduction reaction, generate reduction breeze;
Described reduction breeze is sent into a described molten point of stove, to described molten point of stove coal injection and oxygen and is made by described oxygen coal gun
Described coal dust and oxygen combustion, obtain the ore deposit liquid after reduction reaction and slag;
The described molten point of high-temperature flue gas that stove produces is passed through described reduction shaft furnace;
Cool down in described rotating shaft and described baffle interior blowing air.
Method the most according to claim 9, it is characterised in that described method further comprises the steps of:
By speed governing batcher governing speed to control described breeze and the feeding amount of flux;
By regulating the proportioning of the coal dust of described oxygen coal gun and oxygen to regulate the quantity of unburned coal powder so that unreduced breeze
Reaction further;
By promoting the heating-up temperature of described oxygen coal gun to realize ore deposit liquid and slag separation in stove, realize stove by peripheral slag skimmer
Outer ore deposit liquid and slag separation;
By the regulation described breeze time of staying in described reduction shaft furnace to control the reduction degree of described breeze;
The temperature in described reduction shaft furnace is entered to control flue gas by controlling the water yield in high-temperature flue gas pipeline;
Ore deposit is regulated by the delivery rate controlling described breeze behind the feed opening of described reduction shaft furnace detection material position further
The feeding amount of powder, to prevent described feed opening from blocking.
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CN106976221A (en) * | 2017-03-14 | 2017-07-25 | 南通苏源化纤有限公司 | A kind of speed-adjustable automatic feed hopper for extrusion spinning |
CN108359762A (en) * | 2018-02-23 | 2018-08-03 | 攀枝花正德环保新材料科技开发有限公司 | Vanadium-titanium magnetite reduction device and vanadium titano-magnetite processing unit (plant) |
CN108359763A (en) * | 2018-02-23 | 2018-08-03 | 攀枝花正德环保新材料科技开发有限公司 | Vanadium titano-magnetite process equipment and processing technology |
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CN106976221A (en) * | 2017-03-14 | 2017-07-25 | 南通苏源化纤有限公司 | A kind of speed-adjustable automatic feed hopper for extrusion spinning |
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CN108359763A (en) * | 2018-02-23 | 2018-08-03 | 攀枝花正德环保新材料科技开发有限公司 | Vanadium titano-magnetite process equipment and processing technology |
CN108359762B (en) * | 2018-02-23 | 2019-10-22 | 攀枝花正德环保新材料科技开发有限公司 | Vanadium-titanium magnetite reduction device and vanadium titano-magnetite processing unit (plant) |
CN108359763B (en) * | 2018-02-23 | 2019-10-22 | 攀枝花正德环保新材料科技开发有限公司 | Vanadium titano-magnetite process equipment and processing technology |
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