CN106057080A - Bus stop billboard - Google Patents
Bus stop billboard Download PDFInfo
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- CN106057080A CN106057080A CN201610679262.4A CN201610679262A CN106057080A CN 106057080 A CN106057080 A CN 106057080A CN 201610679262 A CN201610679262 A CN 201610679262A CN 106057080 A CN106057080 A CN 106057080A
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- billboard
- antistatic coating
- carbon fiber
- copper powder
- copper
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/04—Signs, boards or panels, illuminated from behind the insignia
- G09F13/0404—Signs, boards or panels, illuminated from behind the insignia the light source being enclosed in a box forming the character of the sign
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
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Abstract
The application relates to a bus stop billboard, comprising a support rod, a stop display panel disposed above the support rods, a first billboard and a second billboard disposed on two sides of the support rods, and a power module, a lighting module and a control module disposed in the first and second billboards; the power module, the lighting module and the control module are electrically connected with one another; the surface of the power module, the lighting module and the control module is coated with an antistatic coating.
Description
Technical field
The application relates to billboard field, particularly relates to a kind of bus platform billboard.
Background technology
Go on a journey for convenience of people, be typically provided with public bus network information at bus platform or show bus with billboard
Stop, bus information shows, owing to bus platform flow of the people is relatively big, therefore bus platform has become as the input of vast businessman
The first-selection of advertisement.
Existing bus platform billboard the most only has advertisement dynamic display of functional, owing to display device is that a kind of electronics sets
Standby, passenger frequently contacts, and can form electrostatic on surface, affects the normal work of billboard.
Currently for antistatic coating, it is presented below as development trend: develop the addition type antistatic coating of high performance-price ratio,
And reach preferable anti-static effect, be on the one hand exploitation high conductivity, low cost novel conductive fillers, to replace
The precious metal materials such as silver, nickel, copper；On the other hand it is the electric conductivity improving addition type conductive filler, to keep the thing of original matrix
Reason-chemical property, the most still facing a lot of problem for efficient conductive filler needs to solve.
Summary of the invention
It is desirable to provide a kind of bus platform billboard, to solve problem set forth above.
Embodiments of the invention provide a kind of bus platform billboard, including support bar, is located at above support bar
Platform display board, the billboard one being located at support bar both sides and billboard two, the power supply being located in billboard one and billboard two
Module, lighting module and control module；Described power module, lighting module and control module electrically connect each other；Described electricity
Source module, lighting module and control module surface-coated have antistatic coating.
The technical scheme that embodiments of the invention provide can include following beneficial effect:
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect, thus solves problem set forth above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not constitute any limit to the present invention
System, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to the following drawings
Other accompanying drawing.
Fig. 1 is the structural representation of billboard of the present invention.
Fig. 2 is the preparation flow figure of antistatic coating of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Electrostatic coatings is a kind of functional coating, and it can conduct electric charge and can get rid of stored charge, say, that electrostatic
The existing antistatic property of coating, has again the barrier propterty of coating itself.The U.S. is the earliest in the conducting resinl patent that 1948 announce
Disclosed electrically-conducting paint；In early days, mainly based on silver system and carbon system anti-static coatings.
Along with the R and D of antistatic coating, Related product is more and more abundanter, its building industry, electron trade,
Furniture industry, aviation and military field application are wide.At present, antistatic coating is divided into Intrinsical and addition type, and Intrinsical resists
Electrostatic coatings is to be film forming matter by the polymer itself with electric conductivity, but, it is high that preparation cost prepared by this kind of coating, and application is relatively
Few；Addition type antistatic coating is to add certain conductive filler in nonconducting resin itself to realize static conductive function, its
Being formed conductive network in resin by conductive filler, embody electric conductivity, current conductive filler mainly has: carbon-based material, metal mold
Powder, metal-oxide, conducting nanoparticles and antistatic additive etc..
Currently for antistatic coating, it is presented below as development trend: develop the addition type antistatic coating of high performance-price ratio,
And reach preferable anti-static effect, be on the one hand exploitation high conductivity, low cost novel conductive fillers, to replace
The precious metal materials such as silver, nickel, copper；On the other hand it is the electric conductivity improving addition type conductive filler, to keep the thing of original matrix
Reason-chemical property, the most still facing a lot of problem for efficient conductive filler needs to solve.
Application scenarios one:
Fig. 1 shows a kind of bus platform billboard that embodiments herein relates to, and including support bar 1, is located at support
Platform display board 2 above bar, the billboard 1 being located at support bar 1 both sides and billboard 24, it is located at billboard 1 and advertisement
Power module, lighting module and control module in board 24；Described power module, lighting module and control module are each other
Electrical connection；Described power module, lighting module and control module surface-coated have antistatic coating.
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree
Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth
Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with
Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule
Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon
Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating
Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber
Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h
Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into
In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container,
By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2
Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol
0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth
Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum,
It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere
120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling
The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon
Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will
It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds
Amount mass ratio is 10～16%, when copper powder and copper carbon fiber mass ratio are 3:4, and the surface resistivity of described antistatic coating
It is 0.5～1.5 × 107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios two:
Fig. 1 shows a kind of bus platform billboard that embodiments herein relates to, and including support bar 1, is located at support
Platform display board 2 above bar, the billboard 1 being located at support bar 1 both sides and billboard 24, it is located at billboard 1 and advertisement
Power module, lighting module and control module in board 24；Described power module, lighting module and control module are each other
Electrical connection；Described power module, lighting module and control module surface-coated have antistatic coating.
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree
Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth
Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with
Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule
Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon
Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating
Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber
Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h
Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into
In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container,
By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2
Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol
0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth
Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum,
It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere
120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling
The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon
Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will
It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds
Amount mass ratio is 10%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is
0.5×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios three:
Fig. 1 shows a kind of bus platform billboard that embodiments herein relates to, and including support bar 1, is located at support
Platform display board 2 above bar, the billboard 1 being located at support bar 1 both sides and billboard 24, it is located at billboard 1 and advertisement
Power module, lighting module and control module in board 24；Described power module, lighting module and control module are each other
Electrical connection；Described power module, lighting module and control module surface-coated have antistatic coating.
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree
Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth
Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with
Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule
Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon
Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating
Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber
Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h
Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into
In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container,
By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2
Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol
0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth
Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum,
It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere
120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling
The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon
Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will
It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds
Amount mass ratio is 12%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is
0.7×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios four:
Fig. 1 shows a kind of bus platform billboard that embodiments herein relates to, and including support bar 1, is located at support
Platform display board 2 above bar, the billboard 1 being located at support bar 1 both sides and billboard 24, it is located at billboard 1 and advertisement
Power module, lighting module and control module in board 24；Described power module, lighting module and control module are each other
Electrical connection；Described power module, lighting module and control module surface-coated have antistatic coating.
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree
Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth
Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with
Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule
Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon
Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating
Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber
Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h
Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into
In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container,
By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2
Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol
0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth
Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum,
It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere
120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling
The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon
Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will
It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds
Amount mass ratio is 14%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is
1.1×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Application scenarios five:
Fig. 1 shows a kind of bus platform billboard that embodiments herein relates to, and including support bar 1, is located at support
Platform display board 2 above bar, the billboard 1 being located at support bar 1 both sides and billboard 24, it is located at billboard 1 and advertisement
Power module, lighting module and control module in board 24；Described power module, lighting module and control module are each other
Electrical connection；Described power module, lighting module and control module surface-coated have antistatic coating.
The present invention is provided with antistatic coating on power module, lighting module and the control module surface of billboard, its surface
Resistivity is relatively low, possesses good antistatic effect.
Preferably, described antistatic coating is formed by antistatic coating coating, and described antistatic coating uses unsaturation tree
Fat is base material, containing cis-butenedioic anhydride in described unsaturated-resin, and phthalic anhydride, disodiumedetate poly-400, propylene glycol, ethylene glycol, fourth
Enediol, NaOH, dibutyl tin laurate, MEHQ.
In antistatic coating involved by the application, unsaturated-resin is base material, is that the aqueous of a kind of ultraviolet light polymerization is coated with
Material, described unsaturated-resin side base contains the highly polar groups such as ether, hydroxyl, carboxyl, can produce conductive ion, become macromolecule
Electrolyte, the surface resistivity of described unsaturated-resin is 5.2 × 109Ω/cm2。
Preferably, described antistatic coating uses copper powder and copper carbon fiber to be filler, described copper powder and described coppered carbon
Fiber quality is than for 3:4, and described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
In the antistatic coating of the application, copper powder uniformly mixes with copper carbon fiber, is internally formed two dimension conduction at coating
Network, reduces the surface resistivity of antistatic coating further.
Preferably, such as Fig. 2, the making step of described antistatic coating is as follows:
Step one, Treatment of Carbon:
Carbon fiber is cut into 2～5mm, is then immersed in 10h in acetone soln, then with deionized water to carbon fiber
Clean 3～5 times；At room temperature, the carbon fiber after cleaning is immersed in concentrated nitric acid, takes out, then use deionized water after 1h
Repeatedly clean, next put into oscillation cleaning 1h in supersonic cleaning machine, at 100 DEG C, be dried 2h；Dried carbon fiber is put into
In magnetic control sputtering device, 10-4It is deposited with one layer of copper film at carbon fiber surface under Pa base vacuum, obtains copper carbon fiber；
Step 2, process copper powder:
50ml dehydrated alcohol concentrated hydrochloric acid solution is formulated in clean container, then weighs 25g copper powder and put in container,
By solution stirring 1h, it is purified, then rinse 3 times with ether and dehydrated alcohol, until by-product HCl and CuCl2
Clean from Copper Powder Surface, then copper powder is placed in vacuum drying oven, take out standby after being dried 12h；
Step 3, prepares unsaturated-resin:
Take cis-butenedioic anhydride 0.44mol, phthalic anhydride 0.06mol, poly-400 0.145mol of disodiumedetate, propylene glycol
0.12mol, ethylene glycol 0.18mol, butylene glycol 0.05mol, add 0.3mol NaOH, 0.1% catalyst dibutyltin cinnamic acid two fourth
Ji Xi, the polymerization inhibitor MEHQ mixing of 5/10000ths, fill this blend in the 250ml there-necked flask of band water knockout drum,
It is placed in conduction oil, electric stirring, 160 DEG C of nitrogen atmospheres react 60min；It is warmed up to 180 DEG C, melt polymerization in nitrogen atmosphere
120min, then it is warming up to 195 DEG C, in nitrogen atmosphere, melt polymerization is 60 to acid number, is cooled to 100 DEG C and pours out, obtains after cooling
The transparent unsaturated-resin of buff；
Step 4, prepares antistatic coating:
First weigh unsaturated-resin 100ml, add 5g copper powder and copper carbon fiber, be sufficiently mixed, add 3% silicon
Alkane coupling agent, by mixture mechanical agitation, obtains antistatic coating.
Preferably, the antistatic coating prepared being coated in target object surface, coating thickness is 1～3 μm, then will
It irradiates under distance ultraviolet source 10cm and makes curing of coatings.
Show it is further preferred that antistatic coating involved by the application to be carried out antistatic test, when copper powder adds
Amount mass ratio is 16%, and when copper powder and copper carbon fiber mass ratio are 3:4, the surface resistivity of described antistatic coating is
1.5×107Ω/cm2；After 60 days, aging resistance test shows, surface resistivity variable quantity is less than 5%.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (3)
1. a bus platform billboard, including support bar, is located at the platform display board above support bar, is located at support bar both sides
Billboard one and billboard two, power module, lighting module and the control module be located in billboard one and billboard two；Institute
State power module, lighting module and control module to electrically connect each other；It is characterized in that, described power module, lighting module
Antistatic coating is had with control module surface-coated.
Billboard the most according to claim 1, it is characterised in that described antistatic coating coats shape with antistatic coating
Becoming, described antistatic coating is with unsaturated-resin as base material, with copper powder and copper carbon fiber as filler.
Billboard the most according to claim 2, it is characterised in that described copper powder and described copper carbon fiber mass ratio are 3:
4, described copper powder size is 200 mesh, and described copper carbon fiber copper film thickness is 110nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610679262.4A CN106057080A (en) | 2016-08-16 | 2016-08-16 | Bus stop billboard |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610679262.4A CN106057080A (en) | 2016-08-16 | 2016-08-16 | Bus stop billboard |
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Family
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| CN102807808A (en) * | 2012-08-07 | 2012-12-05 | 衡阳恒缘电工材料有限公司 | Unsaturated resin varnish and preparation method thereof |
| CN202615737U (en) * | 2012-05-30 | 2012-12-19 | 郑州圣光照明工程有限公司 | Explosion-proof type oil and gas product indicating lamp box |
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| CN204667807U (en) * | 2015-06-02 | 2015-09-23 | 宿迁市艾伦特科技有限公司 | A kind of bus platform billboard |
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2016
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| CN202615737U (en) * | 2012-05-30 | 2012-12-19 | 郑州圣光照明工程有限公司 | Explosion-proof type oil and gas product indicating lamp box |
| CN102807808A (en) * | 2012-08-07 | 2012-12-05 | 衡阳恒缘电工材料有限公司 | Unsaturated resin varnish and preparation method thereof |
| CN104448676A (en) * | 2014-12-29 | 2015-03-25 | 安徽瑞研新材料技术研究院有限公司 | Metal macromolecule alloy shielding material and machining process thereof |
| CN204667807U (en) * | 2015-06-02 | 2015-09-23 | 宿迁市艾伦特科技有限公司 | A kind of bus platform billboard |
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Application publication date: 20161026 |