CN105970125A - Molding method for improving room-temperature plasticity of metal glass component - Google Patents
Molding method for improving room-temperature plasticity of metal glass component Download PDFInfo
- Publication number
- CN105970125A CN105970125A CN201610099865.7A CN201610099865A CN105970125A CN 105970125 A CN105970125 A CN 105970125A CN 201610099865 A CN201610099865 A CN 201610099865A CN 105970125 A CN105970125 A CN 105970125A
- Authority
- CN
- China
- Prior art keywords
- metal glass
- module
- temperature
- glass component
- plasticity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Powder Metallurgy (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The invention discloses a molding method for improving the room-temperature plasticity of a metal glass component. The method has key technology that two measures of a mold-filling narrow channel and large mold-filling pressure are utilized to provide a subcooled liquid with a large enough deformation ratio and a high rheological rate during a mold-filling process, so that highly-dispersed local micro-areas having significant differences of microstructures and properties are triggered to form in the component after molding. When serving a load, the component enables a high-density shear belt to be started, so that the plasticity is obviously improved and brittle failure is prevented. The method mainly comprises: leading a pulse large current in a metal glass blank to make the temperature of the metal glass blank quickly rise to a subcooled liquid phase region and to make the metal glass blank become a subcooled liquid and to be softened; under the function of the mold-filling pressure, making the subcooled liquid pass through a pre-made mold-filling narrow channel at a high speed and to be injected in a cavity module; and performing molding to obtain the metal glass component with required shape and size. The method is easy to operate, saved in energy and free of pollution, needs no vacuum condition, and is particularly suitable for producing a metal glass component with high plasticity requirement and complicated shape.
Description
Technical field
The invention belongs to metal glass component and manufacture field shaping technique, particularly relate to a kind of raising metal glass component room temperature
The forming method of plasticity.
Background technology
Metal glass (also known as non-crystaline amorphous metal) has the performance more excellent than conventional corresponding crystal alloy material, such as pole
High intensity (close to theoretical value), good elastic performance (elastic limit is about 2%), good corrosion resistance, Flouride-resistani acid phesphatase energy
Power and anti-wear performance etc., be that a class range of application constantly expands and the new function material of great potential and structural material.So
And, one of bottleneck of restriction metal glass material range of application is its temperature-room type plasticity the lowest even plastic-less deformation ability.But,
Metal glass material has brittleness at room temperature, easily forms crackle when applying external force and exceeding its yield strength and causes moment crushing
Fracture, leaves serious potential safety hazard；Additionally, due to its relatively low thermal conductivity, higher hardness, the machining of metal glass
Poor-performing, it is impossible to obtained the workpiece of accurate complicated shape by conventional mechanical processing technique, thus seriously constrain metal
The engineer applied that glass material is actual.In order to reverse this situation, people have done lot of experiments and have worked and propose multiple
Effective ways, are broadly divided into following two aspect:
On the one hand, in order to improve the temperature-room type plasticity of metal glass, researchers or take to introduce the second crystal and form amorphous/crystalline substance mutually
Composite material, or by microalloying, change over distribution ratio and regulate and control alloying component, or use precompressed, cold rolling and shot-peening etc.
Mechanically deform means are to methods such as the prefabricated small shear bands of metal glass material.Such as, Johnson seminar in 2000
(Physical Review Letters 84.13 (2000): 2901-2904) is first at Zr-Ti-Cu-Ni-Be non-crystaline amorphous metal
In situ introduce Ti-Zr-Nb crystal the second phase on matrix, this crystal can not only stop mutually localization shear band Quick Extended,
Promote the generation of more shear band, moreover it is possible to participate in energy dissipation and plastic deformation by producing the sliding of dislocation, thus improve whole
The plasticity of individual material；2007, seminar of Wang Wei China of the Chinese Academy of Sciences (Science 315 (2007): 1385-1388) was by adjusting
Zr-Cu-Al-Ni block amorphous alloy composition, introduces the soft or hard district of microinhomogeneities micro-nano-scale in other words, successfully prepares
Go out the compression plasticity superplastic alloy system more than 150%；2010, M.H. Lee et al. (Scripta Materialia
62.9 (2010): 678-681) to Zr44Ti11Cu9.8Ni10.2Be25And Zr55Ti5Al10Cu20Bulk amorphous alloy carries out the coldest
Roll, prefabricated a large amount of micro-nano-scale shear bands, thus obtain bigger temperature-room type plasticity.
Regrettably, relevant with disordered state structure lower thermal conductivity and high rigidity are still present in these gold strengthening plasticity
Belong in glass material so that they are still difficult to be made into required engineering component by conventional mach mode, thus
Weaken the using value of its reality.
On the other hand, in order to obtain the metal glass component of desired shape, people generally use thermoplastic forming processes,
First metal glass is heated to its supercooling liquid phase region with certain speed so that it is show low viscosity rheological behaviour, one
Determine under load effect, be pressed in the copper mold chamber being pre-designed, obtain the metal glass part of required form after cooling.Should
Method can mold tens nanometers to centimeter-scale, different metal glass part, such as: Jan Schroers etc.
People (Nature 457.7231 (2009): 868-872) success imprints out diameter on porous alumina membrane and is about 13 nm
Metal glass rod, and on the silicon chip etched in advance, produce diameter be about the amorphous gear of 300 μm；William L.
Johnson et al. (Scripta Materialia 60.3 (2009): 160-163) is by Ф 19 х 20 mm's
Zr35Ti30Be27.5Cu7.5Bulk amorphous alloy rod is pressed into 2 х 10 х 60 mm lath-shapeds exactly.
But, conventional heating means can not provide the rate of heat addition (generally less than 1.67 DEG C/s) faster, adds
Thermoplastic forming processes used relatively low strain rate (generally less than 10 in the past-1 s-1) so that whole forming process is taken
Between longer, this results in bulk amorphous alloy generation major structural relaxation, even crystallization, causes hot-short phenomenon, causes its temperature-room type plasticity
And fracture strength substantially reduces.As far back as 2007, Takamasa Yoshikawa et al. (Key Engineering
Materials Vols. 340-341 (2007) pp 113-118) by bulk amorphous alloy Zr55Cu30Al10Ni5Carry out thermoplastic
Property molding research, find: after experiencing 676 K thermoplastic moldings, this fast body amorphous room temperature compressed rupture strength is from as cast condition 1500
MPa is down to 200 MPa suddenly, even if under lower temperature 667 K, its fracture strength also reduces 100 MPa, shows conventional thermoplastic
Property forming method has the negative effect can not ignore to bulk amorphous alloy mechanical property.
It is important to note that 2011, William L. Johnson et al. (Science 332.6031
(2011): 828-833) to Pd43Cu27Ni10P20Bulk amorphous alloy passes to big pulse current, and the most time-consuming 3 ms are the most successfully heated
To supercooling liquid phase region (~ 720 K), 20 MPa side crops industry are used just to be compressed into circular amorphous component, whole forming process
Only used time 40 ms.This unusual heating means have more than 1 х 105The rate of heat addition of K/s, substantially reduces into
The type time so that hot-short phenomenon is avoided, remain original as cast condition amorphous fracture strength, but, how to improve bulk amorphous alloy
The brittleness at room temperature of component intrinsic does not has been resolved in the above-mentioned methods.
In sum, how to strengthen metal glass temperature-room type plasticity and to be effectively made into engineering component be to realize metal glass
Shifting to an earlier date of the real engineer applied of glass, is also the big target of Study on Metallic Glass two.Although research both at home and abroad and invention be not achieved with
Few progress and positive effect, but realize this two big target the most simultaneously, it is possible to simply and efficiently obtain high-ductility metal glass structure
Part remains an outstanding question, is badly in need of method and technical innovation.
Summary of the invention
For disadvantages described above or the Improvement requirement of prior art, the invention provides a kind of raising metal glass component room temperature
The forming method of plasticity, uses and fills type narrow passage and big mold filling pressure two aspect measure, make subcooled liquid in cavity filling process
Obtain sufficiently large deformation ratio and high rheological rate, thus after causing molding, material is internally formed microstructure and character tool
The local microcell of many highly disperseds distribution that there were significant differences, when military service load effect, these microcells will promote to cut in a large number
Cut band to be formed, and then metal glass component temperature-room type plasticity is greatly improved.The present invention obtains metal glass by a series of research
The moulding process that glass is optimal, can be that commercial production provides technique to instruct.
To achieve these goals, the present invention adopts the following technical scheme that
1 one kinds of forming methods improving metal glass component temperature-room type plasticity, it is characterised in that
Operation according to the following steps:
(1) pre-set in filling type narrow passage module and narrower fill type passage；
(2) block metal glass stock is prepared, it is ensured that its cross-sectional uniformity is consistent；
(3) metal glass blank prepared by (2) is placed in punch module and fills between type narrow passage module, it is ensured that laminating is closely；
Punch module is connected respectively with die cavity module positive pole and the negative pole of Current Heating module；
(4) mold filling pressure that compression module pre-add on drift is suitable is utilized；
(5) starting impulse electric current heating module, selects adequate impulse current parameters；Pulse current depends on from pulse power positive pole
Secondary flow through punch module, metal glass blank, fill type narrow passage module, die cavity module, return to pulse power negative pole and constitute complete
Loop；Uniformly through Joule heat produced by the pulse current of metal glass billet cross section, metal glass blank is quickly heated
To supercooling liquid phase region, reach predetermined forming temperature；
(6) under the effect of mold filling pressure, metal glass blank, at a high speed by filling type narrow passage, injects die cavity module and is allowed to fill
Full；
(7) close stream of pulses heating module, after being cooled to room temperature, shed mold filling pressure, obtain metal glass component.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that described narrower fill type
The ratio that narrow passage amasss with metal glass billet cross section is 1:2 ~ 1:16.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that added mold filling pressure is
100~500 MPa；Pressuring method can be to use oil pressure, pneumatic or other modes.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that suitable in step (5)
Pulse current parameter is warming up to supercooling liquid phase region in needing to make metal glass blank 1 ~ 5 ms, reaches predetermined forming temperature.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that it is characterized in that, molding
Temperature: glass transition temperature is 1 ~ 1.2.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that block metal glass embryo
Material is for have the simple lamellar of geometry of uniform crosssection, bar-shaped or block blank.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that described bulk metal glass
Glass blank can be following any one or combination: Zr base, Ti base, Cu base, Mg base, Pd base, Ni base, Fe base, La base
Or Ce base.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that step (4) pre-add is suitable
The method of mold filling pressure, can be the spring adjusting certain compression ratio, it is also possible to be other conventional mechanical pressure method.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that heating pulse electric current returns
Between road and upper mold module, insulating with potsherd or other insulant, during ensureing electrified regulation, upper mold module will not be burnt
Melt and destroy.
Described a kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that metal glass stock is adopted
Prepare with any one in following method: water quenching, melt casting method, melt suction casting method, high temperature insostatic pressing (HIP) powder sintering or
Prepared by arbitrary known methods such as person's electric spark powder sintering.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that described fill type narrow passage with
The ratio that metal glass billet cross section amasss is 1:2 ~ 1:16, to ensure to trigger in cavity filling process subcooled liquid drastic deformation.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that added mold filling pressure is according to tool
Body metal glass material character and determine, generally 100 ~ 500 MPa, fill type speed with obtain superelevation；Pressuring method is permissible
Use oil pressure, pneumatic or other modes.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that use big Current Heating
Method, i.e. passes to big pulse current to metal glass blank, is warming up to supercooling liquid phase region in being allowed to 1 ~ 5 ms.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that applicable forming temperature according to
Concrete non-crystaline amorphous metal system glass transition temperature and determine, it may be assumed that forming temperature/glass transition temperature approximates 1 ~ 1.2.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that block metal glass stock is
There is the simple lamellar of geometry of uniform crosssection, bar-shaped or block blank.
A kind of forming method improving metal glass component temperature-room type plasticity, it is characterised in that described block metal glass base
Material can be any one or combination: Zr base, Ti base, Cu base, Mg base, Pd base, Ni base, Fe base, La base or Ce
Base.
A kind of forming method improving metal glass parts temperature-room type plasticity, it is characterised in that the side of its preset mold filling pressure
Method, can be the spring adjusting certain compression ratio, it is also possible to be other conventional mechanical pressure method.
A kind of forming method improving metal glass parts temperature-room type plasticity, it is characterised in that heating pulse current loop with
Between mould, insulate with potsherd or other insulant, ensure during electrified regulation mould will not scorification and destroy.
A kind of forming method improving metal glass parts temperature-room type plasticity,
(1) first by metal glass blank clamping the most well prepared in advance in upper mold module, and to blank above
Punch module preset suitable mold filling pressure.Before metal glass blank heating, owing to it is in room temperature rigid solid state,
Set pressure is not result in that it has any deformation or displacement；
(2) blank is heated rapidly to supercooling liquid phase region by the big electric current of make pulse, and it is special that glass blank is immediately transferred to have rheology
Property subcooled liquid, under mold filling pressure effect, the subcooled liquid that blank is formed is injected lower mold module with high rheological rate
Shaping die cavity in, final quickly cooling obtains metal glass component.
Above-mentioned (1), (2) is characterized in that, is to fill type narrow passage, its section between upper mold module and lower mold module
Area is sufficiently small with the ratio of upper mold sectional area, and according to stock volume and metal glass characteristic, its ratio ranges is 1:2 ~ 1:16,
It is to ensure that cavity filling process forms sufficiently large deformation one of ratio and the high key of rheological rate；
Above-mentioned (1), (2) is characterized in that, preset mold filling pressure is sufficiently high, be obtain superelevation the key filling type speed it
Two, added mold filling pressure determines, in the range from 100 ~ 500 MPa according to concrete metal glass material character.
The equipment that the present invention uses is as it is shown in figure 1, described metal glass blank 5 is vertically placed among upper mold module 6, and leads to
Cross insulation module 4 to be allowed to and upper mold module 6 electric insulation；Described punch module 6, fill type narrow passage module 2 respectively with metal glass
Glass blank 5 upper end and lower end are connected and ensure that laminating is closely；Described die cavity module 1 be placed in fill under type narrow passage module 2 and with
Fit tightly；Described Current Heating module 3 both positive and negative polarity is connected to punch module 7, die cavity module 1, is sent
Pulse current flows through punch module 7, metal glass blank 5 successively from Current Heating module 3 positive pole, fills type narrow passage
Module 2, die cavity module 1 to Current Heating module 3 negative pole, constitute complete loops；Described compression module 8 is placed in punch module
On 7, to provide desirable pressure to punch module 7.
It is in place of the method for present invention raising different from the past metal glass temperature-room type plasticity: the present invention can not only be notable
Strengthen the temperature-room type plasticity of metal glass material, metal glass blank can also synchronize to make the metal glass of desired shape simultaneously
Glass component, it is achieved the integrated molding of high-ductility metal glass component；Using this method to make metal glass component can be direct
Carrying out in atmosphere, the metal glass component not only dimensional accuracy made is high, surface roughness is low, and surface-brightening, anaerobic
Change.
It is in place of present invention thermoplastic forming processes different from the past: the present invention uses and fills type narrow passage and big fill type
Pressure two aspect measure, makes subcooled liquid obtain sufficiently large deformation ratio and high rheological rate in cavity filling process, thus
After causing molding, material is internally formed microstructure and character has the local microcell that many highly disperseds of significant difference are distributed.
Result shows, this method is possible not only to be made to precisely metal glass blank the component of required form, size, more can be notable
Ground improves the brittleness at room temperature of metal glass component intrinsic, it is thus achieved that the metal glass component of high-ductility, thus improves metal glass material
The engineer applied value that material is actual.
Accompanying drawing explanation
Fig. 1 is the equipment principle schematic diagram of the present invention；
Wherein: 1. die cavity module, type narrow passage module, 3. Current Heating module, 4. insulation module, 5. metal glass are 2. filled
Blank, 6. upper mold module, 7. punch module, 8. compression module.
Fig. 2 is the process flow diagram of the present invention.
Fig. 3 is the schematic diagram of present example 1.
Fig. 4 is XRD and the DSC collection of illustrative plates of present example 1.
Fig. 5 is metal glass material room temperature compressive stress strain curve before and after present example 1 molding.
Fig. 6 is metal glass material nano hardness scattergram before and after present example 1 molding.
Fig. 7 is the schematic diagram of present example 2.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, right
The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, and
It is not used in the restriction present invention.
Embodiment 1
As it is shown on figure 3, the present embodiment is with Zr57Ti5Al10Cu20Ni8The bar-shaped stock of (atomic percent) block metal glass is 415
At DEG C as a example by coining game money, specifically comprise the following steps that
1, in filling type narrow passage module 2, pre-set diameter 1.5～4mm, long 5～15mm fill type passage；
2, by high pure metal element by composition proportion, the metal glass rod of diameter 6mm, cutting polishing are cast through vacuum melting suction
Growth 15mm～25mm metal glass blank 5；
3, game money to be imprinted is placed in advance in die cavity module 1；
4, metal glass blank 5 it is placed in punch module 7 and fills between type narrow passage module 2, and ensureing to fit tightly；By drift
Module 7 is connected positive pole and the negative pole of Current Heating module 3 respectively with die cavity module 1；
5, the mold filling pressure of compression module 8 pre-add 200～250MPa is utilized；
6, unbalanced pulse electric current heating module 3, selects suitable pulse current parameter, by metal glass blank heating in 3ms
To 415 DEG C；After end to be formed, it is turned off；
7, after being cooled to room temperature, shed the mold filling pressure on compression module 8, take out metal glass component, as shown in Figure 3.
In the present embodiment after metal glass blank and molding the amorphous structure of metal glass workpiece by X x ray diffraction
And means of differential scanning calorimetry (DSC) method determines, as shown in Figure 4 (XRD).
In the present embodiment after metal glass blank and molding the temperature-room type plasticity of metal glass workpiece all on universal testing machine
It is compressed test to determine, as shown in Figure 5.
In this example, before and after the molding of metal glass blank, the change of micro-structural properties is measured by nano-hardness tester, and result is such as
Shown in Fig. 6.
Embodiment 2
As it is shown in fig. 7, the present embodiment is with Zr48Cu36Al8Ag8The bar-shaped stock of (atomic percent) block metal glass is at 495 DEG C
As a example by compacted under is gear and screw element, specifically comprise the following steps that
1, pre-setting diameter 1.5 ~ 4 mm in filling type narrow passage module 2, long 5 ~ 15 mm fill type passage；
2, by high pure metal element by composition proportion, casting the metal glass rod of diameter 6 mm through vacuum melting suction, cutting is beaten
Wear into long 15 mm ~ 25 mm metal glass blanks 5；
3, in lower mold 1, gear and screw-like die cavity it are pre-designed；
4, metal glass blank 5 it is placed in punch module 7 and fills between type narrow passage module 2, and ensureing to fit tightly；By drift
Module 7 is connected positive pole and the negative pole of Current Heating module 3 respectively with die cavity module 1；
5, the mold filling pressure of compression module 8 pre-add 200 ~ 250 MPa is utilized；
6, unbalanced pulse electric current heating module 3, selects suitable pulse current parameter, by metal glass blank heating in 3 ms
To 495 DEG C；After end to be formed, it is turned off；
7, after being cooled to room temperature, shed the mold filling pressure on compression module 8, take out metal glass component, as shown in Figure 7.
In the present embodiment after metal glass blank and molding the amorphous structure of metal glass workpiece still by X x ray diffraction
(XRD) and means of differential scanning calorimetry (DSC) method determines, result is similar with Fig. 4 in example 1, is amorphous state before and after showing molding
Structure, the most no longer accompanying drawing explanation.
In the present embodiment after metal glass blank and molding the temperature-room type plasticity of metal glass workpiece still on universal testing machine
Being compressed test to determine, result shows, after molding the plasticity of metal glass material from 0.1% (as cast condition) be substantially increased to
2.2%, improve more than 20 times.Due to length reason, the most no longer accompanying drawing explanation.
Claims (10)
1. the forming method improving metal glass component temperature-room type plasticity, it is characterised in that
Operation according to the following steps:
(1) pre-set in filling type narrow passage module and narrower fill type passage；
(2) block metal glass stock is prepared, it is ensured that its cross-sectional uniformity is consistent；
(3) metal glass blank prepared by (2) is placed in punch module and fills between type narrow passage module, it is ensured that laminating is closely；
Punch module is connected respectively with die cavity module positive pole and the negative pole of Current Heating module；
(4) mold filling pressure that compression module pre-add on drift is suitable is utilized；
(5) starting impulse electric current heating module, selects adequate impulse current parameters；Pulse current depends on from pulse power positive pole
Secondary flow through punch module, metal glass blank, fill type narrow passage module, die cavity module, return to pulse power negative pole and constitute complete
Loop；Uniformly through Joule heat produced by the pulse current of metal glass billet cross section, metal glass blank is quickly heated
To supercooling liquid phase region, reach predetermined forming temperature；
(6) under the effect of mold filling pressure, metal glass blank, at a high speed by filling type narrow passage, injects die cavity module and is allowed to fill
Full；
(7) close stream of pulses heating module, after being cooled to room temperature, shed mold filling pressure, obtain metal glass component.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that described
The narrower ratio filling type narrow passage long-pending with metal glass billet cross section is 1:2 ~ 1:16.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that added by fill
Type pressure is 100 ~ 500 MPa；Pressuring method can be to use oil pressure, pneumatic or other modes.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that step
(5) the adequate impulse current parameters in is warming up to supercooling liquid phase region in needing to make metal glass blank 1 ~ 5 ms, reaches to make a reservation for into
Type temperature.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that its feature
Being, forming temperature/glass transition temperature is 1 ~ 1.2.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that block gold
Belonging to glass raw material is to have the simple lamellar of geometry of uniform crosssection, bar-shaped or block blank.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that described piece
Body metal glass blank can be following any one or combination: Zr base, Ti base, Cu base, Mg base, Pd base, Ni base, Fe
Base, La base or Ce base.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that step
(4) method of the mold filling pressure that pre-add is suitable, can be the spring adjusting certain compression ratio, it is also possible to be that other conventional mechanical adds
Pressure method.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that heating arteries and veins
Rush between current loop and upper mold module, insulate with potsherd or other insulant, ensure upper mold mould during electrified regulation
Block will not scorification and destroy.
A kind of forming method improving metal glass component temperature-room type plasticity the most as claimed in claim 1, it is characterised in that metal
Prepared by any one in the glass raw material following method of employing: water quenching, melt casting method, melt suction casting method, high temperature insostatic pressing (HIP) powder
Prepared by end arbitrary known method such as sintering process or electric spark powder sintering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610099865.7A CN105970125B (en) | 2016-02-23 | 2016-02-23 | A kind of forming method for improving glassy metal component temperature-room type plasticity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610099865.7A CN105970125B (en) | 2016-02-23 | 2016-02-23 | A kind of forming method for improving glassy metal component temperature-room type plasticity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105970125A true CN105970125A (en) | 2016-09-28 |
| CN105970125B CN105970125B (en) | 2017-11-10 |
Family
ID=56988637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610099865.7A Active CN105970125B (en) | 2016-02-23 | 2016-02-23 | A kind of forming method for improving glassy metal component temperature-room type plasticity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105970125B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111515248A (en) * | 2020-04-24 | 2020-08-11 | 燕山大学 | Vacuum electric rolling device and method for online adjusting roughness of iron-based amorphous strip |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067191A (en) * | 2007-06-15 | 2007-11-07 | 清华大学 | Pd Ni-Si-P block amorphous alloys and producing method thereof |
| US20080302775A1 (en) * | 2004-09-17 | 2008-12-11 | Noble Advanced Technologies, Inc. | Metal forming apparatus and process with resistance heating |
| CN202671600U (en) * | 2012-07-11 | 2013-01-16 | 山东大学 | Device for improving plasticity of bulk amorphous alloy and structural component of bulk amorphous alloy at room temperature |
| CN103962434A (en) * | 2014-05-07 | 2014-08-06 | 华中科技大学 | Electroplastic forming method for block metallic glass and device thereof |
-
2016
- 2016-02-23 CN CN201610099865.7A patent/CN105970125B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080302775A1 (en) * | 2004-09-17 | 2008-12-11 | Noble Advanced Technologies, Inc. | Metal forming apparatus and process with resistance heating |
| CN101067191A (en) * | 2007-06-15 | 2007-11-07 | 清华大学 | Pd Ni-Si-P block amorphous alloys and producing method thereof |
| CN202671600U (en) * | 2012-07-11 | 2013-01-16 | 山东大学 | Device for improving plasticity of bulk amorphous alloy and structural component of bulk amorphous alloy at room temperature |
| CN103962434A (en) * | 2014-05-07 | 2014-08-06 | 华中科技大学 | Electroplastic forming method for block metallic glass and device thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111515248A (en) * | 2020-04-24 | 2020-08-11 | 燕山大学 | Vacuum electric rolling device and method for online adjusting roughness of iron-based amorphous strip |
| CN111515248B (en) * | 2020-04-24 | 2021-08-03 | 燕山大学 | Vacuum electric rolling device and method for online adjusting roughness of iron-based amorphous strip |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105970125B (en) | 2017-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69823966T2 (en) | METHOD AND DEVICE FOR PRODUCING METALLIC GLASSES | |
| CN103233190B (en) | Method for preparing semisolid blank | |
| EP3530772B1 (en) | Plastic forming and toughening process method and apparatus based on ultrasonic vibration | |
| CN101338391B (en) | Quick setting block aluminum alloy with high strength and high ductibility and toughness and method for preparing same | |
| CN106238552B (en) | High-duty pulsatile impact hydraulic forming method | |
| CN104015009B (en) | A kind of mobile phone center, the preparation method of bonnet | |
| CN103447432B (en) | A kind of isothermal forging process of large scale magnesium alloy parts | |
| US10946448B2 (en) | Cold additive and hot forging combined forming method of amorphous alloy parts | |
| CN102029381A (en) | Processing and forming method for workpieces made of blocky metal glass or composite material of blocky metal glass | |
| CN101792906A (en) | Bionic coupling method for processing machinery parts by local laser melting and consolidation | |
| CN102029299B (en) | Multidirectional combined type circulating upsetting device and upsetting method | |
| JPH1176475A (en) | Golf club | |
| CN101812628A (en) | Fe-Ga based magnetostrictive wire and preparation method thereof | |
| CN206169020U (en) | Highduty pulse impact hydroforming equipment | |
| CN108517477A (en) | A kind of ultra-fine crystallization gradient control method of depth taper copper conic liner tissue | |
| CN110273119A (en) | A kind of uniform grain refining preparation method of tantalum alloy material echelon incremental deformation | |
| CN101829771A (en) | Forming method of block-shaped amorphous composite material | |
| CN105970125B (en) | A kind of forming method for improving glassy metal component temperature-room type plasticity | |
| CN102029300A (en) | Back-pressure four-way reciprocating heading device and processing method thereof | |
| Wang et al. | Influence of twist extrusion process on consolidation of pure aluminum powder in tubes by equal channel angular pressing and torsion | |
| CN108994299A (en) | A kind of heating of powder metallurgy superalloy element stages squeezes control property device and application method | |
| CN105970130B (en) | A kind of method that alternately backward extrusion prepares fine grain magnesium alloy | |
| CN109127756B (en) | Extrusion die and extrusion method for high-strength magnesium alloy | |
| CN103725921A (en) | Special high-performance alloy copper rod for hot punching | |
| CN1332058C (en) | Prepn of rod superfine crystal material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190122 Address after: 224500 Xin'an Avenue 779-3, Binhai Medical Industrial Park, Yancheng City, Jiangsu Province Patentee after: Jiangsu Chaotic New Materials Technology Co., Ltd. Address before: 230009 No. 193, Tunxi Road, Hefei, Anhui Patentee before: Hefei University of Technology |