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CN105970115A - Economical high-performance copper-containing free-cutting austenitic stainless steel alloy material - Google Patents

Economical high-performance copper-containing free-cutting austenitic stainless steel alloy material Download PDF

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Publication number
CN105970115A
CN105970115A CN201610372423.5A CN201610372423A CN105970115A CN 105970115 A CN105970115 A CN 105970115A CN 201610372423 A CN201610372423 A CN 201610372423A CN 105970115 A CN105970115 A CN 105970115A
Authority
CN
China
Prior art keywords
alloy material
stainless steel
austenitic stainless
performance
steel alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610372423.5A
Other languages
Chinese (zh)
Inventor
徐裕来
李钧
张华伟
彭伟
武昭妤
肖学山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINGHUA SPECIAL STAINLESS STEEL INSTITUTE OF SHANGHAI UNIVERSITY
Original Assignee
XINGHUA SPECIAL STAINLESS STEEL INSTITUTE OF SHANGHAI UNIVERSITY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINGHUA SPECIAL STAINLESS STEEL INSTITUTE OF SHANGHAI UNIVERSITY filed Critical XINGHUA SPECIAL STAINLESS STEEL INSTITUTE OF SHANGHAI UNIVERSITY
Priority to CN201610372423.5A priority Critical patent/CN105970115A/en
Publication of CN105970115A publication Critical patent/CN105970115A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses an economical high-performance copper-containing free-cutting austenitic stainless steel alloy material. The economical high-performance copper-containing free-cutting austenitic stainless steel alloy material comprises, by mass percent, larger than or equal to 0.1% and smaller than or equal to 0.15% of C, 16.0%-18.0% of Cr, 1.4%-3.4% of Ni, 0.15%-0.35% of N, smaller than or equal to 0.75% of Si, larger than or equal to 8.0% and smaller than or equal to 12.0% of Mn, smaller than or equal to 0.04% of P, smaller than or equal to 0.03% of S, larger than or equal to 1.0% and smaller than or equal to 2.5% of Cu, and the balance Fe and inevitable impurities. The alloy material has good cutting performance and also has good hot working performance, and the alloy material has excellent corrosion resisting performance in the chloridion-enriched environment.

Description

A kind of economical high-performance cupric Cutting free austenitic stainless steel alloy material
Technical field
The present invention relates to a kind of economical high-performance cupric Cutting free austenitic stainless steel alloy material, belong to steel and alloy material Material technical field.
Background technology
Austenitic stainless steel has excellent combination property and is widely used, but is as product cutting processing Automatization and high speed development, the bad cutting ability of austenitic stainless steel causes that cutlery service life reduction, production efficiency are low, adds Work high in cost of production problems.In order to improve the cutting ability of austenitic stainless steel, can be by improving the sulfur in steel further Content.But the raising of sulfur content, will reduce the hot-working character of stainless steel material and the corrosion resistant in rich chloride environment Erosion performance.Therefore, sulfur content brings up to a certain degree, in terms of cutting ability for be useful, and to decay resistance and Hot-working aspect is disadvantageous.
Summary of the invention
It is an object of the invention to provide and a kind of not only there is good cutting ability, and there is preferable hot-workability The economical high-performance cupric Cutting free austenitic stainless steel alloy material of energy.
The present invention is achieved by the following technical solution:
A kind of economical high-performance cupric Cutting free austenitic stainless steel alloy material, it has following composition and percent mass Than (%): 0.1≤C≤0.15, Cr:16.0-18.0, Ni:1.4-3.4, N:0.15-0.35, Si≤0.75,8.0≤Mn≤ 12.0, P≤0.04, S≤0.03,1.0≤Cu≤2.5, surplus is Fe and inevitable impurity.
Its production technology comprises the following steps: uses the induction melting process that tradition is conventional, after dispensing is founded, waters Injection forming, forge hot, 980-1050 ° of C annealing, isothermal holding;Temperature retention time is according to the effective thickness of alloy material, every 1mm Carry out according to the standard of 1.5min.
Its production technology also includes Ageing Treatment step: by above-mentioned austenitic stainless steel alloy material again at 720-780 ° of C Carry out Ageing Treatment 2-4 hour, allow nanoscale Cu Rich Phase Precipitation.
Adding copper alloying element in austenitic stainless steel of the present invention, copper is austenitic formation and stable element, can be substantially Improve the stability of austenite.A certain amount of copper can improve the intensity of low-alloy steel in steel, improves the resistance to of austenitic stainless steel Corrosive nature, improves processing characteristics.The present invention adds copper in austenitic stainless steel, coordinates the heat treatment work after optimizing Skill, the alloy material more excellent to obtain combination property by separating out nano level copper-rich precipitated phase in austenitic matrix. Steel room temperature tensile tensile strength in the range of present component is in 830-850MPa scope, and yield strength is at 380-390MPa model Enclosing, fracture elongation is more than 53%.
The mechanism of the present invention is as described below: copper is austenitic formation and stable element, can significantly improve stablizing of austenite Property.In austenitic stainless steel, add copper, nano level copper-rich phase can be separated out after Ageing Treatment in austenitic matrix, change Kind hot-working character and cutting ability.
The present invention compared with prior art has the advantages that
1, the present invention is possible not only to improve the cutting ability of austenitic stainless steel, and the heat that can improve austenitic stainless steel adds Work performance, overcomes the defect improved reducing austenitic stainless steel material hot-working character of sulfur content in prior art.
2, the austenitic stainless steel alloy material of the present invention has the decay resistance of excellence in rich chloride environment.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the invention will be further described.
Embodiment 1: a kind of economical high-performance cupric Cutting free austenitic stainless steel alloy material, it has following one-tenth Divide and mass percent (%):
Cr 16.7%
Ni 2.1%
Cu 1.4%
N 0.24%
Mn 10.1%
C 0.12%
Si 0.32%
S 0.02%
P 0.01%
Fe surplus
Its production technology comprises the following steps: uses the induction melting process that tradition is conventional, after comprehensive dispensing is founded, waters Injection forming, through forge hot and 1050 ° of C annealings, isothermal holding, temperature retention time is pressed according to the effective thickness of alloy material, every 1mm Standard according to 1.5min is carried out, then through 720 ° of C Ageing Treatment 3 hours, and final to prepare economical high-performance cupric Cutting free difficult to understand Family name's body stainless steel alloy material.This alloy material room temperature tensile tensile strength 845 MPa, yield strength 390 MPa, extension Rate 53%.
Embodiment 2: a kind of economical high-performance cupric Cutting free austenitic stainless steel alloy material, it has following one-tenth Divide and mass percent (%):
Cr 17.5%
Ni 2.8%
Cu 2.2%
N 0.27%
Mn 11.2%
C 0.13%
Si 0.37%
S 0.01%
P 0.01%
Fe surplus
Its production technology comprises the following steps: uses the induction melting process that tradition is conventional, after comprehensive dispensing is founded, waters Injection forming, through forge hot and 1000 ° of C annealings, isothermal holding, temperature retention time is pressed according to the effective thickness of alloy material, every 1mm Standard according to 1.5min is carried out, then through 750 ° of C Ageing Treatment 3 hours, and final to prepare economical high-performance cupric Cutting free difficult to understand Family name's body stainless steel alloy material.This alloy material room temperature tensile tensile strength 830 MPa, room-temperature yield strength 380 MPa, fracture Elongation percentage 55%.
The present invention has good structure stability, cutting ability and decay resistance.The cupric Cutting free of the present invention is difficult to understand Family name's body stainless steel alloy material is better than 203S rustless steel in terms of machinability and economy is more significantly.
Embodiment, only to facilitate understand technical scheme, is not intended that the limit to scope System, every without departing from any letter perhaps according to the technical spirit of the present invention, above scheme made in technical solution of the present invention Single amendment, equivalent variations and modification, within all still falling within scope.

Claims (3)

1. an economical high-performance cupric Cutting free austenitic stainless steel alloy material, it is characterised in that: it has following Composition and mass percent (%): 0.1≤C≤0.15, Cr:16.0-18.0, Ni:1.4-3.4, N:0.15-0.35, Si≤ 0.75,8.0≤Mn≤12.0, P≤0.04, S≤0.03,1.0≤Cu≤2.5, surplus is Fe and inevitable impurity.
Economical high-performance cupric Cutting free austenitic stainless steel alloy material the most according to claim 1, its feature exists In: its production technology comprises the following steps: uses the induction melting process that tradition is conventional, after dispensing is founded, pours into Type, forge hot, 980-1050 ° of C annealing, isothermal holding;Temperature retention time according to the effective thickness of alloy material, every 1mm according to The standard of 1.5min is carried out.
Economical high-performance cupric Cutting free austenitic stainless steel alloy material the most according to claim 2, its feature exists In: its production technology also includes Ageing Treatment step: when being carried out at 720-780 ° of C by above-mentioned austenitic stainless steel alloy material again Effect processes 2-4 hour.
CN201610372423.5A 2016-05-31 2016-05-31 Economical high-performance copper-containing free-cutting austenitic stainless steel alloy material Pending CN105970115A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610372423.5A CN105970115A (en) 2016-05-31 2016-05-31 Economical high-performance copper-containing free-cutting austenitic stainless steel alloy material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610372423.5A CN105970115A (en) 2016-05-31 2016-05-31 Economical high-performance copper-containing free-cutting austenitic stainless steel alloy material

Publications (1)

Publication Number Publication Date
CN105970115A true CN105970115A (en) 2016-09-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498285A (en) * 2016-11-30 2017-03-15 中国科学院金属研究所 A kind of austenite antimicrobial stainless steel without the need for Ageing Treatment
CN110607479A (en) * 2019-04-24 2019-12-24 上海大学 Stainless steel for valve spring and preparation method of steel wire of stainless steel
CN111809124A (en) * 2020-07-23 2020-10-23 深圳市富鹏达金属材料有限公司 Low-cost nonmagnetic alloy steel

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1213013A (en) * 1997-07-29 1999-04-07 于西纳公司 Austenitic stainless steel having very low nickel content
CN1554795A (en) * 2003-12-27 2004-12-15 张体勇 High antibiotic property stainless steel
CN1995435A (en) * 2006-12-29 2007-07-11 东莞市星宇特殊钢材有限公司 Austenite magnet-free rustless cut-easy steel
CN101878319A (en) * 2007-11-29 2010-11-03 Ati资产公司 Lean austenitic stainless steel
WO2014097184A2 (en) * 2012-12-19 2014-06-26 Centro Sviluppo Materiali S.P.A. Austenitic stainless steel with high twinning induced plasticity, process for the production thereof and use thereof in the mechanical industry

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1213013A (en) * 1997-07-29 1999-04-07 于西纳公司 Austenitic stainless steel having very low nickel content
CN1554795A (en) * 2003-12-27 2004-12-15 张体勇 High antibiotic property stainless steel
CN1995435A (en) * 2006-12-29 2007-07-11 东莞市星宇特殊钢材有限公司 Austenite magnet-free rustless cut-easy steel
CN101878319A (en) * 2007-11-29 2010-11-03 Ati资产公司 Lean austenitic stainless steel
WO2014097184A2 (en) * 2012-12-19 2014-06-26 Centro Sviluppo Materiali S.P.A. Austenitic stainless steel with high twinning induced plasticity, process for the production thereof and use thereof in the mechanical industry

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498285A (en) * 2016-11-30 2017-03-15 中国科学院金属研究所 A kind of austenite antimicrobial stainless steel without the need for Ageing Treatment
CN106498285B (en) * 2016-11-30 2019-02-12 中国科学院金属研究所 A kind of austenite antimicrobial stainless steel without ageing treatment
CN110607479A (en) * 2019-04-24 2019-12-24 上海大学 Stainless steel for valve spring and preparation method of steel wire of stainless steel
CN110607479B (en) * 2019-04-24 2021-11-05 上海大学 Stainless steel for valve spring and preparation method of steel wire of stainless steel
CN111809124A (en) * 2020-07-23 2020-10-23 深圳市富鹏达金属材料有限公司 Low-cost nonmagnetic alloy steel

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Application publication date: 20160928