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CN105820681A - Reflective thermal-insulation real stone paint and preparation method thereof - Google Patents

Reflective thermal-insulation real stone paint and preparation method thereof Download PDF

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Publication number
CN105820681A
CN105820681A CN201610330424.3A CN201610330424A CN105820681A CN 105820681 A CN105820681 A CN 105820681A CN 201610330424 A CN201610330424 A CN 201610330424A CN 105820681 A CN105820681 A CN 105820681A
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CN
China
Prior art keywords
mineral varnish
true mineral
reflective insulation
rotating speed
parts
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610330424.3A
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Chinese (zh)
Inventor
王月琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HANGZHOU MAKEDOLLAR ENVIRONMENTAL PROTECTION NEW MATERIAL Co Ltd
Original Assignee
HANGZHOU MAKEDOLLAR ENVIRONMENTAL PROTECTION NEW MATERIAL Co Ltd
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Application filed by HANGZHOU MAKEDOLLAR ENVIRONMENTAL PROTECTION NEW MATERIAL Co Ltd filed Critical HANGZHOU MAKEDOLLAR ENVIRONMENTAL PROTECTION NEW MATERIAL Co Ltd
Priority to CN201610330424.3A priority Critical patent/CN105820681A/en
Publication of CN105820681A publication Critical patent/CN105820681A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to building materials and discloses reflective thermal-insulation real stone paint .The reflective thermal-insulation real stone paint comprises, by weight, 30-40 parts of water-based polymer emulsion, 20-25 parts of deionized water, 4-9 parts of hollow glass microbeads, 3-6 parts of sepiolite, 6-12 parts of pigment filler, 3-9 parts of dispersant, 5-8 parts of an anti-foaming agent, 3-9 parts of a flatting agent, 2-8 parts of a coalescing agent, 0.2-0.6 part of mildew preventive M-8 and 8-16 parts of colored sand .The invention further discloses a preparation method of the reflective thermal-insulation real stone paint .The reflective thermal-insulation real stone paint has the advantages that natural color and luster of natural real stone are achieved, and the reflective thermal-insulation effect is good.

Description

True mineral varnish of reflective insulation and preparation method thereof
Technical field
The present invention relates to structure material, relate to a kind of true mineral varnish of reflective insulation, particularly related to the preparation method of the true mineral varnish of reflective insulation.
Background technology
External reflective heat-insulation paint starting relatively early, is studied the most deep, is made great progress.The forties in 20th century, U.S. Alexander Schwartz et al. introduces the air that heat conductivity is low between multilayer aluminum film, makes composite, started the research of reflective heat-insulation paint.Phase late 1970s, along with the fast development of science and technology, radiation heat insulation and reflective insulation technology also achieve huge progress.
The also existing substantial amounts of research of the watersoluble insulating mold coating for construction of China, and achieve bigger achievement.Liu Xianchun et al. develops a kind of heat-reflecting insulating coating, and this coating is with acrylic acid alkyd based resin as film forming matter, and the filler of addition has Rutile type titanium dioxide, zinc oxide and mica powder, and when coating layer thickness is 20-30um, reflectance i.e. can reach 80%.One of developing Gu Xiaoming et al. can reflect various length ultraviolet line and ultrared insulating moulding coating, and reflectance can be high by 80%.The above institute obtains true mineral varnish and is mainly used in roofing; play roof waterpoof material protection and reduce the effect that temperature rises; but when exterior wall, it is impossible to prevent the polyphenyl plate heat preserving layer in external wall outer insulation body from producing cracking because of the acute variation of the external environment temperature difference, coming off.
Summary of the invention
The present invention is in order to make up the deficiencies in the prior art, it is provided that a kind of natural colour with natural real stone has again the true mineral varnish of reflective insulation of certain heat insulation property, additionally provides the preparation method of the true mineral varnish of reflective insulation.
In order to solve above-mentioned technical problem, the present invention is addressed by following technical proposals:
The true mineral varnish of reflective insulation, calculates by weight, and its raw materials used composition and content are as follows:
As preferably, aqueous polymer emulsion is acrylic emulsion or silicone acrylic emulsion.
As preferably, color stuffing is titanium dioxide or nano silicon.
As preferably, dispersant is sodium tripolyphosphate.
As preferably, defoamer is polyoxyethylene polyoxypropylene glycerin ether or polydimethylsiloxane or polyoxyethylene polyoxy propanol amidogen ether.
As preferably, levelling agent is alkyl-modified organosiloxane or polyester modified organic siloxane or PSI.
As preferably, coalescents is Lauryl Alcohol ester.
The preparation method of the true mineral varnish of above-mentioned reflective insulation, specifically includes following steps:
1) by weight, first deionized water, dispersant are joined in Scattered Kettle, the rotating speed of regulation Scattered Kettle is to 800~1000rpm, stirring 6min, is then adjusted to 700rpm by rotating speed, is added by 1/2 defoamer in Scattered Kettle, then regulation rotating speed is to 600~800rpm, it is slowly added to color stuffing, stirs 5min, obtain slurry A;
2) in slurry A, it is slowly added to aqueous polymer emulsion, coalescents and 1/2 defoamer, continues stirring 15~20min;Then regulation rotating speed is to 400~500rpm, adds antifungus agent M-8, levelling agent, meerschaum, hollow glass micropearl, stirs 8~10min, regulate rotating speed again and add color sand to 600rpm, stir 5min, finally rotating speed is adjusted to 200~300rpm, continue stirring 15min, prepare the true mineral varnish of reflective insulation.
Due to the fact that and have employed above technical scheme, there is significant technique effect: utilize reflective insulation principle, by adjusting formula, hollow glass micropearl and the meerschaum with heat insulation and radiation-resisting functional is introduced in traditional true mineral varnish, compared to the true mineral varnish only added obtained by hollow glass micropearl, its radiation resistance is greatly improved, and with the addition of infrared external reflection color stuffing, further adds the reflective insulation performance of true mineral varnish;Dispersant improves the dispersive property of aqueous polymer emulsion;Defoamer penetrates into the elasticity destroying gas in foam system, suppresses and destroy the generation of foam;Levelling agent can effectively reduce surface tension of liquid, increases spreadability, makes film forming uniform, natural;Antifungus agent M-8 properties of product while having the effect of sterilization and anticorrosion are stable, safety and environmental protection;Color sand makes true mineral varnish have colourful color, and can not fade.The present invention prepares the true mineral varnish of gained and had both had the effect of imitative stone material, has again certain heat insulation property, is a kind of novel building energy-saving material having many uses, and market prospect is good.
Further, effects of energy saving and emission reduction is notable, the heat preservation and insulation of architectural reflective heat-insulation paint, and energy consumption of air conditioning system in buildings can be made to decline more than 20% (referring mainly to the cold areas to the south of Xia Redong);Reduce city haze in a large number;Reduce secondary transformation building waste, additionally, the application of architectural reflective heat-insulation paint, replace or partly instead of the application of warming plate, therefore decrease the produced building waste of secondary transformation that warming plate technique is brought, improve the environment protecting of reconstruction of existing building.
Detailed description of the invention
Example below is that the present invention is described in further detail, but is not to limit the scope of the present invention.
Embodiment 1
The true mineral varnish of reflective insulation of the present invention, calculates by weight, and its raw materials used composition and content are as follows:
The preparation method of the true mineral varnish of above-mentioned reflective insulation, specifically includes following steps:
1) by weight, first deionized water, sodium tripolyphosphate STTP are joined in Scattered Kettle, the rotating speed of regulation Scattered Kettle is to 800rpm, stirring 6min, is then adjusted to 700rpm by rotating speed, is added by 1/2 polyoxyethylene polyoxypropylene glycerin ether in Scattered Kettle, then regulation rotating speed is to 650rpm, it is slowly added to titanium dioxide, stirs 5min, obtain slurry A;
2) in slurry A, it is slowly added to acrylic emulsion, Lauryl Alcohol ester and 1/2 polyoxyethylene polyoxypropylene glycerin ether, continues stirring 15min;Then regulation rotating speed is to 500rpm, adds antifungus agent M-8, alkyl-modified organosiloxane, meerschaum, hollow glass micropearl, stirs 9min, regulate rotating speed again and add color sand to 600rpm, stir 5min, finally rotating speed is adjusted to 200rpm, continue stirring 15min, prepare the true mineral varnish of reflective insulation.
Embodiment 2
The true mineral varnish of reflective insulation of the present invention, calculates by weight, and its raw materials used composition and content are as follows:
The preparation method of the true mineral varnish of above-mentioned reflective insulation, specifically includes following steps:
1) by weight, first deionized water, sodium tripolyphosphate STTP are joined in Scattered Kettle, the rotating speed of regulation Scattered Kettle is to 1000rpm, stirring 6min, is then adjusted to 700rpm by rotating speed, is added by 1/2 polydimethylsiloxane in Scattered Kettle, then regulation rotating speed is to 800rpm, it is slowly added to titanium dioxide, stirs 5min, obtain slurry A;
2) in slurry A, it is slowly added to silicone acrylic emulsion, Lauryl Alcohol ester and 1/2 polydimethylsiloxane, continues stirring 20min;Then regulation rotating speed is to 420rpm, adds antifungus agent M-8, polyester modified organic siloxane, meerschaum, hollow glass micropearl, stirs 10min, regulate rotating speed again and add color sand to 600rpm, stir 5min, finally rotating speed is adjusted to 300rpm, continue stirring 15min, prepare the true mineral varnish of reflective insulation.
Embodiment 3
The true mineral varnish of reflective insulation of the present invention, calculates by weight, and its raw materials used composition and content are as follows:
The preparation method of the true mineral varnish of above-mentioned reflective insulation, specifically includes following steps:
1) by weight, first deionized water, sodium tripolyphosphate STTP are joined in Scattered Kettle, the rotating speed of regulation Scattered Kettle is to 900rpm, stirring 6min, is then adjusted to 700rpm by rotating speed, is added by 1/2 polyoxyethylene polyoxy propanol amidogen ether in Scattered Kettle, then regulation rotating speed is to 600rpm, it is slowly added to nano titanium oxide, stirs 5min, obtain slurry A;
2) in slurry A, it is slowly added to silicone acrylic emulsion, Lauryl Alcohol ester and 1/2 polyoxyethylene polyoxy propanol amidogen ether, continues stirring 18min;Then regulation rotating speed is to 400rpm, adds antifungus agent M-8, polymethyl-benzene base Siloxanes, meerschaum, hollow glass micropearl, stir 8min, then regulates rotating speed to adding color sand after 600rpm, stirs 5min, rotating speed is finally adjusted to 230rpm, continue stirring 15min, prepare the true mineral varnish of reflective insulation.
The product reflective insulation true mineral varnish the performance test results of the present invention is as shown in table 1
The product reflective insulation true mineral varnish the performance test results of table 1 present invention
In a word, the foregoing is only presently preferred embodiments of the present invention, all impartial changes made according to scope of the present invention patent and modification, all should belong to the covering scope of patent of the present invention.

Claims (8)

1. the true mineral varnish of reflective insulation, it is characterised in that count by weight, including following components:
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: aqueous polymer emulsion is third Olefin(e) acid emulsion or silicone acrylic emulsion.
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: color stuffing is titanium dioxide or receives Rice silicon dioxide.
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: dispersant is sodium tripolyphosphate.
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: defoamer is that polyoxypropylene gathers Oxygen Ethylene Glycol ether or polydimethylsiloxane or polyoxyethylene polyoxy propanol amidogen ether.
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: levelling agent is alkyl-modified to have Organic siloxane or polyester modified organic siloxane or PSI.
The true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that: coalescents is Lauryl Alcohol Ester.
The preparation method of the true mineral varnish of reflective insulation the most according to claim 1, it is characterised in that include following Step:
1) by weight, first joining in Scattered Kettle by deionized water, dispersant, the rotating speed of regulation Scattered Kettle is extremely 800~1000rpm, stir 6min, then rotating speed is adjusted to 700rpm, 1/2 defoamer is added Scattered Kettle In, then regulation rotating speed is to 600~800rpm, is slowly added to color stuffing, stirs 5min, obtains slurry A;
2) in slurry A, it is slowly added to aqueous polymer emulsion, coalescents and 1/2 defoamer, continues stirring 15~20 min;Then regulation rotating speed is to 400~500rpm, adds antifungus agent M-8, levelling agent, meerschaum, hollow Glass microballoon, stirs 8~10min, then regulates rotating speed to adding color sand after 600rpm, stirs 5min, After rotating speed is adjusted to 200~300rpm, continue stirring 15min, prepare the true mineral varnish of reflective insulation.
CN201610330424.3A 2016-05-17 2016-05-17 Reflective thermal-insulation real stone paint and preparation method thereof Pending CN105820681A (en)

Priority Applications (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349855A (en) * 2016-08-31 2017-01-25 铃鹿复合建材(上海)有限公司 Reflective thermal insulating really stone paint
CN106519865A (en) * 2016-11-29 2017-03-22 安徽美琳建筑材料有限公司 Quick-dry stone-like coating special for interior architecture wall surfaces
CN106634093A (en) * 2016-12-05 2017-05-10 青岛天源伟业保温防水工程有限公司 Environmental-friendly heat-preservation insect expelling coating
CN107383952A (en) * 2017-08-23 2017-11-24 重庆索利特涂料有限公司 A kind of true mineral varnish of heat preservation energy-saving and preparation method thereof
CN107572903A (en) * 2017-09-21 2018-01-12 苏州振振好新型建材科技有限公司 A kind of high-performance radiation proof exterior wall true stone paint
CN107603289A (en) * 2017-09-21 2018-01-19 苏州振振好新型建材科技有限公司 A kind of preparation method of high-performance radiation proof exterior wall true stone paint

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1326933B1 (en) * 2000-10-03 2007-08-15 CPS Color Equipment S.p.A. con unico socio A reflective paint and a method for its use
CN104109439A (en) * 2014-07-28 2014-10-22 漳州三德利油漆涂料有限公司 Heat preserving really stone paint and preparation method thereof
CN104293056A (en) * 2014-10-08 2015-01-21 杭州潮头建材有限公司 Water-based colorful real stone-type stone-like coating and production process thereof
CN104356810A (en) * 2014-11-21 2015-02-18 苏州大乘环保建材有限公司 Reflective thermal insulation real stone paint
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1326933B1 (en) * 2000-10-03 2007-08-15 CPS Color Equipment S.p.A. con unico socio A reflective paint and a method for its use
CN104109439A (en) * 2014-07-28 2014-10-22 漳州三德利油漆涂料有限公司 Heat preserving really stone paint and preparation method thereof
CN104293056A (en) * 2014-10-08 2015-01-21 杭州潮头建材有限公司 Water-based colorful real stone-type stone-like coating and production process thereof
CN104356810A (en) * 2014-11-21 2015-02-18 苏州大乘环保建材有限公司 Reflective thermal insulation real stone paint
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof

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Title
王菲: "海泡石族矿物纤维材料的解束处理及应用研究", 《中国优秀硕士论文全文数据库》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349855A (en) * 2016-08-31 2017-01-25 铃鹿复合建材(上海)有限公司 Reflective thermal insulating really stone paint
CN106519865A (en) * 2016-11-29 2017-03-22 安徽美琳建筑材料有限公司 Quick-dry stone-like coating special for interior architecture wall surfaces
CN106634093A (en) * 2016-12-05 2017-05-10 青岛天源伟业保温防水工程有限公司 Environmental-friendly heat-preservation insect expelling coating
CN107383952A (en) * 2017-08-23 2017-11-24 重庆索利特涂料有限公司 A kind of true mineral varnish of heat preservation energy-saving and preparation method thereof
CN107572903A (en) * 2017-09-21 2018-01-12 苏州振振好新型建材科技有限公司 A kind of high-performance radiation proof exterior wall true stone paint
CN107603289A (en) * 2017-09-21 2018-01-19 苏州振振好新型建材科技有限公司 A kind of preparation method of high-performance radiation proof exterior wall true stone paint

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