CN105801932A - Rubber threading plug and preparation process thereof - Google Patents
Rubber threading plug and preparation process thereof Download PDFInfo
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- CN105801932A CN105801932A CN201610239066.5A CN201610239066A CN105801932A CN 105801932 A CN105801932 A CN 105801932A CN 201610239066 A CN201610239066 A CN 201610239066A CN 105801932 A CN105801932 A CN 105801932A
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- wire passing
- agent
- softening agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/242—Applying crosslinking or accelerating agent onto compounding ingredients such as fillers, reinforcements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2309/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a rubber threading plug and a preparation process thereof, and belongs to the technical field of rubber product processing.The rubber threading plug is prepared from, by mass, 90-110 parts of crude rubber NBR1052, 40-60 parts of carbon black N550, 20-40 parts of carbon black N774, 3-7 parts of softener DOP, 1-2.5 parts of softener RD, 1-2.5 parts of softener MB, 0.5-1.2 parts of softener WAX, 3-7 parts of compounding agent ZnO-A, 1-2.5 parts of adhesive SA, 2-4 parts of adhesive 1102, 0.5-1.2 parts of S, 1-2.5 parts of vulcanizing agent TT and 1-3 parts of vulcanizing agent CZ.The raw materials are sequentially subjected to mixing, vulcanizing forming, finishing and secondary vulcanizing to obtain the rubber threading plug finished product.The rubber threading plug is moderate in elasticity, can allow a wire to easily penetrate through, can also have a good sealing effect and is high in wear resistance, and the service life is greatly prolonged.
Description
Technical field
The invention belongs to rubber processing technique field, be specifically related to a kind of rubber wire passing plug and system thereof
Standby technique.
Background technology
Wire passing plug is mainly used in electric wire process of deployment fixing electric wire and protecting, initial wire passing plug
For plastic material, it can be fixed protection to wire, but requires the occasion of sealing at some,
Owing to the hardness of plastic material is relatively big, the worn diameter of wire is necessarily less than through wires hole, the use of wire passing plug
Can not reach the use requirement sealed, the use of rubber wire passing plug can solve the problem that this problem, but existing
The elasticity of some rubber wire passing plug can not make electric wire pass well, and the elasticity of life-time service can be increasingly
Difference, sealing effectiveness cannot be steady in a long-term, and service life is shorter.
Summary of the invention
The shortcoming that instant invention overcomes prior art, it is provided that a kind of rubber wire passing plug and preparation technology thereof,
This rubber wire passing plug elasticity is moderate, and wearability is good, elastically keeps preferably, and sealing effectiveness is stable, compares
In existing rubber wire passing plug, significantly extend service life.
The concrete technical scheme of the present invention is:
A kind of rubber wire passing plug, the through wires hole that this wire passing plug is provided through in the axial direction, crucial
Point is that the raw material preparing this wire passing plug includes carrying out 90-110 part rubber of proportioning according to mass fraction
NBR1052,40-60 part white carbon black N550,20-40 part white carbon black N774,3-7 part softening agent DOP, 1-2.5
Part softening agent RD, 1-2.5 part softening agent MB, 0.5-1.2 part softening agent WAX, 3-7 part compounding ingredient
ZnO-A, 1-2.5 part binding agent SA, 2-4 part binding agent 1102,0.5-1.2 part S, 1-2.5 part sulfur
Agent TT, 1-3 part vulcanizing agent CZ.
The described raw material preparing this wire passing plug includes carry out proportioning according to mass fraction 100 parts
NBR1052,50 parts of white carbon black N550,30 parts of white carbon black N774,5 parts of softening agent DOP, 1.5 parts of softening agents
RD, 1.5 parts of softening agent MB, 0.8 part of softening agent WAX, 5 parts of compounding ingredient ZnO-A, 1.5 parts of binding agents
SA, 1102,0.8 part of S of 3 parts of binding agents, 1.5 parts of vulcanizing agent TT, 2 parts of vulcanizing agent CZ.
The described raw material preparing this wire passing plug includes carry out proportioning according to mass fraction 90 parts
NBR1052,45 parts of white carbon black N550,25 parts of white carbon black N774,5 parts of softening agent DOP, 1.5 parts of softening agents
RD, 1.5 parts of softening agent MB, 1 part of softening agent WAX, 6 parts of compounding ingredient ZnO-A, 1.8 parts of binding agents
SA, 1102,1 part of S of 2 parts of binding agents, 2 parts of vulcanizing agent TT, 2 parts of vulcanizing agent CZ.
The described raw material preparing this wire passing plug includes carry out proportioning according to mass fraction 100 parts
NBR1052,60 parts of white carbon black N550,40 parts of white carbon black N774,7 parts of softening agent DOP, 2 parts of softening agents
RD, 1.5 parts of softening agent MB, 1 part of softening agent WAX, 3 parts of compounding ingredient ZnO-A, 1 part of binding agent SA,
1102,1.2 parts of S of 2 parts of binding agents, 2 parts of vulcanizing agent TT, 1 part of vulcanizing agent CZ.
The described raw material preparing this wire passing plug includes carry out proportioning according to mass fraction 110 parts
NBR1052,50 parts of white carbon black N550,20 parts of white carbon black N774,4 parts of softening agent DOP, 2 parts of softening agents
RD, 2 parts of softening agent MB, 0.8 part of softening agent WAX, 4 parts of compounding ingredient ZnO-A, 2 parts of binding agent SA,
1102,1 part of S of 4 parts of binding agents, 2.5 parts of vulcanizing agent TT, 3 parts of vulcanizing agent CZ.
The preparation technology of the wire passing plug of proportioning raw materials as mentioned above, key point is, described preparation technology
Step as follows:
A raw material prepares
Each for described raw material constituent according to mass fraction proportioning and uniformly being mixed, the raw material obtained is standby
With;
B is mixing
Raw material is carried out mixing, obtains elastomeric compound;
C sulfidization molding
Elastomeric compound is carried out sulfidization molding, obtains rubber wire passing plug semi-finished product;
D repairs
Rubber wire passing plug semi-finished product are carried out appearance finishing so that it is Glabrous limit;
E post-cure
Rubber wire passing plug semi-finished product after finishing are vulcanized again, finally gives rubber wire passing plug
Product.
In described step A, before raw material carries out proportioning, rubber NBR1052 is plasticated.
In described step C, the equipment used by sulfidization molding is vulcanizing press.
The invention has the beneficial effects as follows: in the present invention, rubber wire passing plug is to add white carbon black, soft in rubber
Agent, compounding ingredient, binding agent and vulcanizing agent improve the intensity of wire passing plug, elasticity and wearability, make
During by rubber wire passing plug in the present invention, electric wire can easily through in the through wires hole of rubber wire passing plug and
Not having elastomeric material abrasion, the elasticity of rubber makes electric wire be tightly fixed in through wires hole, seals
Effect is preferable, uses the mode of post-cure to improve the mechanical property of rubber wire passing plug, increasing in the preparation
Adding its stability, the using effect of rubber wire passing plug is steady in a long-term, and service life is longer.
Accompanying drawing explanation
Fig. 1 is the schematic flow sheet of rubber wire passing plug preparation technology in the present invention.
Detailed description of the invention
The present invention relates to a kind of rubber wire passing plug and preparation technology thereof, this rubber wire passing plug is at axis direction
On the through wires hole that is provided through, electric wire is fixed through through wires hole, and the diameter of through wires hole is less than institute
Wear the diameter of electric wire, utilize the elasticity of rubber to carry out through wires hole and both sides, line contacts position completely cutting off close
Envelope, dust, water, oil and other impurity all can not pass through through wires hole, prepare the raw material bag of this wire passing plug
Include according to mass fraction carry out proportioning 90-110 part rubber NBR1052,40-60 part white carbon black N550,
20-40 part white carbon black N774,3-7 part softening agent DOP, 1-2.5 part softening agent RD, 1-2.5 part softens
Agent MB, 0.5-1.2 part softening agent WAX, 3-7 part compounding ingredient ZnO-A, 1-2.5 part binding agent SA,
2-4 part binding agent 1102,0.5-1.2 part S, 1-2.5 part vulcanizing agent TT, 1-3 part vulcanizing agent CZ,
Above-mentioned constituent is used to carry out the preparation of rubber wire passing plug.
Embodiment 1, as it is shown in figure 1, prepare the raw material of rubber wire passing plug before carrying out proportioning, first will
Rubber NBR1052 plasticates, and the process of plasticating can increase the plasticity of rubber, is conducive to being sulfided into
Molding effect in the type course of processing, plasticates after end, various constituents is mixed, then
Carrying out the preparation of rubber wire passing plug, preparation technology specifically comprises the following steps that
A raw material prepares
According to mass fraction ratio, prepare 100 parts of NBR1052,50 parts of white carbon black N550,30 parts of white carbon blacks
N774,5 parts of softening agent DOP, 1.5 parts of softening agent RD, 1.5 parts of softening agent MB, 0.8 part of softening agent
WAX, 5 parts of compounding ingredient ZnO-A, 1.5 parts of binding agent SA, 1102,0.8 part of S of 3 parts of binding agents, 1.5
Part vulcanizing agent TT, 2 parts of vulcanizing agent CZ, obtain preparation and produce line plug after above-mentioned constituent uniformly being mixed
Raw material, standby;
B is mixing
Use mixing roll to carry out mixing to uniform mixed raw material, obtain elastomeric compound, in the process,
Sizing material is played strengthening action by white carbon black 550 and white carbon black 774, and softening agent DOP, RD, MB and WAX are
The auxiliary agent of processing characteristics and serviceability for improving sizing material, can increase the plasticity of sizing material, reduces
Compound viscosity and mixing time temperature, improve dispersibility and Combination, improve sizing material in sulfidation
Hot strength, percentage elongation and wearability, compounding ingredient ZnO-A can regulate the wearability of rubber, bonding
Agent SA and 1102 can increase the globality of sizing material, compounding ingredient and binding agent and combine to wearability
Improve effect more preferable, mixing after elastomeric compound possess certain hardness, hot strength, elasticity, wear-resisting
The mechanical properties such as property;
C sulfidization molding
With vulcanizing press, elastomeric compound is carried out sulfidization molding, obtain rubber wire passing plug semi-finished product, sulfuration
Agent S, TT and CZ make to produce between rubber molecule crosslinking in sulfidation, so that the elasticity of rubber,
Hardness and hot strength are greatly improved;
D repairs
Rubber wire passing plug semi-finished product are carried out appearance finishing so that it is Glabrous limit;
E post-cure
Use vulcanizer that the rubber wire passing plug semi-finished product after finishing are vulcanized again, allow rubber molecule
Continue crosslinking, improve the mechanical property of rubber, increase the stability of rubber, finally give rubber threading
Plug finished product.
Embodiment 2, as preparing the another kind of ratio of this rubber wire passing plug raw material, raw material includes
According to mass fraction carry out 90 parts of NBR1052 of proportioning, 45 parts of white carbon black N550,25 parts of white carbon black N774,
5 parts of softening agent DOP, 1.5 parts of softening agent RD, 1.5 parts of softening agent MB, 1 part of softening agent WAX, 6
Part compounding ingredient ZnO-A, 1.8 parts of binding agent SA, 1102,1 part of S of 2 parts of binding agents, 2 parts of vulcanizing agents
TT, 2 parts of vulcanizing agent CZ, use the raw material of mentioned component to sequentially pass through mixing, sulfidization molding, finishing
And after post-cure, obtain rubber wire passing plug finished product.
Embodiment 3, as preparing the another kind of ratio of this rubber wire passing plug raw material, raw material includes
According to mass fraction carry out 100 parts of NBR1052 of proportioning, 60 parts of white carbon black N550,40 parts of white carbon black N774,
7 parts of softening agent DOP, 2 parts of softening agent RD, 1.5 parts of softening agent MB, 1 part of softening agent WAX, 3 parts join
Mixture ZnO-A, 1 part of binding agent SA, 1102,1.2 parts of S of 2 parts of binding agents, 2 parts of vulcanizing agent TT, 1
Part vulcanizing agent CZ, uses the raw material of mentioned component to sequentially pass through mixing, sulfidization molding, finishing and secondary
Rubber wire passing plug finished product is obtained after sulfuration.
Embodiment 4, as preparing the another kind of ratio of this rubber wire passing plug raw material, raw material includes
According to mass fraction carry out 110 parts of NBR1052 of proportioning, 50 parts of white carbon black N550,20 parts of white carbon black N774,
4 parts of softening agent DOP, 2 parts of softening agent RD, 2 parts of softening agent MB, 0.8 part of softening agent WAX, 4 parts join
Mixture ZnO-A, 2 parts of binding agent SA, 1102,1 part of S of 4 parts of binding agents, 2.5 parts of vulcanizing agent TT, 3
Part vulcanizing agent CZ, uses the raw material of mentioned component to sequentially pass through mixing, sulfidization molding, finishing and secondary
Rubber wire passing plug finished product is obtained after sulfuration.
By to the component of rubber wire passing plug raw material and the improvement of proportioning thereof, improving rubber in the present invention
Processing characteristics in wire passing plug production process and the mechanical property such as the elasticity of finished product, wearability, tensile property
Can, it is not only convenient for processing, and produces the rubber wire passing plug that obtains and enable to electric wire and facilitate penetration of it
Through wires hole, the elastomeric material around through wires hole weares and teares without material substantially, and resilience is good, through wires hole
Being fixed by electric wire tight, rubber wire passing plug is preferable to the sealing property of through wires hole both sides, it is possible to anti-
Only oil, water and dust pass through, and have well for the electric wire within through wires hole and other related elements
Protective effect.
Claims (8)
1. a rubber wire passing plug, the through wires hole that this wire passing plug is provided through in the axial direction, its
Feature exists: the raw material preparing this wire passing plug includes carrying out 90-110 part rubber of proportioning according to mass fraction
NBR1052,40-60 part white carbon black N550,20-40 part white carbon black N774,3-7 part softening agent DOP, 1-2.5
Part softening agent RD, 1-2.5 part softening agent MB, 0.5-1.2 part softening agent WAX, 3-7 part compounding ingredient
ZnO-A, 1-2.5 part binding agent SA, 2-4 part binding agent 1102,0.5-1.2 part S, 1-2.5 part sulfur
Agent TT, 1-3 part vulcanizing agent CZ.
A kind of rubber wire passing plug the most according to claim 1, it is characterised in that: described preparation
The raw material of this wire passing plug includes carrying out 100 parts of NBR1052 of proportioning, 50 parts of white carbon blacks according to mass fraction
N550,30 parts of white carbon black N774,5 parts of softening agent DOP, 1.5 parts of softening agent RD, 1.5 parts of softening agents
MB, 0.8 part of softening agent WAX, 5 parts of compounding ingredient ZnO-A, 1.5 parts of binding agent SA, 3 parts of binding agents
1102,0.8 part of S, 1.5 parts of vulcanizing agent TT, 2 parts of vulcanizing agent CZ.
A kind of rubber wire passing plug the most according to claim 1, it is characterised in that: described preparation
The raw material of this wire passing plug includes carrying out 90 parts of NBR1052 of proportioning, 45 parts of white carbon blacks according to mass fraction
N550,25 parts of white carbon black N774,5 parts of softening agent DOP, 1.5 parts of softening agent RD, 1.5 parts of softening agents
MB, 1 part of softening agent WAX, 6 parts of compounding ingredient ZnO-A, 1.8 parts of binding agent SA, 2 parts of binding agents 1102,
1 part of S, 2 parts of vulcanizing agent TT, 2 parts of vulcanizing agent CZ.
A kind of rubber wire passing plug the most according to claim 1, it is characterised in that: described preparation
The raw material of this wire passing plug includes carrying out 100 parts of NBR1052 of proportioning, 60 parts of white carbon blacks according to mass fraction
N550,40 parts of white carbon black N774,7 parts of softening agent DOP, 2 parts of softening agent RD, 1.5 parts of softening agent MB,
1 part of softening agent WAX, 3 parts of compounding ingredient ZnO-A, 1 part of binding agent SA, 2 parts of binding agents 1102,1.2
Part S, 2 parts of vulcanizing agent TT, 1 part of vulcanizing agent CZ.
A kind of rubber wire passing plug the most according to claim 1, it is characterised in that: described preparation
The raw material of this wire passing plug includes carrying out 110 parts of NBR1052 of proportioning, 50 parts of white carbon blacks according to mass fraction
N550,20 parts of white carbon black N774,4 parts of softening agent DOP, 2 parts of softening agent RD, 2 parts of softening agent MB,
0.8 part of softening agent WAX, 4 parts of compounding ingredient ZnO-A, 2 parts of binding agent SA, 4 parts of binding agents 1102,1
Part S, 2.5 parts of vulcanizing agent TT, 3 parts of vulcanizing agent CZ.
6. the preparation technology of the rubber wire passing plug of proportioning raw materials as claimed in claim 1, it is characterised in that
The step of described preparation technology is as follows:
A raw material prepares
Each for described raw material constituent according to mass fraction proportioning and uniformly being mixed, the raw material obtained is standby
With;
B is mixing
Raw material is carried out mixing, obtains elastomeric compound;
C sulfidization molding
Elastomeric compound is carried out sulfidization molding, obtains rubber wire passing plug semi-finished product;
D repairs
Rubber wire passing plug semi-finished product are carried out appearance finishing so that it is Glabrous limit;
E post-cure
Rubber wire passing plug semi-finished product after finishing are vulcanized again, finally gives rubber wire passing plug
Product.
The preparation technology of rubber wire passing plug the most according to claim 6, it is characterised in that: described
Step A in, before raw material carries out proportioning, rubber NBR1052 is plasticated.
The preparation technology of rubber wire passing plug the most according to claim 6, it is characterised in that: described
Step C in, the equipment used by sulfidization molding is vulcanizing press.
Priority Applications (1)
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CN201610239066.5A CN105801932A (en) | 2016-04-18 | 2016-04-18 | Rubber threading plug and preparation process thereof |
Applications Claiming Priority (1)
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CN201610239066.5A CN105801932A (en) | 2016-04-18 | 2016-04-18 | Rubber threading plug and preparation process thereof |
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Publication Number | Publication Date |
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CN105801932A true CN105801932A (en) | 2016-07-27 |
Family
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CN201610239066.5A Pending CN105801932A (en) | 2016-04-18 | 2016-04-18 | Rubber threading plug and preparation process thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101442889A (en) * | 2008-12-13 | 2009-05-27 | 东方电气集团东方汽轮机有限公司 | Electrical wire wall-passing device |
CN101597391A (en) * | 2009-06-12 | 2009-12-09 | 浙江荣康密封件有限公司 | A kind of highly-abrasion-resistant butadiene-acrylonitrile-rubber vulcanized rubber and preparation method thereof |
CN201757964U (en) * | 2010-07-22 | 2011-03-09 | 深圳市洲明科技股份有限公司 | Waterproofing threading plug for LED display screen |
CN105189634A (en) * | 2013-03-05 | 2015-12-23 | 大金工业株式会社 | Acrylonitrile butadiene rubber composition, acrylonitrile butadiene rubber molded article, and method for producing same |
-
2016
- 2016-04-18 CN CN201610239066.5A patent/CN105801932A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101442889A (en) * | 2008-12-13 | 2009-05-27 | 东方电气集团东方汽轮机有限公司 | Electrical wire wall-passing device |
CN101597391A (en) * | 2009-06-12 | 2009-12-09 | 浙江荣康密封件有限公司 | A kind of highly-abrasion-resistant butadiene-acrylonitrile-rubber vulcanized rubber and preparation method thereof |
CN201757964U (en) * | 2010-07-22 | 2011-03-09 | 深圳市洲明科技股份有限公司 | Waterproofing threading plug for LED display screen |
CN105189634A (en) * | 2013-03-05 | 2015-12-23 | 大金工业株式会社 | Acrylonitrile butadiene rubber composition, acrylonitrile butadiene rubber molded article, and method for producing same |
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Application publication date: 20160727 |