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CN105705203A
CN105705203A CN201480051820.1A CN201480051820A CN105705203A CN 105705203 A CN105705203 A CN 105705203A CN 201480051820 A CN201480051820 A CN 201480051820A CN 105705203 A CN105705203 A CN 105705203A
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CN105705203B (zh
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N·巴拉德
S·A·F·邦
E·霍施德尔
G·罗伯茨
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Unilever IP Holdings BV
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    • C—CHEMISTRY; METALLURGY
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Abstract

清洁组合物，其是干洗洗发剂，所述清洁组合物包含基质和推进剂，其中基质包含含有磁性颗粒的皮脂吸收剂，其中磁性颗粒具有4nm至50nm范围内的粒径，并且其中磁性颗粒涂布有稳定化分散剂，并且其中磁性颗粒分散于液体载体中。

Description

组合物
本发明涉及一种用于施用至头发的包含皮脂吸收剂的干洗洗发剂组合物。
干洗洗发剂是用于清洁头发而无需用水清洗的组合物。在由于缺少时间或缺少可得的水而可能没有机会清洗头发的日子里，该产品提供了提供清洁感和外表的适合产品。
数据库GNPD(在线)英敏特(Mintel)2011年11月(2011-11)“即用型干洗洗发剂(InstantDryShampoo)”XP002683579，数据库登录号1669958，公开了一种包含辛烯基琥珀酸铝淀粉、二氧化硅和甘油的干洗洗发剂。该组合物还包含丁二醇。
数据库GNPD(在线)英敏特(Mintel)2011年2月(2012-02)“即用型干洗洗发剂(InstantDryShampoo)”XP002683580，数据库登录号1727707，公开了一种包含辛烯基琥珀酸铝淀粉、二氧化硅和甘油的干洗洗发剂。该组合物还包含丁二醇。
当前的干洗洗发剂技术通常采用疏水改性淀粉。然而，这些颗粒是差的皮脂吸收剂。而且吸入皮脂的淀粉颗粒是柔软的且难以从头发纤维除去，导致粘性的且不清洁的头发。另外，淀粉颗粒可导致白色颗粒出现于头发上，这是用户不期望的。为对抗此问题，配制者必须添加有色颜料以掩盖白色颗粒。因此，需要开发具有高皮脂吸收性能、快速动力学的稳健颗粒来从头发纤维快速除去可容易除去的最大量皮脂。
我们已经惊讶地发现改进的干洗洗发剂可使用粒径在4nm-50nm范围内且分散于液体载体中的磁性颗粒来配制。这些颗粒以常见方式施用于头发，并通过在头发上或穿过头发使用磁性梳或刷子来除去。颗粒被吸引到磁体并从头发上除去。没有留下白色残留物。因此，给消费者提供了在非清洗日子里的简单却有效的清洁头发的方法。
因此，在第一方面，本发明提供了清洁组合物，其是干洗洗发剂，其包含基质和推进剂(propellant)，其中基质包含含有磁性颗粒的皮脂吸收剂，其中磁性颗粒具有4nm至50nm范围内的粒径，并且其中磁性颗粒涂布有稳定化分散剂，并且其中磁性颗粒分散于液体载体中。
优选地，组合物基本不包含醇。更优选地，组合物基本不包含乙醇。更优选地，组合物包含所述组合物的0-2重量％、最优选0-1重量％的醇。更优选地，组合物包含所述组合物的0-2重量％、更优选0-1重量％的乙醇。
优选地，基质占组合物的5-20重量％。
优选地，基质包含所述基质的2-75重量％的皮脂吸收剂。
用于本发明的磁性颗粒由具有4-50nm，优选5-20nm，最优选10nm的平均粒径的亚畴(sub-domain)磁性颗粒组成。
优选的颗粒是铁磁磁铁矿。
磁性颗粒在液体载体(优选油)中为悬浮液形式。油优选选自矿物油、植物油和硅油。
优选的植物油选自葵花油、油菜籽油、橄榄油、澳洲坚果油、石榴油、椰油和甜杏仁油。
优选的矿物油选自石蜡油、烃油、芳香油和环烷油以及脂肪酯。优选的实例是己烷、己醇、环己醇、甲苯和萘。
优选的硅油选自低分子量环二甲聚硅氧烷，线性、支化、超支化和星形聚硅氧烷，例如聚二甲基硅氧烷醇、聚二甲基硅氧烷和氨基硅氧烷。商业实例包括：道康宁Q7-9120硅氧烷流体，12500；瓦克AK50硅氧烷流体和AK100硅氧烷。优选的氨基硅氧烷是氨端聚二甲基硅氧烷，例如DC8500，INCI名：双(C13-C15)PG氨端聚二甲基硅氧烷。
烷基甲基硅氧烷(AMS)INCI名：C30-45烷基聚甲基硅氧烷( ST-Wax30)。
磁性颗粒涂布有稳定化分散剂，优选油溶性表面活性剂或油乳化剂。优选的油溶性表面活性剂或油乳化剂具有3-10的HLB值。油溶性商业表面活性剂的实例包括：TERGITOLNP-4至NP-7，TritonX-15、X-35和X-45，以及TERGITOL15-S-3和15-S-5，可购自陶氏化学(DowChemicals)。
颗粒悬浮液(即油中的磁性颗粒)优选包含以体积计2-20％、优选5-10％的磁性固体，1-20％、优选5-15％、最优选10％的稳定化分散剂，以及70-97％、优选75-90％、最优选85％的液体载体。
优选地，磁性颗粒包含苯乙烯/聚二乙烯基苯共聚物。
优选地，磁性颗粒包含疏水丙烯酸酯，所述疏水丙烯酸酯优选包含疏水基团。优选地，疏水基团包含烷基。优选地，所述烷基包含8-22个碳。优选的丙烯酸酯包括甲基丙烯酸月桂酯、甲基丙烯酸-2-乙基己酯和丙烯酸丁酯。
最优选的磁性颗粒是例如可从FerrotecGmbh或E-MagnetsUK购得的铁磁流体。
优选地，皮脂吸收剂具有如使用马尔文(Malvern)(DLS)粒度分析仪2000测量的20-120微米、更优选30-90微米的平均粒径d(0.5)。
优选地，干洗洗发剂包含优选以基质的0.1-5重量％存在的油。
优选地，油是肉豆蔻酸异丙酯、苄醇、PPG-3苄基醚肉豆蔻酸酯。最优选的是肉豆蔻酸异丙酯。
优选地，干洗洗发剂包含丙二醇。优选地，任何丙二醇以基质的0.5-5重量％存在。
在根据本发明的组合物中，丙二醇减少或防止白色残留物沉积在头发上。这对于具有深色头发的用户是特别成问题的。
本发明的组合物还包含推进剂以在混合之前立即使基质悬浮并且促进其从其容器排出。
组合物储存于加压容器中。优选地，容器是气雾剂罐。更优选地，容器是未涂漆的气雾剂罐。
适合的推进剂是本领域熟知的并且包括丁烷、异丁烯和丙烷。
实施例
通过将皮脂直接施用于发束，用对照处理未处理的发束。
然后用包含测试颗粒之一的干洗洗发剂组合物来处理发束，然后用磁体除去所述颗粒。然后，将残留的皮脂的量测量为施用的量的百分比。
表1
通过悬浮聚合反应使用铁磁流体将颗粒磁化。该铁磁流体包封于微颗粒内部。
磁性多孔颗粒的合成
根据表2所示的配方，在配备有机械搅拌器和氮气进口的1升反应器中，通过悬浮聚合反应来制备磁性多孔颗粒。非均质反应混合物被排气半小时，同时以500rpm搅拌。然后将氮源提升到溶液上方，并且将搅拌速率降至350rpm。使反应在70℃进行18小时。通过过滤收集产生的多孔颗粒，并通过蒸馏水和乙醇洗涤多孔颗粒。然后将颗粒留在1升丙酮溶液中搅拌过夜，以彻底除去任意线性聚合物。再次过滤最终产物，并在60℃在真空中干燥24小时。
表2
通过使用比率为1∶0.25(DVB∶铁磁流体)的磁性颗粒，获得用于更好磁性作用的适合量的铁磁流体。降低铁磁流体的比率并不导致任何显著的磁性作用。
表3
以下是包含磁性颗粒的干洗洗发剂的制剂。它们通过标准工艺制成并包含表1所述的任意磁性颗粒。
INCI名 干洗洗发剂
SD醇40-B(变性酒精) 13.510
肉豆蔻酸异丙酯 0.250
磁性颗粒 1.875
二氧化硅 0.065
香料(香精) 0.300
异丁烷(85％)、丙烷(15％) 84
100.000

Claims (11)

1.清洁组合物，其是干洗洗发剂，所述清洁组合物包含基质和推进剂，其中所述基质包含含有磁性颗粒的皮脂吸收剂，其中所述磁性颗粒具有4nm至50nm范围内的粒径，并且其中所述磁性颗粒涂布有稳定化分散剂，并且其中所述磁性颗粒分散于液体载体中。
2.根据权利要求1所述的组合物，其中所述液体载体是油。
3.根据权利要求1或权利要求2所述的组合物，其中所述基质占所述组合物的5-20重量％。
4.根据任一项前述权利要求所述的组合物，其中所述基质包含所述基质的2-75重量％的皮脂吸收剂。
5.根据任一项前述权利要求所述的组合物，其中所述皮脂吸收剂包含平均粒径为20-120微米的颗粒。
6.根据任一项前述权利要求所述的组合物，其中所述颗粒包含苯乙烯/聚二乙烯基苯共聚物。
7.根据任一项前述权利要求所述的组合物，其中所述颗粒包含丙烯酸酯。
8.根据权利要求7所述的组合物，其中所述丙烯酸酯是疏水改性丙烯酸酯。
9.根据权利要求8所述的组合物，其中所述疏水丙烯酸酯包含含有8-22个碳的烷基。
10.根据任一项前述权利要求所述的组合物，其包含0.1-5重量％的油。
11.根据权利要求9所述的组合物，其中所述油是肉豆蔻酸异丙酯。
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BR112016006372B1 (pt) 2020-08-04
JP2016540735A (ja) 2016-12-28
US9889075B2 (en) 2018-02-13
JP6525989B2 (ja) 2019-06-05
EP3060308B1 (en) 2019-08-14
WO2015059169A1 (en) 2015-04-30

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