CN105670398B - One kind is left white glue and preparation method thereof - Google Patents
One kind is left white glue and preparation method thereof Download PDFInfo
- Publication number
- CN105670398B CN105670398B CN201610229587.2A CN201610229587A CN105670398B CN 105670398 B CN105670398 B CN 105670398B CN 201610229587 A CN201610229587 A CN 201610229587A CN 105670398 B CN105670398 B CN 105670398B
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- Prior art keywords
- left white
- white glue
- remover
- water
- surplus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003292 glue Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000003960 organic solvent Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 24
- 229920002125 Sokalan® Polymers 0.000 claims description 21
- 239000004584 polyacrylic acid Substances 0.000 claims description 21
- -1 cetyl ester Chemical class 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 13
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 12
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 12
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 claims description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 12
- 241001272567 Hominoidea Species 0.000 claims description 11
- 238000013019 agitation Methods 0.000 claims description 9
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical group OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 6
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000010189 synthetic method Methods 0.000 abstract description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D107/00—Coating compositions based on natural rubber
- C09D107/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to one kind to be left white glue and preparation method thereof.Existing market be the problem of being left white glue in use be left white glue quick-drying, very viscous or glue easily penetrates into paper bottom, cause to be left white it is undesirable, be not easy to dry or situations such as more difficult removal.The present invention by percentage to the quality, takes 55% ~ 65% natural emulsion, 20% ~ 30% remover, surplus is water；Heveatex and remover are added in beaker successively, stirs and evenly mixs, then adds water, produce and be left white glue；Wherein remover includes, and 10% ~ 35% polyalkyl acrylate, 5% ~ 10% organic solvent, 4% ~ 6% emulsifying agent, surplus is water.The present invention is left white glue and easily peeled off from drawing paper, does not glue pen, the cleaning of picture and paintbrush can be kept lossless；It is formulated simple and environmentally-friendly simultaneously, to human body fanout free region, synthetic method is simple to operation, securely and reliably, uses and stores and be all very convenient.
Description
Technical field：The present invention relates to one kind to be left white glue and preparation method thereof.
Background technology：Existing market is left white glue in use problem is encountered that being left white glue quick-drying, causes to be left white
Situation is undesirable, paintbrush and the dry and hard waste of glue.It is very viscous that some are left white glue product, is not easy drying；It is left white glue glue on paper
Easily penetrate into paper bottom, it is more difficult to remove.
The content of the invention：The purpose of the present invention is to provide one kind by adding a kind of macromolecule remover to be left white glue and its preparation
Method, overcomes that the prior art feature of environmental protection is poor, causes the wasting of resources, is left white the defects of situation is undesirable.
The technical solution adopted in the present invention is：
One kind is left white glue：
Include the component of following mass percent：
55% ~ 65% natural emulsion；
20% ~ 30% remover；
Surplus is water.
The remover includes the component of following mass percent：
10% ~ 35% polyalkyl acrylate；
5% ~ 10% organic solvent；
4% ~ 6% emulsifying agent；
Surplus is water.
Described polyalkyl acrylate is selected from polyacrylic acid eicosane base ester, polyacrylic acid stearyl, polypropylene
One or more mixtures in sour cetyl ester, polyacrylic acid tetradecane base ester.
Described emulsifying agent is the mixture of sorbitan fatty ester and APES, mass mixing
Than for 1：0.2~1.
Described organic solvent is selected from pentamethylene, pentane, hexamethylene, n-hexane, normal heptane, cycloheptane, N, N- diformazans
One or more mixtures in base formamide.
A kind of preparation method for being left white glue, it is characterised in that：
Comprise the following steps：
Step 1：Prepare remover：
（1）By percentage to the quality, take 10% ~ 35% polyalkyl acrylate, 5% ~ 10% organic solvent, 4% ~ 6%
Emulsifying agent, surplus are water；
（2）Polyalkyl acrylate, organic solvent, emulsifying agent are fully mixed successively, then added under agitation
Water, continue to stir, produce remover；
Step 2：Preparation is left white glue：
（1）By percentage to the quality, 55% ~ 65% natural emulsion, 20% ~ 30% remover is taken, surplus is water；
（2）Heveatex and remover are added in beaker successively, stirs and evenly mixs, then adds water, produce and be left white glue.
Described polyalkyl acrylate is selected from polyacrylic acid eicosane base ester, polyacrylic acid stearyl, polypropylene
One or more mixtures in sour cetyl ester, polyacrylic acid tetradecane base ester.
Described emulsifying agent is the mixture of sorbitan fatty ester and APES, mass mixing
Than for 1：0.2~1.
Described organic solvent is selected from pentamethylene, pentane, hexamethylene, n-hexane, normal heptane, cycloheptane, N, N- diformazans
One or more mixtures in base formamide.
The present invention has advantages below：
The glue of the present invention that is left white can meet that watercolor leaving blank for the point, line, surface that become clear, particularly those complexity become
Change bright point, line, surface or even body repeatedly allow sky requirement.Easily peeled off from drawing paper, do not glue pen, picture and picture can be kept
The cleaning of pen is lossless.Simultaneously this be left white glue formula it is simple and environmentally-friendly, to human body fanout free region, synthetic method is simple to operation, safely may be used
Lean on, use and store and be all very convenient.
Embodiment
With reference to embodiment, the present invention will be described in detail.
One kind of the present invention is left white glue, includes the component of following mass percent：
55% ~ 65% natural emulsion；
20% ~ 30% remover；
Surplus is water；
The remover includes the component of following mass percent：
10% ~ 35% polyalkyl acrylate；
5% ~ 10% organic solvent；
4% ~ 6% emulsifying agent；
Surplus is water；
Described polyalkyl acrylate is selected from polyacrylic acid eicosane base ester, polyacrylic acid stearyl, polypropylene
One or more mixtures in sour cetyl ester, polyacrylic acid tetradecane base ester.
Described emulsifying agent is the mixture of sorbitan fatty ester and APES, mass mixing
Than for 1：0.2~1.
Described organic solvent is selected from pentamethylene, pentane, hexamethylene, n-hexane, normal heptane, cycloheptane, N, N- diformazans
One or more mixtures in base formamide.
A kind of preparation method for being left white glue, it is characterised in that：
Comprise the following steps：
Step 1：Prepare remover：
（1）By percentage to the quality, take 10% ~ 35% polyalkyl acrylate, 5% ~ 10% organic solvent, 4% ~ 6%
Emulsifying agent, surplus are water；
（2）Polyalkyl acrylate, organic solvent, emulsifying agent are fully mixed successively, then added under agitation
Water, continue to stir, produce remover；
Step 2：Preparation is left white glue：
（1）By percentage to the quality, 55% ~ 65% natural emulsion, 20% ~ 30% remover is taken, surplus is water；
（2）Heveatex and remover are added in beaker successively, stirs and evenly mixs, then adds water, produce and be left white glue.
Described polyalkyl acrylate is selected from polyacrylic acid eicosane base ester, polyacrylic acid stearyl, polypropylene
One or more mixtures in sour cetyl ester, polyacrylic acid tetradecane base ester.
Described emulsifying agent is the mixture of sorbitan fatty ester and APES, mass mixing
Than for 1：0.2~1.
Described organic solvent is selected from pentamethylene, pentane, hexamethylene, n-hexane, normal heptane, cycloheptane, N, N- diformazans
One or more mixtures in base formamide.
Embodiment 1：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）20 parts of polyacrylic acid cetyl esters, 10 parts of pentane, 4 parts of mass mixing ratios are 1:1 Sorbitan
The mixture of alcohol fatty acid ester and APES, after fully mixing, 66 parts of water is added under agitation, continue to stir
Mix, produce remover；
2）Take 1）In obtained 20 parts of remover, add 55 parts of natural emulsions, 25 parts of water, mix, produce and be left white glue.
Embodiment 2：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）25 parts of polyacrylic acid stearyls, 12 parts of pentamethylene, 5 parts of mass mixing ratios are 1:0.8 Sorbitan
The mixture of sugar alcohol fatty acid ester and APES, after fully mixing, 58 parts of water are added under agitation, are continued
Stirring, produces remover.
2）Take 1）Middle 22 parts of remover, 58 parts of natural emulsions are added, 20 parts of water, mixes, produces and be left white glue.
Embodiment 3：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）22 parts of polyacrylic acid stearyls, 17 parts of cycloheptane, 7 parts of mass mixing ratios are 1:0.5 Sorbitan
The mixture of sugar alcohol fatty acid ester and APES, after fully mixing, 54 parts of water are added under agitation, are continued
Stirring, produces remover.
2）Take 1）Middle 25 parts of remover, 55 parts of natural emulsions are added, 20 parts of water, mixes, produces and be left white glue.
Embodiment 4：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）23 parts of polyacrylic acid tetradecane base esters, 16 parts of normal heptane, 6 parts of mass mixing ratios are 1:0.4 Sorbitan
The mixture of sugar alcohol fatty acid ester and APES, after fully mixing, 55 parts of water are added under agitation, are continued
Stirring, produces remover.
2）Take 1）Middle 26 parts of remover, 57 parts of natural emulsions are added, 17 parts of water, mixes, produces and be left white glue.
Embodiment 5：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）18 parts of polyacrylic acid eicosane base esters, 14 parts of n-hexane, 8 parts of mass mixing ratios are 1:0.3 Sorbitan
The mixture of sugar alcohol fatty acid ester and APES, after fully mixing, 60 parts of water are added under agitation, are continued
Stirring, produces remover.
2）Take 1）Middle 30 parts of remover, 62 parts of natural emulsions are added, 8 parts of water, mixes, produces and be left white glue.
Embodiment 6：
The above-mentioned method for being left white glue is prepared, is comprised the following steps
1）21 parts of polyacrylic acid stearyls, 14 parts of DMF, 7 parts of mass mixing ratios are 1:0.2
Sorbitan fatty ester and APES mixture, fully mix after, add under agitation
58 parts of water, continue to stir, produce remover.
2）Take 1）Middle 29 parts of remover, 58 parts of natural emulsions are added, 13 parts of water, mixes, produces and be left white glue.
Present disclosure is not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention
And any equivalent conversion taken technical solution of the present invention, it is that claim of the invention is covered.
Claims (4)
1. one kind is left white glue, it is characterised in that：
Include the component of following mass percent：
55% ~ 65% natural emulsion；
20% ~ 30% remover；
Surplus is water；
Described remover includes the component of following mass percent：
10% ~ 35% polyalkyl acrylate；
5% ~ 10% organic solvent；
4% ~ 6% emulsifying agent；
Surplus is water；Described polyalkyl acrylate is polyacrylic acid eicosane base ester, polyacrylic acid stearyl, poly- third
One or more mixtures in olefin(e) acid cetyl ester, polyacrylic acid tetradecane base ester.
2. one kind according to claim 1 is left white glue, it is characterised in that：Described organic solvent be pentamethylene, pentane,
One or more mixtures in hexamethylene, n-hexane, normal heptane, cycloheptane, N,N-dimethylformamide.
3. one kind according to claim 1 is left white glue, it is characterised in that：Described emulsifying agent is sorbitan fatty
The mixture of acid esters and APES, mass mixing ratio 1：0.2~1.
A kind of 4. preparation method for being left white glue according to any one in claim 1 ~ 3, it is characterised in that：
Comprise the following steps：
Step 1：Prepare remover：
（1）By percentage to the quality, 10% ~ 35% polyalkyl acrylate, 5% ~ 10% organic solvent, 4% ~ 6% emulsification is taken
Agent, surplus are water；
（2）Polyalkyl acrylate, organic solvent, emulsifying agent are fully mixed successively, then add water under agitation, after
Continuous stirring, produces remover；
Step 2：Preparation is left white glue：
（1）By percentage to the quality, 55% ~ 65% natural emulsion, 20% ~ 30% remover is taken, surplus is water；
（2）Heveatex and remover are added in beaker successively, stirs and evenly mixs, then adds water, produce and be left white glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610229587.2A CN105670398B (en) | 2016-04-14 | 2016-04-14 | One kind is left white glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610229587.2A CN105670398B (en) | 2016-04-14 | 2016-04-14 | One kind is left white glue and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105670398A CN105670398A (en) | 2016-06-15 |
| CN105670398B true CN105670398B (en) | 2018-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610229587.2A Expired - Fee Related CN105670398B (en) | 2016-04-14 | 2016-04-14 | One kind is left white glue and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106906688A (en) * | 2017-03-03 | 2017-06-30 | 山东太阳生活用纸有限公司 | Stripping agent for yankee dryer |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0423878A (en) * | 1990-05-16 | 1992-01-28 | Izumiya:Kk | Water-soluble rubber cement adhesive |
| CN1590483A (en) * | 2004-03-11 | 2005-03-09 | 武汉工业学院 | Temporary tearable protechtive paint and its preparation method |
| CN101633826A (en) * | 2008-07-25 | 2010-01-27 | 宁波松鹤文具有限公司 | Toy glue and method for preparing same |
| CN102675527B (en) * | 2012-05-18 | 2013-12-25 | 华南理工大学 | Preparation method of water-borne long-chain acrylate separant |
| CN103013383B (en) * | 2012-12-27 | 2015-08-19 | 广东达美新材料有限公司 | A kind of water-borne pressure sensitive adhesive and preparation method thereof |
| CN105086857B (en) * | 2015-09-06 | 2018-02-16 | 南通宝加利新材料有限公司 | A kind of environment-friendly type aqueous rubber protective film and preparation method thereof |
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| CN105670398A (en) | 2016-06-15 |
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