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CN105618762A - Steel bond hard alloy injection molding mold core - Google Patents

Steel bond hard alloy injection molding mold core Download PDF

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Publication number
CN105618762A
CN105618762A CN201610106755.9A CN201610106755A CN105618762A CN 105618762 A CN105618762 A CN 105618762A CN 201610106755 A CN201610106755 A CN 201610106755A CN 105618762 A CN105618762 A CN 105618762A
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parts
steel
bonded carbide
steel bonded
powder
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王亚莉
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/007Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/105Metallic powder containing lubricating or binding agents; Metallic powder containing organic material containing inorganic lubricating or binding agents, e.g. metal salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/2602Mould construction elements

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

A steel bond hard alloy injection molding mold core is characterized in that the steel bond hard alloy injection molding mold core is composed of steel bond hard alloy; a steel bond hard alloy manufacturing raw material comprises a hard phase and a steel-based adhesion agent; and components of the steel-based adhesion agent have high strength, and the strength of the steel bond hard alloy is further improved under the action of the hard phase. By means of the procedures of pressing and sintering, heating and forging, annealing, machining, quenching and tempering, the manufacturing procedure is simpler, and cost is reduced.

Description

A kind of steel bonded carbide injection core
Technical field
The present invention relates to a kind of steel bonded carbide injection core, belongs to technical field of mold.
Background technology
Mould generally comprises dynamic model and cover half, one set of die can only produce a kind of product, want to produce other product needed and design new dynamic model and cover half, existing mold can introduce core rod and mould is designed, the major part mould containing core rod also cannot realize changing core rod and realize producing the function of different product, it is desirable to during other products of volume production, it is necessary to whole set of die disassembled, the mould being replaced with correspondence produces, and such design have impact on work efficiency and also considerably increases production cost.
Summary of the invention
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 20-30 part, two chromium boride 10-20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.5-0.6%, Mg1-2%, Nb2-3%, Mn0.6-0.7%, Si1.2-1.4%, Zn2.2-2.4%, Al1.1-1.3%, V0.2-0.3%, Ag0.06-0.07%, Ba0.02-0.03%, Zr0.02-0.03%, B0.01-0.02%, surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 820-830 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Described a kind of steel bonded carbide injection core, base steel binding agent (weight) is by C0.5%, Mg1%, Nb2%, Mn0.6%, Si1.2%, Zn2.2%, Al1.1%, V0.2%, Ag0.06%, Ba0.02%, Zr0.02%, B0.01%, and surplus is Fe composition.
Described a kind of steel bonded carbide injection core, base steel binding agent (weight) is by C0.6%, Mg2%, Nb3%, Mn0.7%, Si1.4%, Zn2.4%, Al1.3%, V0.3%, Ag0.07%, Ba0.03%, Zr0.03%, B0.02%, and surplus is Fe composition.
Described a kind of steel bonded carbide injection core, base steel binding agent (weight) is by C0.55%, Mg1.5%, Nb2.5%, Mn0.65%, Si1.3%, Zn2.3%, Al1.2%, V0.25%, Ag0.065%, Ba0.025%, Zr0.025%, B0.015%, surplus is Fe composition.
Described a kind of steel bonded carbide injection core, hard phase (weight) is by titanium nitride 20 parts, two chromium borides 10 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
Described a kind of steel bonded carbide injection core, hard phase (weight) is by titanium nitride 30 parts, two chromium borides 20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
Described a kind of steel bonded carbide injection core, hard phase (weight) is by titanium nitride 25 parts, two chromium borides 15 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
Described a kind of steel bonded carbide injection core, wherein in annealing operation: annealing temperature 820 DEG C, keeps 4.5h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
Described a kind of steel bonded carbide injection core, wherein in annealing operation: annealing temperature 830 DEG C, keeps 4h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
Described a kind of steel bonded carbide injection core, wherein in annealing operation: annealing temperature 825 DEG C, keeps 5h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
A kind of manufacture method of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 20-30 part, two chromium boride 10-20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.5-0.6%, Mg1-2%, Nb2-3%, Mn0.6-0.7%, V0.2-0.3%, Ag0.06-0.07%, Ba0.02-0.03%, Zr0.02-0.03%, B0.01-0.02%, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 820-830 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Foregoing invention content having the beneficial effects that relative to prior art: 1) in steel bonded carbide injection core of the present invention hard phase by titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthana composition improves the mechanical performance of material; 2) composition of base steel binding agent has higher-strength, then under the effect of hard phase, steel bonded carbide intensity obtains further raising, and 3) pass through compacting sintering, heats forged, annealing, machining, quenching, tempering process makes manufacturing process more simple, reduces cost.
Detailed description of the invention
In order to the technical characteristic of the present invention, purpose and effect are more clearly understood from, now describe the specific embodiment of the present invention in detail.
Embodiment 1
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 20 parts, two chromium borides 10 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.5%, Mg1%, Nb2%, Mn0.6%, Si1.2%, Zn2.2%, Al1.1%, V0.2%, Ag0.06%, Ba0.02%, Zr0.02%, B0.01%, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 820 DEG C, keep 4h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Embodiment 2
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 30 parts, two chromium borides 20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.6%, Mg2%, Nb3%, Mn0.7%, Si1.4%, Zn2.4%, Al1.3%, V0.3%, Ag0.07%, Ba0.03%, Zr0.03%, B0.02%, and surplus is Fe composition, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 830 DEG C, keep 5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Embodiment 3
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 25 parts, two chromium borides 15 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.55%, Mg1.5%, Nb2.5%, Mn0.65%, Si1.3%, Zn2.3%, Al1.2%, V0.25%, Ag0.065%, Ba0.025%, Zr0.025%, B0.015%, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 825 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Embodiment 4
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 22 parts, two chromium borides 11 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.53%, Mg1.4%, Nb2.3%, Mn0.62%, Si1.3%, Zn2.3%, Al1.2%, V0.23%, Ag0.064%, Ba0.022%, Zr0.021%, B0.012%, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 823 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
Embodiment 5
A kind of steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 28 parts, two chromium borides 17 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.56%, Mg1.7%, Nb2.8%, Mn0.68%, Si1.3%, Zn2.3%, Al1.2%, V0.27%, Ag0.066%, Ba0.027%, Zr0.028%, B0.019%, and surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C.
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 828 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.

Claims (10)

1. a steel bonded carbide injection core, it is characterized in that steel bonded carbide injection core is made up of steel bonded carbide, steel bonded carbide manufactures raw material and includes hard phase and base steel binding agent, hard phase (weight) is by titanium nitride 20-30 part, two chromium boride 10-20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition; Base steel binding agent (weight) is by C0.5-0.6%, Mg1-2%, Nb2-3%, Mn0.6-0.7%, Si1.2-1.4%, Zn2.2-2.4%, Al1.1-1.3%, V0.2-0.3%, Ag0.06-0.07%, Ba0.02-0.03%, Zr0.02-0.03%, B0.01-0.02%, surplus is Fe composition; The weight ratio of hard phase and base steel binding agent is 1.5,
Steel bonded carbide mixes through powder, compacting sintering, heats forged, annealing, machining, quenching, and tempering process is prepared from:
Wherein in powder mixed processes: weigh titanium nitride, two chromium borides, chromium carbide, yittrium oxide, lanthanum oxide powder mixes according to aforementioned proportion, carries out ball milling alloying according to ratio of grinding media to material 15:1, and abrading-ball is hardened steel ball, Ball-milling Time 30h, applies the high-purity argon gas of more than 99.9%, it is thus achieved that hard phase powder; Weighing base steel adhesive powder, carry out ball milling, Ball-milling Time 40h according to ratio of grinding media to material 16:1, interpolation dehydrated alcohol is process control agent; Hard phase powder after ball milling and base steel adhesive powder are mixed, ball milling 20 hours again, it is thus achieved that steel bonded carbide mixed-powder;
Wherein in compacting sintering operation: the steel bonded carbide mixed-powder of above-mentioned acquisition is dried, screening, it is pressed into the size shape of required product; Then carrying out vacuum-sintering, 50 DEG C/min of heating rate carries out insulation 1 hour when being warming up to 1410 DEG C,
Wherein in heats forged operation: initial forging temperature is at 1200 DEG C, and final forging temperature is at 980 DEG C;
Wherein in annealing operation: annealing temperature 820-830 DEG C, keep 4-5h, after then cooling to 150 DEG C with the furnace, take out natural cooling in air;
Wherein quenching, in tempering process: the temperature of described Quenching Treatment is 1030 DEG C, described temper is heated to 520 DEG C from room temperature by workpiece, heating rate 35 DEG C/h, be incubated 2 hours, after be cooled to 330 DEG C, rate of temperature fall 24 DEG C/h, it is incubated 5 hours, after be again cooled to 220 DEG C, rate of temperature fall 20 DEG C/h, be incubated 3 hours, rear air cooling, to room temperature, finally gives steel bonded carbide injection core.
2. a kind of steel bonded carbide injection core as claimed in claim 1, base steel binding agent (weight) is by C0.5%, Mg1%, Nb2%, Mn0.6%, Si1.2%, Zn2.2%, Al1.1%, V0.2%, Ag0.06%, Ba0.02%, Zr0.02%, B0.01%, surplus is Fe composition.
3. a kind of steel bonded carbide injection core as claimed in claim 1, base steel binding agent (weight) is by C0.6%, Mg2%, Nb3%, Mn0.7%, Si1.4%, Zn2.4%, Al1.3%, V0.3%, Ag0.07%, Ba0.03%, Zr0.03%, B0.02%, surplus is Fe composition.
4. a kind of steel bonded carbide injection core as claimed in claim 1, base steel binding agent (weight) is by C0.55%, Mg1.5%, Nb2.5%, Mn0.65%, Si1.3%, Zn2.3%, Al1.2%, V0.25%, Ag0.065%, Ba0.025%, Zr0.025%, B0.015%, surplus is Fe composition.
5. a kind of steel bonded carbide injection core as claimed in claim 1, hard phase (weight) is by titanium nitride 20 parts, two chromium borides 10 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
6. a kind of steel bonded carbide injection core as claimed in claim 1, hard phase (weight) is by titanium nitride 30 parts, two chromium borides 20 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
7. a kind of steel bonded carbide injection core as claimed in claim 1, hard phase (weight) is by titanium nitride 25 parts, two chromium borides 15 parts, chromium carbide 4 parts, yittrium oxide 2 parts, lanthana 2 parts composition.
8. a kind of steel bonded carbide injection core as claimed in claim 1, wherein in annealing operation: annealing temperature 820 DEG C, keeps 4.5h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
9. a kind of steel bonded carbide injection core as claimed in claim 1, wherein in annealing operation: annealing temperature 830 DEG C, keeps 4h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
10. a kind of steel bonded carbide injection core as claimed in claim 1, wherein in annealing operation: annealing temperature 825 DEG C, keeps 5h, takes out natural cooling in air after then cooling to 150 DEG C with the furnace.
CN201610106755.9A 2016-02-27 2016-02-27 Steel bond hard alloy injection molding mold core Withdrawn CN105618762A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110834075A (en) * 2019-12-02 2020-02-25 广州市型腔模具制造有限公司 Machining process of engine cylinder body cavity die
CN116024483A (en) * 2022-12-30 2023-04-28 江苏群达机械科技有限公司 Low-alloy high-strength Cr-Mo steel material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110834075A (en) * 2019-12-02 2020-02-25 广州市型腔模具制造有限公司 Machining process of engine cylinder body cavity die
CN116024483A (en) * 2022-12-30 2023-04-28 江苏群达机械科技有限公司 Low-alloy high-strength Cr-Mo steel material and preparation method thereof
CN116024483B (en) * 2022-12-30 2023-09-15 江苏群达机械科技有限公司 Low-alloy high-strength Cr-Mo steel material and preparation method thereof

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Application publication date: 20160601