CN105602465A - Wear-resistant adhesive tape - Google Patents
Wear-resistant adhesive tape Download PDFInfo
- Publication number
- CN105602465A CN105602465A CN201610066159.2A CN201610066159A CN105602465A CN 105602465 A CN105602465 A CN 105602465A CN 201610066159 A CN201610066159 A CN 201610066159A CN 105602465 A CN105602465 A CN 105602465A
- Authority
- CN
- China
- Prior art keywords
- adhesive tape
- wear
- mass parts
- parts
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2409/00—Presence of diene rubber
- C09J2409/006—Presence of diene rubber in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a wear-resistant adhesive tape. The wear-resistant adhesive tape comprises a base material layer, a bonding layer and a release film, wherein the bonding layer and the release film are respectively lamellarly fitted at the two sides of the base material layer, and the base material layer comprises the following main components: 45-60 parts by mass of styrene-butadiene rubber, 30-40 parts by mass of natural rubber, 10-20 parts by mass of a reinforcing agent, 1-2 parts by mass of an accelerator, 2-4 parts by mass of an ultraviolet-proof agent, 20-30 parts by mass of a plasticizer, 2-3 parts by mass of an anti-aging agent, 15-20 parts by mass of polyester staple fibers, 3-5 parts by mass of silicate minerals, and 1-3 parts by mass of fiber powder. The adhesive tape disclosed by the invention is greatly improved in wear-resistant property and also has good bonding property.
Description
Technical field
The present invention relates to adhesive tape, relate in particular to a kind of wear-resisting adhesive tape, belong to tape technology field.
Background technology
Nineteen twenty-eight, Richard invented adhesive tape in Shandong in Minnesota ,USA Sao Paulo. GlueBand can be divided into by his effect: high temperature gummed tape, two-sided tape, insulating tape, extraordinary adhesive tape,Pressure sensitive adhesive tape, cross cutting adhesive tape, different effects is applicable to different industry requirements. On tape surfaceScribble one deck sticker, could make adhesive tape cling article.
The patent of publication No. CN103614087A discloses a kind of high hardness wear-resisting adhesive tape, bagDraw together: outer wearing layer and hose lining belt, described outer wearing layer is made up of aluminum alloy films,Described aluminum alloy films is made up of metallic aluminium and magnesium metal, described hose lining belt by fiber cloth andThe bonding formation of white glue with vinyl, described outer wearing layer and described hose lining belt are bonding by adhesiveTogether, the material of described adhesive is all-purpose adhesive, and by the way, this invention can beWhen ensureing adhesive tape excellent adhering, strengthen the hardness of tape surface, made tape surface moreWear-resisting, not cracky. But outer aluminum alloy material, the metal material of using of this wear-resisting adhesive tapeSkin is acid-alkali-corrosive-resisting not, and poor ductility, involves great expense, and is not suitable for routine use.
Summary of the invention
Object of the present invention is exactly the defect for prior art, and a kind of wear-resisting adhesive tape is provided, and carriesThe anti-wear performance of high adhesive tape.
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, and described substrate layer chief component is: 45～60Mass parts butadiene-styrene rubber, 30～40 mass parts natural rubbers, 10～20 mass parts reinforcing agents, 1～2Mass parts promoter, 2～4 mass parts ultraviolet screeners, 20～30 mass parts plasticizer, 2～3Mass parts age resistor, the terylene short fiber of 15～20 mass parts, 3～5 mass parts silicate minerals,The fiber powder of 1～3 mass parts.
Terylene short fiber has good anti-wear performance, the terylene short fiber of appropriate level and rubber combinedAfter, can reinforced wear-resistant performance. Select suitable plasticizer can improve plasticizer and resinCompatibility, prevents that plasticizer from emanating between adhesive tape and clung body, reduces adhesive property.
Further, described fiber powder is plant fibre powder or azelon powder, described inThe particle diameter of fiber powder is 2～3 μ m. Adding of fiber powder, make polymer wrapped fiber powderMaterial, the shrinkage factor of polymeric material and fiber powder material differs very large, in the mistake of film formingCheng Zhonghui produces more hole, has improved the voidage of polymeric material, improves polymeric materialThe hydrophilicity of material, is conducive to the infiltration of adhesive, reduces the phenomenon of coming unstuck, simultaneously fiber powderBody material plays the effect of physical crosslinking, improves the intensity of polymer, increases anti-wear performance.
Further, described ultraviolet screener be UV-9, UV-327, UV-356, zinc oxide,One in titanium oxide. Object is to prevent that light from making base material free-radical oxidation cause aging, color and lusterDimmed.
Further, described reinforcing agent is high styrene resin or phenolic resins.
Further, described promoter is cobalt naphthenate, cobalt iso-octoate, diethyl-dithio ammoniaOne or more in base zinc formate, PZ. Promoter can promoteThe material of sulfurization. Can shorten the cure time of rubber or reduce curing temperature, reducing sulfurationThe physical and mechanical properties of agent consumption and raising rubber etc.
Further, described plasticizer is diisononyl phthalate, phthalic acid two fourthsOne in ester, di-sec-octyl phthalate, diisooctyl phthalate. It is suitable to selectPlasticizer can improve the compatibility of plasticizer and resin, prevent plasticizer segregation adhesive tape withBetween clung body, reduce adhesive property.
Further, described age resistor is N-phenyl-α-aniline, two (the 2.2-dimethylbenzyls of 4.4-Base) diphenylamines, 6-ethyoxyl-2,2,4-trimethyl-1, the one in 2-dihyaroquinoline.Age resistor refer to prevent or to suppress such as oxygen, heat, light, ozone, mechanical stress, heavy metal fromThe factors disrupt product properties such as son, prolongation goods store and service life.
Further, described silicate mineral is length 10～20 μ m, and draw ratio is 15～25Calcium carbonate crystal whisker. Calcium carbonate has good stability as inorganic material, and quality is harder, structureBe not easy destroyedly, be added on anti-wear performance and the intensity that in rubber, can strengthen rubber, stillCalcium titanate is more crisp, and the draw ratio while being difficult for keeping adding, if the length of the calcium titanate whisker addingDegree and draw ratio are improper, are unfavorable on the contrary the raising of the performance of rubber, therefore select suitable lengthThe calcium titanate whisker of degree and draw ratio has great importance.
The invention has the beneficial effects as follows:
(1) use compounded rubber material, take into account ductility, corrosion resistance and anti-wear performance,Simultaneously with low cost, compounded rubber can reinforced wear-resistant performance after adding terylene short fiber.
(2) silicate mineral add the anti-wear performance that can greatly improve product.
(3) fiber powder add the voidage that has improved polymeric material, improve polymerThe hydrophilicity of material, is conducive to the infiltration of adhesive, and fiber powder material plays physics simultaneouslyCrosslinked effect, the intensity of raising polymer.
Detailed description of the invention
Below by embodiment, the present invention is described further.
Embodiment 1
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, it is characterized in that: described substrate layer is mainConsist of: 45 mass parts butadiene-styrene rubber, 30 mass parts natural rubbers, the high benzene second of 10 mass partsOlefine resin, 1 mass parts cobalt naphthenate, 2 mass parts UV-9,20 mass parts phthalic acidsDinonyl, 2 mass parts N-phenyl-α-aniline, the terylene short fiber of 15 mass parts, 3 qualityPart length 10 μ m, the calcium carbonate crystal whisker that draw ratio is 15,1 mass parts particle diameter is planting of 2 μ mFibres powder.
Embodiment 2
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, it is characterized in that: described substrate layer is mainConsist of 60 mass parts butadiene-styrene rubber, 40 mass parts natural rubbers, 20 mass parts phenolic aldehydeResin, 1 mass parts cobalt naphthenate and cobalt iso-octoate mixture, 2 mass parts titanium oxide, 20 matterAmount part di-sec-octyl phthalate, 2 mass parts 6-ethyoxyl-2,2,4-trimethyl-1,2-Dihyaroquinoline, the terylene short fiber of 15 mass parts, 5 mass parts length 20 μ m, draw ratio is20 calcium carbonate crystal whisker, 2 mass parts particle diameters are the azelon powder of 2.5 μ m.
Embodiment 3
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, it is characterized in that: described substrate layer is mainConsist of: 50 mass parts butadiene-styrene rubber, 35 mass parts natural rubbers, the high benzene second of 15 mass partsOlefine resin, 1 mass parts cobalt iso-octoate, 2 mass parts UV-356,25 mass parts O-phthalicsAcid dinonyl, two (2.2-dimethyl benzyl) diphenylamines of 2 mass parts 4.4-, 15 mass partsTerylene short fiber, 5 mass parts length 16 μ m, the calcium carbonate crystal whisker that draw ratio is 20,1Mass parts particle diameter is the plant fibre powder of 3 μ m.
Embodiment 4
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, it is characterized in that: described substrate layer is mainConsist of: 50 mass parts butadiene-styrene rubber, 35 mass parts natural rubbers, the high benzene second of 15 mass partsOlefine resin, 1 mass parts PZ, 2 mass parts zinc oxide, 25 matterAmount part diisononyl phthalate, 2.5 mass parts N-phenyl-α-aniline, 18 mass partsTerylene short fiber, 4 mass parts length 16 μ m, the calcium carbonate crystal whisker that draw ratio is 18,2 qualityPart particle diameter is the plant fibre powder of 2 μ m.
Embodiment 5
A kind of wear-resisting adhesive tape: comprise substrate layer, tack coat and mould release membrance, described tack coat with fromType film becomes respectively stratiform to be fitted in the both sides of substrate layer, it is characterized in that: described substrate layer is mainConsist of: 60 mass parts butadiene-styrene rubber, 40 mass parts natural rubbers, 20 mass parts phenolic aldehyde treesFat, 1 mass parts cobalt naphthenate, 2 mass parts UV-327,20 mass parts phthalic acids twoDifferent ninth of the ten Heavenly Stems ester, 2.5 mass parts N-phenyl-α-aniline, the terylene short fiber of 18 mass parts, 4 mass partsLength 15 μ m, the calcium carbonate crystal whisker that draw ratio is 18,2 mass parts particle diameters are planting of 2.3 μ mFibres powder or azelon powder.
Prepare adhesive tape according to embodiment 1～5 and make size 15cm*5cm together with normal tape,The sample that thickness is identical, uses reciprocating plain grinding instrument, uses sand paper as abrasive material, by size phaseSame adhesive tape is tested respectively, observes the abrasion condition of adhesive tape.
Table 1
Result can be found out by experiment, adhesive tape prepared by the present invention, and compared to common adhesive tape,Can obviously improve anti abrasive performance.
In view of the present invention program embodiment is numerous, each embodiment experimental data is huge numerous, discomfortClose in the explanation of particularize herein, but the content of the required checking of each embodiment and obtainingTermination opinion all approaches, so the checking content of each embodiment is not illustrated one by one, hereinOnly using above-mentioned part embodiment as the excellent part of representative explanation the present patent application. Relate to sameWhen the different testing scheme of index, adopt arbitrary all passable that the present invention program points out, and allDo not exceed in the scope of protection of present invention.
The embodiment of this place to the claimed not limit part of technical scope midrange of the present invention withAnd in embodiment technical scheme, the equal replacement of single or multiple technical characterictics is formedNew technical scheme, equally all in the scope of protection of present invention; Side of the present invention simultaneouslyIn all embodiment that enumerate or do not enumerate of case, the parameters in same embodiment onlyRepresent an example (being a kind of feasible scheme) of its technical scheme, and parameters itBetween there is not strict cooperation and qualified relation, wherein each parameter is without prejudice to axiom and thisInvention is stated while asking and can mutually be replaced, except special declaration.
Claims (8)
1. wear-resisting adhesive tape: comprise substrate layer, tack coat and a mould release membrance, described tack coatBecome respectively stratiform to be fitted in the both sides of substrate layer with mould release membrance, it is characterized in that: described substrate layerChief component is: 45～60 mass parts butadiene-styrene rubber, 30～40 mass parts natural rubbers, 10～20Mass parts reinforcing agent, 1～2 mass parts promoter, 2～4 mass parts ultraviolet screeners, 20～30Mass parts plasticizer, 2～3 mass parts age resistor, the terylene short fiber of 15～20 mass parts, 3～5Mass parts silicate mineral, the fiber powder of 1～3 mass parts.
2. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described fibreDimension powder is plant fibre powder or azelon powder, and the particle diameter of described fiber powder is2～3μm。
3. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described anti-Ultraviolet ray agent is the one in UV-9, UV-327, UV-356, zinc oxide, titanium oxide.
4. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described benefitStrong agent is high styrene resin or phenolic resins.
5. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described shortEntering agent is cobalt naphthenate, cobalt iso-octoate, zinc diethyl dithiocarbamate, DMDSFor one or more in carbaminate.
6. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described increasingMould agent and be diisononyl phthalate, dibutyl phthalate, phthalic acid di-secondary pungentOne in ester, diisooctyl phthalate.
7. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described anti-Old agent is N-phenyl-α-aniline, two (2.2-dimethyl benzyl) diphenylamines of 4.4-, 6-ethyoxyl-2,2,4-trimethyl-1, the one in 2-dihyaroquinoline.
8. the wear-resisting adhesive tape of one according to claim 1, is characterized in that: described siliconHydrochlorate mineral are length 10～20 μ m, the calcium carbonate crystal whisker that draw ratio is 15～25.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610066159.2A CN105602465A (en) | 2016-01-29 | 2016-01-29 | Wear-resistant adhesive tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610066159.2A CN105602465A (en) | 2016-01-29 | 2016-01-29 | Wear-resistant adhesive tape |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105602465A true CN105602465A (en) | 2016-05-25 |
Family
ID=55982836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610066159.2A Pending CN105602465A (en) | 2016-01-29 | 2016-01-29 | Wear-resistant adhesive tape |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105602465A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321151A (en) * | 2018-08-30 | 2019-02-12 | 宁波吉象塑胶科技股份有限公司 | Mute adhesive tape |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1071937A (en) * | 1991-10-29 | 1993-05-12 | 阿克佐公司 | Tire and adhesive tape compositions |
| CN104311931A (en) * | 2014-11-04 | 2015-01-28 | 天长市高新技术创业服务中心 | High-strength ageing-resistant wear-resisting anti-flaming modified styrene butadiene rubber |
| CN104861234A (en) * | 2015-04-28 | 2015-08-26 | 安徽同丰橡塑工业有限公司 | Wear-resistant styrene butadiene rubber material |
-
2016
- 2016-01-29 CN CN201610066159.2A patent/CN105602465A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1071937A (en) * | 1991-10-29 | 1993-05-12 | 阿克佐公司 | Tire and adhesive tape compositions |
| CN104311931A (en) * | 2014-11-04 | 2015-01-28 | 天长市高新技术创业服务中心 | High-strength ageing-resistant wear-resisting anti-flaming modified styrene butadiene rubber |
| CN104861234A (en) * | 2015-04-28 | 2015-08-26 | 安徽同丰橡塑工业有限公司 | Wear-resistant styrene butadiene rubber material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321151A (en) * | 2018-08-30 | 2019-02-12 | 宁波吉象塑胶科技股份有限公司 | Mute adhesive tape |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Wan et al. | Superior fatigue resistant bioinspired graphene‐based nanocomposite via synergistic interfacial interactions | |
| Abdelmouleh et al. | Modification of cellulose fibers with functionalized silanes: effect of the fiber treatment on the mechanical performances of cellulose–thermoset composites | |
| Idicula et al. | A study of the mechanical properties of randomly oriented short banana and sisal hybrid fiber reinforced polyester composites | |
| JP2008174667A (en) | Active energy ray-curable adhesive composition and polarizing plate using the same | |
| El-Tayeb et al. | Evaluation of glass fiber reinforced polyester composite for multi-pass abrasive wear applications | |
| Mansour et al. | A nanomechanical approach on the measurement of the elastic properties of epoxy reinforced carbon nanotube nanocomposites | |
| Ashori et al. | Glass fiber-reinforced epoxy composite with surface-modified graphene oxide: enhancement of interlaminar fracture toughness and thermo-mechanical performance | |
| Sarath Kumar et al. | Synergistic effect of carbon fabric and multiwalled carbon nanotubes on the fracture, wear and dynamic load response of epoxy-based multiscale composites | |
| EP3283448A1 (en) | Graphite oxide reinforced fiber in hosts such as concrete or asphalt | |
| Aziz et al. | A comparative assessment of different dispersing aids in enhancing magnetorheological elastomer properties | |
| CN105602465A (en) | Wear-resistant adhesive tape | |
| Manroshan et al. | Effect of nanosized calcium carbonate on the mechanical properties of latex films | |
| Ponnarengan et al. | Evaluation of mechanical properties of novel GLARE laminates filled with nanoclay | |
| Mayer et al. | Adhesion of functional layers based on epoxy and polyurethane resins for aluminum substrate | |
| Umeki et al. | A new unidirectional carbon fiber prepreg using physically modified epoxy matrix with cellulose nano fibers and spread tows | |
| JP2015171770A (en) | Glass with scattering prevention performance | |
| Kim et al. | Contact splitting in dry adhesion and friction: reducing the influence of roughness | |
| Saber et al. | Enhancement of barrier and mechanical performance of steel coated with epoxy filled with micron and nano alumina fillers | |
| CN105542675A (en) | Preparation method of wear-resistant adhesive tape | |
| Sabagh et al. | SiAlON nanoparticles effect on the behaviour of epoxy coating | |
| Lal et al. | Study on the repeatability of manufacturing nano-silica (SiO2) reinforced composite laminates | |
| KR102046146B1 (en) | Silicone release film with excellent stability in peeling force over time and optical display using the same | |
| Kurita et al. | The insert effect of cellulose nanofiber layer on glass fiber‐reinforced plastic laminates and their flexural properties | |
| CN108610896A (en) | A kind of transparent hard layer coating fluid composition, a kind of Obstruct membrane and a kind of quantum dot film | |
| JP6790827B2 (en) | Laminated film and its manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160525 |
|
| RJ01 | Rejection of invention patent application after publication |